With Solid Polymer Derived From At Least One -n=c=x (x Is Chalcogen) Reactant Wherein At Least One Of The Reactants Forming The Solid Polymer Is Saturated; Or With Spfi Or Sicp Derived From A -n=c=x Reactant Wherein At Least One Of The Necessary Reactants Is Saturated Patents (Class 524/507)
  • Patent number: 5641829
    Abstract: A waterborne coating composition contains a base neutralized, stable, aqueous dispersion of a hydroxyl functional acrylic polymer containing less than 1 percent acid, having a number average molecular weight ranging from about 500 to about 4500 and having an acid value of at least about 1.5 and no greater than about 10 is prepared from a vinyl monomer component containing at least about 50 percent 2-hydroxyethyl acrylate and at least one other comonomer. The proportion of each monomer is selected so that the resultant polymer forms stable dispersion in water without externally added surfactant. The coating composition also contains a crosslinking agent adapted to react with the hydroxyl groups of the acrylic polymer.
    Type: Grant
    Filed: June 6, 1995
    Date of Patent: June 24, 1997
    Assignee: PPG Industries, Inc.
    Inventors: Suryya K. Das, Soner Kilic
  • Patent number: 5639361
    Abstract: Binder systems suitable for electrodeposition coating and based on basic, thermally crosslinkable epoxy or polyurethane resins as binders (B), containing from 0.001 to 1% by weight of a polymer (I) whose predominant components are ethyl acrylate and/or n-propyl acrylate, based on the overall solids content of the binder system.
    Type: Grant
    Filed: October 3, 1995
    Date of Patent: June 17, 1997
    Assignee: BASF Lacke + Farben, AG
    Inventors: Klaus Humke, Udo Strauss, Hans Schupp, Thomas Schwerzel, Dieter Faul, Helmut Fobbe
  • Patent number: 5637639
    Abstract: A process for preparing poly(urethane/urea) prepolymers and aqueous poly(urethane/urea) dispersions (PUDs) therefrom, the poly(urethane/urea) polymers having high heat resistance and good water resistance. The method employs a water soluble volatile organic solvent, such as acetone, at a level of 0.1-5%, based on final dispersion weight, a level which does not require removal for purposes of flash point considerations.
    Type: Grant
    Filed: September 15, 1995
    Date of Patent: June 10, 1997
    Assignee: H.B. Fuller Licensing and Financing, Inc.
    Inventors: Youlu Duan, Sonja Stammler
  • Patent number: 5631341
    Abstract: A self-emulsifiable polyisocyanate mixture having a hexamethylene diisocyanate monomer content of not more than 1.0% by weight and an average NCO functionality of 2.0 to 3.7 obtained by subjecting hexamethylene diisocyanate to urethanation with a branched dihydric alcohol having overall 4 to 35 carbon atoms, of which 2 to 33 carbon atoms are a total number of the carbon atoms possessed by one or more branches, a hydrophilic surfactant having one or more active hydrogen atoms capable of reacting with NCO group and 3 to 90 alkylene oxide units, an aliphatic compound having one or more active hydrogen atoms capable of reacting with NCO group and 8 or more carbon atoms and an unbranched glycol having 1 to 10 carbon atoms; uretdione-forming reaction; and isocyanurate-forming reaction.
    Type: Grant
    Filed: December 11, 1995
    Date of Patent: May 20, 1997
    Assignee: Nippon Polyurethane Industry Co., Ltd.
    Inventors: Takeshi Morishima, Shin Konishi, Shinjiro Hama
  • Patent number: 5629372
    Abstract: A clear coating composition containing about 45-80% by weight of a binder and 20-55% by weight of an organic liquid; wherein the binder contains(A) about 40-90% by weight, based on the weight of the binder, of an acrylic polymer containing polymerized hydroxyl containing monomers of the following group of hydroxy alkyl acrylate or methacrylates having 1-4 carbon atoms in the alkyl group, and polymerized alkyl acrylates and methacrylates having 1-18 carbon atoms in the alkyl groups, or styrene or any mixtures of the above and 0.1-5.0% by weight, based on the weight of the acrylic polymer, of polymerized fluoroalkyl containing monomer represented by the formula ##STR1## where R is hydrogen or an alkyl group having 1-2 carbon atoms, n is an integer of 1-11 and R.sub.
    Type: Grant
    Filed: October 16, 1995
    Date of Patent: May 13, 1997
    Assignee: E. I. Du Pont de Nemours and Company
    Inventors: Douglas R. Anton, Michael J. Darmon, William F. Graham, Richard R. Thomas
  • Patent number: 5629046
    Abstract: A water-based coating composition and methods of making and using the same are disclosed. The composition includes a halogenated resin, a polyol, a surfactant, and an amine. It is suitable for coating a variety of substrates including polyolefinic substrates such as polypropylene, and operates without aromatic organic solvents.
    Type: Grant
    Filed: February 7, 1995
    Date of Patent: May 13, 1997
    Assignee: A-Line Products Corporation
    Inventors: Alger E. Laura, Ronald J. Easton, Kurt C. Frisch, Han X. Xiao
  • Patent number: 5626915
    Abstract: A water-based coating composition and methods of making and using the same are disclosed. The composition includes a halogenated resin, a polyol, a surfactant, and an amine. It is suitable for coating a variety of substrates including polyolefinic substrates such as polypropylene, and operates without aromatic organic solvents.
    Type: Grant
    Filed: February 7, 1995
    Date of Patent: May 6, 1997
    Assignee: A-Line Products Corporation
    Inventors: Alger E. Laura, Ronald J. Easton, Kurt C. Frisch, Han X. Xiao
  • Patent number: 5620747
    Abstract: A water-based coating composition and methods of making and using the same are disclosed. The composition includes a halogenated resin, a polyol, a surfactant, and an amine. It is suitable for coating a variety of substrates including polyolefinic substrates such as polypropylene, and operates without aromatic organic solvents.
    Type: Grant
    Filed: February 7, 1995
    Date of Patent: April 15, 1997
    Assignee: A-Line Products Corporation
    Inventors: Alger E. Laura, Ronald J. Easton, Kurt C. Frisch, Han X Xiao
  • Patent number: 5614582
    Abstract: A resinous composition for water paint crosslinkable at the normal temperature is provided, which is suitable for painting interiors and exteriors of buildings, bridges, vehicles and et al, which is non-odored, as well as which has advantages in safe and hygienic aspects. A resinous composition for a water paint, which is obtained by blending an aqueous dispersion of a carbonyl group-containing copolymer (A) with a carbonyl group-containing aqueous polyurethane resin (B) at the ratio of 100 parts by weight of solids in (A) to 5.about.150 parts by weight of (B), and then adding as a crosslinking agent a hydrazide compound having at least 2 hydrazide groups per one molecule (C) at the ratio of 0.01.about.2 moles of (C) to 1 mole of carbonyl group contained in the said (A) and (B) components, wherein the said polyurethane resin (B) being obtained by copolymerizing an unsaturated polyurethane resin obtained by the reaction of a diisocyanate compound with a polyol having a number average molecular weight of 60.
    Type: Grant
    Filed: October 14, 1994
    Date of Patent: March 25, 1997
    Assignee: Kansi Paint Co., Ltd.
    Inventors: Makoto Hori, Reijiro Nishida, Yasuo Takaya, Yasuharu Nakayama, Masami Sugishima
  • Patent number: 5612404
    Abstract: Disclosed are aqueous, single-package or two-package coating compositions having pH above 7.0 that contain as the binder a polyurea which is the product of a polyisocyanate and an anionic amino polymer synthesized in water from olefinically unsaturated monomers including primary or secondary amine containing monomers, the monomers being substantially free of acid groups. The polymerization of the amino polymer is carried out in the presence of an azo initiator dispersed in water by neutralization of acid groups present on the initiator.
    Type: Grant
    Filed: December 21, 1995
    Date of Patent: March 18, 1997
    Assignee: PPG Industries, Inc.
    Inventors: Suryya K. Das, Soner Kilic, Robert E. Jennings, James A. Claar
  • Patent number: 5612406
    Abstract: The invention concerns a process for the production of block copolymers or aqueous dispersions and emulsions thereof, whereby azo macroinitiators are reacted with radical-polymerizable monomers or a mixture of several radical-polymerizable monomers. The azo macroinitiators are obtained by reacting simple reactive azo compounds with prepolymers with a molecular weight between 400 and 20000, which possess at least 2 functional groups, e.g. polyurethanes or polyesters.The aqueous block copolymer dispersions and emulsions produced according to the invention are suitable for use for the production of paints, adhesives etc.
    Type: Grant
    Filed: April 3, 1996
    Date of Patent: March 18, 1997
    Assignee: Dainippon Ink & Chemicals Inc.
    Inventors: Rainer B. Frings, Shigeru Komazaki, Gerwald F. Grahe
  • Patent number: 5610232
    Abstract: Aqueous dispersion adhesives of anionic polyurethanes which have high heat resistance and low activation temperature, even when employed without addition of a crosslinker. The polyurethane is the reaction product of an isocyanate terminated polyurethane prepolymer, and water. The polyurethane prepolymer is the reaction product of a polyol component and a diisocyanate component, the polyol component including:a sulfonated polyester polyol,a hydroxy carboxylic acid of the formula:(HO).sub.x R(COOH).sub.ywherein (R) represents a straight or branched, hydrocarbon radical containing 1 to 12 carbon atoms, and x and y represent values from 1 to 3, and optionally,a low molecular weight aliphatic diol having a molecular weight of from 60 to 400a non-sulfonated polyol,and the diisocyanate component being selected from the group consisting of aromatic diisocyanates, isopherone diisocyanate, hexamethylene diisocyanate and mixtures thereof.
    Type: Grant
    Filed: June 7, 1995
    Date of Patent: March 11, 1997
    Assignee: H.B. Fuller Licensing & Financing, Inc.
    Inventors: Youlu Duan, Sonja Stammler, Scott Rhein, Lowell Lindquist
  • Patent number: 5610224
    Abstract: The present invention relates to ionic and nonionic polyamide modified polyurethane polymers for use in coating compositions, a method for forming the polymer and coating compositions containing these polymers. The polyamide modified polyurethane polymers of the present invention include polyamide formed from aromatic, aliphatic, or cycloaliphatic anhydrides or diacid halides and an amine containing compound such as amino alcohol, amino thiol, diamine or mixtures thereof, wherein the reactive terminii of the polyamide ere substituted by hydroxyl or thiol functional groups, together with a chain extending alcohol and diisocyanate functional monomer.
    Type: Grant
    Filed: July 29, 1996
    Date of Patent: March 11, 1997
    Assignee: BASF Corporation
    Inventors: Jeffrey S. DePue, Gregory G. Menovcik
  • Patent number: 5608000
    Abstract: Aqueous dispersion adhesives of anionic polyurethanes which have high heat resistance and low activation temperature, even when employed without addition of a crosslinker. The polyurethane is the reaction product of an isocyanate terminated polyurethane prepolymer, and a chain extender. The polyurethane prepolymer is the reaction product of a polyol component and a diisocyanate component, the polyol component including:a sulfonated polyester polyol,a hydroxy carboxylic acid of the formula:(HO).sub.x R(COOH).sub.ywherein (R) represents a straight or branched, hydrocarbon radical containing 1 to 12 carbon atoms, and x and y represent values from 1 to 3, anda low molecular weight aliphatic diol having a molecular weight of from 60 to 400.
    Type: Grant
    Filed: September 9, 1994
    Date of Patent: March 4, 1997
    Assignee: H. B. Fuller Licensing & Financing, Inc.
    Inventors: Youlu Duan, Sonja Stammler
  • Patent number: 5605721
    Abstract: The present invention is directed to an underlayment composition for an artificial playing surface comprised of a butadiene rubber, such as polybutadiene or styrene-butadiene that is commercially available as recycled polycord tires that have been granulized. An inorganic-base moisture-retaining agent such as vermiculite or perlite is also included in the composition in addition to a binder comprised of a mixture of isocyanate polyurethane and an inorganic acid. The present invention also provides a method of making the present composition. The method comprises the steps of mixing thoroughly granulized particles of butadiene rubber in a mixing container, mixing an inorganic-based moisture-retaining component with the butadiene rubber, mixing an acid having a pH .ltoreq.3 with the butadiene rubber and the inorganic-based moisture-retaining component, and mixing an isocyanate polyurethane with the butadiene rubber, the inorganic-based moisture-retaining component and the acid.
    Type: Grant
    Filed: June 7, 1995
    Date of Patent: February 25, 1997
    Inventor: Joseph W. Di Geronimo
  • Patent number: 5594065
    Abstract: An improved two component coating system based upon crosslinkable hydroxy containing polymers and a polyisocyanate crosslinker. The improvement resides in the utilization of a water-borne hydroxy-terminated polyurethane prepolymer/acrylate hybrid, preferably a hydroxy acrylate hybrid, in combination with a water-dispersible polyisocyanate.
    Type: Grant
    Filed: May 9, 1995
    Date of Patent: January 14, 1997
    Assignee: Air Products and Chemicals, Inc.
    Inventors: Chao-Fong Tien, Charles R. Hegedus, Thomas M. Santosusso, Jeanine M. Snyder, Lisa A. Mercando
  • Patent number: 5594064
    Abstract: A composition comprising an inorganic filler and binder component containing a glassy polymer and a rubbery polymer is provided. The glassy polymer contacts and encapsulates the filler. The compositions are especially useful in the fabrication of flexible magnetic recording media and abrasive articles.
    Type: Grant
    Filed: May 3, 1995
    Date of Patent: January 14, 1997
    Assignee: International Business Machines Corporation
    Inventor: Richard L. Bradshaw
  • Patent number: 5589535
    Abstract: An aqueous coating composition containing at least one water-dispersible polyurethane resin containing air-drying groups and optionally further binder resins and conventional paint additives, which polyurethane resin contains structural units derived from(A) polyisocyanates,(B) polyols containing air-drying groups,(C) optionally polyols which are free of air-drying groups,(D) compounds having at least two groups which are reactive with isocyanate groups and at least one group capable of anion formation,(E) optionally monoalcohls containing air-drying groups,(F) and/or compounds which differ from (B), (C), (D) and (E) and contain at least one group which is reactive with NCO groups, which has excellent pigment compatibility and the coatings produced therefrom have good corrosion protection and good mechanical properties even in the absence of siccatives.
    Type: Grant
    Filed: May 30, 1995
    Date of Patent: December 31, 1996
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Michael Schwab, Gerd Walz, Gerhard Merten
  • Patent number: 5587421
    Abstract: A mixture containsa) water-emulsifiable polyisocyanates andb) carbonic esters or lactones as organic solvents.
    Type: Grant
    Filed: August 18, 1995
    Date of Patent: December 24, 1996
    Assignee: BASF Aktiengesellschaft
    Inventors: Peter Weyland, Reinhard Treiber, Alwin Sturm, Horst Seibert, Hans Renz, Jurgen Reichert, Karl Haberle
  • Patent number: 5580265
    Abstract: Disclosed are sealant compositions having excellent slump and spew resistant, even at relatively high operating temperatures for electrical connectors. The sealants, which are flowable at such elevated temperatures, comprise two essential components: elastomeric thermoplastic polymer, preferably an organic polymer composite comprising diblock and triblock copolymers, and extender for the polymer. The extender may comprise a primary and a secondary extender, such as polybutene oil and mineral oil, respectively.
    Type: Grant
    Filed: August 29, 1994
    Date of Patent: December 3, 1996
    Assignee: The Whitaker Corporation
    Inventors: Francis F. Koblitz, Thomas J. Lynch, Ricky C. Mellinger
  • Patent number: 5571857
    Abstract: A method for preparing an aqueous adhesive polyurethane/acrylic polymer dispersion by reacting a polyol, a carboxylic acid-containing polyol and a polyisocyanate to form an anionic, water dispersible prepolymer, subsequently chain extending to form the polyurethane component of the polyurethane/acrylic polymer and polymerizing at least one acrylic monomer in the presence of the prepolymer and/or polyurethane to form the acrylic polymer component, characterized by using isophorone diisocyanate as the polyisocyanate and performing the chain extension with a composition comprising a monofunctional amine and a difunctional amine in a 1:4 to 4:1 weight ratio.
    Type: Grant
    Filed: June 30, 1995
    Date of Patent: November 5, 1996
    Assignee: Air Products and Chemicals, Inc.
    Inventors: Bruce A. Gruber, Richard Derby
  • Patent number: 5569685
    Abstract: Aqueous two-component coating agents contain 7.5 to 25 wt. % of at least one epoxide resin in the form of a dispersion, with respect to the resin solids, 1.5 to 15 wt. % of at least one water-miscible polyamine, 2 to 15 wt. % of at least one chlorinated polyolefin with a degree of chlorination of 15 to 40 wt. %, 0 to less than 5 wt. % of one or more organic solvents, 35 to 85 wt. % of water, and conventional lacquer additives, pigments and fillers. The coating agents are suitable for use in processes for coating plastic substrates, in particular polyolefin substrates.
    Type: Grant
    Filed: February 27, 1995
    Date of Patent: October 29, 1996
    Assignee: Herberts GmbH
    Inventors: Peter Schreiber, Stefanie Goecke, Reinhard Windmann
  • Patent number: 5567762
    Abstract: Resins based on a copolymerizate reacted with by a polyisocyanate, partially and transitorily blocked in the form of urea by an amino derivative, in which i) the polymerizate is based on styrene, at least two acrylic monomers of formula (I), H.sub.2 C.dbd.C(R)--COOR.sub.1, where R.dbd.hydrogen or methyl, R.sub.1 .dbd.hydrogen, linear or branched C.sub.1 -C.sub.14 alkyl radical, C.sub.1 -C.sub.4 hydroxyalkyl radical, and amongst which at least one of these acrylic monomers possesses a hydroxyl group, and at least one vinyl ester of a C.sub.9 -C.sub.19 trialkylacetic acid, ii) the polyisocyanate is chosen from the group of aliphatic polyisocyanates of formula (II) O.dbd.C.dbd.N--A--N.dbd.C.dbd.O where A represents a linear or branched C.sub.4 -C.sub.10 alkylene group and cyclic aromatic or cyclic aliphatic polyisocyanates and iii) this polyisocyanate is partially and transitorily blocked in the form of urea by a pyrazole group of formula (III) ##STR1## where R.sub.2, R.sub.3 and R.sub.4 .dbd.H or C.sub.1 -C.
    Type: Grant
    Filed: March 13, 1995
    Date of Patent: October 22, 1996
    Assignee: Societe Francaise Hoechst
    Inventors: Henri Coyard, Phillippe Deligny
  • Patent number: 5563207
    Abstract: Water-dispersible polyisocyanate compositions based on aliphatic and aromatic diisocyanates and having an NCO content, based on solids, of 6 to 21% by weight, a weight ratio of incorporated TDI units to incorporated HDI units of 6:1 to 0.1:1 and a content of ethylene oxide units, arranged within terminal polyether chains, of 5 to 40% by weight; a method for the preparation of these polyisocyanate compositions by reacting a polyisocyanate component with monovalent polyether alcohols containing ethylene oxide units at an NCO/OH equivalent ratio of 2:1 to 120:1; and aqueous coating compositions containing these polyisocyanate compositions and polyhydroxyl compounds as the binder.
    Type: Grant
    Filed: April 25, 1995
    Date of Patent: October 8, 1996
    Assignee: Bayer Aktiengesellschaft
    Inventors: Martin Brahm, Wolfgang Kremer, Lutz Schmalstieg, Joachim Probst, Werner Kubitza
  • Patent number: 5556912
    Abstract: Improved aqueous binder dispersions including polyurethanes and water-based physically drying coating compositions containing these aqueous dispersions which are particularly suitable for plain and metallic colored base coats employed for automotive repair lacquer coatings.
    Type: Grant
    Filed: December 21, 1994
    Date of Patent: September 17, 1996
    Assignee: Herberts GmbH
    Inventors: Thomas Brock, Klaus Wandelmaier
  • Patent number: 5552228
    Abstract: The invention provides a waterborne coating composition comprising an emulsion having a continuous aqueous phase and a dispersed organic phase comprising a solution of water-reducible, film-forming, air-drying maleinized polybutadiene polymer in a water-immiscible hydrocarbon solvent; and a method of making the waterborne coating composition which comprises dissolving the maleinized polybutadiene in the solvent to form a solution, and emulsifying the solution in water with nonionic surfactant to form an oil-in-water emulsion.
    Type: Grant
    Filed: September 2, 1994
    Date of Patent: September 3, 1996
    Assignee: Minnesota Mining and Manufacturing Company
    Inventor: James J. Fong
  • Patent number: 5548016
    Abstract: A primer composition for adhering a topcoat to a flexible plastic substrate includes a blend of acrylic and urethane resins, and pigments dispersed in a water based solvent system. About 10 to about 20 percent of the resins are polyurethene by weight, the balance of the resins consisting essentially of acrylic polymers. The composition consists of from about 15 to 30 percent resins, and from about 20 to about 35 percent pigments by weight, and has a total solids content of from about 35 to about 70 percent. The water based solvent system is primarily water, but contains water-miscible organic components which provide for rapid drying, and good coalescing and film forming properties, while minimizing volatile organic content. The compositions dry rapidly at ambient conditions upon application to flexible plastic substrates to provide a continuous, flexible film which exhibits excellent adhesion with the substrate and with subsequently applied topcoats.
    Type: Grant
    Filed: March 31, 1994
    Date of Patent: August 20, 1996
    Assignee: Tremco, Inc.
    Inventor: Robert M. Provenzola
  • Patent number: 5541251
    Abstract: Aqueous selfcrosslinkable resin composition comprising an aqueous dispersion of at least one polyurethane polymer having anionic salt groups as sole chain-pendant functional group and at least one vinyl polymer having chain-pendant acetoacetoxyalkyl ester groups. A selfcrosslinking reaction between the polyurethane polymer and the vinyl polymer will take place during and/or after film formation, resulting in the formation of a polymeric film having properties not found to be those of the non-functional polymer components.
    Type: Grant
    Filed: January 12, 1995
    Date of Patent: July 30, 1996
    Assignee: U C B S.A.
    Inventors: Dirk Bontinck, Michel Tielemans, Jean-Marie Loutz, Andr e Vandersmissen, Luc De Koninck
  • Patent number: 5541239
    Abstract: A solid, coherent film of dried varnish formed from liquid suspension varnish composition, the film of dried varnish consisting essentially of a solid coherent film polymer constituent formed by the drying of the liquid component of said suspension varnish composition, and, embedded in said solid coherent film polymer, solid ultraviolet absorbing polymer particles in the amount of from about two or three percent, by weight, or greater, based on the weight of said solid coherent film polymer, and methods and composition for making the same are disclosed.
    Type: Grant
    Filed: January 24, 1995
    Date of Patent: July 30, 1996
    Inventor: Newell W. Heywood, Jr.
  • Patent number: 5538717
    Abstract: Colored or colorless aqueous nail polish containing particles of polyester-polyurethane which are anionic in dispersion, and in which the particle size is between 2 and 40 nm, and the hardness (as measured using a Persoz' clock) of the film produced after drying for 24 hours at 30.degree. C. and 50% relative humidity from a 300 .mu.m-thick layer of an aqueous dispersion of said particles containing 28% dry matter is between 50 and 300 seconds.
    Type: Grant
    Filed: October 14, 1994
    Date of Patent: July 23, 1996
    Assignee: L'Oreal
    Inventor: Val erie de La Poterie
  • Patent number: 5539018
    Abstract: The present Application relates to a polymer dispersion comprising an aqueous continuous phase and dispersed particles, which consist of a polymerized, water-soluble, urethane-modified allyl ether polyester and polymerized monomers, wherein at least two polymerized monomers A and B together with a water-soluble urethane-modified allyl ether polyester constitute the dispersion particle and are produced according to the core-shell model (multiphase).
    Type: Grant
    Filed: February 10, 1995
    Date of Patent: July 23, 1996
    Assignee: Wolff Walsrode Aktiengesellschaft
    Inventors: Erhard L uhmann, Lutz Hoppe, Wolfgang Dannhorn, Hans-J urgen Juhl
  • Patent number: 5534575
    Abstract: Hot melt adhesives which include at least 5% of a thermoplastic elastomer block copolymer having a Vicat softening temperature of at least 60.degree. C. and a melting point of at least 100.degree. C., have improved thermal resistance properties and can be applied with conventional hot melt application equipment at temperatures of between about 149.degree. C. and about 204.degree. C. The adhesives are particularly suited to use in above-the-belt locations in automobile interiors and in furniture bonding. Especially suitable thermoplastic elastomers are polyether-polyester and polyether-polyamide segmented polymers with melting points above 149.degree. C. Hot melt adhesives based on these thermoplastic elastomers can be formulated to provide a range of properties including pressure sensitive properties and contact adhesive properties.
    Type: Grant
    Filed: January 30, 1995
    Date of Patent: July 9, 1996
    Assignee: H. B. Fuller Licensing & Financing, Inc.
    Inventors: Mary E. Foster, Eugene R. Simmons, Lowell G. Lindquist, William L. Bunnelle
  • Patent number: 5525669
    Abstract: Aqueous emulsions which include polyvinyl butyral are prepared by mixing a nonionic emulsifier with polyvinyl butyral and, if desired, with a plasticizer resin and, if desired, with one or more solvents, and adding water under the action of shear forces.
    Type: Grant
    Filed: August 8, 1994
    Date of Patent: June 11, 1996
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Markus A. Schafheutle, Gerhard Merten
  • Patent number: 5523328
    Abstract: Disclosed as one embodiment is a method of producing useful articles from ground whole tire waste, which includes the steps of continuously extruding a heated mixture of ground whole tire waste and thermoplastic binder material into a continuously cooled, open-ended casting chamber. The apparatus for practicing this embodiment includes an extruder, a transition nozzle having an outlet with a cross-section corresponding to the desired cross-section of the useful article, and a casting chamber being constructed and arranged to remove thermal energy from an inner surface of the casting chamber.
    Type: Grant
    Filed: May 16, 1994
    Date of Patent: June 4, 1996
    Assignee: Renewed Materials Industries, Inc.
    Inventors: James E. Rosenbaum, Frank R. Keith
  • Patent number: 5523344
    Abstract: Adhesive formulations are blends of aqueous polymer dispersions and a hydrophobic plasticizer. The blended dispersed polymers include at least one hard sulfonated polyester urethane, at least one soft non-sulfonated polyester urethane, and at least one polar non-polyurethane water-based polymer or copolymer. A high molecular weight elastomeric non-sulfonated polyurethane polymer and a crosslinker are optional further components in the blend. The formulations are useful as non-heat activating, one-component adhesives which generate excellent green strength, water and heat resistant bonds.
    Type: Grant
    Filed: June 7, 1995
    Date of Patent: June 4, 1996
    Assignee: H. B. Fuller Licensing & Financing, Inc.
    Inventors: Mike Maksymkiw, Gray Haider, Michael Dochniak, Leonard Jannusch, Paul Wade
  • Patent number: 5521249
    Abstract: Copolymers of vinyl aromatic monomers and propoxylated allyl alcohols having an average of 2 or less oxypropylene groups are disclosed. The copolymers, which have hydroxyl numbers of 80-260 mg KOH/g and number average molecular weights from 500-3500, are particularly useful for polyurethanes, alkyd resins and coatings, melamine-based coatings, and unsaturated polyester resins.
    Type: Grant
    Filed: April 12, 1995
    Date of Patent: May 28, 1996
    Assignee: ARCO Chemical Technology, L.P.
    Inventor: Shao-Hua Guo
  • Patent number: 5521246
    Abstract: The present invention is directed to improved aqueous dispersions containing polyurethane/vinyl polymers and to a method for making such aqueous polyurethane-vinyl polymer dispersion. The aqueous dispersions comprise a urethane prepolymer having carboxyl functionality therein and a vinyl monomer polymerized therewith. The improvement in these dispersions resides in shelf-stability and self crosslinkability at low temperature with the polyurethanes having the carboxyl functionality in quaternary form and such dispersions containing polymer having pendant epoxide groups. When the aqueous dispersions are cast as a film and the water removed, crosslinking between the carboxyl group and epoxide group occurs.
    Type: Grant
    Filed: July 25, 1994
    Date of Patent: May 28, 1996
    Assignee: Air Products and Chemicals, Inc.
    Inventors: Chao-Fong Tien, Chung-Ling Mao, Jeanine M. Snyder, Adalgery Beck
  • Patent number: 5514722
    Abstract: The present invention is directed to an underlayment composition for an artificial playing surface comprised of a butadiene rubber, such as polybutadiene or styrene-butadiene that is commercially available as recycled polycord tires that have been granulized. An inorganic-base moisture-retaining agent such as vermiculite or perlite is also included in the composition in addition to a binder comprised of a mixture of isocyanate polyurethane and an inorganic acid. The present invention also provides a method of making the present composition. The method comprises the steps of mixing thoroughly granulized particles of butadiene rubber in a mixing container, mixing an inorganic-based moisture-retaining component with the butadiene rubber, mixing an acid having a pH.ltoreq.3 with the butadiene rubber and the inorganic-based moisture-retaining component, and mixing an isocyanate polyurethane with the butadiene rubber, the inorganic-based moisture-retaining component and the acid.
    Type: Grant
    Filed: August 12, 1994
    Date of Patent: May 7, 1996
    Assignee: Presidential Sports Systems, Inc.
    Inventor: Joseph W. Di Geronimo
  • Patent number: 5510054
    Abstract: Disclosed is a polyurethane elastomer having a density of from about 100 to about 1100 kg/m.sup.3, and an abrasion loss of less than about 300 mg, as determined in accordance with Test Method A of ISO 4649. Such elastomer can be prepared by reacting a urethane-modified polyisocyanate with at least one polyol in the presence of from about 0.1 to about 10 parts per 100 parts by weight of polyol' of a liquid polybutadiene comprising 1,2-butene, 2,3-(trans)butene and 2,3-(cis)butene moieties, wherein the 1,2-butene content is less than about 50 percent, based on total butene content, and the 2,3 (cis)-butene content is greater than the 2,3-(trans)butene content.
    Type: Grant
    Filed: June 29, 1995
    Date of Patent: April 23, 1996
    Assignee: Dow Italia S.P.A.
    Inventor: Stefano Mussini
  • Patent number: 5508337
    Abstract: The present invention relates to a powder coating composition having a glass transition temperature of 20.degree. to 80.degree. C. and containing(A) 56 to 86.9% by weight of a polyacrylate polyol component having a hydroxyl number of 30 to 155 and a glass transition temperature of 30.degree. to 120.degree. C.,(B) 0.1 to 9% by weight of a polyester polyol component having a hydroxyl number of 40 to 180 and a glass transition temperature of -40.degree. to 80.degree. C.,(C) 13 to 35% by weight of a polyisocyanate component having a glass transition temperature of -40.degree. to 60.degree. C.
    Type: Grant
    Filed: May 5, 1994
    Date of Patent: April 16, 1996
    Assignee: Bayer Aktiengesellschaft
    Inventors: Christian Wamprecht, Reinhard Halpaap, Hans-Ulrich Meier-Westhues, Wolfgang Schultz
  • Patent number: 5508370
    Abstract: The invention relates to a blocked polyisocyanate having an NCO functionality of from 2.2 to 4.5 and an average molecular weight of 800 to 25,000 and containing (1) blocked isocyanate groups corresponding to an NCO content of 5 to 20 wt. % calculated as free NCO, relative to unblocked polyisocyanate, (2) 1 to 75 meq of ionic groups per 100 g of blocked polyisocyanate, and (3) 3 to 40 wt.
    Type: Grant
    Filed: October 12, 1993
    Date of Patent: April 16, 1996
    Assignee: Bayer Aktiengesellschaft
    Inventors: Helmut Reiff, Karl-Heinz Passon, Hans-Albert Ehlert, Peter Nussbaum
  • Patent number: 5500253
    Abstract: Crosslinkable aqueous-based coating compositions are described which are covalently bonded to a wooden surface to which they are applied. The compositions contain a crosslinkable polymer, a mono and/or polyethylenically unsaturated monomer which can be graft polymerized onto cellulose molecules present in said wooden surface, a water soluble peroxy free radical polymerization catalyst, a source of cations capable of creating free radical sites in said cellulose molecules and, optionally, a crosslinking agent for said crosslinkable polymer. The coating may be air dried under ambient conditions to provide a crosslinked coating which is chemically bonded to the underlying wooden surface.
    Type: Grant
    Filed: January 6, 1995
    Date of Patent: March 19, 1996
    Assignee: James A. Bolton
    Inventors: Mohan L. Sanduja, Irene Berlina, Carl Horowitz, Paul Thottathil
  • Patent number: 5500475
    Abstract: Provided are thickeners based on an aqueous preparation of nonionic, water-dispersible or water-soluble polyurethanes, to their production and to their use. The nonionic, water-dispersible or water-soluble polyurethanes are obtainable by reaction of polyfunctional isocyanates with polyether polyols, monohydric alcohols and, if desired, polyhydric alcohols, wherein the monohydric alcohols contain at least one other polar group. Also provided is a process for the production of such thickeners. The thickeners are particularly suitable for thickening emulsion paints.
    Type: Grant
    Filed: May 10, 1994
    Date of Patent: March 19, 1996
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventors: Ulrich Eicken, Herbert Fischer, Wolfgang Gress, Rainer Hoefer, Doris Oberkobusch, Ludwig Schieferstein
  • Patent number: 5496908
    Abstract: A water-soluble polyurethane, including a polymer backbone; end groups provided on the ends of the polymer backbone and containing water-soluble oxyethylene groups having a molecular weight ranging from 400 to 15,000, and groups pendant from the polymer backbone and containing hydrocarbon groups having 8-22 carbon atoms, in a number of at least 0.1 per urethane bond. The water-soluble polyurethane has moderate viscosities in aqueous solution and is especially useful as a thickener, for instance, in alkyd- or latex-based paints.
    Type: Grant
    Filed: March 16, 1994
    Date of Patent: March 5, 1996
    Assignee: Berol Nobel AB
    Inventors: Peter Bostrom, Annelie Askenbom, Eva Gottberg-Klingskog
  • Patent number: 5496884
    Abstract: An adhesive composition containing a polyvinyl alcohol-stabilized butadiene polymer latex and a methylene donor compound. The butadiene polymer latex is prepared by an emulsion polymerization in the presence of polyvinyl alcohol. The adhesive composition may also contain other optional ingredients such as a supplemental polymeric film-forming component, a nitroso compound crosslinker, a maleimide compound crosslinker, a vulcanizing agent, and an acid-scavenging compound. The polyvinyl alcohol-stabilized butadiene polymer latex and methylene donor compound combine to provide a tightly crosslinked, robust film which provides for excellent adhesion and environmental resistance.
    Type: Grant
    Filed: November 12, 1993
    Date of Patent: March 5, 1996
    Assignee: Lord Corporation
    Inventors: Mark A. Weih, Helmut W. Kucera, Patrick A. Warren, Douglas H. Mowrey
  • Patent number: 5494954
    Abstract: An organic colloidal dispersion of polar polymeric microparticles synthesized directly in a non-aqueous polar medium is disclosed. The dispersion is particularly useful for controlling rheological properties such as sag and metallic flake orientation in coating compositions.
    Type: Grant
    Filed: November 21, 1994
    Date of Patent: February 27, 1996
    Assignee: PPG Industries, Inc.
    Inventors: Suryya K. Das, Soner Kilic
  • Patent number: 5492961
    Abstract: The application relates to a binder for water-based coating agents, containing a mixture of a carbonate-containing polyurethane prepared by reacting (A)(i) a polyisocyanate containing no hydrophilic groups, (ii) a high molecular weight organic polyhydroxyl compound containing hydrophilic groups and polyhydroxy carbonates, (iii) a lower molecular weight compound containing at least two isocyanate-reacting groups, and (iv) an ionic compound containing at least one isocyanate-reacting hydrogen atom, with (B)(i) one or more polyurethanes prepared by free radical polymerization of a polyurethane macromonomer, in the presence of (ii) an unsaturated monomer copolymerizable with (i).
    Type: Grant
    Filed: November 15, 1994
    Date of Patent: February 20, 1996
    Assignee: Herberts Gesellschaft mit beschrankter Haftung
    Inventors: Thomas Brock, Klaus Wandelmaier
  • Patent number: 5489643
    Abstract: Described is a coating composition for the formation of a back coat layer in a magnetic recording medium, which comprises carbon black, a binder and a solvent. The binder is composed of an acrylic-polymer-modified polyurethane resin and a vinyl chloride copolymer having at least one type of terminal groups selected from hydroxyl groups, carboxyl groups or tertiary amino groups.
    Type: Grant
    Filed: March 17, 1994
    Date of Patent: February 6, 1996
    Assignees: Dainichiseika Color & Chemicals Mfg. Co., Ltd., Ukima Coulor & Chemicals Mfg. Co., Ltd.
    Inventors: Eiichi Sugawara, Setsuo Hirose, Yoshinori Konno, Masatoshi Nakajima, Toshiaki Higuchi
  • Patent number: 5484827
    Abstract: The invention provides UV-stabilizer concentrates, which, relative to the total weight, consist ofA) 40 to 80 weight-% of at least one thermoplastic polyurethaneB) 10 to 30 weight-% 1,3,5-tri-glycidyl-isocyanurate andC) 10 to 30 weight-% 2-(2-hydroxy-3,5,-di-tert-amyl-phenyl)-2H-benzotriazole and/or 1,6-hexane-di-yl-bis-(3-(3-benzotriazole-N-yl)-4-hydroxy-5-tert-butyl)-phe nyl-propanoate.The invention also discloses a process for their production, and their utilization to stabilize TPU against UV- and thermal-degradation.
    Type: Grant
    Filed: September 30, 1994
    Date of Patent: January 16, 1996
    Assignee: BASF Elastogran GmbH
    Inventors: Frank Prissok, Friedhelm Lehrich, Gerhard Lehr, Aleksander Glinka, Douglas J. Harrop
  • Patent number: 5476718
    Abstract: A compound water-sealing sealant comprising a non-water-swelling thermoplastic resin (A), preferably a vinyl chloride resin, and a water-swelling resin (C) obtained by kneading together 10 to 97% by weight of the non-water-swelling thermoplastic resin (A) and 3 to 90% by weight of a water-swelling material (B). The compound water-sealing sealant is molded by the conjoint extrusion molding of the non-water-swelling thermoplastic resin (A) and the water-swelling resin (C). The water-swelling material (B) is a water-swelling urethane resin which is a prepolymer having isocyanate groups in which the content of terminal NCO groups amounts to 1 to 12%, preferably 2 to 7%, obtained by the reaction of polyisocyanate with at least one polyether polyol of the formulaR[(OR.sub.1)n OH]pwherein R is a polyhydric alcohol residue;(OR.sub.
    Type: Grant
    Filed: February 9, 1995
    Date of Patent: December 19, 1995
    Assignees: Asahi Denka Kogyo Kabushiki Kaisha, Riken Vinyl Industry Co., Ltd.
    Inventors: Isamu Ichizuka, Shuitsu Takahashi, Kouzi Hara, Hiroshi Waki, Shinji Kobe, Tadayuki Sakurada, Yoshitaka Okouchi, Ken Ohkubo, Hiroshi Shimizu