From Dicarboxylic Acid Or Derivative And At Least One Polyol; Or From A Diester Of A Polycarboxylic Acid As Sole Reactant Patents (Class 524/601)
  • Patent number: 5723528
    Abstract: The impact strength of a thermoplastic molding composition containing polyalkylene terephthalate resin is improved upon the incorporation therewith of a particular silicone rubber powder. The silicone rubber powder, added at a level of about 8 to 25 percent, contains a mixture of (a) a polydiorganosiloxane and (b) finely divided silica filler.
    Type: Grant
    Filed: July 6, 1995
    Date of Patent: March 3, 1998
    Assignee: Bayer Corporation
    Inventor: James P. Mason
  • Patent number: 5712362
    Abstract: The invention relates to a process for the production of UV-stable polycarbonates, to the polycarbonates obtainable in accordance with the invention and to their use for the production of sheets, more particularly plastic panels.
    Type: Grant
    Filed: August 10, 1995
    Date of Patent: January 27, 1998
    Assignee: Bayer AG
    Inventors: Thomas Scholl, Peter Bier
  • Patent number: 5686510
    Abstract: A biaxially oriented polyester film made of a polyester composition,(A) which polyester composition comprises (a) an aromatic copolyester having a melting point of 210-245.degree. C., (b) first inert fine solid particles having an average particle diameter of 0.05 to 0.6 .mu.m, and (c) second inert fine solid particles having an average particle diameter of 0.3 to 2.5 .mu.m, the ratio of the average particle diameter of the second inert fine solid particles to the average particle diameter of the first inert fine solid particles being at least 2.5, and the amounts of the components (b) and (c) being 0.01 to 3% by weight and 0.001 to 0.2% by weight, respectively, based on the total weight of the components (a), (b) and (c);(B) which polyester film has a plane orientation coefficient of 0.08 to 0.16; and,(C) which polyester film shows excellent moldability when laminated onto a metal sheet and subjected to deep drawing.A can for drinks, foods, etc.
    Type: Grant
    Filed: November 10, 1994
    Date of Patent: November 11, 1997
    Assignee: Teijin Limited
    Inventors: Takeo Asai, Kinji Hasegawa, Mitsumasa Ono
  • Patent number: 5679724
    Abstract: An ink for ink jet printing includes an emulsifiable polymer resin and a pigment, and may be made by: (a) combining (1) an emulsion of an emulsifiable polymer resin in an anionic medium with (2) a pigment and a cationic surfactant; and (b) aggregating particles in the mixture of step (a) to a desired particle size, thereby producing a solution of aggregated particles. The particles can optionally be coalesced to alter the particle size of the particles.
    Type: Grant
    Filed: September 29, 1995
    Date of Patent: October 21, 1997
    Assignee: Xerox Corporation
    Inventors: Guerino G. Sacripante, Raj D. Patel, Marcel P. Breton, Michael A. Hopper, Grazyna E. Kmiecik-Lawrynowicz, Beng S. Ong
  • Patent number: 5674589
    Abstract: A copolyester composition comprising poly(ethylene naphthalate bibenzoate) ("PENBB") and 0.001 to 5% by weight of fine silica particles having an average diameter of 0.01 to 3.0 .mu.m. Further, films are made from this copolyester composition.
    Type: Grant
    Filed: June 2, 1995
    Date of Patent: October 7, 1997
    Assignee: Hoechst Celanese Corp.
    Inventors: Cynthia Bennett, E-Won Choe, John Anthony Flint, Bodo Kuhmann
  • Patent number: 5665853
    Abstract: The tensile strength properties of paper are improved by adding to paper stock a resin composition comprising a water-soluble polymer containing a polyhydric alcohol such as sorbitol in the backbone of the polymeric molecule.
    Type: Grant
    Filed: September 3, 1996
    Date of Patent: September 9, 1997
    Assignee: Geo Speciality Chemicals, Inc.
    Inventor: Jose M. Rodriguez
  • Patent number: 5663276
    Abstract: A wholly aromatic polyester having excellent moldability, heat resistance and blistering resistance and a composition thereof are obtained from an aromatic polyester composed of six specified types of structural unit and having an optical melt anisotropy. The composition can provide electronic heater parts and oven-ware both excellent in mechanical strength, heat resistance, moldability and microwave oven resistance, and various other heat-resistant members. Molded articles made from this composition can be coated with fluorocarbon resin without the necessity for pretreatment such as heat treatment.
    Type: Grant
    Filed: February 15, 1995
    Date of Patent: September 2, 1997
    Assignee: Nippon Petrochemicals Company, Limited
    Inventors: Hiroyoshi Yoneta, Satoshi Murouchi, Hideo Watanabe
  • Patent number: 5663282
    Abstract: A method for preparing rapidly crystallized polyesters from macrocyclic polyester oligomers comprising the step of contacting macrocyclic polyester oligomers, polymerization catalysts and nucleating agents.
    Type: Grant
    Filed: August 19, 1996
    Date of Patent: September 2, 1997
    Assignee: General Electric Company
    Inventors: Michael Leslie Todt, John William Carbone
  • Patent number: 5637356
    Abstract: Polyesters are formed from diols and dibasic carboxylic acids at an OH/COOH ratio to provide --OH termination, and then end-capped with tribasic carboxylic acids. A major portion of the dibasic carboxylic acids used to form the polyesters have the formula: ##STR1## where x=8-32, y=0-8, x+y=8-32. The polyesters are used as support resins for forming acrylic resin emulsions. The polyester/acrylic acid emulsions are useful, for example, as textile size.
    Type: Grant
    Filed: March 5, 1996
    Date of Patent: June 10, 1997
    Assignee: Morton International, Inc.
    Inventors: Ronald J. Kerr, John P. Petrovich, Stephen J. Walker, J. Alvin Binkley
  • Patent number: 5623014
    Abstract: A dispersion or solution of a free radical polymer, polycondensate or polyadduct, which consist of from 0.001 to 20% by weight of aldehyde groups --CHO or keto groups --CO--, contains, as a crosslinking agent, a compound having at least two H.sub.2 N--O---groups or oxime ether groups derived therefrom.
    Type: Grant
    Filed: December 13, 1994
    Date of Patent: April 22, 1997
    Assignee: Basf Aktiengesellschaft
    Inventors: Gerhard Bauer, Oral Aydin, Kaspar Bott, Horst Neuhauser, Gregor Ley, Albrecht Zosel, Jochen Wild, Albrecht Harreus, Eckehardt Wistuba
  • Patent number: 5614008
    Abstract: The present invention provides inks which contain a near infrared fluorophoric compound incorporated into a water-dissipatible polyester backbone. The inks of the present invention are preferably colorless or "invisible" but could be made slightly colored if desirable. Specifically, the inks of the present invention comprise:A. between about 1 and 10 weight percent of at least one water-dissipatable polyester having from about 0.1 ppm by weight to about 10% by weight of a thermally stable near infrared fluorophoric compound copolymerized therein;B. between about 5 and 75 weight percent of at least aliphatic humectant;C. between about 0 and 15 weight percent of at least one lower aliphatic alcohol of no more than 3 carbon atoms;D. water and optionally up to about 2 weight percent of one or more additives;wherein the weight percentages of components A-D equal 100%.
    Type: Grant
    Filed: October 23, 1995
    Date of Patent: March 25, 1997
    Inventors: Nelson Z. Escano, James J. Krutak, Sr.
  • Patent number: 5599875
    Abstract: Coating compositions and processes for coating wood and wood materials are described. The compositions comprise a first component comprising at least one reactive thinner and at least one unsaturated polyester, and a second component comprising a curing catalyst. The unsaturated polyester of the first component is the reaction product of: (a) a mixture of at least one saturated aliphatic dicarboxylic acid with 6 to 10 carbon atoms and at least one ethylenically unsaturated aliphatic dicarboxylic acid selected from maleic acid, fumaric acid, itaconic acid, citraconic acid, and mixtures thereof; (b) a diol component consisting of at least one of 1,4-dimethylolcyclohexane and substituted dimethylolcyclohexanes, with up to 50 mol % monomeric or oligomeric glycol, based on total moles of the diol component; and (c) up to 10 mol % of a polyol, based on total moles of polyester reactants. The compositions and processes of the invention result in coatings with improved hardness and aged cold crack resistance.
    Type: Grant
    Filed: August 28, 1995
    Date of Patent: February 4, 1997
    Assignee: BASF Lacke + Farben, AG
    Inventors: Karl-Dieter Depping, Horst Hintze-Bruning
  • Patent number: 5597861
    Abstract: A waterborne paint is provided by dissolving or dispersing a polyester resin and a crosslinker in an aqueous medium containing a base. The polyester resin contains a hydroxy-terminated polyalkadienediol having an average degree of polymerization from 5 to 50, a hydrogenated product thereof or a mixture thereof in a proportion from 1 to 30% by weight of the entire polyester-forming reactants, and has an acid number from 5 to 150, a hydroxyl number from 30 to 250. The paint is useful for forming a multilayer coating film on automobile bodies by applying the paint between an electrodeposition coating layer and a top coating layer.
    Type: Grant
    Filed: March 15, 1995
    Date of Patent: January 28, 1997
    Assignee: Nippon Paint Company, Ltd.
    Inventors: Yasuhiko Nakae, Shigeru Ishida, Shoichi Mure, Yasuhiro Shibata
  • Patent number: 5576371
    Abstract: A coating composition for preventing corrosion of a substrate including corrodable material, the coating composition comprising: a cycloaliphatic epoxy compound; a polyester compound; and a catalyst.
    Type: Grant
    Filed: January 19, 1995
    Date of Patent: November 19, 1996
    Assignee: A. O. Smith Corporation
    Inventors: Ming C. Kuo, Staer S. Kirsten, Gary W. Marshall
  • Patent number: 5569532
    Abstract: A biaxially oriented polyester film having improved surface properties, scratch resistance and abrasion resistance comprises the particulate slip agents of a calcium carbonate having an average particle diameter ranging from 0.01 to 3 .mu.m, alumina having an average particle diameter ranging from 0.005 to 3 .mu.m and a Mohs' hardness of 8 or more and a melamine formaldehyde condensate having an average particle diameter ranging from 0.01 to 3 .mu.m, wherein each of the slip agents is in an amount ranging from 0.01 to 4 wt. % based on the weight of the polyester.The film is useful in manufacturing condensers, medical articles, photographic films, packaging and labelling materials and, particularly, magnetic recording media.
    Type: Grant
    Filed: September 13, 1994
    Date of Patent: October 29, 1996
    Assignee: SKC Limited
    Inventors: Kwang-Hyung Lee, Joon-Hee Han, Young-Jin Lee
  • Patent number: 5563223
    Abstract: A coat resin composition comprising a polyester (A) comprising an acid component comprising an aromatic dicarboxylic acid in a proportion of 50-100% by mole relative to the entire acid component and other carboxylic acid(s) in a proportion of 50-0% by mole relative to the entire acid component, and a glycol component comprising 2-methyl-1,3-propanediol and/or 1,3-propanediol in a proportion of 1-25% by mole relative to the entire glycol component and an alkylene glycol having 5 to 10 carbon atoms in a proportion of 75-99% by mole relative to the entire glycol component, or an alicyclic glycol in a proportion of 20-85% by mole relative to the entire glycol component, an addition product of bisphenol A with alkylene oxide in a proportion of 80-15% by mole relative to the entire glycol component and other glycol(s) in a proportion of 0-50% by mole relative to the entire glycol component, wherein the total of the glycols is 100% by mole, the polyester (A) having a reduced viscosity of not less than 0.
    Type: Grant
    Filed: June 29, 1995
    Date of Patent: October 8, 1996
    Assignee: Toyo Boseki Kabushiki Kaisha
    Inventors: Hiroshi Tachika, Kenji Ohama, Keiichiro Togawa, Masami Oka
  • Patent number: 5552475
    Abstract: Substituted polycarboxylic acids or substituted anhydrides as acidifying agents stabilize a waterborne polyester from saponification, provided: (a) the acidification is carried out to an extent sufficient to provide an acid number of at least 40 milligrams KOH per gram of polyester resin; and (b) the substitution on the polycarboxylic acid or anhydride is either an alkenyl group having at least four carbon atoms or a cyclic group in which the ring is not aromatic. The relatively high acid number renders the polyester dispersible in water without the need to rely on surfactants.
    Type: Grant
    Filed: October 4, 1993
    Date of Patent: September 3, 1996
    Assignee: PPG Industries, Inc.
    Inventors: Padmanabhan Sundararaman, Ronald R. Ambrose, Douglas R. Camp, Truman F. Wilt
  • Patent number: 5534573
    Abstract: Triazine compounds useful as flame retardants have the formula: ##STR1## where Am represents an amino group, Pp represents a phosphonate group and Z represents an amino group or a phosphonate group, or are polymers comprising repeating units of the formula: ##STR2## where ##STR3## is a diamine residue. The triazine compounds are used as flame retardants in plastics materials, particularly polyurethane foam or artificial fibres, or in intumescent fire protection compositions.
    Type: Grant
    Filed: June 8, 1994
    Date of Patent: July 9, 1996
    Assignee: Courtaulds PLC
    Inventor: Jonathan S. Leake
  • Patent number: 5530059
    Abstract: Disclosed is a water-dissipatable alkyd resin containing a sulfonate group. The alkyd resin is prepared by reacting at least one monoglyceride, a polycarboxylic acid, and a polyol sulfomonomer adduct containing at least one sulfonate group. The alkyd resin is useful to prepare cross-linked coatings such as obtained with oil based paints.
    Type: Grant
    Filed: November 25, 1994
    Date of Patent: June 25, 1996
    Inventors: William W. Blount, Jr., Thauming Kuo
  • Patent number: 5525700
    Abstract: This invention relates to liquid crystalline polymers (LCPs) derived from (I) hydroquinone and/or 4,4'-biphenol and/or bis(4-hydroxylphenyl) ether, (II) terephthalic acid, (lII) 2,6-naphthalene dicarboxylic acid and/or 4,4'-bibenzoic acid, (IV) 4-hydroxybenzoic acid, (V) 6-hydroxy-2-naphthoic acid, and optionally (VI) an aliphatic diol in specified ratios. In addition to forming exceptionally tough films, the LCPs are useful as molding resins or for blending with other thermoplastic polymers.
    Type: Grant
    Filed: April 17, 1995
    Date of Patent: June 11, 1996
    Assignee: E. I. Du Pont de Nemours and Company
    Inventors: Michael R. Samuels, Marion G. Waggoner
  • Patent number: 5516837
    Abstract: A molding resin composition comprising 99.9 to 50% by weight of polyimide represented by the formula: ##STR1## and 0.1 to 50% by weight of polyether ketone resin and/or polyester resin, and more particularly comprising the polyester resin capable of forming an anisotropical molten phase at a temperature of 420.degree. C. or less, and a polyimide-based molding resin composition which comprises the said resins and other additives such as phenolic resin, fluororesin, graphite, carbon fibers, aromatic polyamide fibers, potassium titanate fibers and a crystallization accelerator, and is excellent in thermal resistance, chemical resistance, mechanical strength and processability.
    Type: Grant
    Filed: March 2, 1994
    Date of Patent: May 14, 1996
    Assignee: Mitsui Toatsu Chemicals, Inc.
    Inventors: Toshihiko Tsutsumi, Toshiyuki Nakakura, Toshiaki Takahashi, Atsushi Morita, Yoshihisa Gotoh, Hiroyasu Oochi
  • Patent number: 5514748
    Abstract: A molding resin composition comprising 99.9 to 50% by weight of polyimide represented by the formula: ##STR1## and 0.1 to 50% by weight of polyether ketone resin and/or polyester resin, and more particularly comprising the polyester resin capable of forming an anisotropical molten phase at a temperature of 420.degree. C. or less, and a polyimide-based molding resin composition which comprises the said resins and other additives such as phenolic resin, fluororesin, graphite, carbon fibers, aromatic polyamide fibers, potassium titanate fibers and a crystallization accelerator, and is excellent in thermal resistance, chemical resistance, mechanical strength and processability.
    Type: Grant
    Filed: June 7, 1995
    Date of Patent: May 7, 1996
    Assignee: Mitsui Toatsu Chemicals, Inc.
    Inventors: Toshihiko Isutsumi, Toshiyuki Nakakura, Shuichi Morikawa, Katsunori Shimamura, Toshiaki Takahashi, Atsushi Morita, Nobuhito Koga, Akihiro Yamaguchi, Masahiro Ohta, Yoshihisa Gotoh, Masaki Amano, Hiroyasu Oochi, Kayako Ito
  • Patent number: 5512614
    Abstract: A binder mixture for stoving lacquers comprising A) at least one alkyd resin; and B) at least one poly-N-acyl alkyleneimine prepared by cationic polymerization of a monomer mixture ofa) from 10 to 90% by weight of at least one monomer corresponding to formula (I): ##STR1## in which Z is a direct bond or the group CR.sup.5 R.sup.6, R.sup.1 to R.sup.4 can be the same or different and represent H or a C.sub.1-8 alkyl group, R.sup.5 and R.sup.6 can be the same or different and represent H or a C.sub.1-2 alkyl group, R.sup.7 is a hydroxyl-containing alkyl or alkylene group of a hydroxycarboxylic acid containing 2 to 32 carbon atoms,b) from 90 to 10% by weight of at least one monomer corresponding to formula (II): ##STR2## in which Z and R.sup.1 to R.sup.6 are as defined above and R.sup.8 is the radical of an aromatic monocarboxylic acid, andc) from 0 to 80% by weight of at least one monomer corresponding formula (III): ##STR3## in which Z and R.sup.1 to R.sup.6 are as defined above, and R.sup.
    Type: Grant
    Filed: February 13, 1995
    Date of Patent: April 30, 1996
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventors: Ulrich Eicken, Herbert Fischer, Wolfgang Gress, Ulrich Nagorny, Norbert Stork
  • Patent number: 5510417
    Abstract: An aqueous dispersion comprising (A) a polyester comprising an aromatic dicarboxylic acid, an addition product of bisphenol A with ethylene oxide and/or propylene oxide, and a dicarboxylic acid having a metal base of sulfonic acid and/or a polyol having a metal base of sulfonic acid, (B) a water-soluble organic compound having a boiling temperature of about 60.degree. C. to about 250.degree. C., (C) water and (D) a neutralizer; the amounts of the components A, B, C and D satisfying the following ratios of (1) to (3):(1) A/B/C being about 1% to about 70% by weight/about 0% to about 69% by weight/about 9% to about 99% by weight,(2) B/(B+C) being about 0 to about 0.7 (weight ratio), and(3) the equivalent ratio of D to A being about 0.1 to about 20.
    Type: Grant
    Filed: November 4, 1994
    Date of Patent: April 23, 1996
    Assignee: Toyo Boseki Kabushiki Kaisha
    Inventors: Hiroshi Tachika, Keiichiro Togawa, Hiroshi Fujimoto
  • Patent number: 5510453
    Abstract: The invention relates to novel branched polyesters containing allyl groups, which polyesters are water-emulsifiable, and their use as raw materials for lacquers.
    Type: Grant
    Filed: April 7, 1995
    Date of Patent: April 23, 1996
    Assignee: Wolff Walsrode Aktiengesellschaft
    Inventors: Burkhard Kressdorf, Erhard Luhmann, Wolfgang Dannhorn, Lutz Hoppe
  • Patent number: 5504142
    Abstract: The present invention relates to a mixture comprising (i) a thermoplastic elastomer, (ii) at least one chemical mediator acting on the behavior of insects and acarids and chosen from pheromones, kairomones, or allomones, and optionally, (iii) undecylenic acid or derivatives thereof. The invention is particularly useful for treating crops against insects and acarids.
    Type: Grant
    Filed: May 4, 1995
    Date of Patent: April 2, 1996
    Assignee: Elf Atochem S.A.
    Inventors: Henri-Jean Caupin, Roland Leroux, Michel Guillon
  • Patent number: 5489448
    Abstract: A water-free, water-free reducible primer composition having a volatile organic content of less than 3 pounds per gallon yields a tough, flexible, and weatherable film when applied to metal or plastic substrates. The base resin is a polyester having an acid number of from about 50 to about 60 and a hydroxyl number of from about 160 to about 200. The polyester is the reaction product of from about 0.45 to about 0.5 mole % of adipic acid, from about 0.35 to about 0.4 mole % of neopentyl glycol, and from about 0.15 to about 0.2 mole % of trimethylolpropane.
    Type: Grant
    Filed: July 26, 1994
    Date of Patent: February 6, 1996
    Assignee: Bee Chemical Company
    Inventors: Michael L. Jackson, Frank A. Stubbs, Joseph M. Mecozzi, Dean T. Smith
  • Patent number: 5489481
    Abstract: This development provides crystalline unsaturated polyesters having unreacted olefinically unsaturated monomer entrapped within its crystal lattice. The crystalline polyester can be used in high performance, structural SMC products or as a size or binder for glass fiber reinforcements or mats.
    Type: Grant
    Filed: December 27, 1994
    Date of Patent: February 6, 1996
    Assignee: Owens-Corning Fiberglas Technology, Inc.
    Inventors: William G. Hager, John D. Rinehart, James V. Gauchel, Edward L. Wilson
  • Patent number: 5484842
    Abstract: Aqueous dispersions having low VOCs are dispersions or solutions of polyesters. The polyesters useful are formed from A) between about 30 and about 60 mole percent polycarboxylic acids, of which at least about 80 mole percent comprises cyclohexanedicarboxylic acids, B) between about 35 and about 70 mole percent polyols of which at least about 95 mole percent comprises diols, and between about 40 and about 100 mole percent of the polyol content comprising cycloaliphatic diols, and C) between about 5 and about 25 mole percent of a monomer having dihydroxy, monocarboxylic acid functionality. The molar ratio of (B+C)/A is between about 1.01 and about 1.30, whereby the polyester is hydroxyl-terminated having hydroxyl numbers of between about 20 and about 150 and acid numbers between about 30 and about 100. The weight average molecular weight of the polyester is between about 1000 and about 20,000.
    Type: Grant
    Filed: May 23, 1994
    Date of Patent: January 16, 1996
    Assignee: Morton International, Inc.
    Inventors: Ronald J. Lewarchik, Marc L. Smith, Michael R. Sestrick
  • Patent number: 5468838
    Abstract: Polysuccinimide, polyaspartic acid and their salts are prepared by reaction of maleic anhydride and ammonia, polycondensation of the resulting product in the presence of a solubilizing agent and, if appropriate, hydrolysis.
    Type: Grant
    Filed: March 14, 1994
    Date of Patent: November 21, 1995
    Assignee: Bayer AG
    Inventors: Gunther Boehmke, Gerd Schmitz
  • Patent number: 5464878
    Abstract: A degradable polymeric foam having a density of not more than 16 lb. per cu ft. comprising a polymer alloy comprising:(i) from 50 to 100% of one or more co or homopolymers having a molecular weight of greater than 40,000 comprising the residues of one or more monomers of the Formula:--OCR.sub.1 R.sub.2 (CR.sub.3 R.sub.4).sub.n CO-- (I)or--OCH(CH.sub.3)CO-- (II)wherein in Formula I, R.sub.1, R.sub.2, R.sub.3, and R.sub.4 are independently selected from the group consisting of a hydrogen atom and a C.sub.1-4 alkyl radical, and n is zero or an integer from 1 to 5, provided that when a monomer residue of Formula II is present and in Formula I n is 1 and R.sub.2, R.sub.3, and R.sub.4 are hydrogen, R.sub.1 can not be a methyl radical; and(ii) from 0 to 50 weight % of one or more polymers selected from the group consisting of polymers having a Hildebrand parameter (.sigma.) of not more than 3 MPA.sup.1/2 different from that of the one or more co or homopolymers.
    Type: Grant
    Filed: June 11, 1993
    Date of Patent: November 7, 1995
    Assignee: Camelot Technologies, Inc.
    Inventors: Speros P. Nemphos, James T. McQueen
  • Patent number: 5463013
    Abstract: A modified aromatic polycarbonate resin containing at least one substituted phenyloxy group of the formula (I) in an amount of at least 5 mol % of the total amount of terminals, ##STR1## wherein: X is a halogen atom or a monovalent aliphatic hydrocarbon group having 1 to 10 carbon atoms,p is an integer of 0 to 4, and ##STR2## The present invention provide a modified aromatic polycarbonate resin of which the melt fluidity and electric properties are improved without impairing the excellent properties inherent to a polycarbonate resin such as transparency, heat resistance and dimensional stability.
    Type: Grant
    Filed: April 26, 1994
    Date of Patent: October 31, 1995
    Assignee: Teijin Chemicals, Ltd.
    Inventors: Toshimasa Tokuda, Ikkoh Furukawa, Masayoshi Miyauchi
  • Patent number: 5462983
    Abstract: Biodegradable moldable products and films prepared from a compatible blend containing a biodegradable, hydrophobic, starch ester and a biodegradable polyester, and optionally a biodegradable and miscible plasticizer and/or a compatible filler.
    Type: Grant
    Filed: July 27, 1993
    Date of Patent: October 31, 1995
    Assignee: Evercorn, Inc.
    Inventors: Steven Bloembergen, Ramani Narayan
  • Patent number: 5459209
    Abstract: An improved coating composition having one or more polymeric binders dispersed in a liquid medium, wherein the improvement comprises an anti-sag and anti-settling effective amount of oxidized ethylene-carbon monoxide copolymer.
    Type: Grant
    Filed: April 8, 1994
    Date of Patent: October 17, 1995
    Assignee: AlliedSignal Inc.
    Inventor: Michael Jablon
  • Patent number: 5446082
    Abstract: A water-dispersible polyester composition for an image recording medium, comprising (1) a polyester having a glass transition temperature of not less than 40.degree.C., a specific gravity of not less than 1.25, a value of SP of 9.5-12.0, and at least one kind of hydrophilic polar group, and which is insoluble in methyl ethyl ketone, toluene, and a mixed solvent thereof, wherein 65% by mole or more of a glycol component constituting the polyester is ethylene glycol, in a proportion of 5-50% by weight, (2) an organic compound compatible with water in a proportion of 0-20% by weight, and (3) water in a proportion of 30-95% by weight all percentages by weight being based upon the total weight of said composition containing components (1), (2) and (3). When used for an image recording layer of an image recording medium, the composition of the invention is conducive to the durability of the recorded images excellent in heat resistance, resistance to plasticizer, resistance to fingerprint, and solvent resistance.
    Type: Grant
    Filed: May 4, 1993
    Date of Patent: August 29, 1995
    Assignee: Toyo Boseki Kabushiki Kaisha
    Inventors: Haruo Asai, Mitsuru Kuwahara, Nobukazu Kotera
  • Patent number: 5430096
    Abstract: Stable aqueous size of ammonia-and/or amine-neutralized poly(amide-acid) of certain aromatic dianhydrides with certain aromatic diamines.
    Type: Grant
    Filed: April 28, 1994
    Date of Patent: July 4, 1995
    Assignee: E. I. Du Pont de Nemours and Company
    Inventors: Sang-Hak Hwang, Thomas J. Proffitt, Jr.
  • Patent number: 5428100
    Abstract: There are provided a liquid crystal polyester resin composition comprising 100 parts by weight of a liquid crystal polyester, 45 to 80 parts by weight of graphite having an average particle size of 5 .mu.m or more and 0 to 140 parts by weight of talc having an average particle size of 5 .mu.m or more, the total amount of the graphite and the talc being 55 to 185 parts by weight. There are provided a molded article such as a carrier for electronic part, a heat-resistant tray for IC, or the like, which has high heat resistance in soldering, only slight anisotropy and warpage, a surface resistivity of 1.times.10.sup.4 to 1.times.10.sup.8 .OMEGA., and an initial voltage due to electrification and a half-life (a time required for the initial voltage due to electrification to be reduced to one-half) which are controlled to be further reduced; and a liquid crystal polyester resin composition excellent in moldability which gives said molded article.
    Type: Grant
    Filed: June 1, 1993
    Date of Patent: June 27, 1995
    Assignee: Sumitomo Chemical Company, Limited
    Inventors: Kuniaki Asai, Tadayasu Kobayashi, Mituo Maeda
  • Patent number: 5409979
    Abstract: Liquid-crystal polyesters have been found to present special concerns when molded. The composition of the present invention has been found to provide unexpectedly superior processability results for such class of polymers. The improved liquid-crystal polyester resin composition comprises:(a) 100 parts by weight of a liquid-crystal polyester resin, and(b) 0.01 to 5 parts by weight of a fatty acid ester represented by the general formula: ##STR1## wherein at least one of X.sup.1, X.sup.2, X.sup.3 and X.sup.4 is a ##STR2## group and the others are each --H, --OH, or an alkyl or aryl group, and R is an alkyl or alkenyl group having 2 to 30 carbon atoms. It surprisingly has been found through empirical research that good mold release is made possible in the liquid-crystal polyester resin composition of the present invention coupled with a good retention of mechanical properties (i.e., flexural strength and flexural modulus) in the resulting article.
    Type: Grant
    Filed: June 4, 1993
    Date of Patent: April 25, 1995
    Assignee: Polyplastics Co., Ltd.
    Inventor: Mikio Nakai
  • Patent number: 5395875
    Abstract: Compositions comprising copolyetherester resins, copolyetherimide ester resins, or mixtures thereof, in combination with a high molecular weight polyester resin or mixture of such resins, with relatively high loadings of fillers selected from zinc oxide, barium sulfate, zirconium oxide, zirconium silicate, strontium sulfate or a mixture of any of such fillers, provide highly dense thermoplastic molded articles with properties suitable to replace ceramics and filled thermosets in many important applications.
    Type: Grant
    Filed: February 16, 1993
    Date of Patent: March 7, 1995
    Assignee: General Electric Company
    Inventors: Joel D. Allen, Dennis W. Champlain, Richard J. Clark, Lawrence R. Wallace
  • Patent number: 5391690
    Abstract: A process for producing a (co)polycarbonate or a (co)polyestercarbonate having a high molecular weight and excellent hue, heat stability and mechanical properties by reacting a dihydroxyl compound with a diester of carbonic acid and/or a diester of dicarbonic acid in the presence of a transesterification catalyst, wherein at least part of the reaction process is conducted in the presence of a specified organic phosphorus compound, or, in the presence of a specified organic phosphorus compound and a hindered phenol compound. A (co)polycarbonate or (co)polyester-carbonate composition having excellent hue, heat stability and mechanical properties, comprising a (co)polycarbonate and/or a (co)polyestercarbonate and, a specified organic phosphorus compound, or, a specified organic phosphorus compound and a hindered phenol compound.
    Type: Grant
    Filed: June 2, 1993
    Date of Patent: February 21, 1995
    Assignee: Daicel Chemical Industries,Ltd.
    Inventors: Tatsuya Kanno, Tsutomu Yamato, Yasuhiro Oshino, Yutaka Fukuda, Yoshihiro Iguchi, Takaaki Kuwana, Toshihiro Matsumoto
  • Patent number: 5387628
    Abstract: A process for producing a (co)polycarbonate or a (co)polyestercarbonate having a high molecular weight and excellent hue, heat stability and mechanical properties by reacting a dihydroxyl compound with a diester of carbonic acid and/or a diester of dicarbonic acid in the presence of a transesterification catalyst, wherein at least part of the reaction process is conducted in the presence of a specified organic phosphorus compound, or, in the presence of a specified organic phosphorus compound and a hindered phenol compound. A (co)polycarbonate or (co)polyester-carbonate composition having excellent hue, heat stability and mechanical properties, comprising a (co)polycarbonate and/or a (co)polyestercarbonate and, a specified organic phosphorus compound, or, a specified organic phosphorus compound and a hindered phenol compound.
    Type: Grant
    Filed: September 9, 1993
    Date of Patent: February 7, 1995
    Assignee: Daicel Chemical Industries, Ltd.
    Inventors: Tatsuya Kanno, Tsutomu Yamato, Yasuhiro Oshino, Yutaka Fukuda, Yoshihiro Iguchi, Takaaki Kuwana, Toshihiro Matsumoto
  • Patent number: 5386003
    Abstract: Water dispersible polyester polymers, polyesteramides polymers and blends of these polymers are dispersed in water and spray dried to form fine powders. In the solid state, these powders can absorb oils and/or diffuse ambient light, thereby resulting in the production of significant reduction in gloss and tack of lipids in cosmetic and personal care products when applied to ordinarily oily skin.
    Type: Grant
    Filed: March 15, 1993
    Date of Patent: January 31, 1995
    Assignee: Eastman Chemical Company
    Inventors: Carol J. Greene, Stephen H. Wu
  • Patent number: 5380590
    Abstract: A water-dispersible aromatic polyester comprising a dicarboxylic acid component and a glycol component, wherein (A) at least 95 mol% of the dicarboxylic acid component is composed of an aromatic dicarboxylic acid component containing 30 to 99.5 mol% of a 2,6-naphthalenedicarboxylic acid component and at least 0.005 mol% to less than 5 mol% of an aromatic dicarboxylic acid component having a sulfonic acid salt group, and (B) at least 95 mol% of the glycol component is composed of an ethylene glycol component and a component from a propylene oxide adduce of bisphenol A, the molar ratio of the ethylene glycol component:the component of a propylene oxide adduct of bisphenol A being 40-99:60-1; and a fast-adhesion polyester film comprising a polyester film and a coating which contains the above water-dispersible aromatic polyester and is formed on at least one surface of the polyester film.
    Type: Grant
    Filed: March 4, 1994
    Date of Patent: January 10, 1995
    Assignee: Teijin Limited
    Inventors: Tomoki Nakamura, Tetsuo Ichihashi, Masayuki Fukuda
  • Patent number: 5378757
    Abstract: Disclosed is a water-dissipatable alkyd resin containing a sulfonate group. The alkyd resin is prepared by reacting at least one monoglyceride, a polycarboxylic acid, and a polyol sulfomonomer adduct containing at least one sulfonate group. The alkyd resin is useful to prepare cross-linked coatings such as obtained with oil based paints.
    Type: Grant
    Filed: November 15, 1993
    Date of Patent: January 3, 1995
    Assignee: Eastman Chemical Company
    Inventors: William W. Blount, Jr., Thauming Kuo
  • Patent number: 5370939
    Abstract: An alkyd resin comprising allyloxypropanol and unsaturated drying oil compound residues in the resin chain. The invention further includes the method for manufacturing the resin and coatings made therefrom.
    Type: Grant
    Filed: November 17, 1992
    Date of Patent: December 6, 1994
    Assignee: Reichhold Chemicals, Inc.
    Inventors: Roy C. Williams, Kyu-Jun Kim
  • Patent number: 5362519
    Abstract: The present invention relates to polyesters which are particularly suitable in coating compositions which are sprayed with compressed fluids which act as viscosity reducing diluents.
    Type: Grant
    Filed: July 16, 1993
    Date of Patent: November 8, 1994
    Assignee: Union Carbide Chemicals & Plastics Technology Corporation
    Inventors: John N. Argyropoulos, Cheryl C. Bone, Charles W. Glancy
  • Patent number: 5358789
    Abstract: Provided are polyester resins containing hydroxy functionalized isophthalate ester moieties useful in coating compositions. The invention provides both solvent-borne as well as water-borne coating compositions comprised of the resins and a crosslinker such as a melamine-type crosslinker. Polyester resins of the present invention having a T.sub.g of greater than about 50.degree. C. are useful in thermosetting powder coating compositions. The coatings thus provided possess excellent acid resistance, hardness, impact resistance, and stain resistance.
    Type: Grant
    Filed: March 3, 1994
    Date of Patent: October 25, 1994
    Assignee: Eastman Chemical Company
    Inventors: Thauming Kuo, Charles H. Foster
  • Patent number: 5359025
    Abstract: Provided are novel phenolic-functional polyesters which are prepared by a direct polycondensation process. The polyesters formed therefrom are useful in enamel compositions and upon curing provide coatings which exhibit superior hardness, impact resistance and acid resistance heretofore unachievable with other polyester-based coatings.
    Type: Grant
    Filed: October 18, 1993
    Date of Patent: October 25, 1994
    Assignee: Eastman Chemical Company
    Inventor: Thauming Kuo
  • Patent number: 5356989
    Abstract: An aqueous dispersion suitable for use as various coatings is provided. The dispersion includes polyester resin (A), a water soluble organic compound (B), water (C), and a neutralizer (D). The polyester resin has an acid number of 50 equivalents/10.sup.6 g or more. The polycarboxylic acid component of the resin contains aromatic dicarboxylic acid having no metal sulfonate groups in an amount in the range of 50 to 99.99 mole percent, and dicarboxylic acid having a metal sulfonate group in an amount in the range of 0.01 to 20 mole percent based on the total moles of the polycarboxylic acid component. The polyol component of the resin contains diol in an amount in the range of 30 to 100 mole percent based on the total moles of the polyol component. The diol has an alkyl group with 1 to 3 carbon atoms on a side chain, and the total number of carbon atoms in the diol is 6 to 25. The water soluble organic compound has a boiling point in the range of 60.degree. to 250.degree. C.
    Type: Grant
    Filed: January 18, 1994
    Date of Patent: October 18, 1994
    Assignee: Toyo Boseki Kabushiki Kaisha
    Inventors: Hiroshi Tachika, Keiichiro Togawa, Hiroshi Fujimoto
  • Patent number: 5356984
    Abstract: Blends of metallic, preferably ferromagnetic, particles, macrocyclic oligomer compositions, especially poly(alkylene dicarboxylate) oligomers, and catalysts/initiators for polymerization of said macrocyclic oligomers are molded into magnets having high metal loadings, typically about 60-85% by volume. Compression molding of such blends can be conducted at relatively low pressures.
    Type: Grant
    Filed: February 14, 1994
    Date of Patent: October 18, 1994
    Assignee: General Electric Company
    Inventors: John W. Carbone, James Day, Michael L. Todt