Polyvinyl Alcohol Or Modified Form Thereof Patents (Class 524/503)
-
Patent number: 5143966Abstract: In a vinyl acetate-ethylene copolymer emulsion prepared by the aqueous emulsion copolymerization of vinyl acetate and ethylene in the presence of a polyvinyl alcohol stabilizing system, the improvement which comprises a vinyl acetate-ethylene copolymer emulsion prepared in the presence of a stabilizing system consisting essentially of:(a) 0.2 top 1.5 wt % low molecular weight, partially hydrolyzed polyvinyl alcohol,(b) 0.5 to 2.5 wt % medium molecular weight, partially hydrolyzed polyvinyl alcohol, and(c) 1 to 4 wt % medium molecular weight and/or high molecular weight, fully hydrolyzed polyvinyl alcohol,the weight percentages based on vinyl acetate monomer.Type: GrantFiled: November 7, 1990Date of Patent: September 1, 1992Assignee: Air Products and Chemicals, Inc.Inventors: Hsueh-Chi Lee, William E. Lenney
-
Patent number: 5141973Abstract: A method of preparing a polyvinyl alcohol hydrogel contains the steps of charging an aqueous solution of a polyvinyl alcohol having a degree of hydrolysis of not less than 95 mol % and an average polymerization degree of not less than 500 into a container, the aqueous solution containing the polyvinyl alcohol in a concentration of not less than 5 wt. %, cooling the aqueous solution of the polyvinyl alcohol at a temperature of from - (minus) 9.degree. C. to - (minus) 3.degree. C., subjecting the aqueous solution of the polyvinyl alcohol to physical stimulation, and then maintaining the aqueous solution of the polyvinyl alcohol at a temperature of from - (minus) 5.degree. C. to + (plus) 5.degree. C. The polyvinyl alcohol hydrogel may be contained in a plastic container. An MRI phanton is composed of the plastic container containing such polyvinyl alcohol hydrogel.Type: GrantFiled: December 27, 1989Date of Patent: August 25, 1992Assignee: Nippon Oil Co., Ltd.Inventors: Tomokazu Kobayashi, Toshio Morihiro
-
Patent number: 5122557Abstract: The present invention relates to light polarizing films containing water-soluble, transparent organic polymers and dichroic dyes capable of fluorescence and to new dichroic dyes.Type: GrantFiled: June 3, 1991Date of Patent: June 16, 1992Assignee: Bayer AktiengesellschaftInventors: Uwe Claussen, Friedrich W. Krock
-
Patent number: 5118741Abstract: Such food packing materials as heat shrinkable films or such formed containers for food as bottles are manufatured by forming resin compositions of the following compostions: (a) 100 weight parts of vinyl chloride based resin obtained by adding 0.005 to 0.5 weight parts of partially saponified polyvinyl alcohol, degree of saponification 20-55 mol %, means degree of polymerization 150-600, to 100 weight parts of loaded vinyl chloride monomer or a mixture of vinyl based monomer with vinyl chloride as main, during suspension-polymerizing in an aqueous medium under the existence of 0.03-0.08 weight parts of partially saponified polyvinyl alcohol, degree of saponification 65-80 mol %, means degree of polymerization 600-1000, or else in slurry after completion of the suspension-polymerizing: (b) 0.3 to 5 weight parts of non-toxic stabilizer for food which is a liquid composite stabilizer; and (c) 4 to 15 weigth parts of butadiene-styrene based copolymer resin.Type: GrantFiled: September 5, 1991Date of Patent: June 2, 1992Assignee: Shin-Etsu Chemical Co., Ltd.Inventors: Tadashi Amano, Shigehiro Hoshida
-
Patent number: 5118751Abstract: The invention relates to a redispersible powder composition comprisinga) a base polymer from the group comprising vinyl ester polymers, styrene polymers, acrylate polymers and vinyl chloride polymers,b) 2 to 15% by weight, relative to the base polymer, of polyvinyl alcohol having a degree of hydrolysis of 85 to 94 mol % and a Hoppler viscosity of 2 to 25 mPa.multidot.s,c) 3 to 30% by weight, relative to the total weight of polymer components, of a fine antiblocking agent,d) 0.1 to 2% by weight, relative to the base polymer, of antifoams, which containse) 1 to 8% by weight, relative to the base polymer, of a fully hydrolyzed 1-alkylvinyl ester/vinyl ester copolymer having a Hoppler viscosity of 1 to 5 mPa.multidot.s. The redispersible composition according to the invention is suitable in particular for use in flowing, hydraulically setting leveling compounds.Type: GrantFiled: August 23, 1991Date of Patent: June 2, 1992Assignee: Wacker Chemie GmbHInventors: Joachim Schulze, Hardy Herold, Juergen Hinterwinkler
-
Patent number: 5116900Abstract: An aqueous coating composition for glass fibers is provided which contains a polycarbonate precursor material and a water soluble film former or binder. The resulting coated glass fibers have excellent flexibilty with little or no powdering of the coating composition off the fibers.Type: GrantFiled: February 13, 1990Date of Patent: May 26, 1992Assignee: Owens-Corning Fiberglas CorporationInventors: Martin C. Flautt, Leonard J. Adzima
-
Patent number: 5112902Abstract: A process for preparing particles of a high water-absorbent resin which comprises mixing a powder of a high water-absorbent resin having a water content of 10 to 60% by weight with a powder of water-soluble high molecular weight compound and drying the mixture. The obtained particles according to the present invention are suitable for use of sanitary goods, water-retaining agents or soil conditioner in the fields of agriculture and horticulture and other various uses.Type: GrantFiled: May 17, 1990Date of Patent: May 12, 1992Assignee: Nippon Gohsei Kagaku Kogyo Kabushiki KaishaInventors: Tetsuo Moriya, Susumu Kondo, Shinji Sanuki
-
Patent number: 5110859Abstract: Novel polyvinyl alcohols include, in the polymeric backbone, vinyl units containing pendant hydrophobic groups. The polymers are made by hydrolysis of corresponding polyvinyl acylates under conditions are avoid hydrolysis of the pendant hydrophobic groups from the polymer. These groups are preferably bonded into the polymer as allyl ether units. The hydrophobic units act as internal plasticizers in films or other shaped articles formed from the polymers and, in particular, gives significant benefit in viscosity and other rheology characteristics of aqueous compositions formed from the polymer.Type: GrantFiled: October 19, 1990Date of Patent: May 5, 1992Inventors: Peter Flesher, David Farrar
-
Patent number: 5110856Abstract: A vinyl acetate-ethylene copolymer emulsion is disclosed, comprising a vinyl acetate-ethylene copolymer composed of from 10 to 40% by weight of an ethylene unit and from 90 to 60% by weight of a vinyl acetate unit and an emulsifying dispersant in an amount of from 2.5 parts by weight or more but less than 5.0 parts by weight per 100 parts by weight of the vinyl acetate unit, and having a mean particle size of not larger than 0.9 .mu.m and a solids content of from 65 to 75% by weight, wherein the emulsifying dispersant contains from 1.0 to 1.9 parts by weight of partially saponified polyvinyl alcohol prepared so as to have an average polymerization degree of from 300 to 1,000 and from 1.0 to 3.0 parts by weight of a polyoxyethylene nonionic surface active agent having an HLB of from 16.5 to 17.5 per 100 parts by weight of the vinyl acetate unit. A process for producing the vinyl acetate-ethylene copolymer is also disclosed.Type: GrantFiled: September 17, 1991Date of Patent: May 5, 1992Assignee: Sumitomo Chemical Co., Ltd.Inventors: Takeo Oyamada, Yoshito Taira, Masayoshi Nitta, Yasuo Kaneshima, Tateshi Kurino, Shizuo Narisawa
-
Patent number: 5110657Abstract: An anti-skid coating composition for coating various substrates including structural panel board surfaces, comprises a binder made of urea formaldehyde resin, polyvinyl acetate, ammonium chloride and a dispersant. The binder is used in conjunction with an aggregate, such as walnut shells. A method is also provided for coating the substrates to impart slip resistance thereto.Type: GrantFiled: May 22, 1990Date of Patent: May 5, 1992Assignee: Reichhold Chemicals, Inc.Inventor: Winston C. Ainslie
-
Patent number: 5110855Abstract: A blend consisting essentially of a major portion of an amorphous polyamide and a minor portion of an ethylene vinyl alcohol copolymer exhibits gas barrier properties which are less dependent on humidity than are those of either of the component polymers. Films and laminated structures which incorporate the material of these blends are suitable for use as packaging materials.Type: GrantFiled: April 17, 1990Date of Patent: May 5, 1992Assignee: E. I. Du Pont de Nemours and CompanyInventor: Philip S. Blatz
-
Patent number: 5104914Abstract: It is the object of this invention to provide a method for the preparation of an antiblocking agent which is effective in its antiblocking activity but is considerable less visible in photographic enlargements made from the film containing the antiblock of this invention.There is described a process for the preparation of monodispersed polymer particles between 5 and 10 microns in diameter which comprises preparing a dispersion of monosized seed polymer particles and then adding to this dispersion an ethylenically unsaturated monomer which is different from the monomer used to prepare the seed polymer particles, together with a polymerization initiator and completing the polymerization, the refractive index of one of the polymers produced being greater than 1.54 and the refractive index of the other polymer being less than 1.54.The refractive index of gelatin is 1.54. There is produced by the process of the present invention a particle which comprises two polymers.Type: GrantFiled: May 10, 1990Date of Patent: April 14, 1992Assignee: Ilford LimitedInventors: Peter J. Elton, John L. Cawse
-
Patent number: 5100952Abstract: A gel-forming composition capable of plugging highly permeable zones in a subterranean formation. The composition comprises water, a water-dispersible polyvinyl alcohol copolymer and a crosslinking agent which is a mixture of an aldehyde and a phenolic component in an amount effective to cause gelation of the aqueous solution of the copolymer. The resultant gel is exceptionally thermally stable and, therefore, can be used as an effective profile control agent in all enhanced oil recovery operations, including steam flooding. Also provided is a process for recovering oil from a subterranean oil-bearing formation.Type: GrantFiled: May 18, 1990Date of Patent: March 31, 1992Assignee: Mobil Oil CorporationInventors: Dennis H. Hoskin, Paul Shu
-
Patent number: 5100949Abstract: This invention provides(i) an overcoating agent for heat-sensitive recording materials which contains as an active component an emulsion of a graft copolymer prepared by graft-copolymerizing an acrylamide or methacrylamide as a monomer (A), a methyl acrylate or methacrylate as a monomer (B), an acrylic or methacrylic acid as a monomer (C) and if required, a monomer other than said monomers as a monomer (D) which is copolymerizable therewith onto a polyvinyl alcohol in the presence of a fatty acid ester of sucrose and water, and(ii) an overcoating agent for heat-sensitive recording materials which contains as an active component an emulsion of a graft copolymer prepared by graft-copolymerizing a methyl acrylate or methacrylate as a monomer (E), a lower hydroxyalkyl acrylate or methacryalte as a monomer (F), an acrylic or methacrylic acid as a monomer (G) and if required, a monomer other than said monomers as a monomer (H) which is copolymerizable therewith onto a polyvinyl alcohol in the presence of a fatty acType: GrantFiled: November 8, 1989Date of Patent: March 31, 1992Assignee: Arakawa Chemical Industries, Ltd.Inventors: Nobuyuki Takahashi, Tetsuya Inoue, Mika Koda
-
Patent number: 5100944Abstract: The use of ethylene glycol diacetate in place of methyl chloroform (1,1,1-trichloroethane) in conventional waterborne packaging and converting adhesives provides comparable adhesive products with reduced environmental and health related problems.Type: GrantFiled: August 14, 1990Date of Patent: March 31, 1992Assignee: National Starch and Chemical Investment Holding CorporationInventors: John W. Walker, Joseph Wieczorek, David W. Lydzinski, Malie Tsurunaga
-
Patent number: 5098943Abstract: A water repellent having the following components (A), (B), (C) and (D) emulsified in water:(A) a wax having a melting point of from 40.degree. to 90.degree. C.;(B) a styrene-maleic anydride copolymer;(C) a water-soluble alkaline compound; and(D) a polyvinyl alcohol having a saponification degree of at least 85 mol %.Type: GrantFiled: May 9, 1991Date of Patent: March 24, 1992Assignee: Mitsubishi Kasei CorporationInventors: Toru Tagawa, Takao Tadenuma, Yasoji Ozawa
-
Patent number: 5096958Abstract: A hydrophilic surface treatment chemicals comprising, on a solid basis,(a) 1-10 parts by weight of at least partially saponified polyvinyl acetate having a saponification degree of 45 or more and a polymerization degree of 100-600,(b) 0.3-15 parts by weight of water-soluble nylon, and(c) 0.1-5 parts by weight of a water-soluble amino resin,a weight ratio of the component (b) to the total of the components (a) and (c), (b)/[(a)+(c)], being in the range of 1-1/4, and a weight ratio of the component (a) to the component (c), (a)/(c), being in the range of 1/0.05-1/0.5. The hydrophilic surface treatment bath is prepared by properly diluting the chemicals for surface-treating aluminum members.Type: GrantFiled: August 10, 1990Date of Patent: March 17, 1992Assignee: Nippon Paint Co., Ltd.Inventors: Shigeyuki Meguro, Kiyotada Yasuhara
-
Patent number: 5092953Abstract: A water-based adhesive composition comprising a polyvinyl alcohol stabilized vinyl chloride-ethylene copolymer latex and 5-50 wt %, based on copolymer, of a polyisocyanate material. The adhesive composition has improved pot life and is used to prepare wood composites demonstrating improved water resistance.Type: GrantFiled: November 13, 1989Date of Patent: March 3, 1992Assignee: Air Products and Chemicals, Inc.Inventors: Richard Derby, Bheema R. Vijayendran
-
Patent number: 5091448Abstract: A new stable liquid suspension of water soluble polymer, and a method of preparation are provided. Such compositions comprise of at least an iso-parrafinic oil medium, one styrene/isoprene copolymer, a water soluble polymer and preferably some hydrophobic fumed silica mixed together in the appropriate quantities and conditions.Type: GrantFiled: April 24, 1990Date of Patent: February 25, 1992Assignee: Phillips Petroleum CompanyInventors: John E. Hostettler, Marshall D. Bishop
-
Patent number: 5091463Abstract: A resin composition comprising polyarylene sulfide, polyvinylidene fluoride and optionally ultrafine particles. A method of adhering a polyarylene sulfide article and a polyvinylidene fluoride article by using a resin composition comprising polyarylene sulfide, polyvinylidene fluoride and optionally ultrafine particles as an adhesive comprises the steps of melting portions of the polyarylene sulfide article and the polyvinylidene fluoride article to be adhered and the adhesive at a temperature between a melting point of the polyarylene sulfide and 400.degree. C.; bringing the portions to be adhered into contact with each other via the adhesive in a molten state; and cooling the adhered portions in a contact state.Type: GrantFiled: October 23, 1989Date of Patent: February 25, 1992Assignee: Tonen Sekiyukagaku Kabushhiki KaishaInventors: Shunji Onishi, Yoshinori Ichikawa, Junji Takeuchi
-
Patent number: 5089555Abstract: A thermosetting powder composition is disclosed which comprises:a functional thermoplastic resin capable of reacting with a cyanate group and a molecular weight of at least 10,000;a polyfunctional cyanate compound; anda viscosity controlling agent which is a compound having at least one functional group capable of reacting with the functional thermoplastic resin and/or the polyfunctional cyanate compound and a molecular weight of less than 10,000. The composition is useful as a powder coating composition or a raw material for the formation of molded articles.Type: GrantFiled: September 8, 1989Date of Patent: February 18, 1992Assignee: Somar CorporationInventors: Katsuji Kitagawa, Hideki Tashima, Kunimitsu Matsuzaki
-
Patent number: 5084503Abstract: A vinyl acetate-ethylene copolymer emulsion comprising an aqueous colloidal dispersion of a copolymer containing 65 to 90 wt % vinyl acetate and 10 to 35 wt % ethylene prepared by the emulsion polymerization of the monomers in the presence of a stabilizing system consisting essentially of an 86 to 90 mole % partially hydrolyzed polyvinyl alcohol, a 98 to 99+ mole % fully hydrolyzed polyvinyl alcohol, in a partially hydrolyzed polyvinyl alcohol:fully hydrolyzed polyvinyl alcohol weight ratio from 3:1 to 1:3, and a nonionic polyalkoxylated surfactant.Also disclosed is a carpet backing adhesive composition comprising such a vinyl acetate-ethylene copolymer emulsion, about 0.1 to 3 parts by weight dispersant, about 0.1 to 10 parts by weight thickening agent and between 300 and about 1000 parts by weight filler, all of the components being per 100 parts of the copolymer.Type: GrantFiled: December 22, 1989Date of Patent: January 28, 1992Assignee: Air Products and Chemicals, Inc.Inventor: John G. Iacoviello
-
Patent number: 5070134Abstract: A vinyl acetate-ethylene copolymer emulsion is disclosed, comprising a vinyl acetate-ethylene copolymer composed of from 10 to 40% by weight of an ethylene unit and from 90 to 60% by weight of a vinyl acetate unit and an emulsifying dispersant in an amount of from 2.5 parts by weight or more but less than 5.0 parts by weight per 100 parts by weight of the vinyl acetate unit, and having a mean particle size of not larger than 0.9 .mu.m and a solids content of from 65 to 75% by weight, wherein the emulsifying dispersant contains from 1.0 to 1.9 parts by weight of partially saponified polyvinyl alcohol prepared so as to have an average polymerization degree of from 300 to 1,000 and from 1.0 to 3.0 parts by weight of a polyoxyethylene nonionic surface active agent having an HLB of from 16.5 to 17.5 per 100 parts by weight of the vinyl acetate unit. A process for producing the vinyl acetate-ethylene copolymer is also disclosed.Type: GrantFiled: February 28, 1990Date of Patent: December 3, 1991Assignee: Sumitomo Chemical Co., Ltd.Inventors: Takeo Oyamada, Yoshito Taira, Masayoshi Nitta, Yasuo Kaneshima, Tateshi Kurino, Shizuo Narisawa
-
Patent number: 5070126Abstract: A film easily soluble in cold water comprises a water-soluble copolymer composed of 6 to 40 mol % of an allyl ester moiety and 94 to 60 mol % of a vinyl ester moiety and having a degree of sponification of not less than 65 mol %. The film is easily soluble in cold water and such solubility in cold water is not lowered even if it comes into contact with either alkaline or acidic materials and it can suitably used as wrapping material for packages which are directly thrown into water together with packed materials.Type: GrantFiled: December 21, 1990Date of Patent: December 3, 1991Assignee: Aicello Chemical Co., Ltd.Inventors: Shigekazu Toyonishi, Takashi Nakajima
-
Patent number: 5064938Abstract: The invention discloses a process for the production of a particulate polymer which contains few fine particles and has a narrow particle size distribution and a controlled bulk specific gravity. Characteristic features of the process of this invention reside in that a polymer latex obtained by emulsion polymerization is successively processed through the following steps (I) and (II):Step (I) The polymer latex is coagulated into a slurry in which particles thus coagulated are dispersed in water.Step (II) The slurry obtained in Step (I), an organic liquid almost insoluble in water and incapable of dissolving the polymer and water are mixed for granulation under the conditions that(a) The proportion of water in the whole mixture is 50-85 wt. %,(b) The amount of the organic liquid is 15-150 parts by weight per 100 parts by weight of the polymer in the polymer latex, and(c) The temperature T (.degree.C.) of the whole mixture is maintained for 0.Type: GrantFiled: November 23, 1990Date of Patent: November 12, 1991Assignee: Mitsubishi Rayon Co., Ltd.Inventors: Fumio Suzuki, Hideaki Habara, Yutaro Fukuda, Haruki Sato, Hiromasa Inada
-
Patent number: 5064894Abstract: Non-agglomerating elastomeric organopolysiloxane particulates having a mean particle size ranging from 50 .mu.m to 3 mm, uniformly coated with silica powder on the face surfaces thereof and well adapted as a soft filler material for natural or synthetic polymers or as a controlled release dosage form, are produced by (a) forming an oil-in-water emulsion of .alpha.,.omega.-dihydroxydiorganopolysiloxane oils, silica powder, a platinum curing catalyst and, optionally, an active principle such as a medicament or an agrochemical, and then (b) breaking and polycondensation crosslinking such emulsion into the desired particles by heating it to a temperature ranging from 40.degree. to 100.degree. C.Type: GrantFiled: January 19, 1990Date of Patent: November 12, 1991Assignee: Rhone-Poulenc ChimieInventors: Daniel Desmonceau, Rafael Jorda
-
Patent number: 5064713Abstract: An elastomeric adhesive composition useful in resurfacing applications is provided. The composition includes a liquid dispersion of a polar latex resin binder, a chemical plasticizer, a volatile glycol ether solvent and a thickening agent. The binder is an emulsion of water and a polyvinyl acetate homopolymer with a polyvinyl alcohol protective colloid and is present in a concentration effective in adhering a resurfacing fabric to a surface wetted with the composition. The chemical plasticizer acts to plasticize and tackify the latex resin binder. The thickening agent is present in an amount effective to modify the viscosity of the composition so that it will not flow once applied to a surface. In addition, the invention comprehends a resurfacing composition and a method of resurfacing.Type: GrantFiled: January 14, 1991Date of Patent: November 12, 1991Assignee: Lindsay Finishes, Inc.Inventors: Donald C. DuLaney, Robert H. Lindsay
-
Patent number: 5057570Abstract: A method for preparing a high solids, aqueous paper coating composition which comprises adding dry particulate solids of a partially hydrolyzed, low molecular weight polyvinyl alcohol to a high solids, aqueous paper coating composition and mixing without external heating until dissolved, preferably by mixing the polyvinyl alcohol solids into the aqueous pigment dispersion followed by the addition of binders and other additives to make the paper coating composition.Type: GrantFiled: June 13, 1990Date of Patent: October 15, 1991Assignee: Air Products and Chemicals, Inc.Inventors: Gerald D. Miller, Michael M. Baas
-
Patent number: 5051462Abstract: A halogen-containing thermoplastic resin composition comprising a halogen-containing thermoplastic resin (A), a metallic soap (B) and an ash- and alkali metal-lean ethylene-vinyl acetate copolymer hydrolysate (C) having an ethylene content of 20 to 75 mole percent, a degree of saponification not less than 50 mole percent, an ash content not exceeding 300 ppm and an alkali metal content not exceeding 200 ppm, the proportions of (B) and (C) based on 100 parts of weight by (A) being 0.1 to 5 parts by weight and 0.1 to 5 parts by weight, respectively. The composition may further include, in addition to (A), (B) and (C) mentioned above, at least one compound (D) selected from the group consisting of .beta.-diketone compounds, organic phosphorous esters and aminocarboxylic acid compounds, the proportion of (D) based on 100 parts by weight of (A) being 0.Type: GrantFiled: August 11, 1988Date of Patent: September 24, 1991Assignee: Nippon Gohsei Kagaku Kogyo Kabushiki KaishaInventors: Hiroshi Takida, Takamasa Moriyama, Yoshimi Akamatu, Makoto Kunieda
-
Patent number: 5034281Abstract: The present invention provides resin compositions comprising a blend of two different saponified products of ethylene-vinyl acetate copolymers. The composition is much improved compared to a single EVOH in flexibility without adversely affecting the transparency and gas barrier property. Laminate films comprising at least one layer of said composition are excellent in resistance to dropping shock, ability to prevent air-back, skin-pack adaptability and shrink-packaging capability.Type: GrantFiled: September 10, 1990Date of Patent: July 23, 1991Assignee: Kuraray Co., Ltd.Inventors: Akihiko Kawasaki, Tohei Moritani
-
Patent number: 5032632Abstract: A composition of a copolymer of ethylene and vinyl alcohol, 0.01 to 0.5 weight percent of a monovalent or divalent metal salt of an aliphatic carboxylic acid having 3 to 9 carbon atoms and 0.05 to 0.5 weight percent of a hindered phenolic antioxidant exhibits improved stability toward oxidative gel formation at elevated temperatures.Type: GrantFiled: May 15, 1990Date of Patent: July 16, 1991Assignee: E. I. du Pont de Nemours and CompanyInventor: Ronald L. Saxton
-
Patent number: 5032363Abstract: Ion selective parts are described which comprise a polymeric material, an ion selective component and optionally furthermore a plasticizer and which ion sensitive parts are suited for the determination of the concentration or activity of ions in liquid media. The polymeric material of said ion sensitive parts is a copolymer in which 5-25 mol-% of the monomeric units of said copolymer are substituted with one or more hydrophilic substituents which are selected from the group comprising hydroxy groups, carboxylic acid groups, sulphonic acid groups and phosphonic acid groups. The inventive ion selective parts have, compared with corresponding ion selective parts in which the polymeric material is free of the stated hydrophilic groups or has a lower content of said hydrophilic groups, a better stability of the standard potential E.sub.o and a lower asymmetry potential or no asymmetry potential at all.Type: GrantFiled: August 24, 1988Date of Patent: July 16, 1991Assignee: Willi Moller AGInventors: Wilhelm Simon, Lucas F. J. Durselen
-
Patent number: 5019609Abstract: A film easily soluble in cold water includes a water-soluble copolymer composed of 2 to 40 mol % of an allyl ester moiety, 97.5 to 50 mol % of a vinyl ester moiety and 0.5 to 10 mol % of at least one member selected from the group consisting of unsaturated monocarboxylic acid, unsaturated dicarboxylic acid and anhydrides thereof, and the copolymer has a degree of saponification of not less than 65 mol %. The film is easily soluble in cold water and such solubility in cold water is not lowered even if the film comes into contact with either alkaline or acidic materials and it can suitably used as wrapping material for packages which are directly thrown into water together with packed materials. The copolymer may be used of such an allyl ester, vinyl ester and further one of unsaturated carboxylic acids.Type: GrantFiled: May 11, 1990Date of Patent: May 28, 1991Assignee: Aicello Chemical Co., Ltd.Inventors: Shigekazu Toyonishi, Takashi Nakajima
-
Patent number: 5006593Abstract: Dispersions of polymer systems comprising two normally incompatible polymer networks, one of which is held together by physical interactions and the other by chemical cross-links, the networks being catenated, are useful for making coating compositions, films and molded articles.Type: GrantFiled: June 16, 1988Date of Patent: April 9, 1991Assignee: E. I. Du Pont de Nemours and CompanyInventors: Donald E. Brasure, Eugene G. Sommerfeld
-
Patent number: 4997874Abstract: An aqueous suspension of a multivalent-metal-modified salicylic acid resin, which is suitable for use in the production of color-developing sheets for pressure-sensitive recording paper sheets, contains a specific multivalent-metal-modified salicylic acid resin at the first-mentioned resin. Fine particles of the specific multivalent-metal-modified salicylic acid is dispersed in an aqueous solution of a dispersant composed of at least one compound selected from the group consisting of:(a) water-soluble anionic high-molecular compounds composed of polyvinyl alcohol derivatives containing sulfonic acid groups in their molecules, and salts thereof,(b) acrylamide-modified polyvinyl alcohols, and(c) water-soluble anionic high-molecular compounds composed of polymers or copolymers comprising particular styrenesulfonic acid derivatives as their essential components.The aqueous dispersion is prepared by finely grinding the specific multivalent-metal-modified salicylic acid in the aqueous solution of the dispersant.Type: GrantFiled: March 17, 1988Date of Patent: March 5, 1991Assignee: Mitsui Toatsu Chemicals, IncorporatedInventors: Makoto Asano, Kiyoharu Hasegawa, Masatoshi Takagi, Akihiro Yamaguchi, Keizaburo Yamaguchi, Yoshimitsu Tanabe, Hiroyuki Akahori
-
Patent number: 4983432Abstract: A barrier resin composition is disclosed is which contains 50 to 95 weight percent ethylene/vinyl alcohol copolymer having a melt flow of 0.1 to 100 g/10 minutes as measured at 210.degree. C. and 50 to 5 weight percent mica having a particle size of less than 74 microns and an aspect ratio of from 10 to 150. The composition can be prepared by melt blending a mixture of the ethylene/vinyl alcohol copolymer and the mica. Alternatively, the composition can be prepared by forming a dispersion of this mica in a solution of the ethylene/vinyl alcohol copolymer followed by precipitating the ethylene/vinyl alcohol copolymer.Type: GrantFiled: December 20, 1988Date of Patent: January 8, 1991Assignee: E. I. Du Pont de Nemours and CompanyInventor: Thomas C. Bissot
-
Patent number: 4980404Abstract: One-component adhesives for adhesive bonds having increased high-temperature strengths contain(A) aqueous dispersions of carboxyl-containing polyacrylates and(B) organic polyamino compounds having a molecular weight of from 250 to 15,000 and an amino functionality greater than 5.Type: GrantFiled: March 7, 1989Date of Patent: December 25, 1990Assignee: BASF AktiengesellschaftInventors: Oral Aydin, Hans Kast
-
Patent number: 4975481Abstract: An aqueous contact adhesive containing an aqueous dispersion of a water-immiscible solvent. The aqueous contact adhesive can contain additives such as preservatives, anti-oxidants, thickeners and thixotropicizing agents, emulsifiers and protective colloids. The contact adhesive has outstanding properties, particularly in regard to the absence of surface tackiness of substrate surfaces coated with the contact adhesive and a high initial tack of the substrate surfaces fitted together under pressure.Type: GrantFiled: November 2, 1988Date of Patent: December 4, 1990Assignee: Henkel Kommanditgesellschaft auf AktienInventors: Horst Tamm, Franz-Bernhard Knop, Claus Kirchner
-
Patent number: 4954557Abstract: In a process for preparing a molded article by melt-molding a mixture of (A) a hydrolyzed ethylene-vinyl acetate copolymer having an ethylene content of 20 to 80% by mole and a degree of hydrolysis in the vinyl acetate units of at least 90% by mole and (B) an olefin resin, the improvement which comprises melt-molding said mixture in the presence of a hydrotalcite solid solution (C) having the formula (I):{(M.sub.1.sup.2+).sub.yl (M.sub.2.sup.2+).sub.y2 }.sub.1-x (M.sup.3+).sub.x (OH).sub.2 (A.sup.n-).sub.x/n.mH.sub.2 O (I)According to the process of the present invention, long run processability during melt-molding can be remarkably improved, and the obtained molded article has excellent qualities, e.g., the film has few fish eyes.Type: GrantFiled: January 25, 1989Date of Patent: September 4, 1990Assignees: Nippon Gohsei Kagaku Kogyo Kabushiki Kaisha, Kyowa Kogyo Kabushiki KaishaInventors: Teruo Iwanami, Shigeo Miyata, Takamasa Moriyama
-
Patent number: 4940743Abstract: A storage-stable aqueous emulsion of a low molecular weight, alkoxy-functional silicone resin by weight comprising approximately(a) 1-60% of a silicone resin having a viscosity of from 2 to 2000 mPa.s and of the formula ##EQU1## in which R.sup.1 is a monovalent hydrocarbon group having 1 to 14 carbon atoms,R.sup.2 is a monovalent hydrocarbon group having 1 to 18 carbon atoms,x is from 0.75 to 1.5, andy is from 0.2 to 2,(b) 0.1 to 10% of an emulsifying agent, and(c) 30 to 98.5% by weight of water, the emulsion having an alkaline pH, whereby the storage stability due to reduced hydrolysis is improved.Type: GrantFiled: March 22, 1985Date of Patent: July 10, 1990Assignee: Bayer AktiengesellschaftInventors: Wolfgang Grape, Ottfried Schlak, Armand de Montigny, Hermann Kober
-
Patent number: 4921898Abstract: A vinyl acetate-ethylene copolymer emulsion which is about 65-70% solids and has a viscosity of less than about 3,500 is disclosed. The emulsion is prepared by copolymerization of vinyl acetate and ethylene monomers in the presence of a stabilizing system consisting essentially of 2-4 wt %, based on vinyl acetate monomer, of a polyvinyl alcohol having a 100-600 degree of polymerization and 2-4wt %, based on vinyl acetate monomer, of a surfactant. Such emulsions demonstrate an improved speed of set as an adhesive.Type: GrantFiled: February 17, 1987Date of Patent: May 1, 1990Assignee: Air Products and Chemicals, Inc.Inventors: William E. Lenney, John G. Iacoviello
-
Patent number: 4910242Abstract: Moisture-hardening joint sealing compositions based on polyurethane prepolymers, swellable polymer powders, plasticizers and other auxiliaries have increased stability in storage when they contain C.sub.8 -C.sub.20 olefins as stabilizers.Type: GrantFiled: August 10, 1988Date of Patent: March 20, 1990Assignee: Henkel Kommanditgesellschaft auf AktienInventors: Tore Podola, Wolfgang Ernst, Winfried Emmerling
-
Patent number: 4906679Abstract: A process for production of corrugated board using an aqueous adhesive which contains polyvinyl alcohol and clay, or polyvinyl alcohol, clay and water-soluble boron compound, the ratio of clay to polyvinyl alcohol being in the range of 200 to 600 parts by weight based on 100 parts by weight of polyvinyl alcohol, the ratio of water-soluble boron compound being not more than 15 parts by weight based on 100 parts by weight of polyvinyl alcohol, the solid content of the adhesive being 25 to 60% by weight characterized in that(a) a polyvinyl alcohol concentration in the solution excluding solid other than polyvinyl alcohol from adhesive being in the region bounded by the following formulas:Y.gtoreq.-0.0014 X+9.4 (i)Y.ltoreq.-0.0061 X+26.3 (ii)200.ltoreq.X.ltoreq.3500 (iii)wherein Y is defined by the following formula: ##EQU1## and X is degree of polymerization of polyvinyl alcohol, (b) the viscosity of the adhesive measured by a Brookfield viscometer being from 200 to 6000 centipoises at 85.degree. C.Type: GrantFiled: November 29, 1988Date of Patent: March 6, 1990Assignees: Kuraray Co., Ltd., Rengo Co., Ltd.Inventors: Masateru Tokuno, Kinichi Shirakawa, Takatoshi Koyakumaru, Takuji Okaya, Hiroji Kohno, Hiroyuki Onishi
-
Patent number: 4900771Abstract: Thermally stable hot applied plastisol compositions are especially useful in the assembly of metal parts. The compositions have adhesive and sealant qualities which allow them to be used in automotive assembly plants. Compositions of the invention comprise as major ingredients finely divided polyvinyl chloride resin, plasticizer, thermoplastic polymeric resin which is solid at room temperature but softens to a flowable state at application temperature, and an adhesion promotion system. Optionally a filler, wax, heat stabilizer, pigment, wetting agent, or mixtures thereof may be added. The individual components work synergistically to get good application properties, metal adhesion, wash-out resistance, and paintability.Type: GrantFiled: January 26, 1989Date of Patent: February 13, 1990Assignee: Aster, Inc.Inventors: Michael J. Gerace, Janet M. Gerace
-
Patent number: 4892763Abstract: The invention relates to fiber glass reinforced resins suitable to be used for producing articles such as containers, bottles and the like by stretch-blowing, and it relates also to the so obtained articles.The resins are mixed with from 0.3% to 5% by weight of glass fibers having a diameter from 5 to 20 microns and chopped to lengths such that the length to diameter ratio ranges between 50 to 1000.Type: GrantFiled: January 16, 1985Date of Patent: January 9, 1990Inventor: Diego Duse
-
Patent number: 4888386Abstract: Both waterborne and solvent enamels can be sprayed in a common paint spray booth and be detackified by a composition comprising a blend of a melamine-formaldehyde polymer, polyvinyl alcohol and a styrene acrylate copolymer. The invention also contemplates the use of these compositions in detackifying paint in paint spray booths.Type: GrantFiled: February 21, 1989Date of Patent: December 19, 1989Assignee: Nalco Chemical CompanyInventors: Shu-Jen W. Huang, David W. Scheimann
-
Patent number: 4883714Abstract: An aqueous printing ink or its semi-aqueous or non-aqueous concentrate exemplified as comprising a substantially homogeneous system of the components:(1) from about 4 to about 80 weight % of one or more polyester materials having an acid component of from about 75 to about 84 mole % isophthalic acid and conversely from about 25 to about 16 mole % 5-sodiosulfoisophthalic acid, and having a glycol component of from about 45 to about 60 mole % diethylene glycol and conversely from about 55 to about 40 mole % 1,4-cyclohexanedimethanol or ethylene glycol or mixtures thereof;(2) from about 1 to about 60 weight % of pigment material;(3) from substantially none to about 90 weight % of water; and(4) from about 0.05 to about 30.0 weight % of polyvinyl alcohol.Type: GrantFiled: January 9, 1989Date of Patent: November 28, 1989Assignee: Eastman Kodak CompanyInventors: Rebecca R. Stockl, Kenneth R. Barton, Melvin A. Caldwell
-
Patent number: 4879336Abstract: In a coating slip for coating flat surfaces comprising an aqueous dispersion, with a solids content of 8 to 65% by weight, of 100 parts by weight of a pigment, 3 to 30 parts by weight of synthetic high-molecular-weight binder based on copolymers of acrylates, styrene, butadiene and unsaturated carboxylic acid esters and 0.5 to 2 parts by weight of a cobinder the improvement comprising using a cobinder polymer containing a large degree of hydroxyl groups comprising (a) 50 to 95% by weight of vinyl alcohol units, (b) 5 to 50% by weight of 1-alkylvinyl alcohol units of 1 to 4 alkyl carbon atoms, (c) 0 to 20% by weight of vinyl acylate units, (d) 0 to 20% by weight of allyl alcohol units and (e) 0 to 5% by weight of other polymerizable monomers having improved pigment shock behavior and very good activity as an optical brightener support.Type: GrantFiled: November 17, 1988Date of Patent: November 7, 1989Assignee: Wacker-Chemie GmbHInventors: Bernd Schilling, Karl-Ernst Fickert
-
Patent number: 4868053Abstract: The present invention relates to thermoplastically processible polymer materials with good mechanical properties and high flame resistance.Type: GrantFiled: April 13, 1988Date of Patent: September 19, 1989Assignee: Bayer AktiengesellschaftInventors: Christian Ohm, Stephen D. Pask, Wolfgang Wieder, Werner Obrecht, Karl-Heinz Schabel
-
Patent number: 4859717Abstract: A novel cross-linked polymer is obtained by cross-linking polyvinyl alcohol with a cross-linking agent which is a mixture of a phenolic component and an aldehyde or a mixture of a naphtholic component and an aldehyde. The resulting polymer is exceptionally thermally stable and, therefore, can be used as an effective permeability control agent in all enhanced oil recovery operations, including steam flooding.Type: GrantFiled: September 4, 1987Date of Patent: August 22, 1989Assignee: Mobil Oil CorporationInventors: Dennis H. Hoskin, Paul Shu