Natural Rubber Patents (Class 524/575.5)
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Patent number: 8318846Abstract: An object of the present invention is to provide an olefin-based thermoplastic elastomer composition that has both weatherability and flexibility at low temperatures, is excellent in fluidity, and causes no stickiness even in the use at high temperatures; a process oil composition for elastomers that serves as the raw material of the thermoplastic elastomer composition and contributes to the above characteristics; and an oil-extended elastomer containing the process oil composition. The process oil composition for elastomers of the present invention has a property that, when 20 parts by weight of the process oil composition for elastomers are blended with respect to 100 parts by weight of a propylene homopolymer, the melting point of the propylene homopolymer is lowered by 2 to 4.5° C. compared to that of the propylene homopolymer without blending.Type: GrantFiled: November 10, 2006Date of Patent: November 27, 2012Assignee: Mitsui Chemicals, Inc.Inventors: Yuichi Ito, Hidenari Nakahama, Kotaro Ichino
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Publication number: 20120283380Abstract: The invention relates to an elastic coupling comprised of connecting flanges located on the drive input and drive output side as well as comprised of at least one rubber .body arranged between them. The invention proposes that the at least one rubber body contains silicic acid/silica as filler agent as well as dyeing pigments.Type: ApplicationFiled: November 3, 2010Publication date: November 8, 2012Applicant: HACKFORTH GmbHInventor: Ralf Bauermeister
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Patent number: 8299161Abstract: There is disclosed a composition comprising defatted soy flour and a natural rubber in aqueous or dried form. There is also disclosed rubber compositions comprising the compositions comprising defatted soy flour and a natural rubber. There is further disclosed use of the compositions comprising defatted soy flour and a natural rubber, as well as use of rubber compositions including the compositions comprising defatted soy flour and a natural rubber, in the production of various products such as pneumatic tires and tire components, and the like.Type: GrantFiled: December 28, 2006Date of Patent: October 30, 2012Assignee: Bridgestone CorporationInventors: Terrence E. Hogan, William L. Hergenrother, Christopher Robertson, Maria Tallman
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Patent number: 8293827Abstract: A method for producing a rubber composition, the method including: preparing a modified natural rubber by releasing protein from rubber particles in a natural rubber latex by adding at least one organic compound selected from formaldehyde, paraformaldehyde, formalin, and glyoxal to the above mentioned natural rubber latex and then drying so as to include the released protein therein; and mixing at least one selected from carbon black and silica in this modified natural rubber. Such method reduces viscosity and improves molding processibility of the rubber composition, as well as reducing hysteresis loss.Type: GrantFiled: November 4, 2009Date of Patent: October 23, 2012Assignee: The Yokohama Rubber Co. LtdInventors: Takashi Matsuda, Makoto Ashiura, Tetsuji Kawazura
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Publication number: 20120264875Abstract: The invention relates to a method for preparing a silica/natural rubber masterbatch, comprising the following successive steps: doping the silica with an at least divalent metallic element; preparing at least one dispersion of the resulting doped silica in water; bringing a natural rubber field latex into contact with the aqueous doped-silica dispersion and mixing them together so as to obtain a coagulum; recovering the coagulum; and drying the recovered coagulum so as to obtain the masterbatch.Type: ApplicationFiled: October 25, 2010Publication date: October 18, 2012Applicants: MICHELIN RECHERCHE ET TECHNIQUE S.A., COMPAGNIE GENERALE DES ETABLISSEMENTS MICHELINInventors: Julien Berriot, Benoit De Gaudemaris, Géraldine Laffargue
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Publication number: 20120259060Abstract: A rubber composition comprising a metal salt of a carboxylic acid used as a curing agent, a highly unsaturated dieene rubber, a filler and a sulfur vulcanization system of between 0.5 phr and 8 phr of sulfur and at least one vulcanization accelerator. Particular embodiments may further include between 1 phr and 6 phr of a metal salt of a carboxylic acid that increases a tear index of the cured elastomer composition by at least 50 percent as compared to a similar cured elastomer composition, such similar cured elastomer composition being different in composition only in that it (1) lacks the metal salt of a carboxylic acid and (2) has an increased amount of the sulfur vulcanization system at about the same sulfur to accelerator ratio to maintain a 10% modulus of elongation at 23 0C to within 15% of the modulus of the cured rubber composition.Type: ApplicationFiled: December 28, 2010Publication date: October 11, 2012Inventor: Xiaofeng Shaw Yang
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Patent number: 8278385Abstract: The invention is to provide a rubber composite and tire using the rubber composite, which, when the rubber composite is used as the tread rubber of a tire, enables the tire to have high wear resistance and hence have a long life while presenting a low rolling resistance and enables an automobile that uses the tires to reduce fuel consumption during traveling. The rubber composite of the invention comprises 100 parts by weight of a rubber component composed of at least one kind of rubber, selected from a group of natural rubber, synthetic isoprene rubber and synthetic diene rubber and 10 to 100 parts by weight of a carbon black blended therein, the carbon black is specified to satisfy the relation X/Y?0.84, where X is the mercury intrusion specific surface area (m2/g), measured by mercury porosimetry and Y is the CTAB specific surface area (m2/g). The tire of the invention is one that uses the above rubber composite as its tread portion.Type: GrantFiled: July 22, 2008Date of Patent: October 2, 2012Assignee: Bridgestone CorporationInventor: Hidetada Fujisawa
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Patent number: 8273804Abstract: An object of the present invention is to provide a rubber composition for a tire, which can achieve well-balanced improvement in fuel economy, abrasion resistance, and performance on ice and snow, and a studless tire for a passenger vehicle using the rubber composition. The present invention relates to a rubber composition for a tire, including a rubber component and silica, wherein the rubber component contains a modified natural rubber with a phosphorus content of 200 ppm or less, and butadiene rubber, and the silica has a CTAB specific surface area of 180 m2/g or more and a BET specific surface area of 185 m2/g or more.Type: GrantFiled: January 3, 2011Date of Patent: September 25, 2012Assignee: Sumitomo Rubber Industries, Ltd.Inventor: Akihiro Nishimura
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Publication number: 20120238694Abstract: The novel group of polymers is presented under the name of Powdered Metastable Polymer Material (PMPM). PMPM is in a chemically stable state at an ambient temperature of 25° C. for a relatively long time, but it is in a thermodynamically unstable state, and may change to either a stable state (in this case, re-vulcanization), or an unstable state (in this case, decomposition). According to the prior art, these PMPMs are, under various conditions, reactive, malleable, processable, compoundable, re-vulcanizable and re-polymerizable, and thus makes it possible to form new vulcanized or coagulated products, with or without moulds, with or without other polymers or elastomers, cross-linking agents, compatibilizers, various additives, etc.Type: ApplicationFiled: July 2, 2010Publication date: September 20, 2012Applicant: MERCURHONEInventor: Beom-Jun Yi
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Publication number: 20120232208Abstract: Disclosed are a vibration isolating rubber composition that balances a low dynamic-to-static modulus with high durability, and a vibration isolating rubber that is formed by curing said rubber composition. The vibration isolating rubber composition is characterized by including a diene rubber, and a carbon black and a silica as fillers, and in that the mixing ratio of the carbon black (a) and the silica (b) is (a)/(b)=80/20 to 20/80 (weight ratio).Type: ApplicationFiled: November 15, 2010Publication date: September 13, 2012Applicant: BRIDGESTONE CORPORATIONInventor: Takahiro Saito
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Publication number: 20120225984Abstract: This invention relates to novel sulfur-containing silane coupling agents, and organic polymers containing carbon-carbon double bonds. These novel silanes can be carried on organic and inorganic fillers. The invention also relates to articles of manufacture, particularly tires, made from the elastomer compositions described herein.Type: ApplicationFiled: April 27, 2012Publication date: September 6, 2012Applicant: Momentive Performance Materials Inc.Inventors: Richard W. CRUSE, W. Michael YORK, Eric R. POHL, Antonio CHAVES, Prashant JOSHI
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Patent number: 8236875Abstract: The invention relates to a rubber mixture, in particular for vehicle air-inflated tires, seat belts, belts and hoses. The rubber mixture is characterized by the following composition: at least one polar or non-polar rubber and at least one bright and/or dark filler and at least one softener, wherein the softener is free of polycyclic aromatics according to Directive 76/769/EEC, and wherein the carbon source for the softener comes from non-fossil sources, and other additives.Type: GrantFiled: January 13, 2011Date of Patent: August 7, 2012Assignee: Continental Reifen Deutschland GmbHInventors: Carla Recker, Thorsten Reese, Jens Schöning
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Publication number: 20120196976Abstract: The invention relates to the use of an adhesive composition between a vulcanized rubber part and an uncured or prevulcanized or vulcanized rubber part, based on at least one highly unsaturated elastomer chosen from the group formed by natural rubber, polyisoprene, polybutadiene, styrene-butadiene, styrene-isoprene and butadiene-isoprene copolymers and styrene-butadiene-isoprene terpolymers, an aliphatic solvent and a “curing” system comprising at least one stable aryl dinitrile oxide compound.Type: ApplicationFiled: March 30, 2010Publication date: August 2, 2012Applicants: Michelin Rechercheet Technique S.A., Societe De Technologie MichelinInventors: José Carlos Araujo Da Silva, Vincent Hunault, Pierre Robert, Anne Veyland
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Patent number: 8232338Abstract: A rubber composition based on at least one diene elastomer, containing less than 2 phr of zinc, phr meaning parts per hundred parts of rubber (elastomer), and based on at least one reinforcing filler and one sulphur-based crosslinking system, comprising a zinc carboxylate of formula: (RCOO)2Zn, in which R represents a hydrocarbon group chosen from cyclic or non-cyclic, linear or branched alkyl groups having 1 to 16 carbon atoms, aryl groups, aralkyl groups or alkaryl groups having 1 to 16 carbon atoms. Also disclosed is a process for preparing such a rubber composition which is suitable for manufacturing tires or semi-finished products made of rubber intended for these tires.Type: GrantFiled: December 21, 2007Date of Patent: July 31, 2012Assignee: Michelin Recherche et Technique S.A.Inventors: José Carlos Araujo Da Silva, Anne Veyland
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Patent number: 8227538Abstract: A rubber mixture with improved abrasion with improved abrasion performance, in particular for pneumatic tires, has the following composition: from 30 to 100 phr of at least one diene rubber; from 0.1 to 10 phr of at least one vulcanization accelerator selected from the group consisting of: thiazole accelerators, mercapto accelerators, sulfenamide accelerators, guanidine accelerators, thiuram accelerators, dithiocarbamate accelerators, amine accelerators, thioureas, and/or other accelerators; and a vulcanization system of sulfur comprising elemental sulfur, sulfur donor and silane between 0.25 and 0.08 moles per 100 parts by weight of the rubber elastometer, whereby the free sulfur contributes in the range of 0 to 70%, the sulfur donor contributes in the range of 5 to 30%, and the silane contributes in the range of 20 to 95%.Type: GrantFiled: June 5, 2008Date of Patent: July 24, 2012Assignee: Continental AGInventors: William Michael York, Carla Recker, Katharina Herzog, Hajo Weinreich, Boris Mergell, Viktoriya Tkachenko, Norbert Mueller, Juergen Wagemann
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Publication number: 20120150316Abstract: The object of the present patent is characterized by being a brand-new device which was developed to control the esophageal flow; it is made of biosynthetic material based on the natural latex extracted from the rubber tree Hevea brasiliensis, to be applied in the esophagus in order to control or limit the speed and amount of food intake and, thus, to provide weight loss. It preserves all digestive system functions, decreases food intake with the reduction of the esophagus lumen and, in turn, decreases the organ emptying, thus controlling the speed and amount of food intake.Type: ApplicationFiled: August 31, 2009Publication date: June 14, 2012Inventor: Jose da Conceiçao Carvalho
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Publication number: 20120130010Abstract: Provided is a railcar shock absorber rubber composition that can provide high cured rubber hardness and simultaneously achieve electrical insulating properties and suppression of a decrease in elastic modulus after strain loading, and includes a diene rubber as a main component, hydrous silicic acid or wet silica with a BET specific surface area of 70 to 130 m2/g, and carbon black with a DBP oil absorption of 130 cm3/100 g or less, wherein 30 to 100 parts by weight of the hydrous silicic acid or wet silica and 5 to 40 parts by weight of the carbon black are present based on 100 parts by weight of the total amount of the rubber component.Type: ApplicationFiled: November 14, 2011Publication date: May 24, 2012Applicant: TOYO TIRE & RUBBER CO., LTD.Inventor: Toshio Azechi
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Patent number: 8182626Abstract: A tire composition with a Shore A hardness, according to DIN 53 505 and ASTM D2240, of not less than 40 and not greater than 95 and a glass-transition temperature Tg (E?max), according to DIN 53 513 with a specified temperature sweep of ?80° C. to +80° C. and a specified compression of 10+0.2% at 10 Hz, not less than ?80° C. and not greater than 0° C., with improved abrasion performance, in particular for pneumatic tires, has the following composition: at least one vulcanizable diene rubber selected from natural rubbers, synthetic polyisoprene rubbers, polyisobutylene rubbers, polybutadiene rubbers (BR), and random styrene-butadiene rubbers; from 35 to 300 phr of at least one active filler selected from carbon blacks, silicas, silicon based fillers, and metal oxides, of which at least 10 phr must be carbon blacks, silicas, or some combination thereof; from 0 to 250 phr of other or further additives; from 0.Type: GrantFiled: October 30, 2008Date of Patent: May 22, 2012Assignee: Continental AGInventors: Carla Recker, William Michael York, Thomas Kramer, Katharina Herzog, Boris Mergell, Richard W. Cruse
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Patent number: 8183327Abstract: The present invention provides: a rubber composition for a tire having favorable productivity, excellent heat aging resistance and abrasion resistance, and excellent fuel economy; and a pneumatic tire using the rubber composition. The rubber composition contains neither soluble sulfur nor insoluble sulfur, and contains diene rubber, 1-15 parts by mass of compound 1 represented by formula (1) and 0.1-5 parts by mass of compound 2 represented by formula (2), per 100 parts by mass of the diene rubber, and the amount ratio of compound 1 to compound 2 (compound 1/compound 2) is 1-8. wherein R1-R4 are the same or different, and represent C1-20 alkyl, C6-20 aryl, or C7-20 aralkyl, and n represents an integer of 1-12; wherein R5-R7 are the same or different, and represent C5-12 alkyl, x and y are the same or different, and represent an integer of 2-4, and m represents an integer of 0-10.Type: GrantFiled: September 23, 2010Date of Patent: May 22, 2012Assignee: Sumitomo Rubber Industries, Ltd.Inventor: Kazuo Hochi
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Patent number: 8173738Abstract: The present invention provides a rubber composition for a tire which makes it possible to consider an effect on environment, prepare for decrease in supply quantity of petroleum in future and improve weather resistance and rubber strength in good balance, and a tire prepared by using the rubber composition. The rubber composition of the present invention comprises not less than 20 parts by weight of a silica, not more than 5 parts by weight of a carbon black and 2 to 20 parts by weight of a turpentine soot and/or lamp black having an average particle diameter of not more than 1,000 nm, based on 100 parts by weight of a rubber component comprising a natural rubber and/or an epoxidized natural rubber, and a tire prepared by using the rubber composition.Type: GrantFiled: September 21, 2011Date of Patent: May 8, 2012Assignee: Sumitomo Rubber Industries Ltd.Inventors: Tomoaki Hirayama, Takao Wada
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Publication number: 20120108738Abstract: The present invention provides a rubber crawler with high durability by using the rubber composition, wherein said rubber composition exhibits enhanced adherence between rubber and metal reinforcing material, such as steel cord and the like, particularly adherence after heat aging and under high humidity, without using vulcanizing retarder, such as CTP, which has possibility of generating problems, such as blooming and lowering rubber physical properties after vulcanization; using vulcanization accelerator having the adequate vulcanization retarding effect exerting excellent working ability; lowering rubber scorching as much as possible. The rubber crawler of the present invention comprises a rubber composition as the treatment rubber thereof, which comprises in the amount of 0.1 to 10 parts by weight of sulfenamide-containing vulcanization accelerator, 0.03 to 3 parts by weight of cobalt-containing composition as the equivalent amount of cobalt and 0.Type: ApplicationFiled: June 25, 2010Publication date: May 3, 2012Applicant: BRIDGESTONE CORPORTATIONInventor: Yoshikazu Tanimoto
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Publication number: 20120108732Abstract: The present invention provides: a white turbid dispersion liquid of a chemical for rubber, containing the chemical for rubber at a concentration of 1% by mass or more; a method for producing the white turbid dispersion liquid of a chemical for rubber, containing mixing a solution containing a chemical for rubber dissolved in a good solvent for the chemical for rubber, with a poor solvent for the chemical for rubber; and a wet master batch containing a chemical for rubber, containing a liquid mixture containing the white turbid dispersion liquid of a chemical for rubber, and a rubber latex, or a rubber latex and a filler slurry, the liquid mixture being coagulated, and thus provides: the dispersion liquid of a chemical for rubber that is for making various chemicals for rubber be contained in a rubber wet master batch with good dispersibility; the method for producing the same; and the rubber master batch that provides a rubber composition enhanced in thermal aging resistance, reinforcing property, elastic modType: ApplicationFiled: April 22, 2010Publication date: May 3, 2012Applicant: BRIDGESTONE CORPORATIONInventors: Atsushi Nakayama, Takeshi Kasai, Masaaki Izuchi, Fumiteru Nishiura
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Publication number: 20120101219Abstract: A process for manufacturing a vulcanized rubber comprising the first step of kneading S-(3-aminopropyl)thiosulfuric acid and/or a metal salt thereof, a rubber component, a filler and a sulfur component to obtain a kneaded product, and the second step of subjecting the kneaded product obtained in the first step to a heat treatment.Type: ApplicationFiled: June 23, 2010Publication date: April 26, 2012Applicant: SUMITOMO CHEMICAL COMPANY, LIMITEDInventors: Orhan Ozturk, Yasuo Uekita, Kenichi Takeuchi
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Patent number: 8163838Abstract: A process of producing an artificial latex, comprising the steps: (a) cement formation, wherein a rubber is dissolved in a suitable hydrocarbon solvent; (b) emulsification of the cement formed in step (a), together with an aqueous soap solution, thus forming an oil-in-water emulsion; (c) hydrocarbon solvent removal, resulting in a latex of the rubber having particles of a median particle size in the range of from about 0.5 to 2.0 ?m, and optionally (d) latex concentration, forming an artificial latex with a higher solids content, characterized in that in step (b) a premix is formed first, which is subsequently homogenized into an oil-in-water emulsion, and wherein the premix is formed by mixing the cement with the aqueous soap solution at a volume ratio of 1:1.Type: GrantFiled: December 18, 2007Date of Patent: April 24, 2012Assignee: Kraton Polymers US LLCInventors: Adrie A. Van Der Huizen, Marc S. Sonderman, Arwin W. Van Der Waal, Wouter De Jong, Anton Nicolai
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Publication number: 20120083571Abstract: A rubber composition, comprising a rubber component, and a carbon black, the carbon black satisfying the dibutyl phthalate (DBP) absorption number [unit: mL/100 g] of the carbon black is from 90 to 180, the difference of the BET specific surface area (BET5) [unit: m2/g] of the carbon black from the external specific surface area (STSA) [unit: m2/g] thereof satisfies the following: 5<(BET5)?(STSA)<12, the ratio between the Stokes diameter (Dst) of the carbon black and the Stokes diameter distribution (?D?50 (half band width)) thereof satisfies the following: 0.70<the ratio of (?D?50)/(Dst)<1.10, and the ratio between the BET specific surface area (BET5) [unit: m2/g] of the carbon black and the iodine adsorption number (IA) [unit: mg/g] thereof satisfies the following: 1.05<the ratio of (BET5)/(IA)<1.35.Type: ApplicationFiled: August 16, 2011Publication date: April 5, 2012Applicant: TOYO TIRE & RUBBER CO., LTD.Inventor: Shinya Hasegawa
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Publication number: 20120082791Abstract: Waterborne, polymer based coating compositions for interior and exterior use on elastomeric substrates (such as tires) with one or more polymer latex resins (having one or more carboxylic acid groups) in an amount sufficient to provide polymer solids in an amount of from 5 to 50% by weight of the coating; optionally one or more coalescing agents in an amount effective to coalesce and fuse polymer particles of the polymer latex resin into a relatively stretchable film when cured; one or more defoaming agents in an amount effective to enhance foam dissipation prior to film formation; one or more coupling agents having a first reactive group which is capable of bonding with the one or more carboxylic acid groups and a second reactive group which is capable of bonding with an elastomers substrate. Also, a method for applying such compositions to elastomeric substrates, such as tires.Type: ApplicationFiled: September 20, 2011Publication date: April 5, 2012Inventor: Robert Richard Liversage
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Patent number: 8148452Abstract: The object of the present invention is provide a rubber composition for coating a tire cord, which improves adhesion with a tire cord and has an effect of recovering adhesion with a tire cord at hygrothermal aging with maintaining the initial vulcanization rate. The present invention relates to a rubber composition for coating a tire cord comprising 0.7 to 3 parts by weight of benzothiazolyl sulfenamide or benzothiazolyl sulfenimide represented by the chemical formula (1): (wherein R1 is a linear alkyl group having a branched structure of 3 to 16 carbon atoms, and R2 is a linear alkyl group having a branched structure of 3 to 16 carbon atoms or a benzothiazolyl sulfide group) and 3 to 7 parts by weight of sulfur based on 100 parts by weight of a rubber component containing at least 60% by weight of a natural rubber and/or an isoprene rubber.Type: GrantFiled: May 30, 2008Date of Patent: April 3, 2012Assignee: Sumitomo Rubber Industries, Ltd.Inventor: Tatsuya Miyazaki
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Patent number: 8143344Abstract: The present invention is further directed to a method of producing a particulate composite of silica and elastomer comprising the steps of dispersing a diene based elastomer in a hydrophobic liquid to form an elastomer dispersion; mixing the elastomer dispersion with an aqueous solution of an alkali metal silicate to form a mixture; adding a precipitating agent to the mixture to precipitate a porous silica onto the dispersed elastomer to form a particulate composite of silica and elastomer comprising a porous silica shell at least partially surrounding a core of diene based elastomer; and optionally adding a separating agent to remove the hydrophobic liquid from the particulate composite.Type: GrantFiled: December 3, 2009Date of Patent: March 27, 2012Assignee: The Goodyear Tire & Rubber CompanyInventors: Georges Koster, Wolfgang Lauer
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Publication number: 20120067447Abstract: A method of delivering a concentrated quantity of sealing elements to a leak site in a vessel (1) comprises the steps of deploying a flexible body of material (4) and at least one sealing element (3) into fluid (2) flowing within the vessel upstream of the leak site whereby the body of material transports the sealing elements through the vessel to the leak site where the body of material is drawn to the leak by fluid flow created by a pressure differential at the leak site, and wherein the sealing element(s) are constrained by the body of material at the leak site such that the sealing element(s) become(s) entrained within the leak.Type: ApplicationFiled: April 16, 2010Publication date: March 22, 2012Inventor: Nicholas John Ryan
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Patent number: 8138260Abstract: By a rubber composition for a side wall, including a rubber component containing a natural rubber component consisting of a natural rubber and a modified natural rubber, 20 to 60 parts by mass of silica, and 0.5 to 15 parts by mass of at least any one of a terpene-based resin and a rosin-based resin based on 100 parts by mass of the rubber component, and a pneumatic tire provided with a side wall rubber using the same, a rubber composition for a side wall in which both of maintenance of properties desired in a rubber composition for a side wall such as durability and improvement in processibility can be realized while a use amount of a raw material derived from a petroleum source is reduced, and a pneumatic tire in which running safety is improved by providing with a side wall rubber using the same, are provided.Type: GrantFiled: March 14, 2008Date of Patent: March 20, 2012Assignee: Sumitomo Rubber Industries, Ltd.Inventor: Issei Nakakita
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Publication number: 20120065325Abstract: Provided are a rubber composition including: a rubber component formed of a diene-based rubber; and a filler, in which when an actual density determined by JIS K6268 method A is represented by dc, and a density and a mass fraction of a component i determined by constituent analysis are represented by di and ?i, respectively, dc·?(?i/di)?0.980 satisfies a specific relationship, and hence the rubber composition reduces the weight of a tire without reducing the durability of the tire such as abrasion resistance and achieves a high level of balance between the weight reduction and a reduction in the rolling resistance of the tire, and a pneumatic tire using the composition.Type: ApplicationFiled: April 22, 2010Publication date: March 15, 2012Applicant: BRIDGESTONE CORPORATIONInventor: Atsushi Nakayama
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Publication number: 20120065324Abstract: The present invention provides an oil extended rubber for a tire, which is obtained by a process for preparing an oil extended rubber for a tire, comprising: (a) a step of preparing an oil-in-water type emulsion by emulsifying a vegetable oil having an iodine value of not less than 135 with a surfactant; (b) a step of mixing said emulsion of vegetable oil and a modified natural rubber latex, and then maturing the mixture; and (c) a step of coagulating the mixture obtained in the step (b) to obtain a lump of a rubber.Type: ApplicationFiled: September 19, 2011Publication date: March 15, 2012Inventors: Toshiaki Sakaki, Naoya Ichikawa, Takayuki Hattori, Chee-Cheong Ho, Choong Dick Hean
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Publication number: 20120053264Abstract: Provided are a process for efficiently producing a rubber wet master batch in which a dispersibility of carbon black in the rubber is improved, in which a reinforcing property and an abrasion resistance of the rubber can be enhanced by using carbon black having a high surface activity, in which a yield of the carbon black in the wet master batch obtained is not reduced and in which a handling property of the carbon black is good as compared with master batches prepared by using a granulated and dried substance of carbon black prepared by a conventional wet method and non-granulated carbon black, a carbon black-containing rubber wet master batch obtained by the above process and a rubber composition and a tire prepared by using the master batch.Type: ApplicationFiled: March 16, 2010Publication date: March 1, 2012Applicants: ASAHI CARBON, BRIDGESTONE CORPORATIONInventors: Atsushi Nakayama, Masaaki Izuchi, Fumiteru Nishiura, Takeshi Kasai, Kenji Hara, Takashi Yagi
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Publication number: 20120046413Abstract: A pneumatic tire obtained by using a rubber composition containing 100 parts by mass of a rubber component comprising at least one of natural rubber and diene base synthetic rubber, 20 to 150 parts by mass of precipitated silica as a filler in which a cetyltrimethylammonium bromide-adsorbing specific surface area (CTAB) (m2/g) and the mode Aac in diameters (nm) of primary aggregates determined by acoustic measurement of particle size distribution satisfy equation (A) shown below and in which a difference between an ignition loss (mass reduction % when heated at 750° C. for 3 hours) and a heating loss (mass reduction % when heated at 105° C. for 2 hours) satisfies equation (B) shown below and 1 to 25 parts by mass of at least one specific sulfur-containing silane compound as a silane coupling agent: Aac??0.Type: ApplicationFiled: April 28, 2010Publication date: February 23, 2012Applicant: BRIDGESTONE CORPORATIONInventor: Naohiro Sasaka
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Publication number: 20120040118Abstract: A rubber latex composition is disclosed having reduced allergenicity. Methods for producing a rubber latex composition having reduced allergenicity are also disclosed.Type: ApplicationFiled: October 28, 2011Publication date: February 16, 2012Applicant: Vystar CorporationInventors: William Doyle, Matthew Clark, Travis Honeycutt
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Patent number: 8110625Abstract: Provided is a rubber composition comprising an inorganic filler, a compound having at least one group A reacting with a rubber and two or more groups B adsorbing on the inorganic filler described above in the same molecule, a compound having the group A reacting with a rubber and an amino group in the same molecule or acrylate or methacrylate having a specific structure and further comprising, if necessary, a silane coupling agent. This makes it possible to provide a rubber composition which is excellent in the dispersibility of an inorganic filler, so that it does not elevate a viscosity of a non-vulcanized rubber and does not damage the processability and which does not bring about roughening on the surface of a rubber and is improved in a storage modulus.Type: GrantFiled: August 4, 2010Date of Patent: February 7, 2012Assignees: Bridgestone Corporation, Kao CorporationInventors: Daisuke Nohara, Masaaki Tsuchihashi, Isao Nishi, Tetsuo Takano
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Publication number: 20110306700Abstract: The invention relates to a rubber composition that is free of zinc or that contains less than 0.5 phr of zinc, which can be used for the manufacture of tyres, based on at least: one diene elastomer; one sulphur-based crosslinking system; one inorganic filler as reinforcing filler; one blocked mercaptosilane of general formula I below: (R3O)R2R1—Si—Z—S—C(?O)-A in which: R1 and R2, which are identical or different, represent a monovalent hydrocarbon-based group chosen from alkyls, which are linear or branched, cycloalkyls or aryls, having from 1 to 18 carbon atoms; R3 represents a monovalent hydrocarbon-based group chosen from linear or branched alkyls having from 1 to 4 carbon atoms; A represents hydrogen or a monovalent hydrocarbon-based group chosen from alkyls, which are linear or branched, cycloalkyls or aryls, having from 1 to 18 carbon atoms; Z represents a divalent bonding group comprising from 1 to 18 carbon atoms.Type: ApplicationFiled: December 18, 2009Publication date: December 15, 2011Applicant: Michelin Recherche ET Technique S.A.Inventors: Laure Belin, Karine Longchambon, José Carlos Araujo Da Silva
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Patent number: 8053496Abstract: A process for producing a rubber wet master batch contains at least a filler, a dispersing solvent and a rubber latex liquid as raw materials, comprising: a step (I) of, at the time of dispersing the filler into the dispersing solvent, adding at least one portion of the rubber latex liquid thereto, thereby preparing a slurry containing the filler to which rubber latex particles adhere; a step (II) of mixing the slurry with the rest of the rubber latex liquid, thereby preparing the rubber latex liquid containing the rubber-latex-particle-adhering filler; and a step (III) of solidifying and drying the rubber latex liquid containing the rubber-latex-particle-adhering filler.Type: GrantFiled: April 18, 2011Date of Patent: November 8, 2011Assignee: Toyo Tire & Rubber Co., Ltd.Inventors: Norio Minouchi, Takashi Miyasaka
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Patent number: 8048951Abstract: A rubber latex composition is disclosed having reduced allergenicity. Methods for producing a rubber latex composition having reduced allergenicity are also disclosed.Type: GrantFiled: January 20, 2009Date of Patent: November 1, 2011Assignee: Vystar CorporationInventors: William Doyle, Matthew Clark, Travis Honeycutt
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Patent number: 8044118Abstract: The present invention provides a process for preparing an oil extended rubber, in which an effect on environments can be taken into consideration, provision for the future decrease of petroleum supply can be satisfied, and further, strength is excellent without molecular breakage, an oil extended rubber obtained by the preparation process, and a tire using the oil extended rubber. A process for preparing an oil extended rubber, comprising (a) a step of preparing an oil-in-water type emulsion by emulsifying a vegetable oil having an iodine value of not less than 135 with a surfactant, (b) a step of mixing said emulsion and a modified natural rubber latex, and then aging the mixture, and (c) a step of coagulating the mixture obtained in the step (b) to obtain a lump of a rubber, an oil extended rubber obtained by the preparation process, and a rubber composition for a tire and a tire which use the oil extended rubber.Type: GrantFiled: March 21, 2007Date of Patent: October 25, 2011Assignee: Sumitomo Rubber Industries, Ltd.Inventors: Toshiaki Sakaki, Naoya Ichikawa, Takayuki Hattori, Chee-Cheong Ho, Choong Dick Hean
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Patent number: 8044131Abstract: There is provided a rubber composition for a tread having excellent hardness and improving the processability and grip performance of a tire, and a tire comprising thereof. A rubber composition for a tread comprising 30 to 80 parts by weight of silica having a BET specific surface area of less than 150 m2/g and 10 parts by weight or less of carbon black based on 100 parts by weight of a rubber component comprising an epoxidized natural rubber, and a tire comprising thereof.Type: GrantFiled: January 5, 2006Date of Patent: October 25, 2011Assignee: Sumitomo Rubber Industries, Ltd.Inventors: Tomoaki Hirayama, Takao Wada, Mamoru Uchida
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Patent number: 8044133Abstract: The present invention provides a rubber composition for a tire which makes it possible to consider an effect on environment, prepare for decrease in supply quantity of petroleum in future and improve weather resistance and rubber strength in good balance, and a tire prepared by using the rubber composition. The rubber composition of the present invention comprises not less than 20 parts by weight of a silica, not more than 5 parts by weight of a carbon black and 2 to 20 parts by weight of a turpentine soot and/or lamp black having an average particle diameter of not more than 1,000 nm, based on 100 parts by weight of a rubber component comprising a natural rubber and/or an epoxidized natural rubber, and a tire prepared by using the rubber composition.Type: GrantFiled: June 14, 2007Date of Patent: October 25, 2011Assignee: Sumitomo Rubber Industries, Ltd.Inventors: Tomoaki Hirayama, Takao Wada
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Publication number: 20110253285Abstract: The present invention relates to a natural rubber that contains 200 ppm or less of phosphorus.Type: ApplicationFiled: December 14, 2009Publication date: October 20, 2011Inventors: Naoya Ichikawa, Toshiaki Sakaki, Sumiko Miyazaki, Tomohiro Hosokawa, Ai Matsuura
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Patent number: 8039546Abstract: This invention provides a modified natural rubber latex formed by charging a polar group-containing mercapto compound into a natural rubber latex to add the polar group-containing mercapto compound to a natural rubber molecule in the natural rubber latex, a modified natural rubber formed by coagulating and drying the modified natural rubber latex, and the rubber composition using the modified natural rubber and being excellent in the low loss factor, wear resistance and fracture characteristics.Type: GrantFiled: November 25, 2005Date of Patent: October 18, 2011Assignee: Bridgestone CorporationInventor: Hajime Kondou
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Patent number: 8013054Abstract: Elastomeric compositions comprising at least one C4 to C7 monoolefin elastomer, at least one polyalphaolefin, and optionally at least one hydrocarbon polymer additive are disclosed. The PAO comprises oligomers of one or more C2 to C20 alpha-olefins having a kinematic viscosity at 100° C. of 3 to 3000 cSt and a Mw/Mn of less than 4. In one aspect, the elastomeric composition may have improved flex fatigue properties and have a fatigue life of 450,000 Kc or more as measured by ASTM D 412 die C. In another aspect, an elastomeric composition may have improved impermeability and have a permeation coefficient at 40° C. of 160 cc*mm/(m2?day) or less.Type: GrantFiled: June 26, 2009Date of Patent: September 6, 2011Assignee: ExxonMobil Chemical Patents Inc.Inventors: Michael Brendan Rodgers, David J. Lohse, Scott C. Solis, Rick D. Davis, Jung Hun Lee
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Publication number: 20110196085Abstract: Biomarker stabilizing agents. In at least one embodiment of a stabilizing bead of the present disclosure, the stabilizing bead comprises a latex particle having a carboxylate group, and a stabilizing agent functionally coupled to the latex particle, wherein the stabilizing agent is capable of completely or substantially preventing the degradation or inactivation of a diagnostic agent in close proximity to the stabilizing agent. Optionally, an embodiment of a stabilizing bead may further comprise at least one of human serum albumin (HSA) and bovine serum albumin (BSA). Moreover, an embodiment of a stabilizing bead of the present disclosure may further comprise a linker group coupled to latex particle.Type: ApplicationFiled: October 18, 2010Publication date: August 11, 2011Inventors: Richard H. Selinfreund, Rakesh Vig, Richard P. Gill
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Patent number: 7989546Abstract: The Invention relates to a method for the preservation of natural rubber latex comprising the step of adding to natural latex at least one hydrophobically modified saccharide. The hydrophobically modified saccharide is preferably a hydrophobically modified fructan, a hydrophobically modified starch hydrolysate, or a mixture thereof. The invention further relates to a natural rubber latex containing a hydrophobically modified saccharide, and to vulcanized natural rubber products containing a hydrophobically modified saccharide.Type: GrantFiled: March 4, 2008Date of Patent: August 2, 2011Assignee: Beneo-Orafti S.A.Inventors: Karl Booten, Amir Hashim Bin Yatim, Manroshan Singh
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Publication number: 20110184121Abstract: A method of producing a polymer latex drag reducer. The method begins by forming an aqueous solution comprising a surfactant, a buffer and water. The method then forms an organic solution comprising a monomer and a co-stabilizer. The aqueous solution and the organic solution are mixed to form an emulsion. The emulsion is then subjecting to a high shear device to produce a miniemulsion, wherein the monomers are broken into small droplets followed by polymerizing the miniemulsion with the addition of an initiator, wherein a nucleation occurs in the small monomer droplets.Type: ApplicationFiled: January 26, 2011Publication date: July 28, 2011Applicant: ConocoPhillips CompanyInventors: Zhiyi Bao, Kenneth W. Smith
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Publication number: 20110180195Abstract: Alkoxy-modified silsesquioxane compounds are described. The alkoxy-modified silsesquioxane compounds contain an alkoxysilane group that participates in an alkoxysilane-silica reaction as a silica dispersing agent in rubber, with the release of zero to about 0.1% by weight of the rubber of volatile organic compounds (VOC), especially alcohol, during compounding and further processing. Further described are methods for making alkoxy-modified silsesquioxanes, methods for making vulcanizable rubber compounds containing alkoxy-modified silsesquioxanes, vulcanizable rubber compounds containing alkoxy-modified silsesquioxanes, and pneumatic tires comprising a component that contains alkoxy-modified silsesquioxanes.Type: ApplicationFiled: September 16, 2010Publication date: July 28, 2011Applicant: Bridgestone CorporationInventors: William L. Hergenrother, Chenchy J. Lin, Terrence E. Hogan, Ashley S. Hilton
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Publication number: 20110178235Abstract: The present invention provides a rubber composition for an inner liner, which can achieve both excellent low heat build-up and high flex crack growth resistance while having processability excellent enough to eliminate the need for mastication, and further has good air impermeability, and also provides a pneumatic tire produced using the rubber composition. The present invention relates to a rubber composition for an inner liner, including: a rubber component that contains a modified natural rubber with a phosphorus content of 200 ppm or less, and carbon black and/or a white filler.Type: ApplicationFiled: January 14, 2011Publication date: July 21, 2011Inventor: Mutsuki SUGIMOTO