Abstract: The disclosed invention provides starting compositions for making lignin hybrid polymers, reactions of lignin and polymer precursors to manufacture lignin hybrid polymers, and final lignin hybrid polymers produced. The most important process requirement is the compatibility of lignin and polymer precursors. Lignin and the polymer precursors must be compatible to assure that the lignin and polymers precursors react and produce a lignin hybrid polymer with useful properties. The lignin hybrid polymers can be in the form of a polyol, a thermoplastic resin, or a thermoset resin. The lignin hybrid polyol, thermoplastic resin, or thermoset resin can be used in a wide range of products including, but not limited to, coatings, adhesives, sealants, elastomers, binders, thermoset resins, thermoplastic resins, and polyurethane systems.

Abstract: The disclosed invention provides starting compositions for making lignin hybrid polymers, reactions of lignin and polymer precursors to manufacture lignin hybrid polymers, and final lignin hybrid polymers produced. The most important process requirement is the compatibility of lignin and polymer precursors. Lignin and the polymer precursors must be compatible to assure that the lignin and polymers precursors react and produce a lignin hybrid polymer with useful properties. The lignin hybrid polymers can be in the form of a polyol, a thermoplastic resin, or a thermoset resin. The lignin hybrid polyol, thermoplastic resin, or thermoset resin can be used in a wide range of products including, but not limited to, coatings, adhesives, sealants, elastomers, binders, thermoset resins, thermoplastic resins, and polyurethane systems.

Abstract: Compositions for forming an improved vapor mitigation barrier are contemplated, such compositions being formed as an aqueous mixture of an asphalt component and a latex component, with the latex component including a chemically resistant latex, the chemically resistant latex being an acrylonitrile butadiene copolymer, an elastomeric fluoropolymer, or both. Such compositions, when cured and formed into a vapor mitigation barrier, may be seen to substantially mitigate diffusion of chlorinated hydrocarbons across the barriers. Also contemplated are methods for forming such vapor mitigation barriers, as well as vapor mitigation barrier products formed via the application of such compositions to various substrates.

Abstract: A tack coat includes a first phase and a second phase. The first phase includes asphalt, and the second phase includes an emulsifier and a rheology modifier. Optionally, the second phase also includes a material insoluble in the water. The pH of the second phase can be between 1-3, 6-8, or 9-13.

Abstract: A pavement composition includes a recycled hot mix asphalt (HMA) sheet mix composition including more than 50% and up to 100% recycled fines mixed with a rejuvenating agent. The recycled fines of the HMA sheet mix are separated from a reclaimed asphalt pavement (RAP) composition and substantially all of the recycled fines are capable of passing through a sieve having an opening size of ? inch (9.5 mm). Pavement systems include an existing pavement layer and a thin-lift overlay made of the recycled HMA sheet mix on the existing pavement layer. Pavement systems also include a three-layer system including a leveling course layer, an interlayer, and a surface course layer in which the leveling course layer and/or the surface course layer include a recycled HMA sheet mix composition.

Abstract: A nonvolatile cold modified asphalt binder and a nonvolatile cold recycled asphalt mixture using the same are manufactured by optimally mixing a petroleum asphalt, a native asphalt, a polymer modifier, process oil, and an adhesive strength enhancer. The nonvolatile cold modified asphalt binder includes at least one petroleum asphalt selected from a straight asphalt or a blown asphalt; at least one native asphalt selected from gilsonite, glance pitch, and grahamite; a rubber-modified-compound (RMC) polymer modifier which is a vinyl aromatic hydrocarbon-conjugated diene block copolymer including at least one of a styrene-butadiene block copolymer (SBS), a styrene-isoprene block copolymer (SIS), and a styrene-ethylene-butylene block copolymer (SEBS); at least one process oil selected from paraffin oil, naphthenic oil, aromatic oil, natural oil, and mineral oil; and at least one adhesive strength enhancer selected from rosin esters, modified acryls, modified silicones, polyvinyl esters, and silicone resins.

Abstract: An inkjet receiving medium having enhanced surface properties has a substrate and a topcoat layer disposed thereon. The topcoat layer has: (a) one or more water-soluble salts of a multivalent metal cation; and (b) composite particles having a Rockwell Hardness of less than or equal to R90 and each of the composite particles comprising domains of a (i) first organic polymer and domains of a (ii) second organic polymer. The domains of the (ii) second organic polymer are dispersed within the domains of the (i) first organic polymer. The melting point of the (i) first organic polymer is lower than the melting point of the (ii) second organic polymer. The weight ratio of the (i) first organic polymer to the (ii) second organic polymer is chosen such that the (b) composite particles have a density of 1.0-1.5 g/ml.

Abstract: An aqueous composition can be used for pre-treating a substrate prior to inkjet printing. This composition includes: (a) one or more water-soluble salts of a multivalent metal cation; and (b) composite particles having a Rockwell Hardness of less than or equal to R90 and each of the composite particles comprising domains of a (i) first organic polymer and domains of a (ii) second organic polymer. The domains of the (ii) second organic polymer are dispersed within the domains of the (i) first organic polymer. Moreover, the melting point of the (i) first organic polymer is lower than the melting point of the (ii) second organic polymer. The weight ratio of the (i) first organic polymer to the (ii) second organic polymer is chosen such that the (b) composite particles have a density of 1.0-1.5 g/ml.

Abstract: This invention encompasses asphalt cement emulsions, as well as methods for preparing a pre-treated rubber-modified asphalt cement emulsions and methods for coating industrial surfaces using asphalt cement emulsions.

Abstract: The present invention relates a novel approach to prepare Polymer Modified Bitumen by using terephthalamide additives, derived from PET, for improving bitumen quality. Particularly, the present invention provides a process to utilize waste PET, which is a threat to environment and is available commercially in different physical forms, for conversion into industrially useful additive for bituminous product.

Abstract: Adhesive compound as a permeant barrier, comprising (i) block copolymers having a construction A-B-A, (A-B)n, (A-B)nX, or (A-B-A)nX, where X is the radical of the coupling reagent, n is a whole number between 2 and 10, A is a polymer made of a vinyl aromatic compound and B is a polymer block made of an alkene or diene, wherein this polymer block can also be hydrated, with the condition that at least part of the A blocks is sulfonated, optionally with two-block copolymers in the form of A-B as an admixture component, and (ii) at least one tackifier resin.

Abstract: Temperature-stable adhesive compound, comprising (i) block copolymers having a construction A-B-A, (A-B)n, (A-B)nX, or (A-B-A)nX, where X is the radical of a coupling reagent, n is an integer between 2 and 10, A is a polymer block of a vinylaromatic, and B is a polymer block of an alkene or diene, at least some of the A blocks being sulfonated, and optionally diblock copolymers of the form A-B, and (ii) at least one tackifier resin, and (iii) at least one metal complex with a substitutable complexing agent.

Abstract: Provided herein is a tack coat for use with paving applications and a method of making the same. The tack coat is substantially non-tracking, and includes asphalt, a pH adjustor, an emulsifier, acrylic, and water. In certain embodiments, the tack coat may also include a stabilizer to prevent settling of the emulsion during storage. The method of producing the tack coat involves heating the asphalt in one tank, and heating the water and emulsifier in a second, separate tank. This mixture of the water and emulsifier is referred to as soap, and is then mixed with asphalt, and the acrylic may be added to the mixture immediately thereafter, with a stabilizer, or later, just prior to shipment of the product, in which case a stabilizer may not be required. The tack coat exhibits moderate softness, with a penetration value above 40 dmm.

Abstract: A composition is provided for use in a pavement surface, comprising (a) asphalt in an amount of from 40 to 70 parts by weight; (b) an electrically neutral copolymer in an amount of from greater than 0 to 10 parts by weight; (c) an emulsifier in an amount of from 0.1 to 4 parts by weight; (d) an acid or a base in an amount of from 0.1 to 4 parts by weight; and (e) water in an amount of from 25 to 60 parts by weight. A method of making a composition, a method of applying a composition, and a paved surface is also disclosed.

Abstract: An acid modified asphalt binder is combined with an emulsifier solution to produce an emulsified asphalt binder. The acid modified asphalt binder may be formed by combining an asphalt binder, a phosphorous-based acid, and, optionally, a polymer modifier. The emulsifier solution may be produced by forming an aqueous solution of an amine and a phosphorous-based acid, which forms an aqueous solution comprising an amine phosphate. The emulsified asphalt binder may be combined with an aggregate to form a paving material. In other examples, the emulsified asphalt binder may be used alone, for example in a chip seal application, or in a diluted form, for example in a fog seal application.

Abstract: A non-carboxylated styrene-butadiene copolymer, preparation method and use thereof are provided. The non-carboxylated styrene-butadiene copolymer is prepared by hot polymerization in the absence of acid monomers and is used in asphalt-based systems such as asphalt emulsions.

Abstract: This invention encompasses asphalt cement emulsions, as well as methods for preparing a pre-treated rubber-modified asphalt cement emulsions and methods for coating industrial surfaces using asphalt cement emulsions.

Abstract: One embodiment provides a process for preparing an asphalt-coated crumb rubber composition that meets the specification set forth in ASTM D80-02 or deviations thereof which may be established by the specifying agency from time to time. The process generally comprises obtaining asphalt of different penetration grades, combining the asphalt of each grade with preselected chemicals to form separate premixed components, blending the premixed components together under predetermined conditions to form, upon curing, an asphalt-coated crumb rubber composition that meets certain physical requirements for asphalt-rubber binder (ARB), such as those set forth in ASTM D8-02. Advantageously, the resulting asphalt-coated crumb rubber composition not only meets the physical requirements of ARB used in road paving but also has improved dispersion of the rubber, such as dispersion of the rubber in an oil-in-water emulsion of an asphalt.

Abstract: A method of producing a cationic asphalt slurry composition which can be used as an asphalt paving sealer or as a paving or repair composition. In the method and composition, latex and other polymers are used to build viscosity and a pH buffering filler is added to prevent flocculation. Consequently, the cationic composition can be stored without irreversibly settling or separating, and without breaking for several days prior to use. In addition, non-expansive clay and a polar polymer hardening agent are used so that, when applied, the composition will set and develop strength very quickly.

Abstract: The present invention is related to dispersion compositions and asphalt compositions including the dispersion compositions. The dispersion compositions include a microgels dispersed in a continuous oil phase. The dispersed microgels include at least one water swollen/swellable polymer, water soluble polymer, or combination thereof. The asphalt compositions include bitumen, aggregate, and a dispersion composition having a microgels dispersed in oil. The dispersed microgels include at least one water swollen/swellable polymer, water soluble polymer, or combination thereof.

Abstract: A method of manufacturing a wood product including using a water and wax mixture with wood particles in a production process of wood products, wherein the wax mixture includes a hydrocarbon wax, and a water-repellant material selected from the group consisting of (a) an asphaltite, (b) a polyolefin copolymer, (c) a polyolefin synthetic wax, and (d) combinations thereof, and forming a wood product.

Abstract: A polymer-modified emulsion used for rejuvenating or repairing deteriorated asphalt pavement includes an asphalt phase containing an asphalt and a rejuvenating agent, and an aqueous phase including water, an acrylic polymer or copolymer and an emulsifying agent.

Abstract: One embodiment provides a process for preparing an asphalt-coated crumb rubber composition that meets the specification set forth in ASTM D80-02 or deviations thereof which may be established by the specifying agency from time to time. The process generally comprises obtaining asphalt of different penetration grades, combining the asphalt of each grade with preselected chemicals to form separate premixed components, blending the premixed components together under predetermined conditions to form, upon curing, an asphalt-coated crumb rubber composition that meets certain physical requirements for asphalt-rubber binder (ARB), such as those set forth in ASTM D8-02. Advantageously, the resulting asphalt-coated crumb rubber composition not only meets the physical requirements of ARB used in road paving but also has improved dispersion of the rubber, such as dispersion of the rubber in an oil-in-water emulsion of an asphalt.

Abstract: Disclosed herein are an asphalt concrete mixture, an asphalt binder composition, and methods of preparing the related compositions. The asphalt binder compositions include a polyphosphoric acid, a macromolecular polymer having a saturated backbone with macromolecular modifications, and sulfur. The compositions are capable of being performance graded.

Abstract: Methods and compositions for improving the strength and longevity of secondary roadways through environmentally sound practices are disclosed herein. A composition for road sealing includes acrylic and vinyl acetate powdered polymer mixed with native soil.

Abstract: The invention is a method of treating, restoring or sealing a surface comprising applying an emulsion comprising a latex polymer, a cationic emulsifier, and optionally a recycling agent to the surface to wet the surface and depositing a surface treatment layer on the surface, wherein the depositing step occurs while the surface is wetted. The invention also includes a surface pretreatment composition comprising water, at least one acrylic latex polymer, an aromatic recycling agent, and at least one cationic emulsifier. Furthermore, the invention includes the surface resulting from the application of the emulsion used in the invention and concentrated emulsions for use with the surface treatment composition.

Abstract: A process for improving the rheological properties of an aqueous dispersion comprising adding a rheology modifier to the aqueous dispersion, and then adding a water soluble synthetic polymer flocculant to the aqueous dispersion. The rheology modifier may be selected from the group consisting of natural polymers, semi-natural polymers, synthetic materials and combinations thereof. The water soluble synthetic polymer flocculant may be selected from the group consisting of water soluble anionic polymers, cationic polymers, amphoteric polymers, nonionic polymers, and combinations thereof.

Abstract: Aqueous liquid and moisture vapor are added to water absorbent resin powder so that particles of the water absorbent resin powder are bound. Supplying the aqueous liquid and moisture vapor to the water absorbent resin powder reduces the amount of particles that remain unbound (ungranulated) and increases the concentration of the water absorbent resin bound particles to provide improved drying efficiency and to obtain particulate water absorbent resin having excellent properties even when the bound particles are highly concentrated. The present invention provides (i) a method for binding water absorbent resin and (ii) a method for producing particulate water absorbent resin including the step of binding particles of water absorbent resin powder.

Abstract: A non-carboxylated styrene-butadiene copolymer, preparation method and use thereof are provided. The non-carboxylated styrene-butadiene copolymer is prepared by hot polymerization in the absence of acid monomers and is used in asphalt-based systems such as asphalt emulsions.

Abstract: Styrene-based copolymers having acid monomer units, dispersions, preparation method and use thereof are provided. The styrene-based copolymer is prepared by polymerizing styrene, one or more acid monomers, and optionally butadiene at a temperature of 40° C. or greater and then is vulcanized. The obtained styrene-based copolymer is used in asphalt-based systems.

Abstract: A method of manufacturing a water-resistant gypsum product including forming an aqueous mixture of gypsum, water and a wax mixture, wherein the wax mixture includes a hydrocarbon wax, and a substitute material selected from the group consisting of (a) an asphaltite, (b) a polyolefin homopolymer, (c) a polyolefin copolymer, and (d) combinations thereof; and forming the mixture into a structure, and drying the structure while permitting hydration of the gypsum to form a gypsum product.

Abstract: The present disclosure generally relates to formulations of, and methods of making and using, recycled reclaimed asphalt pavement.

Abstract: The disclosure relates generally to the use of low molecular weight polymers to aggregate mineral components in aqueous mineral slurries to release and separate individual components of the slurry, which may then be recovered from the slurry.

Abstract: Provided are a polychloroprene latex giving a rubber-asphalt composition superior in low-temperature stability and film-forming property on the material to be coated, a rubber-asphalt composition and a utilization method thereof, a sheet, and a waterproof coating film. The rubber-asphalt composition includes a major agent containing 10 to 40 mass % of the anionic polychloroprene latex comprising potassium ions in an amount of 0.7 to 1.5 parts by mass and sodium ions in an amount of controlled to be 0.2 part by mass or less with respect to 100 parts by mass of the solid matter and 60 to 90 mass % of an anionic asphalt emulsion; and a coagulating agent of an aqueous solution containing a polyvalent metal salt as the principal component.

Abstract: This disclosure relates to bituminous compositions and methods of producing the same. More particularly, the disclosure relates to the production of bituminous compositions formulated with performance-graded bitumen-containing solvent-free bitumen emulsions which exhibit controllable, temperature-dependent interfacial rheology. When employed in paving applications, these bituminous compositions develop adhesive strength and load-bearing strength properties at rates comparable to traditional hot mix paving compositions and at rates faster than traditional cold mix paving compositions.

Abstract: Aqueous asphalt/wax emulsions are disclosed herein for use in gypsum formulations and other building products. The emulsions may include water; a wax component; an asphalt component; and at least one emulsifier. Optional additives may also be included in the emulsion or in a slurry formed from such emulsion for preparing a settable gypsum composition herein. Methods of making such emulsions are also provided.

Abstract: This invention encompasses asphalt cement emulsions, as well as methods for preparing a pre-treated rubber-modified asphalt cement emulsions and methods for coating industrial surfaces using asphalt cement emulsions.

Abstract: The invention is a method of treating, restoring or sealing a surface comprising applying an emulsion comprising a latex polymer, a cationic emulsifier, and optionally a recycling agent to the surface to wet the surface and depositing a surface treatment layer on the surface, wherein the depositing step occurs while the surface is wetted. The invention also includes a surface pretreatment composition comprising water, at least one acrylic latex polymer, an aromatic recycling agent, and at least one cationic emulsifier. Furthermore, the invention includes the surface resulting from the application of the emulsion used in the invention and concentrated emulsions for use with the surface treatment composition.

Abstract: A process for the production of a bituminous composition, includes (i) producing a mix of aggregates with a maximum diameter less than or equal to 30 mm and of an amount less than or equal to 0.8 g per square meter of specific surface developed by the aggregates of at least one cationic polymer in the liquid form having a density of cationic charges greater than or equal to 0.5 meq/g and an intrinsic viscosity of from 0.01 to 0.8 dl/g; and (ii) putting the mix obtained in stage (i) into contact with at least one bituminous binder. A bituminous composition includes at least one specific cationic polymer and the use of at least one specific cationic polymer in the surface treatment of aggregates intended for the preparation of a bituminous composition are the other two subject-matters of the present invention.

Abstract: The invention is a method of treating, restoring or sealing a surface comprising applying an emulsion comprising a latex polymer, a cationic emulsifier, and optionally a recycling agent to the surface to wet the surface and depositing a surface treatment layer on the surface, wherein the depositing step occurs while the surface is wetted. The invention also includes a surface pretreatment composition comprising water, at least one acrylic latex polymer, an aromatic recycling agent, and at least one cationic emulsifier. Furthermore, the invention includes the surface resulting from the application of the emulsion used in the invention and concentrated emulsions for use with the surface treatment composition.

Abstract: The present invention relates to carboxyl-containing polymers having higher storage stability and improved processability in the form of powders, pellets or granules and to their use in laundry detergents and cleaners, and also in further fields of use.

Abstract: A method for formulating an emulsified polymer modified asphalt, and the emulsion thus created. The method includes mixing at least one polymer and a first binder in a high shear device to produce a polymer-binder composite, where the polymer is at least 70% butadiene; mixing the polymer-binder composite with a second binder to form a polymer modified asphalt; and emulsifying the polymer modified asphalt by combining effective amounts of an emulsifying agent and of water with the polymer modified asphalt. The polymer-binder composite may be produced at lower than room temperature or may include metal fatty acids, such that the resultant polymer-binder composite may be stored and transported at room temperature.

Abstract: Methods and compositions for improving the strength and longevity of secondary roadways through environmentally sound practices are disclosed herein. A composition for road sealing includes an aqueous emulsion of acrylic and vinyl acetate polymer, water, and a resin-modified emulsion, wherein the resin-modified emulsion includes a mixture of pitch and rosin, an emulsifying agent, and water.

Abstract: Methods and compositions for improving the strength and longevity of secondary roadways through environmentally sound practices are disclosed herein. A composition for road sealing includes an aqueous emulsion of acrylic and vinyl acetate polymer, water, and a resin-modified emulsion, wherein the resin-modified emulsion includes a mixture of pitch and rosin, an emulsifying agent, and water.

Abstract: Co-agglomerated dispersions and methods for their preparation are described herein. The co-agglomerated dispersions are prepared by co-agglomerating an anionic polymer dispersion and inert particles. The polymers for use in the co-agglomerated dispersions are derived from one or more monomers including at least one conjugated diene monomer. The inert particles have a particle size of less than 2 ?m. Also described herein is an aqueous dispersion including co-agglomerated particles formed from at least one polymer and at least one inert material. Further described herein are foamed polymers, latex-based adhesives, waterproofing membranes, sound absorbing coatings, and methods for their preparation and use.

Abstract: An environmentally friendly composition and related methods of use and production of an asphalt prime coat, suitable for application to a base road structure, are described herein. The composition includes an asphaltine, and an emulsion of a natural hydrocarbon resin mixed with a penetrating component, which can include a very limited quantity an organic solvent, or can omit organic solvents. If organic solvents are omitted, a hydrophobic wax can be added for moisture retention and water impermeability. Dispersion agents can be used to facilitate penetration into the base road. Rheology modifying agents and/or alcohols can be used to add flexibility, decrease curing time, and improve thickness and viscosity. The prime coat contains a lower quantity of volatile organic compounds than conventional prime coats, reducing environmental impact. The drying time of the composition is less than alternative compositions.

Abstract: Bituminous paving mixtures containing lubricating agents or additives may be prepared at hot mix temperatures and cooled, paved and compacted at temperatures 10-55 Celsius degrees lower than the hot mix temperatures. The increased temperature range between the hot mix temperatures and the paving and compacting temperatures is facilitated by the improved compacting properties of the paving mixture when it includes the lubricating agents or additives.

Abstract: The present invention is related to dispersion compositions and asphalt compositions including the dispersion compositions. The dispersion compositions include a microgels dispersed in a continuous oil phase. The dispersed microgels include at least one water swollen/swellable polymer, water soluble polymer, or combination thereof. The asphalt compositions include bitumen, aggregate, and a dispersion composition having a microgels dispersed in oil. The dispersed microgels include at least one water swollen/swellable polymer, water soluble polymer, or combination thereof.

Abstract: A method of operating a paving system includes establishing a plan for paving a work area which is based on a positional temperature model. The method further includes receiving temperature data for paving material and comparing the temperature data with data predicted by the positional temperature model. Operation of the paving system is adjusted where actual data differs from model predicted data. A paving system and control system are provided having an electronic control unit configured to compare electronic temperature data with a positional temperature model for paving material. The electronic control unit can control machines of the paving system based on comparing actual data with model predicted data, and can further update either or both of a plan for paving a work area and the positional temperature model itself based on differences between actual data and model predicted data.

Abstract: A bituminous composition including, based on total weight of the bituminous composition, (a) hard bitumen in an amount of 0.5% to 7.5% by weight, the hard bitumen being characterized by a penetration number of 100 dmm or less at 25° C. as determined according to the American Association of State Highway and Transportation Officials (AASHTO) Method T49; (b) emulsifier in an amount of 0.0005% to 0.2% by weight, wherein the emulsifier has a Hildebrand solubility parameter of at least 19 (MPa)1/2; (c) water; and (d) aggregate in an amount of 90% to 99% by weight, the aggregate having an aggregate surface that is wetted with the hard bitumen, wherein the bituminous composition is at a temperature ranging from 50° C. to 140° C.