Abstract: This invention relates to a rubber composition being excellent in the low heat buildup and fracture properties (resistance to crack growth). and more particularly to a rubber composition, characterized by compounding 10-100 parts by mass of an inorganic filler and/or carbon black based on 100 parts by mass of a rubber component including not less than 10 mass % of a modified conjugated diene-based polymer having a cis-1,4 bond content of not less than 90% and a vinyl bond content of not more than 1.2% and a primary amino group. In this case, the modified conjugated diene-based polymer is obtained by (1) reacting the predetermined conjugated diene-based polymer having an active terminal with a compound having two or more predetermined functional groups and (2) further reacting the resulting product with a compound having a primary amino group.

Abstract: The present invention is directed to a self-healing rubber composition comprising a functionalized elastomer comprising: a polymeric backbone chain derived from a monomer comprising at least one conjugated diene monomer and optionally at least one vinyl aromatic monomer; and a functional group bonded to the backbone chain, the functional group comprising a multidentate ligand capable of complexing with a metal ion; and a partitioned metal ion. The invention is further directed to a pneumatic tire comprising the self-healing rubber composition.

Abstract: A method for producing a rubber composition, comprising a first mixing step of causing a diene rubber, a carbon black, and a dihydrazide compound to react with each other in the presence of no silica while the three of the diene rubber, the carbon black, and the dihydrazide compound are kneaded, and a second mixing step of adding a silica to the kneaded product yielded through the first mixing step, and then mixing the silica with the kneaded product.

Abstract: The present application provides a polymer composite comprising at least one polymer and a reclaimed pyrolyzed carbon black (pCB), wherein the pCB comprises less than about 10 ?g/g of polycyclic aromatic hydrocarbons (PAH). Also provided are polymer composite and consumer-ready formulations of the low PAH pCB and methods of manufacturing such composites and formulations.

Abstract: A method for preparing a coupled polymer, the method comprising the steps of: (i) polymerizing monomers to form a reactive polymer, and (ii) reacting the reactive polymer with a boronic ester containing a cyano group.

Abstract: A rubber composition that can be used in applications such as automotive tires and can improve the fuel efficiency performance and driving stability of automobiles and the like, a method for producing a rubber composition, and a tire using the same are provided.

Abstract: There is provided a modified conjugated diene-based polymer having a silyl group substituted with one or more alkoxy groups, and one or more nitrogen atoms on the chain ends of a conjugated diene-based polymer, the modified conjugated diene-based polymer being obtained by polymerizing a conjugated diene compound, or copolymerizing a conjugated diene compound with an aromatic vinyl compound, by using a polyfunctional anionic polymerization initiator prepared from a polyvinyl aromatic compound and an organolithium compound in a range of a molar ratio (the polyvinyl aromatic compound/the organolithium compound) of from 0.05 to 1.0, so as to obtain the conjugated diene-based polymer, and by reacting a living polymer end of the conjugated diene polymer with the compound having a silyl group substituted with two or more alkoxy groups, and one or more nitrogen atoms.

Abstract: The invention relates to a block diene elastomer corresponding to the following formula: where: n and m are each an integer of greater than or equal to 0, such that n+m?1 and n+m?20, each A block is composed of a polybutadiene, each B block is composed of a diene elastomer, the molar content of units resulting from conjugated dienes of which is greater than 15%, the B blocks being identical to one another, X is an organic or inorganic group which can comprise a functional group which interacts with a reinforcing filler, the number-average molecular weight Mn1 of each A block varies from 2 500 to 20 000 g/mol, the number-average molecular weight Mn2 of each B block varies from 80 000 to 350 000 g/mol, and the content of 1,2- linkages in each A block is between 1 and 20%.

Abstract: The invention relates to unique applications for the novel high melt flow, low viscosity, selectively hydrogenated styrene-butadiene-styrene (hSBS) or selectively hydrogenated controlled distribution styrene-butadiene/styrene-styrene (hSBSS) block copolymers, wherein the melt flow rate of said block copolymer is at least 100 g/10 min at 230° C. under 2.16 kg mass according to ASTM D1238. These block copolymers are novel and have the highest melt flow rate of any styrenic block copolymer also possessing high strength and elasticity. It has applications that prior to the present invention were not normally possible due to the normal low melt flow rate of styrenic block copolymers. The present invention also encompasses various fields of use such as a fiberglass hSBS or hSBSS reinforced mat, low viscosity hSBS or hSBSS coatings for industrial uses, hot melt adhesives prepared from hSBS or hSBSS blended with polyalpha-olefins, and elastic film, fiber, and nonwoven constructions using hSBS or hSBSS.

Abstract: The present invention relates to a modified polymer obtained by grafting a compound comprising at least one group Q, and at least one group A bonded together by at least, and preferably, one “spacer” group Sp in which: Q comprises an azo-carbonyl group capable of being grafted onto the polymer chain by an “ene reaction”, A comprises an associative group comprising at least one nitrogen atom, Sp is an atom or a group of atoms forming a bond between Q and A.

Abstract: The present invention provides a rubber composition for a tread which enables improvement in fuel economy, breaking performance, and abrasion resistance in a balanced manner; a method for producing the rubber composition; and a heavy-load tire. The present invention relates to a rubber composition for a tread of a heavy-load tire, including a modified natural rubber having a phosphorus content of 200 ppm or less, and carbon black.

Abstract: A sulfur-containing cycloaliphatic compound, useful as a crosslinker for filled sulfur-vulcanizable elastomer compositions, is represented by the general formula: G[-CaH2a—S[C(?O)]bR]n wherein G is selected from the group consisting of: saturated, monocyclic aliphatic group of valence n containing from 5 to 12 carbon atoms and optionally containing at least one halogen, and saturated monocyclic silicone [RSiO—]n[R2SiO—]p group of valence n; wherein each R independently is a hydrogen or monovalent hydrocarbon of up to 20 carbon atoms; each occurrence of subscripts a and b independently is an integer wherein a is 2 to 6 and b is 0 or 1; p is an integer of from 0 to 3; and, n is an integer of from 3 to 6, with the provisos that when b is 0, R is a hydrogen atom, and when G is a non-halogenated, saturated monocyclic aliphatic group of 6 carbon atoms, n cannot be 3.

Abstract: A rubber formulation with good wet traction properties includes one or more elastomers and at least two types of particulate filler materials including at least one of which has a relatively high free surface energy in water (i.e., a supplemental filler). The formulation containing the supplemental filler(s) can provide a vulcanizate that has a British pendulum (skid) number that is at least ˜5% greater than that of a vulcanizate made from an essentially identical formulation that does not contain the supplemental filler(s). Also provided is a method for providing such a formulation which involves identifying one or more supplemental fillers having relatively high free surface energies in water, replacing at least 15% (by wt.) of one or more of the conventional particulate fillers in the formulation with an approximately equivalent volume of supplemental filler particles, and providing the modified formulation.

Abstract: A resin composition for laser engraving, comprises (Component A) an ethylenically unsaturated group-containing binder polymer; and (Component B) a tertiary ester group- and ethylenically unsaturated group-containing compound. The tertiary ester group in Component B is preferably a group represented by Formula (I). In Formula (I), R1 to R3 independently denote a monovalent hydrocarbon group, at least two of R1 to R3 may be bonded to each other to from at least one ring structure, and the wavy line portion denotes a position of bonding to another moiety.

Abstract: A method for preparing a functionalized polymer, the method comprising the steps of polymerizing monomer to form a reactive polymer, and reacting the reactive polymer with a polycyano compound.

Abstract: After hydrolyzing a phospholipid bonded to a molecular end of a natural rubber, a compound having a polar group reacting with a hydroxyl group is condensed with a hydroxyl group contained in the phospholipid-hydrolyzed natural rubber to thereby obtain a modified natural rubber in which a polar group is present at a molecular end. The modified natural rubber thus obtained in which a polar group is present at a molecular end is used for a rubber component of a rubber composition, whereby a rubber composition in which carbon black and silica as fillers are bonded to the rubber component to enhance a reinforcing effect and which is excellent in a low hysteresis loss property and abrasion resistance to a large extent is obtained. An enzyme or an alkali is used for hydrolyzing the phospholipid, and a condensing agent is used for condensing the polar group-containing compound.

Abstract: There are provided a modified conjugated diene-based polymer having a good balance between the hysteresis loss properties and the wet skid resistance, practically sufficient abrasion resistance and fracture strength, and high processability when formed into a vulcanized product, and a modified conjugated diene-based polymer composition. A method for producing a modified conjugated diene-based polymer, comprising: a polymerization step of polymerizing a conjugated diene compound or copolymerizing a conjugated diene compound with an aromatic vinyl compound using an alkali metal compound or an alkaline earth metal compound as a polymerization initiator to obtain a conjugated diene-based polymer having a reactive end, and a modifying step of reacting a compound having a specific structure with the reactive end of the conjugated diene-based polymer.

Abstract: A rubber composition for a tire, and a pneumatic tire are provided in which the fuel economy, abrasion resistance, and deterioration resistance can be improved in a good balance. The present invention relates to a rubber composition for a tire, containing a rubber component that contains: a modified natural rubber having a phosphorus content of not more than 200 ppm; and butadiene rubber, wherein 60 to 95% by mass of the modified natural rubber and 5 to 40% by mass of the butadiene rubber are contained based on 100% by mass of the rubber component.

Abstract: The present invention provides a modified natural rubber which simultaneously achieves good fuel economy and good heat-aging resistance, and the production method thereof. The present invention also provides a tire rubber composition and a pneumatic tire which are produced using the modified natural rubber. The present invention relates to a modified natural rubber which is obtainable by treating a rubber coagulated from a saponified natural rubber latex, with a basic compound and then with an acidic compound.

Abstract: There is provided a method of producing a conjugated diene rubber capable of being used as a starting material for a crosslinked rubber that can be used in applications such as tire treads and can raise the fuel efficiency.

Abstract: A process for the synthesis of a diene copolymer comprising at least two blocks, at least one of the blocks being composed of a diene elastomer, characterized in that it comprises a stage of 1,3-dipolar reaction of two polymers defined as being: a) a diene elastomer bearing an alkyne functional group at one or each of its chain ends, and b) a polymer bearing at least one azide functional group. This process of synthesis can be adjusted, whatever the nature of the monomers necessary to form each of the blocks of the copolymer. Each block can be synthesized with an appropriate chemistry, independently of the other block.

Abstract: A method for producing a modified conjugated diene-based polymer including a polymerization step of obtaining a conjugated diene-based polymer having an active end by use of a polymerization initiator containing a compound having at least one nitrogen atom in a molecule and an organic lithium compound; and a modification step of reacting a modifier represented by the following chemical formula (6) with the active end of the conjugated diene-based polymer: wherein R4 to R7 each independently represent an alkyl group having 1 to 20 carbon atoms or an aryl group having 6 to 20 carbon atoms; R8 represents an alkylene group having 3 to 10 carbon atoms; R9 represents an alkylene group having 1 to 20 carbon atoms; m is an integer of 1 or 2; and n is an integer of 2 or 3.

Abstract: Disclosed is a terminal modifier for conjugated diene polymers. The terminal modifier has both at least two amine groups and at least one alkoxysilane group. A terminally modified conjugated diene polymer which is coupled at the terminus with the terminal modifier, and a polymer composition for use in tires, comprising the terminally modified, conjugated diene polymer are also provided. When applied to tire treads, the polymer composition comprising the terminally modified, conjugated diene polymer significantly increases the disperability and binding to rubber of silica, thereby greatly contributing to an improvement of the tire treads in dynamic properties including wet traction, rolling resistance, Mooney viscosity and processability.

Abstract: A coating composition adapted for application on a fastener, the coating composition composed of a binder component composed of a polymeric resin present in the composition at a concentration between 1.0% and 15.0% by total composition weight, wherein the binder component is composed of at least one of a solvent dispersible compound; a reactive cross-linking component present in the composition in an amount between 1.0% and 80.0%; at least one curing agent; optionally at least one expansion agent, wherein at least one of the curing agent or the reactive cross-linking component are physically and reactively isolated from other components of the composition.

Abstract: Impact-modified polystyrene resins such as HIPS and ABS resins are blended with a brominated vinyl aromatic-butadiene copolymer. The brominated copolymer is an effective flame retardant in these compositions, allowing in many cases a V-1 rating to be achieved in the UL-94 vertical burn test.

Abstract: Polymer-filler coupling compounds with the formula B-A-Sx—N are claimed. In these compounds, B is an azaheterocyclic oxygen or sulfur containing moiety, or an allyltin moiety; Sx is a polysulfide, where x is between 2 and about 10; A is a linking atom or group that forms a bridge between B and Sx; and N is a blocking group. Sx can be a disulfide. N can be a conventional blocking group or other group such as -A-B. Methods for using the polymer-filler coupling compounds to modify polymers containing unsaturated carbon-carbon bonds and promote filler dispersion are also claimed. Additionally, vulcanizable rubber compositions containing the polymer-filler coupling compounds and methods for making vulcanized rubber compositions using the polymer-filler coupling compounds are also claimed.

Abstract: Provided is a synthesis method of a modified conjugated diene polymer. Conjugated diene monomers are reacted in a reaction system. A modifier is added into the reaction system while the reaction proceeds to a predetermined extent. The modifier has a structure represented by formula (1): wherein R1-R11 each independently represent a C1-C5 alkyl group; 1?m?300; 0?a?65; 0?b?65; 0?c?40; 0<a+b; 0?c/(a+b+c)?0.8; the X and Y are structures respectively represented by formula (2) and formula (3): wherein R12, R16, and R17 each independently represent a C1-C5 alkylene group and R13-R15 each independently represent a C1-C5 alkyl group.

Abstract: The invention relates to a wiper rubber for windshield wipers, which contains at least one rubber component that is cured by vulcanization, the material of the wiper rubber containing, at least in the unvulcanized state, a combination of a cross-linking agent with sulfur and/or with a sulfur donor.

Abstract: The present invention has its object to provide a rubber composition for a tread which can prevent reversion and can also achieve environmental performance (excellent rolling resistance, response to depletion of oil resources, attention to CO2 emission), wet grip performance, dry grip performance, handling stability, and durability (abrasion resistance, crack resistance) in a well-balanced manner. The present invention also aims to provide a pneumatic tire using the rubber composition for the tread thereof. The rubber composition for a tread includes a rubber component containing 35% by mass or more of an epoxidized natural rubber; and a white filler, wherein a total sulfur content is less than 1.75% by mass, and a crosslink density is 7.0×10?5 mol/cm3 or more.

Abstract: In order to provide a tire which is excellent in processability and which is excellent as well in a low fuel consumption, abrasion resistance and fracture resistance, assumed is such a constitution that used for a tire member is a rubber composition which contains a modified natural rubber having a polar group in the rubber molecule and precipitated silica, wherein a cetyltrimethylammonium bromide-adsorbing specific surface area (CTAB) (m2/g) of the precipitated silica and the mode Aac in diameters (nm) of primary aggregates thereof determined by acoustic measurement of particle size distribution satisfy an equation: Aac??0.76×(CTAB)+274.

Abstract: Thermoplastic elastomer compositions are described comprising multigraft copolymers. The multigraft copolymers can comprise a rubbery polymeric backbone and a plurality of glassy polymeric side chains, each attached at one of a plurality of branch points randomly spaced along the backbone. The copolymer materials have high tensile strength, high strain at break, and low residual strain after elongation. The compositions can be used as adhesives and in a wide variety of high tech, medical, and commodity applications.

Abstract: A method for preparing a functionalized polymer, the method comprising the steps of polymerizing monomer to form a reactive polymer; and reacting the reactive polymer with a protected oxime compound containing an acyl group.

Abstract: To provide a charging member that can have a uniform electrical resistance, can not easily change in electrical resistance even by any long-term continuous electrification and, as a result thereof, may cause less change in its charging performance with time. A charging member having a conductive support and an elastic-material layer; the elastic-material layer comprising a vulcanized rubber; the vulcanized rubber being a vulcanized product of a composition which comprises i) a binder polymer comprising a polymer having a butadiene skeleton and ii) carbon black as electrically conductive particles; and the polymer having a butadiene skeleton has a molecular terminal modified with an atomic group having a specific structure.

Abstract: A process for the preparation of a 1,3-butadiene and styrene copolymer comprising the following steps: a) anionically polymerizing a blend comprising from 5% by weight to 40% by weight of styrene and from 60% by weight to 95% by weight of 1,3-butadiene, with respect to the overall weight of the mixture, in the presence of at least one hydrocarbon solvent, of at least one lithium-based catalyst having the general formula LiR1 wherein R1 represents a linear or branched C3-C10 alkyl group, and of least one polar modifier; b) optionally, reacting the copolymer obtained in step (a) with at least one chain-end monomer selected from 1,3-butadiene, styrene and ?-methylstyrene; c) reacting from 10% by weight to 70% by weight, preferably from 20% by weight to 50% by weight, of the lithium-terminated polymeric chains present in the copolymer obtained in step (a) or in step (b), with at least one coupling agent selected from liquid polyepoxides having at least three reactive sites capable of reacting with the carbon-lith

Abstract: This invention relates to preparation and use of in situ functionalized elastomers in a rubber composition, namely post polymerization functionalization of elastomers, in rubber compositions containing precipitated silica filler reinforcement and tires having components thereof.

Abstract: A method for preparing a polydiene polymer, the method comprising: (i) preparing an active polymerization mixture by introducing conjugated diene monomer, and optionally monomer copolymerizable therewith, and a lanthanide-based catalyst system; (ii) adding a nitrile compound containing a protected amino group to the active polymerization mixture; and (iii) adding a co-functionalizing agent to the active polymerization mixture.

Abstract: This invention relates to a rubber composition being excellent in the low heat buildup and fracture properties (resistance to crack growth). and more particularly to a rubber composition, characterized by compounding 10-100 parts by mass of an inorganic filler and/or carbon black based on 100 parts by mass of a rubber component including not less than 10 mass % of a modified conjugated diene-based polymer having a cis-1,4 bond content of not less than 90% and a vinyl bond content of not more than 1.2% and a primary amino group. In this case, the modified conjugated diene-based polymer is obtained by (1) reacting the predetermined conjugated diene-based polymer having an active terminal with a compound having two or more predetermined functional groups and (2) further reacting the resulting product with a compound having a primary amino group.

Abstract: The present invention provides a rubber composition capable of improving the rubber strength and fuel economy in a balanced manner, and a pneumatic tire formed from the rubber composition. The present invention relates to a rubber composition including a rubber component, carbon black, and a compound represented by formula (I) below, wherein the amount of the carbon black is 10 to 100 parts by mass per 100 parts by mass of the rubber component: wherein R1 and R2 are the same as or different from each other, and each represent a hydrogen atom, a C1-C20 alkyl group, a C1-C20 alkenyl group, or a C1-C20 alkynyl group; Mr+ represents a metal ion; and r represents a valence of the metal ion.

Abstract: A building material comprising a substrate layer and a pressure-sensitive adhesive layer, where the pressure-sensitive adhesive layer includes expandable graphite.

Abstract: There is disclosed a functionalized elastomer of formula I where R1, R2 and R3 are independently C1 to C8 alkyl or C1 to C8 alkoxy, with the proviso that at least two of R1, R2 and R3 are C1 to C8 alkoxy; R4 is C1 to C8 alkanediyl, C1 to C8 arylene, C1 to C8 alkylarylene, C1 to C8 arylalkanediyl, or a covalent bond; R5 is C2 alkanediyl; Si is silicon; X is sulfur or oxygen; and P is a diene based elastomer, and n is 1 or 2.

Abstract: The invention relates to a tire having a component composed of a composite of rubber chafer and outer sidewall layer components comprised of rubber compositions containing the same or different specialized cis 1,4-polybutadiene elastomers.

Abstract: Curable rubber compositions and cured articles are based on the use of zinc activator compositions for the sulfur cure. Activator compositions contain zinc and a polymeric component having a plurality of COOH groups, at least some of which are neutralized with the zinc. With polymeric zinc activators, sulfur cure can be activated at levels of zinc below those used in conventional systems.

Abstract: The present invention comprises an uncrosslinked composition of a styrenic block copolymer and PMS-I/B-PMS (paramethylstyrene-isoprene/butadiene-paramethylestyrene) block copolymer, optionally with one or more antioxidants and a carbon radical scavenger. The mid-block IB is a random mixture of isoprene and butadiene. Further, a process is disclosed for making the uncrosslinked composition. The present invention also includes an uncrosslinked composition of homo polystyrene, and PMS-I/B-PMS block copolymer, optionally with one or more antioxidants and a carbon radical scavenger. The present invention also comprises a crosslinked polyolefin-free composition of PMS-I/B-PMS block copolymer, optionally with a styrenic block copolymer and one or more antioxidants, a carbon radical scavenger, and free radical initiator.

Abstract: The invention is a two-part composition comprising: A) in one part (i) one or more isocyanate functional prepolymers; and B) in a second part (ii) one or more compounds having isocyanate reactive groups; (iii) one or more fillers selected such that the composition is nonconductive; (iv) one or more catalysts for the reaction of isocyanate groups with active hydrogen containing compounds wherein either or both of the one or more isocyanate functional prepolymers and the one or more compounds having isocyanate reactive groups have solid organic particles grafted thereto such that the composition contains from about 6 to about 13 percent by weight of the total composition of solid organic particles. In a preferred embodiment, the second part comprises from about 35 to about 65 percent by weight of one or more compound having isocyanate reactive groups which have solid organic particles grafted to the backbone.

Abstract: It is an object of the present invention to provide a tire rubber composition and a pneumatic tire produced using the rubber composition, which improve mechanical strength, abrasion resistance, rolling resistance, wet grip performance, and dry grip performance in good balance. The present invention relates to a tire rubber composition comprising: a rubber component that contains a modified diene rubber; and a silica component that contains a silica surface-treated with a silane coupling agent, wherein the amount of the modified diene rubber in 100% by mass of the rubber component is 15% by mass or more, and the dispersion ratio of the silica component is 70% or higher.

Abstract: A method containing a step of reacting a conjugated diene polymer having an alkali metal or alkaline earth metal active end with a hydrocarbyloxysilane compound having one or more of each of the following functional groups I and II in its molecule to obtain a modified conjugated diene polymer containing a functional group II, and a step of mixing the modified conjugated diene polymer and a compound such as organic acid. A modified conjugated diene rubber which can be used as a raw material of a cross-linked rubber which can be used in tire treads and the like and can enhance low fuel consumption performance is provided. The functional group I is a hydrocarbyloxysilyl group. The functional group II is a nitrogen-containing group in which both of two hydrogen atoms of a primary amino group are substituted with protective groups.

Abstract: The invention relates to a latex composition wherein the latex composition comprises a butyl ionomer or partially halogenated butyl rubber ionomer. The latex composition is formed by dissolving the butyl ionomer in a suitable solvent, emulsifying the polymer in the solvent, adding water and optionally a minor amount of a suitable surfactant system to the emulsion and concentrating the emulsion to remove the water. The advantages of butyl ionomer latex include lower emulsifier levels, increased latex stability, improved interaction and adhesion to polar substrates and surfaces. Through the judicious choice of emulsifiers and/or washing to remove excess emulsifier a film with enhanced non-extractable polymeric antimicrobial function can be created. These properties of ionomer latex are useful in coatings, dipped goods and sponge applications.

Abstract: A process for producing a conjugated diene-based polymer which comprises, in the first modification, modifying a conjugated diene-based polymer having active chain ends, which is obtained by polymerizing a diene-based monomer singly or with other monomers and has a content of a cis-1,4 unit of 75% by mole or greater in the conjugated diene portion of the main chain, by reacting the active chain ends with a hydrocarbyloxysilane compound and reacting the modified polymer with a specific compound such as a hydrocarbyloxysilane compound, and a rubber composition containing the polymer modified in accordance with the above process and, preferably, 10 to 100 parts by weight of silica and/or carbon black per 100 parts by weight of the rubber component containing the modified polymer, are provided. The rubber composition containing silica and/or carbon black exhibits improved fracture properties, abrasion resistance, low heat buildup property and excellent workability.

Abstract: This invention relates to the modification of elastomers especially epoxidised rubber by reaction with unsaturated silanes, to the modified elastomers produced and to articles produced by shaping and curing modified elastomer compositions. In a process according to the present invention, the silane has the formula: R?—CH?CH—C(O)X—Y—SiRaR?(3-a)??(I) or R?—C?C—C(O)X—Y—SiRaR?(3-a)??(II) in which R, R?, a, Y, X and R? are as defined in the description.

Abstract: A method for preparing a functionalized polymer, the method comprising the steps of: (i) polymerizing monomer to form a reactive polymer; and (ii) reacting the reactive polymer with a protected hydrazone compound containing an acyl group.