Natural Rubber Patents (Class 524/575.5)
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Patent number: 12071568Abstract: The present invention relates to adhesive mixtures containing resorcinol and/or resorcinol esters, melamine formaldehyde ethers and sulfenamide derivatives and also silica for use in rubbers, to the production thereof, to vulcanizates and composite articles produced therefrom and to the use thereof.Type: GrantFiled: July 22, 2019Date of Patent: August 27, 2024Assignee: LANXESS Deutschland GmbHInventors: Hermann-Josef Weidenhaupt, Melanie Wiedemeier-Jarad, Stephan Meese, Jens-Hendrik Fischer, Nele De Smet
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Patent number: 12060487Abstract: A tire comprises a rubber composition based on at least a rubber crumb, a diene elastomer, a pro-oxidant, a reinforcing filler and a crosslinking system, said rubber crumb representing 30% by mass or more of the composition, and exhibiting a ratio of the chloroform extract to the acetone extract of less than 2, the chloroform and acetone extracts being expressed as percentages by mass.Type: GrantFiled: December 13, 2019Date of Patent: August 13, 2024Assignee: COMPAGNIE GENERALE DES ETABLISSEMENTS MICHELINInventors: Nathalie Coste, Severin Dronet, Guillaume Hennebert
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Patent number: 11794530Abstract: A tire with in-situ generated intrinsic puncture sealant layers and intrinsic noise damper comprising a supporting tire carcass having one or more layers of ply, an outer circumferential tread, and a radially inner layer, a pair of beads, sidewalls extending radially inward from the axial outer edges of a tread portion to join the respective beads, a sealant comprising at least one layer of sealant, disposed radially inwardly from said radially inner layer of said tire carcass, an intrinsic cellular noise damper as the innermost layer adjacent to the sealant, wherein said noise damper has a density less than 1.3 g/cm3; and wherein said sealant provides self-sealing properties to the tire.Type: GrantFiled: February 15, 2021Date of Patent: October 24, 2023Assignee: Triangle Tyre Co. Ltd.Inventors: Ramendra Nath Majumdar, Wang Dapeng
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Patent number: 11781020Abstract: Composite particles may be produced by drying slurries containing silica particles and graphenic carbon particles in a liquid carrier. Elastomeric formulations comprising a base elastomer composition and the silica-graphenic carbon composite particles are also disclosed. The formulations possess favorable properties such as increased stiffness and are useful for many applications such as tire treads.Type: GrantFiled: August 10, 2020Date of Patent: October 10, 2023Assignee: PPG Industries Ohio, Inc.Inventors: Lucas Dos Santos Freire, Qi Ding, Cynthia Kutchko, Shuyang Pan, Nathan J. Silvernail
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Patent number: 11738599Abstract: The introduction of graphene as an additive in rubber compounds is disclosed. The product shows increased barrier protection for tire innerliners, with no tradeoffs in other characteristics.Type: GrantFiled: July 15, 2022Date of Patent: August 29, 2023Inventors: Douglas Paschall, Adel F. Halasa, Michael Brendan Rodgers
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Patent number: 11732111Abstract: A natural rubber composition includes a base resin including natural rubber, a filler including carbon black and silica, and an additive. The carbon black has a diameter of 20 nm to 50 nm, and the silica has a surface area of 100 to 150 m2/g. The additive includes at least one of a coupling agent, an activator, a crosslinking agent, an accelerator, or an anti-aging agent.Type: GrantFiled: July 14, 2021Date of Patent: August 22, 2023Assignees: Hyundai Motor Company, Kia CorporationInventors: Sung Hyun Lee, Hyun Ho Park, Jae Seok Lee
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Patent number: 11653668Abstract: A chewing gum base comprises rubber derived from Russian Dandelion (TKS). Methods of extracting and purifying the rubber are provided. Gum base compositions and methods of compensating for variable ratios of elastomer:resin in the rubber are disclosed.Type: GrantFiled: September 29, 2017Date of Patent: May 23, 2023Assignee: WM. WRIGLEY JR. COMPANYInventors: David R. Phillips, Xiaohu Xia
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Patent number: 11597821Abstract: The introduction of graphene as an additive in truck tire treads is disclosed. The product shows increased electrical resistance in tire treads, with no tradeoffs in other characteristics.Type: GrantFiled: July 14, 2022Date of Patent: March 7, 2023Inventors: Douglas Paschall, Adel F. Halasa, Michael Brendan Rodgers
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Patent number: 11572458Abstract: A rubber composition is based on at least one elastomer comprising epoxide functions, a crosslinking system comprising a polycarboxylic acid and an imidazole and at least one phenolic compound, the aromatic nucleus of said phenolic compound being substituted with at least a carboxyl group, a hydrogenocarbonyl group, an amino group or an aminoalkyl radical.Type: GrantFiled: December 11, 2018Date of Patent: February 7, 2023Assignee: COMPAGNIE GENERALE DES ETABLISSEMENTS MICHELINInventors: Anne-Lise Thuilliez, Odile Gavard-Lonchay
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Patent number: 11292149Abstract: A new composition has been invented which for restores the appearance of finished wood surfaces. The composition includes between 20 and 40%, by volume, of at least two oils; between 60 and 80%, by volume, of an organic, nonpolar solvent; and, at least two colorants, with a first colorant comprising about twice, by volume of a second colorant. The at least two oils may be any combination of tung oil, boiled linseed oil, and, olive oil, preferably all three are present. The organic, nonpolar solvent may be high grade mineral spirits. The first colorant may be yellow oxide and the second colorant may be raw umber.Type: GrantFiled: May 3, 2019Date of Patent: April 5, 2022Inventor: Eric Trindl
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Patent number: 11118020Abstract: Disclosed herein is method for preparing a masterbatch by dispersing chemically modified cellulose nanofibers having carboxy groups under acidic conditions and then mixing the dispersed cellulose nanofibers with rubber latex. More specifically, the present disclosure provides a method for producing a masterbatch, including: (A) a step of introducing a carboxy group to a cellulose-based raw material to prepare a modified cellulose; (B) a step of carrying out defibration treatment and dispersion treatment of the modified cellulose to prepare a cellulose nanofiber; (C) a step of acidifying the cellulose nanofiber to prepare an acid type cellulose nanofiber; and (D) a step of mixing the acid type cellulose nanofiber and a rubber component. The rubber composition having excellent strength such as tensile strength can be provided by using the obtained masterbatch.Type: GrantFiled: December 21, 2016Date of Patent: September 14, 2021Assignee: NIPPON PAPER INDUSTRIES CO., LTD.Inventors: Kotaro Ito, Yusuke Yasukawa
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Patent number: 10850563Abstract: Provided is a pneumatic tire having excellent chipping resistance. The present invention relates to a pneumatic tire formed from a rubber composition, the rubber composition having an elongation at break of 540% or higher as measured under the following test conditions: Tensile rate: 8.3 m/sec, Temperature: 75° C., Specimen: No. 3 dumbbell.Type: GrantFiled: February 16, 2018Date of Patent: December 1, 2020Assignee: SUMITOMO RUBBER INDUSTRIES, LTD.Inventors: Tetsuya Maekawa, Shinichiro Honda
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Patent number: 10753053Abstract: Desired combinations of physical properties can be achieved with a pavement marking composition including non-crosslinked elastomeric materials dispersed within a polymeric material. Notably, the pavement marking composition does not include any reinforcing materials, such as, for example, ceramic fibers, asbestos, silicon dioxide, and/or talc. Despite the lack of reinforcing materials, the pavement marking composition has good tensile strength in both the downweb and crossweb directions.Type: GrantFiled: November 21, 2011Date of Patent: August 25, 2020Assignee: 3M Innovative Properties CompanyInventor: Thomas P. Hedblom
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Patent number: 10710408Abstract: A rubber compound for treads comprising a styrene-butadiene rubber (SBR), carbon black and a vulcanization system. The filler comprises 5 to 30 phr of a thermoplastic polymer, preferably polylactic acid, having a Tg ranging from 50 to 70° C., a molecular weight (Mw) not exceeding 200,000 g/mol and a crystallinity not exceeding 0%.Type: GrantFiled: August 31, 2016Date of Patent: July 14, 2020Assignee: BRIDGESTONE CORPORATIONInventors: Gianluca Forte, Claudia Aurisicchio, Giammatteo Gaeta
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Patent number: 10667957Abstract: A bandage comprising a base substrate, a wound covering portion, a first side coupling member and a second side coupling member, and a first side and second side adhesive portion. The base substrate includes a central region, a first side region and a second side region, and comprises an elastic member. The wound covering portion is positioned over the central region. The first side coupling member extends over the first side region. The second side coupling member extending over the second region. The first side adhesive portion is positioned on the first side region. The second side adhesive portion positioned on the second side region. A method of use as well as a protective carrier are likewise disclosed.Type: GrantFiled: November 11, 2016Date of Patent: June 2, 2020Assignee: BANDGRIP, INC.Inventors: Fred Smith, Keith Hoglund, Tom Pruter
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Patent number: 10479843Abstract: The present invention provides a method for producing natural rubber with which the odors of solid natural rubber is easily reduced, and further which does not degrade physical properties such as heat aging resistance. The present invention relates to a method for producing natural rubber, the method including a sheeting step including sheeting a non-deproteinized solid natural rubber to form a natural rubber sheet, the natural rubber sheet having a moisture content of 20% or less.Type: GrantFiled: March 17, 2016Date of Patent: November 19, 2019Assignee: SUMITOMO RUBBER INDUSTRIES, LTD.Inventors: Ai Matsuura, Lucksanaporn Tarachiwin, Kamalin Kanyawararak, Hironori Inamoto, Noa Kaneko
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Patent number: 10138359Abstract: The present invention aims to provide rubber compositions for tires that contain a natural rubber achieving a balanced improvement in abrasion resistance, breaking performance, and processability to achieve a balanced improvement in abrasion resistance, breaking performance, and processability, and also provide pneumatic tires containing such rubber compositions for tires. Included is a rubber composition for tires comprising a modified natural rubber prepared by treating natural rubber latex with a proteolytic enzyme, and then treating the treated natural rubber latex with a lipolytic enzyme and/or a phospholipid degrading enzyme. Also included is a rubber composition for tires, comprising a modified natural rubber prepared by centrifuging natural rubber latex to recover a latex fraction comprising latex particles having an average particle size of 0.25 ?m or less.Type: GrantFiled: September 24, 2015Date of Patent: November 27, 2018Assignee: SUMITOMO RUBBER INDUSTRIES, LTD.Inventors: Ai Matsuura, Lucksanaporn Tarachiwin, Hathainat Kum-Ourm
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Patent number: 9920150Abstract: A process is described for the production of phosphorus-containing organic polymers through reaction of dialkyl phosphites with organic polymers comprising carbon-carbon double bonds in the presence of organic compounds that form free radicals under the reaction conditions, with covalent linkage of the phosphorus atom of the dialkyl phosphite to a carbon atom of the organic polymer.Type: GrantFiled: June 6, 2014Date of Patent: March 20, 2018Assignee: BASF SEInventors: Alexander Koenig, Konrad Knoll
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Patent number: 9862814Abstract: Provided are pneumatic tires or studless winter tires that achieve a balanced improvement in fuel economy, reinforcing properties (flex crack growth resistance, abrasion resistance, tensile strength, adhesive strength, resistance to air permeation), grip performance (wet-grip performance, performance on snow and ice), handling stability, and heat aging resistance, and methods for producing such a pneumatic tire or studless winter tire. The present invention relates to a pneumatic tire including at least one component selected from the group consisting of a sidewall, a base tread, a bead apex, a clinch apex, an innerliner, and an undertread, each of which is formed from a rubber composition that contains a highly purified, modified natural rubber whose pH is adjusted to 2 to 7, and carbon black and/or a white filler.Type: GrantFiled: May 12, 2014Date of Patent: January 9, 2018Assignee: SUMITOMO RUBBER INDUSTRIES, LTD.Inventors: Toshiaki Sakaki, Yuka Yokoyama
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Patent number: 9757983Abstract: This invention relates to a tire having a rubber component, such as a tread. with filler reinforcement containing surface modified graphene and precipitated silica which may be or may include pre-hydrophobated precipitated silica.Type: GrantFiled: June 7, 2016Date of Patent: September 12, 2017Assignee: The Goodyear Tire & Rubber CompanyInventors: Ling Du, Xiaoping Yang, Carl Trevor Ross Pulford
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Patent number: 9410033Abstract: The present invention provides a rubber composition for an undertread, which has improved in processability, fuel economy, and tensile properties in a balanced manner, and also provides a pneumatic tire formed from the rubber composition. The present invention relates to a rubber composition for an undertread, including: a rubber component containing a modified natural rubber having a phosphorus content of 200 ppm or less; and carbon black and/or a white filler, wherein the modified natural rubber is contained in an amount of 5% by mass or more per 100% by mass of the rubber component.Type: GrantFiled: September 11, 2014Date of Patent: August 9, 2016Assignee: SUMITOMO RUBBER INDUSTRIES, LTD.Inventors: Yoshihiro Kagawa, Naoya Ichikawa
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Patent number: 9217077Abstract: A sulfur-crosslinkable rubberizing mixture for strengthening elements in motor vehicle pneumatic tires comprises 70 to 100 phr (parts by weight, based on 100 parts by weight of total rubbers in the mixture) of natural rubber, up to 30 phr of at least one polybutadiene, 40 to 70 phr of at least one carbon black and a bonding system. Further, motor vehicle pneumatic tires are disclosed that comprise the sulfur-crosslinked rubberizing mixture. The key conflict between tear propagation resistance, stiffness and heat build-up is solved by virtue of the carbon black being a nanostructured carbon black with a rough surface.Type: GrantFiled: February 20, 2014Date of Patent: December 22, 2015Assignee: Continental Reifen Deutschland GmbHInventors: Thorsten Torbruegge, Marc Kreye, Thomas Kramer, Carla Recker
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Patent number: 9181355Abstract: The present invention provides a modified natural rubber having a reduced tan ?, a method for producing the modified natural rubber, a rubber composition produced using the modified natural rubber, and a pneumatic tire produced using the rubber composition. The present invention also provides a modified natural rubber having a reduced tan ?, a method for producing the modified natural rubber, a rubber composition produced using the modified natural rubber and achieving good fuel economy and abrasion resistance at the same time, and a pneumatic tire produced using the rubber composition. The present invention relates to a modified natural rubber having a phosphorus content of 200 ppm or less and a total content of sodium and potassium of 350 ppm or less. The invention also relates to a modified natural rubber having a phosphorus content of 200 ppm or less and a nitrogen content of 0.2% by mass or less.Type: GrantFiled: June 9, 2011Date of Patent: November 10, 2015Assignee: SUMITOMO RUBBER INDUSTRIES, LTD.Inventors: Naoya Ichikawa, Toshiaki Sakaki, Lucksanaporn Tarachiwin, Kamalin Kanyawararak
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Patent number: 9181378Abstract: The present invention provides a modified natural rubber that offers higher efficiency of graft polymerization or attachment of a polar group-containing compounds, and that possesses excellent low loss factor, wear resistance and fracture resistance when used as a rubber composition, a rubber composition using the modified natural rubber and a tire using the rubber composition. In the present invention, a polar group-containing compound is graft polymerized or attached under mechanical shear force to a natural rubber raw material having a nitrogen content of 0.4 mass % or less.Type: GrantFiled: May 1, 2013Date of Patent: November 10, 2015Assignee: BRIDGESTONE CORPORATIONInventors: Taku Yamamoto, Haruki Minojima, Takeshi Kasai
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Patent number: 9074075Abstract: A sulfur-crosslinkable rubberizing mixture for strengthening elements in motor vehicle pneumatic tires comprises 70 to 100 phr (parts by weight, based on 100 parts by weight of total rubbers in the mixture) of natural rubber, up to 30 phr of at least one polybutadiene, 40 to 70 phr of at least one carbon black and a bonding system. Further, motor vehicle pneumatic tires are disclosed that comprise the sulfur-crosslinked rubberizing mixture. The key conflict between tear propagation resistance, stiffness and heat build-up is solved by virtue of the carbon black being a nanostructured carbon black with a rough surface.Type: GrantFiled: February 20, 2014Date of Patent: July 7, 2015Assignee: Continental Reifen Deutschland GmbHInventors: Thorsten Torbruegge, Marc Kreye, Thomas Kramer, Carla Recker
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Patent number: 9034980Abstract: A pneumatic tire for a commercial vehicle with a tread, wherein at least the part of the tread which comes into contact with the road contains a sulphur-vulcanized rubber mixture. The sulphur-vulcanized rubber mixture contains 90 to 50 phr (parts by weight, based on 100 parts by weight, of all of the rubbers in the mixture) of natural rubber, 10 to 50 phr of at least one polybutadiene having a glass transition temperature Tg of ?110 to ?65° C. and 5 to 50 phr of at least one aliphatic and/or aromatic hydrocarbon resin having a softening point (ring and ball to ASTM E 28) of 0 to 150° C., and a mean molecular weight Mn of less than 2000 g/mol and a polydispersity D=Mw/Mn of 1 to 5.Type: GrantFiled: April 22, 2013Date of Patent: May 19, 2015Assignee: Continental Reifen Deutschland GmbHInventors: Carla Recker, Philipp Koelle, Thomas Kramer, Christoph Jocher, Thorsten Torbruegge, Fabian Dettmer, Norbert Daldrup
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Publication number: 20150126657Abstract: The present invention includes a process for producing treated filler that includes (a) treating a slurry that includes untreated filler where the untreated filler has not been previously dried, with a treating composition that includes a treating agent, thereby forming a treated filler slurry, and (b) drying the treated filler slurry to produce treated filler. The treating agent can include a polymer having (i) at least one first group that interacts with the untreated filler and (ii) at least one second group that interacts with a rubber matrix into which the treated filler is incorporated. The present invention also is directed to treated filler prepared by the process, as well as rubber compounding compositions and tires including the treated filler.Type: ApplicationFiled: October 7, 2014Publication date: May 7, 2015Inventors: Timothy Allen Okel, Peter Lawrence Votruba-Drzal, Justin Jonathan Martin, Raphael O. Kollah, Truman Wilt, Brian K. Rearick, Clint Steven Edelman, Linda K. Anderson, Feng Wang, Kurt G. Olson
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Patent number: 9023938Abstract: Method for the production of an initial rubber composition, in the course of which the following steps are carried out in succession: A—a rubber matrix, reinforcing fillers, and other components if required, with the exception of the cross-linking system, are introduced into a mixing means of the internal mixer type, comprising a mixing chamber in which there are mounted rotors which are driven in rotation and have radial projections forming a gap (e) between themselves and the vessel, B—said components are mixed in the chamber until a uniform mixture is obtained, care being taken to ensure that the temperature of the mixture remains at or below 170° C., after which C—the rotation speed of the rotors is adjusted so as to bring the rubber composition to a dropping temperature in the range from 180° C. to 240° C.Type: GrantFiled: July 25, 2012Date of Patent: May 5, 2015Assignees: Compagnie Generale des Etablissements Michelin, Michelin Recherche et Technique, S.A.Inventors: Jean-Marc Loubaresse, Marie Eloy, Floriandre Voisin, Gérald Huguenot, Julien Loyau
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Publication number: 20150119496Abstract: Provided is a method of producing a wet master batch, including the step of: solid-liquid separating and dehydrating a coagulum slurry obtained by mixing a rubber latex with a carbon black slurry containing a carbon black dispersed in water and coagulating the mixture, the solid-liquid separating and dehydrating step including gravity filtering and vacuum filtering the coagulum slurry on a filtration filter and then pressurizing, by means of a pressurizer, the coagulum slurry on the outer peripheral surface of a drum, to thereby pressure dehydrate the coagulum slurry. Also provided is a solid-liquid separating and dehydrating apparatus for wet master batch production, which includes: a filtration filter; a filtration portion; a drum; and a pressurizer.Type: ApplicationFiled: October 28, 2014Publication date: April 30, 2015Applicant: BRIDGESTONE CORPORATIONInventor: Yasuto YANAGISAWA
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Patent number: 9010393Abstract: Tyre and rubber composition for tyre, based on at least one isoprene elastomer (for example natural rubber), an inorganic filler as reinforcing filler (for example silica) and a coupling system which provides the bonding between the said reinforcing inorganic filler and the isoprene elastomer, the said coupling system comprising, in combination: as first coupling agent, a silane sulphide compound; as second coupling agent, an at least bifunctional organosilicon compound (for example an organosilane or an organosiloxane) which can be grafted to the elastomer by means of an azodicarbonyl functional group (—CO—N?N—CO—).Type: GrantFiled: May 11, 2006Date of Patent: April 21, 2015Assignee: Michelin Recherche et Technique, S.A.Inventors: Jose Carlos Araujo Da Silva, Nathalie Binde, Pierre Robert, Sebastien Sterin, Anne Veyland
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Publication number: 20150059606Abstract: An object of the present invention is to provide a relief printing plate precursor for laser engraving that is excellent in rinsing properties for engraving residue and engraving sensitivity and can give a sharp engraved shape. Disclosed is a relief printing plate precursor for laser engraving comprising a relief-forming layer formed of a resin composition for laser engraving, or a crosslinked relief-forming layer obtained by crosslinking the relief-forming layer formed of the resin composition for laser engraving, wherein the resin composition for laser engraving comprises a binder polymer as Component A, and carbon black of which pH is higher than 6 and an average particle size when being dispersed into water is equal to or less than 500 nm as Component B.Type: ApplicationFiled: August 28, 2014Publication date: March 5, 2015Applicant: FUJIFILM CORPORATIONInventor: Yuichi YASUHARA
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Patent number: 8962752Abstract: This invention relates to a rubber composition being excellent in the low heat buildup and fracture properties (resistance to crack growth). and more particularly to a rubber composition, characterized by compounding 10-100 parts by mass of an inorganic filler and/or carbon black based on 100 parts by mass of a rubber component including not less than 10 mass % of a modified conjugated diene-based polymer having a cis-1,4 bond content of not less than 90% and a vinyl bond content of not more than 1.2% and a primary amino group. In this case, the modified conjugated diene-based polymer is obtained by (1) reacting the predetermined conjugated diene-based polymer having an active terminal with a compound having two or more predetermined functional groups and (2) further reacting the resulting product with a compound having a primary amino group.Type: GrantFiled: April 22, 2014Date of Patent: February 24, 2015Assignee: Bridgestone CorporationInventors: Junko Matsushita, Yoichi Ozawa
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Publication number: 20150045497Abstract: The present application provides a polymer composite comprising at least one polymer and a reclaimed pyrolyzed carbon black (pCB), wherein the pCB comprises less than about 10 ?g/g of polycyclic aromatic hydrocarbons (PAH). Also provided are polymer composite and consumer-ready formulations of the low PAH pCB and methods of manufacturing such composites and formulations.Type: ApplicationFiled: October 27, 2014Publication date: February 12, 2015Inventors: Vincent W. Y. WONG, Rui RESENDES, Timothy James CLARK
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Patent number: 8952091Abstract: The present invention provides a rubber composition for an inner liner, which can achieve both excellent low heat build-up and high flex crack growth resistance while having processability excellent enough to eliminate the need for mastication, and further has good air impermeability, and also provides a pneumatic tire produced using the rubber composition. The present invention relates to a rubber composition for an inner liner, including: a rubber component that contains a modified natural rubber with a phosphorus content of 200 ppm or less, and carbon black and/or a white filler.Type: GrantFiled: January 14, 2011Date of Patent: February 10, 2015Assignee: Sumitomo Rubber Industries, Ltd.Inventor: Mutsuki Sugimoto
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Patent number: 8946334Abstract: A rubber composition for tires, which includes a rubber component containing a natural rubber component consisting of at least either a natural rubber or an epoxidized natural rubber, and an inorganic filler containing silica, and a pneumatic tire using such a rubber composition for tires are provided. The rubber composition can be used as a rubber composition for clinch apex, and in this case, the rubber component preferably consists of the natural rubber component, with the inorganic filler being contained in a range of 50 to 80 parts by mass and carbon black being contained in a range of 2 to 5 parts by mass relative to 100 parts by mass of the rubber component.Type: GrantFiled: March 7, 2008Date of Patent: February 3, 2015Assignee: Sumitomo Rubber Industries, Ltd.Inventors: Yoichi Mizuno, Toshikazu Kondo
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Patent number: 8921468Abstract: A rubber composition for a tire includes a rubber component containing at least one of a natural rubber and an epoxidized natural rubber, silica and a natural based wax, wherein the silica is contained in an amount of 10 parts by mass or more based on 100 parts by mass of the rubber component and the natural based wax is contained in an amount of 1.2% by mass or more and 2% by mass or less based on the total mass of the rubber composition for a tire, and to a tread, a side wall, a clinch and a tire using the rubber composition.Type: GrantFiled: March 14, 2008Date of Patent: December 30, 2014Assignee: Sumitomo Rubber Industries, Ltd.Inventors: Tomoaki Hirayama, Takao Wada, Noboru Wakabayashi, Keiji Ikeda
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Publication number: 20140364560Abstract: This invention relates to hydrolysable silanes useful in the modification of elastomers, and as coupling agents for diene elastomer compositions containing a filler. In particular the invention relates to novel hydrolysable silanes containing a piperazine ring and an ether or thioether linkage.Type: ApplicationFiled: December 7, 2012Publication date: December 11, 2014Inventors: Michael Wolfgang Backer, Thomas Chaussee, Damien Deheunynck, Sebastien Grofils
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Patent number: 8901206Abstract: The natural rubber of the present invention is natural rubber obtained by leaving standing for a prescribed period of time a hydrous coagulum obtained from a natural rubber latex to which a preservative is added and/or from a coagulum of a natural rubber latex to which a preservative is added and drying it. The natural rubber coagulum is inhibited from being changed in a molecular weight even in a standing step (aging) in a high moisture condition, whereby the natural rubber having stable mechanical properties is obtained. An isothiazoline base compound is used for the preservative. Further, a rubber composition containing the natural rubber is prepared, and a tire is produced by using the rubber composition.Type: GrantFiled: February 3, 2012Date of Patent: December 2, 2014Assignee: Bridgestone CorporationInventor: Masahiro Kawashima
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Publication number: 20140350174Abstract: The present invention relates to a method for producing a rubber composition obtained by compounding a rubber component (A) containing at least one kind selected from natural rubber and synthetic diene rubber, a filler containing an inorganic filler (B), a silane coupling agent (C), and thiourea, the method comprising kneading the rubber composition in plural stages, the rubber component (A), the whole or a part of the inorganic filler (B), the whole or a part of the silane coupling agent (C), and the thiourea being kneaded in the first stage of kneading, and thus provides a method for producing a rubber composition excellent in low-heat-generation property through enhancement of the reactivity between the coupling agent and the rubber component.Type: ApplicationFiled: December 21, 2012Publication date: November 27, 2014Applicant: BRIDGESTONE CORPORATIONInventors: Noriaki Yukimura, Satoshi Horie, Takumi Toda
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Publication number: 20140350173Abstract: The present invention provides a method for producing a rubber composition provided by compounding a rubber component (A) comprising at least one selected from natural rubbers and synthetic diene rubbers, a filler containing an inorganic filler (B), a silane coupling agent (C), and at least one vulcanization accelerator (D) selected from specific compounds, wherein the rubber composition is kneaded in a plurality of stages and wherein, in the first stage (X) of kneading, a portion (A?) of the rubber component (A), all or a portion of the inorganic filler (B), all or a portion of the silane coupling agent (C), and all or a portion of the vulcanization accelerator (D) are added and kneaded, and in or after the second stage of kneading, the residual portion (A?) of the rubber component (A) is added and kneaded, and the method for producing a rubber composition enables production of a rubber composition capable of suitably having a low-heat-generation property by further improving the coupling function activity oType: ApplicationFiled: December 21, 2012Publication date: November 27, 2014Applicant: BRIDGESTONE CORPORATIONInventor: Shigeaki Matsuo
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Publication number: 20140329102Abstract: An adhesive includes a polymeric latex, a penetrant selected from the group consisting of: terpenes, polylimonene, limonene, carvone, a-pinene, citral, dipentene, 1,8-cineole, eucalyptol, citronellol, geraniol, citronellene, terpinen-4-ol, borneol, camphor, guayule resin, and combinations thereof; and a reinforcing filler. The adhesive has a solids content of 35-65% and a pH of 9 to 12. Articles of manufacture, such as tires and air springs incorporate the adhesive to join rubber interfaces. A method of making the adhesive is also is provided.Type: ApplicationFiled: December 7, 2012Publication date: November 6, 2014Inventors: Amy M. Randall, William L. Hergenrother, Sheel Agarwal, Ashley S. Hilton
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Patent number: 8877831Abstract: Methods and compositions are provided that relate to weighted elastomers. The weighted elastomers may comprise an elastomer and a weighting agent attached to an outer surface of the elastomer. An embodiment includes a method of cementing that comprises providing a cement composition containing cement, water, and a weighted elastomer. In addition, the cement composition may be introduced into a subterranean formation and allowed to set therein.Type: GrantFiled: March 12, 2012Date of Patent: November 4, 2014Assignee: Halliburton Energy Services, Inc.Inventors: Craig W. Roddy, Jeffery D. Karcher, Rickey L. Morgan, D. Chad Brenneis
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Patent number: 8875765Abstract: The present invention provides a rubber composition for a clinch apex which improves in fuel economy, flex crack growth resistance, and processability in a balanced manner, and also provides a pneumatic tire produced using the rubber composition. The present invention relates to a rubber composition for a clinch apex, including: a modified natural rubber having a phosphorus content of 200 ppm or less; and at least one of carbon black and a white filler.Type: GrantFiled: September 14, 2012Date of Patent: November 4, 2014Assignee: Sumitomo Rubber Industries, Ltd.Inventors: Isamu Tsumori, Naoya Ichikawa
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Publication number: 20140316058Abstract: An elastomer composite with silica-containing filler is described, along with methods to make the same. The advantages achieved with the elastomer composite and methods are further described.Type: ApplicationFiled: June 30, 2014Publication date: October 23, 2014Applicant: Cabot CorporationInventors: Michael D. Morris, Anand Prakash, Frederick H. Rumpf
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Patent number: 8846806Abstract: The present invention is directed to a process for producing treated filler including (a) treating a slurry of untreated filler which has not been previously dried, with a treating composition including an organosilane material of specified structure (I); and (b) drying the treated filler slurry. The present invention also is directed to treated filler prepared by the process, as well as rubber compounding compositions and tires including the treated filler.Type: GrantFiled: September 20, 2012Date of Patent: September 30, 2014Assignee: PPG Industries Ohio, Inc.Inventors: Justin J. Martin, Timothy A. Okel, Raphael O. Kollah
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Publication number: 20140287217Abstract: Elastomeric materials and articles of manufacture produced using elastomeric materials are disclosed. In an embodiment, a rubber-based elastomeric material includes a diene rubber component, a reinforcing component, and a wax component. The rubber-based elastomeric material is provided in the form of a film having a thickness of at least about 30 mils. The film exhibits a flexural modulus of less than about 0.06 MPa.Type: ApplicationFiled: March 22, 2013Publication date: September 25, 2014Applicant: HONEYWELL INTERNATIONAL INC.Inventor: William Andrus Williams
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Patent number: 8841361Abstract: A rubber composition includes an elastomer having an elongation at break (Eb) of about 50% or more according to ASTM-D 412 at 25° C., a water-insoluble keratin, and a reinforcing filler. A tire component including the composition and a method for making the composition are also disclosed.Type: GrantFiled: February 7, 2012Date of Patent: September 23, 2014Assignee: Bridgestone CorporationInventors: William L. Hergenrother, Lori L. Shultz, Chenchy Jeffrey Lin
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Publication number: 20140256845Abstract: Method for preparing a silica/natural rubber masterbatch, including: doping the silica with magnesium; preparing at least one dispersion of the resulting doped silica in water; bringing a natural rubber field latex into contact with the aqueous doped-silica dispersion and mixing them together so as to obtain a coagulum; recovering the coagulum; and drying the recovered coagulum so as to obtain the masterbatch.Type: ApplicationFiled: October 10, 2012Publication date: September 11, 2014Applicant: MICHELIN RECHERCHE ET TECHNIQUE, S.A.Inventors: Benoit De Gaudemaris, Geraldine Laffargue, Julien Berriot
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Publication number: 20140249250Abstract: A method for producing a rubber composition containing a rubber wet master batch has a masticating process. The masticating process comprises step 1 of charging the rubber wet master batch into an enclosed kneading chamber that has a stirring rotor showing a rotation speed controllable automatically through a control unit and that is capable of detecting and outputting an internal temperature, step 2 of setting a first control time and a first target temperature in the control unit, and step 3 of stirring the inside of the kneading chamber while making a PID control for adjusting an actually measured temperature in the kneading chamber to the first target temperature through the control unit on the basis of information on the actually measured temperature and the first target temperature, thereby automatically controlling the rotation speed, until the first control time elapses after the completion of the two steps.Type: ApplicationFiled: July 13, 2012Publication date: September 4, 2014Applicant: TOYO TIRE & RUBBER CO., LTD.Inventor: Takashi Miyasaka
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Publication number: 20140249247Abstract: Preparation of a masterbatch of diene elastomer and silica including preparing at least one silica dispersion in water; bringing into contact and mixing an elastomer latex and the aqueous silica dispersion in the presence of a metal salt in order to obtain a coagulum; and recovering the coagulum and drying the recovered coagulum in order to obtain the masterbatch. The molar content of zinc cations, defined as the number of moles of zinc cations of the zinc salt per BET unit area of the silica, is between 1.19*10?6 and 5.62*10?6 mol/m2.Type: ApplicationFiled: October 10, 2012Publication date: September 4, 2014Applicant: MICHELIN RECHERCHE ET TECHNIQUE, S.A.Inventors: Benoit De Gaudemaris, Geraldine Laffargue, Julien Berriot