With Solid Polymer Derived From At Least One -n=c=x (x Is Chalcogen) Reactant Wherein At Least One Of The Reactants Forming The Solid Polymer Is Saturated; Or With Spfi Or Sicp Derived From A -n=c=x Reactant Wherein At Least One Of The Necessary Reactants Is Saturated Patents (Class 524/507)
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Patent number: 5641829Abstract: A waterborne coating composition contains a base neutralized, stable, aqueous dispersion of a hydroxyl functional acrylic polymer containing less than 1 percent acid, having a number average molecular weight ranging from about 500 to about 4500 and having an acid value of at least about 1.5 and no greater than about 10 is prepared from a vinyl monomer component containing at least about 50 percent 2-hydroxyethyl acrylate and at least one other comonomer. The proportion of each monomer is selected so that the resultant polymer forms stable dispersion in water without externally added surfactant. The coating composition also contains a crosslinking agent adapted to react with the hydroxyl groups of the acrylic polymer.Type: GrantFiled: June 6, 1995Date of Patent: June 24, 1997Assignee: PPG Industries, Inc.Inventors: Suryya K. Das, Soner Kilic
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Patent number: 5639361Abstract: Binder systems suitable for electrodeposition coating and based on basic, thermally crosslinkable epoxy or polyurethane resins as binders (B), containing from 0.001 to 1% by weight of a polymer (I) whose predominant components are ethyl acrylate and/or n-propyl acrylate, based on the overall solids content of the binder system.Type: GrantFiled: October 3, 1995Date of Patent: June 17, 1997Assignee: BASF Lacke + Farben, AGInventors: Klaus Humke, Udo Strauss, Hans Schupp, Thomas Schwerzel, Dieter Faul, Helmut Fobbe
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Patent number: 5637639Abstract: A process for preparing poly(urethane/urea) prepolymers and aqueous poly(urethane/urea) dispersions (PUDs) therefrom, the poly(urethane/urea) polymers having high heat resistance and good water resistance. The method employs a water soluble volatile organic solvent, such as acetone, at a level of 0.1-5%, based on final dispersion weight, a level which does not require removal for purposes of flash point considerations.Type: GrantFiled: September 15, 1995Date of Patent: June 10, 1997Assignee: H.B. Fuller Licensing and Financing, Inc.Inventors: Youlu Duan, Sonja Stammler
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Patent number: 5631341Abstract: A self-emulsifiable polyisocyanate mixture having a hexamethylene diisocyanate monomer content of not more than 1.0% by weight and an average NCO functionality of 2.0 to 3.7 obtained by subjecting hexamethylene diisocyanate to urethanation with a branched dihydric alcohol having overall 4 to 35 carbon atoms, of which 2 to 33 carbon atoms are a total number of the carbon atoms possessed by one or more branches, a hydrophilic surfactant having one or more active hydrogen atoms capable of reacting with NCO group and 3 to 90 alkylene oxide units, an aliphatic compound having one or more active hydrogen atoms capable of reacting with NCO group and 8 or more carbon atoms and an unbranched glycol having 1 to 10 carbon atoms; uretdione-forming reaction; and isocyanurate-forming reaction.Type: GrantFiled: December 11, 1995Date of Patent: May 20, 1997Assignee: Nippon Polyurethane Industry Co., Ltd.Inventors: Takeshi Morishima, Shin Konishi, Shinjiro Hama
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Patent number: 5629372Abstract: A clear coating composition containing about 45-80% by weight of a binder and 20-55% by weight of an organic liquid; wherein the binder contains(A) about 40-90% by weight, based on the weight of the binder, of an acrylic polymer containing polymerized hydroxyl containing monomers of the following group of hydroxy alkyl acrylate or methacrylates having 1-4 carbon atoms in the alkyl group, and polymerized alkyl acrylates and methacrylates having 1-18 carbon atoms in the alkyl groups, or styrene or any mixtures of the above and 0.1-5.0% by weight, based on the weight of the acrylic polymer, of polymerized fluoroalkyl containing monomer represented by the formula ##STR1## where R is hydrogen or an alkyl group having 1-2 carbon atoms, n is an integer of 1-11 and R.sub.Type: GrantFiled: October 16, 1995Date of Patent: May 13, 1997Assignee: E. I. Du Pont de Nemours and CompanyInventors: Douglas R. Anton, Michael J. Darmon, William F. Graham, Richard R. Thomas
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Patent number: 5629046Abstract: A water-based coating composition and methods of making and using the same are disclosed. The composition includes a halogenated resin, a polyol, a surfactant, and an amine. It is suitable for coating a variety of substrates including polyolefinic substrates such as polypropylene, and operates without aromatic organic solvents.Type: GrantFiled: February 7, 1995Date of Patent: May 13, 1997Assignee: A-Line Products CorporationInventors: Alger E. Laura, Ronald J. Easton, Kurt C. Frisch, Han X. Xiao
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Patent number: 5626915Abstract: A water-based coating composition and methods of making and using the same are disclosed. The composition includes a halogenated resin, a polyol, a surfactant, and an amine. It is suitable for coating a variety of substrates including polyolefinic substrates such as polypropylene, and operates without aromatic organic solvents.Type: GrantFiled: February 7, 1995Date of Patent: May 6, 1997Assignee: A-Line Products CorporationInventors: Alger E. Laura, Ronald J. Easton, Kurt C. Frisch, Han X. Xiao
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Patent number: 5620747Abstract: A water-based coating composition and methods of making and using the same are disclosed. The composition includes a halogenated resin, a polyol, a surfactant, and an amine. It is suitable for coating a variety of substrates including polyolefinic substrates such as polypropylene, and operates without aromatic organic solvents.Type: GrantFiled: February 7, 1995Date of Patent: April 15, 1997Assignee: A-Line Products CorporationInventors: Alger E. Laura, Ronald J. Easton, Kurt C. Frisch, Han X Xiao
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Patent number: 5614582Abstract: A resinous composition for water paint crosslinkable at the normal temperature is provided, which is suitable for painting interiors and exteriors of buildings, bridges, vehicles and et al, which is non-odored, as well as which has advantages in safe and hygienic aspects. A resinous composition for a water paint, which is obtained by blending an aqueous dispersion of a carbonyl group-containing copolymer (A) with a carbonyl group-containing aqueous polyurethane resin (B) at the ratio of 100 parts by weight of solids in (A) to 5.about.150 parts by weight of (B), and then adding as a crosslinking agent a hydrazide compound having at least 2 hydrazide groups per one molecule (C) at the ratio of 0.01.about.2 moles of (C) to 1 mole of carbonyl group contained in the said (A) and (B) components, wherein the said polyurethane resin (B) being obtained by copolymerizing an unsaturated polyurethane resin obtained by the reaction of a diisocyanate compound with a polyol having a number average molecular weight of 60.Type: GrantFiled: October 14, 1994Date of Patent: March 25, 1997Assignee: Kansi Paint Co., Ltd.Inventors: Makoto Hori, Reijiro Nishida, Yasuo Takaya, Yasuharu Nakayama, Masami Sugishima
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Patent number: 5612404Abstract: Disclosed are aqueous, single-package or two-package coating compositions having pH above 7.0 that contain as the binder a polyurea which is the product of a polyisocyanate and an anionic amino polymer synthesized in water from olefinically unsaturated monomers including primary or secondary amine containing monomers, the monomers being substantially free of acid groups. The polymerization of the amino polymer is carried out in the presence of an azo initiator dispersed in water by neutralization of acid groups present on the initiator.Type: GrantFiled: December 21, 1995Date of Patent: March 18, 1997Assignee: PPG Industries, Inc.Inventors: Suryya K. Das, Soner Kilic, Robert E. Jennings, James A. Claar
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Patent number: 5612406Abstract: The invention concerns a process for the production of block copolymers or aqueous dispersions and emulsions thereof, whereby azo macroinitiators are reacted with radical-polymerizable monomers or a mixture of several radical-polymerizable monomers. The azo macroinitiators are obtained by reacting simple reactive azo compounds with prepolymers with a molecular weight between 400 and 20000, which possess at least 2 functional groups, e.g. polyurethanes or polyesters.The aqueous block copolymer dispersions and emulsions produced according to the invention are suitable for use for the production of paints, adhesives etc.Type: GrantFiled: April 3, 1996Date of Patent: March 18, 1997Assignee: Dainippon Ink & Chemicals Inc.Inventors: Rainer B. Frings, Shigeru Komazaki, Gerwald F. Grahe
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Patent number: 5610232Abstract: Aqueous dispersion adhesives of anionic polyurethanes which have high heat resistance and low activation temperature, even when employed without addition of a crosslinker. The polyurethane is the reaction product of an isocyanate terminated polyurethane prepolymer, and water. The polyurethane prepolymer is the reaction product of a polyol component and a diisocyanate component, the polyol component including:a sulfonated polyester polyol,a hydroxy carboxylic acid of the formula:(HO).sub.x R(COOH).sub.ywherein (R) represents a straight or branched, hydrocarbon radical containing 1 to 12 carbon atoms, and x and y represent values from 1 to 3, and optionally,a low molecular weight aliphatic diol having a molecular weight of from 60 to 400a non-sulfonated polyol,and the diisocyanate component being selected from the group consisting of aromatic diisocyanates, isopherone diisocyanate, hexamethylene diisocyanate and mixtures thereof.Type: GrantFiled: June 7, 1995Date of Patent: March 11, 1997Assignee: H.B. Fuller Licensing & Financing, Inc.Inventors: Youlu Duan, Sonja Stammler, Scott Rhein, Lowell Lindquist
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Patent number: 5610224Abstract: The present invention relates to ionic and nonionic polyamide modified polyurethane polymers for use in coating compositions, a method for forming the polymer and coating compositions containing these polymers. The polyamide modified polyurethane polymers of the present invention include polyamide formed from aromatic, aliphatic, or cycloaliphatic anhydrides or diacid halides and an amine containing compound such as amino alcohol, amino thiol, diamine or mixtures thereof, wherein the reactive terminii of the polyamide ere substituted by hydroxyl or thiol functional groups, together with a chain extending alcohol and diisocyanate functional monomer.Type: GrantFiled: July 29, 1996Date of Patent: March 11, 1997Assignee: BASF CorporationInventors: Jeffrey S. DePue, Gregory G. Menovcik
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Patent number: 5608000Abstract: Aqueous dispersion adhesives of anionic polyurethanes which have high heat resistance and low activation temperature, even when employed without addition of a crosslinker. The polyurethane is the reaction product of an isocyanate terminated polyurethane prepolymer, and a chain extender. The polyurethane prepolymer is the reaction product of a polyol component and a diisocyanate component, the polyol component including:a sulfonated polyester polyol,a hydroxy carboxylic acid of the formula:(HO).sub.x R(COOH).sub.ywherein (R) represents a straight or branched, hydrocarbon radical containing 1 to 12 carbon atoms, and x and y represent values from 1 to 3, anda low molecular weight aliphatic diol having a molecular weight of from 60 to 400.Type: GrantFiled: September 9, 1994Date of Patent: March 4, 1997Assignee: H. B. Fuller Licensing & Financing, Inc.Inventors: Youlu Duan, Sonja Stammler
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Patent number: 5605721Abstract: The present invention is directed to an underlayment composition for an artificial playing surface comprised of a butadiene rubber, such as polybutadiene or styrene-butadiene that is commercially available as recycled polycord tires that have been granulized. An inorganic-base moisture-retaining agent such as vermiculite or perlite is also included in the composition in addition to a binder comprised of a mixture of isocyanate polyurethane and an inorganic acid. The present invention also provides a method of making the present composition. The method comprises the steps of mixing thoroughly granulized particles of butadiene rubber in a mixing container, mixing an inorganic-based moisture-retaining component with the butadiene rubber, mixing an acid having a pH .ltoreq.3 with the butadiene rubber and the inorganic-based moisture-retaining component, and mixing an isocyanate polyurethane with the butadiene rubber, the inorganic-based moisture-retaining component and the acid.Type: GrantFiled: June 7, 1995Date of Patent: February 25, 1997Inventor: Joseph W. Di Geronimo
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Patent number: 5594065Abstract: An improved two component coating system based upon crosslinkable hydroxy containing polymers and a polyisocyanate crosslinker. The improvement resides in the utilization of a water-borne hydroxy-terminated polyurethane prepolymer/acrylate hybrid, preferably a hydroxy acrylate hybrid, in combination with a water-dispersible polyisocyanate.Type: GrantFiled: May 9, 1995Date of Patent: January 14, 1997Assignee: Air Products and Chemicals, Inc.Inventors: Chao-Fong Tien, Charles R. Hegedus, Thomas M. Santosusso, Jeanine M. Snyder, Lisa A. Mercando
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Patent number: 5594064Abstract: A composition comprising an inorganic filler and binder component containing a glassy polymer and a rubbery polymer is provided. The glassy polymer contacts and encapsulates the filler. The compositions are especially useful in the fabrication of flexible magnetic recording media and abrasive articles.Type: GrantFiled: May 3, 1995Date of Patent: January 14, 1997Assignee: International Business Machines CorporationInventor: Richard L. Bradshaw
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Patent number: 5589535Abstract: An aqueous coating composition containing at least one water-dispersible polyurethane resin containing air-drying groups and optionally further binder resins and conventional paint additives, which polyurethane resin contains structural units derived from(A) polyisocyanates,(B) polyols containing air-drying groups,(C) optionally polyols which are free of air-drying groups,(D) compounds having at least two groups which are reactive with isocyanate groups and at least one group capable of anion formation,(E) optionally monoalcohls containing air-drying groups,(F) and/or compounds which differ from (B), (C), (D) and (E) and contain at least one group which is reactive with NCO groups, which has excellent pigment compatibility and the coatings produced therefrom have good corrosion protection and good mechanical properties even in the absence of siccatives.Type: GrantFiled: May 30, 1995Date of Patent: December 31, 1996Assignee: Hoechst AktiengesellschaftInventors: Michael Schwab, Gerd Walz, Gerhard Merten
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Patent number: 5587421Abstract: A mixture containsa) water-emulsifiable polyisocyanates andb) carbonic esters or lactones as organic solvents.Type: GrantFiled: August 18, 1995Date of Patent: December 24, 1996Assignee: BASF AktiengesellschaftInventors: Peter Weyland, Reinhard Treiber, Alwin Sturm, Horst Seibert, Hans Renz, Jurgen Reichert, Karl Haberle
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Patent number: 5580265Abstract: Disclosed are sealant compositions having excellent slump and spew resistant, even at relatively high operating temperatures for electrical connectors. The sealants, which are flowable at such elevated temperatures, comprise two essential components: elastomeric thermoplastic polymer, preferably an organic polymer composite comprising diblock and triblock copolymers, and extender for the polymer. The extender may comprise a primary and a secondary extender, such as polybutene oil and mineral oil, respectively.Type: GrantFiled: August 29, 1994Date of Patent: December 3, 1996Assignee: The Whitaker CorporationInventors: Francis F. Koblitz, Thomas J. Lynch, Ricky C. Mellinger
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Patent number: 5571857Abstract: A method for preparing an aqueous adhesive polyurethane/acrylic polymer dispersion by reacting a polyol, a carboxylic acid-containing polyol and a polyisocyanate to form an anionic, water dispersible prepolymer, subsequently chain extending to form the polyurethane component of the polyurethane/acrylic polymer and polymerizing at least one acrylic monomer in the presence of the prepolymer and/or polyurethane to form the acrylic polymer component, characterized by using isophorone diisocyanate as the polyisocyanate and performing the chain extension with a composition comprising a monofunctional amine and a difunctional amine in a 1:4 to 4:1 weight ratio.Type: GrantFiled: June 30, 1995Date of Patent: November 5, 1996Assignee: Air Products and Chemicals, Inc.Inventors: Bruce A. Gruber, Richard Derby
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Patent number: 5569685Abstract: Aqueous two-component coating agents contain 7.5 to 25 wt. % of at least one epoxide resin in the form of a dispersion, with respect to the resin solids, 1.5 to 15 wt. % of at least one water-miscible polyamine, 2 to 15 wt. % of at least one chlorinated polyolefin with a degree of chlorination of 15 to 40 wt. %, 0 to less than 5 wt. % of one or more organic solvents, 35 to 85 wt. % of water, and conventional lacquer additives, pigments and fillers. The coating agents are suitable for use in processes for coating plastic substrates, in particular polyolefin substrates.Type: GrantFiled: February 27, 1995Date of Patent: October 29, 1996Assignee: Herberts GmbHInventors: Peter Schreiber, Stefanie Goecke, Reinhard Windmann
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Patent number: 5567762Abstract: Resins based on a copolymerizate reacted with by a polyisocyanate, partially and transitorily blocked in the form of urea by an amino derivative, in which i) the polymerizate is based on styrene, at least two acrylic monomers of formula (I), H.sub.2 C.dbd.C(R)--COOR.sub.1, where R.dbd.hydrogen or methyl, R.sub.1 .dbd.hydrogen, linear or branched C.sub.1 -C.sub.14 alkyl radical, C.sub.1 -C.sub.4 hydroxyalkyl radical, and amongst which at least one of these acrylic monomers possesses a hydroxyl group, and at least one vinyl ester of a C.sub.9 -C.sub.19 trialkylacetic acid, ii) the polyisocyanate is chosen from the group of aliphatic polyisocyanates of formula (II) O.dbd.C.dbd.N--A--N.dbd.C.dbd.O where A represents a linear or branched C.sub.4 -C.sub.10 alkylene group and cyclic aromatic or cyclic aliphatic polyisocyanates and iii) this polyisocyanate is partially and transitorily blocked in the form of urea by a pyrazole group of formula (III) ##STR1## where R.sub.2, R.sub.3 and R.sub.4 .dbd.H or C.sub.1 -C.Type: GrantFiled: March 13, 1995Date of Patent: October 22, 1996Assignee: Societe Francaise HoechstInventors: Henri Coyard, Phillippe Deligny
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Patent number: 5563207Abstract: Water-dispersible polyisocyanate compositions based on aliphatic and aromatic diisocyanates and having an NCO content, based on solids, of 6 to 21% by weight, a weight ratio of incorporated TDI units to incorporated HDI units of 6:1 to 0.1:1 and a content of ethylene oxide units, arranged within terminal polyether chains, of 5 to 40% by weight; a method for the preparation of these polyisocyanate compositions by reacting a polyisocyanate component with monovalent polyether alcohols containing ethylene oxide units at an NCO/OH equivalent ratio of 2:1 to 120:1; and aqueous coating compositions containing these polyisocyanate compositions and polyhydroxyl compounds as the binder.Type: GrantFiled: April 25, 1995Date of Patent: October 8, 1996Assignee: Bayer AktiengesellschaftInventors: Martin Brahm, Wolfgang Kremer, Lutz Schmalstieg, Joachim Probst, Werner Kubitza
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Patent number: 5556912Abstract: Improved aqueous binder dispersions including polyurethanes and water-based physically drying coating compositions containing these aqueous dispersions which are particularly suitable for plain and metallic colored base coats employed for automotive repair lacquer coatings.Type: GrantFiled: December 21, 1994Date of Patent: September 17, 1996Assignee: Herberts GmbHInventors: Thomas Brock, Klaus Wandelmaier
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Patent number: 5552228Abstract: The invention provides a waterborne coating composition comprising an emulsion having a continuous aqueous phase and a dispersed organic phase comprising a solution of water-reducible, film-forming, air-drying maleinized polybutadiene polymer in a water-immiscible hydrocarbon solvent; and a method of making the waterborne coating composition which comprises dissolving the maleinized polybutadiene in the solvent to form a solution, and emulsifying the solution in water with nonionic surfactant to form an oil-in-water emulsion.Type: GrantFiled: September 2, 1994Date of Patent: September 3, 1996Assignee: Minnesota Mining and Manufacturing CompanyInventor: James J. Fong
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Patent number: 5548016Abstract: A primer composition for adhering a topcoat to a flexible plastic substrate includes a blend of acrylic and urethane resins, and pigments dispersed in a water based solvent system. About 10 to about 20 percent of the resins are polyurethene by weight, the balance of the resins consisting essentially of acrylic polymers. The composition consists of from about 15 to 30 percent resins, and from about 20 to about 35 percent pigments by weight, and has a total solids content of from about 35 to about 70 percent. The water based solvent system is primarily water, but contains water-miscible organic components which provide for rapid drying, and good coalescing and film forming properties, while minimizing volatile organic content. The compositions dry rapidly at ambient conditions upon application to flexible plastic substrates to provide a continuous, flexible film which exhibits excellent adhesion with the substrate and with subsequently applied topcoats.Type: GrantFiled: March 31, 1994Date of Patent: August 20, 1996Assignee: Tremco, Inc.Inventor: Robert M. Provenzola
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Patent number: 5541251Abstract: Aqueous selfcrosslinkable resin composition comprising an aqueous dispersion of at least one polyurethane polymer having anionic salt groups as sole chain-pendant functional group and at least one vinyl polymer having chain-pendant acetoacetoxyalkyl ester groups. A selfcrosslinking reaction between the polyurethane polymer and the vinyl polymer will take place during and/or after film formation, resulting in the formation of a polymeric film having properties not found to be those of the non-functional polymer components.Type: GrantFiled: January 12, 1995Date of Patent: July 30, 1996Assignee: U C B S.A.Inventors: Dirk Bontinck, Michel Tielemans, Jean-Marie Loutz, Andr e Vandersmissen, Luc De Koninck
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Patent number: 5541239Abstract: A solid, coherent film of dried varnish formed from liquid suspension varnish composition, the film of dried varnish consisting essentially of a solid coherent film polymer constituent formed by the drying of the liquid component of said suspension varnish composition, and, embedded in said solid coherent film polymer, solid ultraviolet absorbing polymer particles in the amount of from about two or three percent, by weight, or greater, based on the weight of said solid coherent film polymer, and methods and composition for making the same are disclosed.Type: GrantFiled: January 24, 1995Date of Patent: July 30, 1996Inventor: Newell W. Heywood, Jr.
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Patent number: 5538717Abstract: Colored or colorless aqueous nail polish containing particles of polyester-polyurethane which are anionic in dispersion, and in which the particle size is between 2 and 40 nm, and the hardness (as measured using a Persoz' clock) of the film produced after drying for 24 hours at 30.degree. C. and 50% relative humidity from a 300 .mu.m-thick layer of an aqueous dispersion of said particles containing 28% dry matter is between 50 and 300 seconds.Type: GrantFiled: October 14, 1994Date of Patent: July 23, 1996Assignee: L'OrealInventor: Val erie de La Poterie
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Patent number: 5539018Abstract: The present Application relates to a polymer dispersion comprising an aqueous continuous phase and dispersed particles, which consist of a polymerized, water-soluble, urethane-modified allyl ether polyester and polymerized monomers, wherein at least two polymerized monomers A and B together with a water-soluble urethane-modified allyl ether polyester constitute the dispersion particle and are produced according to the core-shell model (multiphase).Type: GrantFiled: February 10, 1995Date of Patent: July 23, 1996Assignee: Wolff Walsrode AktiengesellschaftInventors: Erhard L uhmann, Lutz Hoppe, Wolfgang Dannhorn, Hans-J urgen Juhl
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Patent number: 5534575Abstract: Hot melt adhesives which include at least 5% of a thermoplastic elastomer block copolymer having a Vicat softening temperature of at least 60.degree. C. and a melting point of at least 100.degree. C., have improved thermal resistance properties and can be applied with conventional hot melt application equipment at temperatures of between about 149.degree. C. and about 204.degree. C. The adhesives are particularly suited to use in above-the-belt locations in automobile interiors and in furniture bonding. Especially suitable thermoplastic elastomers are polyether-polyester and polyether-polyamide segmented polymers with melting points above 149.degree. C. Hot melt adhesives based on these thermoplastic elastomers can be formulated to provide a range of properties including pressure sensitive properties and contact adhesive properties.Type: GrantFiled: January 30, 1995Date of Patent: July 9, 1996Assignee: H. B. Fuller Licensing & Financing, Inc.Inventors: Mary E. Foster, Eugene R. Simmons, Lowell G. Lindquist, William L. Bunnelle
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Patent number: 5525669Abstract: Aqueous emulsions which include polyvinyl butyral are prepared by mixing a nonionic emulsifier with polyvinyl butyral and, if desired, with a plasticizer resin and, if desired, with one or more solvents, and adding water under the action of shear forces.Type: GrantFiled: August 8, 1994Date of Patent: June 11, 1996Assignee: Hoechst AktiengesellschaftInventors: Markus A. Schafheutle, Gerhard Merten
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Patent number: 5523328Abstract: Disclosed as one embodiment is a method of producing useful articles from ground whole tire waste, which includes the steps of continuously extruding a heated mixture of ground whole tire waste and thermoplastic binder material into a continuously cooled, open-ended casting chamber. The apparatus for practicing this embodiment includes an extruder, a transition nozzle having an outlet with a cross-section corresponding to the desired cross-section of the useful article, and a casting chamber being constructed and arranged to remove thermal energy from an inner surface of the casting chamber.Type: GrantFiled: May 16, 1994Date of Patent: June 4, 1996Assignee: Renewed Materials Industries, Inc.Inventors: James E. Rosenbaum, Frank R. Keith
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Patent number: 5523344Abstract: Adhesive formulations are blends of aqueous polymer dispersions and a hydrophobic plasticizer. The blended dispersed polymers include at least one hard sulfonated polyester urethane, at least one soft non-sulfonated polyester urethane, and at least one polar non-polyurethane water-based polymer or copolymer. A high molecular weight elastomeric non-sulfonated polyurethane polymer and a crosslinker are optional further components in the blend. The formulations are useful as non-heat activating, one-component adhesives which generate excellent green strength, water and heat resistant bonds.Type: GrantFiled: June 7, 1995Date of Patent: June 4, 1996Assignee: H. B. Fuller Licensing & Financing, Inc.Inventors: Mike Maksymkiw, Gray Haider, Michael Dochniak, Leonard Jannusch, Paul Wade
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Patent number: 5521249Abstract: Copolymers of vinyl aromatic monomers and propoxylated allyl alcohols having an average of 2 or less oxypropylene groups are disclosed. The copolymers, which have hydroxyl numbers of 80-260 mg KOH/g and number average molecular weights from 500-3500, are particularly useful for polyurethanes, alkyd resins and coatings, melamine-based coatings, and unsaturated polyester resins.Type: GrantFiled: April 12, 1995Date of Patent: May 28, 1996Assignee: ARCO Chemical Technology, L.P.Inventor: Shao-Hua Guo
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Patent number: 5521246Abstract: The present invention is directed to improved aqueous dispersions containing polyurethane/vinyl polymers and to a method for making such aqueous polyurethane-vinyl polymer dispersion. The aqueous dispersions comprise a urethane prepolymer having carboxyl functionality therein and a vinyl monomer polymerized therewith. The improvement in these dispersions resides in shelf-stability and self crosslinkability at low temperature with the polyurethanes having the carboxyl functionality in quaternary form and such dispersions containing polymer having pendant epoxide groups. When the aqueous dispersions are cast as a film and the water removed, crosslinking between the carboxyl group and epoxide group occurs.Type: GrantFiled: July 25, 1994Date of Patent: May 28, 1996Assignee: Air Products and Chemicals, Inc.Inventors: Chao-Fong Tien, Chung-Ling Mao, Jeanine M. Snyder, Adalgery Beck
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Patent number: 5514722Abstract: The present invention is directed to an underlayment composition for an artificial playing surface comprised of a butadiene rubber, such as polybutadiene or styrene-butadiene that is commercially available as recycled polycord tires that have been granulized. An inorganic-base moisture-retaining agent such as vermiculite or perlite is also included in the composition in addition to a binder comprised of a mixture of isocyanate polyurethane and an inorganic acid. The present invention also provides a method of making the present composition. The method comprises the steps of mixing thoroughly granulized particles of butadiene rubber in a mixing container, mixing an inorganic-based moisture-retaining component with the butadiene rubber, mixing an acid having a pH.ltoreq.3 with the butadiene rubber and the inorganic-based moisture-retaining component, and mixing an isocyanate polyurethane with the butadiene rubber, the inorganic-based moisture-retaining component and the acid.Type: GrantFiled: August 12, 1994Date of Patent: May 7, 1996Assignee: Presidential Sports Systems, Inc.Inventor: Joseph W. Di Geronimo
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Patent number: 5510054Abstract: Disclosed is a polyurethane elastomer having a density of from about 100 to about 1100 kg/m.sup.3, and an abrasion loss of less than about 300 mg, as determined in accordance with Test Method A of ISO 4649. Such elastomer can be prepared by reacting a urethane-modified polyisocyanate with at least one polyol in the presence of from about 0.1 to about 10 parts per 100 parts by weight of polyol' of a liquid polybutadiene comprising 1,2-butene, 2,3-(trans)butene and 2,3-(cis)butene moieties, wherein the 1,2-butene content is less than about 50 percent, based on total butene content, and the 2,3 (cis)-butene content is greater than the 2,3-(trans)butene content.Type: GrantFiled: June 29, 1995Date of Patent: April 23, 1996Assignee: Dow Italia S.P.A.Inventor: Stefano Mussini
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Patent number: 5508337Abstract: The present invention relates to a powder coating composition having a glass transition temperature of 20.degree. to 80.degree. C. and containing(A) 56 to 86.9% by weight of a polyacrylate polyol component having a hydroxyl number of 30 to 155 and a glass transition temperature of 30.degree. to 120.degree. C.,(B) 0.1 to 9% by weight of a polyester polyol component having a hydroxyl number of 40 to 180 and a glass transition temperature of -40.degree. to 80.degree. C.,(C) 13 to 35% by weight of a polyisocyanate component having a glass transition temperature of -40.degree. to 60.degree. C.Type: GrantFiled: May 5, 1994Date of Patent: April 16, 1996Assignee: Bayer AktiengesellschaftInventors: Christian Wamprecht, Reinhard Halpaap, Hans-Ulrich Meier-Westhues, Wolfgang Schultz
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Patent number: 5508370Abstract: The invention relates to a blocked polyisocyanate having an NCO functionality of from 2.2 to 4.5 and an average molecular weight of 800 to 25,000 and containing (1) blocked isocyanate groups corresponding to an NCO content of 5 to 20 wt. % calculated as free NCO, relative to unblocked polyisocyanate, (2) 1 to 75 meq of ionic groups per 100 g of blocked polyisocyanate, and (3) 3 to 40 wt.Type: GrantFiled: October 12, 1993Date of Patent: April 16, 1996Assignee: Bayer AktiengesellschaftInventors: Helmut Reiff, Karl-Heinz Passon, Hans-Albert Ehlert, Peter Nussbaum
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Patent number: 5500253Abstract: Crosslinkable aqueous-based coating compositions are described which are covalently bonded to a wooden surface to which they are applied. The compositions contain a crosslinkable polymer, a mono and/or polyethylenically unsaturated monomer which can be graft polymerized onto cellulose molecules present in said wooden surface, a water soluble peroxy free radical polymerization catalyst, a source of cations capable of creating free radical sites in said cellulose molecules and, optionally, a crosslinking agent for said crosslinkable polymer. The coating may be air dried under ambient conditions to provide a crosslinked coating which is chemically bonded to the underlying wooden surface.Type: GrantFiled: January 6, 1995Date of Patent: March 19, 1996Assignee: James A. BoltonInventors: Mohan L. Sanduja, Irene Berlina, Carl Horowitz, Paul Thottathil
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Patent number: 5500475Abstract: Provided are thickeners based on an aqueous preparation of nonionic, water-dispersible or water-soluble polyurethanes, to their production and to their use. The nonionic, water-dispersible or water-soluble polyurethanes are obtainable by reaction of polyfunctional isocyanates with polyether polyols, monohydric alcohols and, if desired, polyhydric alcohols, wherein the monohydric alcohols contain at least one other polar group. Also provided is a process for the production of such thickeners. The thickeners are particularly suitable for thickening emulsion paints.Type: GrantFiled: May 10, 1994Date of Patent: March 19, 1996Assignee: Henkel Kommanditgesellschaft auf AktienInventors: Ulrich Eicken, Herbert Fischer, Wolfgang Gress, Rainer Hoefer, Doris Oberkobusch, Ludwig Schieferstein
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Water-soluble polyurethane and use thereof to thicken water-based systems such as water-based paints
Patent number: 5496908Abstract: A water-soluble polyurethane, including a polymer backbone; end groups provided on the ends of the polymer backbone and containing water-soluble oxyethylene groups having a molecular weight ranging from 400 to 15,000, and groups pendant from the polymer backbone and containing hydrocarbon groups having 8-22 carbon atoms, in a number of at least 0.1 per urethane bond. The water-soluble polyurethane has moderate viscosities in aqueous solution and is especially useful as a thickener, for instance, in alkyd- or latex-based paints.Type: GrantFiled: March 16, 1994Date of Patent: March 5, 1996Assignee: Berol Nobel ABInventors: Peter Bostrom, Annelie Askenbom, Eva Gottberg-Klingskog -
Patent number: 5496884Abstract: An adhesive composition containing a polyvinyl alcohol-stabilized butadiene polymer latex and a methylene donor compound. The butadiene polymer latex is prepared by an emulsion polymerization in the presence of polyvinyl alcohol. The adhesive composition may also contain other optional ingredients such as a supplemental polymeric film-forming component, a nitroso compound crosslinker, a maleimide compound crosslinker, a vulcanizing agent, and an acid-scavenging compound. The polyvinyl alcohol-stabilized butadiene polymer latex and methylene donor compound combine to provide a tightly crosslinked, robust film which provides for excellent adhesion and environmental resistance.Type: GrantFiled: November 12, 1993Date of Patent: March 5, 1996Assignee: Lord CorporationInventors: Mark A. Weih, Helmut W. Kucera, Patrick A. Warren, Douglas H. Mowrey
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Patent number: 5494954Abstract: An organic colloidal dispersion of polar polymeric microparticles synthesized directly in a non-aqueous polar medium is disclosed. The dispersion is particularly useful for controlling rheological properties such as sag and metallic flake orientation in coating compositions.Type: GrantFiled: November 21, 1994Date of Patent: February 27, 1996Assignee: PPG Industries, Inc.Inventors: Suryya K. Das, Soner Kilic
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Patent number: 5492961Abstract: The application relates to a binder for water-based coating agents, containing a mixture of a carbonate-containing polyurethane prepared by reacting (A)(i) a polyisocyanate containing no hydrophilic groups, (ii) a high molecular weight organic polyhydroxyl compound containing hydrophilic groups and polyhydroxy carbonates, (iii) a lower molecular weight compound containing at least two isocyanate-reacting groups, and (iv) an ionic compound containing at least one isocyanate-reacting hydrogen atom, with (B)(i) one or more polyurethanes prepared by free radical polymerization of a polyurethane macromonomer, in the presence of (ii) an unsaturated monomer copolymerizable with (i).Type: GrantFiled: November 15, 1994Date of Patent: February 20, 1996Assignee: Herberts Gesellschaft mit beschrankter HaftungInventors: Thomas Brock, Klaus Wandelmaier
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Patent number: 5489643Abstract: Described is a coating composition for the formation of a back coat layer in a magnetic recording medium, which comprises carbon black, a binder and a solvent. The binder is composed of an acrylic-polymer-modified polyurethane resin and a vinyl chloride copolymer having at least one type of terminal groups selected from hydroxyl groups, carboxyl groups or tertiary amino groups.Type: GrantFiled: March 17, 1994Date of Patent: February 6, 1996Assignees: Dainichiseika Color & Chemicals Mfg. Co., Ltd., Ukima Coulor & Chemicals Mfg. Co., Ltd.Inventors: Eiichi Sugawara, Setsuo Hirose, Yoshinori Konno, Masatoshi Nakajima, Toshiaki Higuchi
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Patent number: 5484827Abstract: The invention provides UV-stabilizer concentrates, which, relative to the total weight, consist ofA) 40 to 80 weight-% of at least one thermoplastic polyurethaneB) 10 to 30 weight-% 1,3,5-tri-glycidyl-isocyanurate andC) 10 to 30 weight-% 2-(2-hydroxy-3,5,-di-tert-amyl-phenyl)-2H-benzotriazole and/or 1,6-hexane-di-yl-bis-(3-(3-benzotriazole-N-yl)-4-hydroxy-5-tert-butyl)-phe nyl-propanoate.The invention also discloses a process for their production, and their utilization to stabilize TPU against UV- and thermal-degradation.Type: GrantFiled: September 30, 1994Date of Patent: January 16, 1996Assignee: BASF Elastogran GmbHInventors: Frank Prissok, Friedhelm Lehrich, Gerhard Lehr, Aleksander Glinka, Douglas J. Harrop
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Patent number: 5476718Abstract: A compound water-sealing sealant comprising a non-water-swelling thermoplastic resin (A), preferably a vinyl chloride resin, and a water-swelling resin (C) obtained by kneading together 10 to 97% by weight of the non-water-swelling thermoplastic resin (A) and 3 to 90% by weight of a water-swelling material (B). The compound water-sealing sealant is molded by the conjoint extrusion molding of the non-water-swelling thermoplastic resin (A) and the water-swelling resin (C). The water-swelling material (B) is a water-swelling urethane resin which is a prepolymer having isocyanate groups in which the content of terminal NCO groups amounts to 1 to 12%, preferably 2 to 7%, obtained by the reaction of polyisocyanate with at least one polyether polyol of the formulaR[(OR.sub.1)n OH]pwherein R is a polyhydric alcohol residue;(OR.sub.Type: GrantFiled: February 9, 1995Date of Patent: December 19, 1995Assignees: Asahi Denka Kogyo Kabushiki Kaisha, Riken Vinyl Industry Co., Ltd.Inventors: Isamu Ichizuka, Shuitsu Takahashi, Kouzi Hara, Hiroshi Waki, Shinji Kobe, Tadayuki Sakurada, Yoshitaka Okouchi, Ken Ohkubo, Hiroshi Shimizu