With Solid Polymer Derived From At Least One -n=c=x (x Is Chalcogen) Reactant Wherein At Least One Of The Reactants Forming The Solid Polymer Is Saturated; Or With Spfi Or Sicp Derived From A -n=c=x Reactant Wherein At Least One Of The Necessary Reactants Is Saturated Patents (Class 524/507)
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Publication number: 20090318596Abstract: The present invention provides compositions that enable excellent early hardness development in coating applications, the compositions comprising a blend of one or more copolymer, pA, having a Tg of 20° C. or higher, and one or more polyurethane copolymer in aqueous dispersion, pB, together with one or more additive chosen from a coalescent having a normal boiling point of from 150° C. to no greater than 300° C., a naturally derived plasticizer, and mixtures thereof. The polyurethane copolymer comprises at least 40 wt. %, based on the weight of polyurethane solids, of: (i) a first polyol having a molecular weight of at least 850, wherein the first polyol is a polyether polyol, or (ii) a second polyol chosen from a polyester, a polycaprolactam, a polycarbonate and a combination thereof, wherein the second polyol has a molecular weight of at least 1,500, or (iii) a combination of one or more first polyol and one or more second polyol. The compositions may be ambient curable.Type: ApplicationFiled: June 5, 2009Publication date: December 24, 2009Inventors: Zhenwen Fu, Andrew Hejl, Aurelia C. Sheppard, Andrew J. Swartz
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Publication number: 20090312469Abstract: The present invention provides compositions that enable excellent hardness in coating applications, the compositions containing one or more copolymer having as copolymerized units one or more acrylic monomer with a phosphorus acid-functional group, a polymeric side chain containing multi-acid functional groups, a salt thereof, or a combination thereof, one or more polyurethane dispersion made from a high molecular weight polyol, and one or more coalescent having a normal boiling point of 190° C. or higher. The compositions may be ambient curable.Type: ApplicationFiled: June 8, 2009Publication date: December 17, 2009Inventors: Kathleen A. Koziski, Gary R. Larson, William J. Rosano, Aurelia de las Cuestas Sheppard
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Publication number: 20090298974Abstract: A polymeric composite material, and method of making the same, including a polymeric blend that includes at least one thermoplastic polymer; at least one functionalized polymer; at least one polyetheramine thermoplastic material; and a plurality of particles (e.g. naturally occurring organic materials) distributed substantially homogeneously throughout the polymeric blend. Articles employing such materials are also disclosed.Type: ApplicationFiled: May 30, 2008Publication date: December 3, 2009Applicant: Zephyros, Inc.Inventors: Craig Chmielewski, Justin Kaffenberger
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Publication number: 20090297744Abstract: Gas barrier layers and composites contain a low gel sheet produced from a composition containing a thermoplastic polyurethane (TPU), a hydroxyl functional copolymer, and a gel reducing additive. The gel reducing additive has functional groups that can react with isocyanate groups to reduce gel formation during the processing of blends of urethane containing polymers and hydroxyl functional polymers. Multilayer composites containing the low gel sheets can be made into inflatable membranes for containing an inflationary gas. In a particularly preferred embodiment, the membranes are used as bladders of cushioning devices in the soles of shoes, particularly athletic shoes.Type: ApplicationFiled: August 12, 2009Publication date: December 3, 2009Inventors: Richard L. Watkins, Yihua Chang
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Patent number: 7619031Abstract: A low-heat accumulating thermoplastic resin composition containing 100 parts by mass of a thermoplastic resin [A] and 0.1 to 15 parts by mass of an inorganic pigment [B] having an infrared-reflecting property, and a molded product comprising the composition. The low-heat accumulating thermoplastic resin composition of the present invention is capable of providing a dark-colored molded product exhibiting a less heat accumulation as well as excellent weather resistance and impact resistance.Type: GrantFiled: August 6, 2003Date of Patent: November 17, 2009Assignee: Techno Polymer Co., Ltd.Inventors: Yuuichi Kanayama, Kenichi Noguchi, Yasuo Takahashi, Hideyuki Kurimoto
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Patent number: 7619019Abstract: The present invention provides reactive aqueous or solvent borne compositions comprising one or more low-temperature curing alkylether functional aminoplast resins having an average degree of polymerization of from 1.0 to 2.0, preferably alkylether group containing melamines, one or more hydroxyl group containing resins or polymers, such as acrylics and polyesters, one or more unblocked acid catalysts each having a pKa of 0.25 to 1.0, such as organic sulfonic acids, and one or more volatile amines, e.g. N-dipropylamine, that have a relative evaporation rate (RER) of 50-500, wherein, RER equals (p)(M)/11.6, with p being the vapor pressure of the amine in mm Hg and M being the molecular weight of the amine. The compositions cure at from 60° C. to 135° C., e.g. below 105° C., to form durable coatings suitable for plastic substrates, such as automotive plastics.Type: GrantFiled: March 14, 2006Date of Patent: November 17, 2009Assignee: Nippon Paint (USA), Inc.Inventors: James C. Drescher, Michael L. Jackson, Lisa M. Muller, Frank A. Stubbs, Robert D. Tokash
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Patent number: 7615592Abstract: A water- and oil-repellent agent is produced by subjecting (a) a polyfluoroalkyl group-containing (meth)acrylate and (b) a fluorine atom-free polymerizable monomer to an emulsification treatment in the presence of (c) a polyethylene oxide adduct type, cationic surfactant, or both of the cationic surfactant and a polyethylene oxide adduct type, non-ionic surfactant, and (d) a glycol-based compound, followed by copolymerization reaction in the presence of a polymerization initiator, and admixing the resulting aqueous dispersion with (e) a blocked isocyanate, and gives a satisfactory water and oil repellency to not only synthetic fibers, but also natural fibers, and also has a distinguished washing durability.Type: GrantFiled: May 27, 2005Date of Patent: November 10, 2009Assignee: Unimatec Co., LtdInventors: Toshimasa Sagawa, Haruyoshi Tatsu
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Publication number: 20090274846Abstract: The present invention provides an aqueous two-package type clear coating composition comprising: (A) an aqueous dispersion of a hydroxyl group- and acid group-containing acrylic resin having a hydroxyl value of 30 to 200 mg KOH/g, an acid value of 5 to 50 mg KOH/g, a weight average molecular weight of 3,000 to 30,000, and a glass transition temperature of ?30 to +40° C. obtained by radical polymerization of 10 to 50 mass % of a secondary hydroxyl group-containing monomer (a) and 50 to 90 mass % of at least one other unsaturated monomer (b); and (B) a polyisocyanate curing agent obtained by mixing (c) a polyisocyanate compound and (d) a compound containing an anionic functional group, a polyoxyethylene group, and a hydrocarbon group, and a process for forming a multilayer topcoat film using the same.Type: ApplicationFiled: October 23, 2007Publication date: November 5, 2009Inventors: Seiji Wada, Yuta Baba, Koki Chiga, Takashi Noguchi, Takato Adachi, Hiroyuki Onoyama, Hideo Sugai
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Publication number: 20090275690Abstract: The adhesion between a low surface energy (i.e., nonpolar) material, e.g., a polyolefin such as polyethylene, and a high surface energy (i.e., polar) material, e.g., a polyester, polyurethane, polycarbonate or polylactic acid, is promoted by blending with the nonpolar material typically from 15 to less than 50 wt % of a diol-based thermoplastic polyurethane (d-TPU), e.g., a polydiene diol-based TPU, based on the combined weight of the nonpolar material and the d-TPU. The promoted adhesion allows for the effective painting, printing, over-molding or HF-welding of a nonpolar substrate, e.g., a polyolefin film, with a polar coating, e.g., a paint, ink, etc. Aqueous dispersions can also be made from the blend of nonpolar material and d-TPU.Type: ApplicationFiled: October 31, 2007Publication date: November 5, 2009Inventors: Laura B. Weaver, Ashish Batra, Patricia Ansems, Gary M. Strandburg, Matthew J. Kalinkowski
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Patent number: 7605209Abstract: The present invention provides coating compositions that include reactive diluents and have high performance, low VOC levels, and low irritation levels. Certain embodiments of the present invention include water and water-dispersible polymers and other embodiments do not include water.Type: GrantFiled: May 27, 2004Date of Patent: October 20, 2009Assignee: Valspar Sourcing, Inc.Inventors: T. Howard Killilea, James M Bohannon
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Publication number: 20090253845Abstract: The invention relates to methacrylate resins and to their use.Type: ApplicationFiled: July 23, 2007Publication date: October 8, 2009Applicant: EVONIK ROEHM GMBHInventors: Peter Neugebauer, Günter Schmitt, Ingrid Kizewski, Dieter Raab, Heike Heeb
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Publication number: 20090247690Abstract: Crosslinkable compositions based on polyamide and on ?-olefin-vinyl acetate copolymers, where the compositions comprise a crosslinking initiator, and also a co-crosslinking agent, and crosslinkable compositions based on polyamides and on ?-olefin-vinyl acetate copolymers, where these compositions comprise a crosslinking initiator and the amount of polyamide in the compositions is <30% by weight. The present invention further relates to the preparation of the crosslinkable compositions of the invention, to the use of the crosslinkable compositions of the invention for the production of thermoplastic elastomers, to a process for the crosslinking of the compositions of the invention to give a thermoplastic elastomer, and also to the thermoplastic elastomers themselves and to their use for the production of mouldings.Type: ApplicationFiled: February 27, 2009Publication date: October 1, 2009Applicant: LANXESS Deutschland GmbHInventors: Kay Varnhorn, Jorg Mertinkat
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Publication number: 20090233064Abstract: There are provided an ink set including an ink composition having excellent color developability, ejection stability, and fixity and a pigment fixer having excellent abrasion resistance and dry-cleaning resistance; a method for producing an ink jet recorded matter with the ink set, the ink jet recorded matter having excellent color developability, ejection stability, abrasion resistance, and dry-cleaning resistance; and an ink jet recorded matter obtained by the method. An ink set includes an ink composition containing a water-dispersible pigment dispersoid and a reaction agent, and a pigment fixer containing polymeric microparticles having a glass transition temperature of ?10° C. or lower, an acid value of 100 mg KOH/g or less, and prepared using at least alkyl (meth)acrylate and/or cyclic alkyl (meth)acrylate.Type: ApplicationFiled: March 5, 2009Publication date: September 17, 2009Inventors: Masahiro YATAKE, Yoshimasa TAMURA
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Publication number: 20090226678Abstract: There are provided a liquid composition for making pigment fixed having a high resistance to rubbing and a good dry-cleanability; an ink set including the liquid composition for making pigment fixed and an ink composition excellent in terms of color intensity, discharge stability, and adhesiveness; and a method for producing ink-jet-recorded matter on a fabric having a high resistance to rubbing and good dry-cleanability using the liquid composition for making pigment fixed and the ink composition. The liquid composition for making pigment fixed according to the present invention contains at least a reactant and polymer fine particles synthesized from an alkyl (meth)acrylate and/or cyclic alkyl (meth)acrylate, the glass transition temperature and acid value of the liquid composition being equal to or lower than ?10° C. and equal to or lower than 100 mg KOH/g, respectively.Type: ApplicationFiled: March 5, 2009Publication date: September 10, 2009Inventors: Masahiro YATAKE, Yoshimasa TAMURA
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Patent number: 7569636Abstract: An aqueous coating composition with an improved open time comprising (a) a crosslinkable water-dispersible oligomer(s); (b) a dispersed polymer(s), (c) a pigment(s) with an oil absorption number ?25 g oil/100 g pigment and optionally (d) a Newtonian-like thickener(s) and (e) a thixotropic thickener(s) wherein the weight ratio of (a):(b) is in the range of from 10:90 to 60:40; wherein (d)+(e)=0.1 to 10 wt % and wherein said composition when drying to form a coating has a tack-free time of ?24 hours.Type: GrantFiled: March 22, 2004Date of Patent: August 4, 2009Assignee: DSM IP assets B.V.Inventors: Ronald Tennebroek, Tijs Nabuurs, Gerardus C Overbeek, Jan Bouman
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Patent number: 7569628Abstract: The present invention relates to a styrenic thermoplastic resin composition, and more particularly to a styrenic thermoplastic resin composition comprising a non-halogen flame-retardant having superior flame-retarding properties and impact strength. The present invention provides a flame-retarding styrenic thermoplastic resin composition comprising a) 100 weight parts of a base resin comprising i) 10 to 50 weight parts of a rubber-modified styrene-containing graft copolymer, ii) 5 to 20 weight parts of phenol novolac resin, and iii) 20 to 70 weight parts of a styrene-containing copolymer; and b) 5 to 20 weight parts of an aromatic phosphate. In addition, the a) base resin may further comprise iv) 10 to 40 weight parts of a thermoplastic polyurethane resin.Type: GrantFiled: June 25, 2007Date of Patent: August 4, 2009Assignee: LG Chem, Ltd.Inventors: Sung-Ho Lee, Chan-Hong Lee, Yong-Yeon Hwang, Ki-Young Nam, Tae-Hak Kim
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Patent number: 7569622Abstract: A biological substance related article includes a coating formed by causing a biological substance adsorption preventive coating composition to come in contact with a surface of the biological substance related article and heating the composition, the biological substance adsorption preventive coating composition including: (A) a copolymer obtained by copolymerizing raw material monomers including a monomer A1 shown by the following general formula (1) and an active hydrogen group-containing monomer A2; (B) a crosslinking agent reactive with an active hydrogen group; and (C) a solvent. CH2?CR3COOR1OR2??(1) (R1 represents an alkylene group having 1 to 4 carbon atoms, R2 represents an alkyl group having 1 to 4 carbon atoms, and R3 represents a hydrogen atom or a methyl group).Type: GrantFiled: November 8, 2005Date of Patent: August 4, 2009Assignee: JSR CorporationInventors: Masayuki Takahashi, Kinji Yamada, Toshihiro Ogawa
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Publication number: 20090176070Abstract: A pigment dispersion is provided that includes a pigment, a pigment dispersant, a polymer dispersion stabilizer and water, wherein the polymer dispersion stabilizer is an alpha-olefin/maleic anhydride copolymer expressed by the formula (1) below. A recording ink is also provided that includes the pigment dispersion, a surfactant, a water-dispersible resin, a humectant and water. In the structural formula (1), R represents an alkyl group and n is an integer of 30 to 100.Type: ApplicationFiled: December 15, 2006Publication date: July 9, 2009Inventors: Hiroshi Goto, Akihiko Matsuyama, Kiyofumi Nagai
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Publication number: 20090169748Abstract: An ink composition comprising: (a) water; (b) a pigment dispersion comprising a pigment and a polymeric dispersant wherein the polymeric dispersant is a copolymer comprising at least a hydrophobic methacrylate or acrylate monomer containing an aliphatic chain having greater than or equal to 12 carbons, and a hydrophilic methacrylic or acrylic acid monomer, wherein the copolymer comprises at least 10% by weight of the methacrylate or acrylate monomer and at least 5% by weight of the methacrylic or acrylic acid monomer, and wherein the copolymer comprises, in total, 20 to 95 weight % of hydrophobic monomer; and (c) at least one water-dispersible polyurethane.Type: ApplicationFiled: September 22, 2008Publication date: July 2, 2009Inventors: Gary L. House, Thomas B. Brust, Yongcai Wang
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Publication number: 20090159206Abstract: Moisture curable hot melt adhesive compositions that contain functionally modified polyolefins and have improved green strength before set are prepared without using added crystalline polyester polyol.Type: ApplicationFiled: December 20, 2007Publication date: June 25, 2009Applicant: National Starch and Chemical Investment Holding CorporationInventor: Yongxia Wang
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Publication number: 20090156721Abstract: An improved aqueous acrylic emulsion pressure sensitive adhesive (PSA) composition of improved sheer strength includes an aqueous acrylic emulsion including at least one hydrophobic monomer, at least one hydrophilic monomer, and at least one hydrogen bonding monomer; and a peel control additive. The PSA composition is substantially devoid of phosphate-based surfactants.Type: ApplicationFiled: December 12, 2007Publication date: June 18, 2009Inventors: Kang I. Lee, Keith D. King
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Patent number: 7537650Abstract: This invention relates to an ink jet ink set comprising a colored aqueous ink and a substantially colorless aqueous ink, wherein the colored ink comprises a cationic coloring agent and the colorless ink comprises an anionic polymer or oligomer.Type: GrantFiled: March 30, 2005Date of Patent: May 26, 2009Assignee: Eastman Kodak CompanyInventors: Richard P. Szajewski, Xiaoru Wang
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Patent number: 7534830Abstract: An aqueous dispersion of polyurethane-addition polymer hybrid particles, where the isocyanates used to make the polyurethane polymer portion of the particles comprise a mixture of aromatic polyisocyanate and aliphatic polyisocyanate wherein the aromatic isocyanate is free of sterically hindered isocyanate moieties. The dispersions are suitable for use in coatings, including varnishes, paints, inks and adhesives.Type: GrantFiled: June 9, 2005Date of Patent: May 19, 2009Assignee: Imperial Chemical IndustriesInventor: Neal Williams
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Publication number: 20090124751Abstract: A two-part moisture-curable resin composition comprises: a) a first part substantially free of moisture comprising: (1) moisture-curable silylated resin and, (2) optionally, one or more additional components selected from the group consisting of plasticizer, solvent, thixotropic agent, particulate material, moisture scavenger, isocyanate scavenger, crosslinker, adhesion promoter, U.V. stabilizer and antioxidant; and, b) a second part comprising: (1) water in an amount sufficient to cure moisture-curable silylated resin (a)(1); (2) at least one plasticizer and/or particulate material, (3) nonionic surfactant in an amount sufficient to provide a stable emulsion of plasticizer (b)(2), if present, and a stable suspension of particulate material (b)(2), if present, (4) optionally, one or more additional components selected from the group consisting of solvent, thixotropic agent, pH adjuster, U.V.Type: ApplicationFiled: November 14, 2007Publication date: May 14, 2009Inventors: Gary M. Lucas, Patrice J. Lehmann
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Publication number: 20090123742Abstract: Method of applying corrosion control coats, especially integrated pretreatment layers or coats for atmospheric corrosion control, to metallic surfaces, using copolymers comprising as monomeric building blocks 20% to 70% by weight of monomers containing nitrogen heterocycles, 10% to 50% by weight of monomers containing acidic groups, 10% to 50% by weight of vinylaromatic monomers, and optionally 0% to 25% by weight of further monomers. Copolymers of the stated composition, and also preparations for applying corrosion control coats.Type: ApplicationFiled: April 18, 2007Publication date: May 14, 2009Applicant: BASF SEInventors: Guido Vandermeulen, Alexander Gothlich, Markus Hickl, Michael Dornbusch, Monica Fernandez Gonzalez, Konrad Roschmann, Hermann Bergmann
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Publication number: 20090111934Abstract: A novel method for the preparation of an aqueous polyacrylate modified polyurethane dispersion is disclosed. The preparation method includes three main steps: a) preparation of polyacrylate polymer or copolymer emulsion; b) preparation of polyurethane prepolymer with carboxylic groups and neutralization treatment to the carboxylic groups; and c) dispersion and chain-extension of polyurethane prepolymer by adding the polyacrylate emulsion into the polyurethane prepolymer under vigorous agitation, or other mechanical operation. The aqueous polyacrylate modified polyurethane dispersion has self-crosslinkability when an unsaturated acetoacetoxy compound is used for the preparation of the polyacrylate emulsion.Type: ApplicationFiled: October 2, 2008Publication date: April 30, 2009Inventors: Caideng Yuan, Guohua Chen, Xixiang Zhang, Zongjin Li, Zhimeng Liu
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Publication number: 20090111935Abstract: This invention offers an aqueous urethane resin composition which contains a urethane resin obtained through reaction of acrylic polyol formed by copolymerization of carbonyl functional group-containing unsaturated monomer, hydrophilic group-containing unsaturated monomer and, where necessary, still other unsaturated monomer; with polyisocyanate compound and, where necessary, carboxyl group-containing diol; can form film of excellent physical properties such as spreadability and flexibility; and becomes ambient temperature-curable when combined with a crosslinking agent.Type: ApplicationFiled: October 28, 2008Publication date: April 30, 2009Inventors: Takeshi Fujii, Hiromi Harakawa
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Publication number: 20090105399Abstract: The invention describes transparent plastics mixtures having low-temperature impact resistance composed of a thermoplastic polyurethane (TPU) and of an impact-modified poly(meth)acrylate (PMMA).Type: ApplicationFiled: August 28, 2006Publication date: April 23, 2009Applicants: Evonik Roehm GmbH, CPS GMBHInventors: Klaus Schultes, Peter Battenhausen, Ursula Golchert, Adalbert Loidl
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Publication number: 20090093585Abstract: The present invention relates to liquid entrapping devices (e.g., absorbent non-woven fibrous mats) and to a process for preparing such devices. More particularly, the present invention relates to mechanically strong absorbent materials made from such liquid entrapping devices (e.g., non-woven fibrous mats) and to a method for preparing same. In one embodiment, a liquid entrapping device of the present invention comprises at least one hydrophilic elastomeric fibrous component (HEFC) and at least one wetting agent component. In another embodiment, a liquid entrapping device of the present invention comprise at least one hydrophilic elastomeric fibrous component (HEFC), at least one absorbent component, and at least one wetting agent component. In one instance, the wetting agent component of the present invention is contained on and/or within the fibers and/or nanofibers that form the liquid entrapping device (e.g., a non-woven fibrous mat) of the present invention.Type: ApplicationFiled: February 2, 2007Publication date: April 9, 2009Applicants: THE UNIVERSITY OF AKRON, SNS NANO FIBER TECHNOLOGY, LLCInventors: Daniel J. Smith, Horst Ring
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Patent number: 7514497Abstract: According to the invention a body may be produced in plastic, in particular by means of rotational casting method, by using a suspension or paste with plastic particles, comprising at least partly a thermoplastic elastomer, in particular SEBS, SBS or TPU. Said invention presents the advantage of no danger to health.Type: GrantFiled: October 8, 2001Date of Patent: April 7, 2009Assignee: C.H. Erbsloeh KGInventor: Gerhard Barich
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Publication number: 20090069465Abstract: Pseudoplastic curable mixtures comprising (A) at least one reaction product of (a1) at least one reaction product of (a11) at least one olefinically unsaturated carboxylic acid with (a12) at least one glycidyl ester of an unsaturated carboxylic acid (a121) with (a2) at least one polyisocyanate having an epoxide group (calculated as M=42 daltons) content <0.2% by weight and an acid number <10 mg KOH/g and also (B) at least one rheology control additive, process for preparing them, and their use.Type: ApplicationFiled: December 8, 2005Publication date: March 12, 2009Applicant: Basf Coatings AktiengsellschaftInventors: Bertold Austrup, Gunter Ott, Hubert Baumgart, Karl-Heinz Joost
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Patent number: 7491778Abstract: Articles coated with a water-resistant coating that absorbs water to provide the water-resistant effect, and desorbs water when the coating is dried, and a method of providing water resistance and corrosion resistance to articles prepared with such coatings. The coating is formed by applying a composition comprising an aqueous solution of a superabsorbent water-soluble polymer precursor, optionally a viscosity modifying agent, and optionally a lubricant onto the surfaces of the article, and curing to form a coating comprising the superabsorbent polymer.Type: GrantFiled: September 30, 1999Date of Patent: February 17, 2009Assignee: Neptco JV LLCInventors: Martin C. Flautt, James R. Priest, David V. Stotler, Thomas P. Hager
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Patent number: 7485679Abstract: A color and/or effect coating material which is free from rheological aids based on phyllosilicates and comprises (A) a water-soluble, water-dilutable and/or water-dispersible polyurethane; (B) a color and/or effect pigment; (C) a dispersing assistant selected from the group consisting of the reaction products of (c1) a functionalized copolymer containing (c11) a copolymerized olefinically unsaturated monomer isocyanate groups, anhydride groups and epoxy groups; and (c12) a copolymerized olefinically unsaturated monomer which is free from isocyanate-, anhydride- and epoxy-reactive functional groups; (c2) at least one homopolymeric polyalkylene glycol, and (c3) at least one compound of the general formula I: NR2—C(O)—NR2??(I) in which the variables R are selected from the group consisting of hydrogen atoms and organic radicals, at least one of the radicals R containing at least one reactive functional group selected from the group consisting of isocyanate-, anhydride- and epoxy-reactive groups; and (D)Type: GrantFiled: November 5, 2003Date of Patent: February 3, 2009Assignee: BASF Coatings AGInventors: Sapper Goetz-Ekkehard, Hummert Tobias
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Publication number: 20090030137Abstract: Polyacetal composition comprising polyacetal, ultrahigh molecular weight polyethylene, and a compatibilizer comprising ethylene/vinyl acetate copolymer and, optionally, at least one epoxy-containing compound.Type: ApplicationFiled: July 26, 2007Publication date: January 29, 2009Inventor: Ramabhadra Ratnagiri
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Patent number: 7482399Abstract: A pseudoplastic clearcoat slurry comprising solid and/or highly viscous particles which are dimensionally stable under storage and application conditions and at least one wetting agent selected from the group consisting of alkoxylated fatty alcohols having from 16 to 18 carbon atoms in the alkyl radical and containing on average per molecule at least 20 oxaalkanediyl groups; process for preparing it, and its use.Type: GrantFiled: July 23, 2002Date of Patent: January 27, 2009Assignee: BASF Coatings AGInventors: Fatmir Raka, Joachim Woltering, Heike Florack
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Patent number: 7479519Abstract: The curable urethane polymer adhesive or coating of the present invention comprises at least one ethylenically unsaturated monomer and in one embodiment an aliphatic conjugated diene monomer, a hydroxy functional monomer, and a colloid having hydroxy functionality and a moiety having isocyanate functionality. The colloid having hydroxy functionality is present with the ethylenically unsaturated monomer and the hydroxy-functional monomer during polymerization so as to become incorporated into the latex to provide stabilization.Type: GrantFiled: October 27, 2005Date of Patent: January 20, 2009Assignee: Mallard Creek Polymers, Inc.Inventor: Venkataram Krishnan
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Patent number: 7479520Abstract: An aqueous coating material, substantially or completely free from volatile organic compounds and preparable by mixing with one another (A) at least one aqueous primary dispersion comprising dispersed and/or emulsified, solid and/or liquid polymer particles and/or dispersed solid core/shell particles with a diameter ?500 nm, preparable by free-radical microemulsion or miniemulsion polymerization of at least one olefinically unsaturated monomer in the presence of at least one hydrophobic additive, and (B) at least one secondary aqueous polyurethane dispersion comprising at least one polyurethane and at least one light stabilizer selected from the group of the regenerable free-radical scavengers, a process for preparing it and its use.Type: GrantFiled: February 13, 2002Date of Patent: January 20, 2009Assignee: BASF Coatings AGInventors: Ralf Nickolaus, Heinz-Peter Rink, Reinhold Clauss, Elisabeth Wessling, Wilma Löcken, Maximilian Bendix, Dunja Mikolajetz
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Publication number: 20090018254Abstract: Disclosed herein is an aqueous multicomponent system comprising (I) at least one aqueous binder component comprising (A) at least one secondary dispersion comprising (A1) at least one water-soluble or water-dispersible (meth)acrylate copolymer which can be prepared by a multistage copolymerization and has at least two isocyanate-reactive functional groups, and (A2) at least one low molecular weight or oligomeric, or at least one low molecular weight and oligomeric, substantially unbranched, hydrophobic polyester having at least two hydroxyl groups in the molecule, an OH number of 56 to 500 mg KOH/g, an acid number less than 10 mg KOH/g, and a number-average molecular weight Mn of 300 to 2000 Daltons, the at least one aqueous binder further comprising (B) at least one additive. The aqueous multicomponent system further comprises at least one water-free crosslinking component comprising at least one hydrophilicized polyisocyanate.Type: ApplicationFiled: February 8, 2007Publication date: January 15, 2009Applicant: BASF COATINGS AGInventors: Inge Huster, Bernhard Lettmann, Egbert Nienhaus
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Patent number: 7473442Abstract: Disclosed are multi-component waterborne coating compositions that include a first component and a second component which are mixed together prior to application of the composition to a substrate. The first component includes an aqueous dispersion of (i) a polycarbonate-polyurethane polymer, and (ii) an acrylic polyol having a number average molecular weight of no more than 5,000. The second component includes a material having functional groups reactive with the functional groups of the acrylic polyol and/or the polycarbonate-polyurethane polymer. Also disclosed are coatings formed from such compositions and substrates at least partially coated with such compositions.Type: GrantFiled: September 14, 2005Date of Patent: January 6, 2009Assignee: PPG Industries Ohio, Inc.Inventors: Michael J. Ziegler, William H. Retsch, Jr.
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Publication number: 20080311064Abstract: It is an object of our invention to provide capsule particles and a method of creating larger and robust capsule particles that will have excellent storage stability and enhanced perfumer performance in a range of consumer products.Type: ApplicationFiled: June 12, 2007Publication date: December 18, 2008Inventors: Yabin Lei, Lewis Michael Popplewell
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Publication number: 20080302479Abstract: The invention relates to cured (meth)acrylate based adhesive composition, comprising at least two co-continuous phases of interpenetrating networks and at least two types of polymeric inclusions, in which one of the co-continuous phases comprises a polymer or copolymer based on at least one acrylic or methacrylic acid monomer or a derivative thereof. These compositions exhibit better facture toughness, especially at low temperatures.Type: ApplicationFiled: December 5, 2006Publication date: December 11, 2008Applicant: Huntsman International LLCInventors: Pauline Goodall Barker, Dimiter Lubomirov Kotzev
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Patent number: 7452935Abstract: A two-component floor coating composition comprising: (a) an aqueous solution of a polyhydroxypolyacrylate having acid groups neutralized with a tertiary amine containing at least two hydroxy groups; said solution comprising an organic solvent; and (b) an aliphatic polyisocyanate.Type: GrantFiled: September 8, 2005Date of Patent: November 18, 2008Assignee: Rohm and Haas CompanyInventors: Caroline S. Slone, Theodore Tysak
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Publication number: 20080275179Abstract: A low profile connector assembly comprises at least one contact having a surface mount portion and a wire engagement portion extending from the surface mount portion, and a housing insertable over the at least one contact and retained to the at least one contact. The housing encloses the wire engagement portion and has a wire receiving aperture therethrough. The wire receiving aperture provides access to the wire engagement portion when the housing is retained to the contact.Type: ApplicationFiled: February 21, 2006Publication date: November 6, 2008Applicant: POLYONE CORPORATIONInventors: Stephen Horton, Brent Cassata
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Publication number: 20080262131Abstract: The invention relates to one-component aqueous dispersion adhesives containing at least one copolymer A of monomers ethylene, vinyl acetate and, optionally, at least one (meth)acrylate and either at least one polyurethane with carboxyl groups and carbodiimide groups PUR-COOH-CDI or a mixture of a polyurethane with carboxyl groups PUR-000H and with a carbodiimide CDI. These dispersion adhesives are particularly well-suited for use as laminating adhesives and sealing adhesives. The invention also relates to the precoating of flat materials with a one-component aqueous dispersion adhesive.Type: ApplicationFiled: May 17, 2005Publication date: October 23, 2008Inventors: Martin Linnenbrink, Peter Kuehnemund, Jurgen Mueller
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Patent number: 7427647Abstract: A coating composition useful for coating automobile and truck bodies comprising a binder of a. polyisocyanate crosslinking agent; b. an isocyanate-reactive component having at least one compound having the following formula: wherein X, Y, R1, R2, m and n are described in the specification, and c. 0.05 to 10% by weight, based on the total weight of the coating composition, of a metal alkoxide compound; and containing optional additional polymeric components, oligomeric components and antioxidants, light absorbers and light stabilizers.Type: GrantFiled: January 12, 2006Date of Patent: September 23, 2008Assignee: E.I. du Pont de Nemours & CompanyInventors: Stefan Reinartz, Robert John Barsotti, Patrick Henry Corcoran, Kalindi Dogra, Christian Peter Lenges, Laura Ann Lewin, Klaus Wissing
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Publication number: 20080220273Abstract: The invention relates to ethylene/?-olefin compositions containing at least one ethylene/?-olefin random interpolymer and at least one polydiene diol-based polyurethane, and where the at least one ethylene/?-olefin interpolymer has a PRR from ?6 to 75, and a density less than, or equal to, 0.93 g/cc.Type: ApplicationFiled: September 12, 2006Publication date: September 11, 2008Inventor: Laura B. Weaver
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Patent number: 7423077Abstract: Coating materials, processes for preparing them, and their use. The coating materials include hydroxyl-containing (meth)acrylate (co)polymer, carbamate- and hydroxyl-functional compound, an amino resin, and a triazine compound. At least 10 equivalent % of the hydroxyl groups present in (A) and/or (B) are primary hydroxyl groups. The coating materials after curing have a storage modulus E? in the rubber-elastic range of at least 1.5*107 Pa, the storage modulus E? having been measured by dynamic mechanical thermoanalysis (DMTA) on homogeneous free films with a thickness of 40±10 ?m.Type: GrantFiled: January 20, 2004Date of Patent: September 9, 2008Assignee: BASF Coatings AGInventors: Guido Wilke, Vince Cook, Thomas Farwick
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Publication number: 20080214718Abstract: Treating metal or metal oxides such as ZnO with PIBSA and analogous molecules yields a hydrophobic powder. The powder can provide improved optical clarity when incorporated into a polymer matrix in comparison to untreated hydrophilic ZnO.Type: ApplicationFiled: January 4, 2008Publication date: September 4, 2008Applicant: AIR PRODUCTS AND CHEMICALS, INC.Inventors: Frank Vito DiStefano, Lisa Ann Mercando, Jennifer Anne Bierkamp
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Patent number: 7419723Abstract: It is an object of the present invention to provide a base coating composition for decorated moldings containing silver plating layer and a top clear coating composition for decorated moldings containing silver plating layer, and decorated moldings obtainable by using these compositions; the compositions and moldings are to be excellent in silver deposition tendency, basecoat film smoothness, adhesion and/or film appearance.Type: GrantFiled: June 3, 2004Date of Patent: September 2, 2008Assignees: Honda Motor Co., Ltd., Nippon Bee Chemical Co., Ltd.Inventors: Tatsuya Itakura, Takashi Yamamoto, Manabu Yamaoka, Toshihiko Uchiyama
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Patent number: 7419724Abstract: One aspect of the present invention is an adhesive composition formed from two packs. One pack includes an isocyanate-functional prepolymer formed by reacting a polyisocyanate with an alcohol (e.g., polyol). The isocyanate equivalents from the polyisocyanate exceed the hydroxyl equivalents from the alcohol. The second pack is an aqueous polymer emulsion. These two packs are combined to form the novel adhesive composition. Another aspect of the invention is a method for joining together two surfaces of wood products by application of an adhesive thereto. The first step in this method is to mist with water the wood product surfaces to be joined. An adhesive composition then is applied to the misted wood product surfaces. Alternatively, the water misting can be replaced with an aqueous emulsion being part of the adhesive composition. Finally, the adhesive composition is cured.Type: GrantFiled: July 24, 2003Date of Patent: September 2, 2008Assignee: Ashland, Inc.Inventors: Gang-Fung Chen, Gary J. Walworth