Solid Graft Or Solid Graft-type Copolymer With Other Solid Polymer, Sicp, Or Spfi Patents (Class 524/504)
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Publication number: 20120028047Abstract: The invention provides a fiber reinforced resin composition comprising a melt-kneaded product (A) prepared by melt-kneading a first resin (A1) and a second resin (A2) that has reactive functional group as well as a third resin (B) and a fibrous filler (C), wherein, with respect to the contents of the components, the first resin (A1), the second resin with a reactive functional group (A2), and the third resin (B) account for 0.1 to 75 wt %, 0.1 to 15 wt %, and 10 to 99.8 wt %, respectively, to form a resin composition while said fibrous filler (C) accounts for 0.1 to 300 parts by weight per 100 parts by weight of said resin composition, said first resin (A1) and said third resin (B) forming a matrix resin, said second resin (A2) being dispersed as particles in said matrix resin, and said particles having a number average particle diameter of 10 to 1,000 nm.Type: ApplicationFiled: March 16, 2010Publication date: February 2, 2012Inventors: Naokichi Imai, Masato Honma, Takayuki Fujiwara, Takashi Fujioka, Masaru Akita, Makiko Saito
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Patent number: 8106121Abstract: The invention relates to graft polyols with a bimodal particle size distribution and a total solid content of between 5 and 65 wt. %. Said polyols contain small particles with a particle diameter of between 0.05 and 0.7 ?m and large particles with a particle diameter of between 0.4 and 5.0 ?m, whereby the peaks of the large and small particles measured during a representation according to the light-scattering analysis method do not overlap. The total solid content with the defined particle sizes consists of a volumetric fraction of between 5 and 45% small particles and a volumetric fraction of between 95 and 55% large particles, said volumetric fractions totalling 100%. The invention also relates to a method for producing graft polyols of this type and to the use thereof for producing polyurethanes.Type: GrantFiled: March 13, 2003Date of Patent: January 31, 2012Assignee: BASF AktiengesellschaftInventors: Bernd Zaschke, Andreas Hoppe, Marita Schuster, Marion Wenzel, Klaus Wagner
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Publication number: 20120015186Abstract: A molding material comprising the following components (A) to (D) at the following ratios, in which the component (D) is bonded to a composite comprising the components (A) to (C) and the order in the weight average molecular weight is component (D)>component (B)>component (C); (A) 1 to 75 wt % of a reinforcing fiber bundle; (B) 0.01 to 10 wt % of a first propylene-based resin; (C) 0.01 to 10 wt % of a second propylene-based resin having carboxylate groups bound to the polymer chains thereof; and (D) 5 to 98.98 wt % of a third propylene-based resin. A molding material of this invention provides a long fiber-reinforced thermoplastic resin molding material containing a propylene-based resin as the matrix resin, which allows the reinforcing fibers to be well dispersed into the molded article produced at the time of injection molding and allows the molded article produced to have excellent mechanical properties.Type: ApplicationFiled: December 24, 2009Publication date: January 19, 2012Applicant: TORAY INDUSTRIES, INC.Inventors: Masato Honma, Atsuki Tsuchiya, Keiichi Asami
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Publication number: 20120016068Abstract: Disclosed is an aromatic vinyl-based thermoplastic resin composition. The thermoplastic resin composition is based on a thermoplastic resin including a rubber-modified acrylic graft copolymer and uses a branched aromatic vinyl copolymer resin including a silicon compound. The thermoplastic resin composition can exhibit both improved impact resistance and flowability. In addition, the thermoplastic resin composition can have excellent weather resistance and moldability.Type: ApplicationFiled: December 7, 2010Publication date: January 19, 2012Applicant: CHEIL INDUSTRIES INC.Inventors: Jin Hwa CHUNG, Kee Hae KWON, Il Jin KIM, Kwang Soo PARK, Ja Kwan KOO
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Publication number: 20110318517Abstract: The invention relates to an adhesive composition comprising, relative to its total weight: from 1 to 40% of a polyethylene (A) grafted with a functional monomer or a blend of a polyethylene (A1) with a second polymer (A2) different from (A1), said blend of (A1) and (A2) being co-grafted with an unsaturated functional monomer, the content by weight of unsaturated functional monomer relative to (A) being in the range from 30 to 100000 ppm; from 25 to 98% of a non-grafted polyethylene (B) having a density in the range from 0.900 to 0.965; from 1 to 35% of an elastomeric product (C). The invention also relates to a multilayer structure comprising this composition, said structure being able to serve as protection of metal tubes used for the fabrication of oil pipelines and gas pipelines.Type: ApplicationFiled: January 28, 2010Publication date: December 29, 2011Applicant: Arkema FranceInventors: Arnaud Gerbaulet, Samuel Devisme, Laurent Quiller
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Publication number: 20110313095Abstract: The present invention relates to a mixture, comprising at least one thermoplastic polymer as component (A) and at least one photocatalytically active particle, comprising a non-porous core comprising at least one metal oxide or semimetal oxide with a diameter of from 0.1 nm to 1 ?m, and, at least to some extent surrounding the core, at least one porous outer layer comprising at least one further metal oxide or further semimetal oxide with an average layer thickness of from 0.1 to 10 nm, as component (B), to a process for the production of this mixture according to any of claims 1 to 5, via mixing of components (A) and (B), to the use of the mixture as photocatalytically active surface, to moldings, comprising this mixture, and to the use of this mixture for the production of moldings.Type: ApplicationFiled: February 25, 2010Publication date: December 22, 2011Applicant: BASF SEInventors: Leonie Felicitas Braun, Alexandra Seeber, Dirk Klingler
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Publication number: 20110303263Abstract: The invention relates to the use in a photovoltaic module of a film of a composition as a backsheet or as an encapsulant, this composition comprising, with respect to the total weight of the composition: from 1 to 99% of a polyethylene having an ethylene whose level by weight is greater than or equal to 80% chosen from the homopolymers of ethylene and the copolymers of ethylene and another alpha-olefin; from 99 to 1% of a polyolefin B, other than A, carrying a reactive functional group X chosen from the anhydride carboxylic acids and epoxides. The invention further relates to a photovoltaic module comprising the film of the composition according to the invention and also a process for the manufacture of this module.Type: ApplicationFiled: December 14, 2009Publication date: December 15, 2011Applicant: Arkema FranceInventors: Catherine Corfias-Zuccalli, Laurent B. Cartier, Samuel Devisme, Stephane Bizet
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Publication number: 20110306701Abstract: The thermoplastic molding composition comprises a) as component A, from 3 to 78% by weight of one or more styrene copolymers which have no units derived from maleic anhydride, b) as component B, from 15 to 90% by weight of one or more polyamides, c) as component C, from 5 to 50% by weight of one or more impact-modifying graft rubbers without olefinic double bonds in the rubber phase, d) as component D, from 1 to 25% by weight of one or more styrene copolymers which have, based on the entire component D, from 0.5 to 5% by weight of units derived from maleic anhydride, e) as component E, from 1 to 30% by weight of one or more further rubbers based on olefinic monomers without core-shell structure, and having at least 0.1% by weight of functional monomers, f) as component F, from 0 to 50% by weight of one or more fibrous or particulate fillers, g) as component G, from 0 to 40% by weight of further additives, where the entire amount of components A to E and, if appropriate, F and G is 100% by weight.Type: ApplicationFiled: January 29, 2010Publication date: December 15, 2011Applicant: BASF SEInventors: Martin Weber, Marko Blinzler, Christian Schweiger, Christoph Schneidereit
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Patent number: 8076407Abstract: Hot melt adhesives are provided that have improved heat resistance. The adhesives comprise a metallocene polyolefin, an amorphous ?-olefin polymer, a tackifier and a functional polyolefin. The functional polyolefin is used in an amount sufficient to increase the heat resistance. A preferred functional polyolefin is a maleated polyolefin such as maleated polypropylene. A preferred tackifier is a hydrogenated hydrocarbon tackifier.Type: GrantFiled: February 8, 2008Date of Patent: December 13, 2011Assignee: Henkel AG & Co. KGaAInventors: Richard J. Ellis, Michaela Stolbova
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Patent number: 8076413Abstract: The present invention provides an aqueous metallic coating composition comprising: (A) an aqueous film-forming resin; (B) a curing agent; (C) a phosphoric acid group-containing resin having an acid value of 10 to 200 mg KOH/g and obtained by copolymerizing a phosphoric acid group-containing polymerizable unsaturated monomer (a) represented by formula (1) with other polymerizable unsaturated monomer(s) (b); (D) a nitrogen-containing compound represented by formula (2); and (E) a metallic pigment. The present invention further provides a method for forming a multilayer coating film using the aqueous metallic coating composition.Type: GrantFiled: September 27, 2007Date of Patent: December 13, 2011Assignee: Kansai Paint Co., Ltd.Inventors: Nobuhiko Narita, Shuichi Nakahara, Hiroyuki Onoyama, Hironori Tonomura, Yasushi Nakao, Yoshizumi Matsuno
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Patent number: 8076394Abstract: Compositions and methods for printing on specialty media are disclosed. The methods comprise the steps of providing a fixing fluid, providing a dye- or pigment-based ink-jet ink containing an effective amount of a polyvinyl(alcohol-acetate) species, jetting the fixing fluid onto the specialty media forming a coated substrate, and jetting the ink-jet ink onto the coated substrate. Additionally, a gelled printed image on a substrate is disclosed comprising a fixing fluid containing a fixing agent and an aqueous ink-jet ink containing a polyvinyl(alcohol-acetate) species. In both the method and with respect to the image, the polyvinyl(alcohol-acetate) species used can be a known species, or one of a number of new graft copolymers containing a polyvinyl(alcohol-acetate) polymer as one of the constituents of the copolymer.Type: GrantFiled: May 15, 2009Date of Patent: December 13, 2011Assignee: Hewlett-Packard Development Company, L.P.Inventor: Alexey S Kabalnov
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Publication number: 20110300322Abstract: The invention relates to a novel halogen-free and acid-free, readily soluble adhesion promoter for polyolefins, said promoter containing (meth)acrylate-grafted, amorphous polyolefins.Type: ApplicationFiled: February 26, 2010Publication date: December 8, 2011Applicants: EVONIK DEGUSSA GmbH, EVONIK RÖHM GmbHInventors: Stephan Kohlstruk, Lutz Mindach, Stefanie Maus, Hinnerk Gordon Becker, Sven Balk
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Patent number: 8067495Abstract: The present invention relates to a thermoplastic elastomer composition and a glass panel molding assembly for a vehicle. The thermoplastic elastomer composition comprising a polymer component (1) that comprises a styrene-type thermoplastic elastomer and a polyolefin-type polymer {except for the additives in item (5) below}, a non-aromatic-rubber softener (2), a higher fatty acid derivative (4), and at least one type of an additive (5) selected from (5-a) a vinyl polymer graft-olefin polymer, (5-b) a polyorganosiloxane cross-linked powder; and (5-c) a polyorganosiloxane graft-olefin polymer. And the glass panel molding assembly for a vehicle produced from the aforementioned composition.Type: GrantFiled: April 7, 2006Date of Patent: November 29, 2011Assignee: Dow Corning Toray Company, Ltd.Inventors: Haruhiko Furukawa, Masakazu Irie
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Publication number: 20110288205Abstract: A process for the manufacture of a polymer dispersion comprising the steps of i) providing a mixture comprising from 2 to 60 parts by weight of a first polypropylene polymer having sufficient carboxylic acid and/or carboxylic acid anhydride groups equivalent to an acid value of from 2 to 50 mg KOH/g nv polymer and from 40 to 98 parts by weight of a second polymer having a molar excess of functional groups capable of reacting with the carboxylic acid and/or carboxylic acid anhydride groups of the polypropylene ii) causing the polymers to melt at a chosen temperature under conditions of high shear in an extruder to form an intimate mixture of the polymers iii) causing some of the carboxylic acid and/or carboxylic acid anhydride groups of the polypropylene to react with at least some of the functional groups of the second polymer to form a reaction mixture, under conditions of high shear in an extruder iv) rapidly cooling the reaction mixture outside the extruder to form a solid product v) optionally breaking upType: ApplicationFiled: November 10, 2009Publication date: November 24, 2011Applicant: AKZO NOBEL COATINGS INTERNATIONAL B.V.Inventor: Riaz Ahmad Choudhery
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Publication number: 20110281054Abstract: The invention relates to a novel halogen-free and acid-free, readily soluble priming bonding agent for polyolefins, said agent containing (meth)acrylate-grafted, amorphous polyolefins.Type: ApplicationFiled: February 26, 2010Publication date: November 17, 2011Applicants: EVONIK DEGUSSA GMBH, EVONIK ROEHM GMBHInventors: Stephan Kohlstruk, Sven Balk, Hinnerk Gordon Becker, Lutz Mindach, Thomas Arnold, Cornelia Baumann, Elke Seipel
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Publication number: 20110281984Abstract: The present invention relates to a thermoplastic elastomer vulcanizate having two respectively thermoplastic and liquid silicone elastomer phases, and the preparation process thereof.Type: ApplicationFiled: April 15, 2011Publication date: November 17, 2011Inventors: Nicolas Garois, Philippe Sonntag, Satha Hong, Grégory Martin, David Galpin
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Patent number: 8053509Abstract: The present invention provides a starch-(meth)acrylate graft copolymer and the preparation process thereof. The starch-(meth)acrylate graft copolymer is prepared by copolymerizing (meth)acrylate monomer and starch in a weight ratio of (0.4˜8):1, the graft copolymer having a skeleton of large starch molecule is grafted with one or more (meth)acrylate monomer with a grafting ratio of no less than 70%. The present invention further provides an oil swellable material, which comprises the starch-(meth)acrylate graft copolymer above as the swelling agent; and also an oil- and water-swellable material, which comprises the starch-(meth)acrylate graft copolymer above, water absorbing agent, reactive monomer, surfactant and material matrix. Further, sealing articles and packers prepared from the above oil swellable material and oil- and water-swellable material are also provided.Type: GrantFiled: December 30, 2006Date of Patent: November 8, 2011Assignee: Starse Energy and Technology (Group) Co., Ltd.Inventors: Qiang Wang, Aili Cao, Huian Yi
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Publication number: 20110263781Abstract: The invention is directed to a polymer thick film encapsulant composition comprising thermoplastic fluoropolymer resin and acrylic resin dissolved in organic solvents. The deposited encapsulant composition is processed at a time and energy sufficient to remove all solvent and form an encapsulant. The invention is further directed to using the encapsulant composition to form an encapsulant in PTC heater circuitry and, in particular, in PTC heater circuitry in mirror heater and seat heater applications.Type: ApplicationFiled: April 21, 2010Publication date: October 27, 2011Applicant: E. I. DU PONT DE NEMOURS AND COMPANYInventors: Vince Arancio, Jay Robert Dorfman
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Patent number: 8044134Abstract: The present invention relates to a polylactic acid resin composition. The composition includes about 25 to about 80 parts by weight of a polylactic acid resin, (B) about 20 to about 75 parts by weight of a polycarbonate resin, and (C) about 0.01 to about 5 parts by weight of a chain extender including an amine group, based on about 100 parts by weight of (A)+(B). The polylactic acid resin composition of the present invention is environmentally-friendly and has excellent hydrolysis resistance and simultaneously improved mechanical strength and heat resistance, and accordingly can be used for manufacturing various molded products requiring heat resistance and mechanical strength, for example vehicles, machine parts, electronic parts, office machines, miscellaneous goods, and the like.Type: GrantFiled: June 5, 2009Date of Patent: October 25, 2011Assignee: Cheil Industries Inc.Inventors: Young-Mi Chung, Chang-Do Jung
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Publication number: 20110251326Abstract: The present invention relates to a polymer composition containing the following components: a) 30-97 mass % of aromatic polycarbonate, b) 0.5-20 mass % of a metal compound capable of being activated by electromagnetic radiation and thereby forming elemental metal nuclei, and c) 2.5-50 mass % of at least one rubber-like polymer, wherein the sum of a)-c) is 100%.Type: ApplicationFiled: August 11, 2008Publication date: October 13, 2011Applicant: DSM IP Assets B.V.Inventors: Edwin Adriaan Andre Van Hartingsveldt, Martinus Louis Maria Bos
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Patent number: 8026309Abstract: A process is provided for producing a compatibilized polymeric blend. A first thermoplastic polymer and a reactive moiety are provided to a progressive melt kneading apparatus. The reactive moiety comprises a first reactive group capable of reacting with the first thermoplastic polymer but not a second polymer and a second reactive group capable of reacting with the second polymer but not the first polymer. The first thermoplastic polymer and the reactive moiety are then melt kneaded so that the first reactive group reacts with the first thermoplastic polymer and the second reactive group is grafted to the first thermoplastic polymer, forming a molten self-compatibilizer. A molten second polymer is then provided. The molten self-compatibilizer is melt kneaded with the molten second polymer so that the second reactive group reacts with the second polymer to form a compatibilized polymeric blend. Also provided are articles formed from the compatibilized polymer blend.Type: GrantFiled: February 29, 2008Date of Patent: September 27, 2011Assignee: PRS Mediterranean Ltd.Inventors: Izhar Halahmi, Oded Erez, Adi Erez
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Patent number: 8022146Abstract: A thermoplastic copolymer prepared from acrylonitrile and para-alpha-dimethylstyrene via bulk or solution polymerization has an improved heat distortion temperature and can be used together with graft copolymers and further components for the preparation of thermoplastic moldings.Type: GrantFiled: November 11, 2008Date of Patent: September 20, 2011Assignee: BASF SEInventors: Gerrit Luinstra, Florian Becker, Matthias Müller, Dirk Meckelnburg, Jens Assmann
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Publication number: 20110220667Abstract: Disclosed is an impact-resistant modified polyamide moulding compound which is suitable in particular for the production of containers having a good oxygen barrier and low-temperature impact strength. Also disclosed are containers which are produced from the thermoplastic polyamide moulding compound. In particular, storage or transport containers for industrial chemicals, agrochemicals, the cosmetic industry, pharmaceutical industry or foodstuffs industry can be produced from the polyamide moulding compound of the invention.Type: ApplicationFiled: March 11, 2011Publication date: September 15, 2011Applicant: EMS-PATENT AGInventors: Mark Pfleghar, Gerhard Zaschke, Roland Treutlein, Ulrich Presenz
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Publication number: 20110223395Abstract: A pigment dispersion including: 2 to 35% by mass of a pigment (a); 10 to 30 parts by mass of a polymer (b) with respect to 100 parts by mass of the pigment (a), the polymer (b) containing 5 to 30% by mass of a repeating unit represented by the following Formula (1) and having a weight average molecular weight of 10000 to 200000; and 15 to 50 parts by mass of a graft copolymer (c) having a polyalkylene imine chain or a polyallylamine chain in a main chain thereof and a polyester chain in a side chain thereof with respect to 100 parts by mass of the pigment (a), in which a total of the contents of the polymer (b) and the graft copolymer (c) is in the range of 25 to 70 parts by mass with respect to 100 parts by mass of the pigment (a).Type: ApplicationFiled: March 9, 2011Publication date: September 15, 2011Applicant: FUJIFILM CORPORATIONInventors: Norihide SHIMOHARA, Ippei NAKAMURA
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Publication number: 20110224355Abstract: The present invention provides a thermoplastic resin composition for a vehicular lamp housing, which is excellent in balance of physical properties with regard to such as impact resistance and fluidity, and of which hot plate weldability, vibration weldability and laser weldability are improved when a vehicular lamp housing is welded with other members.Type: ApplicationFiled: September 9, 2009Publication date: September 15, 2011Applicant: NIPPON A&L INC.Inventors: Hajime Tomita, Tokuo Tatsuda, Tetsuya Yamamoto, Seiji Tamai
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Publication number: 20110217542Abstract: There are provided a pressure-sensitive adhesive composition containing stably dispersed metal-based fine particles, having further reinforced mechanical properties, and being capable of forming a pressure-sensitive adhesive layer with excellent refractive index and excellent adhesive strength, and a pressure-sensitive adhesive sheet produced therewith.Type: ApplicationFiled: August 4, 2009Publication date: September 8, 2011Applicant: Nitto Denko CorporationInventors: Yutaka Moroishi, Keisuke Hirano, Fumiko Nakano, Akiko Tanaka
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Patent number: 8013053Abstract: The present invention relates to a water-based ink for ink-jet printing which exhibits a high optical density even upon one-pass printing on plain papers and is suitable for high-speed printing, and a dispersion used in the water-base ink. There are provided a water dispersion for ink-jet printing, including water-insoluble polymer particles containing a colorant, and a nonionic organic compound satisfying the following conditions I and II: I: Water containing 0.001% by weight of the nonionic organic compound has a surface tension of 70 mN/m or less as measured at 25° C.; and II: A solubility of the nonionic organic compound in 100 g of water is 0.30 g or less as measured at 25° C., a water-based ink containing the water dispersion, and a method of conducting a one-pass printing using the water-based ink.Type: GrantFiled: December 27, 2006Date of Patent: September 6, 2011Assignee: Kao CorporationInventors: Hiroyuki Yoshida, Isao Tsuru, Ryuma Mizushima
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Patent number: 8008388Abstract: Glass fiber reinforced olefin compositions comprise polypropylene homopolymers, polypropylene copolymers, opacifying pigments, fibrous reinforcers, light stabilizers, lubricants and antioxidants. The opacifying pigments are advantageously ZnO, ZnS or surface treated anatase TiO2.Type: GrantFiled: December 14, 2005Date of Patent: August 30, 2011Assignee: Ferro CorporationInventors: Deenadayalu Chundury, Benjamin A. Jones, Theophilus McGee, Morris Mou-Shen Lee, Junior R. Seymour
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Publication number: 20110207838Abstract: Disclosed is a thermoplastic resin composition including a) 50 to 92 weight percent of a recycled thermoplastic, wherein said recycled thermoplastic includes at least 60 weight percent of a recycled polyamide selected from the group consisting of polyamide 66, polyamide 6, and copolymers having repeat units of polyamide 66 and polyamide 6; and 8 to 30 weight percent of polymer toughener, wherein said polymer toughener comprises at least one acid polymer toughener(s) wherein said polymer toughener has an averaged calculated acid number of about 10 to about 90 mg KOH/g before blending into said thermoplastic composition.Type: ApplicationFiled: February 21, 2011Publication date: August 25, 2011Applicant: E.I. DU PONT DE NEMOURS AND COMPANYInventor: Avelino F. Lima
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Publication number: 20110196087Abstract: The present invention relates to the use of mixtures comprising polymer types A, B and AB as or in adhesives, polymer type A being a copolyester prepared with cocondensation of unsaturated aliphatic dicarboxylic acids, polymer type B being a (meth)acrylate homopolymer and/or copolymer, and polymer type AB being a graft copolymer of polymer type A and polymer type B.Type: ApplicationFiled: May 29, 2008Publication date: August 11, 2011Inventors: Gabriele Brenner, Rene Koschabek, Sven Balk, Thorsten Brand, Gerd Loehden
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Publication number: 20110190437Abstract: The present invention features polylactic acid composite compositions, more particularly a composite composition. The provided polylactic acid composite composition preferably includes the biomaterial polylactic acid resin and, accordingly, it is capable of effectively reducing carbon dioxide emission. Hence, it goes along with the low-carbon, green growth initiative. Further, with improved mechanical strength and heat resistance, it is usefully applicable to automotive interiors/exteriors, construction interiors, etc.Type: ApplicationFiled: March 31, 2010Publication date: August 4, 2011Applicant: HYUNDAI MOTOR COMPANYInventors: Chae Hwan Hong, Do Suck Han
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Publication number: 20110184103Abstract: The invention relates to ductile two-component moulding parts which are resistant to stress cracking and warping under the influence of chemicals, i.e. dimensionally stable two-component moulding parts.Type: ApplicationFiled: September 17, 2009Publication date: July 28, 2011Applicant: BAYER MATERIALSCIENCE AGInventors: Andreas Seidel, Eckhard Wenz, Manfred Nawrotii, Rainer Protte
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Publication number: 20110171479Abstract: An emulsion comprising the following (A), (B) and (C): (A) an olefinic copolymer comprising a structural unit derived from ethylene and/or a linear ?-olefin and a structural unit derived from a vinyl compound represented by the formula (I): CH2?CH—R??(I) wherein R represents a secondary alkyl group, a tertiary alkyl group or a alicyclic hydrocarbon group, or a polymer obtained by graft polymerizing an ?,?-unsaturated carboxylic acid anhydride to the olefinic copolymer, (B) an acrylic resin comprising a structural unit derived from an ?,?-unsaturated carboxylic acid and a structural unit derived from an ?,?-unsaturated carboxylic acid ester, (C) water.Type: ApplicationFiled: September 9, 2009Publication date: July 14, 2011Applicant: SUMITOMO CHEMICAL COMPANY, LIMITEDInventors: Masashi Nagano, Mutsuko Higo, Junji Morimoto, Tsuyoshi Takei, Kenji Sogoh
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Publication number: 20110166278Abstract: The invention relates to a method for the impregnation of continuous fibers that comprises coating said fibers with a polymer matrix containing: (a) at least one fluorinated polymer grafted with at least one carboxylic polar function and (b) optionally at least one fluorinated nongrafted polymer. The invention also relates to the composite fibers that can be obtained by said method and to the use thereof.Type: ApplicationFiled: June 27, 2008Publication date: July 7, 2011Applicant: Arkema FranceInventors: Gilles Hochstetter, Michael Werth
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Publication number: 20110166284Abstract: The invention relates to a silicone free defoamer for solvent based coatings, especially clear wood coatings preferably based on a graft copolymer of poly alkyl vinyl ether.Type: ApplicationFiled: May 6, 2009Publication date: July 7, 2011Applicant: BASF SEInventors: Weiqiu Hu, Frank Oliver Heinrich Pirrung, Petrus Johannes Harbers, Chuanjin Zhu, Min Zhu
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Patent number: 7973104Abstract: The present invention relates to rubbery core/shell polymers that have improved heat and ultraviolet light resistance. These polymers can be blended with thermoplastics to make leathery compositions. The core/shell polymers of this invention have an inner core and an outer shell. The inner core is has repeat units which are derived from (a) butyl acrylate, (b) a member selected from the group consisting of methyl methacrylate, ethyl methacrylate, methyl acrylate, and ethyl acrylate, (c) optionally, an alkoxy ethyl acrylate or an alkoxy ethyl methacrylate, (d) acrylonitrile, (f) a cross-linking agent, and (g) a monomer containing reactive cure sites The outer core has repeat units which are derived from (d) acrylonitrile, (e) styrene, and (f) additional cross-linking agent. The outer core of these polymers is void of repeat units that are derived from methyl methacrylate.Type: GrantFiled: June 29, 2006Date of Patent: July 5, 2011Assignee: Eliokem S.A.S.Inventor: Hung Dang Ngoc
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Publication number: 20110160378Abstract: The present invention provides a polyamide resin composition comprising (A) about 100 parts by weight of polyamide resin; (B) about 0.1 to about 50 parts by weight of titanium dioxide; and (C) about 1 to about 20 parts by weight of modified polyolefin, wherein the (C) modified polyolefin is prepared by grafting a monomer that is miscible with the polyamide resin into a main chain of the polyolefin.Type: ApplicationFiled: December 20, 2010Publication date: June 30, 2011Applicant: CHEIL INDUSTRIES INC.Inventors: Pil Ho Kim, In Sik Shim, Jong Cheol Lim, Sun Mi Park
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Publication number: 20110159293Abstract: Disclosed is a polycarbonate resin composition that includes (A) a polycarbonate resin, (B) a rubber modified vinyl-based graft copolymer including a rubbery polymer having an average particle diameter of about 0.05 to about 0.5 ?m, and (C) a rubber modified vinyl-based copolymer including a rubber-phase particle having an average particle diameter of about 0.6 to about 10 ?m as a dispersion phase. A molded product using the polycarbonate resin composition is also provided.Type: ApplicationFiled: December 29, 2010Publication date: June 30, 2011Applicant: CHEIL INDUSTRIES INC.Inventors: Jung-Eun Park, Doo-Han Ha
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Publication number: 20110160377Abstract: The present invention provides an aromatic vinyl thermoplastic resin composition including (A) about 10 to about 99% by weight of a thermoplastic resin (A) including (a1) an aromatic vinyl copolymer resin, (a2) a rubber-modified vinyl graft copolymer, or a combination of (a1) and (a2); and (B) about 1 to about 90% by weight of a branched aromatic vinyl copolymer resin including a silicon based compound. The thermoplastic resin composition of the present invention can have excellent impact strength, improved flow properties, and compactability.Type: ApplicationFiled: December 17, 2010Publication date: June 30, 2011Applicant: CHEIL INDUSTRIES INC.Inventors: Jin Hwa Chung, Kee Hae Kwon, Ja Kwan Koo, Il Jin Kim
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Patent number: 7968206Abstract: This invention relates to a method for forming a multi-layer coating, comprising sequentially applying a primer surfacer, a basecoat, and a clear coat composition on an automotive substrate in a wet-on-wet-on-wet manner, and simultaneously curing the applied three layers together in a single baking step, wherein the primer surfacer comprises: a film forming binder, a volatile organic liquid carrier, and pigment(s); and the binder contains about: (a) about 30 to 80% by weight, based on the weight of the binder, of a hydroxyl functional polyester resin; (b) about 10 to 30% by weight, based on the weight of the binder, of a crosslinking agent selected from the group consisting of a melamine resin, a blocked polyisocyanate resin, or a mixture thereof; (c) about 10 to 40% by weight, based on the weight of the binder, of a dispersed graft polymer comprising a non-crosslinked core of acrylic polymer which is substantially non-soluble in non-polar organic solvent and, grafted to the core, one end of an acrylic staType: GrantFiled: March 18, 2010Date of Patent: June 28, 2011Assignee: E. I. du Pont de Nemours and CompanyInventors: Jeffery W. Johnson, San C. Yuan
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Publication number: 20110152402Abstract: The present invention provides a thermoplastic resin composition that can have improved scratch resistance comprising: (A) about 10 to about 20% by weight of a rubber modified aromatic vinyl graft copolymer resin; (B) about 30 to about 50% by weight of polymethylmethacrylate (PMMA) resin; and (C) about 40 to about 60% by weight of an aromatic vinyl copolymer resin including about 5 to about 50% by weight of a (meth)acrylate alkyl ester. The thermoplastic resin composition of the present invention can have a good balance of various properties such as scratch resistance, impact strength, colorability, gloss, and injection molding properties.Type: ApplicationFiled: December 17, 2010Publication date: June 23, 2011Applicant: CHEIL INDUSTRIES INC.Inventors: Sung Hun Jin, Chang Min Hong, Dong Hui Chu, Tae Woog Jang, In Chol Kim, Yu Ho Kim, Don Keun Lee
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Publication number: 20110152435Abstract: A resin composition comprises a carbon-based nanofiller (A), a modified polyolefin-based polymer (B), and two or more resins (C) other than the modified polyolefin-based polymer (B), the resin composition comprising a dispersed phase formed from a resin (Caff) which has a highest affinity for the carbon-based nanofiller (A) among the two or more resins (C), and a continuous phase formed from the remaining one or more resins (C1), wherein at least part of the modified polyolefin-based polymer (B) is present at an interface between the dispersed phase and the continuous phase, and the carbon-based nanofiller (A) is present in the dispersed phase.Type: ApplicationFiled: September 18, 2009Publication date: June 23, 2011Applicant: KABUSHIKI KAISHA TOYOTA CHUO KENKYUSHOInventors: Takuya Morishita, Mitsumasa Matsushita, Yoshihide Katagiri, Kenzo Fukumori, Minoru Takahara, Takashi Ohta
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Publication number: 20110142888Abstract: Film coating compositions based on a co-processed mixture of a polyvinyl alcohol-polyether graft polymer and polyvinyl alcohol (component A), a N-vinylpyrrolidone-vinyl acetate copolymer (component B) and pigments (component C).Type: ApplicationFiled: December 16, 2010Publication date: June 16, 2011Applicant: BASF SEInventors: Thorsten Cech, Verena Geiselhart, Thorsten Agnese
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Patent number: 7960468Abstract: An aqueous coating composition, comprising A) at least one water-dilutable hydroxy-functional binder and B) at least one polyisocyanate crosslinking agent with free isocyanate groups, wherein component A) comprises A1) 40-95 wt. % of at least one water-dilutable hydroxy-functional (meth)acrylic copolymer with a hydroxyl value of 60-250 mg of KOH/g and an acid value of 5-50 mg of KOH/g, which is obtained by free-radical copolymerization performed in a non-aqueous phase, wherein the ratio of primary hydroxyl groups to secondary hydroxyl groups in the (meth)acrylate copolymer A1) is 1:0.1 to 1:1.2 and at least 80% of the secondary hydroxyl groups result from reaction products of a monoepoxy ester and an unsaturated acid-functional monomer, and A2) 5-60 wt. % of at least one water-dilutable polyester oligomer, wherein the total of the weight percentages of component A1) and A2) add up to 100 wt.Type: GrantFiled: September 29, 2004Date of Patent: June 14, 2011Assignee: E.I. du Pont de Nemours and CompanyInventors: Wiebke Becker, Volker Duecoffre, Carmen Flosbach, Birgit Kleuser
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Patent number: 7943692Abstract: A polycarbonate composition and its use as a molded article and as housing or a part of electronic device are disclosed. The polycarbonate composition includes a polycarbonate resin, a liquid crystalline polymer resin, a core-shell grafted copolymer and a low molecular weight polyolefin. The composition has an impact strength of at least about 68 kg·cm/cm when a specimen of the composition is subject to a chemical treatment and the chemically treated specimen is tested according to the standard ASTM D256 (?? notched). The composition has an impact resistance of exhibiting substantially no cracking when a specimen of the composition is subject to a chemical treatment and the chemically treated specimen is tested at 0.6 m according to the standard ASTM D3029. The chemical treatment includes submerging the specimen in paint thinner for 20 seconds and thereafter drying the specimen at 70° C. for 5 minutes.Type: GrantFiled: October 27, 2005Date of Patent: May 17, 2011Assignee: Cheil Industries Inc.Inventors: Bong Jae Lee, Kyung Tae Kim, Sung Sig Min, Jong Cheol Lim
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Publication number: 20110111153Abstract: A method for producing a high strength, flexible crosslinked polyethylene (PEX) material is provided wherein the base polymer is intermixed with a polymer modifier which affects the amorphous region of the polymer, leaving the crystalline portion of the base polymer virtually unaffected. Consequently, the amorphous region's density is lowered, resulting in a more flexible final product, while the crosslinked molecular structure and/or crystalline portion of the polymer, which controls the strength of the base polymer, remains strong. The polymer modifier can comprise a hydrocarbon fluid such as PAO, Group III basestocks, or a gas-to-liquid hydrocarbon. The plastic material has particular utility in the production of tubing, piping, and conduits for transporting gases, liquids, and the like, as well as wire and cable coatings such as jacketing and insulation.Type: ApplicationFiled: December 31, 2010Publication date: May 12, 2011Applicants: EXXONMOBIL CHEMICAL COMPANY INC., ZURN PEX, INC.Inventors: Robert G. Russell, Rodney Mize, Gary Lee Runyan, Bruce A. Harrington, Bryan R. Chapman, David B. Dunaway, Gerd Arthur Allermann
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Patent number: 7939596Abstract: Disclosed herein is an aqueous coating material comprising (A) at least one polyurethane which is ionically stabilized, nonionically stabilized, or a combination thereof, and which is saturated, unsaturated, grafted with olefinically unsaturated compounds, or a combination thereof, (B) at least one wetting agent or dispersant; and (C) at least one organic solvent selected from the group consisting of dimethyl sulfoxide, sulfolane, 2-methyl-1-butanol, 3-methyl-1-butanol, 2-methyl-1-pentanol, hexyl glycol, 1,6-hexanediol, diethylene glycol, triethylene glycol, glycerol, solutions of trimethylolpropane, solutions of pentaerythritol, solutions of sorbitol, reactive polyether polyols with a number-average molecular weight of 110 to 6000 daltons and a hydroxyl number of 25 to 1000 mg KOH/g, propylene glycol monobutyl ether, dipropylene glycol dimethyl ether, glycerol ethoxylate, ethyl 3-ethoxypropionate, gamma-butyrolactone, N-(2-hydroxyethyl)piperidine, N-methylmorpholine, N-(2-hydroxyethyl)morpholine, N-acetylmorType: GrantFiled: December 13, 2006Date of Patent: May 10, 2011Assignee: BASF Coatings AGInventors: Bernhard Steinmetz, Michaela Ebert, Elke Röhr, Berthold Deppisch, Gerd Hückmann
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Patent number: 7935747Abstract: The invention relates to a pigment preparation for coloring polymers. The inventive preparation comprises one or more pigments and a carrier. According to the invention, the carrier includes an oligomer or a combination of low-molecular-weight polymers from the group containing polymers and copolymers of ethylene-acrylic acid, ethylene-maleic anhydride or polypropylene-maleic anhydride. The carrier also includes a polymer from the group containing polymers of ethylene-ethyl acrylate, ethylene/butyl acrylate, ethylene/methacrylic acid, polypropylene with grafted methyl polymethacrylate, polypropylene with grafted polystyrene or block copolymers of styrene. For organic pigments, the preparation contains 50%-70% pigment and 50%-30% carrier. For inorganic pigments, the preparation contains 60%-90% pigment and 40%-10% carrier. The invention comprises a polyvalent pigment preparation which can be used in the production of color concentrates with specific bases and high precision.Type: GrantFiled: June 21, 2005Date of Patent: May 3, 2011Assignee: IQAP Masterbatch Group, S.L.Inventor: Josep Castanyer Collell
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Patent number: 7923508Abstract: The present invention relates to a flame retardant styrene-based resin composition with high impact property. The styrene-based resin composition of the present invention comprises 1-30 parts by weight of a flame retardant, 0.5-15 parts by weight of a flame retardant aid and 0.1-15 parts by weight of a styrene-containing graft copolymer per 100 parts by weight of a base resin comprising a rubber-modified styrene-based copolymer and offers high impact property and good rigidity and fluidity, without appearance problem under a variety of processing conditions.Type: GrantFiled: October 7, 2005Date of Patent: April 12, 2011Assignee: LG Chem, Ltd.Inventors: Jin-woo Yi, Ki-young Nam, Yong-yeon Hwang, Tae-woo Kim, Young-shim Kim, Chan-hong Lee
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Patent number: 7919559Abstract: Disclosed herein is a chemical-resistant and impact-resistant thermoplastic resin composition having excellent hydrolysis resistance. The thermoplastic resin composition comprises (A) about 1 to about 97.9% by weight of an epoxy group-containing vinyl copolymer resin; (B) about 1 to about 97.9% by weight of a rubber modified aromatic vinyl copolymer resin; (C) about 1 to about 97.9% by weight of a polyester resin; and (D) about 0.1 to about 97% by weight of an amorphous cycloaliphatic diol modified polyester.Type: GrantFiled: December 16, 2008Date of Patent: April 5, 2011Assignee: Cheil Industries Inc.Inventors: Jee Kwon Park, Jun Myung Kim, Jin Hwan Choi, Jae Won Lee