Solid Graft Or Solid Graft-type Copolymer With Other Solid Polymer, Sicp, Or Spfi Patents (Class 524/504)
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Patent number: 8975328Abstract: An aqueous liquid medium for analyzing, purifying or separating species in an element having walls or for treating the walls of an element. The medium includes at least a polymer consisting of several polymeric segments. The polymer is of the irregular block-copolymer or irregular comb-like polymer type and has on the average at least three junction points between polymeric segments of different chemical or topological nature. The medium may be used in methods for analyzing, purifying or separating species and methods for treating an element to be contacted with a fluid and/or species contained in the fluid during preservation, transport, analysis, purification or separation of the fluid.Type: GrantFiled: August 29, 2007Date of Patent: March 10, 2015Assignee: Institute CurieInventors: Jean-Louis Viovy, Valessa Barbier
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Publication number: 20150065637Abstract: A thermoplastic resin composition which contains (A) a graft copolymer that is obtained by grafting at least two kinds of monomers, which are selected from the group consisting of aromatic vinyl monomers, vinyl cyanide monomers and other copolymerizable monomers, onto a rubbery polymer, (B) a polymer that is obtained by polymerizing at least two kinds of monomers, which are selected from the group consisting of aromatic vinyl monomers, vinyl cyanide monomers and other copolymerizable monomers, and (C) a polyester that contains at least an alicyclic diol and an aromatic dicarboxylic acid. When the total of the components (A)-(C) is taken at 100% by mass, the component (A) is 15-50% by mass; and the component (A) has a linear expansion coefficient of from 12.5×10?5/° C. to 19×10?5/° C.Type: ApplicationFiled: March 29, 2013Publication date: March 5, 2015Applicant: ASAHI KASEI CHEMICALS CORPORATIONInventors: Akiko Sugioka, Tomoyuki Fujisawa
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Publication number: 20150057406Abstract: The architectural compositions, such as paints and stains, include an additive comprising a plurality of latex particles added to an existing mixture of opacifying pigments and a film-forming binder as an admixture. Each latex particle is made from a latex polymer copolymerized with a polymerizable surfactant. The latex polymer is a non-film forming polymer at ambient temperatures.Type: ApplicationFiled: November 3, 2014Publication date: February 26, 2015Inventors: Gary Dandreaux, Ashley Brewer, Caleb Jardel, Paulina Ogorzalek, Luz Clarena Shavel, Robert Sheerin
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Patent number: 8962740Abstract: An oxygen scavenging polyolefin composition and methods of making thereof are described herein. In one approach, the composition includes a continuous non-polar polyolefin matrix having oxygen scavenging domains dispersed therein. The oxygen scavenging domains include an oxidizable polymer, a transition metal catalyst or salt thereof, and a catalytic promoter effective to bind with oxygen passing through the continuous non-polar polyolefin matrix. The oxygen scavenging domains forming a discrete polar region within the continuous non-polar polyolefin matrix. The composition further includes a polymeric compatibilizer having a polar moiety and a non-polar moiety and in amounts effective to uniformly disperse the polar oxygen scavenging domains in the continuous non-polar polyolefin matrix.Type: GrantFiled: September 10, 2012Date of Patent: February 24, 2015Assignee: Kraft Foods Group Brands LLCInventors: Ying (Lora) Liang, Surendra Agarwal, Alexander Greenfield
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Publication number: 20150051333Abstract: A transparent ABS resin composition of the present invention comprises: an acrylonitrile-butadiene-styrene graft (g-ABS) copolymer which is copolymerized by mixture of acrylate based monomer, styrene based monomer, and acrylonitrile based monomer (a2) on butadiene based rubber polymer (a1); and (B) a styrene-acrylonitrile based copolymer, satisfies a relation denoted by Equation 1 and Equation 2 below, and has excellent impact resistance, scratch resistance, and transparency: 0?|X?Y|?0.005??(Equation 1) 0?|X?Z|?0.005??(Equation 2) In the Equations, X is refractive index of the acrylonitrile-butadiene-styrene graft (g-ABS) copolymer, Y is refractive index of the butadiene based rubber polymer (a1), and Z is refractive index of the styrene-acrylonitrile based copolymer (B).Type: ApplicationFiled: December 11, 2012Publication date: February 19, 2015Inventors: Jun Hwan Ahn, Il Jin Kim, Jae Wang Lee
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Patent number: 8957139Abstract: There is provided a microparticle/polyrotaxane-containing coating with high abrasion resistance and chemical resistance. There are also provided a microparticle/polyrotaxane-containing coating film and a coated article. The microparticle/polyrotaxane-containing coating includes a solvent-based coating material, a modified polyrotaxane having a caprolactone modification group (—CO(CH2)5OH) and microparticles having an average particle size of smaller than 380 nm. The microparticle/polyrotaxane-containing coating film is in the form of a layer of the microparticle/polyrotaxane-containing coating on an article to be coated. The coated article includes the microparticle/polyrotaxane-containing coating film and an article to be coated.Type: GrantFiled: February 9, 2010Date of Patent: February 17, 2015Assignees: Nissan Motor Co., Ltd., Advanced Softmaterials, Inc.Inventors: Tatsuya Suzuki, Kentarou Watanabe, Tetsurou Kikugawa, Masahiko Yamanaka, Changming Zhao, Yuki Hayashi, Yuki Amamoto
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Publication number: 20150036207Abstract: Pigment based inks are provided. The inks include a non-polar carrier fluid and a surface-functionalized pigment particle including a nitrogen-linked moiety to the surface of the pigment particle through a nitrogen link at one end of the nitrogen-linked moiety and a graft copolymer having two or three blocks attached at another end, the pigment particle suspended in the non-polar carrier fluid, the nitrogen-linked moiety further including an alkyl chain interposed between the nitrogen-linked moiety and the graft copolymer having the structure (I), where X is the nitrogen-linked moiety and Y is a copolymer, and the letter a is an integer between 0 and about 5,000, while the letter b is an integer of 2 or more.Type: ApplicationFiled: January 17, 2012Publication date: February 5, 2015Inventors: Zhang-Lin Zhou, Qin Liu
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Publication number: 20150038634Abstract: The present invention provides a composition including at least one polymerizable liquid component having at least one rubber impact modifier; at least one polymerization initiator, and at least one polymer component.Type: ApplicationFiled: July 30, 2014Publication date: February 5, 2015Inventors: Benjamin Jiemin SUN, Camelia GHERGULESCU, Andrew YOUNG
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Patent number: 8940822Abstract: A method of improving the transfer efficiency of applying a topcoat layer to a primed component includes applying an organic solventborne, carboxyl functional olefin based polymer composition to a substrate to provide a primed component before electrostatically applying a coating composition comprising principal resin and crosslinker to the primed component to form a topcoat layer, wherein the carboxyl functional olefin based polymer is neutralized with at least one amine-containing compound to form a salted carboxyl functional polymer.Type: GrantFiled: April 15, 2013Date of Patent: January 27, 2015Assignee: BASF Coatings GmbHInventors: Timothy S. December, William Merritt
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Publication number: 20150017451Abstract: There is described a polymer blend of a first and second polymer comprising: a) a first polymer of: vinyl (co)polymer; alkyd; urethane acrylic copolymer; polyurethane and/or polyester; b) a second copolymer from: b1) optionally at least 10 wt-% of one or derivatives of itaconic acid and/or isomers thereof; b2) up to 20 wt-% of one or more acid functional (or potentially acid functional) monomer(s) and b3) vinyl monomer(s) where wt % of each monomer (b1 to b3) is based on total (b) and where at least one of the first and second polymer is obtained from an itacon-functional monomer such as itaconic acid and/or its derivatives.Type: ApplicationFiled: February 4, 2013Publication date: January 15, 2015Inventors: Tijs Nabuurs, Jeffrey Stubbs, Matthew Stewart Gebhard, Gerardus Cornelis Overbeek
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Publication number: 20150011692Abstract: The invention relates to a thermoplastic molding compound containing: a) 50 to 85 parts of one or more terpolymers based on acrylnitril, alpha-methylstyrene, and styrene as component A, said terpolymers consisting of: 5 to 30 wt. % styrene, 15 to 35 wt. % acrylnitril, 50 to 70 wt. % alpha-methylstyrene, and 0 to 5 wt. % additional copolymerizable monomers, b) 15 to 50 parts of one or more impact-modifying graft rubbers with an olefinic double bond in the rubber phase as component B, c) 0 to 45 parts of one or more copolymers based on styrene and acrylnitril as component C, said copolymers consisting of: 71 to 81 wt. % styrene, 29 to 19 wt. % acrylnitril, and 0 to 5 wt. % additional copolymerizable monomers, and optionally additives and fibrous and/or particulate fillers. The thermoplastic molding compound leads to a reduced yellowing of the produced molded body.Type: ApplicationFiled: December 28, 2012Publication date: January 8, 2015Inventors: Peter Ittemann, Rolf Minkwitz, Pascal Hesse, Bernd Niedermaier
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Publication number: 20150005435Abstract: A thermoplastic resin composition includes (A) a first rubber-modified acrylic-based graft copolymer having an average rubber particle diameter of greater than or equal to about 100 nm and less than about 200 nm, (B) a second rubber-modified acrylic-based graft copolymer having an average rubber particle diameter of greater than or equal to about 200 nm and less than or equal to about 400 nm, (C) a first vinyl-based copolymer of an aromatic vinyl monomer and a unsaturated nitrile monomer, and (D) a second vinyl-based copolymer of an alkyl (meth)acrylate monomer, an aromatic vinyl monomer, and a unsaturated nitrile monomer. A molded article can be made using the same.Type: ApplicationFiled: April 9, 2014Publication date: January 1, 2015Applicant: Cheil Industries Inc.Inventors: Ji-Eun PARK, Ja-Yoon KIM, Kyun-Ha BAN, Chang-Min HONG
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Publication number: 20150005422Abstract: Disclosed herein are a thermoplastic resin composition and a molded article produced therefrom. The thermoplastic resin composition includes a thermoplastic resin, an inorganic filler, and a maleic anhydride (MAH)-grafted rubber, and has a coefficient of linear expansion from about 20×10?6 cm/cm° C. to about 35×10?6 cm/cm° C., as measured in accordance with ASTM D696. The thermoplastic resin composition can exhibit low shrinkage, excellent impact resistance and excellent flexural modulus and can have a good balance therebetween.Type: ApplicationFiled: June 19, 2014Publication date: January 1, 2015Inventors: Dong In HA, Dong Min PARK, Seung Shik SHIN, Kyuong Sik CHIN
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Publication number: 20140360405Abstract: Provided is a water-in-oil type emulsion adhesive, which is excellent in open shelf stability and thus a coating is difficult to be formed inside of a machine, which is excellent in storage stability, and which can be rapidly attached with low energy. The water-in-oil type emulsion adhesive includes an oil phase and an aqueous phase, wherein the oil phase contains at least an organic solvent and an emulsifier, the aqueous phase contains at least water and a polymer compound, and the aqueous phase has a particle diameter of from 1 to 100 ?m by a volume-based average diameter.Type: ApplicationFiled: June 10, 2014Publication date: December 11, 2014Inventors: Akiko HAYASHI, Yuki URANO, Kokoro KINOE, Hiroyuki OGAWA
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Publication number: 20140357779Abstract: Disclosed is a method to form an aqueous dispersion comprising a blend composition comprising or consisting essentially of about 75 to about 99.9 weight % of an ionomer composition and about 0.1 to about 25 weight % of an ethylene acrylate ester copolymer composition, a grafted polyolefin composition or a combination thereof, the method comprising mixing the solid blend composition with water heated to a temperature from about 80 to about 100° C.Type: ApplicationFiled: August 19, 2014Publication date: December 4, 2014Inventor: RICHARD ALLEN HAYES
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Patent number: 8901216Abstract: The present invention relates to impact-modified polyester/polycarbonate compositions containing: A) 41 to 80 parts by weight, in each case relative to the sum of the parts by weight of components A+B+C+D, of aromatic polycarbonate, B) 5 to 40 parts by weight, in each case relative to the sum of the parts by weight of components A+B+C+D, of polyester with a content of isophthalic acid building blocks, C) 1 to 15 parts by weight, in each case relative to the sum of the parts by weight of components A+B+C+D, of rubber-modified graft polymer, D) 0 to 25 parts by weight, in each case relative to the sum of the parts by weight of components A+B+C+D, of a flame retardant, E) 0 to 20 parts by weight, in each case relative to the sum of the parts by weight of components A+B+C+D=100, of vinyl (co)polymer, F) 0 to 50 parts by weight, in each case relative to the sum of the parts by weight of components A+B+C+D=100, of additives, wherein all the stated parts by weights in the present application are normalized such thatType: GrantFiled: August 22, 2011Date of Patent: December 2, 2014Assignee: Bayer MaterialScience AGInventors: Achim Feldermann, Eckhard Wenz
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Patent number: 8889767Abstract: The thermoplastic molding composition comprises a) as component A, from 3 to 78% by weight of one or more styrene copolymers which have no units derived from maleic anhydride, b) as component B, from 15 to 90% by weight of one or more polyamides, c) as component C, from 5 to 50% by weight of one or more impact-modifying graft rubbers without olefinic double bonds in the rubber phase, d) as component D, from 1 to 25% by weight of one or more styrene copolymers which have, based on the entire component D, from 0.5 to 5% by weight of units derived from maleic anhydride, e) as component E, from 1 to 30% by weight of one or more further rubbers based on olefinic monomers without core-shell structure, and having at least 0.1% by weight of functional monomers, f) as component F, from 0 to 50% by weight of one or more fibrous or particulate fillers, g) as component G, from 0 to 40% by weight of further additives, where the entire amount of components A to E and, if appropriate, F and G is 100% by weight.Type: GrantFiled: January 29, 2010Date of Patent: November 18, 2014Assignee: Styrolution GmbHInventors: Martin Weber, Marko Blinzler, Christian Schweiger, Christoph Schneidereit
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Patent number: 8889769Abstract: The invention relates to a thermoplastic molding composition containing at least one polyester, a compound of the formula (I) a mixture of compounds of the formula (II) and optionally additional compounds and additives. The invention further relates to the use of the thermoplastic molding composition for the producing fibers, foils and moldings. The invention further relates to fibers, foils and moldings containing the thermoplastic molding composition.Type: GrantFiled: June 26, 2012Date of Patent: November 18, 2014Assignee: BASF SEInventors: Martin Weber, Rolf Minkwitz, Nok-Young Choi, Peter Eibeck
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Patent number: 8889781Abstract: Disclosed is a thermoplastic composition including a) a recycled thermoplastic including polyamide resin, polyolefin and mineral filler, wherein the recycled thermoplastic includes at least 60 weight percent content of recycled polyamide selected from the group consisting of polyamide 66, polyamide 6, blends of polyamide 66 and polyamide 6, and copolymers having repeat units of polyamide 66 and polyamide 6; and at least 1 weight percent content of polyolefin; b) polymer toughener, wherein the polymer toughener includes at least 50 to 85 weight percent non-functionalized rubber and 15 to 50 weight percent of a functionalized rubber; and c) 10 to 50 reinforcing agent having a minimum aspect ratio of 3; and molded articles manufactured therefrom.Type: GrantFiled: August 21, 2012Date of Patent: November 18, 2014Assignee: E I du Pont de Nemours and CompanyInventors: Avelino F Lima, Barbara Ann Wood
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Publication number: 20140336327Abstract: The present disclosure provides masterbatch compositions comprising a polypropylene grafted with a grafting monomer selected from maleic anhydride, acrylic acid or other acid or anhydride functional groups that could be grafted to a polypropylene backbone and a metallocene catalyzed polypropylene base resin. Additionally, the present disclosure provides a polymer composition which includes from 0.1 to 10.0 wt. % of the masterbatch composition, and from 50 to 90% of a third polypropylene, and from 5 to 45% of a filler.Type: ApplicationFiled: May 8, 2014Publication date: November 13, 2014Applicants: Equistar Chemicals, LP, Basell Polyolefine GmbHInventors: Maged G. Botros, Thomas Mecklenburg
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Publication number: 20140329955Abstract: A polypropylene resin composition includes 1 to 30 wt % of homopolypropylene having a melt index of 2 to 6 g/10 min at 230° C. and 2.16 kg, and an isotacticity index of 97% or more, 1 to 40 wt % of homopolypropylene having a melt index of 16 to 22 g/10 min at 230° C. and 2.16 kg, and an isotacticity index of 96% or more, and 20 to 40 wt % of a glass fiber having an excellent rigidity supplementation effect as an inorganic filler for improving heat resistance, mechanical properties, and 1 to 10 wt % of denatured polypropylene as a compatibilizer maximizes compatibility of the polypropylene resin and the glass fiber, based on a total weight of the composition. The composition has excellent rigidity, short-term heat resistance, long-term heat resistance, and fusion strength, at a reduced weight and production cost.Type: ApplicationFiled: December 19, 2013Publication date: November 6, 2014Applicants: Kia Motors Corporation, Hyundai Motor CompanyInventors: Jee-Young YOUN, Hyeok-Jung LIM
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Publication number: 20140329100Abstract: Thermoplastic moulding composition (F), comprising: A) from 5 to 80% by weight of a graft polymer (A) having bimodal particle size distribution and a moisture content of 0 to 27% by weight, made, based on (A), a1) from 40 to 90% by weight of an elastomeric particulate graft base (a1), obtained by emulsion polymerization of based on (a1), a11) from 70 to 100% by weight of at least one conjugated diene, or of at least one C1-8-alkyl acrylate, or of mixtures of these, a12) from 0 to 30% by weight of at least one other monoethylenically unsaturated monomer and a13) from 0 to 10% by weight of at least one polyfunctional, cross linking monomer; a2) from 10 to 60% by weight of a graft a2), made, based on a2), a21) from 64 to 76% by weight of at least one vinyl aromatic monomer, a22) from 24 to 36% by weight of acrylonitrile, a23) from 0 to 30% by weight of at least one other monoethylenically unsaturated monomer, and a24) from 0 to 10% by weight of at least one polyfunctional, cross linking monomer; B) from 10 to 94Type: ApplicationFiled: December 15, 2011Publication date: November 6, 2014Applicant: BASF SEInventors: Michel Pepers, Christian Schade, Davy Roger Suwier, Norbert Niessner
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Patent number: 8877854Abstract: The present invention relates to a reinforced thermoplastic resin composition having excellent moldability, processability, and mechanical strengths, as well as being capable of improving the drop impact resistance (surface impact strength determined by a falling ball test). The reinforced thermoplastic resin composition of the present invention includes 10 to 60% by mass of a graft copolymer (A) having a graft chain (A2) grafted to a rubber polymer (A1); 40 to 90% by mass of a matrix polymer (B) which includes one or more types of polymers selected from the group consisting of a vinyl-based copolymer (B-1), a polycarbonate resin (B-2), and a polyester resin (B-3); 0.1 to 50 parts by mass of an inorganic filler (D); and 0.5 to 20 parts by mass of a glycidyl ether unit-containing polymer (E) having a mass average molecular weight of 3,000 to 200,000.Type: GrantFiled: December 26, 2008Date of Patent: November 4, 2014Assignee: UMG ABS, Ltd.Inventors: Koichi Tezuka, Masahito Nakamoto, Emiko Fujimoto
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Patent number: 8871859Abstract: The present disclosure provides an aqueous dispersion comprising a solid particle and a structured vinyl polymeric dispersant, wherein said structured vinyl polymer dispersant comprises at least one hydrophilic segment and at least one hydrophobic segment, the hydrophilic segment comprising at least one crosslinkable moiety, wherein the crosslinkable moiety is cross-linked with a crosslinking agent that is substantially insoluble in the aqueous ink vehicle. These dispersions when used in ink jet inks provide images with the requisite optical density and chroma needed for emerging ink jet applications.Type: GrantFiled: November 23, 2010Date of Patent: October 28, 2014Assignee: E I du Pont de Nemours and CompanyInventors: Xiaoqing Li, Christian Jackson
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Patent number: 8871855Abstract: A terminally unsaturated polyolefin satisfying the following (1) to (4): (1) the mesopentad fraction [mmmm] of propylene chain unit or butene-1 chain unit is 20 to 80 mol %; (2) the number of terminal vinylidene groups per molecule is 1.3 to 2.5; (3) the weight-average molecular weight Mw is 500 to 100,000; and (4) the molecular weight distribution Mw/Mn is 1.1 to 2.6.Type: GrantFiled: May 17, 2011Date of Patent: October 28, 2014Assignee: Idemitsu Kosan Co., Ltd.Inventors: Shuji Machida, Tomio Tatsumi, Takenori Fujimura
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Publication number: 20140315037Abstract: The instant invention provides to polymeric blend formulation, and a multilayer structure comprising a skin layer derived from the polymeric blend formulation, and method of making the same. The polymeric blend formulation comprises: (a) 40 to 65 percent by weight of an ethylene-based copolymer composition; (b) 15 to 40 percent by weight of a chlorinated olefin polymer composition; (c) from 0.1 to 25 percent by weight of a filler; (d) 10 to 30 weight percent by weight of an adhesion promoting agent; and (e) optionally, 1 to 4 percent by weight of a mineral oil.Type: ApplicationFiled: July 25, 2012Publication date: October 23, 2014Inventor: Sherrika D. Daniel
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Patent number: 8865342Abstract: Provided a polycarbonate resin composition excellent in flame resistance, impact resistance, and color fastness. A polycarbonate resin composition containing, per 100 parts by mass of polycarbonate resin (A), 0.001 to 30 parts by mass of flame retardant (B), 0.001 to 1 part by mass of fluoropolymer (C), and 0.5 to 10 parts by mass of graft copolymer (D) obtainable by graft-copolymerizing a diene-based rubber with a (meth)acrylate ester compound, the graft copolymer (D) having (i) a sulfur content of 100 to 1500 ppm, and (ii) an average particle size of 70 to 240 nm.Type: GrantFiled: November 15, 2011Date of Patent: October 21, 2014Assignee: Mitsubishi Engineering-Plastics CorporationInventors: Toshiki Monden, Yutaka Shiraishi
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Patent number: 8858839Abstract: A thermoplastic composition comprises: a compatibilized blend of a poly(arylene ether), an aliphatic-aromatic polyamide and a polymeric compatibilizer; and an impact modifier; wherein the aliphatic-aromatic polyamide is composed of units derived from a dicarboxylic acid and units derived from a diamine and the units derived from a dicarboxylic acid comprise 60 to 100 mol % of units derived from terephthalic acid and the units derived from a diamine comprise 60 to 100 mol % of units derived from 1,9-nonanediamine, 2-methyl-1,8-octanediamine, or a combination of 1,9-nonanediamine and 2-methyl-1,8-octanediamine.Type: GrantFiled: October 28, 2013Date of Patent: October 14, 2014Assignee: SABIC Global Technologies B.V.Inventors: Shabarinath Kutti Gounder, Roshan Kumar Jha, Mark D. Elkovitch
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Patent number: 8853319Abstract: The thermoplastic molding composition comprises: a) as component A, from 0 to 97.9% by weight of one or more (methyl)styrene-acrylonitrile copolymers which do not have any units derived from maleic anhydride, and which have an intrinsic viscosity smaller than 85 ml/g, b) as component B, from 1 to 98.9% by weight of one or more (methyl)styrene-acrylonitrile copolymers which have, based on the entire component B, from 0.5 to 5% by weight of units derived from maleic anhydride, c) as component C, from 1 to 75% by weight of glass fibers, d) from 0.1 to 20% by weight of one or more flow promoters, selected from d1) as component D1, at least one highly branched or hyperbranched polycarbonate with an OH number of from 1 to 600 mg KOH/g of polycarbonate (to DIN 53240, part 2), d2) as component D2, at least one highly branched or hyperbranched polyester of AxBy type, where x is at least 1.1 and y is at least 2.Type: GrantFiled: May 6, 2010Date of Patent: October 7, 2014Assignee: Styrolution GmbHInventors: Martin Weber, Marko Blinzler, Roelef Van Der Meer
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Publication number: 20140296416Abstract: Thermoplastic molding compositions comprising the following components: a) 3 to 91.8 wt % of a polyamide, as component A b) 3 to 91.8 wt % of a styrene copolymer, as component B c) 5 to 91.8 wt % of an impact-modifying grafted rubber, as component C d) 0.2 to 1.5 wt % of a compound of formula (I), as component D: e) 0 to 0.9 wt % of a mixture of formula (II), as component E: f) 0 to 0.9 wt % of a further stabilizer component F, g) 0 to 25 wt % of one or more styrene copolymers which include from 0.5 to 5 wt % of maleic anhydride-derived units, as component G, and also optionally further added-substance materials, have advantageous weathering properties.Type: ApplicationFiled: October 5, 2012Publication date: October 2, 2014Inventors: Rolf Minkwitz, Marko Blinzler, Rebekka Von Benten, Piyada Charoensirisomboon
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Publication number: 20140288225Abstract: A polymeric composition is a blend of one or more heterophasic copolymers of propylene and ethylene produced by a multistep polymerization, wherein the heterophasic copolymers comprise a low crystalline matrix component and a soft amorphous elastomeric component, in which both the matrix component and the soft amorphous elastomeric component contain greater than 55% by weight propylene; one or more additional elastomeric components selected from the group of an ethylene/?-olefin C3-C20 copolymer with a total ethylene concentration of greater than or equal to 65% by weight; and a propylene/?-olefin C2, C4-C20 copolymer with a total propylene concentration of greater than or equal to 65% by weight; 5-65% by weight of the total composition of one or more inorganic or organic reinforcement materials; and 0.01-4% by weight of the total composition of a maleic anhydride grafted polypropylene compatibilizer or coupling agent. The polymeric composition has a low crystallinity of less than 30 J/gram measured by DSC.Type: ApplicationFiled: June 11, 2014Publication date: September 25, 2014Applicant: ASAHI KASEI PLASTICS NORTH AMERICA, INC.Inventors: Katherine M. Shipley, Sameer G. Mehta, Vaibhav Vishnu Apte, Laura Therese Shereda
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Publication number: 20140275339Abstract: The present invention relates to a process for the preparation of stabilised impact-modified polycarbonate compositions using dilute aqueous acidic solutions, and to the compositions so prepared themselves.Type: ApplicationFiled: October 23, 2012Publication date: September 18, 2014Inventors: Andreas Seidel, Hans-Jürgen Thiem
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Patent number: 8835548Abstract: Crosslinked, melt-shaped articles are manufactured by a process that does not require the use of post-shaping external heat or moisture, the process comprising the steps of: A. Forming a crosslinkable mixture of a 1. Organopolysiloxane containing one or more functional end groups; and 2. Silane-grafted or silane-copolymerized polyolefin; and B. Melt-shaping and partially crosslinking the mixture; and C. Cooling and continuing crosslinking the melt-shaped article. Crosslinking is promoted by the addition of a catalyst to the mixture before or during melt-shaping or to the melt-shaped article.Type: GrantFiled: September 14, 2010Date of Patent: September 16, 2014Assignee: Union Carbide Chemicals & Plastics Technology LLCInventors: Mohamed Esseghir, Jeffrey M. Cogen, Saurav S. Sengupta
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Patent number: 8829104Abstract: Disclosed is a styrene-based resin composition that comprises 5-20 parts by mass of (D) a fire retardant per 100 parts by mass of a resin composition (1) that comprises 30-51 mass % of (A) a graft copolymer obtained by graft polymerization of a diene rubber polymer with an aromatic vinyl monomer and an unsaturated nitrile monomer, 10-55 mass % of (B) a copolymer comprising two or more monomers selected from among aromatic vinyl monomers, unsaturated nitrile monomers and unsaturated carboxylic acid alkyl ester monomers, and 15 to 39% by mass of a copolymer (C) comprising one kind of unsaturated carboxylic acid alkyl ester monomers, or two or more unsaturated carboxylic acid alkyl ester monomers, ((A)+(B)+(C)=100 mass %), wherein the diene rubber polymer constitutes 15-25 mass % of the resin composition (1).Type: GrantFiled: March 18, 2011Date of Patent: September 9, 2014Assignee: Asahi Kasei Chemicals CorporationInventors: Tomoyuki Fujisawa, Mihoko Yamamoto
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Publication number: 20140243465Abstract: Provided is a resin composition including at least: polyolefin in an amount of from 50% by mass to 90% by mass; an electro-conductive agent; and a compound represented by General Formula (1) below, In General Formula (1), R is preferably a divalent group having a number overage molecular weight of 1,000 or greater and derived from acrylic polymer.Type: ApplicationFiled: February 20, 2014Publication date: August 28, 2014Applicant: Ricoh Company, Ltd.Inventors: Makoto Matsushita, Akira Izutani, Chiyoshi Nozaki
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Publication number: 20140228492Abstract: Disclosed is a polyamide resin composition for a wheel cover, which has an excellent balance between rigidity and toughness, improved low temperature impact property, excellent heat resistance, and improved strength of the surface of the composition and the weld. In particular, the polyamide resin composition comprises a polyamide 6 resin, an ethylene-based copolymer, a styrene-based copolymer, a maleic anhydride grafted styrene, an imide-based copolymer, nano-minerals, and a phenolic heat-resistant material.Type: ApplicationFiled: July 8, 2013Publication date: August 14, 2014Inventors: Duck-Hyoung Hwang, Yong-Chul Lee, Sung-Woo Lee, Chang-Gyu Kim, Ji-Hyuk Park
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Publication number: 20140216656Abstract: An adhesive two-part formulation is provided that includes an amount of free-radical curable monomers, each of said monomers containing at least one acrylate moiety. Also preset in the formulation is an amount of a chlorosulfonated polymer; a Lewis acid; a polyfunctional monomer amount of dimethacrylate monomer, trimethacrylate monomer, an elastomer, a thermoplastic additive, or a combination thereof. A borane-amine complex is provided as an activator. A process of applying the formulation to a substrate includes mixing together the formulation components such that each part has a storage stability at 50° C. for 30 days where the viscosity at 30 days is within 40% of an initial viscosity. The mixture is applied to the substrate and then allowed to cure to achieve an initial strength of at least 345 kiloPascals (kPa) within 30 minutes and 40 minutes for adhesive:activator weight ratio of 1:1 and 10:1, respectively.Type: ApplicationFiled: December 11, 2013Publication date: August 7, 2014Applicant: Illinois Tool Works, Inc.Inventors: Prashant Koshti, Brajesh Shukla, Subodh Deshpande, Dan Doe, Peter Carbutt
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Publication number: 20140220843Abstract: The disclosed hydrophobic adhesive composition comprises a hydrophobic adhesive matrix and water absorbent fibers dispersed throughout the adhesive matrix to provide water management capabilities to the adhesive composition. The disclosed adhesive composition can adhered to a variety of surfaces, such as skin, and will easily remove from the surface. Therefore, the disclosed adhesive is particularly well suitable for application to skin wherein the absorbent fiber can absorb perspiration, water, or wound fluid from skin.Type: ApplicationFiled: August 17, 2012Publication date: August 7, 2014Applicant: 3M INNOVATIVE PROPERTIES COMPANYInventors: Junkang J. Liu, Cary A. Kipke, Ting Fan
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Patent number: 8779051Abstract: The instant invention provides a thermoplastic composition, method of producing the same, and articles made therefrom. The thermoplastic composition according to present invention comprises the melt blending product of: (a) from 10 to 75 percent by weight of a continuous phase, based on the total weight of the thermoplastic composition, wherein said continuous phase comprises one or more thermoplastic polymers; and (b) from 25 to 90 percent by weight of a dispersed phase comprising one or more core/shell polymer particles, based on the total weight of the thermoplastic composition, wherein said one or more core/shell polymer particles comprise a crosslinked elastomer core and a thermoplastic shell and wherein said core/shell polymer has an average particle size diameter in the range of from 70 to 10,000 nm.Type: GrantFiled: July 6, 2011Date of Patent: July 15, 2014Assignees: Dow Global Technologies LLC, Rohm and Haas CompanyInventors: Srdjan Kisin, Eric G. Lundquist, Timothy E. Clayfield, Yannick Saint-Gerard, Veera Nelliappan
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Patent number: 8779050Abstract: The present invention relates to non-aging, impact-modified polycarbonate compositions and molding compositions comprising: A) from 60 to 86 parts by weight (based on the sum of components A+B+C) of aromatic polycarbonate and/or aromatic polyester carbonate, B) from 4 to 12 parts by weight (based on the sum of components A+B+C) of graft polymer comprising: B.1 from 10 to 50 wt. % (based on the graft polymer B) of a shell of at least one vinyl monomer, and B.2 from 90 to 50 wt. % (based on the graft polymer B) of a graft base of silicone-acrylate composite rubber, C) from 10 to 30 parts by weight (based on the sum of components A+B+C) of a polymer or copolymer based on vinyl monomer, and D) from 0 to 20 parts by weight of polymer additives.Type: GrantFiled: July 20, 2012Date of Patent: July 15, 2014Assignee: Bayer Materialscience AGInventors: Achim Feldermann, Andreas Seidel, Eckhard Wenz
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Publication number: 20140187690Abstract: A flame retardant thermoplastic resin composition includes: (A) about 60% by weight (wt %) to about 90 wt % of a polycarbonate resin including a first polycarbonate having a weight average molecular weight from about 30,000 g/mol to about 50,000 g/mol and a second polycarbonate having a weight average molecular weight from about 5,000 g/mol to about 20,000 g/mol; (B) about 10 wt % to about 40 wt % of an aromatic vinyl resin having a fogging index (FI) of about 0.8 or less as calculated by Equation 1 defined in the specification; (C) about 1 part by weight to about 20 parts by weight of an impact modifier based on about 100 parts by weight of (A)+(B); and (D) about 5 parts by weight to about 30 parts by weight of a flame retardant based on about 100 parts by weight of (A)+(B.Type: ApplicationFiled: December 3, 2013Publication date: July 3, 2014Applicant: Cheil Industries Inc.Inventors: Dong Kil CHOI, Su Hak BAE, Jung Hun LEE, Dong Min PARK, Seung Shik SHIN, Min Jung JOO
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Publication number: 20140186612Abstract: A transparent thermoplastic resin composition includes (A) a rubber-modified vinyl-based copolymer; and (B) a cyanated vinyl-aromatic vinyl-based copolymer, wherein the (A) rubber-modified vinyl-based copolymer includes a rubbery polymer having an average particle size of about 500 ? to about 1,900 ?, the (B) cyanated vinyl-aromatic vinyl-based copolymer has a glass transition temperature of about 105° C. or less, and a difference in index of refraction between the (A) rubber-modified vinyl-based copolymer and the (B) cyanated vinyl-aromatic vinyl-based copolymer is about 0.01 or less. The transparent thermoplastic resin composition can have excellent properties in terms of scratch resistance, transparency, and/or impact resistance.Type: ApplicationFiled: June 25, 2013Publication date: July 3, 2014Inventors: Young Chul KWON, Kang Yeol PARK, Yoen Kyoung KIM, Dong Hyun PARK, Seon Ae LEE, Jin Seong LEE
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Publication number: 20140187694Abstract: Disclosed is a polypropylene resin composition and interior and exterior materials for vehicles using the same, particularly an olefin-based polypropylene resin composition including: about 50 to 70% by weight of a high crystalline polypropylene; about 10 to 20% by weight of a reactor made thermoplastic polyolefin (RTPO) polypropylene; about 5 to 20% by weight of an inorganic filler; about 10 to 20% by weight of a rubber elastomer; and about 3% by weight or less of a slip agent, based on the total weight of the composition. The composition provides excellent physical properties such as high strength and impact resistance, and thus superior resistance to damage, and shows low gloss characteristics and excellent fluidity.Type: ApplicationFiled: June 6, 2013Publication date: July 3, 2014Inventors: Kyeong-Hoon Jang, Dae-Sik Kim, Han-Ki Lee, Hak-Soo Kim, Jung-Gyun Noh, Tae-Sik Lee, Im-Taek Sung, Kyung-Beom Seo
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Publication number: 20140187704Abstract: Disclosed are a transparent thermoplastic resin composition including (A) about 5 to about 40 wt % of an impact-reinforcing agent having a core-shell structure where an acrylic-based compound is grafted on a rubber core including a copolymer of an acrylic-based monomer and a diene-based monomer, to form a shell, and (B) about 60 to about 95 wt % of an acrylic-based resin, and a molded article using the same.Type: ApplicationFiled: October 3, 2013Publication date: July 3, 2014Applicant: Cheil Industries Inc.Inventors: Kee-Hae KWON, In-Chol KIM, Jung-Eun PARK, Jeong-Min LEE, Jin-Young HUH, Chang-Min HONG
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Patent number: 8765838Abstract: A non-aqueous ink composition for inkjet printing, comprising 5 to 15% by mass of pigment relative to a mass of the non-aqueous ink composition, a pigment dispersant in such an amount that a mass ratio of the pigment dispersant to the pigment ranges from 0.2 to 2.0, and an organic solvent, the pigment dispersant comprising (A) a polyamide having a polyester side chain and/or a copolymer of vinylpyrrolidone and a C10-40 alkene, and (B) an alkyl(alkyl)acrylate copolymer having a C12-25 alkyl group and a nitrogen-containing group in such an amount that a mass ratio of the dispersant (B) to a total of the dispersant (A) and the dispersant (B), (B)/[(A)+(B)], ranges from 0.75 to 0.99. The ink composition has good storage stability and causes no satellite even printed in an environment of a low temperature.Type: GrantFiled: September 27, 2011Date of Patent: July 1, 2014Assignee: Riso Kagaku CorporationInventors: Tetsuo Hosoya, Toshihiro Endo
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Publication number: 20140179850Abstract: What is described is the use of a polyamide moulding composition for the production of a stain-resistant article, the staining tendency (ST) of the article being at least 2. Here, the composition contains 30-100% by weight of a polyamide or a polyamide mixture, consisting of 50-100% by weight of at least one amorphous and/or microcrystalline polyamide having a glass transition temperature of at least 100° C., based on: 20-100 mol % of at least one cycloaliphatic diamine; and 0-80 mol % of at least one other aliphatic and/or aromatic diamine; and also aromatic and/or aliphatic dicarboxylic acids comprising at least 6 carbon atoms, and 0-50% by weight of at least one semi-aromatic polyamide. In addition the moulding composition comprises 0.01-20% by weight of one or several inorganic white pigments.Type: ApplicationFiled: December 20, 2013Publication date: June 26, 2014Applicant: EMS-PATENT AGInventors: Etienne Aepli, Mark Pfleghar, Botho Hoffman, Heinz Hoff
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Patent number: 8759431Abstract: A durable polyoxymethylene composition includes a polyoxymethylene copolymer with 1,3-dioxolane as a comonomer, a lubricant, an inorganic filler, a nucleating agent including a sodium salt, a stabilizer, an anti-static agent. A ramp is made of the durable polyoxymethylene. The ramp and the durable polyoxymethylene have excellent micro-wear-resistant property.Type: GrantFiled: May 30, 2012Date of Patent: June 24, 2014Assignee: Min Aik Technology Co., Ltd.Inventors: Jung-Pao Chang, Chi-En Lin
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Patent number: 8759437Abstract: In a composite component assembled from at least one component piece comprising a polyamide molding composition with at least one component piece comprising a vulcanized elastomer, the polyamide molding composition comprises at least 40% by weight of a mixture of the following constituents: a) 60 to 99 parts by weight of polyamide and b) 1 to 40 parts by weight of a graft copolymer obtainable using the following monomers: a) 0.5% to 25% by weight, based on the graft copolymer, of a polyamine having at least 4 nitrogen atoms and also ?) 75% to 99.5% by weight, based on the graft copolymer, of polyamide-forming monomers selected from lactams, ?-amino carboxylic acids and/or equimolar combinations of diamine and dicarboxylic acid, wherein the parts by weight of a) and b) sum to 100. The presence of the graft copolymer effectuates improved adherence between the component pieces.Type: GrantFiled: May 3, 2011Date of Patent: June 24, 2014Assignee: Evonik Degussa GmbHInventors: Andreas Pawlik, Harald Haeger
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Patent number: 8748529Abstract: A pigment dispersion including: 2 to 35% by mass of a pigment (a); 10 to 30 parts by mass of a polymer (b) with respect to 100 parts by mass of the pigment (a), the polymer (b) containing 5 to 30% by mass of a repeating unit represented by the following Formula (1) and having a weight average molecular weight of 10000 to 200000; and 15 to 50 parts by mass of a graft copolymer (c) having a polyalkylene imine chain or a polyallylamine chain in a main chain thereof and a polyester chain in a side chain thereof with respect to 100 parts by mass of the pigment (a), in which a total of the contents of the polymer (b) and the graft copolymer (c) is in the range of 25 to 70 parts by mass with respect to 100 parts by mass of the pigment (a).Type: GrantFiled: March 9, 2011Date of Patent: June 10, 2014Assignee: FUJIFILM CorporationInventors: Norihide Shimohara, Ippei Nakamura
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Publication number: 20140155537Abstract: Disclosed herein is a curable composition comprising ethylene copolymer elastomer, a relatively small amount of a polyamide, and optionally a compatibilizer wherein curable composition demonstrates improved heat aging properties without the loss of tensile strength. Also disclosed is the process for making such curable ethylene copolymer elastomer.Type: ApplicationFiled: November 20, 2013Publication date: June 5, 2014Applicant: E I DU PONT DE NEMOURS AND COMPANYInventor: Steven R. Oriani