With Solid Polymer Derived From At Least One -n=c=x (x Is Chalcogen) Reactant Wherein At Least One Of The Reactants Forming The Solid Polymer Is Saturated; Or With Spfi Or Sicp Derived From A -n=c=x Reactant Wherein At Least One Of The Necessary Reactants Is Saturated Patents (Class 524/507)
  • Patent number: 5792806
    Abstract: An aqueous coating composition which includes, as essential components thereof, (A) an acrylic resin emulsion, (B) a urethane resin emulsion, (C) a crosslinking agent and (D) an acidic phosphate or phosphite ester.
    Type: Grant
    Filed: September 12, 1996
    Date of Patent: August 11, 1998
    Assignee: Kansai Paint Company, Limited
    Inventors: Yoshinori Yamamoto, Tuguo Nezu, Yoshinori Kato
  • Patent number: 5783632
    Abstract: The present invention is a two-component coating composition comprising an acrylic polymer having a T.sub.g between 53.degree. C. and 86.degree. C. and a diisocyanate crosslinker. The crosslinking agent is preferably the isocyanurate of hexamethylene diisocyanate, derivatives thereof, biurets of the isocyanurate of hexamethylene diisocyanate and derivatives thereof. The coating composition exhibits excellent durability and resistance to environmental etch.
    Type: Grant
    Filed: September 13, 1996
    Date of Patent: July 21, 1998
    Assignee: BASF Corporation
    Inventor: Faith S. Loney-Crawford
  • Patent number: 5770647
    Abstract: A friction sound-preventing surface-treating agent is composed of an acryl-vinyl chloride based paint resin, and 2-60 wt % of spherical and/or non-spherical polyurethane particles having an average particle diameter of 1-50 .mu.m as a solid component relative to said acryl-vinyl chloride based paint resin.
    Type: Grant
    Filed: September 12, 1997
    Date of Patent: June 23, 1998
    Assignees: Nissan Motor Co., Ltd., Tokushu Shikiryo Color & Chemicals, Inc.
    Inventors: Tetsuro Watanabe, Kimihiro Matsumoto, Satoru Ichikawa, Kuniko Matsuya
  • Patent number: 5767187
    Abstract: Provided is an aqueous-dispersible, self-crosslinkable interpenetrating polymer network composition which comprises an aqueous-dispersible, isocyanate-based thermoplastic polymer containing urethane and/or urea linkage and an interpenetrating polymer containing latent reactive functionality, whereby the two polymers are at least partially entangled with each other on a molecular level. Also provided are aqueous dispersions of such self-crosslinkable interpenetrating polymer networks, methods of producing such aqueous dispersions, coating compositions therefrom and coated substrates and films obtained from it.
    Type: Grant
    Filed: May 16, 1995
    Date of Patent: June 16, 1998
    Assignee: Cytec Technology Corp.
    Inventor: Howard Robert Lucas
  • Patent number: 5767188
    Abstract: Water-based primer composition made up of (A) a water-compatibilised modified polyolefin type resin, which is a modified polyolefin resin modified with an .alpha.,.beta.-unsaturated carboxylic acid, of a saponification value of 10-60 mg KOH/g, a number average molecular mass of 4000-30,000 and a degree of chlorination of 0-30 wt %, water-compatibilised by means of an amine compound, and if necessary additionally by a surfactant, (B) a water-compatibilised acrylic resin of a glass transition temperature of -50.degree. to 20.degree. C., and (C) a water-compatibilised polyurethane resin of a break elongation of 200-600%, and if necessary an additional curing agent, in which the contents of the different components are (A) 25-70 wt %, the sum of (B) and (C) 30-75 wt %, and the ratio by weight of (B)/(C) 100/0-50/50.
    Type: Grant
    Filed: January 19, 1996
    Date of Patent: June 16, 1998
    Assignee: BASF Lacke +Farben, AG
    Inventors: Joshimasa Kamikuri, Ulrich Hermann, Kazuyoshi Furuuchi, Toshihiko Nakamishi
  • Patent number: 5763011
    Abstract: A urethane-resin based coating for reducing friction includes a urethane paint and a first powder. The coating is to be applied to a shaped article which is to be subjected to a heat treatment at a certain temperature after the application of the coating to the shaped article. The first powder has a melting point lower than the certain temperature and a solubility parameter which is smaller than or larger than that of the urethane paint by at least 0.5. The coating optionally further includes a second powder which has a melting point higher than the certain temperature. The coating provides the shaped article with low friction, irrespective of the coating film's thickness.
    Type: Grant
    Filed: January 23, 1996
    Date of Patent: June 9, 1998
    Assignee: Kinugawa Rubber Ind. Co., Ltd.
    Inventors: Masayoshi Miyama, Naoaki Hoshino
  • Patent number: 5763529
    Abstract: Provided is an aqueous-dispersible, self-crosslinkable interpenetrating polymer network composition which comprises an aqueous-dispersible, isocyanate-based thermoplastic polymer containing urethane and/or urea linkage and an interpenetrating polymer containing latent reactive functionality, whereby the two polymers are at least partially entangled with each other on a molecular level. Also provided are aqueous dispersions of such self-crosslinkable interpenetrating polymer networks, methods of producing such aqueous dispersions, coating compositions therefrom and coated substrates and films obtained from it.
    Type: Grant
    Filed: March 31, 1994
    Date of Patent: June 9, 1998
    Assignee: Cytec Technology Corp.
    Inventor: Howard Robert Lucas
  • Patent number: 5759666
    Abstract: The invention provides novel macromonomer and carboxyl functional polyurethanes having a high carboxyl content. The invention further provides dispersions, coatings and magnetic recording media comprising these polyurethanes, or blends or copolymers of these polyurethanes with quaternary ammonium compounds. The invention further provides novel dispersions, coatings and magnetic recording media comprising combinations of carboxyl functional polyurethanes having a high carboxyl content with quaternary ammonium polymers.
    Type: Grant
    Filed: December 21, 1995
    Date of Patent: June 2, 1998
    Assignee: Minnesota Mining and Manufacturing Company
    Inventors: James G. Carlson, Nelson T. Rotto, Jeffrey T. Anderson, Carol-Lynn Spawn, Albena V. Blagev
  • Patent number: 5759631
    Abstract: Coating composition comprising(A) at least one hydroxyl group-containing polyacrylate resin obtained by polymerizing(a) from 5 to 80% by weight of a cycloaliphatic ester of methacrylic acid and/or acrylic acid, or a mixture of such monomers,(b) from 10 to 50% by weight of a hydroxyl group-containing alkyl ester of methacrylic acid and/or acrylic acid, or mixtures of such monomers,(c) from 0 to 25% by weight of a hydroxyl group-containing, ethylenically unsaturated monomer, different from (a) and (b), or a mixture of such monomers,(d) from 5 to 80% by weight of an aliphatic ester of methacrylic and/or acrylic acid, different from (a)-(c), or a mixture of such monomers,(e) from 0 to 40% by weight of an aromatic vinyl hydrocarbon, different from (a)-(d), or a mixture of such monomers, and(f) from 0 to 40% by weight of an additional ethylenically unsaturated monomer, different from (a)-(e), or a mixture of such monomers,and(B) at least one crosslinking agent.
    Type: Grant
    Filed: September 3, 1996
    Date of Patent: June 2, 1998
    Assignee: BASF Lacke+Farben AG
    Inventors: Heinz-Peter Rink, Michael Brunnemann
  • Patent number: 5759369
    Abstract: An electrophoresis separation medium is disclosed comprising a matrix of a copolymer composed of a linear hydrophilic polymer segment having a selected substantially uniform segment length and hydrophobic polymer segments carried on each end. Also disclosed is an electrophoresis method employing the separation medium which permits high resolution separation of polynucleotides, especially in DNA sequencing operations.
    Type: Grant
    Filed: March 24, 1995
    Date of Patent: June 2, 1998
    Assignee: The Perkin-Elmer Corporation
    Inventors: Steven Michael Menchen, Mitchell A. Winnik, Ben F. Johnson
  • Patent number: 5753740
    Abstract: The present invention relates to a water-based coating composition suited for surface treatment of the metal sheets or plates to be used in building materials, household electric appliances, automobiles and so forth. The object of the present invention is to provide a water-based coating composition for the steel or metal coated steel surface treatment which gives coating films firmly adhering to metal plates and showing a high degree of hardening as well as excellent corrosion resistance, water resistance and weldability upon baking under low-temperature short-period conditions, has electric conductivity suited for electrodeposition coating and provides lubricating property in processing to thereby prevent powdering during processing as well as a method of forming coating films using said composition.
    Type: Grant
    Filed: June 4, 1996
    Date of Patent: May 19, 1998
    Assignee: Nippon Paint Co., Ltd.
    Inventors: Taketoshi Odawa, Toshihiro Okai
  • Patent number: 5750613
    Abstract: This invention relates to aqueous, crosslinkable binder dispersions which have a low solvent content and contain hydroxy-functional polyethers, hydroxy-functional acrylate copolymers and hydroxy- and carboxy-functional acrylate copolymers, to a process for the production of these binders, to one and two-component binder compositions containing these binders and to the use of the binder compositions in coating compositions.
    Type: Grant
    Filed: July 30, 1996
    Date of Patent: May 12, 1998
    Assignee: Bayer Aktiengesellschaft
    Inventors: Harald Blum, Armin Sickert, Wieland Hovestadt
  • Patent number: 5747166
    Abstract: The invention relates to aqueous coatings comprising(A) a water-thinable polyacrylate resin and(B) a blocked polyisocyanate or a mixture of blocked polyisocyanates,wherein the water-thinable polyacrylate resin (A) has a hydroxyl number of 60 to 180, an acid number of 10 to 100, and a glass transition temperature (Tg) of -40.degree. C. to +60.degree. C.
    Type: Grant
    Filed: May 14, 1996
    Date of Patent: May 5, 1998
    Assignee: BASF Corporation
    Inventors: Stephan Schwarte, Horst Grosch
  • Patent number: 5744518
    Abstract: Compositions and methods for improving the characteristics of foundry cores which includes adding to the foundry aggregate mixture one or more biphenyl compounds.
    Type: Grant
    Filed: July 31, 1995
    Date of Patent: April 28, 1998
    Assignee: Borden Chemical, Inc.
    Inventor: Michael M. Geoffrey
  • Patent number: 5744542
    Abstract: An aqueous two-component polyisocyanate coating composition is based on an essentially isocyanate-free emulsifier that comprises the reaction product of:(i) an isocyanate and(ii) a member selected from the group consisting of: hydroxy functional polyalkyl ethers containing at least five ethylene oxide, alcohols different from said polyalkyl ethers, amine compounds, and combinations thereof. The hydroxy functional polyalkyl ether is provided in a quantity sufficient to react at least one equivalent of isocyanate groups in polyisocyanate (i), and the total amounts of reactants (ii) are sufficient to react all of the isocyanate groups of the polyisocyanate (i).
    Type: Grant
    Filed: November 6, 1996
    Date of Patent: April 28, 1998
    Assignee: PPG Industries, Inc.
    Inventors: Jonathan T. Martz, Joseph M. Carney, Robert E. Jennings, Karen D. Donnelly
  • Patent number: 5744534
    Abstract: A light scattering material is prepared by mixing with and dispersing in a transparent elastomer matrix particles of a transparent material. The matrix has a Tg of lower than room temperature and the transparent material has a different index of refraction form the matrix.
    Type: Grant
    Filed: April 12, 1996
    Date of Patent: April 28, 1998
    Assignee: Bridgestone Corporation
    Inventors: Minoru Ishiharada, Itsuo Tanuma, Kazuo Naito
  • Patent number: 5741828
    Abstract: The present invention is directed to a coating composition which includes a component A and component B. Component A is either an emulsion or dispersion having a hydrophobic elastomer stabilized with at lease one emulsifier. Component B is a dispersion or solution of a hydrophilic polymer which is insoluble in water, swellable in water and soluble in one or more water-miscible solvents. The hydrophobic elastomers may be polymers or copolymers of butadiene, isoprene, chloroprene, styrene, acrylonitrile, ethylene, propylene, isobutylene, alkylacrylates and alkylmethacrylates; polyrethanes, polyureas, polysiloxanes, elastomeric polyamides and polyesters. The hydrophilic polymers may be segmented polyurethanes, segmented polyures, segmented polyesters, partially hydrolyzed poly(vinyl acetate), partially hydrolyzed polyacrylonitrile, partially aminolyzed polyacrylonitrile, and ethylene glycol monomethacrylate.
    Type: Grant
    Filed: April 19, 1996
    Date of Patent: April 21, 1998
    Assignee: S.K.Y. Polymers, Inc.
    Inventors: Vladimir A. Stoy, Gerald A. Gontarz, Jr.
  • Patent number: 5741843
    Abstract: Disclosed are sealant compositions having excellent slump and spew resistant, even at relatively high operating temperatures for electrical connectors. The sealants, which are flowable at such elevated temperatures, comprise two essential components: elastomeric thermoplastic polymer, preferably an organic polymer composite comprising diblock and triblock copolymers, and extender for the polymer. The extender may comprise a primary and a secondary extender, such as polybutene oil and mineral oil, respectively.
    Type: Grant
    Filed: May 31, 1995
    Date of Patent: April 21, 1998
    Assignee: The Whitaker Corporation
    Inventors: Francis Frederick Koblitz, Thomas John Lynch, Ricky Charles Mellinger
  • Patent number: 5741845
    Abstract: The invention concerns a process for the production of block copolymers or aqueous dispersions and emulsions thereof, whereby azo macroinitiators are reacted with radical-polymerizable monomers or a mixture of several radical-polymerizable monomers. The azo macroinitiators are obtained by reacting simple reactive azo compounds with prepolymers with a molecular weight between 400 and 20000, which possess at least 2 functional groups, e.g. polyurethanes or polyesters.The aqueous block copolymer dispersions and emulsions produced according to the invention are suitable for use for the production of paints, adhesives etc.
    Type: Grant
    Filed: June 7, 1995
    Date of Patent: April 21, 1998
    Assignee: Dainippon Ink & Chemicals Inc.
    Inventors: Rainer B. Frings, Shigeru Komazaki, Gerwald F. Grahe
  • Patent number: 5741847
    Abstract: A polymer polyol is produced by a process comprising free radical polymerizing an addition polymerizable di-(substituted phenyl)monomer (e.g., methacrylic ester of diglycidylether of tetrabromobisphenol A) component in the presence of a polyol, wherein the monomer has at least one aromatic halogen and at least one aromatic ethylenically unsaturated substituent. The polymer polyol can also be made by copolymerizing said monomer with an additional ethylenically unsaturated monomer component such as styrene and acrylonitrile. Said polymer polyols are reacted with a polyisocyanate compound forming a flame retardant polyurethane foam.
    Type: Grant
    Filed: May 23, 1996
    Date of Patent: April 21, 1998
    Assignee: The Dow Chemical Company
    Inventors: Wayne R. Willkomm, Ruben Solis, Kenneth J. Hinze
  • Patent number: 5739194
    Abstract: Aqueous dispersions of urethane polymers and vinyl polymers (e.g., acrylics) are disclosed that provide water-based coating compositions with good adhesion following humidity exposure. The dispersion is predominately urethane, and the polyurethane is made from a first and a second polyisocyanate, the first polyisocyanate having at least one open carbon chain greater than six carbon atoms in length between two isocyanate groups, preferably at least eight carbon atoms in length. The vinyl monomers are polymerized in the presence of the aqueously dispersed polyurethane.
    Type: Grant
    Filed: June 24, 1996
    Date of Patent: April 14, 1998
    Assignee: PPG Industries, Inc.
    Inventors: Anbazhagan Natesh, Shanti Swarup, Mary Ellen Rosenberger, Mary Eifert, Karl F. Schimmel, John W. Burgman
  • Patent number: 5733538
    Abstract: A hemocompatible surface-modifying additive is provided for modifying polyurethane or polyurethane urea substrates. The additive has a polyurethane or polyurethane urea hard block or an alternative block which is miscible with the poly(urethane) or poly(urethane-urea) base polymer, a polysiloxane hydrophobic soft block, an optional hydrophilic spacer and a peptide selected from the group consisting of Arg-Gly-Asp, X-Arg-Gly-Asp, Arg-Gly-Asp-X and X-Arg-Gly-Asp-X', wherein X and X' are amino acids.
    Type: Grant
    Filed: June 7, 1995
    Date of Patent: March 31, 1998
    Assignee: Thoratec Laboratories, Inc.
    Inventor: Judy S. Riffle
  • Patent number: 5725789
    Abstract: Oil and water repellent compositions for the treatment of fiber containing substrates such as fabric and the like, substrates treated with these compositions and methods for the treatment of substrates are described. The compositions of the invention comprise (a) a polyalkoxylated polyurethane and (b) a fluorochemical acrylate polymer comprising the polymerized reaction product of a fluorinated acrylate or methacrylate monomer, at least one alkyl acrylate or methacrylate monomer and a polymerizable cationic emulsifier comprising a quaternary amine surfactant. Additionally, (c) a polyalkylene glycol fluorochemical acrylate copolymer and (d) a fluorochemical adipate ester can also be included within the compositions. The above components are blended together within the composition at a weight ratios of (a):(b), or (a)+(c):(b), or (a)+(c)+(d):(b) of from 19:1 to 1:19 and preferably about 1:1.
    Type: Grant
    Filed: November 13, 1996
    Date of Patent: March 10, 1998
    Assignee: Minnesota Mining and Manufacturing Company
    Inventors: Charles D. Huber, Michael A. Yandrasits
  • Patent number: 5723544
    Abstract: A thermoplastic molding composition is disclosed comprising (i) a thermoplastic polyurethane resin and (ii) an ionomer. The ionomer is a salt of a copolymer, having a weight average molecular weight of 1,000 to 200,000, of 70 to 99 percent olefin and about 1 to 30 percent of alpha, beta-ethylenically unsaturated carboxylic acid. At least some of said carboxylic acid is neutralized by a monovalent counter-ion. The composition is characterized by its improved processability.
    Type: Grant
    Filed: January 3, 1997
    Date of Patent: March 3, 1998
    Assignee: Bayer Corporation
    Inventor: Bin Lee
  • Patent number: 5723534
    Abstract: A two part polyurethane adhesive system and method of using the adhesive to bond polyurethane foams, polystyrene foams, and other substrates. The first part of the adhesive system is a hydrophilic polyurethane prepolymer prepared by reacting a high molecular weight, multi-functional polyol which has been copolymerized randomly from propylene oxide and ethylene oxide, with a diisocyanate or polyisocyanate. This reaction mixture is then diluted with either a flame retardant, a plasticizer, a solvent which is not considered a volatile organic compound, or a combination of these chemicals. The second part of the adhesive system is an aqueous phase curing agent. In addition to water, the components of the aqueous phase may include a tackifying agent or a catalyst or both.
    Type: Grant
    Filed: October 11, 1996
    Date of Patent: March 3, 1998
    Assignee: Polyfoam Products, Inc.
    Inventor: Pat L. Murray
  • Patent number: 5712003
    Abstract: Provided is a blow-molded article which can be readily formed with good Gloss and with substantially no surface unevenness, even without application of surface coating, and which can be used as a finished product without further treatment. The blow-molded article has a base layer and a surface layer. The base layer is formed from a thermoplastic resin material having a melt index (MI) of about 0.05-2.0 and a flexural modulus of 1,470 MPa (15,000 kgf/cm.sup.2) or more. The surface layer is formed from a colored or transparent thermoplastic resin material having an MI of about 1-30 provided that it is higher than that of the base layer, and excellent weather resistance. The thermoplastic resins used to form the base and surface layers should be resins of the same family.
    Type: Grant
    Filed: October 20, 1995
    Date of Patent: January 27, 1998
    Assignee: Toyoda Gosei Co., Ltd.
    Inventors: Kiyoshi Suenaga, Syojirou Miyamoto, Koichi Ogiso
  • Patent number: 5712337
    Abstract: A hardenable composition suitable for flooring and for coating concrete surfaces comprising(a) an acrylic binder comprising a (meth)acrylic ester of the formula ##STR1## where R.sub.1 is C.sub.2-6 alkylene, n is 0-3 and R.sub.2 is a radical of an aromatic or alicyclic dicarboxylic acid ester or a dicyclopentenyl radical, n being 0 only when R.sub.2 is a dicyclopentenyl radical, and(b) a component which is one or both (preferably both) of carbon black and a polyfunctional aliphatic or aromatic polyester- or polyether- urethane oligomer. The composition also preferably comprises aggregate such as sand. The compositions have excellent impact resistance and flexural strength.
    Type: Grant
    Filed: October 30, 1996
    Date of Patent: January 27, 1998
    Assignee: MBT Holding AG
    Inventor: Karoly Discho
  • Patent number: 5709909
    Abstract: Disclosed is a filler paste comprising polyurethane resin, chlorinated polyolefin, filler and/or extender, and organic solvents. The filler paste may also include physically drying binders, pigments, and/or rheological additives. Also disclosed is a basecoat containing the filler paste. The basecoat containing the filler paste may be applied directly to polyolefin substrates. After a flash-off period, a basecoat that does not contain the filler paste may be applied on top of the first basecoat layer. After a flash-off period for the second basecoat layer, a clearcoat may be applied and subsequently the applied layers may be cured together, with heating.
    Type: Grant
    Filed: October 3, 1996
    Date of Patent: January 20, 1998
    Assignee: BASF Lacke & Farben, AG
    Inventors: Frank Leibfarth, Hans Josef Oslowski, Doris Maria Bohm, Andreas Gobel
  • Patent number: 5708074
    Abstract: A process for the preparation of water-dilutable polyvinylbutyral dispersions by (1) reacting an aliphatic acid having from one to three isocyanate-reactive groups and from one to three acid groups, or a mixture of such acids, with one or more polyfunctional isocyanates whose average functionality is at least two, where the quantity of the isocyanate component is chosen such that the ratio of the number of isocyanate groups to the number of isocyanate-reactive groups of the acid component is between 2.2:1 and 1.7:1; (2) then reacting from 25 to 75% of the remaining isocyanate groups with at least one monofunctional compound selected from monoalcohols and monoamines; and (3) reacting this NCO-functional emulsifier resin further with polyvinylbutyral and, if desired, with an appropriate plasticizer resin using a suitable auxiliary solvent. The polyvinylbutyral dispersions prepared in this way can be used as binders and binder components for coatings with good adhesion.
    Type: Grant
    Filed: May 1, 1996
    Date of Patent: January 13, 1998
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Gerhard Merten, Ralph Schaefer, Markus Schafheutle, Martin Gerlitz
  • Patent number: 5708072
    Abstract: A process is disclosed for preparing water-dilutable enamel paint binders based on oligourethane-acrylate copolymers. A specific monomer mixture is polymerized in the presence of a water-insoluble oligourethane obtained by reacting an aliphatic ester diol with a diisocyanate. Water dilutability is achieved by using (meth)acrylic acid. These enamel paint binders are used in combination with cross-linking components and if required other enamel paint binders to formulate baking enamels.
    Type: Grant
    Filed: June 5, 1996
    Date of Patent: January 13, 1998
    Assignee: Vianova Resins Aktiengesellschaft
    Inventors: Laszlo Tulacs, Hans Hiden, Werner Wilfinger, Johann Luttenberger
  • Patent number: 5705557
    Abstract: A one-component aqueous coating system comprising (A) a hydrophilic polyacrylate polyol or polyesterpolyol containing at least one hydroxyl group, (B) a polyisocyanate which is water resistant at room temperature or a blocked polyisocyanate, (C) optionally a pigment or a conventional paint auxiliary, such as an antifoam, a levelling agent, a catalyst or a thixotropic agent, and a further reactive additive component (D), in a quantity of from 2 to 20% by weight, based on the overall solids content of (A), (B) and (D), the additive component (D) being characterized in that it contains at least one reactive OH, NH, NH.sub.2 or SH group and has a functionality of at least 1.5 to 3.0 relative to the crosslinking agent (B), a solubility in water of below 2% by weight and a molecular weight of 500-2000 g/mol.
    Type: Grant
    Filed: December 7, 1995
    Date of Patent: January 6, 1998
    Assignee: Huels Aktiengesellschaft
    Inventors: Hartwig Lange, Martina Ortelt
  • Patent number: 5703158
    Abstract: Sulfonated polyester polyols and mixtures of sulfonated polyester polyols and hydroxy carboxylic acids are used to prepare improved aqueous anionic poly(urethane/urea) dispersions with a high crystallization rate, low heat activation temperature, high green strength, stability at low pH, which show good compatibility with other water based polymers and with crosslinkers. The aqueous anionic poly(urethane/urea) dispersions have high heat resistance after curing or blending with a crosslinker.
    Type: Grant
    Filed: November 22, 1994
    Date of Patent: December 30, 1997
    Assignee: H.B. Fuller Licensing & Financing, Inc.
    Inventors: Youlu Duan, Michael J. Dochniak, Sonja Stammler
  • Patent number: 5700862
    Abstract: An aqueous coating composition comprising: (A) 10 to 95% by weight (based on solid content) of a film forming polymer which is prepared by neutralizing at least a part of acid groups contained in a copolymer having a number average molecular weight ranging from 6,000 to 50,000 prepared by copolymerizing (A1) 5 to 40% by weight of an amide group-containing ethylenically unsaturated monomer, (A2) 3 to 15% by weight of an acid group-containing ethylenically unsaturated monomer, (A3) 10 to 40% by weight of a hydroxyl group-containing ethylenically unsaturated monomer, and (A4) a remainder amount of ethylenically unsaturated monomers other than the monomers (A1) to (A3); and (B) 5 to 90% by weight (based on solid content) of an aqueous dispersion of carboxyl group-containing acrylic resin particles having a particle size ranging from 0.01 to 1.0 .mu.m and an acid value ranging from 20 to 80.
    Type: Grant
    Filed: May 26, 1995
    Date of Patent: December 23, 1997
    Assignee: Nippon Paint Co., Ltd.
    Inventors: Katsuhiko Sho, Yasuhiro Shibata, Keizou Ishii, Tsuyoshi Imamura, Kunihiko Takeuchi
  • Patent number: 5698623
    Abstract: Addition of a polyurethane or polyurea polymer to each part of a particulate filled precursor of a two-part resin stabilizes the filler against settling from suspension, and provides thixotropic response when the precursors are expressed from a container.
    Type: Grant
    Filed: June 12, 1996
    Date of Patent: December 16, 1997
    Inventor: Richard L. Jacobs
  • Patent number: 5693737
    Abstract: The invention relates to a blocked polyisocyanate having an NCO functionality of from 2.2 to 4.5 and an average molecular weight of 800 to 25,000 and containing (1) blocked isocyanate groups corresponding to an NCO content of 5 to 20 wt. % calculated as free NCO, relative to unblocked polyisocyanate, (2) 1 to 75 meq of ionic groups per 100 g of blocked polyisocyanate, and (3) 3 to 40 wt.
    Type: Grant
    Filed: January 19, 1996
    Date of Patent: December 2, 1997
    Assignee: Bayer Aktiengesellschaft
    Inventors: Helmut Reiff, Karl-Heinz Passon, Hans-Albert Ehlert, Peter Nussbaum
  • Patent number: 5693423
    Abstract: A water-based coating composition and methods of making and using the same are disclosed. The composition includes a halogenated resin, a polyol, a surfactant, and an amine. It is suitable for coating a variety of substrates including polyolefinic substrates such as polypropylene, and operates without aromatic organic solvents.
    Type: Grant
    Filed: June 22, 1995
    Date of Patent: December 2, 1997
    Assignee: A-Line Products Corporation
    Inventors: Alger E. Laura, Ronald J. Easton, Kurt C. Frisch, Han X Xiao
  • Patent number: 5693736
    Abstract: Polyurethanes which have olefinic double bonds and a content by mass of ethylene oxide units, incorporated via polyethylene glycol, of from 20 to 80% and which are obtainable by reacting (a) at least one organic polyisocyanate with (b) at least one polybutadiene derivative which is reactive toward isocyanates, and (c) if desired, one or more diols which contain, in addition, at least one further hydroxyl group or carboxyl group, and (d) a polyoxyalkylene glycol component having a molar mass of from 500 to 10,000 g/mol, wherein the ratio of NCO to OH equivalents, based on all the starting components (a) to (d), is from 0.5:1 to 1.2:1. The polyurethanes are useful, for example, as reactive emulsifiers.
    Type: Grant
    Filed: October 26, 1995
    Date of Patent: December 2, 1997
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Joachim Zoeller, Katja Thiergaertner
  • Patent number: 5688356
    Abstract: The present invention is directed to a water-based adhesive composition comprising an admixture of a first aliphatic water-based urethane resin that is the reaction product of polycaprolactonediol or polycaprolactonetriol, 4,4-methylene bis(cyclohexylisocyanate), and dimethylolpropionic acid extended with a diamine, and a second aliphatic water-based urethane resin that is the reaction product of 2,6-hexanediol, 4,4-methylene bis(cyclohexylisocyanate), and dimethylolpropionic acid extended with a diamine. The first aliphatic water-based urethane resin comprises from about 99 to about 20 percent by weight of the composition, and the second aliphatic water-based urethane resin comprises from about 1 to about 80 percent by weight of the composition. The invention is also directed to methods of adhering a substrate and a workpiece using the adhesive composition of the invention.
    Type: Grant
    Filed: November 6, 1996
    Date of Patent: November 18, 1997
    Assignee: Olin Corporation
    Inventor: Efraim Sagiv
  • Patent number: 5684081
    Abstract: The present invention relates to polyester acrylate/urethane dispersions based on polyester acrylate prepolymers containing hydroxyl groups, obtainable by polyaddition ofA. 40-90 wt. % of one or more polyester acrylate prepolymers containing hydroxyl groups and having an OH content of 40-120 mg of KOH/g andB. 0.1-20 wt. % of one or more mono- and/or difunctional compounds reactive towards isocyanate groups, which compounds contain groups which are cationic, artionic and/or have a dispersant action due to ether groups withC. 10-50 wt. % of one or more polyisocyanatesD. 0.0-30 wt. % of polyolstogether with a subsequent reaction withE. 0.1-10 wt. % of one or more di- and/or polyamines.
    Type: Grant
    Filed: July 9, 1996
    Date of Patent: November 4, 1997
    Assignee: Wolff Walsrode AG
    Inventors: Wolfgang Dannhorn, Reinhold Hecht, Lutz Hoppe, Erhard Luhmann
  • Patent number: 5677373
    Abstract: Process for producing a dispersion, wherein dispersed slightly crosslinked polyvinyl seed particles are swollen with an ionizing liquid, said seed particles containing covalently linked ionizable groups causing a swelling of the seed particles by the ionizing liquid to form a dispersion of droplets, wherein the resulting droplets after the swelling have a volume which is at least five times that of the seed particles. Said ionizing liquid may be or contain a polymerizable monomer or be charged with such a monomer. Polymerization of the monomers is effected in the droplets during or after the swelling, to form polymer particles.
    Type: Grant
    Filed: April 22, 1994
    Date of Patent: October 14, 1997
    Assignee: Sinvent A/S
    Inventors: Arvid Berge, Tom-Nils Nilsen, Jon-Olav Bj.o slashed.rgum, John Ugelstad
  • Patent number: 5672673
    Abstract: A method for the preparation of water-soluble polyaddition compounds containing perfluoroalkyl groups by the reaction of a polyisocyanate component A) with a fluorine-containing alcohol component B), hydrophilic monohydric polyether alcohols C), isocyanate-reactive tertiary amines D) and optionally other isocyanate-reactive components E) at an NCO index of 80 to 200, the resulting polyaddition compounds and their use as dispersants for incorporating solid substances into aqueous paints and coating compositions.
    Type: Grant
    Filed: June 17, 1996
    Date of Patent: September 30, 1997
    Assignee: Bayer Aktiengesellschaft
    Inventors: Stephan Kirchmeyer, Jan Mazanek, Karl-Heinz Kasler
  • Patent number: 5672651
    Abstract: This invention provides compositions for treating fibrous substrates to render those substrates durably repellent to water and oil and durably resistant to dry soil comprising a fluorochemical polymer formed by: (a) reacting a tri- or higher order isocyanate with a fluorochemical alcohol; (b) reacting the resulting product with an amount of water sufficient to react with between 5 and 50% of the isocyanate groups present in the product compound; and (c) thereafter reacting the product with a difunctional poly(oxyalkylene)-containing material.
    Type: Grant
    Filed: October 20, 1995
    Date of Patent: September 30, 1997
    Assignee: Minnesota Mining and Manufacturing Company
    Inventor: Richard S. Smith
  • Patent number: 5672649
    Abstract: A process for preparing aqueous coating agents with adjustable optical effects by mixing at least two storage-stable pre-mixed aqueous modules (units) is described, in whichA) at least one aqueous special effect module containing one or more special effect pigments, one or more anionic and/or non-ionic stabilised water-dilutable binders, one or more organic solvents, at least 20 wt. % of water and optionally conventional lacquer additives, andB) at least one aqueous binder module containing one or more anionic and/or non-ionic stabilised water-dilutable binders, water, and optionally one or more organic solvents, one or more cross-linking agents and/or conventional lacquer additives, are mixed together.
    Type: Grant
    Filed: September 4, 1996
    Date of Patent: September 30, 1997
    Assignee: Herberts GmbH
    Inventors: Thomas Brock, Jurgen Dobert
  • Patent number: 5661207
    Abstract: The invention provides novel polyurethanes which can be used in magnetic media binders applications. The polyurethanes comprise multidentate chelating functional groups pendant from the polymer backbone, which groups are produced by esterification of backbone hydroxyl moieties with cyclic dicarboxylic acid anhydrides which also bear an additional polar functional group such as those selected from the group consisting of --H, --OH, --COOM, --SO.sub.3 M, --SH, --CH.sub.2 COOM, --SCH.sub.2 COOM, --P(.dbd.O)(OM).sub.2, --OP(.dbd.O)(OM).sub.2, and the like. Examples of anhydrides useful in preparation of the polyurethanes include anhydrides of citric acid, mercaptosuccinic acid, dimercaptosuccinic acid and nitrilotriacetic acid. The polyurethanes, which are optionally radiation curable, show high affinity for magnetic pigments, and blends of the polyurethanes with vinyl resins afford excellent binders for magnetic recording media.
    Type: Grant
    Filed: March 8, 1996
    Date of Patent: August 26, 1997
    Assignee: Minnesota Mining and Manufacturing Company
    Inventors: James G. Carlson, Jack G. Truong, Jeffrey T. Anderson, Nelson T. Rotto
  • Patent number: 5658617
    Abstract: A method of manufacturing aqueous dipsersion of polyurethane resins free from urea groups and containing ionic groups and suitable for coating agents, with a number average moleculear weight (Mn) of 10,000 to 300,000 and an acid number of 5 to 50, by preparing a polyurethane prepolymer containing OH groups and with an OH number of 5 to 75 and a number average molecular weight (Mn) of 5,000 to 50,000.
    Type: Grant
    Filed: February 5, 1996
    Date of Patent: August 19, 1997
    Assignee: Herberts Gesellschaft mit beschrankter Haftung
    Inventors: Armin Gobel, Hans-Peter Patzschke
  • Patent number: 5654360
    Abstract: The invention provides a water-based coating composition in two pack form comprising:i) in a first pack a substantially non-aqueous solution of a silicon-containing polymer which is soluble in water miscible organic solvents and essentially soluble in aqueous media, the silicon groups on the polymer being of formula (1):--SiR.sup.1.sub.a R.sub.3-a (1)in which a is 0 to 2, R.sup.1 is Cl-6 alkyl and R is OH or a hydrolysable group, andii) in a second pack a polymer in dispersion in an aqueous liquid carrier for the composition,where the non-volatile binder solids content of the composition is at least 5% by weight and the molar concentration of silicon in the composition is greater than 0 and less than 0.5.
    Type: Grant
    Filed: December 14, 1995
    Date of Patent: August 5, 1997
    Assignee: Imperial Chemical Industries PLC
    Inventor: Peter David Palasz
  • Patent number: 5652294
    Abstract: Disclosed are aqueous, single-component coating compositions that contain as the primary binder component a polyurea which is the reaction product of:(a) a polymeric component containing at least one polymer based on olefinically unsaturated compounds and containing isocyanate-reactive groups comprising primary amino groups and/or secondary amino groups, with the optional additional presence of hydroxyl groups; and(b) a polyisocyanate component containing polyisocyanate groups in amounts sufficient to provide an NCO/NH equivalent ratio of about 0.5:1 to 1:1.
    Type: Grant
    Filed: December 21, 1995
    Date of Patent: July 29, 1997
    Assignee: PPG Industries, Inc.
    Inventors: Robert E. Jennings, Soner Kilic, Masayuki Nakajima
  • Patent number: 5652299
    Abstract: A water-based vacuum forming laminating adhesive includes an ionic water-dispersed polyurethane, a carbodiimide and/or an aziridine, and optionally a vinyl acetate polymer. The polyurethane is characterized by a high polydispersity index, which provides a combination of adhesion and thermal stability. The polyurethane is made by chain extending an isocyanate functional urethane prepolymer with polyamine and ketimine.
    Type: Grant
    Filed: September 20, 1996
    Date of Patent: July 29, 1997
    Assignee: PPG Industries, Inc.
    Inventors: Masayuki Nakajima, Richard L. Coalson, Kurt G. Olson, Umesh C. Desai
  • Patent number: 5652300
    Abstract: A self-emulsifiable polyisocyanate mixture which is of a non-yellowing type, is not deteriorated in weather resistance, has a high hardness and is quick-drying and which is obtained from a specific, NCO-terminated modified HDI and has introduced thereinto a specific, NCO-terminated modified IPDI or a specific, NCO-terminated modified TDI, and an aqueous coating or adhesive composition comprising the above self-emulsifiable polyisocyanate mixture.
    Type: Grant
    Filed: December 11, 1995
    Date of Patent: July 29, 1997
    Assignee: Nippon Polyurethane Industry Co., Ltd.
    Inventors: Yukihiro Morikawa, Shin Konishi, Kouichi Uehara
  • Patent number: 5650461
    Abstract: The present invention relates to paint compositions which provide a Chemical Agent Resitant Coating (CARC), consisting of one layer topcoat paint system, which imparts an increase in the reflectivity at the thermal infra-red region, while controlling the colour in the visible range and are maintaining a low gloss, comprising: an extender selected from polyolefins and substituted polyolefins; a pigment, selected from a metal oxide calcined at a temperature of above 600.degree. C. and a paste of metal flakes and any mixture thereof; a binder consisting of a modified polyurethane resulted from an isocyanate and a co-reactant possessing at least two hydroxy groups, and a solvent system to dissolve the components in the paint composition.
    Type: Grant
    Filed: September 6, 1995
    Date of Patent: July 22, 1997
    Assignee: State of Israel-Ministry of Defence, Armament Development Authority, RAFAEL
    Inventors: Shulamit Wasserman, Igal E. Klein