Solid Polymer Or Sicp Derived From At Least One Carboxylic Acid Or Derivative Reactant Patents (Class 524/539)
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Patent number: 6465559Abstract: A sizing composition which includes an anionic or cationic polyurethane dispersion, a polyolefin wax and a coupling agent.Type: GrantFiled: October 30, 2000Date of Patent: October 15, 2002Assignee: Crompton CorporationInventors: Ibrahim Bechara, Biau-Hung Chang, Pavel Ilmenev
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Patent number: 6462145Abstract: A polymer blend consisting essentially of 80% to 95% by weight, based on the total weight of the composition, of polytrimethylene terephthalate and from 5% to 20% of an elastomeric polyester. Fibers and extrusions produced from the polymer blend are durable under repetitive compressive stresses, exhibit mechanical properties comparable to neat polyamide-6, and provide moisture stability similar to yarns and extrusions comprised of polyamide-6/10 or polyamide-6/12. These fabrics find use as forming fabrics, and press felt fabrics for paper making machines.Type: GrantFiled: July 20, 2000Date of Patent: October 8, 2002Inventors: Paul C. Fleri, Samuel M. Baker
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Patent number: 6461698Abstract: The invention relates to a composition comprising from 20 to 70 parts by weight of poly[ethylene terephthalate] (PET), from 20 to 70 parts by weight of poly[ethylene naphthalate] (PEN) and from 10 to 33 parts by weight of poly[butylene terephthalate] (PBT), the total being 100 parts by weight, in the form of a polymer blend and/or copolymer.Type: GrantFiled: September 22, 2000Date of Patent: October 8, 2002Assignee: Kabushiki Kaisha Kobe Seiko Sho (Kobe Steel, Ltd)Inventors: Farideh Bassam, Michael David Thompson, Barry Woodfine
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Patent number: 6458443Abstract: The invention concerns a stain resist composition comprising: (a) a component selected from the group consisting of (1) an anionically modified phenol formaldehyde polymer comprising a phenol moiety and a formaldehyde moiety, (2) a naphthalene condensate, (3) a lignin sulfonate, (4) a phenol sulfonate derivative, a mixture thereof and (5) a (meth)acrylic polymer comprising residues of acrylic or methacrylic acid; and (b) a polyester.Type: GrantFiled: July 24, 1998Date of Patent: October 1, 2002Assignee: Arrow Engineering, Inc.Inventors: Robert B. Collier, J. Todd Mull
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Patent number: 6448463Abstract: This invention relates to water responsive thermoplastic compositions and articles constructed thereof. This invention particularly relates to thermoplastic copolyester compositions useful for the manufacture of disposable-articles such as disposable diapers and feminine napkins. More particularly, this invention relates to thermoplastic copolyester compositions that are useful as a raw material in the manufacture of nonwovens, barrier films or coatings and as well as for various improved hot melt adhesives compositions useful for incorporating hydrophilic features into disposable articles.Type: GrantFiled: May 6, 1997Date of Patent: September 10, 2002Assignee: H. B. Fuller Licensing & Financing Inc.Inventors: Carolyn A. Fischer, Mai N. Haselman, Mark S. Hull, Mark G. Katsaros, Mark S. Kroll, Greg J. Van Lith, Sharf U. Ahmed, Andualem W. Emiru
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Patent number: 6433070Abstract: A binder composition, at least containing an inorganic filler and a thermoplastic block copolyurethane having in each case at least one soft segment (A) and at least one hard segment (B), at least one hard segment (B) containing a structural element of the formula I is used in particular for the production of magnetic recording media.Type: GrantFiled: September 14, 2000Date of Patent: August 13, 2002Assignee: Emtec Magnetics GmbHInventors: Benedikt Raether, Ulrike Hees, Ria Kress, Albert Kohl, Richard Bradshaw, Gerhard Maier
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Publication number: 20020107319Abstract: The invention provides an amide-type polymer/first polymer blend comprising: a) a polymer colloid system comprising a first polymer comprising a non-core shell polymer and b) and amide polymer. Blends where the polymer colloid system comprises latex polymer particles, a surfactant, and a liquid continuous phases are also described.Type: ApplicationFiled: March 29, 2002Publication date: August 8, 2002Applicant: Eastman Chemical CompanyInventors: David Logan Murray, Allan Scott Jones, Wesley R. Hale, William R. Darnell
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Patent number: 6428900Abstract: A water-sensitive hot melt adhesive composition based on sulfonated branched copolyester polymers for use with articles such as paper products, disposable nonwoven products, tapes, labels and packaging materials. The adhesive composition includes about 10% to about 90%, by weight, of a sulfonated polyester copolymer or a blend of one or more sulfonated polyester polymers; about 0% to about 80%, by weight, of a tackifying resin; about 0% to about 40%, by weight, of a compatible plasticizer; about 5% to about 50% by weight of a polyethylene glycol having a molecular weight greater than 2000 and a melting point greater than 50° C; and about 0% to about 3% by weight of one or more antioxidant. The adhesive maintains the article in an assembled condition by providing adequate adhesive bond strength during normal use, but dissolves in the presence of water thereby permitting the article to be recycled or otherwise disposed of in an environmentally friendly manner.Type: GrantFiled: March 9, 2000Date of Patent: August 6, 2002Assignee: Ato Findley, Inc.Inventor: Baoyu Wang
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Patent number: 6423805Abstract: The open time of a cementitious composition, such as a grout, may be increased by the incorporating therein, as a binder, a polymer composition comprising a film-forming copolymer formed by polymerization of a monomer mixture comprising 1 to 3% of at least one monomer selected from the group of monomers consisting of amides of &agr;,&bgr;-unsaturated C3 to C6 carboxylic acids and at least one hydroxy-(C1 to C8)alkyl (meth)acrylate monomer, wherein the total amount of these monomers is from 2 to 7.5% by weight of said monomer mixture.Type: GrantFiled: April 17, 2000Date of Patent: July 23, 2002Assignee: Rohm and Haas CompanyInventors: Anne Margaret Bacho, Frederick Paul Hinz, Mark Alan Kesselmayer, Kathleen Anne Koziski, Meredith Ann Morgan, Lori Branham Pfahler, Fergus Stuart McColl
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Patent number: 6419851Abstract: Melt processable liquid crystalline terpolyesters of the formula I below: where R is Cl, C6H5, CH3CO, CH3, and process for the preparation thereof are disclosed. The process comprises acetylating 8(3-hydroxyphenyl)octanoic acid and hydroquinone using an acetylating agent followed by acidolysis polycondensation for the removal of acetic acid to effect higher molecular weight formation, post-polymerisation being effected at higher temperatures but below the decomposition temperature.Type: GrantFiled: March 28, 2000Date of Patent: July 16, 2002Assignees: Council of Scientific and Industrial Research, Department of Science and TechnologyInventors: Veena Vijayanathan, Vadakkethonippurathu Sivankutty Nair Prasad, Chennakkattu Krishna Sadasivan Pillai
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Patent number: 6414063Abstract: The application relates to a composition poly[ethylene terephthalate] (PET) and poly[ethylene naphthalate] (PEN), in the form of a polymer blend and/or copolymer, in which the PET:PEN mol ratio is from 20:80 to 80:20, and from 0.1 to 5.0 wt. %, based on the total weight of the composition, of a transition metal salt of a carboxylic acid.Type: GrantFiled: September 20, 2000Date of Patent: July 2, 2002Assignee: Kobe Steel, Ltd.Inventors: Farideh Bassam, Michael David Thompson, Barry Woodfine
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Patent number: 6407158Abstract: The present invention relates to a water-soluble or water-dispersible polymeric salt, to a cosmetic or pharmacuetical composition which comprises at least one such polymeric salt, and to the use of the polymeric salts.Type: GrantFiled: March 20, 2000Date of Patent: June 18, 2002Assignee: BASF AktiengesellschaftInventors: Son Nguyen Kim, Axel Sanner, Peter Hössel
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Patent number: 6403685Abstract: An improved capacitor roll with alternating film and foil layers is impregnated with an adhesive, elastomeric gel composition. The gel composition is a blend of a plasticizer, a polyol, a maleic anhydride that reacts with the polyol to form a polyester, and a catalyst for the reaction. The impregnant composition is introduced to the film and foil layers while still in a liquid form and then pressure is applied to aid with impregnation. The impregnant composition is cured to form the adhesive, elastomeric gel. Pressure is maintained during curing.Type: GrantFiled: August 6, 2001Date of Patent: June 11, 2002Assignee: Sandia CorporationInventors: David Glenn Shaw, John Randolph Pollard, Robert Aubrey Brooks
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Patent number: 6395823Abstract: The present invention relates to a composite made by the process of melt mixing (a) a polymer having at least one isocyanate reactive group, wherein the polymer is from 30 to 90% by weight of the composite; (b) a thermoplastic polyurethane at from 0.1 to less than 10% by weight of the composite; and (c) a reinforcing fiber at from 9.9 to 60% by weight of the composite, wherein the sum of the weight percentages of components (a)-(c) is equal to 100%, wherein the polymer (a) is not a polyamide. The invention further relates to a composite prepared by the process of melt mixing (a) a polymer having at least one isocyanate reactive group, wherein the polymer is from 25 to 90% by weight of the composite; (b) a thermoplastic polyurethane at from 0.1 to 10% by weight of the composite; (c) a reinforcing fiber at from 9.8 to 60% by weight of the composite, and (d) an epoxy compound at from 0.1 to 5% by weight of the composite, wherein the sum of the weight percentages of components (a)-(d) is equal to 100%.Type: GrantFiled: January 31, 2000Date of Patent: May 28, 2002Assignee: Eastman Chemical CompanyInventors: Andrew E. Brink, Jeffrey T. Owens
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Patent number: 6395820Abstract: A substantially solvent free, aqueous, pigmented, two component polyurethane-polyurea dispersion comprising: (a) an aqueous mixture of an acid-containing polymeric polyol and a polyol free of acid groups, wherein the mixture has an average hydroxyl functionality of at least 1.5 and an acid number between about 15 and 200; and an amine or a blend of amines having an average active hydrogen functionality of at least 1.5, the amine or blend of amines being present in a sufficient amount to substantially neutralize the acid-containing polymeric polyol; (b) one or more polyisocyanates; and (c) two or more different pigments; characterized by reducing or eliminating flooding of the pigments with (d) an aqueous polymer emulsion present in an amount sufficient to impart thixotropy to the mixture of (a) and (d).Type: GrantFiled: November 15, 1999Date of Patent: May 28, 2002Assignee: Air Products and Chemicals, Inc.Inventors: Denise Luise Lindenmuth, Charles Raymond Hegedus, Frank Ralph Pepe
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Patent number: 6376596Abstract: A curable coating composition comprising functionalized oligomer components i and ii which cross-link at cure to form a three-dimensional network having chains of substantially uniform, controllable molecular weight between cross-links; oligomers i and ii having weight average molecular weights not exceeding about 3,000, a polydispersity for (i) not exceeding about 1.5, and functionalities that react with one another to cross-link i and ii at cure to yield coatings with an excellent balance of hardness and mar resistance.Type: GrantFiled: November 12, 1998Date of Patent: April 23, 2002Assignee: E. I. du Pont de Nemours and CompanyInventors: Robert John Barsotti, Isidor Hazan, Bruce Lyle Neff
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Patent number: 6376589Abstract: There is disclosed a coating composition comprising a binder component consisting of (A′) hydroxyl group-containing polyester resin having a number average molecular weight of 2,000-20,000, glass transition temperature of −40° C. to 30° C. and hydroxyl value of 5-95 mgKOH/g, (B) blocked polyisocyanate compound blocked with &egr;-caprolactam, and the equivalent ratio of the blocked isocyanate groups in said blocked polyisocyanate compound (B)/the hydroxyl groups in said polyester resin (A) being in the range of 0.7-1.2, and 0.5-30 parts by weight of said resin fine particles (C) with an average particle diameter of 8-70 &mgr;m, which do not completely melt at the time of coating film curing, per 100 parts by weight of said binder component. Said coating composition can form a coating film having excellent popping resistance. hardness, processibility, anti-tackiness, blocking resistance and curability by a high temperature short time baking.Type: GrantFiled: June 24, 1999Date of Patent: April 23, 2002Assignee: Kansai Paint Co., Ltd.Inventors: Shoichi Tanaka, Hideyuki Abe
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Patent number: 6372840Abstract: In a dispersion containing acrylic polymer microparticles, particularly useful in automotive coatings, the dispersion is formed by free radical addition copolymerization of unsaturated monomers in a hydrocarbon dispersing medium in the presence of first and second polymeric dispersion stabilizers. The first polymeric dispersion stabilizer has an acrylic backbone and polyester side chains, and the second polymeric dispersion stabilizer is a branched polyester formed from the reaction of polyol, polyacid or anhydride, and fatty acid.Type: GrantFiled: June 28, 2000Date of Patent: April 16, 2002Assignee: PPG Industries Ohio, Inc.Inventors: Mohamad D. Shalati, Susana C. Steppan, Michael A. Mayo
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Publication number: 20020042469Abstract: The invention provides a thermosetting aqueous primer composition that includes a dispersed polyurethane polymer, an acrylic polymer emulsion polymerized in the presence of the polyurethane dispersion, and a crosslinking component that is reactive with at least one of the polyurethane polymer and the acrylic polymer. The polyurethane polymer has a glass transition temperature of 0° C. or less. The acrylic polymer has a glass transition temperature that is at least about 20° C. higher than the glass transition temperature of polyurethane resin. The invention further provides a composite coating having as a primer layer a cured layer of the primer composition of the invention and having at least one topcoat layer.Type: ApplicationFiled: December 6, 2001Publication date: April 11, 2002Inventor: Sunitha Grandhee
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Patent number: 6365664Abstract: The present invention, which addresses the needs of the prior art, provides irreversible, hydrophilic gels which can be incorporated into dressing compositions, dermatologically compatible compositions, wound packings, wound dressings, burn dressings, drug delivery dressings, dry films, cosmetic masks and cosmetic wrap dressings. The gels of the invention include a blend of a hydrophilic poly(aldehyde) and a polymer selected from the group consisting of a poly(amide), a poly(amine) and a poly(alcohol).Type: GrantFiled: July 25, 2000Date of Patent: April 2, 2002Assignee: Hydromer, Inc.Inventor: Micahel Eknoian
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Patent number: 6359059Abstract: Low VOC automotive paint compositions containing reactive urea/urethanes are disclosed. Clearcoat and single stage topcoat formulations are found to be especially useful according to this invention.Type: GrantFiled: March 7, 1997Date of Patent: March 19, 2002Assignee: BASF CorporationInventors: Stewart Shepler, Patrick J. Mormile, Sudhakar Dantiki, David W. Braun
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Publication number: 20020022680Abstract: Storage-stable, essentially aqueous one-component dispersions, which comprise deactivated isocyanates and isocyanate-reactive polymers and cross-link already at low temperatures, are described.Type: ApplicationFiled: September 24, 2001Publication date: February 21, 2002Applicant: Jowat Lobers und Frank GmbH & Co. KGInventors: Dieter Guse, Theodor Hippold, Christian Terfloth
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Publication number: 20020017631Abstract: Provided is a liquid crystal polyester resin composition, which comprises 5-20 parts by weight of glass fiber having a specific number average fiber diameter and fiber length after molding and 100 parts by weight of a specific liquid crystal polyester resin, and the flexural modulus thereof measured with using a test piece of 0.5 mm thickness is 25 GPa or more; and also provided a process for producing a molded article therefrom. The liquid crystal polyester resin composition is low in specific gravity, and is excellent in processability, mechanical properties, and heat resistance.Type: ApplicationFiled: April 3, 2001Publication date: February 14, 2002Inventors: Mituo Maeda, Satoshi Nagano
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Patent number: 6344508Abstract: In the present invention, the No. I invention relates to a regenerated PET resin composition which comprises formulating 0.5-100 part by weight of a lactone polymer (B) with 100 parts by weight of a regenerated PET resin (A), in which there is improved a molding processability such as an injection moldability and extruding molding, and relates to a molded article therefrom and, the No. II invention relates to a flame retardant resin composition containing a thermoplastic resin (E) and a flame retardant (F), in which bleeding of the flame retardant is suppressed without a decline of a flame retardancy, and relates to a molded article therefrom.Type: GrantFiled: September 14, 2000Date of Patent: February 5, 2002Assignee: Daicel Chemical Industries, Ltd.Inventors: Shunichi Endo, Genichiro Ochiai, Yoshinobu Mizutani, Takuya Miho, Koichi Okumura
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Patent number: 6342576Abstract: A urethanized &bgr;-hydroxyalkylamide compound, a process for its preparation, and powder coating materials containing them.Type: GrantFiled: May 25, 2000Date of Patent: January 29, 2002Assignee: Degussa-Huels AGInventor: Andreas Wenning
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Publication number: 20020010268Abstract: The present invention provides an olefin-based block copolymer that has an olefin block that is substantially saturated and at least one (poly)ester or (poly)ether block. The olefin-based block copolymer of the invention can be prepared by reacting a liquid hydroxyl-functional, saturated or substantially saturated olefin polymer with a chain-extension reagent that is reactive with hydroxyl groups and will polymerize in a head-to-tail arrangement of monomer units. The olefin-based block copolymer of the invention can be used to prepare an adhesion promoter that provides excellent adhesion of subsequent coating layers to olefinic substrates like TPO and superior properties as compared to previously used adhesion promoters containing chlorinated polyolefins.Type: ApplicationFiled: July 17, 2001Publication date: January 24, 2002Inventors: John D. McGee, Daniel Blickberndt, Craig Schang, Walter H. Ohrbom, Keri Krueger
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Patent number: 6340443Abstract: A polyester composition containing fine particles with an average size of 0.03-1.8 &mgr;m which have been surface-modified with polyester (B) of which less than 70 mole percent of the repeating units consist of ethylene terephthalate, butylene terephthalate or ethylene naphthalate units, in polyester (A) of which at least 70 mole percent of the repeating units consist of ethylene terephthalate, butylene terephthalate or ethylene naphthalate units. The composition has a filtration pressure increase rate of no greater than 10 kg cm2/hr when filtered using a double layer of 2400 mesh wire filters with an inner diameter of 64 mm&phgr;, a temperature of 290° C. and a filtration rate of 33.3 g/min.Type: GrantFiled: June 30, 2000Date of Patent: January 22, 2002Assignee: Teijin LimitedInventors: Hideshi Kurihara, Seiichi Takao, Kazumoto Miyajima, Shinya Yamamoto, Toru Takase
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Publication number: 20020002232Abstract: The present invention is directed to a water-based adhesive composition, comprising an admixture of: (A) about 5 to about 80 wt % of an aqueous polyester polyurethane dispersion; and (B) about 95 to about 20 wt % of an aqueous aliphatic polyurethane dispersion. The present invention is also directed to a method of adhering a workpiece or adherent to a substrate using the above water-based adhesive composition.Type: ApplicationFiled: July 17, 2001Publication date: January 3, 2002Inventors: Efraim Sagiv, Gary L. Diehl, Leonard R. Howell, Julius C. Fister
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Patent number: 6333370Abstract: A binder for a coating composition is obtainable as the reaction product of a carboxyl-terminated fatty acid ester with an ethylenically unsaturated carboxylic acid and an ethylenically unsaturated carboxylic acid ester. The carboxylic fatty acid ester is produced by reaction of an autoxidisable fatty acid and a polyol, with modification to introduce at least one terminal carboxyl group. The reaction is optionally effected in an organic solvent which is substantially removed at the end. The material is neutralized with a base to render it water-soluble. Thixotropy can be endowed by an amine/(poly)isocyanate final reaction stage to prior neutralization.Type: GrantFiled: May 28, 1999Date of Patent: December 25, 2001Assignee: Cray Valley LimitedInventors: Werner Lohs, Robert Thomas Lucas, Simon Edward Vivian
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Patent number: 6329060Abstract: A multi-component composite coating composition is provided which includes a pigmented base coat and a transparent topcoat composition applied over the base coat. The transparent topcoat is deposited from a substantially solvent free film-forming composition which includes a thermosettable dispersion of polymeric microparticles having functionality adapted to react with a crosslinking agent and a hydrophilic crosslinking agent reactive with the functionality of the microparticles. The microparticles are prepared from one or more reaction products of ethylenically unsaturated monomers, one or more hydrophobic polymers and one or more hydrophobic crosslinking agents. Pigmented film-forming compositions as well as curable compositions containing the above-described dispersions also are provided. A method of forming the dispersion of polymeric microparticles is provided.Type: GrantFiled: November 10, 1999Date of Patent: December 11, 2001Assignee: PPG Industries Ohio, Inc.Inventors: Karen A. Barkac, Dennis Leroy Faler, Mary E. Grolemund, Debra Lynn Singer
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Publication number: 20010044492Abstract: A coating composition comprising a solution of an electrically-conductive polymer and an organic solvent media wherein the solvents are selected from the group consisting of alcohols, ketones, cycloalkanes, arenes, esters, glycol ethers and their mixtures; the media having a water content of less than 12 weight percent. Such a coating composition provides a means to protect an imaging element against the accumulation of static electrical charges before and after image processing while also providing the element with improved manufacturability and physical properties.Type: ApplicationFiled: June 13, 2001Publication date: November 22, 2001Inventors: Dwight W. Schwark, Debasis Majumdar, Charles C. Anderson, Robert J. Kress
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Patent number: 6316535Abstract: An aqueous, two component system for coating a substrate includes either a filler incorporated in both components prior to combining the components or an elevated amount of a filler, such as 50% by dry volume, in either component. The filler is preferably calcium carbonate, but may also be selected from titanium dioxide, sand, clay, mica, dolomite, silica, talc, perlite, gypsum, wallastonite, aluminum trihydrate, zinc oxide, barium sulfate, zinc sulfate, and combinations thereof. The first component includes a first polymer containing hydroxyl functional groups or amine functional groups and, optionally, a catalyst, preferably an organotin catalyst. The first polymer is selected from a polyester polyol, an acrylic polyol, a urethane polyol, a polyether polyol, a polyamine, an aldimine, a short oil alkyd, a silicone polyol, a cellulose ester, a vinyl polyol, and combinations thereof and preferably is a polyaspartic ester.Type: GrantFiled: May 18, 1999Date of Patent: November 13, 2001Assignee: Armstrong World Industries, Inc.Inventors: Kenneth G. Caldwell, Raymond H. Fernando, Vijaya K. Pidugu
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Patent number: 6310136Abstract: Compositions of the invention are produced by blending hydroxy-functional polyesters with proteins at elevated temperatures. These compositions can be shaped into articles by known processes such as extrusion, compression molding, and injection molding. Among articles that can be made from such compositions are those with sufficiently strong tensile strengths as to form disposable utensils. However, the compositions are more environmentally friendly than commodity plastics such as polyethylene or polystyrene.Type: GrantFiled: July 28, 2000Date of Patent: October 30, 2001Assignees: The United States of America as represented by the Secretary of Agriculture, The Biotechnology Research & Development Corp.Inventors: Chaohua Wang, Craig J. Carriere
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Patent number: 6309707Abstract: The present invention relates to a coating composition comprising at least three components, characterized in that component (I) contains as binder at least one acrylate copolymer which is dissolved or dispersed in organic solvent and has a number-average molecular weight of between 1000 and 30,000, an OH number of from 40 to 200 and an acid number of from 5 to 150 and/or polyester resin having a number-average molecular weight of between 1000 and 30,000, an OH number of from 30 to 250 and an acid number of from 5 to 150 and/or polyurethane resin having a number-average molecular weight of between 1000 and 30,000, an OH number of from 20 to 200 and an acid number of from 5 to 150, and, if desired, a further binder, the binder components being selected such that a 50% strength solution of the binder in ethoxyethyl propionate has a viscosity at 23° C. of ≦2.Type: GrantFiled: December 20, 1996Date of Patent: October 30, 2001Assignee: BASF Coatings AGInventors: Bernd Mayer, Uwe Meisenburg, Egbert Nienhaus
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Publication number: 20010034405Abstract: An aqueous coating composition (especially a paint or varnish for buildings, vehicles, furniture and metal or plastics containers) which can form coatings on surfaces at ambient temperatures which on drying have improved early hardness and tack-resistance. The coating composition comprises water, optionally pigment and other conventional ingredients and dispersed particles of a highly non-crystalline polyester containing repeating hydroxyalkanoate units (preferably 3-hydroxybutyrate or 3-hydroxyvalerate or their copolymers). The polyester is non-crystalline to the extent that at least 60 wt % of the particles have a density of less than 102 % of Dmin where Dmin is the minimum density attainable by the polyester. The composition may also contain conventional film-forming polymers of the types used in aqueous paint or varnish.Type: ApplicationFiled: April 26, 2001Publication date: October 25, 2001Applicant: Imperial Chemical Industries Plc.Inventor: Philip L. Taylor
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Patent number: 6306956Abstract: The present invention is directed to an aqueous dispersion of a polyester salt and polymeric vehicles which include the aqueous dispersions of a polyester salt. The polymeric vehicle is particularly effective for providing coating binders in cured primer coatings. The primer coating compositions are useful for multilayer paint coating films which have at least two layers of paint film including the cured primer coating composition film. The use of the primer polymeric vehicles of the present invention in conjunction with one or more additional overlaying top coating film layers provide a multiple layer coatings having improved adhesion and chip resistance.Type: GrantFiled: September 24, 1999Date of Patent: October 23, 2001Assignee: McWhorter Technologies, Inc.Inventors: Gary Eugene Spilman, Michael Charles Knight, Jr., Lisa Kay Kemp, Joseph Leo Nothnagel
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Patent number: 6296920Abstract: The invention relates to a reversible thermotropic plastics molding compound. Thermotropic molding compounds of this kind are used, amongst other things, for glass and coverings for shading and light/heat regulation in houses, cars, etc. The molding compound according to the invention consists of two compounds which are not thermodynamically miscible with one another. The first component consists of a plastics material, while the second component is not liquid-crystalline and has a refractive index which is the same as the first component in the transparent range and the temperature dependency of which is different from the temperature dependency of the refractive index of the first component. On raising the temperature, the transmission of the molding compound is thus altered.Type: GrantFiled: August 27, 1999Date of Patent: October 2, 2001Assignee: EMS-Chemie AGInventors: Friedrich Buehler, Manfred Hewel
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Publication number: 20010012868Abstract: A solventless urethane adhesive layer which proves excellent oxygen and moisture barrier properties is formed from the reactio of A) a low molecular weight polyester formed from a single species of linear aliphatic diol and a single species of dicarboxylic acid with B) a single species of diisocyanate.Type: ApplicationFiled: March 14, 2001Publication date: August 9, 2001Inventors: Mai Chen, Jeffrey H. Deitch
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Publication number: 20010008911Abstract: An inkjet printing coating compositions and recording sheets having printable coating compositions on substrates which are suitable for photographic quality prints by inkjet printing technology, such as thermal and piezo. The recording sheet which comprises a substrate and a dried coating composition on the substrate, which coating composition comprises either (i) a hydrophilic or amphiphilic polyether polyurethane plus one or more polymers selected from the group consisting of cellulose ester polymers, cellulose ether polymers and vinyl polymers or (ii) cellulose acetate trimellitate plus optionally one or more polymers selected from the group consisting of cellulose ester polymers, cellulose ether polymers and vinyl polymers; a quaternary ammonium compound; a metal salt chelating agent; and a microcrystalline filler drying agent.Type: ApplicationFiled: January 29, 2001Publication date: July 19, 2001Applicant: AlliedSignal Inc.Inventors: Jyoti Sharma, David James Gibboni, Elizabeth Joyce Lanigan
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Patent number: 6262149Abstract: A water-based latex of an acrylic-modified waterborne alkyd dispersion in water is described. The acrylic-modified waterborne alkyd is a hybrid resin prepared by the polymerization of at least one ethylenically unsaturated monomer in the presence of a waterborne alkyd having at least one pendant sulfonate functionality. The ethylenically unsaturated monomer may also be a latent oxidatively functional (LOF) acrylic monomer. Preparation of the latexes may be achieved by emulsion polymerization of at least one ethylenically unsaturated monomer in the presence of a waterborne alkyd having at least one pendant sulfonate functionality. Preparation of hybrid latexes which contain latent oxidative functional (LOF) acrylic monomers may also be achieved by emulsion polymerization of at least one LOF acrylic monomer in the presence of a waterborne alkyd having at least one pendant sulfonate functionality whereby the latent oxidative functionality of the acrylic polymer survives polymerization.Type: GrantFiled: August 12, 1998Date of Patent: July 17, 2001Assignee: Eastman Chemical CompanyInventors: Mark D. Clark, Thauming Kuo, Rebecca R. Stockl, Glen D. Shields
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Patent number: 6262221Abstract: An improved polyamide resin composition for weldable molded articles which comprises: (a) 99.9-30% by weight of a polyamide-containing compound; (b) 0.1-20% by weight of a plasticizing compound selected from the group consisting of esters of low molecular weight poly(ethylene glycol) having the formula (I) R—COO—(CH2CH2O)n—OC—R (I) wherein R is a branched or straight chain alkyl group having from 1 to 40 carbon atoms, and n is 2 to 20; or a long chain alkyl polyester of formula (II) HOOC—R—CO—(O—R′—O—CO—R—CO)n—O—R′—OH (II) wherein R is alkyl of 16 to 45 carbon atoms, R′ is alkyl of 2 to 6 carbon atoms, or, wherein R is an alkyl of 2 to 6 carbon atoms, R′ is an alkyl of 16 to 45 carbon atoms, and n is 2 to 50.Type: GrantFiled: February 25, 1997Date of Patent: July 17, 2001Assignee: E. I. duPont de Nemours and CompanyInventor: Robert John Palmer
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Patent number: 6261676Abstract: An ultraviolet light absorbing material that resists blooming and migration is made up of a fluoropolymer and an amide functional ultraviolet light absorbing compound, wherein the polymer and the amide functional ultraviolet light absorbing compound are hydrogen bonded to one another. Polymeric films that contain a polymeric matrix and the ultraviolet light absorbing material are useful as the top layer in multilayer constructions such as retroreflective sheetings and conformable marking sheets.Type: GrantFiled: August 3, 1999Date of Patent: July 17, 2001Assignee: 3M Innovative Properties CompanyInventors: David B. Olson, David M. Burns, Bruce B. Wilson
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Patent number: 6251985Abstract: An aqueous coating composition including a combination of hydroxyl group-containing polyols and blocked polyisocyanate cross-linking agents, which dries preferably in pulverulent manner on the surface to be coated and, after stoving, affords coatings having a high resistance to water, chemicals and solvents, in particular on metallic substrates, and a process for the production of the coating composition.Type: GrantFiled: August 18, 1998Date of Patent: June 26, 2001Assignee: Bayer AktiengesellschaftInventors: Christian Wamprecht, Lothar Kahl, Bernd Klinksiek, Nusret Yuva
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Publication number: 20010003761Abstract: Disclosed is a formed article made of a biodegradable resin material which maintains strength sufficient for practical use and, when discarded after use, succumbs to decomposition by the action of microorganisms occurring in the physical world without bringing destruction on the physical environment or inducing public nuisance in consequence of the decomposition. The formed article is formed of a multicomponent polymer material comprising a continuous phase and a disperse phase; the continuous phase is made of a polybutylene succinate type and/or polyethylene adipate type aliphatic polyester and the disperse phase is made of polylactic acid. The continuous phase may comprise the aliphatic polyester containing such an inorganic filler as talc or calcium carbonate. The formed article of biodegradable resin constructed as described above may be manufactured in arbitrarily selected shapes and used for products in various fields, particularly for slide fasteners and separable fasteners.Type: ApplicationFiled: December 14, 1998Publication date: June 14, 2001Inventors: AKIRA ISHIBASHI, MAMORU TANAKA, MUTSUO HIROTA, YOSHIFUMI MIYAJIMA
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Patent number: 6239209Abstract: The polyurethane-acrylic hybrid interpenetrating polymer network is formed by blending a polyurethane prepolymer having acid or amine salt forming groups, air curable ethylenic unsaturation and terminal isocyanate groups or both terminal isocyanate groups and terminal vinyl groups, with one or more vinyl monomers, inert to isocyanate functionality, dispersing the prepolymer/vinyl monomer blend into water, chain extending the terminal isocyanate groups of the prepolymer with one or more active hydrogen containing compound, and reacting the vinyl monomers by free radical polymerization.Type: GrantFiled: February 23, 1999Date of Patent: May 29, 2001Assignee: Reichhold, Inc.Inventors: Shi Yang, Glenn Petschke
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Patent number: 6235816Abstract: A biologically degradable polymer mixture containing at least one biopolymer made from renewable raw materials and a polymer selected from the following materials: an aromatic polyester; a polyester-copolymer with both aliphatic and aromatic blocks; a polyesteramide; a polyglycol; a polyester urethane; and/or mixtures of these components. The preferred renewable raw material is starch, more preferably native starch, most preferably native starch that has been predried.Type: GrantFiled: October 27, 1999Date of Patent: May 22, 2001Assignee: Biotec Biologische Naturverpackungen GmbHInventors: Jurgen Lorcks, Winfried Pommeranz, Harald Schmidt
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Patent number: 6221955Abstract: A polyurethane resin consists of a reaction product of a phosphated polyol, a polyisocyanate and optionally a stabilizing monomer having a salt-forming group, for example, 2,2-dimethyolol propionic acid. The phosphated polyol may be a hydroxyl-terminated, phosphated polyester polyol which is a reaction product of a carboxylic acid, a polyol and a phosphate monomer. The phosphate monomer may be 2-phosphonobutane-1,2,4-tricarboxylic acid. The invention provides aqueous dispersions of phosphated polyurethane resins which are particularly suitable as metal primers for metals such as galvanised steel. The metal primers have improved adhesion under agressive enviroments.Type: GrantFiled: December 9, 1998Date of Patent: April 24, 2001Assignee: Dekro Paints (Proprietary) LimitedInventors: Kibret Mequanint, Ronald Douglas Sanderson
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Patent number: 6214916Abstract: A resin composition having laser marking properties from a NdYAG radiation laser wherein said composition comprises a polyester thermoplastic resin, a sufficient amount of light pigment for forming a light background coloration, and an effective amount of marking agent wherein said polyester thermoplastic resin decomposes in laser struck areas to form dark colored markings in laser struck areas on the light background coloration wherein the marking agent is selected from the group consisting of boron phosphate, zinc oxide, zinc stannate, zinc hydroxy stannate, tin (II) oxalate and mixtures thereof.Type: GrantFiled: April 29, 1998Date of Patent: April 10, 2001Assignee: General Electric CompanyInventors: Franciscus P. M. Mercx, Hendrik Verhoogt, Cor van der Zalm
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Patent number: 6211326Abstract: The invention relates to a process for preparing hydroxyl- and carboxyl-containing polyesterimide resins, comprising as monomeric components: (A) imide-forming compounds having at least two primary amino groups and/or at least two isocyanate groups or imide-forming compounds having at least one primary amino group and/or at least one isocyanate group and at least one further functional group selected from hydroxyl, carboxyl and/or carboxylic anhydride, (B) polycarboxylic acids and/or their anhydrides and/or their esters and (C) polyols, characterized in that (I) component (A) is reacted with part of component (B) to form a polyimide, (II) the polyimide obtained in accordance with stage (I) is reacted with component (C) to form a polyesterimide, and finally (III) the polyesterimide obtained in accordance with stage (II) is reacted with the remaining part of component (B) to form the Also embraced by the invention is the use of the polyesterimides prepared by the process according to the invention as biType: GrantFiled: July 13, 1999Date of Patent: April 3, 2001Assignee: Schenectady International, Inc.Inventors: Brian W. Glasper, Geoffrey C. Rix, Klaus-Wilhelm Lienert
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Patent number: 6197877Abstract: A dispersant of general Formula I T—(A)n(B)p—Z (1) wherein T is hydrogen or a polymerisation terminating group; Z is an acidic or basic group or a moiety containing either an acidic or basic group; A and B are each, independently, oxyalkylene carbonyl groups derivable from &dgr;-valerolactone, &egr;-caprolactone or alkyl substituted &egr;-caprolactone provided that both are not &egr;-caprolactone or &dgr;-valerolactone; n and p are integers; and n+p is from 2 to 100; including salts thereof. Specific examples of dispersants are the reaction product of lauric acid, &dgr;-caprolactone, 7-methyl-&egr;-caprolactone with PEI, the reaction product of lauric acid, &egr;-caprolactone, &dgr;-valerolactone with PEI and the phosphate of the reaction product of dodecanol, &egr;-caprolactone and &dgr;-valerolactone.Type: GrantFiled: April 30, 1999Date of Patent: March 6, 2001Assignee: Zeneca LimitedInventors: Dean Thetford, John David Schofield, Patrick John Sunderland