Two Or More Solid Polymers Derived From Ethylenic Reactants Only Patents (Class 524/515)
  • Patent number: 8236888
    Abstract: A macromolecule including a polymer and a polyhedral radical chemically bonded to a terminus of the polymer provides numerous processing and performance advantages. Further functionalization of this macromolecule also is described as being advantageous in certain circumstances. Methods of providing, functionalizing, and utilizing the macromolecule also are provided.
    Type: Grant
    Filed: July 27, 2011
    Date of Patent: August 7, 2012
    Inventors: Yuan-Yong Yan, Jason Poulton, Xiaorong Wang, Hao Wang, Michelle A. Cottrell
  • Patent number: 8231761
    Abstract: The present invention relates to the use of a quaternary ammonium complex comprising at least one non-cyclic amide as a modifier for a creping adhesive used on a creping cylinder, e.g., a Yankee dryer.
    Type: Grant
    Filed: April 20, 2011
    Date of Patent: July 31, 2012
    Assignee: Georgia-Pacific Consumer Products LP
    Inventors: Jeffery J. Boettcher, Nancy S. Clungeon, Bruce J. Kokko, Elroy W. Post, Phuong V. Luu, Gary L. Worry, Greg A. Wendt
  • Patent number: 8227550
    Abstract: Filled polyolefin compositions comprising: A) from 15% to 55% by weight of a polypropylene component; B) from 20% to 80% by weight of a filler; C) from 4% to 25% of an elastomeric polymer or polymer composition; wherein the percentages of A), B) and C) are referred to the sum of A) B) and C), and A) is selected from the following compositions: a) a polypropylene composition containing from 20% to 80% by weight of a polypropylene fraction AI) having a Melt Flow Rate L (MFRI) value of 500 g/10 min. or more, and from 20% to 80% by weight of a polypropylene fraction AII) having a Melt Flow Rate L (MFRII) value of from 0.1 to 30 g/10 min., the said percentages of AI) and AII) being referred to the sum of AI) and AII); or b) a polypropylene composition containing from 15% to 72% by weight of a polypropylene fraction AI) having a Melt Flow Rate L (MFRI) value of 500 g/10 min. or more, from 15% to 70% by weight of a polypropylene fraction AII) having a Melt Flow Rate L (MFRII) value of from 0.1 to 30 g/10 min.
    Type: Grant
    Filed: December 12, 2007
    Date of Patent: July 24, 2012
    Assignee: Basell Poliolefine Italia s.r.l.
    Inventors: Enrico Masarati, Enrico Costantini, Marco Consalvi
  • Patent number: 8211978
    Abstract: A moldability modifier capable of improving molding processability, and a polypropylene resin composition using the same suitable for automobile exterior parts are provided. The invention relates to a moldability modifier comprising propylene block copolymer (A) containing from 80 to 98 wt % of a propylene homopolymer portion (A1) and from 2 to 20 wt % of a propylene/ethylene random copolymer portion (A2), wherein the MFR of (A1) is 300 g/10 min or more, the ethylene content of (A2) is from 10 to 70 wt %, the [?] of (A2) is 6.5 dl/g or more, and the MFR as a whole is 40 g/10 min or more; and propylene block copolymer (B) containing from 20 to 79 wt % of a propylene polymer portion (B1) and from 21 to 80 wt % of a propylene/ethylene random copolymer portion (B2), wherein the MFR of (B1) is 20 g/10 min or more, the ethylene content of (B2) is from 20 to 70 wt %, the [?] of (B2) is from 2.5 to 9.0 dl/g, and the MFR as a whole is from 0.1 to 50 g/10 min; and a polypropylene resin composition using the same.
    Type: Grant
    Filed: March 23, 2007
    Date of Patent: July 3, 2012
    Assignee: Japan Polypropylene Corporation
    Inventors: Yukihito Zanka, Yuji Ryosho, Ken Shimizu, Masashi Shimouse, Shigeo Mizukami
  • Patent number: 8193273
    Abstract: A thermoplastic elastomer (TPE) is disclosed which has excellent compression set and adhesion to both polyamide 6 and polyamide 6,6 for use in two-part component polymer structures.
    Type: Grant
    Filed: May 17, 2007
    Date of Patent: June 5, 2012
    Assignee: Polyone Corporation
    Inventors: Charles Page, Dirk von Falkenhayn
  • Publication number: 20120128743
    Abstract: The present invention relates to a method of forming polymer on the surface of polymer particles, the method comprising: (i) providing a dispersion comprising a continuous aqueous phase, a dispersed organic phase comprising one or more ethylenically unsaturated monomers, and a RAFT agent as a stabiliser for said organic phase; (ii) polymerising the one or more ethylenically unsaturated monomers under the control of the RAFT agent to form an aqueous dispersion of seed polymer particles; (iii) crosslinking the seed polymer particles; (iv) swelling the crosslinked seed particles with one or more ethylenically unsaturated monomers to form an aqueous dispersion of monomer swollen crosslinked seed polymer particles; (v) increasing the temperature of the monomer swollen crosslinked seed polymer particles to expel at least some of the monomer therein onto the surface of the particles; and polymerising at least the expelled monomer to form polymer on the surface of the particles.
    Type: Application
    Filed: February 24, 2010
    Publication date: May 24, 2012
    Inventors: Brian Stanley Hawkett, Thi Thuy Binh Pham, Christopher Henry Such
  • Patent number: 8173728
    Abstract: The invention relates to stabilized thermoplastic polymers, in particular polyolefin films. The stabilizing composition contains a tertiary amine with a molecular weight greater than 400 g/mol, a UV-absorber and/or a sterically hindered amine light stabilizer (HALS). Further aspects of the invention are a process for stabilizing thermoplastic polymers and the use of the above composition for stabilizing thermoplastic polymers.
    Type: Grant
    Filed: January 22, 2007
    Date of Patent: May 8, 2012
    Assignee: BASF SE
    Inventors: Cesare Lorenzetti, Michela Bonora, Anna Bassi, Mirko Rossi
  • Patent number: 8158698
    Abstract: The present invention provides a powder coating composition comprising at least one glycidyl-functionalised (meth) acrylic resin, 1 to 30 wt %, the wt % based on the total weight of component A), of at least one hydroxyl-functionalised alkyl acrylate alkyl methacrylate copolymer, and at least one component selected from the group consisting of pigments, fillers, cross-linking agents and/or coating additives different from component B). The powder coating composition of this invention can provide coatings having improved impact resistance, corrosion stability, heat resistance and weather resistance. The powder coating also has good properties including good flow behavior and durability against aggressive substances, such as, inorganic acids.
    Type: Grant
    Filed: July 21, 2010
    Date of Patent: April 17, 2012
    Assignee: E. I. du Pont de Nemours and Company
    Inventors: Frank Niggemann, Mike Schneider, Phu Qui Nguyen
  • Patent number: 8158706
    Abstract: A polypropylene resin composition contains 2 to 15 wt % of a moldability improver (A) and 85 to 98 wt % of a polypropylene resin (B). The moldability improver (A) is formed of propylene block copolymers (A-1) and (A-2). Each of the propylene block copolymers (A-1) and (A-2) has a crystalline propylene polymer component (A-11), (A-21) and a propylene-ethylene random copolymer component (A-12), (A-22). The propylene block copolymer (A-1) is characterized in that the melt flow rate of the crystalline propylene polymer component (A-11) is high, whereas the propylene block copolymer (A-2) is characterized in that the content ratio of the propylene-ethylene random copolymer component (A-22) is high. The polypropylene resin (B) is formed of a propylene-ethylene block copolymer (B-1), at least one of an ethylene elastomer and a styrene elastomer (B-2) and an inorganic filler (B-3).
    Type: Grant
    Filed: February 4, 2011
    Date of Patent: April 17, 2012
    Assignee: Nissan Motor Co., Ltd.
    Inventors: Masashi Shimouse, Yukihito Zanka, Takayuki Sato, Mineyuki Saotome, Sinichi Takaragi
  • Patent number: 8129465
    Abstract: The present invention is directed to a polymeric material, particularly a thermoplastic material, the includes thermoplastic polyolefin and an elastomer.
    Type: Grant
    Filed: November 19, 2010
    Date of Patent: March 6, 2012
    Assignee: Dow Global Technologies LLC
    Inventors: James Thomas Seliskar, James David Oelberg
  • Publication number: 20120053255
    Abstract: Composite polystyrene particles have an average size less than 1200 ?m and methods of making them are provided. The composite polystyrene particles can include recycled polystyrene obtained from a variety of sources. The composite polystyrene particles can be used in a variety of applications, including packaging materials and molded supports for the shipment of fragile objects.
    Type: Application
    Filed: March 2, 2011
    Publication date: March 1, 2012
    Applicant: RAPAC
    Inventors: Dennis W. Koerner, Michael Pate, David Wilson
  • Patent number: 8119726
    Abstract: The flame retardant thermoplastic resin composition according to the present invention comprises (A) about 45 to 95 parts by weight of a polycarbonate resin; (B) about 1 to 50 parts by weight of a rubber modified vinyl graft copolymer; (C) about 0 to 50 parts by weight of a vinyl copolymer; (D) about 1 to 30 parts by weight of a mixture of oligomeric phosphoric acid ester compounds consisting of (d1) about 5 to 99% by weight of an oligomeric phosphoric acid ester compound derived from bisphenol-A and (d2) about 1 to 95% by weight of an oligomeric phosphoric acid ester compound derived from resorcinol, per 100 parts by weight of the sum of (A), (B) and (C); and (E) about 0.05˜5 parts by weight of a fluorinated polyolefin resin, per 100 parts by weight of the sum of (A), (B) and (C).
    Type: Grant
    Filed: December 27, 2004
    Date of Patent: February 21, 2012
    Assignee: Cheil Industries Inc.
    Inventors: Jong Cheol Lim, Tae Gon Kang, Hyuk Jin Jung
  • Publication number: 20120041105
    Abstract: The invention relates to a polymer composition containing 3 to 90% by weight of a copolymer H and 3 to 90% by weight of a copolymer K, the copolymers H and K each having polyether macromonomer structural units and acid monomer structural units, which are present in the copolymers H and K in each case in a molar ratio of 1:20 to 1:1, and at least 20 mol % of all structural units of the copolymer H and at least 25 mol % of all structural units of the copolymer K being present in each case in the form of acid monomer structural units, at least 60 mol % of the polyether macromonomer structural units of the copolymer H being represented by the isoprenol polyether derivative structural units and at least 60 mol % of the polyether macromonomer structural units of the copolymer K being represented by the vinyloxy polyether derivative structural units.
    Type: Application
    Filed: November 25, 2009
    Publication date: February 16, 2012
    Inventors: Mario Vierle, Klaus Lorenz, Silke Flakus, Petra Wagner, Christian Scholz, Barbara Wimmer, Manfred Bichler, Angelika Hartl, Martin Winklbauer
  • Patent number: 8110616
    Abstract: An aqueous inkjet recording ink including at least a resin (A), a pigment (B) dispersed with the resin (A), a resin emulsion (C), and an aqueous liquid medium (D), wherein the resin (A) includes hydrophobic structural units (a) and hydrophilic structural units (b), the hydrophobic structural units (a) include a hydrophobic structural unit (a1) in an amount of 40% by mass or more of the resin (A), the hydrophobic structural unit (a1) having an aromatic ring indirectly linked to an atom for forming the main chain of the resin (A), and a hydrophobic structural unit (a2) in an amount of 15% by mass or more of the resin (A), the hydrophobic structural unit (a2) being derived from a C1 to C4 alkyl acrylate or methacrylate, the hydrophilic structural units (b) include a structural unit (b1) derived from an acrylic acid or a methacrylic acid, and the content of the hydrophilic structural units (b) is 15% by mass or less in the resin (A).
    Type: Grant
    Filed: February 9, 2009
    Date of Patent: February 7, 2012
    Assignee: Fujifilm Corporation
    Inventors: Misato Sasada, Takafumi Hosokawa, Takahiro Kato
  • Patent number: 8106123
    Abstract: Processes for enhancing blown film processability and the blown films formed thereby are described herein. One embodiment of the processes generally includes providing a first propylene based heterophasic copolymer having a first melt flow rate, modifying the first propylene based heterophasic copolymer to form a second heterophasic polymer having a second melt flow rate, wherein the second melt flow rate is greater than the first melt flow rate, contacting the first heterophasic polymer, the second heterophasic copolymer or a combination thereof with a plurality of additives, wherein the plurality of additives include a nucleator, polyethylene and mineral oil to form a modified heterophasic copolymer and blowing the modified heterophasic polymer into a film.
    Type: Grant
    Filed: December 17, 2007
    Date of Patent: January 31, 2012
    Assignee: Fina Technology, Inc.
    Inventors: Rodolfo Mier, Mark Miller
  • Patent number: 8106127
    Abstract: An in-reactor polymer blend comprises (a) a propylene-containing first polymer; and (b) an ethylene-containing second polymer such that the polymer blend comprises between about 50 wt % and about 80 wt % units derived from ethylene and between about 50 wt % and about 20 wt % units derived from propylene. The blend is substantially free of dienes and the content of ethylene in the second polymer in the form of ethylene-ethylene-ethylene triads is at least 40%. The second polymer contains at least 0.1 branch having 8 or more carbon atoms per 10,000 carbons. In addition, the blend has a strain hardening index of at least 1.8, a shear thinning slope in the plot of log(dynamic viscosity) versus log(frequency) of less than ?0.2 and exhibits at least two peaks when subjected to Differential Scanning Calorimetry (first melt) corresponding to a first melting point of at least 150° C. and a second melting point of at least 40° C.
    Type: Grant
    Filed: December 15, 2009
    Date of Patent: January 31, 2012
    Assignee: ExxonMobil Chemical Patents Inc.
    Inventors: Carlos U. De Gracia, Kevin R. Squire, Peijun Jiang, Armenag H. Dekmezian, Beverly J. Poole, Cesar A. Garcia-Franco
  • Publication number: 20120016061
    Abstract: The present invention relates to a process to prepare self-binding pigment particles comprising at least one step a) of grinding one or more binders and one or more mineral materials in an aqueous environment to obtain a suspension, characterised in that, prior to and/or during step a), a copolymer is added in the form of an aqueous solution, said copolymer resulting from the polymerisation of: 2.1) at least one anionic monomer that is an alkene; 2.2) at least one oxyalkylated monomer that is an alkene, wherein the oxyalkyl group has a terminal hydrophobic alkyl, aryl, alkyl aryl or aryl alkyl group having 10 to 32 carbon atoms; 2.3) optionally, at least one other monomer that is an acrylic ester, a preferred acrylic ester being ethyl acrylate, and/or an unsaturated amide, a preferred unsaturated amide being acrylamide, as well as to the products obtained by this process, and uses of these products.
    Type: Application
    Filed: January 11, 2010
    Publication date: January 19, 2012
    Inventors: Patrick A.C. Gane, Philipp Hunziker
  • Patent number: 8084546
    Abstract: A method for varying the transport properties of a film cast from a polymer having at least two polymer end blocks A and at least one polymer interior block B wherein each A block is a polymer block resistant to sulfonation and each B block is a polymer block susceptible to sulfonation, and wherein said A and B blocks do not contain any significant levels of olefinic unsaturation. The method includes casting the polymer using a solvent mixture having two or more solvents selected from the group consisting of polar solvents and non-polar solvents.
    Type: Grant
    Filed: July 1, 2011
    Date of Patent: December 27, 2011
    Assignee: Kraton Polymers U.S. LLC
    Inventors: Carl Lesley Willis, Dale Lee Handlin, Jr., Scott Russell Trenor, Brian Douglas Mather
  • Patent number: 8080607
    Abstract: The present invention is directed to a polymeric material, particularly a thermoplastic material, the includes thermoplastic polyolefin and an elastomer.
    Type: Grant
    Filed: January 11, 2007
    Date of Patent: December 20, 2011
    Assignee: Dow Global Technologies LLC
    Inventors: James Thomas Seliskar, James David Oelberg
  • Patent number: 8076408
    Abstract: A radiation resistant composition includes 100 parts by weight of a polymer, 5 to 80 parts by weight of an aromatic series process oil that a polycyclic aromatic (PCA) extract by an IP 346 method (DMSO extraction) is not more than 3% and an aromatic compound content is not less than 20% by a Kurtz analysis, and a radiation resistance imparting agent. The polymer is cross-linked or vulcanized. A wire or a cable includes an insulation and/or a sheath material including the radiation resistant composition.
    Type: Grant
    Filed: December 21, 2009
    Date of Patent: December 13, 2011
    Assignee: Hitachi Cable, Ltd.
    Inventors: Yoshiaki Nakamura, Masami Sorimachi, Hitoshi Kimura, Shigeki Matsuyama
  • Patent number: 8076407
    Abstract: Hot melt adhesives are provided that have improved heat resistance. The adhesives comprise a metallocene polyolefin, an amorphous ?-olefin polymer, a tackifier and a functional polyolefin. The functional polyolefin is used in an amount sufficient to increase the heat resistance. A preferred functional polyolefin is a maleated polyolefin such as maleated polypropylene. A preferred tackifier is a hydrogenated hydrocarbon tackifier.
    Type: Grant
    Filed: February 8, 2008
    Date of Patent: December 13, 2011
    Assignee: Henkel AG & Co. KGaA
    Inventors: Richard J. Ellis, Michaela Stolbova
  • Publication number: 20110293839
    Abstract: The present invention relates to a water-based waterproof composition for coating different substrates characterized in that it is formulated by including a elastomeric acrylic comprising a mechanical reinforcing fiber of an elastic material produced by a fiber yarn process, that, once applied and dried keeps its elongation properties.
    Type: Application
    Filed: July 8, 2009
    Publication date: December 1, 2011
    Applicant: POLIMEROS, ADHESIVOS Y DERIVADOS, S.A. DE C.V.
    Inventor: Ricardo Luis Rodriguez Cantú
  • Patent number: 8063147
    Abstract: An object is to provide a transmission belt which is restrained from being deteriorated in a high-temperature atmosphere, is excellent in softness in a low-temperature atmosphere, and is hardly worn away. To attain the object, the invention provides a transmission belt made of a rubber composition wherein the ratio by weight of a Ziegler-Natta catalyst type ethylene/?-olefin copolymer rubber, which is an ethylene/?-olefin copolymer rubber obtained by polymerization in the presence of a Ziegler-Natta catalyst, to a metallocene type ethylene/?-olefin copolymer rubber, which is an ethylene/?-olefin copolymer rubber obtained by polymerization in the presence of a metallocene catalyst, is from 50/50 to 90/10.
    Type: Grant
    Filed: August 31, 2007
    Date of Patent: November 22, 2011
    Assignee: Bando Chemical Industries, Ltd.
    Inventor: Yasuhiko Yoshida
  • Patent number: 8058348
    Abstract: A polyolefin microporous film comprising polyethylene and polypropylene having a viscosity average molecular weight of 100,000 or higher, the polypropylene being contained in an amount of 4 wt % or more and the terminal vinyl group concentration per 10,000 carbon atoms in the polyolefin constituting the microporous film being 2 or more as measured by infrared spectroscopy. The microporous film has both of a good film breaking resistance and a low thermal shrinkage, is excellent in fuse property, and has a uniform film thickness. Particularly, the microporous film can retain safety in the oven safety test at 150° C. for a battery which is required for use as a lithium ion battery separator.
    Type: Grant
    Filed: July 27, 2006
    Date of Patent: November 15, 2011
    Assignee: Asahi Kasei Chemicals Corporation
    Inventors: Hisashi Takeda, Daisuke Inagaki
  • Publication number: 20110263763
    Abstract: A method for varying the transport properties of a film cast from a polymer having at least two polymer end blocks A and at least one polymer interior block B wherein each A block is a polymer block resistant to sulfonation and each B block is a polymer block susceptible to sulfonation, and wherein said A and B blocks do not contain any significant levels of olefinic unsaturation. The method includes casting the polymer using a solvent mixture having two or more solvents selected from the group consisting of polar solvents and non-polar solvents.
    Type: Application
    Filed: July 1, 2011
    Publication date: October 27, 2011
    Applicant: KRATON POLYMERS U.S. LLC
    Inventors: Carl Lesley Willis, Dale Lee Handlin, JR., Scott Russell Trenor, Brian Douglas Mather
  • Patent number: 8044134
    Abstract: The present invention relates to a polylactic acid resin composition. The composition includes about 25 to about 80 parts by weight of a polylactic acid resin, (B) about 20 to about 75 parts by weight of a polycarbonate resin, and (C) about 0.01 to about 5 parts by weight of a chain extender including an amine group, based on about 100 parts by weight of (A)+(B). The polylactic acid resin composition of the present invention is environmentally-friendly and has excellent hydrolysis resistance and simultaneously improved mechanical strength and heat resistance, and accordingly can be used for manufacturing various molded products requiring heat resistance and mechanical strength, for example vehicles, machine parts, electronic parts, office machines, miscellaneous goods, and the like.
    Type: Grant
    Filed: June 5, 2009
    Date of Patent: October 25, 2011
    Assignee: Cheil Industries Inc.
    Inventors: Young-Mi Chung, Chang-Do Jung
  • Patent number: 8043713
    Abstract: An aqueous dispersion including (A) at least one base polymer selected from the group consisting of an ethylene-based co-polymer and a propylene-based co-polymer; (B) at least one polymeric stabilizing agent; and at least one filler; wherein the polymeric stabilizing agent is different from the at least one base polymer and is compatible with the at least one base polymer and the at least one filler, and wherein the dispersion has filler in the range of greater than 0 to about 600 parts per hundred parts of a combined amount of the at least one base polymer and the polymeric stabilizing agent is disclosed.
    Type: Grant
    Filed: December 15, 2005
    Date of Patent: October 25, 2011
    Assignee: Dow Global Technologies LLC
    Inventors: Ronald Wevers, James Kennedy, Aaron M. Bujnowski, Brad Maurice Moncla
  • Patent number: 8039540
    Abstract: Polymer composition showing an improved balance of flexural modulus, IZOD impact strength and elongation at break comprising (percent by weight): A) a polymer blend comprising: A1) 50-70% of a crystalline propylene homopolymer or copolymer; and A2) 30-50% of one or more copolymer(s) of ethylene with one or more C4-C10 ?-olefin(s) containing from 15 to 35% of said C4-C10 ?-olefin(s); said polymer blend (A) having values of MFR equal to or higher than 10 g/10 min., a total content C4-C10 ?-olefin(s) equal to or higher than 8% and an intrinsic viscosity value of the fraction soluble in xylene at room temperature of from 1.3 to 2 dl/g, the amounts of (A1) and (A2) being referred to the total weight of the polymer blend; and optionally B) 1-15% of an elastomeric polymer different from A2), having a hardness (Shore A, ASTM D-2240) value equal to or lower than 90 points; and/or C) 0.5-20% of a mineral filler; the amounts of optional components (B) and (C) being referred to the total weight of the composition.
    Type: Grant
    Filed: May 30, 2005
    Date of Patent: October 18, 2011
    Assignee: Basell Poliolefine Italia s.r.l.
    Inventors: Anteo Pelliconi, Enea Garagnani
  • Patent number: 8022131
    Abstract: The present invention relates to a water-based ink for ink-jet printing which not only satisfies a high optical density but also exhibits excellent high lighter-fastness and gloss; and a water dispersion used for the water-based ink. There are provided a water dispersion for ink-jet printing containing (A) a self-dispersible pigment, (B) self-emulsifiable polymer particles containing a constitutional unit derived from a salt-forming group-containing monomer, and (C) emulsion polymer particles; and a water-based ink containing the water dispersion.
    Type: Grant
    Filed: February 26, 2010
    Date of Patent: September 20, 2011
    Assignee: Kao Corporation
    Inventors: Yasuhiro Doi, Yasushi Ito, Shigeki Nagashima
  • Patent number: 8008393
    Abstract: This invention provides an automobile water-based paint capable of forming coating film of little metallic mottling and excellent flip-flop property and smoothness, which comprises hydroxyl-containing resin, viscosity-regulating agent and hydrophobic solvent, the viscosity-regulating agent being a copolymer obtained by copolymerizing a monomeric mixture containing a (meth)acrylic acid (salt), monomer represented by the following formula (1) [in which R1 stands for hydrogen or methyl, R2 and R3 stand for hydrogen, methyl or ethyl, R4 stands for C8-24 hydrocarbon group, and n is an integer of 3-60], alkyl (meth)acrylate of which alkyl moiety has 1-4 carbons and a monomer having at least two polymerizable unsaturated groups per molecule, at specific ratios.
    Type: Grant
    Filed: September 19, 2008
    Date of Patent: August 30, 2011
    Assignee: Kansai Paint Co., Ltd.
    Inventors: Tadashi Iida, Yoshizumi Matsuno, Yasushi Nakao
  • Patent number: 8008401
    Abstract: A polyolefin composition comprising an olefin-based thermoplastic elastomer which is superior to conventional olefin-based thermoplastic elastomers in scratch resistance and abrasion resistance and has excellent heat aging resistance is proposed. [Means for Solving the Problem] A polyolefin composition comprising a syndiotactic ?-olefin-based copolymer (A), a polyolefin resin (B) (other than polybutene (C)), polybutene (C), and if necessary, an ethylene-based copolymer rubber (D).
    Type: Grant
    Filed: September 10, 2007
    Date of Patent: August 30, 2011
    Assignee: Mitsui Chemicals, Inc.
    Inventors: Yuichi Ito, Kazuki Mita, Ryoji Mori, Masahiko Okamoto, Toru Takehara, Masakazu Jitsukata, Hayato Kurita
  • Patent number: 8003223
    Abstract: The present invention is directed to a heat-sealable propylene-based polymer composition comprising a propylene polymer composition including a propylene polymer component and propylene/ethylene random copolymer component; an ethylene/?-olefin random copolymer; and a soft propylene polymer composition. The present invention also provides a heat-sealable film using the composition and a packaging bag comprising the film. The heat-sealable film of the present invention has high heat-seal strength, with little decrease in heat-seal strength even after heat treatment. The heat-sealable film also has excellent blocking resistance, rigidity and low-temperature impact resistance.
    Type: Grant
    Filed: October 13, 2006
    Date of Patent: August 23, 2011
    Assignee: Mitsui Chemicals, Inc.
    Inventors: Kazuhide Maruyama, Ichiro Takeishi, Norihide Inoue, Hiroshi Hoya
  • Patent number: 7999029
    Abstract: A macromolecule including a polymer and a polyhedral radical chemically bonded to a terminus of the polymer provides numerous processing and performance advantages. Further functionalization of this macromolecule also is described as being advantageous in certain circumstances. Methods of providing, functionalizing, and utilizing the macromolecule also are provided.
    Type: Grant
    Filed: November 2, 2005
    Date of Patent: August 16, 2011
    Assignee: Bridgestone Corporation
    Inventors: Yuan-Yong Yan, Jason Poulton, Takayuki Yako, Xiaorong Wang, Hao Wang, Michelle A. Cottrell
  • Patent number: 7994253
    Abstract: A composition is described in one aspect as comprising one or more propylene-?-olefin terpolymers; wherein the propylene-?-olefin terpolymer(s) possess a melting temperature (Tm) within the range of from less than 105° C., and a heat of fusion (Hf) within the range of from less than 75 J/g; one or more polyolefin(s); and oil; wherein fillers are present, if at all, at a level that maintains a Haze value of 65% or less for the composition. The terpolymer in one embodiment is a polymer comprising at least 65 wt %, by weight of the terpolymer, of propylene-derived units, within the range of from 5 to 35 wt % of ethylene or other ?-olefin and a diene such as ethylidiene norbornene, and in certain embodiments having a Mooney Viscosity (ML(1+4)@125° C.) within the range of from 10 to 50 (ASTM D1646). The compositions can be cured to form transparent or translucent articles such as sheets that are also flexible.
    Type: Grant
    Filed: April 15, 2008
    Date of Patent: August 9, 2011
    Assignee: ExxonMobil Chemical Patents Inc.
    Inventors: Sunny Jacob, Gary K. Lawrence, Edward John Blok, Ralph E. Raulie
  • Patent number: 7989541
    Abstract: A synthetic-rubber-based composition that consists of a low-molecular-weight rubber selected from polybutadiene comprising about 75% to about 92% cis-1,4 units, sulfur, a vulcanization accelerator, and an active filler wherein the sulfur, accelerator, and active filler are each present in the form of powder having a particular particle-size range. Additionally, this composition may be used to form coatings and rubber concretes.
    Type: Grant
    Filed: December 4, 2008
    Date of Patent: August 2, 2011
    Assignees: Nanotech Industries, Inc., Polymate, Ltd.
    Inventor: Oleg Figovsky
  • Patent number: 7989536
    Abstract: A polymeric nanocomposite comprises a non-polar hyperbranched polystyrene resin. An exfoliated or intercalated onium functionalized clay is dispersed within the resin. Such nanocomposites are more compatible with non-polar polymer matrices used in various articles of manufacture.
    Type: Grant
    Filed: September 29, 2008
    Date of Patent: August 2, 2011
    Assignee: Eastman Kodak Company
    Inventors: Mark R. Mis, Douglas R. Robello, Thomas N. Blanton, Craig L. Barnes
  • Publication number: 20110178226
    Abstract: This invention relates flame retardant compositions containing low molecular weight brominated anionic, chain transfer, vinyl aromatic polymers, hereinafter “ACTVAP”. The compositions can accommodate high bromine content while still exhibiting a low thermally labile bromine content. The compositions have glass transition temperatures, Tg, that are predictive of acceptable melt flows and heat distortion temperatures (HDT) in HIPS and ABS based formulations substrates. The compositions, are suitable flame retardant candidates for use in thermoplastic formulations, e.g. polystyrene and ABS formulations.
    Type: Application
    Filed: June 6, 2008
    Publication date: July 21, 2011
    Applicant: ALBEMARLE CORPORATION
    Inventors: William J. Layman, Arthur G. Mack, Charles H. Kolich, Govindarajulu Kumar
  • Patent number: 7973104
    Abstract: The present invention relates to rubbery core/shell polymers that have improved heat and ultraviolet light resistance. These polymers can be blended with thermoplastics to make leathery compositions. The core/shell polymers of this invention have an inner core and an outer shell. The inner core is has repeat units which are derived from (a) butyl acrylate, (b) a member selected from the group consisting of methyl methacrylate, ethyl methacrylate, methyl acrylate, and ethyl acrylate, (c) optionally, an alkoxy ethyl acrylate or an alkoxy ethyl methacrylate, (d) acrylonitrile, (f) a cross-linking agent, and (g) a monomer containing reactive cure sites The outer core has repeat units which are derived from (d) acrylonitrile, (e) styrene, and (f) additional cross-linking agent. The outer core of these polymers is void of repeat units that are derived from methyl methacrylate.
    Type: Grant
    Filed: June 29, 2006
    Date of Patent: July 5, 2011
    Assignee: Eliokem S.A.S.
    Inventor: Hung Dang Ngoc
  • Patent number: 7968642
    Abstract: A redispersible polymer including, as a redispersing aid, a protective colloid system including from 30% to 100% of a low molecular weight polyacrylamide colloid having a 20% solution viscosity in water of 200 to 800 Centipoise.
    Type: Grant
    Filed: February 22, 2008
    Date of Patent: June 28, 2011
    Assignee: Acquos Pty Ltd
    Inventor: Valentino De Fazio
  • Patent number: 7956129
    Abstract: Novel polymer blends comprise (a) 1-99% by weight of a copolymer of ethylene and an alpha olefin having from 3 to 10 carbon atoms, said copolymer having (iv) a density in the range 0.905 to 0.940 g cm?3, (v) a melt elastic modulus G? (G?=500 Pa) in the range 10 to 150 Pa, and (vi) a melt index in the range 5 to 50, and (b) from 1-99% by weight of a low density polyethylene (LDPE) polymer having a density from 0.914 to 0.928 g cm?3 wherein the sum of (a) and (b) is 100%. The copolymers of component (a) are typically prepared by use of metallocene catalysts. The blends exhibit advantageous melt elastic modulus in the range 30 to 200 Pa. The blends are particularly suitable for extrusion coating applications.
    Type: Grant
    Filed: August 12, 2004
    Date of Patent: June 7, 2011
    Assignee: Ineos Europe Limited
    Inventor: Choon Kooi Chai
  • Patent number: 7951872
    Abstract: A heterogeneous polymer blend comprises a dispersed phase comprising a thermoplastic first polymer having a crystallinity of at least 30% and a continuous phase comprising a second polymer different from the first polymer. The second polymer has a crystallinity of less than 20% and is at least partially cross-linked.
    Type: Grant
    Filed: December 7, 2005
    Date of Patent: May 31, 2011
    Assignee: ExxonMobil Chemical Patents Inc.
    Inventors: Sunny Jacob, Peijun Jiang, Aspy K. Mehta, Pradeep P. Shirodkar, Armenag H. Dekmezian, Weiqing Weng
  • Patent number: 7947760
    Abstract: Polymer emulsion compositions for use in printing inks and printing inks made from the compositions are provided. The emulsion compositions include an aqueous continuous phase containing water and a dissolved carboxylic acid-functional support polymer. The dispersed phase of the emulsion composition contains crosslinked, dispersed polymer particles. The emulsion compositions also include at least one multivalent metal crosslinker and at least one stabilizing agent. The polymer emulsion compositions display superior printability properties in inks and other coatings formulated with them, yet are stable at elevated temperatures for long periods of time.
    Type: Grant
    Filed: September 19, 2005
    Date of Patent: May 24, 2011
    Assignee: BASF Corporation
    Inventors: Rein J. Janmaat, James W. Taylor, Mark van den Brink, Andre van Meer
  • Patent number: 7947379
    Abstract: An aqueous dispersion including (A) at least one base polymer selected from the group consisting of an ethylene-based co-polymer and a propylene-based co-polymer; (B) at least one polymeric stabilizing agent; and at least one filler; wherein the polymeric stabilizing agent is different from the at least one base polymer and is compatible with the at least one base polymer and the at least one filler, and wherein the dispersion has filler in the range of greater than 0 to about 600 parts per hundred parts of a combined amount of the at least one base polymer and the polymeric stabilizing agent is disclosed.
    Type: Grant
    Filed: August 17, 2010
    Date of Patent: May 24, 2011
    Assignee: Dow Global Technologies LLC
    Inventors: Ronald Wevers, James G. Kennedy, Aaron M. Bujnowski, Brad M. Moncla, Wenbin Liang
  • Patent number: 7935747
    Abstract: The invention relates to a pigment preparation for coloring polymers. The inventive preparation comprises one or more pigments and a carrier. According to the invention, the carrier includes an oligomer or a combination of low-molecular-weight polymers from the group containing polymers and copolymers of ethylene-acrylic acid, ethylene-maleic anhydride or polypropylene-maleic anhydride. The carrier also includes a polymer from the group containing polymers of ethylene-ethyl acrylate, ethylene/butyl acrylate, ethylene/methacrylic acid, polypropylene with grafted methyl polymethacrylate, polypropylene with grafted polystyrene or block copolymers of styrene. For organic pigments, the preparation contains 50%-70% pigment and 50%-30% carrier. For inorganic pigments, the preparation contains 60%-90% pigment and 40%-10% carrier. The invention comprises a polyvalent pigment preparation which can be used in the production of color concentrates with specific bases and high precision.
    Type: Grant
    Filed: June 21, 2005
    Date of Patent: May 3, 2011
    Assignee: IQAP Masterbatch Group, S.L.
    Inventor: Josep Castanyer Collell
  • Patent number: 7932316
    Abstract: A composition that includes functionalized polymers and one or more types of particulate filler exhibits both an increased gum Mooney viscosity and a decreased compound Mooney viscosity relative to a comparable composition that includes only one such functionalized polymer. The functionalized polymers include first and second types of functionalities which exhibit a non-covalent interaction that has a bond energy of from about 0.1 to about 20 kJ/mol.
    Type: Grant
    Filed: December 17, 2007
    Date of Patent: April 26, 2011
    Assignee: Bridgestone Corporation
    Inventors: Yuan-Yong Yan, Steven Luo
  • Patent number: 7923501
    Abstract: A polypropylene resin composition contains 2 to 15 wt % of a moldability improver (A) and 85 to 98 wt % of a polypropylene resin (B). The moldability improver (A) is formed of propylene block copolymers (A-1) and (A-2). Each of the propylene block copolymers (A-1) and (A-2) has a crystalline propylene polymer component (A-11), (A-21) and a propylene-ethylene random copolymer component (A-12), (A-22). The propylene block copolymer (A-1) is characterized in that the melt flow rate of the crystalline propylene polymer component (A-11) is high, whereas the propylene block copolymer (A-2) is characterized in that the content ratio of the propylene-ethylene random copolymer component (A-22) is high. The polypropylene resin (B) is formed of a propylene-ethylene block copolymer (B-1), at least one of an ethylene elastomer and a styrene elastomer (B-2) and an inorganic filler (B-3).
    Type: Grant
    Filed: December 19, 2007
    Date of Patent: April 12, 2011
    Assignee: Nissan Motor Co., Ltd.
    Inventors: Masashi Shimouse, Yukihito Zanka, Takayuki Sato, Mineyuki Saotome, Sinichi Takaragi
  • Publication number: 20110073901
    Abstract: Adhesive encapsulating compositions for use in electronic devices such as organic electroluminescent devices, touch screens, photovoltaic devices, and thin film transistors are disclosed herein. The adhesive encapsulating compositions include pressure sensitive adhesives comprising one or more cyclic olefin copolymers, in combination with multifunctional (meth)acrylate monomers and tackifiers.
    Type: Application
    Filed: April 23, 2009
    Publication date: March 31, 2011
    Inventors: Jun Fujita, Tamon Tadera, Fred B. McCormick
  • Patent number: 7916450
    Abstract: A ceramic slurry composition includes 20˜50 wt. % of a ceramic powder, 2˜10 wt. % of a polymer having average molecular weight of 400,000 or more, 0.1˜2 wt. % of a polymer having hydrogen bond-forming functional groups, and 40˜75 wt. % of a solvent. If necessary, the ceramic slurry composition further includes 1˜5 wt. % of a polymer having weight average molecular weight of 400,000 or less.
    Type: Grant
    Filed: May 7, 2008
    Date of Patent: March 29, 2011
    Assignee: Samsung Electro-Mechanics Co., Ltd.
    Inventor: Sung Il Oh
  • Patent number: 7897679
    Abstract: Unique copolymers comprising propylene, ethylene and/or one or more unsaturated comonomers are characterized as having: at least one, preferably more than one, of the following properties: (i) 13C NMR peaks corresponding to a regio-error at about 14.6 and about 15.7 ppm, the peaks of about equal intensity, (ii) a B-value greater than about 1.4 when the comonomer content of the copolymer is at least about 3 wt %, (iii) a skewness index, Six, greater than about ?1.20, (iv) a DSC curve with a Tme that remains essentially the same and a Tmax that decreases as the amount of comonomer in the copolymer is increased, and (v) an X-ray diffraction pattern that reports more gamma-form crystals than a comparable copolymer prepared with a Ziegler-Natta catalyst These polypropylene polymers are made using a nonmetallocene, metal-centered, heteroaryl ligand catalyst. These polymers can be blended with other polymers, and are useful in the manufacture of films, sheets, foams, fibers and molded articles.
    Type: Grant
    Filed: June 27, 2007
    Date of Patent: March 1, 2011
    Assignee: Dow Global Technologies Inc.
    Inventors: James C. Stevens, Daniel D. Vanderlende
  • Publication number: 20110027583
    Abstract: Adhesive compositions suitable for use as tie-layer adhesives in multi-layer films and sheets are provided. The adhesive compositions contain an olefin polymer base resin, a modified polyolefin and a paraffinic liquid hydrocarbon.
    Type: Application
    Filed: July 30, 2009
    Publication date: February 3, 2011
    Applicant: Equistar Chemicals, LP
    Inventors: Chun D. Lee, Charles S. Holland