With Solid Polymer Derived From At Least One -n=c=x (x Is Chalcogen) Reactant Wherein At Least One Of The Reactants Forming The Solid Polymer Is Saturated; Or With Spfi Or Sicp Derived From A -n=c=x Reactant Wherein At Least One Of The Necessary Reactants Is Saturated Patents (Class 524/507)
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Patent number: 8299164Abstract: Disclosed is an aqueous clearcoat material for producing a waterborne urethane-based two-coat coating system, comprising at least one secondary polyacrylate dispersion having a polyacrylate glass transition temperature Tg?20° C. and at least one hybrid polyacrylate-polyurethane dispersion with a weight ratio of the polyacrylate fraction of the secondary dispersion to the polyacrylate-polyurethane fraction of the hybrid dispersion of 1:1 to 4:1, and as curing agent at least one low-viscosity aminosulfonic polyisocyanate and an aqueous basecoat material for producing a waterborne two-coat coating system comprising at least one polyurethane dispersion, at least one hybrid polyacrylate-polyurethane dispersion, and at least one melamine resin. Also disclosed are a waterborne two-coat coating system comprising the clearcoat material and the basecoat material, a process for producing it, its use to coat a substrate, and substrates coated with it.Type: GrantFiled: April 30, 2008Date of Patent: October 30, 2012Assignee: BASF Coatings GmbHInventors: Anne Fickers, Heinz-Peter Rink, Andreas Dopp
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Publication number: 20120268521Abstract: A set of an ink containing a pigment dispersed by a water-soluble resin and having the surface tension of 38 mN/m or less and a reaction liquid containing a polyvalent metal ion and a surfactant, which is an ethylene oxide adduct of a higher alcohol of a linear primary or secondary alcohol or an isoalkyl alcohol, and has a HLB value of 13.0 or more as determined by the Griffin method. The content of the polyvalent metal ion in the reaction liquid is 10.0 times or more in terms of molar ratio as much as an amount of an acidic group derived from the water-soluble resin in the ink and the content of the surfactant in the reaction liquid is 0.15 times or more in terms of mass ratio as much as the total content of the pigment and water-soluble resin in the ink.Type: ApplicationFiled: April 5, 2012Publication date: October 25, 2012Applicant: CANON KABUSHIKI KAISHAInventors: Kenji Moribe, Yasuhito Mori
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Publication number: 20120270992Abstract: The invention provides core-shell hybrid latexes wherein the core comprises poly(acrylate)polymers and the shell comprises vegetable oil-based waterborne polyurethanes, and the latexes lack surfactants. Surfactant-free core-shell hybrid latexes with waterborne vegetable oil-based polyurethanes as the shell and poly(acrylate) as the core have been successfully prepared by seeded emulsion polymerization. The crosslink densities of the polymers obtained can be controlled by using modified vegetable oil polyols with various hydroxyl numbers or by adding a multifunctional vinyl crosslinker to the poly(acrylate) core.Type: ApplicationFiled: April 20, 2012Publication date: October 25, 2012Inventors: Richard C. Larock, Yongshang Lu
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Publication number: 20120258317Abstract: An aqueous two-component aqueous dispersion adhesives, including in particular polyether-polyurethane polymers and ethylene vinyl acetate copolymers (EVA) having a glass transition temperature of greater than 0° C. The dispersion adhesives are optimally suited for use as contact adhesives, and for gluing plastic membranes. It has been demonstrated that the adhesives or the adhesive composite items produced therewith are characterized by an exceptionally low plasticizer absorption behavior, and contact adhesion. The good heat resistance and good bonding to various bases are also advantageous.Type: ApplicationFiled: October 12, 2010Publication date: October 11, 2012Applicant: SIKA TECHNOLOGY AGInventors: Martin Demmig, Andre Buchholz, Christina Bosse, Tino Bendkowski
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Publication number: 20120249663Abstract: An ink jet ink contains a polyurethane polymer and a pigment. The polyurethane polymer has units derived from a polyisocyanate, a polyether polyol having no acid group, and a diol having an acid group. The pigment is dispersed using a polymer other than the polyurethane polymer. The molar ratio of the percentage of the urethane bond in the polyurethane polymer to the percentage of the urea bond in the polyurethane polymer is 85.0/15.0 or more and 100.0/0 or less.Type: ApplicationFiled: March 20, 2012Publication date: October 4, 2012Applicant: CANON KABUSHIKI KAISHAInventors: Kouichirou Okumura, Kenichi Shiiba, Daiji Okamura, Kousuke Yamasaki, Kenji Moribe, Hiromitsu Kishi
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Publication number: 20120252959Abstract: A crosslinked coating composition formed from polyurethane polyols and blocked or unblocked polyisocyanates. The polyisocyanates, in particular, comprise at least bis(isocyanatomethyl) cyclohexane. The coating is substantially free from ester functionality that forms a contiguous part of the network backbone. A clearcoat formed from the described components and having a majority of urethane bonds is very resistant to environmental etch damage.Type: ApplicationFiled: January 10, 2011Publication date: October 4, 2012Applicant: E I DU PONT DE NEMOURS AND COMPANYInventors: Delson Jayme Trindade, Robert R. Matheson
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Publication number: 20120252927Abstract: Surface coating composition, method and apparatus for coating a surface. The surface coating composition comprises a recycled rubber product, one or more binding agent and optionally one or more additional agent.Type: ApplicationFiled: June 18, 2012Publication date: October 4, 2012Inventors: Mathieu MALBOEUF, Dorian BRAUN
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Publication number: 20120252958Abstract: A strippable coating composition for floors which contains at least 50% by weight of an aqueous polyurethane resin relative to the total solid content, wherein the hydroxyl-containing compound component constituting the aqueous polyurethane resin comprises (A) a polyester polyol component prepared from 1,6-hexanediol and either an aliphatic dibasic acid and/or an aromatic dibasic acid, (B) a low-molecular alicyclic diol component, and (C) an unsaturated fatty acid ester polyol. The strippable coating composition can form a coating film that has a tear strength of 0.3N or more, a break strength of 10 MPa or more, and an elongation at break of 50% or more.Type: ApplicationFiled: September 15, 2010Publication date: October 4, 2012Applicants: ADEKA CORPORATION, RINREI WAX CO., LTD.Inventors: Konosuke Yagi, Satoshi Kaneda, Tetsuya Umehara, Shimon Nishida, Tamotsu Nagamatsu, Tatsumi Kosaka
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Publication number: 20120245257Abstract: This invention provides a pellet derived from recycled waste products in particular from a mixture of two or more of cellulose fibers, recyclable plastic, glass and ceramics and other recyclable products such as tetra paks. The pellets can be used to make a variety of extruded or injection molded products including household trim and moldings, decking, shutters, etc.Type: ApplicationFiled: August 26, 2010Publication date: September 27, 2012Applicant: GLOBAL PATENTED TECHNOLOGIES INC.Inventor: Carlo Fascio
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Publication number: 20120235083Abstract: This invention pertains to a composition that can be used to heal cracks in plastics and other substrates. In the present invention, a composition comprising nanotubes, healing agent(s), and end caps for the nanotubes may be used to heal crack(s) as they begin to occur. With the composition, the healing agent(s) are contained within the nanotubes, and a reaction releases the healing agent(s) after the end caps can be removed from the nanotubes. This invention also includes a method of preparing a composition for healing cracks in plastics and other substrates. For this method, the healing agent(s) are filled inside of the nanotubes, and then end caps are bound onto the ends of the nanotubes. After a reaction occurs to remove the end caps and release the healing agent(s), the cracks within the substrate may then be healed.Type: ApplicationFiled: March 19, 2012Publication date: September 20, 2012Inventor: Jorma Antero Virtanen
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Publication number: 20120238689Abstract: Compatibilized blends comprising a first phase comprising a thermoplastic olefin polymer and a second phase comprising a crosslinked, thermoplastic polyurethane are provided. The first phase is a continuous phase and the second phase can be co-5 continuous with the first phase, or dispersed as a non-continuous phase in the first phase. The blends further include a phenolic resole resin which at least partially crosslinks the thermoplastic polyurethane and acts as a compatibilizer for the olefin polymer and the thermoplastic polyurethane.Type: ApplicationFiled: December 11, 2009Publication date: September 20, 2012Inventors: Yabin Sun, Xiang Yang Tai, Li Qiang Fan
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Patent number: 8268922Abstract: Pressure-sensitive adhesive based on a mixture of chemically crosslinked polyurethane and at least one hydrocarbon resin, the chemically crosslinked polyurethane being a reaction product of at least one aliphatic or alicyclic polyisocyanate and a combination of at least one polypropylene glycol diol and one polypropylene glycol triol, reacted with one another catalytically in the presence of the at least one hydrocarbon resin, the at least one hydrocarbon resin being a monomer resin of the styrene/?-methylstyrene type.Type: GrantFiled: June 27, 2007Date of Patent: September 18, 2012Assignee: tesa SEInventors: Uwe Schümann, Kirstin Weiland, Bodo Zu Putlitz
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Publication number: 20120225992Abstract: The invention relates to amino and hydroxy-functional compounds other than polyesters, wherein the compound includes an amine in the form of aspartic acid esters functionality, and wherein the amino and hydroxy-functional compound has (a) a molecular weight (Mn) of at least about 500, (b) an acid value of about 5 or less, (c) a hydroxyl value of about 30 or more, and (d) an amine value of about 30 or more. Preferably, the compound includes molecules having on the average: at least 1 secondary amino group as an aspartate, and/or at least 1 hydroxy group, and an average total functionality of about 1.8 or higher.Type: ApplicationFiled: May 16, 2012Publication date: September 6, 2012Applicant: NUPLEX RESINS B.V.Inventors: Mohamad Deeb SHALATI, NANDA Ajaya, HELLEMS Stephen
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Publication number: 20120225991Abstract: The invention relates to amino and hydroxy-functional polyesters, wherein the amine is in the form of aspartic acid esters functionality, and wherein the amino and hydroxy-functional polyester has (a) a molecular weight (Mn) of at least about 500, (b) an acid value of about 5 or less, (c) a hydroxyl value of about 30 or more, and (d) an amine value of about 30 or more, and (e) an amine functionality of less than 1.8. Preferably, the compound includes molecules having on the average: at least 1 secondary amino group as an aspartate, and/or at least 1 hydroxy group, and an average total functionality of about 1.8 or higher. More preferably, the molecular weight of the amino and hydroxy-functional polyesters is between 204 and 10,000 and preferably between 482 and 5000.Type: ApplicationFiled: May 16, 2012Publication date: September 6, 2012Applicant: NUPLEX RESINS B.V.Inventors: Mohamad Deeb SHALATI, Ajaya NANDA, Stephen HELLEMS
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Publication number: 20120219805Abstract: The present invention is directed to a process for producing a low VOC (volatile organic compound) coating composition. The process can comprise mixing a solvent borne coating component and a low or zero VOC waterborne coating component in the presence of a low molecular weight polytrimethylene ether glycol. The present invention can be used to produce low VOC coatings for automotive original equipment manufacturing (OEM) and refinish coating applications, industrial coating applications on equipments and structures, or architectural coating applications on buildings or other structures. This disclosure is further directed to a coating composition comprising components derived from renewable resources.Type: ApplicationFiled: February 20, 2012Publication date: August 30, 2012Applicant: E. I. DU PONT DE NEMOURS AND COMPANYInventors: AYUMU YOKOYAMA, HARI BABU SUNKARA, RAJESH GOPALAN SALIYA, KARLIS ADAMSONS
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Publication number: 20120220710Abstract: The present disclosure relates to an isocyanate terminated saturated hydrocarbon polymer that can be used as a crosslinking agent in a coating composition. The coating composition can provide a composition that adheres well to resinous substrates. Also provided are coating composition comprising the crosslinking agent and methods for producing the adherent coating composition.Type: ApplicationFiled: November 4, 2010Publication date: August 30, 2012Inventor: Patrick Henry Corcoran
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Patent number: 8248313Abstract: An antenna module includes a radiator made of nanomaterials; the conductivity of the nanomaterials are greater than or equal to about 5.8×107 S/m. The present further discloses a wireless communication device using the antenna module.Type: GrantFiled: November 2, 2009Date of Patent: August 21, 2012Assignees: Shenzhen Futaihong Precision Industry Co., Ltd., FIH (Hong Kong) LimitedInventors: Steven-Philip Marcher, Zhan Li, Ye Xiong, Wei-Dong Hao
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Patent number: 8235251Abstract: The invention relates to cured (meth)acrylate based adhesive composition, comprising at least two co-continuous phases of interpenetrating networks and at least two types of polymeric inclusions, in which one of the co-continuous phases comprises a polymer or copolymer based on at least one acrylic or methacrylic acid monomer or a derivative thereof. These compositions exhibit better facture toughness, especially at low temperatures.Type: GrantFiled: February 17, 2011Date of Patent: August 7, 2012Assignee: Huntsman International LLCInventors: Pauline Goodall Barker, Dimiter Lubomirov Kotzev
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Patent number: 8236895Abstract: Disclosed is a finish paint composition having a hydroxyl group containing resin (A) comprising a hydroxyl group value of 80 to 220 mgKOH/g, a glass transition temperature of ?50° or above but below 0° C., and 25 to 55 mass% of units of 4-hydroxybutyl (meth)acrylate origin, a hydroxyl group containing resin (B) with a hydroxyl group value of 80 to 220 mgKOH/g, and a glass transition temperature of 0 to 50° C., and a crosslinking agent (C) comprising polyisocyanate compound having isocyanate groups, wherein the proportions of hydroxyl group containing resin (A) and hydroxyl group containing resin (B) are, as a ratio of solid fraction masses, from 95/5 to 50/50, and the proportion of isocyanate groups of the crosslinking agent (C) with respect to the hydroxyl groups in total of the hydroxyl group containing resin (A) and the hydroxyl group containing resin (B), as the NCO/OH mol ratio, is 0.5 to 1.5.Type: GrantFiled: August 22, 2008Date of Patent: August 7, 2012Assignees: BASF Coatings Japan Ltd., BASF Coatings GmbHInventors: Hitoshi Taniguchi, Hiroyuki Takagi, Eishi Tsukamoto, Andreas Poppe, Björn Feldmann, Julia Melzer, Sabine Holtschulte, Karl-Heinz Joost
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Publication number: 20120196958Abstract: Provided is a polyalkylene carbonate resin composition for producing a decorating material and an environment-friendly polyalkylene carbonate resin decorating material produced therefrom, and more particularly to polyalkylene carbonate resin composition for producing a decorating material in which a polymer additive is input to impart heat resistance and shape stability of the decorating material, a crosslinker and a chain extender is input to improve the processability at a processing temperature, and a flame retardant agent is added to impart a flame retardant effect, and an environment-friendly polyalkylene carbonate resin decorating material produced therefrom. An environment-friendly polyalkylene carbonate resin decorating material having excellent thermal stability, processability, and dimensional stability can be produced by using the composition according to the present invention.Type: ApplicationFiled: January 26, 2012Publication date: August 2, 2012Applicant: SK INNOVATION CO., LTD.Inventors: Younghyo Park, Inhun Son, Kangmin Jung, Jaekoo Kim, Kwangjin Chung, Myung Ahn Ok
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Patent number: 8222338Abstract: The present invention relates to an aqueous dispersion comprising at least one alkyd resin and at least one addition polymer having at least one (meth)acrylate segment which comprises 1% to 30% by weight of units derived from (meth)acrylates which in the alkyl radical have at least one double bond and 8 to 40 carbon atoms, 0.1% to 10% by weight of units derived from monomers containing acid groups, and 50% to 98.9% by weight of units derived from (meth)acrylates having 1 to 6 carbon atoms in the alkyl radical, based on the weight of the (meth)acrylate segment.Type: GrantFiled: October 6, 2008Date of Patent: July 17, 2012Assignee: Evonik Röhm GmbHInventors: Christine Breiner, Joachim Knebel, Gerold Schmitt
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Publication number: 20120164362Abstract: A primer-less coating composition for facestock comprises: a binder being a water-dispersible polymer; an ethylenically unsaturated compound which is aqueous-dispersible and miscible with or bonded to said water-dispersible polymer, wherein said ethylenically unsaturated compound is able to form a covalent bond with an ink; and a crosslinker, wherein said crosslinker is suitable for binding the coating to the facestock. The coating composition may be applied to a substrate to form a printable film. A printed film in accordance with the invention may be used in a label, for example for use on a container such as a bottle.Type: ApplicationFiled: March 5, 2012Publication date: June 28, 2012Applicant: INNOVIA FILMS LIMITEDInventors: Alastair Hugh Servante, Simon James Read
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Publication number: 20120164404Abstract: A primer-less coating composition for facestock comprises: a binder being a water-dispersible polymer; an ethylenically unsaturated compound which is aqueous-dispersible and miscible with or bonded to said water-dispersible polymer, wherein said ethylenically unsaturated compound is able to form a covalent bond with an ink; and a crosslinker, wherein said crosslinker is suitable for binding the coating to the facestock. The coating composition may be applied to a substrate to form a printable film. A printed film in accordance with the invention may be used in a label, for example for use on a container such as a bottle.Type: ApplicationFiled: March 5, 2012Publication date: June 28, 2012Applicant: INNOVIA FILMS LIMITEDInventors: Alastair Hugh Servante, Simon James Read
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Publication number: 20120160414Abstract: Compositions for coating roofs roof, facades, floors or vertical facings including at least one acrylic polymer and at least one polyurethane polymer and at least one ethylene vinyl acetate emulsion. The compositions combine the advantages of the excellent features of polyurethane compositions with the reduced cost of acrylic compositions in such a manner that a balance between both characteristics is shown. Methods for covering a roof, facade, floor or vertical facing with these compositions and the use thereof as a coating for roofs, facades, floors or vertical facings.Type: ApplicationFiled: December 30, 2011Publication date: June 28, 2012Applicant: Sika Technology AGInventors: Pilar Pámpanas, Carsten Zilg, Carlos Molina, Manuel Rodriguez, Luz Granizo Fernandez
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Publication number: 20120156510Abstract: An anti-soiling composition including: compound (A) having a perfluoropolyether group and an active energy ray-reactive group; and inorganic fine particles (B), wherein compound (A) is contained in an amount of 20 parts by mass or more and 75 parts by mass or less in 100 parts by mass of a solid content of the composition.Type: ApplicationFiled: June 16, 2010Publication date: June 21, 2012Applicant: MITSUBISHI RAYON CO., LTD.Inventors: Hiroshi Okafuji, Hideto Yamazawa
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Publication number: 20120144604Abstract: The present invention provides a multifunctional primer, comprising a first solution including 15 to 55 parts by weight of natural rubber and 750 to 1350 parts by weight of an organic solvent; a second solution from 100 parts by weight of the first solution and additionally 45 to 90 parts by weight of a polyurethane-dispersion; comprising a third solution from 100 parts by weight of the second solution and 100 to 250 parts by weight of a butadiene-based rubber solution containing 50 to 200 parts by weight of a butadiene rubber and 800 to 950 parts by weight of an organic solvent. Additionally a method of manufacturing a shoe is disclosed in an environmentally friendly manner by application of the primer to a transfer sheet, this being dried and cut into appropriate pieces, and this film-type multifunctional primer applied on a non-vulcanized outersole of a shoe.Type: ApplicationFiled: February 17, 2012Publication date: June 14, 2012Inventor: Sung-Hwan Huh
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Publication number: 20120149828Abstract: The present invention is a chemical composition that provides a low friction coating and a low sliding coefficient of friction onto a plastic or metal working part that includes a waterborne polyisocyanate such as ureas, urethanes or tetramethylxylene diisocyanates (TMXDI) in the composition structure and a plurality of cross linkable functional groups that include carboxyl groups and hydroxyl groups that are added utilizing plasma or chemical grafting and etching and a plastic or metal chemical substrate. The composition also includes one or more materials that are single linked or multiple linked hydrogels such as polyvinylpyrrolidone (PVP), polyethylene glycol (PEG) or polyvinyl alcohol (PVA) mixed with the polyisocynate and one or more crosslinkers such as aziridines or carbodiimides that link the hydrogels, the polyisocynate and the substrate together to form the composition.Type: ApplicationFiled: March 25, 2011Publication date: June 14, 2012Inventor: David Scott Webb
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Patent number: 8197590Abstract: Disclosed is a composition containing a fluorine-containing urethane compound (A) and a fluorine-containing polymer (B) having a repeating unit derived from a fluorine-containing monomer represented by the following formula (I): CH2?C(—X)—C(?O)-A-Rf??(I) (wherein X represents a fluorine atom, a chlorine atom, a bromine atom, an iodine atom, a CFX1X2 group (wherein X1 and X2 respectively represent a hydrogen atom, a fluorine atom or a chlorine atom), a cyano group, a straight or branched chain fluoroalkyl group having 1-20 carbon atoms, a substituted or unsubstituted benzyl group, or a substituted or unsubstituted phenyl group; A represents a divalent group; and Rf represents a straight or branched chain perfluoroalkyl group having 1-6 carbon atoms).Type: GrantFiled: October 27, 2005Date of Patent: June 12, 2012Assignee: Daikin Industries, Ltd.Inventors: Ikuo Yamamoto, Shinichi Minami
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Publication number: 20120141747Abstract: Styrene-acrylic dispersants for use in pigment dispersions have lower viscosities than benchmark formulations such as nitrocellulose, dimer-acid based polyamides, and thermoplastic polyurethanes, prepared under otherwise identical conditions. Lower viscosities allow for the preparation of similarly viscous dispersions and inks with the styrene-acrylics when compared to traditional dispersants, at either (a) lower solvent levels, or if solvent levels are to be maintained, (b) higher pigment and solids loadings.Type: ApplicationFiled: July 14, 2010Publication date: June 7, 2012Inventors: Gary A. Deeter, Chien Hsu, Timothy D. Klots
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Patent number: 8192837Abstract: This invention relates to compositions suitable for the formation of an adhesive layer used for in-mold decoration. This invention also relates to in-mold decoration tape or strip, comprising: a carrier layer; a release layer; a durable layer; and an adhesive layer which comprises an adhesive binder, a polymeric particulate material and an inorganic particulate material.Type: GrantFiled: December 17, 2008Date of Patent: June 5, 2012Assignee: Etansi Inc.Inventors: Xiaojia Wang, Cheri Pereria, Pei-Lin Wang, Jing-Den Chen, Rong-Chang Liang
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Publication number: 20120135174Abstract: Provided is a release agent capable of maintaining the inherent detachability of polyolefin and showing good adhesion to the substrate and a release material using the release agent, and an adhesive tape having such release material. A release agent containing at least a polyolefin, an aromatic isocyanate having three or more isocyanate groups in one molecule, and a polyolefin polyol having a number-average molecular weight of 1500 to 5000.Type: ApplicationFiled: August 6, 2010Publication date: May 31, 2012Applicant: NITTO DENKO CORPORATIONInventors: Tsuyoshi Hiramatsu, Tomoko Hatanaka, Toru Iseki
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Publication number: 20120135243Abstract: To provide an aqueous dispersion of a resin wherein dispersed particles are stable with fine particle sizes and whereby bleeding out is suppressed, which is thus useful as e.g. a surface treating agent for a polyolefin substrate, an adhesive or a coating material. A resin dispersion having dispersed in water a polymer (C) having a hydrophilic polymer (B) bonded to a polyolefin (A) in a ratio of (A):(B)=100:5 to 100:500 (weight ratio); a method for producing the resin dispersion; and a coating material and a laminate, employing it.Type: ApplicationFiled: February 3, 2012Publication date: May 31, 2012Applicant: MITSUBISHI CHEMICAL CORPORATIONInventors: Masato ONOE, Toshiya Seko, Yongwoo Shin, Yongjun Jang, Fumihiko Shimizu
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Patent number: 8188184Abstract: An environmentally safe additive and vehicle system are provided for water-based and oil-based printing inks, paints, coatings and adhesives which can be rapidly transferred, dispersed, dispensed, spread, dried and cured. The low cost, stable additive and vehicle system enhance multiple color, high speed printing with sharp, highly defined images and superior quality, and can be used on many different types of substrates, such as paper, paperboard, cardboard, clay coated board, foil, plastic, glass, metal, wood and composites. The additive may be formed by the reaction product of a photoinitiator, such as an UV-activated polyelectrolyte, and a monomer, such as an acrylate or a methacrylate in an aqueous solution. In other embodiments, the additive is formed from a carboxylic acid or anhydride and alkylalkanolamine monomer or a dialkylaminoalkyl acrylate or methacrylate monomer in an aqueous solution.Type: GrantFiled: November 30, 2010Date of Patent: May 29, 2012Assignee: Omnitech Environmental, LLCInventors: Leroy John Cook, Richard T. Skov
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Patent number: 8187371Abstract: An ink composition comprising (a) water, (b) pigment particles, (c) at least one humectant, (d) at least one polyurethane having an average molecular weight of at least about 10,000 and a sufficient number of acid groups to provide an acid number from 60 to about 130, and being present at a weight concentration of greater than 0.7%, and (e) at least one water soluble acrylic polymer comprising carboxylic acid groups, present at a weight concentration of greater than 0.6%, wherein the acid groups on the polyurethane and acrylic polymers are at least partially neutralized only with a monovalent inorganic base.Type: GrantFiled: February 12, 2008Date of Patent: May 29, 2012Assignee: Eastman Kodak CompanyInventors: Thomas B. Brust, Michael J. Carmody, Robert H. Fehnel, Gary L. House, Mark E. Irving, Yongcai Wang, Paul D. Yacobucci
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Patent number: 8188196Abstract: A two-component polyurethane clear coat kit system consisting of: (1) a binder component having a solids content of 42 to 50 wt.-% comprising at least one hydroxyl-functional binder and a volatile organic content of 50 to 58 wt.-%, and (2) a polyisocyanate crosslinker component having a solids content of 66 to 70 wt.-% and a volatile organic content of 30 to 34 wt.-%, wherein the solids content of the polyisocyanate crosslinker component comprises a free polyisocyanate solids content consisting of 75 to 100 wt.-% of at least one polyisocyanate of the 1,6-hexane diisocyanate isocyanurate type and of 0 to 25 wt.-% of at least one polyisocyanate of the isophorone diisocyanate isocyanurate type, wherein the sum of the respective wt.-% in each case totals 100 wt.-%.Type: GrantFiled: February 19, 2010Date of Patent: May 29, 2012Assignee: E. I. du Pont de Nemours and CompanyInventors: Fabian Koehn, Andreas Benfer, Birte Bannert
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Publication number: 20120130003Abstract: An aqueous floor care composition comprising water, polymer particles wherein the polymer particles include units derived from a conjugated diene monomer, units derived from an acidic monomer, and units derived from a hard, non-acidic monomer, an external crosslinking agent, and optionally one or more of a leveling agent, surfactant, polyurethane, alkali-soluble resin, coalescing agent, plasticizer, and wax.Type: ApplicationFiled: January 31, 2012Publication date: May 24, 2012Inventors: Kyung Don KIM, James Gaston, II
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Publication number: 20120130002Abstract: The present invention provides high solids, two-component polyurethane compositions comprising, as one component, polyisocyanate compositions having one or more isocyanurate made from bis(isocyanatomethyl)-cyclohexane, as a second component, one or more high solids polyol, and in either component, one or more tertiary amine catalyst. Optionally, the compositions further comprise one or more zinc amine catalyst. The compositions provide coatings, which exhibit an excellent balance of pot life and dry to touch or tack free time, as well as early rain resistance and hardness, while enabling a lower volatile organic content (VOC) of the compositions for comparable performance.Type: ApplicationFiled: November 16, 2011Publication date: May 24, 2012Inventors: Donald C. Schall, Jia Tang
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Publication number: 20120123043Abstract: To provide a hot melt adhesive composition employing a thermoplastic polyurethane, which has a high adhesive strength even under bonding conditions of low temperature and short time or even to nylon cloth, and which has a favorable adhesive strength in a wide temperature range of from room temperature to low temperature. A hot melt adhesive composition comprising a thermoplastic polyurethane (A) having a flow initiation temperature of from 80 to 150° C. and a phenolic hydroxy group-containing compound (B) having phenolic hydroxy groups and having a molecular weight of at least 1,000.Type: ApplicationFiled: January 24, 2012Publication date: May 17, 2012Applicant: Asahi Glass Company, LimitedInventors: Makito NAKAMURA, Genichirou Enna
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Publication number: 20120107619Abstract: This invention relates to an aqueous coating composition comprising an acrylic or polyester resin (A); a curing agent (B); and a blocked isocyanate group-containing urethane resin emulsion (C) having a weight average molecular weight of 2,000 to 50,000, which is prepared using a polyisocyanate component and a polyol component as starting materials, the polyisocyanate component comprising an alicyclic diisocyanate, and the polyol component comprising a polycarbonate diol in an amount of 50 mass % or more, based on the total amount of the polyol component; (i) when the component (A) is an acrylic resin, the aqueous coating composition comprising the component (C) in an amount of, as solids content, 20 to 60 mass %, based on the total solids content of the components (A), (B) and (C); and (ii) when the component (A) is a polyester resin, the aqueous coating composition comprising the component (C) in an amount of, as solids content, 10 to 50 mass %, based on the total solids content of the components (A), (B) anType: ApplicationFiled: July 1, 2010Publication date: May 3, 2012Applicant: KANSAI PAINT CO., LTD.Inventors: Hiroshi Kitagawa, Munehiro Nakata, Daisuke Takayama, Tatsuya Azuma, Kazuaki Kitazono, Keiji Sugamoto
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Publication number: 20120107618Abstract: Low-gloss, two-component clear coats include a base resin including a urethane resin, an isocyanate resin that combines with the base resin immediately prior to application of the low-gloss, two-component clear coat to form a two-component base resin mixture, wherein the two-component base resin mixture comprises from about 20 weight percent to about 40 weight percent urethane resin and from about 20 weight percent to about 40 weight percent isocyanate resin, and a silica-based flattener, wherein the silica-based flattener comprises from about 5 parts by weight per 100 parts by weight of the two-component base resin mixture to about 20 parts by weight per 100 parts by weight of the two-component base resin mixture, wherein the low-gloss, two-component clear coat has a 60° gloss finish from 22 gloss units to 34 gloss units when cured.Type: ApplicationFiled: November 3, 2010Publication date: May 3, 2012Applicants: Toyota Motor Engineering & Manufacturing North America, Inc., Kansai Paint Company, Ltd., PPG Industries, Inc.Inventors: Yuko Nagata Gidcumb, Scott Dale Kubish, Richard E. Raabe
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Publication number: 20120100394Abstract: Coating compositions comprising (a.1) at least one binder with functional groups (Gr); (a.2) at least one pigment; and (a.3) at least one corrosion-inhibiting component which comprises a parent structure (GK), at least one functional group (Gr?) which is attached covalently to (GK) and which, when a multicoat paint system containing the disclosed coating composition is thermally cured, reacts with at least one of functional groups (Gr) of the binder (a.1) or functional groups (Gr?) of at least one constituent of an adjacent coating (B), and at least one uni- and/or multidentate, potentially anionic ligand (L) which is different from the functional group (Gr?), is attached covalently to (GK), and, when the multicoat paint system is thermally cured, does not lose its capacity as a chelating agent. Also disclosed is a process for producing a multicoat paint system using the disclosed coating composition.Type: ApplicationFiled: January 14, 2010Publication date: April 26, 2012Applicant: BASF COATINGS GMBHInventors: Michael Richert, Wolfgang Duschek, Michael Dornbusch
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Publication number: 20120101210Abstract: The invention relates to novel aqueous two-component coating agents based on hydroxy and/or amino-functional water-dilutable resins and nanoparticle-modified isocyanate-functional curing agents, to a method for the production thereof, and to the use thereof in paints, coatings, and sealants, particularly for corrosion protection applications.Type: ApplicationFiled: March 23, 2010Publication date: April 26, 2012Applicant: Bayer MaterialScience AGInventors: Arno Nennemann, Oliver Pyrlik, Hans-Josef Laas, Carmen Imöhl, Robert Maleika
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Publication number: 20120095152Abstract: The invention relates a mixture of a urethane-aldehyde resin UA prepared by condensation of an aldehyde A1 and an alkyl urethane U, and of a novolak PA, to a process for the preparation of the said mixture, and a method of use thereof as adhesion promoter in rubber goods.Type: ApplicationFiled: May 19, 2010Publication date: April 19, 2012Applicant: Cytec Surface Specialties Germany GmbHInventors: Ralph Schäfer, Peter Ziegler
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INK FOR INK JET RECORDING, INK JET RECORDING DEVICE, IMAGE FORMING METHOD, AND IMAGE RECORDED MEDIUM
Publication number: 20120092411Abstract: Ink for ink jet recording containing a coloring agent, water, an aqueous organic solvent, and a polyacrylic acid ester-based polymer represented by the following chemical structure 1: where R represents a hydrogen atom and a methyl group, X— represents F—, Cl—, and Br—, M+ represents Na+, K+, NH4+, and Li+, and symbols l, m, n, and p independently represent integers of from 10 to 3,000.Type: ApplicationFiled: October 11, 2011Publication date: April 19, 2012Applicant: RICOH COMPANY, LTD.Inventors: Minoru HAKIRI, Mitsuru Naruse, Naoya Morohoshi -
Patent number: 8158697Abstract: An ink composition includes a polyurethane resin and at least one selected from a metal compound and hollow resin particles as a colorant, and in the ink composition described above, the polyurethane resin is a polycarbonate-based or a polyether-based anionic polyurethane resin.Type: GrantFiled: July 27, 2009Date of Patent: April 17, 2012Assignee: Seiko Epson CorporationInventors: Takayoshi Kagata, Tsuyoshi Sano
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Plastic mixtures comprising thermoplastic polyurethane (TPU) and impact-resistant poly(meth)acrylate
Patent number: 8158709Abstract: The present invention relates to a plastics mixture comprising at least one thermoplastic polyurethane A) and at least one impact-modified poly(meth)acrylate B), where the impact-modified poly(meth)acrylate comprises a hard phase whose glass transition temperature is at least 70° C. and a tough phase whose glass transition temperature is at most ?10° C., the average particle size of the tough phase is at most 130 nm, and at least a portion of the tough phase has covalent linkage to the hard phase.Type: GrantFiled: February 27, 2009Date of Patent: April 17, 2012Assignee: Evonik Roehm GmbHInventors: Uwe Numrich, Peter Battenhausen, Guenther Dickhaut, Claude Guenanten -
Patent number: 8151848Abstract: A tire includes at least one outer structural element, wherein the at least one outer structural element is at least partially coated by at least one colored coating layer including a colored composition including (a) 5% by weight to 50% by weight with respect to the total weight of the dry colored composition, of at least one crosslinked polymeric compound obtained by reacting (a1) at least one thermoplastic polyurethane with (a2) at least one polyisocyanate; (b) 10% by weight to 80% by weight with respect to the total weight of the dry colored composition, of at least one thermoplastic polymeric compound having a glass transition temperature higher than or equal to 20° C., and (c) 3% by weight to 50% by weight, with respect to the total weight of the dry colored composition, of at least one coloring agent. Preferably, the at least one structural element is at least one of the tire sidewalls.Type: GrantFiled: December 21, 2005Date of Patent: April 10, 2012Assignee: Pirelli Tyre S.p.A.Inventors: Fabio Negroni, Mauro Paolo Soatto, Paolo Massimino
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Publication number: 20120083566Abstract: Ink composition comprising an liquid vehicle, a colorant system, fluoropolymer particles and polyurethane binders wherein the polyurethane binders has a percentage of hard segment which is below 49 percent.Type: ApplicationFiled: June 18, 2009Publication date: April 5, 2012Inventors: Jason Lazarus Deiner, Sergiy Peleshanko, Lane A. Gregg
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Publication number: 20120070571Abstract: Coating composition comprising a liquid first phase comprising one or more polymer binder components having functional groups capable of cross-linking by electron pair exchange, and a second phase which is a powder material, such as sand, comprising one or more compounds capable of activating crosslinking of the binder components in the liquid phase after the second phase is exposed to the first phase. The activating compound in the second phase may include a Lewis acid or Lewis base. Method of applying a coating composition curable by cross-linking chemistry based on electron pair exchange, wherein after application of a layer of the coating composition on a substrate, a powder material comprising one or more cross-linking activating compounds is sprinkled over the wet layer. After sprinkling the powder material over the coating layer, a second coating layer is applied.Type: ApplicationFiled: September 23, 2011Publication date: March 22, 2012Applicant: AKZO NOBEL COATINGS INTERNATIONAL B.V.Inventor: Franciscus Hubertus Maria STAPPERS
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Patent number: 8138258Abstract: An automotive clear coating composition includes a hydroxyl group-containing acrylic resin obtained using hydroxyalkyl(meth)acrylate having a hydroxyalkyl group having 4-9 carbon atoms as at least a part of its monomer; and a polyfunctional isocyanate compound in which at least a part thereof is an isocyanurate type isocyanate compound. The prepared composition has 25 to 50 mass % of a soft segment part with respect to a total solid content of such acrylic resin and the polyfunctional isocyanate compound, and a ratio of a soft segment part derived from a lactone-containing monomer with respect to the total solid content of such acrylic resin and the polyfunctional isocyanate compound of not more than 4.5 mass %. A cured coating film has a dynamic glass transition temperature within a range of 30 to 60° C. The soft segment part is represented by —CH2)n— wherein n represents an integer of 4 or more.Type: GrantFiled: December 22, 2005Date of Patent: March 20, 2012Assignees: Nippon Paint Co., Ltd., Toyota Jidosha Kabushiki KaishaInventors: Hideaki Tsujioka, Junji Shimada, Hisaki Tanabe, Mirei Kato, Yoshinori Narita