Abstract: A cool roof covering for forming the outermost layer of a bituminous roof coating is provided, this cool roof covering comprising multiple heat-reflecting cap-sheets arranged in an adjacent, overlapping edge fashion and a heat-reflecting cap-sheet adhesive applied to overlapping portions of the cap-sheets for securing these cap-sheets to one another. The heat-reflecting cap-sheets exhibit a solar reflectance of at least 60% and a thermal emittance of at least 65. The heat-reflecting cap-sheet adhesive comprises a storage-stable, VOC-compliant mixture containing at least 10 wt. % of one or more weather-resistant organic resins dissolved in an organic solvent, the adhesive having a viscosity of 15,000 cps or less at 77° F. (25° C.) and exhibiting a lap shear strength of at least about 17 lbf/in when applied to a substrate and dried.

Abstract: The present invention is directed to an air-blown roofing asphalt modified with polyphosphoric acid and roofing products made with the polyphosphoric acid-modified, air-blown asphalt.

Abstract: Modified asphalts have excellent dispersibility and compatibility with polar materials, are usable in applications including railroad track-filling materials, and are inexpensive. A modified asphalt includes an asphalt (A), a viscosity depressant (B) and a copolymer (C) containing a structural unit from a polyalkylene glycol allyl ether (c1), a structural unit from an unsaturated dicarboxylic acid and/or an acid anhydride thereof (c2), and a structural unit from an aromatic vinyl compound (c3).

Abstract: A rejuvenating agent having a viscosity of from 200 to 60000 cSt at 60° C. and comprising 10-90 weight % palm oil and 90-10 weight % bitumen, where the percentages are based upon the total weight of the composition, is disclosed. The rejuvenating agent is suitable for use in hot in-place and hot in-plant recycling processes.

Abstract: In methods of preparing asphalt and elastomeric polymer compositions crosslinked with phenol aldehyde resins and sulfur, such as polymer modified asphalt (PMA), it has been discovered that the MP1 compatibility may be improved by adding certain ionic metal oxides. Suitable ionic metal salts include, but are not necessarily limited to, zinc oxide, cadmium oxide, and the like. Acceptable elastomeric polymers include, but are not necessarily limited to, styrene-butadiene copolymers. Additional sulfur-containing crosslinkers may also be used.

Abstract: A process for preparing a modified asphalt binder composition, the process comprising mixing asphalt, an unsaturated polymer, and phosphorus pentasulfide to form a modified asphalt composition.

Abstract: A polyurethane hot melt adhesive composition comprising an isocyanate, one or more polyols, one or more bituminous materials and optionally one or more thermoplastic materials. Another embodiment is directed to a method for bonding materials together which comprises applying the reactive hot melt adhesive composition in a liquid form to a first substrate, bringing a second substrate in contact with the composition applied to the first substrate, and subjecting the applied composition to conditions which will allow the composition to cool and cure to an irreversible solid form, said conditions comprising moisture. Still another aspect is directed to an article of manufacture comprising the adhesive.

Abstract: The present invention is directed to a process for preparing a polymer modified bituminous binder composition in the substantial absence of crosslinking agents by heating a bitumen component in a stirred tank to a temperature from 160° C. to 221° C.; adding a block copolymer composition to the bitumen component while the bitumen component is being stirred to form a homogeneous mixture of the bitumen component and the block copolymer composition; and continuing to stir the homogeneous mixture while maintaining the temperature from 180° C. to 221° C. for a total period of time from 4 hours to 30 hours thereby forming a cured polymer modified bituminous binder composition.

Abstract: Asphalt and elastomeric polymer compositions crosslinked with mixed polythiomorpholines or at least one alkyl polysulfide can give polymer modified asphalts (PMAs) with improved properties and/or reduced H2S evolution. When at least one alkyl polysulfide is used to completely or partially replace conventional crosslinkers such as S or MBT, mercaptobenzimidazole (MBI) may be optionally used as a co-crosslinker. The use of mixed polythiomorpholines as crosslinkers provide PMAs with better low temperature profiles (BBR m-values). The use of at least one alkyl polysulfide crosslinker gives PMAs with improved PAV-aged DSR results, and reduced H2S evolution. The use of at least one alkyl polysulfide crosslinker together with MBI may give PMAs with improved PAV DSR Fail Temperatures.

Abstract: Rubber particles in a water and polyhydric alcohol solution are added to an asphalt whereby the polyhydric alcohol substantially coats the rubber particles resulting in an easily mixed composition with the mixing temperature being reduced to a range of from about 250° F. to about 310° F. resulting in considerable energy savings. In a similar manner, a filler can be substantially coated by polyvinyl alcohol-water solution and the same blended with an asphalt and mixed at reduced temperatures. Another embodiment relates to the utilization of a polyhydric alcohol that is added to an asphalt and mixed therewith at reduced temperatures.

Abstract: The present invention is directed to a process for preparing a polymer modified bituminous binder composition in the substantial absence of crosslinking agents by heating a bitumen component in a stirred tank to a temperature from 185° C. to 221° C.; adding a block copolymer composition to the bitumen component while the bitumen component is being stirred to form a homogeneous mixture of the bitumen component and the block copolymer composition; and continuing to stir the homogeneous mixture while maintaining the temperature from 185° C. to 221° C. for a period of time from 4 hours to 30 hours thereby forming a cured polymer modified bituminous binder composition.

Abstract: A process for preparing compatible, selectively hydrogenated block copolymer-modified bituminous compositions comprising blowing a mixture of the block copolymer and bitumen with an oxidizing gas at temperatures of at least 375° C. for at least 75 minutes. The modifying polymer is a selectively hydrogenated styrenic block copolymer and no blowing catalyst is required. Stable bituminous compositions comprising 6 to 25 parts by weight of block copolymer per 100 parts of asphalt are also provided as well as their application as roofing shingles.

Abstract: The present invention relates to novel bituminous products and also to novel aqueous emulsions of bituminous products, mixes thereof with aggregates in the form of bituminous mixes, that can be used in the field of sealing, construction and repair of road coverings, pavements and aircraft runways, road coverings, pavements, cycle paths, parking areas and aircraft runways.

Abstract: A lightweight finish composition, method of production and a method of application are provided. The lightweight finish composition comprises a resin dispersion, alkali metal phosphate, alkylolammonium salt of a polyfunctional polymer, and lightweight aggregate such as silica spheres. The lightweight aggregate has a density and weight that is less than those of sand. The combination of alkali metal phosphate and alkylolammonium salt of a polyfunctional polymer stabilizes the lightweight finish composition by preventing the lightweight aggregate from absorbing water, after production of the lightweight finish composition.

Abstract: The binder is produced based on natural bitumen, or bitumen from the oil industry, and comprises a first additive which is constituted by a hydrocarbon wax whose melting point is greater than 85° C. This binder further comprises a fatty acid ester wax which is of synthetic, vegetable or fossil vegetable origin and which has a melting point of less than 85° C. Use in the production of sealing coatings for buildings or civil engineering works, coatings for traffic routes or urban amenities.

Abstract: A modified asphalt composition comprising a naphthenic asphalt; and a block copolymer including a block comprising diene units characterized by having a vinyl content of at least 15% by weight.

Abstract: An asphalt binder is provided, comprising 85 to 97.5 parts by weight of a bitumen and 16 to 2.5 parts by weigh of a polymer composition, wherein the polymer composition comprises: (i) from 2 to 8, preferably from 3 to 6 parts by weight of a styrenic block copolymer having at least two blocks of monovinylaromatic hydrocarbon (A) and at least one block of a conjugated diene (B), wherein the block copolymer composition has a vinyl content of at least 25% by weight, preferably from 25 to 40% by weight, based on the total diene content; (ii) from 0 to 5, preferably from 1 to 3 parts by weight of a styrenic diblock copolymer having one block of monovinylaromatic hydrocarbon (A) and one block of a conjugated diene (B); and (iii) from 0.5 to 3, preferably from 1 to 2.5 parts by weight of an ethylene-vinyl acetate copolymer, wherein the weight ratio of (i)+(ii):(iii) is from 2:1 to 6:1, preferably from 3:1 to 4:1.

Abstract: Disclosed is a modified asphalt composition comprising asphalt and a tapered block copolymer, which contains short butadiene monomer blocks at both ends of aromatic vinyl monomer blocks, that provides comparable or better softening point when compared to conventional compositions, and exhibits superior ductility at low temperature, thereby being applicable to road paving, waterproof sheets and sealants.

Abstract: High performance bituminous mixtures that are useful for the road paving and roofing industries comprise mineral aggregates coated with a thermoplastic polymer composition. Because of their high performance properties, the absence of any aggressive and toxic adhesion promoters and the possibility of using recovered or recycled thermoplastic polymers to form the coating or “membrane,” the bituminous mixtures described herein provide an excellent environmentally friendly solution for pavement construction and roofing industries.

Abstract: In methods of preparing asphalt and elastomeric polymer compositions such as polymer modified asphalt (PMA), it has been discovered that the compatibility can be improved by adding excess amounts of certain organic and inorganic metal salts beyond the proportions normally used. Suitable metal salts may be metal oxides that include, but are not necessarily limited to, zinc oxide, calcium oxide, and the like. The method of the invention also permits asphalt modified with other polymers such as ground tire rubber (GTR) to have improved compatibility. Additionally, the use of excess amounts of these metal salts helps control gel formation.

Abstract: Methods of modifying crude fractions are described herein. The methods generally include blending a crude fraction with an emissions reducing additive to form a modified crude fraction, wherein the modified crude fraction exhibits reduced sulfur emissions. The emissions reducing additive generally includes a dispersion of a metal oxide.

Abstract: Asphalt and elastomeric polymer compositions crosslinked with mixed polythiomorpholines or at least one alkyl polysulfide can give polymer modified asphalts (PMAs) with improved properties and/or reduced H2S evolution. When at least one alkyl polysulfide is used to completely or partially replace conventional crosslinkers such as S or MBT, mercaptobenzimidazole (MBI) may be optionally used as a co-crosslinker. The use of mixed polythiomorpholines as crosslinkers provide PMAs with better low temperature profiles (BBR m-values). The use of at least one alkyl polysulfide crosslinker gives PMAs with improved PAV-aged DSR results, and reduced H2S evolution. The use of at least one alkyl polysulfide crosslinker together with MBI may give PMAs with improved PAV DSR Fail Temperatures.

Abstract: A radial multi-block copolymer composition comprising a polystyrene block A1, a hard block A2 comprising another type of monovinylarene monomer, two soft blocks B, and B2 of conjugated diene monomer and a coupling agent, the composition of the radial multi-block copolymer having the structure (B1A1A2B2)nZ, where the weight percent of n=5+ is greater than about 40 and Z is a residue of the coupling agent. A process comprising (a) anionically polymerizing styrene monomer Al, at least one monovinylarene monomer A2 other than styrene, and at least one conjugated diene monomer B1 to form multi-block copolymer chains having the structure (B1A1A2), wherein the amount of monovinylarene monomer A2 is from about 0.

Abstract: A polymer modified bitumen composition, comprising 80 to 98.5 parts by weight of a bitumen and 20 to 1.

Abstract: The invention relates to anhydrous bituminous products containing one or several specific additives which make it possible to substantially reduce a temperature for producing aggregate and bituminous product mixtures in such a way that it ranges from 20 to 40° C., wherein the temperature of the aggregate and the bituminous product mixture during spreading ranges from 10 to 40° C. and the temperature in the core of the aggregate and bituminous product mixtures during compacting can be raised to 50° C. without degrading the standardized properties of the bituminous product and the bituminous product and aggregate mixture and ensuring the process continuity from transport to compacting according to the state of the art. The inventive aggregate and bituminous product mixtures are particularly suitable for tightening, building and servicing road surfaces, pavements and airfield runways.

Abstract: This invention relates to bituminous compositions comprising an interpolymer and a bituminous material and methods of making and using same. The interpolymer may comprise ethylene, at least one alpha-olefin, and, optionally, at least one diene and the interpolymer is derived from polymer particles having a surface coating comprising a partitioning agent. Methods of making and using the bituminous compositions are also described.

Abstract: In a first aspect, bituminous asphalt binder materials which are modified by the addition of crumb rubber or ground tire rubber are described. In a second aspect, the present invention is directed to methods of producing a modified asphalt binder containing crumb rubber or ground tire rubber. The modified asphalt binders comprise neat asphalt, crumb rubber, one or more synthetic polymers, and one or more acids. The crumb rubber may be obtained from recycled truck and/or automobile tires.

Abstract: Asphalt and polymer mixtures treated with an inorganic acid and cross-linked with sulfur and/or other crosslinkers or accelerators gives a polymer modified asphalt with improved high temperature properties. The acid should be added to the asphalt before the crosslinker.

Abstract: The invention relates to charged bituminous mastics that are used in industrial applications, particularly in the manufacture of indoor or outdoor coatings used for sealing and/or damping vibrations and/or thermal insulation and/or soundproofing and/or fire protection (fire-proofing). The aim of the invention is to provide a mastic which is deformation-resistant when thermally charged and which is also static in ambient temperature conditions prevailing during laying and when ambient temperature is 40° C., which also holds well when cold, offering good dimensional stability. In order to achieve said aim, styrene-indene copolymer resin having a Tg of 40-150° C. and a penetrability at 50° C. of ?10 is used as a structuring agent A of a bituminous mastic comprising bitumen B, a charge C and a polymer D.

Abstract: Block copolymer that can be formed into an ion-conductive membrane are provided. The block copolymer of the invention includes a first polymer block and a second polymer block attached to the first polymer block. The first polymer block has a main polymer chain and one or more side chains extending from the main polymer chain. The one or more side chains include at least one substituent for proton transfer. Block copolymers utilizing phosphoric acid groups are also provided.

Abstract: The present invention is directed to a peroxide curable rubber compound containing a butyl rubber polymer, an olefin polymer of ethylene, at least one ?-olefin and optionally at least one diene, and a high vinyl polybutadiene polymer. The present invention is also directed to a peroxide curable rubber compound containing a butyl polymer, an EP(D)M rubber polymer, and a 1,2-polybutadiene polymer.

Abstract: It is the subject of the present invention to provide a solvent-free ambient-temperature curable composition, excellent in water-resistant adhesion, storage stability and curability, and generates neither smoke nor odor when working therewith. The relevant problem is solved by a curable composition including (A) a natural asphalt and/or petroleum asphalt, (B) a polyoxyalkylene polymer having one or more reactive silicon groups capable of cross-linking by forming siloxane bonds through silanol condensation reaction.

Abstract: The invention provides for processes to produce elastomeric compositions, the processes including contacting at least one elastomer with a processing aid, wherein the processing aid comprises at least one functionalized polymer having at least one anhydride group. The invention also provides for articles such as innerliners for tires produced from the aforementioned elastomeric compositions.

Abstract: In a first aspect, bituminous asphalt binder materials which are modified by the addition of crumb rubber or ground tire rubber are described. In a second aspect, the present invention is directed to methods of producing a modified asphalt binder containing crumb rubber or ground tire rubber. The modified asphalt binders comprise neat asphalt, crumb rubber, one or more synthetic polymers, and one or more acids. The crumb rubber may be obtained from recycled truck and/or automobile tires.

Abstract: This invention provides a rubber composition having an excellent low loss factor and capable of imparting a wear resistance and a fracture resistance to a tire, which is formed by compounding carbon black having a toluene coloring transmittance of not less than 90% and satisfying a relationship between hydrogen emission ratio (% by mass) and cetyltrimethylammonium bromide adsorption specific surface area (CTAB) (m2/g) of the following equation: Hydrogen emission ratio>0.260?6.25×10?4×CTAB into a modified natural rubber formed by adding a polar group-containing monomer to a natural rubber latex to graft-polymerize the polar group-containing monomer onto a natural rubber molecule in the natural rubber latex and then coagulating and drying.

Abstract: A modified asphalt composition is provided comprising at least one plastomer, at least one elastomer, and asphalt. More specifically, a modified asphalt composition is provided comprising an oxidized polyethylene, a styrene-butadiene-styrene block copolymer, and asphalt. A hot mix asphalt composition is also provided comprising the modified asphalt composition and aggregate. Processes for producing the modified asphalt composition and the hot mix asphalt composition is also provided as well as articles produced from these inventive compositions.

Abstract: The present invention relates to a method of improving the hardness and abrasion resistance while maintaining the useful dynamic properties inherent to butyl based tire tread compounds by adding HXNBR to a rubber composition comprising at least one butyl elastomer for a tire tread, in particular a tire tread suitable for a pneumatic tire.

Abstract: An asphalt composition comprising 0.5 to 50 parts by weight of a block copolymer component (I), 100 parts by weight of an asphalt (II) and 0.01 to 10 parts by weight of at least one vulcanizing agent (III) selected from the group consisting of sulfur and a sulfur-containing compound, wherein the block copolymer component (I) comprises at least one modified block copolymer comprising an unhydrogenated or hydrogenated base block copolymer comprising at least one vinyl aromatic polymer block (A) and at least one conjugated diene polymer block (B), and a functional group-containing modifier group bonded to the base block copolymer.

Abstract: Bituminous asphalt binder materials which are modified by the addition of crumb rubber or ground tire rubber and a cross-linking agent are described. In addition, methods are provided for producing a modified asphalt binder containing crumb rubber or ground tire rubber and a cross-linking agent. The modified asphalt binders comprise neat asphalt, crumb rubber, one or more acids and a cross-linking agent. Optionally, the modified asphalt binder may include one or more polymer additives. The crumb rubber may be obtained from recycled truck and/or automobile tires. The addition of crumb rubber in asphalt binders can improve the consistency and properties of the asphalt binders at high and low temperatures. In particular, the modified asphalt binders of the present invention exhibit improved elastic behavior, resulting in improved performance of roads or other surfaces paved using the modified asphalt binder.

Abstract: A second order modified block copolymer which can be obtained by reacting a first order modified block copolymer with a second order modifier, wherein the first order modified block copolymer comprises a base block copolymer and a functional group-containing first order modifier group bonded to the base block co-polymer, wherein the base block copolymer comprises at least one polymer block comprised mainly of vinyl aromatic hydrocarbon monomer units and at least one polymer block comprised mainly of conjugated diene monomer units, and wherein the second order modifier has a specific functional group which is reactive to the functional group of the first order modifier group of the first order modified block copolymer. A second order modified block copolymer containing polymer composition comprising the second order modified block copolymer as well as a thermoplastic resin and/or a rubbery polymer.

Abstract: A hydrogenated copolymer obtained by hydrogenating an unhydrogenated copolymer comprising conjugated diene monomer units and vinyl aromatic monomer units, the hydrogenated copolymer containing at least one hydrogenated copolymer block (B) which is obtained by hydrogenating an unhydrogenated random copolymer block comprised of conjugated diene monomer units and vinyl aromatic monomer units, wherein the hydrogenated copolymer has the following characteristics: the hydrogenated copolymer has a content of the vinyl aromatic monomer units of from more than 40% by weight to less than 95% by weight; at least one peak of loss tangent (tan ?) is observed at ?10 to 80° C. in a dynamic viscoelastic spectrum obtained with respect to the hydrogenated copolymer; and substantially no crystallization peak ascribed to the copolymer block (B) is observed at ?20 to 80° C. in a differential scanning calorimetry (DSC) chart obtained with respect to the hydrogenated copolymer.

Abstract: A hydrogenated copolymer obtained by hydrogenating an unhydrogenated copolymer comprising conjugated diene monomer units and vinyl aromatic monomer units, the hydrogenated copolymer containing at least one hydrogenated copolymer block (B) which is obtained by hydrogenating an unhydrogenated random copolymer block comprised of conjugated diene monomer units and vinyl aromatic monomer units, wherein the hydrogenated copolymer has the following characteristics: the hydrogenated copolymer has a content of the vinyl aromatic monomer units of from more than 40% by weight to less than 95% by weight; at least one peak of loss tangent (tan ?) is observed at ?10 to 80° C. in a dynamic viscoelastic spectrum obtained with respect to the hydrogenated copolymer; and substantially no crystallization peak ascribed to the copolymer block (B) is observed at ?20 to 80° C. in a differential scanning calorimetry (DSC) chart obtained with respect to the hydrogenated copolymer.

Abstract: A polyurethane hot melt adhesive composition comprising an isocyanate, one or more polyols, one or more bituminous materials and optionally one or more thermoplastic materials. Another embodiment is directed to a method for bonding materials together which comprises applying the reactive hot melt adhesive composition in a liquid form to a first substrate, bringing a second substrate in contact with the composition applied to the first substrate, and subjecting the applied composition to conditions which will allow the composition to cool and cure to an irreversible solid form, said conditions comprising moisture. Still another aspect is directed to an article of manufacture comprising the adhesive.

Abstract: The present invention relates to a bituminous composition comprising a bituminous component, an elastomeric polymer component, and a specific cross-linking composition component comprising elemental sulfur, a sulfur-containing derivative, a sulfur activator, a fatty acid or fatty acid derivative and a polymeric carrier. Compositions according to the invention are particularly useful in preparing polymer-modified asphalt (“PMA”) for road applications.

Abstract: The inventive plasticising system is used for plasticising a dienic rubber compound is characterised in that it is based on a MES or TDAE oil and a polylimonene resin. Said rubber compound exhibits an improved abrasion and cut resistance and is based on at least one type of dienic elastomer, a reinforcing filler, a cross-linking system and a plasticising system comprising from 5 to 35 to 35 pce of the MES or TDAE oil and from 5 to 35 to 35 pce of polylimonene resin (pce=parts by weight percent elastomer). Advantageously, said plasticising system also comprises a glycerol unsaturated fatty acid triester (C12-C22), preferably a glycerol trifoliate. The inventive method for producing said compound, using the compound for producing a final or semi-final product for the gripping system of a motor vehicle with ground, in particular the tire or the thread thereof are also disclosed.

Abstract: The present invention is a polymer-modified asphalt composition comprising an elastomeric polymer blend, a low molecular weight plastomer and an un-modified asphalt. Asphalt compositions of the present invention demonstrate improved elasticity and stiffness compared to conventional polymer-modified asphalt compositions.

Abstract: Disclosed herein is a process for improving mechanical properties and thermal stability of composites of poly(vinyl chloride) and at least one natural fiber comprising including in said composite an agent comprising a polymer or copolymer comprising at least one alkali metal salt of at least one polymerized ethylenically unsaturated carboxylic acid. Articles of manufacture comprising the stabilized PVC are also disclosed.

Abstract: Asphalt compositions and methods of forming such are described herein. The asphalt compositions and methods of forming such are generally adapted to enable open air processing while producing asphalt compositions that exhibit properties capable of meeting SUPERPAVE™ specifications.

Abstract: The present invention is directed to an air-blown roofing asphalt modified with polyphosphoric acid and roofing products made with the polyphosphoric acid-modified, air-blown asphalt.

Abstract: A modified asphalt composition is provided comprising at least one plastomer, at least one elastomer, and asphalt. More specifically, a modified asphalt composition is provided comprising an oxidized polyethylene, a styrene-butadiene-styrene block copolymer, and asphalt. A hot mix asphalt composition is also provided comprising the modified asphalt composition and aggregate. Processes for producing the modified asphalt composition and the hot mix asphalt composition is also provided as well as articles produced from these inventive compositions.