Abstract: A method of producing formable material of dissimilar polymers and the amalgamated product produced thereby in which mixed thermoplastic polymers have a small percentage of blown asphalt combined therewith, the asphalt acting somewhat as a flux to promote commingling and amalgamation of the polymers during processing to form a product as in extrusion and injection molding operations.

Abstract: A bituminous mixture having improved physical properties is obtained by adding to a bitumen a polyphosphoric acid (I) containing phosphorus, calculated as P.sub.2 O.sub.5, in amount from 80% to 87% by weight, and a polymer composition (II) comprising (A) a propylene homopolymer or copolymer, (B) optionally an ethylene copolymer fraction insoluble in xylene at ambient temperature and (C) a copolymer fraction soluble in xylene at ambient temperature.

Abstract: The present invention provides for a method of making storage stable road paving binders by blending a minor amount of a polymer having at least one diene monomer with a major amount of asphalt containing at least 0.3% by weight of total nitrogen at an elevated temperature such that the components are sufficiently fluid to blend; treating the asphalt-polymer blend using not more than 250 meq of a sulfonating agent per 100 g of asphalt-polymer blend to introduce the corresponding acid functionality into the blend; maintaining the sulfonated asphalt-polymer blend at a sufficiently elevated temperature and stripping the sulfonated blend with sufficient chemically unreactive gas to remove a major fraction of the acid functionality introduced by sulfonation. The invention also provides for the compositions made by the process. These are useful as binders in road paving applications.

Abstract: A rubber modified asphalt for use as a paving compound is formed by reacting very fine ground particulate rubber with paving grade asphalt and mixing the combination at between 300 and 400 degrees F. The resulting mixture reacts fully within 25 minutes or less to form a freely pouring mixture; the reacted mixture can be held at normal asphalt working temperatures for at least 96 hours without degradation.

Abstract: A flame retardant asphalt material useful for the processing and formation of a roofing membrane includes from about 40 to about 50 parts by weight of asphalt; from about 10 to about 20 parts by weight of a copolymer; from 0 to about 5 parts by weight of polypropylene homopolymer having at least about 45 percent by weight of crystallinity; from about 10 to about 40 parts by weight of a functional filler having a decomposition temperature above the processing temperature of the material; from about 0 to about 15 parts by weight of a non-functional filler; and, from about 0.5 to about 10 parts by weight of an intumescent material.

Abstract: A process is provided for the preparation of bitumen-polymer compositions wherein bitumen is mixed at a composition between 100.degree. C. and 230.degree. C. with a block copolymer of styrene and a conjugated diene and a coupling agent containing a sulphur-donor compound for a duration of at least 10 minutes. The coupling agent is comprised of an elementary sulphur vulcanization agent and at least one sulphur-donor vulcanization accelerator from among morpholine disulphide, N,N'-disulphide of caprolactam and thiuram polysulphides.

Abstract: Blended polymer compositions are disclosed comprising an admixture of (a) a copolymer of ethylene and an alphaolefin and (b) an amorphous polypropylene, and/or amorphous polyolefin, or mixtures thereof.

Abstract: The invention relates to a method for improving the properties of bitumen, asphalt, or a similar material by adding to it a thermoplastic or a thermoelastomer, the solubility and compatibility of the thermoplastic or thermoelastomer being improved by a third component, which is wood resin, turpentine resin, a derivative of these, tall oil, tall-oil pitch, or a constituent or mixture of these. The obtained composition of bitumen, asphalt or a similar material can be used as a binding agent in road pavement materials.

Abstract: A coal-tar-pitch-based roofing composition containing coal tar pitch, a rubbery block polymer, an extender oil, and an antioxidant to retard degradation of the coal tar pitch during blending of the composition, the composition being formed by heating the coat tar pitch, adding the naphthenic extender oil and the rubbery polymer and agitating the components at an elevated temperature for a period of time until phase inversion between the coal tar pitch and the rubbery polymer occurs.

Abstract: An asphalt material, useful for forming a membrane, comprises a mixture of from about 47 to about 74 parts by weight of asphalt, from about 7 to about 15 parts by weight of styrene-butadiene-styrene block copolymer, from about 15 to about 25 parts by weight of a filler component, and from about 1 to about 5 parts by weight of polypropylene homopolymer. A method for preparing a modified-asphalt material comprises the steps of forming a mixture by admixing from about 47 to about 74 parts by weight of asphalt; from about 7 to about 15 parts by weight of a styrene-butadiene-styrene block copolymer; from about 15 to about 25 parts by weight of a filler; and from about 1 to about 5 parts by weight of a polypropylene homopolymer; wherein the polypropylene homopolymer inhibits high temperature crosslinking of the styrene-butadiene-styrene block copolymer.

Abstract: A bituminous composition comprising a bituminous component and an epoxidized polymer of a conjugated diolefin and, optionally, a vinyl aromatic hydrocarbon.

Abstract: The present invention is a bituminous roofing composition which is especially useful to coat and/or saturate a roll roofing membrane. The composition comprises from 2 to 10 percent by weight, based on block copolymer plus bitumen, of a block copolymer of a vinyl aromatic hydrocarbon and a conjugated diene, from 25 to 300 parts by weight per hundred parts of said block copolymer of an endblock compatible resin which has a softening point above 100.degree. C., and the balance being a bituminous material. Preferably, the solubility parameter of the endblock resin is within 0.3 [cal/cm.sup.3 ].sup.1/2 of that of the vinyl aromatic hydrocarbon portion of the block copolymer.

Abstract: An improved paving composition includes between 89-93% graded aggregate, 5.76% asphalt cement, 0.24% SBR polymer and 1-5% graded recycled crumb rubber. The asphalt cement and SBR polymer are blended and heated to form a first mixture. The aggregates are blended and heated to form a second mixture. The two mixtures are blended together prior to the addition of the graded recycled crumb rubber.

Abstract: This bitumen-polymer composition contains:a) at least one bitumen,b) at least one polymer having hydrocarbon chains with mobile hydrogens, said polymer being grafted and crosslinked in situ in said bitumen through a complex of at least one organic silicon compound, said complex being formed from a primary constituent and a secondary constituent, the latter being the organic silicon compound.

Abstract: An asphalt composition comprises asphalt mixed with an asphalt modifier, which combines a thermoplastic elastomeric copolymer and an effective amount of a fibrillated polytetrafluoroethylene and molybdenum disulfide particles. The thermoplastic elastomeric copolymer preferably comprises two incompatible polymers forming a two-phase copolymer including a thermoplastic end block polymer and an elastomeric mid block polymer. Preferably, the thermoplastic end block polymer is a styrene polymer and the elastomeric mid block polymer is selected from a group consisting of polybutadiene, polyisoprene and poly(ethylene-butylene). The asphalt modifier is made by mixing together under high shear, as for example, in a twin screw extruder, particles of a thermoplastic elastomeric copolymer, fibrillatable polytetrafluoroethylene and molybdenum disulfide until the fibrillatable polytetrafluoroethylene is substantially fibrillated and combined with the thermoplastic elastomeric copolymer.

Abstract: A process for preparing an incorporated asphalt composition includes mixing ground tire rubber with distillation tower bottoms to form a wetted mixture of the ground tire rubber with the distillation tower bottoms, bombarding the wetted mixture of ground tire rubber and distillation tower bottoms with air at a temperature of about 350.degree.-485.degree. F. at about 6-15 psi pressure until the mixture is completely incorporated, and recovering the incorporated asphalt composition. The homogenized asphalt product is a two-member composition of distillation tower bottoms having ground tire rubber incorporated therein.

Abstract: Blended polymer compositions are disclosed comprising an admixture of (a) a copolymer of ethylene and an alphaolefin and (b) an amorphous polypropylene, and/or amorphous polyolefin, or mixtures thereof.

Abstract: This invention relates to a composition and method for improving the storage stability of an asphalt that contains a higher molecular weight polymer having a number average molecular weight of at least about 10,000 which comprises adding a storage stable improving amount of a polymerized alpha-olefin prepared from an alpha-olefin of the formula ##STR1## where R is C.sub.6 to C.sub.50 alkyl, R.sup.1 is hydrogen or C.sub.6 to C.sub.50 alkyl, wherein the polymerized alpha-olefin has a number average molecular weight of from about 500 to 5,000 and is characterized in that it has a congealing and melting point which is essentially no higher than the congealing and melting point of the alpha-olefin from which it is prepared.

Abstract: A water absorbing particulate polymer material wherein the polymer material when in dry powder form has a particle size of about 50 .mu.m to about 500 .mu.m and wherein the particles consist of internally bonded finer particles which finer particles have a size below 50 .mu.m. The process of using the water absorbing polymer, material to convert a wet sticky mass of inorganic particulate such as coal fines into a crumbly or flowable solid. A process using a water absorbing particulate polymer material to convert a wet sticky mass of organic particulate material into a crumbly or flowable solid wherein the organic matter can be, for example, food waste or sewage.

Abstract: A process is provided for preparing in aqueous emulsion, a bitumen/polymer binder with a continuous three-dimensional polymeric structure. The process comprises:a) forming a reaction mixture in an emulsion formation zone by feeding to the zone(i) a bitumen-polymer component comprised of a bitumen containing 0.5% to 15%, by weight of the bitumen, of a sulphur-crosslinkable elastomeric polymer, the bitumen/polymer component being in the form of a melt viscosity of not more than 2 Pa.s at the melt temperature,(ii) an aqueous phase containing an effective quantity of an emulsifying system, and(iii) a crosslinking system donating sulphur in a quantity such as to provide 0.

Abstract: A description follows of bitumens modified with recycled and/or virgin polymers, such as polyethylene (PE) and ethylene-vinylacetate copolymer which, having special structural and morphological characteristics, give an improved performance with respect to bitumen as such or modified with traditional polymers; the mixtures thus obtained are used for street paving or different kinds of waterproofing.

Abstract: The invention relates to a method for producing an aqueous asphalt binder emulsion which makes it possible to control the viscosity and breaking properties of the emulsion.

Abstract: Disclosed are asphalt compositions prepared from bitumen, a tri-block copolymer of styrene and butadiene, and from about 0.015 to about 0.075 weight percent of elemental sulfur. The asphalt compositions described herein are useful in industrial applications, such as in hot mix asphalts useful in preparing aggregates for road paving.

Abstract: A bitumenous binder useful in road surfacing is prepared via the blending of from 1-35% by weight of bitumen with a mixture of an ethylene/vinyl acetate copolymer and polyisobutylene having a number average molecular weight of greater than 400 to less than 1,000 wherein the ratio of polyisobutylene:ethylene/vinyl acetate is between 90:10 and 50:50.

Abstract: A floor covering having a bitumen composition as a backing layer, such as carpet tiles, which bitumen composition comprises straight run bitumen and a mixture of high density and low density polyethylene polymers blended and dispersed in the straight run bitumen as a continuous phase in an amount of up to about 12% by weight and which bitumen composition contains a minimum of about 40% by weight of a mineral filler material, such as limestone, and the bitumen composition having improved dimensional stability, adhesion, static loading and electrical conductivity and having lower cost and processing advantages.

Abstract: A mixture containing bitumen and a polymer composition, characterized in that the polymer composition comprises:A) 10-40 parts by weight of an isotactic propylene homopolymer, or a random copolymer of propylene with ethylene and/or a C.sub.4 -C.sub.10 .alpha.-olefin;B) 0-20 parts by weight of a copolymer fraction containing ethylene, which is insoluble in xylene at ambient temperature;C) 50-80 parts by weight of a copolymer fraction of ethylene with propylene and/or C.sub.4 -C.sub.10 .alpha.-olefin, said copolymer fraction being soluble in xylene at ambient temperature and having an intrinsic viscosity greater than 1.5 and up to 2.2 dl/g and having 20 to 45 wt. % ethylene.

Abstract: Disclosed is a damping material, which contains from 3 to 30% by weight of a thermoplastic elastomer containing at least two polymer blocks along with a bitumen and which has a dynamic loss tangent (tan .delta.) of being 0.5 or more in 10% deformation under the condition of 25.degree. C. and 1 Hz.

Abstract: Disclosed in this invention are novel road paving binder compositions and the method of making same. The compositions are made by combining an asphalt that contains sulfonate or sulfonic acid groups, a polymer preferably of butyl rubbers, styrene-butadiene linear diblock polymer, styrene-butadiene-styrene linear or radial triblock polymer and EPDM that has been sulfonated, and mixtures thereof, and a basic neutralizing agent that contains cations having a valence from +1 to +3. The amounts of each are effective to allow formation of one continuous phase or two interdispersed phases that do not segregate on standing at elevated temperatures associated with road paving. The amount of polymer is an amount less than 7 wt. % of total polymer-asphalt composition that is sufficient to produce an asphaltic composition having a viscosity at 135.degree. C. in the range of from about 150 cPs to about 2000 cPs or from about 3000 cPs to about 8000 cPs.

Abstract: The present invention provides an elastomeric-asphalt composition which does not phase separate and which is compatible at high temperatures. This compatible material can be produced without the need to use high shear milling equipment. The elastomeric-asphalt composition is not limited by the tendency of other elastomer polymers to be incompatible with asphalt nor does the composition separate into a polymer-rich phase and an asphalt-rich phase. In a preferred embodiment, the elastomeric materials are SBS and SIS block copolymers.

Abstract: Disclosed in this invention are novel road paving asphaltic compositions having improved viscoelastic properties and storage stability and unexpected phase compatibility. They contain neutralized mixtures of oxidized asphalt and an acid functionalized polymer, which polymer is selected from the group consisting of sulfonated EPDM, sulfonated styrene-butadiene, and acrylic acid terpolymers, in an amount that is sufficient to result in an asphaltic composition having a softening point greater about 55.degree. C. and a viscosity in the range from about 150 cPs to 2000 cPs or from about 3000 cPs to about 8000 cPs at 135.degree. C. and effective to allow the formation of one continuous phase or two interdispersed phases that do not segregate on standing at elevated temperatures. The basic neutralizing agent used in these compositions contain cations having a valence of from +1 to +3, preferably +2. The invention also relates to the products produced by the process and method of making the compositions.

Abstract: A rubber modified asphalt for use as a paving compound is formed by reacting very fine ground particulate rubber with paving grade asphalt and mixing the combination at between 300 and 400 degrees F. The resulting mixture reacts fully within 25 minutes or less to form a freely pouring mixture; the reacted mixture can be held at normal asphalt working temperatures for at least 96 hours without degradation.

Abstract: A polymer-modified asphalt composition containing (a) about 80 to 99.7 weight percent of a polymer-asphalt reaction product prepared by reacting (i) about 100 parts by weight of an asphalt having an initial viscosity at 60.degree. C. of from 100 to 20,000 poise, with (ii) about 0.5 to 11 parts by weight a glycidyl-containing ethylene copolymer containing about 0.1 to about 20 weight percent glycidyl moieties and having a weight-average molecular weight of from about 10,000 to about 1,000,000; and (b) about 0.3 to 20 weight percent of a styrene/conjugated-diene block copolymer having a weight-average molecular weight of from about 100,000 to about 1,000,000.

Abstract: An asphalt composition for use in road pavements is disclosed which comprises chiefly of an asphalt of natural or petroleum origin, a thermoplastic elastomer and/or a styrene-butadiene rubber and a low molecular weight polypropylene. These components are premixed or plant-mixed to form a reformed asphalt which is mixed with an aggregate to provide a paving material having increased compression strength, increased low temperature viscosity and decreased high temperature viscosity.

Abstract: A roofing system incorporates a fire resistant asphalt composition comprising a thermoplastic elastomer modified bitumen, a filler, a brominated diphenyl ether, antimony oxide, and zinc borate. The asphalt composition is utilized with and impregnated into at least one layer of fiberglass or polyester mat. Preferably at least two layers are utilized wherein an upper layer is a fiberglass mat and a lower layer is a polyester mat, both mat layers being impregnated with the composition. In its preferred formulation, the asphalt composition comprises, in weight percent, about 30% to 90% bitumen, about 4% to 16% styrene-butadiene-styrene copolymer, about 10% to 40% filler, and up to about 20% each of the brominated diphenyl ether, the antimony oxide, and the zinc borate. The preferred brominated diphenyl ether is decabromodiphenyl ether.

Abstract: Composition of waterproofing membrane suitable for being applied by means of hot bitumen both on a new covering and on a previous waterproofing layer based on blown bitumen, which is characterized in that it comprises 50 to 80% by weight of distilled bitumen, 8 to 20% by weight of amorphous ethylene-propylene and/or ethylene-propylene-butene 1 copolymer, and 5 to 15% by weight of amorphous polypropylene homopolymer, and optionally up to 40% by weight of a filler and/or up to 1% by weight of an antioxidant.

Abstract: A bituminous composition comprising a bituminous component, a polymer which comprises at least one block of a conjugated diolefin and at least one block of an acrylic monomer such as an alkyl methacrylate and from 0.001 parts to 1 part by weight of a polyfunctional amine having at least two amino groups. An acid or anhydride functionalized conjugated diene block copolymer may be used in place of the acrylic monomer polymer.

Abstract: A bitumen/polymer component of the type consisting of a hydrocarbon matrix is provided in which a sulphur-crosslinked elastomer is distributed homogeneously in a quantity such that it presents 5% to 20% by weight of the bitumen/polymer component. The component exhibits a penetration, determined according to NF standard T 66004, and a ball-and-ring softening temperature, determined according to NF standard T 66008, such that the Pfeiffer number, which links these quantities, assumes values greater than 5 in the case of the bitumen/polymer component.

Abstract: An asphalt blend used for paving is described. The blend contains polyethylene which has been modified by shearing action in the presence of an O-containing gas (such as oxygen or ozone). The blend has improved viscosity at high temperatures and reduced stiffness at low temperatures. A paving mix prepared using the asphalt blend has an improved Marshall Test Value (ASTM DI559), indicating that the paving mix should have a reduced tendency to become rutted under the load of traffic.

Abstract: A stable polymer dispersion having an average particle size of no more than 1 micron comprising water, a surfactant and a polymer comprising at least one conjugated diolefin block and/or vinyl aromatic hydrocarbon block and at least one acrylic monomer block with the structure ##STR1## wherein R.sub.1 is selected from the group consisting of hydrogen, phenyl and alkyl radicals which are linear or branched and contain from 1 to 10 carbon atoms, and R.sub.2 is a cyclic or non-cyclic alkyl radical which is branched at the first carbon atom, contains from 1 to 14 carbon atoms and may contain a tertiary amine or an ether linkage.

Abstract: This invention relates to polymeric compositions comprising unhydrogenated or substantially unhydrogenated sulfonated copolymers of (poly)styrene and a (poly)conjugated diene, e.g., (poly)butadiene or (poly)isoprene, preferably (poly)butadiene containing less than about 1.0 wt. %, preferably less than about 0.8 wt. % sulfur, preferably from about 0.2 to about 0.7, more preferably from about 0.22 to about 0.6 wt. % sulfur, as well as base-neutralized products thereof. The invention includes the polymeric compositions produced by the process of sulfonating unhydrogenated copolymers of (poly)styrene and a conjugated diene, e.g., (poly)butadiene or (poly)isoprene, preferably (poly)butadiene, which process optionally includes base neutralizing the sulfonated copolymer. This invention further relates to the process for making these novel copolymers comprising combining an unhydrogenated or substantially unhydrogenated copolymer of (poly)styrene and a conjugated diene, e.g.

Abstract: A composition for application to a concrete asphalt substrate, such as highways, landing strips of airfields and the like, which forms an uppermost protective layer. The composition penetrates to a certain small depth of the existing substrate. The result is an improved resistance to mechanical stress and to surface abrasion as well as against deterioration as a result of solar radiation. Water penetration is greatly reduced and friction is not reduced.Main components of the composition are an acryl type or styrene type monomer, bitumen and a mineral particulate filler, and a UV protective agent. Certain compositions can contain additional components as well.

Abstract: A bituminous composition comprising a bituminous component, a polymer which comprises at least one block of a conjugated diolefin and at least one block of an acrylic monomer such as an alkyl methacrylate and from 0.001 parts to 1 part by weight of a polyfunctional amine having at least two amino groups. An acid or anhydride functionalized conjugated diene block copolymer may be used in place of the acrylic monomer polymer.

Abstract: Radial and branched block copolymers show a structure: ##STR1## wherein: Z is a radical deriving from a tetrafunctional coupling agent;A is a polystyrene block;B is a polybutadiene blockm, n, p, q are either 1 or zero, with the condition that their sum is comprised within the range of from 1 to 4.Compositions of block copolymers comprise the hereinabove disclosed radial and branched block copolymers, blended with a two-block copolymer B-A, and an "A" homopolymer.The process for the preparation of said radial and branched block copolymers and of the related compositions is disclosed, and furthermore their use is disclosed in bituminous compositions, in order to improve the general characteristics of the bitumens.

Abstract: In accordance with the present invention, there is provided an asphalt composition which incorporates asphalt in admixture with synthetic or natural rubber and elemental selenium or an organo-selenium. There is also provided a process for preparing the above asphalt composition. Preferably, the rubber is obtained from waste tires or tubes.

Abstract: The present invention provides a polymer-modified bitumeniferous composition containing polymer components in the amount of 0.5-50 wt. %, wherein 20-100 wt. % of the polymeric additive is a copolymer comprises of units of: C.sub.6 -C.sub.28 -alkyl (meth)acrylates in the amount of 80-99.9 wt. %, maleic anhydride in the amount of 0.1-20 wt. %, and other polymerizable compounds in the amount of 0-19.9 wt %. The polymer-modified bitumens exhibit excellent and persistent homogeneity, high elastic resilience, and a good range of plasticity.

Abstract: A method of producing cross-linked polymer modified asphalt or bitumen. The method includes the steps of combining by agitation polymers chosen from a group consisting of styrene rubber, styrene butadiene rubber, polydiene rubber and polyolefin diene rubber, 80 to 99% by weight of asphalt or bitumen, with the asphalt or bitumen at temperatures of 130.degree. to 230.degree. C. to form a homogeneous mixture. Thereafter, 0.05 to 2.0% by weight of asphalt of a reactive phenol-aldehyde resin is added to the mixture. The reaction is thereafter completed by continuing agitation of the mixture.

Abstract: A bituminous binder emulsion is provided and is formed from a dispersion of an organic phase consisting of a bituminous binder in an aqueous phase incorporating an emulsifying system made up of one or more emulsifying agents, a water-soluble thickener and optionally, a pH regulating agent. The thickener which may be used to control the viscosity of the emulsion incorporates at least 40% scleroglucan by weight. The emulsion obtained may be used for road building applications, water-proofing in civil engineering or construction works, or for industrial purposes.

Abstract: A bituminous composition comprising: (a) a bitumen, (b) a block copolymer of at least one conjugated diolefin and at least one vinyl aromatic hydrocarbon, and (c) a thermoplastic or low crystallinity polymer.

Abstract: The present invention is an improvement in a process for producing a blend of bitumen and a block copolymer of a vinyl aromatic hydrocarbon and a conjugated diene comprising mixing from 88 to 99.5 weight percent of bitumen with 0.5 to 12 weight percent copolymer at 135.degree. to 250.degree. C., agitating the mixture for at least 30 minutes, adding 0.01 to 2 weight percent sulfur and maintaining the mixture under agitation for at least 30 minutes. The improvement comprises utilizing high shear mixing at a shear rate of at least 10,000 second.sup.-1 to provide said agitation.

Abstract: A bituminous composition comprising a compatible bituminous component and a completely non-tapered radial block copolymer of a conjugated diolefin and a vinyl aromatic hydrocarbon wherein the polymer has from 3 to 6 arms, a molecular weight of from 150,000 to 400,000, a coupling efficiency of at least 95 percent, and a polyvinyl aromatic hydrocarbon blockiness of at least 98.5%.