Conjugated Diene Hydrocarbon Monomer Patents (Class 524/571)
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Patent number: 6084025Abstract: A functionalized polymer prepared by a process comprising the steps of preparing a solution of a cyclic amine compound, an organolithium compound, and from 3 to about 300 equivalents, based upon one equivalent of lithium, of a monomer selected from the group including diene monomers, vinyl aromatic monomers, and mixtures thereof, where the cyclic amine compound is defined by the formula where R.sub.2 is selected from the group consisting of an alkylene, substituted alkylene, oxy- or N-alkylamino-alkylene group having from about 3 to about 16 methylene groups, N is a nitrogen atom, and H is a hydrogen atom, thereby forming a polymerization initiator having the formula where Li is a lithium atom, SOL is a divalent hydrocarbon group having from 3 to about 300 polymerized monomeric units, y is from 0.5 to about 3, and A is a cyclic amine radical derived from the cyclic amine, charging the solution containing (A)Li(SOL)y with from about 0.Type: GrantFiled: March 15, 1999Date of Patent: July 4, 2000Assignee: Bridgestone CorporationInventors: Takashi Kitamura, David F. Lawson, Koichi Morita, Yoichi Ozawa
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Patent number: 6071836Abstract: An electrical substrate material is presented comprising a thermosetting matrix of polybutadiene or polyisoprene in an amount of about 15 to about 50 volume %; a fabric reinforcement in an amount of 0 to about 40 volume %; a particulate filler, preferably ceramic, in an amount of from 0 to about 60 volume %; microballoons in an amount from 0 to about 60 volume %; and optionally a flame retardant. A peroxide cure initiator and/or crosslinking agent may optionally be added. The presence of a very high surface area particulate filler, preferably fumed silica, is also preferred, in that its presence results in a prepreg which has very little tackiness and can therefore be easily handled by operators. This low tackiness feature allows for the use of conventional automated layup processing, including foil cladding, using one or more known roll laminators.Type: GrantFiled: October 22, 1998Date of Patent: June 6, 2000Assignee: World Properties, Inc.Inventors: Michael E. St. Lawrence, Doris I. Hand
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Patent number: 6057392Abstract: A method is disclosed for processing a rubber composition comprising thermomechanically mixing the rubber composition while maintaining a rubber temperature in a range of from 160.degree. C. to 190.degree. C. for a period of time ranging from 4 to 8 minutes, wherein said rubber composition is characterized by(i) 100 parts by weight of at least one sulfur vulcanizable elastomer containing olefinic unsaturation;(ii) 10 to 250 phr of a filler selected from the group consisting of silica, carbon black and mixtures thereof; and(iii) 0.5 to 50 phr of an ester of the formula: ##STR1## wherein R.sup.1 is selected from the group consisting of alkyls having from 16 to 18 carbon atoms and alkenyls and alkadienyls having from 16 to 18 carbon atoms; and R.sup.2 is selected from the group consisting of alkyls having from 12 to 22 carbon atoms.Type: GrantFiled: February 17, 1998Date of Patent: May 2, 2000Assignee: The Goodyear Tire & Rubber CompanyInventors: Lawson Gibson Wideman, Paul Harry Sandstrom
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Patent number: 6057387Abstract: A method of making an aggregate comprising at least a carbon phase and a silicon-containing species phase is disclosed. The method involves introducing a first feedstock into a first stage of a multi-stage reactor, and introducing a second feedstock into the reactor at a location downstream of the first stage. The first and second feedstock comprise a carbon black-yielding feedstock, and at least one feedstock also comprises a silicon-containing compound. The reactor is operated at a sufficient temperature to decompose the silicon-containing compound and to pyrolize the carbon black-yielding feedstock. An additional method is disclosed which involves making an aggregate comprising a carbon phase and a silicon-containing species phase using multi-stage reactor having at least the stages for introducing a feedstock, wherein at least one of the feedstocks comprises a carbon black-yielding feedstock and wherein at least one of the feedstock comprises a silicon-containing compound.Type: GrantFiled: April 17, 1998Date of Patent: May 2, 2000Assignee: Cabot CorporationInventors: Khaled Mahmud, Meng-Jiao Wang
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Patent number: 6054524Abstract: This invention is based upon the unexpected discovery that aliphatic solvents and secondary plasticizers act to reduce the viscosity of plastisol compositions that contain a crosslinked nitrile rubber. It has been unexpectedly found that plastisol compositions having acceptable viscosities which contain more than 30 or even 40 percent crosslinked nitrile rubber can be made by incorporating an aliphatic solvent or an aliphatic plasticizer therein.Type: GrantFiled: September 9, 1998Date of Patent: April 25, 2000Assignee: The Goodyear Tire & Rubber CompanyInventors: Francois Jean-Marie Breton, Hung Dang Ngoc
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Patent number: 6048807Abstract: An electrical substrate material is presented comprising a thermosetting matrix which includes a polybutadiene or polyisoprene resin, an unsaturated butadiene- or isoprene-containing polymer and an ethylene propylene rubber; a particulate filler and, a fabric. Preferred ethylene propylene rubbers are ethylene propylene copolymers and ethylene propylene diene terpolymer rubbers wherein the diene is dicyclopentadiene. The ethylene propylene rubber is present in an amount of up to about 20 wt % with respect to the resin, preferably in an amount of about 1 to about 7 wt %, more preferably about 5 wt %. The presence of the ethylene propylene rubber enhances the dielectric strength of the resulting electrical substrate material, while other electrical, chemical, and mechanical properties of the material are not adversely effected.Type: GrantFiled: August 12, 1998Date of Patent: April 11, 2000Assignee: World Properties, Inc.Inventor: Vincent R. Landi
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Patent number: 6040377Abstract: A chloroprene rubber composition which contains carbon black and of which the breaking elongation A and the static modulus in shear B of the vulcanizate satisfy the following formula:A.gtoreq.-36.4.times.B+1090 (1)where A is the breaking elongation (%) and B is the static modulus in shear (kgf/cm.sup.2).Type: GrantFiled: February 18, 1999Date of Patent: March 21, 2000Assignee: Denki Kagaku Kogyo Kabushiki KaishaInventors: Nobuhiko Fujii, Mitsuyuki Nakada, Kazuomi Aoki
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Patent number: 6028137Abstract: Disclosed are elastomeric compounds including an elastomer and a silicon-treated carbon black, and optionally including a coupling agent. The elastomeric compound exhibits poorer abrasion resistance in the absence of a coupling agent, lower hysteresis at high temperature and comparable or increased hysteresis at low temperature compared to an elastomer containing an untreated carbon black. A variety of elastomers and formulations employing such elastomers are contemplated and disclosed. Elastomeric compounds incorporating an elastomer and an oxidized, silicon-treated carbon black are also disclosed. Also disclosed are methods for preparing elastomers compounded with the treated carbon black.Type: GrantFiled: August 14, 1997Date of Patent: February 22, 2000Assignee: Cabot CorporationInventors: Khaled Mahmud, Meng-Jiao Wang, Robert A. Francis, James A. Belmont
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Patent number: 6025450Abstract: A functionalized polymer includes a polymer chain carrying at least one functional group selected from alkyl, dialkyl and cycloalkyl amine radicals having the general formula ##STR1## and cyclic amine radicals having the general formula ##STR2## where R.sub.1 is an alkyl, cycloalkyl or aralkyl having from 1 to about 12 carbon atoms, and R.sub.2 is an alkylene, substituted alkylene, oxy- or N-alkylamino-alkylene group having from about 3 to about 16 methylene groups. The invention also provides products based upon such polymers.Type: GrantFiled: July 9, 1998Date of Patent: February 15, 2000Assignee: Bridgestone CorporationInventors: David F. Lawson, Mark L. Stayer, Jr., David Saffles, Koichi Morita, Yoichi Ozawa, Ryota Fujio, Thomas A. Antkowiak
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Patent number: 6020441Abstract: Polymers containing ethylenically unsaturated double bonds are hydroformylated by reacting aqueous dispersions of the polymers with hydrogen and carbon monoxide in the presence of suitable hydroformylation catalysts.Also provided are the polymer dispersions obtainable by this process and the hydroformylated polymers themselves.Type: GrantFiled: May 12, 1997Date of Patent: February 1, 2000Assignee: BASF AktiengesellschaftInventors: Edgar Zeller, Hartmann F. Leube, Bernhard Schlarb, Heinz-Josef Kneuper, Michael Roper
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Patent number: 6018015Abstract: The invention relates to belts made of thermoplastic polymer (A) and comprising a sufficient amount of a polymer (B) to render them antistatic, the said polymer (B) comprising polyethylene glycol blocks. Use is advantageously made of polymers (A) containing polyamide-6 (PA-6) or polyamide-12 (PA-12) blocks and polytetramethylene glycol blocks and polymers (B) containing PA-6 or PA-12 blocks and polyethylene glycol blocks.Type: GrantFiled: November 2, 1998Date of Patent: January 25, 2000Assignee: Elf Atochem S.A.Inventors: Patrick Alex, Jun Yamamoto
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Patent number: 6008272Abstract: Disclosed are elastomeric compounds including an elastomer and a silicon-treated carbon black, and optionally including a coupling agent. The elastomeric compound exhibits poorer abrasion resistance, lower hysterisis at high temperature and comparable or increased hysterisis at low temperature compared to an elastomer containing an untreated carbon black. Elastomeric compounds incorporating an elastomer and an oxidized, silicon-treated carbon black are also disclosed. Also disclosed are methods for preparing elastomers compounded with the treated carbon black.Type: GrantFiled: May 12, 1998Date of Patent: December 28, 1999Assignee: Cabot CorporationInventors: Khaled Mahmud, Meng-Jiao Wang, Robert A. Francis
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Patent number: 6004677Abstract: There is provided a process for producing polydienes, such as polybutadiene and polyisoprene, in a gas phase fluidized bed reactor using a pre-activated nickel catalyst which is highly active for cost effective production of these dienes in gas phase.Type: GrantFiled: August 8, 1997Date of Patent: December 21, 1999Assignee: Union Carbide Chemicals & Plastics Technology CorporationInventors: Kevin Joseph Cann, Maria Angelica Apecetche, Minghui Zhang
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Patent number: 5994434Abstract: An adhesion promoter composition containing a Zn, K, Al, Ti or Zr metal salt of an organic acid and at least one of a hydrous inorganic salt and an organic molybdenum compound. The adhesion promoter composition may be used to form an adherent rubber composition. The use of the adhesion promoter composition results in an adherent rubber composition which is stable and has a high adhesive force.Type: GrantFiled: February 26, 1998Date of Patent: November 30, 1999Assignees: Bridgestone Corporation, Japan Energy CorporationInventors: Osamu Uchino, Shinsuke Nakane, Kanji Fujiki, Toru Imori, Kazunori Iida
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Patent number: 5972811Abstract: An electrical substrate material is presented comprising a thermosetting matrix of polybutadiene or polyisoprene and a co-curable second resin distinct from the first resin. A peroxide cure initiator and/or crosslinking agent may optionally be added. The presence of a very high surface area particulate filler, preferably fumed silica, is also preferred, in that its presence results in a prepreg which has very little tackiness and can therefore be easily handled by operators. This low tackiness feature allows for the use of conventional automated layup processing, including foil cladding, using one or more known roll laminators. While the prepreg of this invention is tack-free enough to be handled relatively easily by hand, it is also tacky enough to be tacked to itself using a roll laminator (e.g., nip roller) at room temperature.Type: GrantFiled: June 4, 1998Date of Patent: October 26, 1999Assignee: World Properties, Inc.Inventors: Michael E. St. Lawrence, Doris I. Hand, Vincent R. Landi, Robert H. Walker, Samuel Gazit, Raymond R. Miskiavitch
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Patent number: 5965661Abstract: The invention pertains to a sulfur cross-linkable unvulcanized rubber mixture for the manufacture of treads, in particular for winter tires. The rubber mixture contains polyisoprene, polybutadiene and styrene-butadiene copolymer as well as further fillers and additives. In order to prepare vehicle pneumatic tires which exhibit excellent traction on ice and snow while at least maintaining their wet-gripping ability, the rubber mixture preferably contains, relative to 100 parts of total rubber, 20-100 parts by weight cis-1,4 polyisoprene; 0-65 parts by weight polybutadiene with a cis content of greater than about 90 mole %; and 0-65 parts by weight solution-polymerized styrene-butadiene copolymer; as well as 65-120 parts by weight silicic acid.Type: GrantFiled: December 19, 1997Date of Patent: October 12, 1999Assignee: Continental AktiengesellschaftInventors: Andre du Bois, Joachim Dumke, Anja Schneider, Wolfgang Loreth
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Patent number: 5959048Abstract: An acyclic alkane soluble anionic polymerization initiator includes a mixture of from about 90 to about 10 parts by weight of a lithio amine having the general formula A.sub.1 Li and from about 10 to about 90 parts by weight of at least one other lithio amine having the general formula A.sub.2 Li. A.sub.1 and A.sub.2 are selected from the dialkyl, alkyl, cycloalkyl and dicycloalkyl amine radicals and cyclic amine radicals. There is also provided a method of forming a mixture of anionic polymerization initiators, a functionalized polymer and a method of forming a functionalized polymer.Type: GrantFiled: July 1, 1997Date of Patent: September 28, 1999Assignee: Bridgestone CorporationInventors: David F. Lawson, James E. Hall, Yoichi Ozawa
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Patent number: 5948879Abstract: A maleimide-based copolymer containing maleimide monomer units (a-1), aromatic vinyl monomer units (a-2) and other vinyl monomer units (a-3), wherein,(I) the content of residual maleimide monomer in the copolymer is 0.1% by weight or less, and the content of whole volatiles other than the maleimide monomer is 0.5% by weight or less;(II) a compound obtained from at least one monomer selected from the group consisting of a maleimide monomer, an aromatic vinyl monomer and other vinyl monomers, having a weight-average molecular weight of from 200 to 1,000, is contained in an amount of 2 to 10% by weight;(III) the copolymer has a yellow index of 30 or less; and(IV) the copolymer has an intrinsic viscosity of from 0.3 to 1.5.Type: GrantFiled: October 24, 1997Date of Patent: September 7, 1999Assignee: Mitsubishi Rayon Co., Ltd.Inventors: Hiroshi Mori, Yasuaki Ii, Hisaya Yokohama, Yasunori Tsuneshige, Seizo Fujii, Takanori Nakazato
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Patent number: 5936029Abstract: The present invention provides a method of anionic synthesis of stable macrocyclic polymers that are compounded to form vulcanizable elastomeric compounds exhibiting reduced hysteresis properties. Cyclic organometallic compounds containing divalent metal atoms of Groups IIA and IIB of the Periodic System are employed as initiators of anionic polymerization of conjugated diene, vinyl aromatic and/or triene monomers. Coupling of the living ends of the resulting macrocyclic polymers or copolymers with a coupling agent or a coupling agent that is also a functionalizing agent results in stable macrocyclic polymers with improved hysteresis properties.Type: GrantFiled: September 29, 1997Date of Patent: August 10, 1999Assignee: Bridgestone CorporationInventor: James E. Hall
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Patent number: 5919857Abstract: A plastisol composition based on styrene copolymers, plasticizers and inorganic fillers contains, as styrene copolymers, copolymers which can be produced by emulsion polymerization and contain a) styrene and/or .alpha.-methyl styrene and/or p-methyl styrene and b) 3 to 20 wt.-% (relative to the copolymer) methacrylic acid and/or acrylic acid and/or itaconic acid. To increase the abrasion resistance, further crosslinkers or strengtheners can be added. The plastisols are suitable for use in motor vehicle construction as underseal material, as an adhesive for hood lining, as a compound for grille protection or as a spot-welding paste, and in the packaging products industry as a sealing compound for container closures or as a seam seal or as a flange-joint adhesive for tin cans.Type: GrantFiled: April 7, 1997Date of Patent: July 6, 1999Assignee: Teroson GmbHInventors: Klaus Ruch, Ingolf Scheffler
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Patent number: 5916962Abstract: A rubber composition having good breaking properties, high tan.delta., good wear resistance and a method for preparing a copolymer used in the rubber composition. The copolymer is a butadiene-styrene copolymer prepared in the presence of an organopotassium compound, an oxolanyl alkane and an organolithium initiator compound. The copolymer may be modified. A vulcanite of the rubber composition including 20 parts or more of the copolymer of the present invention has good properties.Type: GrantFiled: May 23, 1996Date of Patent: June 29, 1999Assignee: Bridgestone CorporationInventors: Tadashi Shibata, Ryota Fujio
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Patent number: 5916956Abstract: In a multi-stage process for producing a substantially unvulcanized elastomer composition, a masterbatch is produced by thermomechanical working in a first or other early stage of the multi-stage process. The masterbatch comprises sulfur crosslinkable hydrocarbon elastomer in which is substantially dispersed, particulate fillers, for example carbon black or silicon-treated carbon black, modified carbon black and/or silica and sulfur crosslinking agent effective to crosslink the hydrocarbon elastomer and selected from sulfur donors and sulfur. The filler and sulfur crosslinking agent can be mixed together as a pre-blend prior to being added to the elastomer. The substantially unvulcanized elastomer is then produced in one or more later stages of the multi-stage process, involving further theromechanical working of the masterbatch. A curative additive comprising accelerator, and optionally additional sulfur crosslinking agent, is added and dispersed in the elastomer in the last stage of the multistage process.Type: GrantFiled: January 16, 1997Date of Patent: June 29, 1999Assignee: Cabot CorporationInventors: Meng-Jiao Wang, Trevor Alan Brown, Ralph E. Dickinson
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Tire tread of diene rubber, and naphthenic and/or paraffinic oil, or aromatic oil and mineral filler
Patent number: 5905112Abstract: A tire comprising a tire tread and a tire tread is disclosed wherein the tire tread is prepared from a tread rubber such as an AB block copolymer comprising from 40 to 80%-wt of block A obtained from butadiene having a uniformly distributed vinyl group content of from 8 to 60%-wt based on the total block A content, and from 20 to 60%-wt of block B derived from butadiene, isoprene and styrene; and a combination of naphthenic and/or paraffinic oil and a filler of carbon black, a mineral filler such as silica or a mixture thereof, or a blend of an aromatic oil and a mineral filler.Type: GrantFiled: April 2, 1997Date of Patent: May 18, 1999Assignee: Huels AktiengesellschaftInventor: Walter Hellermann -
Patent number: 5895798Abstract: A liquid rubber composition including a 1,2-polybutadiene resin component dispersed in the form of fine particles in a liquid rubber component in a weight ratio of 1:100 to 50:100 has a high dispersion stability and a low specific gravity and is useful for forming a cured rubber article having a high elastic modulus and a satisfactory mechanical strength and ultimate elongation.Type: GrantFiled: October 6, 1997Date of Patent: April 20, 1999Assignee: Ube Industries, Ltd.Inventors: Naomi Okamoto, Takeshi Shoda
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Patent number: 5883183Abstract: The present invention is directed toward anionic polymerization employing lithio amines mixed with an organic alkali metal compound and optionally, a chelating reagent. The lithio amines have the general formula (A)Li(SOL)y, where SOL is a solubilizing component, A is an alkyl, dialkyl, cycloalkyl or dicycloalkyl amine radical or a cyclic amine, and y is 0 or is from about 0.5 to about 3. The invention is also directed toward polymers and other products made using the initiator, and methods therefor. Further, the invention contemplates a polymer, a polymer composition and products therefrom, which include a functional group from the reaction product of an amine and an organolithium compound. The resulting polymers may be terminated with a terminating, coupling or linking agent, which may provide the polymer with a multifunctionality.Type: GrantFiled: June 6, 1995Date of Patent: March 16, 1999Assignee: Bridgestone CorporationInventors: Takashi Kitamura, David F. Lawson, Koichi Morita, Yoichi Ozawa
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Patent number: 5879805Abstract: A process for the preparation of a 1,2-vinyl-polybutadiene with an adjustable amount of vinyl linkages in the microstructure of the polymer which comprises polymerizing 1,3-butadiene in a gas phase reactor under polymerization conditions using an inert gas in the presence of a catalyst comprising: (a) a cobalt compound; (b) a compound selected from the group consisting of a phosphine, a xanthogen, a thiocyanide, a carbon disulfide, and mixtures thereof; and (c) an organoaluminum compound, and optionally a modifier (d) can be included in the catalyst composition. There is also provided a novel resin particle prepared by the process.Type: GrantFiled: September 9, 1997Date of Patent: March 9, 1999Assignee: Union Carbide Chemicals & Plastics Technology CorporationInventors: Monika Brady, Kevin Joseph Cann
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Patent number: 5877336Abstract: Triorgano substituted-tin lithium initiators are made in a dimethyl ether solvent. The substitution of dimethyl ether as the solvent for the traditional tetrahydrofuran solvent results in an initiator for anionic polymerizations that can produce less 1,2-vinyl repeat units. The dimethyl ether is also easier to remove from the polymerization media because it has a boiling point at one atmosphere of minus 24.8.degree. C. and thus is a gas at 25.degree. C.Type: GrantFiled: December 31, 1996Date of Patent: March 2, 1999Assignee: Bridgestone CorporationInventors: William L. Hergenrother, Tristram W. Bethea
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Patent number: 5859120Abstract: Carbon blacks containing silicon and a process for manufacturing them. The carbon blacks containing silicon are suitable as reinforcing carbon blacks for rubber mixtures and give the latter viscoelastic properties such as reduced rolling resistance in tires. At the same time, the wet traction is even improved in the process.Type: GrantFiled: March 25, 1997Date of Patent: January 12, 1999Assignee: Degussa AktiengesellschaftInventors: Alfons Karl, Burkhard Freund, Karl Vogel
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Patent number: 5858887Abstract: An electrical substrate material is presented comprising a thermosetting matrix of polybutadiene or polyisoprene in an amount of 25 to 50 volume %; a woven glass fabric in an amount of 10 to 40 volume %; a particulate, preferably ceramic filler, in an amount of from 5 to 60 volume %; and a flame retardant. Importantly, the composition comprises only a single resin, i.e., polybutadiene or polyisoprene. A peroxide cure initiator and/or crosslinking agent may optionally be added. The presence of a very high surface area particulate filler, preferably fumed silica, is also preferred, in that its presence results in a prepreg which has very little tackiness and can therefore be easily handled by operators. This low tackiness feature allows for the use of conventional automated layup processing, including foil cladding, using one or more known roll laminators.Type: GrantFiled: August 1, 1996Date of Patent: January 12, 1999Assignee: World Properties, Inc.Inventors: Michael E. St. Lawrence, Doris I. Hand
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Patent number: 5854335Abstract: A bituminous composition which comprises a bituminous component and a block copolymer of a conjugated diene and a monovinylaromatic hydrocarbon, wherein the block copolymer has a vinyl content of at least 25% by weight based on the total diene content and a diblock content of 25 wt % or less, whereas the diblock has an apparent molecular weight which is in the range of from 100,000 to 170,000, is of use particularly in roofing applications.Type: GrantFiled: April 30, 1997Date of Patent: December 29, 1998Assignee: Shell Oil CompanyInventors: Gerardus Wilhelmus Jozef Heimerikx, Aloysius Josephus Atoius Maria Van Hoek, Cornelis Petrus Valkering, Jeroen Van Westrenen
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Patent number: 5830983Abstract: The invention relates to belts made of thermoplastic polymer (A) and comprising a sufficient amount of a polymer (B) to render them antistatic, the said polymer (B) comprising polyethylene glycol blocks. Use is advantageously made of polymers (A) containing polyamide-6 (PA-6) or polyamide-12 (PA-12) blocks and polytetramethylene glycol blocks and polymers (B) containing PA-6 or PA-12 blocks and polyethylene glycol blocks.Type: GrantFiled: December 23, 1996Date of Patent: November 3, 1998Assignee: Elf Atochem S.A.Inventors: Patrick Alex, Jun Yamamoto
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Patent number: 5830930Abstract: Disclosed are elastomeric compounds including an elastomer and a silicon-treated carbon black, and optionally including a coupling agent. The elastomeric compound exhibits poorer abrasion resistance, lower hysterisis at high temperature and comparable or increased hysterisis at low temperature compared to an elastomer containing an untreated carbon black. Elastomeric compounds incorporating an elastomer and an oxidized, silicon-treated carbon black are also disclosed. Also disclosed are methods for preparing elastomers compounded with the treated carbon black.Type: GrantFiled: May 22, 1995Date of Patent: November 3, 1998Assignee: Cabot CorporationInventors: Khaled Mahmud, Meng-Jiao Wang, Robert A. Francis
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Patent number: 5807941Abstract: An saturated nitrile-conjugated diene copolymer obtained by copolymerizing acrylonitrile with butadiene in the presence of a free radical initiator and an alkylthiol compound as a molecular weight modifier. A part of the molecular weight modifier is incorporated in a monomer charge before polymerization, and the remainder thereof is incorporated in a polymerization mixture during polymerization. The alkylthiol compound has 12 to 16 carbon atoms, which include at least three tertiary carbon atoms, and further has a sulfur atom directly bound to at least one of the tertiary carbon atoms. The copolymer has a Mooney viscosity of 15 to 150 and contains 3 to 20 weight % of a fraction having a number average molecular weight of not larger than 35,000. The copolymer is used in combination with a sulfur-containing vulcanizer.Type: GrantFiled: February 28, 1997Date of Patent: September 15, 1998Assignee: Nippon Zeon Co., Ltd.Inventors: Suguru Tsuji, Yuichi Uchizono
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Patent number: 5804661Abstract: An EPDM flashing composition comprises 100 parts by weight of an elastomeric polymer comprising from about 85 to 100 parts by weight of at least one ethylene-propylene-diene terpolymer having up to about 2 percent by weight crystallinity and from 0 to about 15 parts by weight of an ethylene-propylene-diene terpolymer having more than 2 percent by weight crystallinity; from about 40 to 120 parts by weight of a filler selected from the group consisting of reinforcing and non-reinforcing materials and mixtures thereof, per 100 parts of the polymer; from about 40 to 105 parts by weight of a processing material and mixtures thereof, per 100 parts of the polymer; and from about 0.5 to 6 parts by weight of a cure package, per 100 parts of the polymer, the cure package comprising from about 0.1 to 1.25 parts by weight sulfur and from 0.4 to 5 parts by weight of at least one sulfur vulcanizing accelerator and being devoid of hexasulfides and thioureas.Type: GrantFiled: February 21, 1996Date of Patent: September 8, 1998Assignee: Bridgestone/Firestone, Inc.Inventors: James A. Davis, Joseph J. Kalwara, Brian S. Alexander
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Patent number: 5798175Abstract: A pressure sensitive adhesive composition comprising a natural or synthetic rubber and a thermoplastic polyolefin blend comprising ethylene-propylene rubber, hydrogenated polyisoprene and polypropylene.Type: GrantFiled: January 31, 1997Date of Patent: August 25, 1998Assignee: American Tape CompanyInventors: John K. Tynan, Jr., Deborah Anne Chrzanowski
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Patent number: 5798416Abstract: Provided is an automobile vibration-isolating rubber composition, characterized in that a rubber component comprises from 10 to 80% by weight of a polybutadiene rubber which is obtained through the polymerization using a rare-earth element catalyst and which has a cis content of 97% or more, and from 90 to 20% by weight of at least one type of a rubber selected from a natural rubber, a synthetic polyisoprene rubber and a polystyrene-butadiene copolymer rubber. The automobile vibration-isolating rubber obtained by vulcanizing the rubber composition of the present invention has a low dynamic factor compared to the conventional product, making it possible to decrease automobile passenger compartment noise caused by road noise.Type: GrantFiled: July 11, 1996Date of Patent: August 25, 1998Assignee: Toyo Tire & Rubber Co., Ltd.Inventors: Tsuneo Kamata, Makoto Niki, Yoshihide Ueda
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Patent number: 5789463Abstract: An ocular lens material comprising a copolymer obtained by copolymerizing a copolymerizable composition of which the main components are a diene polymer and a monomer capable of copolymerizing with the diene polymer, having high oxygen permeability, high refractive index and high mechanical strength, and being excellent in flexibility and shape recoverability, and its production process are disclosed.Type: GrantFiled: September 3, 1997Date of Patent: August 4, 1998Assignee: Tomey Technology CorporationInventors: Kiyotaka Odagiri, Takuo Kato
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Patent number: 5763388Abstract: A process for the incorporation of silica into a polymer in latex in which a silica is treated with an organo silicon compound coupling agent in aqueous suspension to form a compatibilized silica and then contacting a polymer latex with the compatibilized silica whereby the silica becomes substantially uniformly distributed throughout the latex and can be recovered when the latex is coagulated to yield little residual silica in the liquid residue from the latex. Also described is a process for preparing the compatibilized silica.Type: GrantFiled: December 18, 1996Date of Patent: June 9, 1998Assignee: DSM Copolymer, Inc.Inventors: John W. Lightsey, David J. Kneiling, John M. Long
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Patent number: 5756589Abstract: The present invention relates to a rubber composition containing substantial silica reinforcement and pneumatic tires having treads comprised of such rubber composition. The rubber composition comprises an elastomer, substantial silica reinforcement, optionally a minor amount of carbon black reinforcement, and a triblock copolymer of terminal hard styrene based segments and of internal diene based elastomer segments.Type: GrantFiled: September 19, 1996Date of Patent: May 26, 1998Assignee: Goodyear Tire & Rubber CompanyInventors: Paul Harry Sandstrom, David John Zanzig, Mark Samuel Sinsky
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Patent number: 5733958Abstract: The addition of a chlorinated alkyl phosphate oil to a natural latex emulsion has enabled the formulation of water-based contact cements with the ability to instantly bond porous substrates together. The adhesives offer the user of solvent based contact cements an alternative more practical than hot melts, two-part water-based, or slower setting one-part water-based adhesives in industries where the immediate assembly of porous substrates is necessary.Type: GrantFiled: January 23, 1997Date of Patent: March 31, 1998Assignee: Worthen Industries, Inc.Inventors: Steven E. Adams, Ian L. Churcher, Michael L. Magee, Gary A. Groat
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Patent number: 5723533Abstract: An acyclic alkane soluble anionic polymerization initiator includes a mixture of from about 90 to about 10 parts by weight of a lithio amine having the general formula A.sub.1 Li and from about 10 to about 90 parts by weight of at least one other lithio amine having the general formula A.sub.2 Li. A.sub.1 and A.sub.2 are selected from the dialkyl, alkyl, cycloalkyl and dicycloalkyl amine radicals and cyclic amine radicals. There is also provided a method of forming a mixture of anionic polymerization initiators, a functionalized polymer and a method of forming a functionalized polymer.Type: GrantFiled: November 26, 1996Date of Patent: March 3, 1998Assignee: Bridgestone CorporationInventors: David F. Lawson, James E. Hall, Yoichi Ozawa
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Patent number: 5719207Abstract: The present invention relates to a silica reinforced rubber composition and to pneumatic tires having treads comprised of the silica reinforced rubber compositions.The silica reinforced rubber composition comprises at least one elastomer, silica, a silica coupler, a silylating agent and, optionally, carbon black.Type: GrantFiled: March 18, 1996Date of Patent: February 17, 1998Assignee: The Goodyear Tire & Rubber CompanyInventors: Martin Paul Cohen, John Pennington Lawrence, Cheryl Ann Losey
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Patent number: 5716702Abstract: Disclosed herein is a packaging system comprising predispersed chemicals in preweighed quantities embedded in multiple separated compartments of a masterbatch.Type: GrantFiled: September 25, 1995Date of Patent: February 10, 1998Assignee: Rhein Chemie CorporationInventors: Walter H. Schuette, Anders H. Johansson
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Patent number: 5691408Abstract: A process for manufacturing a water based adhesive which is substantially free of organic solvents and is useful as an adhesive for bonding natural rubber compounds, synthetic rubber compounds and a combination of natural and synthetic rubber compounds, especially during the formation of a tire.Type: GrantFiled: March 7, 1996Date of Patent: November 25, 1997Assignee: Akron Paint & VarnishInventor: Robert J. Murray
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Patent number: 5672639Abstract: The present invention relates to a rubber composition containing a starch/plasticizer composite and to pneumatic tires having at least one component comprised of such rubber composition. Such tire component can be, for example, its circumferential tread or other component of the tire.The starch/plasticizer composite can be a composite of starch and plasticizer such as, for example, poly(ethylenevinyl alcohol) and/or cellulose acetate or any suitable plasticizer which results in such starch/plasticizer composite having a melting point below that of the starch alone, and particularly below about 160.degree. C., and to thereby enable the starch to be more processable with conventional elastomer composition processing equipment.Type: GrantFiled: March 12, 1996Date of Patent: September 30, 1997Assignee: The Goodyear Tire & Rubber CompanyInventors: Filomeno Gennaro Corvasce, Tom Dominique Linster, Georges Thielen
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Patent number: 5668209Abstract: A plastisol composition based on styrene copolymers, plasticizers and inorganic fillers contains, as styrene copolymers, copolymers which can be produced by emulsion polymerization and contain a) styrene and/or .alpha.-methyl styrene and/or p-methyl styrene and b) 3 to 20 wt.-% (relative to the copolymer) methacrylic acid and/or acrylic acid and/or itaconic acid. To increase the abrasion resistance, further crosslinkers or strengtheners can be added. The plastisols are suitable for use in motor vehicle construction as underseal material, as an adhesive for hood lining, as a compound for grille protection or as a spot-welding paste, and in the packaging products industry as a sealing compound for container closures or as a seam seal or as a flange-joint adhesive for tin cans.Type: GrantFiled: February 14, 1996Date of Patent: September 16, 1997Assignee: Teroson GmbHInventors: Klaus Ruch, Ingolf Scheffler
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Patent number: 5652298Abstract: The present invention provides an organic solvent-free composition useful as an adhesive for bonding natural rubber compounds, synthetic rubber compounds and a combination of natural and synthetic rubber compounds.Type: GrantFiled: July 24, 1996Date of Patent: July 29, 1997Assignee: Akron Paint & VarnishInventor: Robert Murray
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Patent number: 5648419Abstract: The invention comprises processes for the production of useful fluid or grease from curable silicone compositions or silicone rubbers, preferably reclaimed or scrap silicone rubber. The processes involve the application of energy in such a manner that a un-curable silicone grease or liquid that contains essentially all of the original material is produced from curable silicone compositions and grease or liquid is produced from silicone rubbers. Suitable energy forms include thermal and mechanical. The fluid or grease produced by the processes are useful as raw materials for the manufacture of silicone products such as: antifoam compounds (defoamers), greases, conformal coatings or rubbers. The materials produced by these processes were unexpectedly found to have exceptional antifoam properties without requiring the addition of other materials or further processing.Type: GrantFiled: October 7, 1996Date of Patent: July 15, 1997Assignee: Genesee Polymers CorporationInventor: Steven S. Kendall
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Patent number: 5618882Abstract: Gel compositions comprising styrene-(ethylene/propylene)styrene (SEPS) block copolymer having Mw of at least 180,000 and polystyrene content of 25-45 weight percent, and at least 300 parts by weight percent, and at least 300 parts by weight of extender liquid per 100 parts by weight of the block copolymer. The extender softens the ethylene/propylene mid-blocks of the copolymer and the resulting gels have unexpectedly higher tack, temperature resistance, and extender-retaining ability than corresponding gels made with styrene(ethylene/butylene)-styrene block copolymers.Type: GrantFiled: November 14, 1994Date of Patent: April 8, 1997Assignee: Raychem LimitedInventors: Philip J. Hammond, John M. Hudson, Hendrik Graulus
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Patent number: 5612407Abstract: A process of making a solvent-free water-based emulsion of an anionically polymerized polymer which comprises: heating the polymer until its viscosity is no more than 3,000 centipoise, (b) mixing water with a surfactant, (c) adding the mixture of (b) to the polymer of (a) while agitating the polymer at high speed, thereby forming an emulsion, (d) cooling the emulsion to below 100.degree. C., and (e) optionally subjecting the emulsion to turbulent flow and/or cavitation. Also included are emulsions of such polymers.Type: GrantFiled: February 20, 1996Date of Patent: March 18, 1997Assignee: Shell Oil CompanyInventor: Jeffrey G. Southwick