Alcohol Compound As Dnrm, I.e., R-oh Patents (Class 524/765)
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Patent number: 5994452Abstract: The present invention relates to primer for promoting adhesion of an electroconductive metal oxide coating over a plastic substrate, to a method of making such a primer, and to a method of adhering an electroconductive metal oxide coating to a plastic substrate. The primer is a carbonate diol-based crosslinked polyurethane, and is more particularly the reaction product of a carbonate diol, a low molecular weight polyol and methylene diisocyanate.Type: GrantFiled: November 5, 1996Date of Patent: November 30, 1999Assignee: PPG Industries Ohio, Inc.Inventors: Thomas G. Rukavina, Robert M. Hunia
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Patent number: 5990233Abstract: The present invention relates to acrylate-based rheology modifiers for use in aqueous compositions having pH of less than or equal to 9 and to the rheologically-modified aqueous compositions, which modifiers contain an emulsion which is prepared by single-stage emulsion polymerization of a C.sub.2 -C.sub.6 alkyl ester of acrylic acid and/or a C.sub.1 -C.sub.6 alkyl ester of methacrylic acid, a monomer chosen from a vinyl-substituted heterocyclic compound containing at least one of a nitrogen or sulfur atom, (meth)acrylamide, a mono- or di- (C.sub.1 -C.sub.4)alkylamino (C.sub.1 -C.sub.4)alkyl (meth)acrylate, a mono or di-(C.sub.1 -C.sub.4)alkylamino (C.sub.1 -C.sub.4)alkyl (meth)acrylamide, and optionally cross-linking monomers and/or associative monomers, in the presence of water, a surfactant, a free-radical initiator and an alcohol selected from C.sub.2 -C.sub.Type: GrantFiled: August 16, 1996Date of Patent: November 23, 1999Assignee: National Starch and Chemical Investment Holding CorporationInventors: Milagros C. Barron, Daniel W. Verstrat, John M. Wilkerson, III
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Patent number: 5985990Abstract: Cross-linked, hydrophilic pressure sensitive adhesive compositions, (meth)acrylate-functional polar polymers which serve as precursors to them, and medical products using such adhesives are disclosed. The cross-linked polymer is prepared by free-radically cross-linking reactive polymers that are functionalized with pendant polymerizable moieties. Medical products that include such compositions are biomedical electrodes, pharmaceutical delivery devices, and medical skin coverings such as wound dressings.Type: GrantFiled: June 23, 1998Date of Patent: November 16, 1999Assignee: 3M Innovative Properties CompanyInventors: Steven S. Kantner, Wilhelm Kuester
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Patent number: 5981644Abstract: A method of producing ABS moulding compositions wherein a solution of polymers in group (A) solvents is gradually supplied to a polymerizing mixture of previously-formed soluble rubber, aromatic mono-alkenyl compounds, ethylenically unsaturated nitrites, optional other copolymerizable compounds and optionally a group (B) solvent or a mixture of group (A) and group (B) solvents, the gradual addition of the polymer solution to the polymerizing mixture being started before the beginning of phase inversion and at a monomer conversion rate of 5 to 15% and a viscosity of the polymerizing mixture of less than 20 Pa.sec with simultaneous continuation of polymerization, the group (A) solvent is an aliphatic (C.sub.1 -C.sub.8) or cycloaliphatic alcohol, ketone, ether, ester and/or nitrile, and the group (B) solvent is an aliphatic (C.sub.4 -C.sub.10), cycloaliphatic and/or aromatic hydrocarbon.Type: GrantFiled: March 14, 1997Date of Patent: November 9, 1999Assignee: Bayer AktiengesellschaftInventors: Ralph Ostarek, Herbert Eichenauer, Karl-Erwin Piejko, Frank Wingler, Claus Wulff
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Patent number: 5942597Abstract: The present invention relates to a process for separating polyhydroxyalkanoate from a biomass, the process comprising extracting the polyhydroxyalkanoate with at least one PHA solvent selected from the group consisting of acetone, acetonitrile, benzene, butyl acetate, butyl propionate, .beta.-butyrolactone, .gamma.-butyrolactone, diethyl carbonate, diethylformamide, dimethyl carbonate, dimethyl succinate, dimethyl sulfoxide, dimethylformamide, ethyl acetate, ethylene glycol diacetate, methyl acetate, methyl ethyl ketone, 1,4-dioxane, tetrahydrofuran, toluene, xylene, and mixtures thereof.Type: GrantFiled: June 28, 1996Date of Patent: August 24, 1999Assignee: The Procter & Gamble CompanyInventors: Isao Noda, Lee Arnold Schechtman
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Patent number: 5939478Abstract: The viscosity of a solvent is modified by thickening the solvent with a silicone latex. A silicone latex having a plurality of crosslinked polysiloxane particles is first prepared by mixing the siloxane polymer, a surfactant, and water; emulsifying the mixture to a gel phase; diluting the emulsion with water; adding a cure package (i.e., a catalyst, a crosslinker, or both, or a self catalytic crosslinker); and then without removing the water from the latex and after the particles of siloxane polymer in the latex have been cured, mixing the latex and solvent to thicken the solvent, forming viscous liquids, gels, and pastes. Water in the latex thickened solvent composition can be stabilized by adding a silicone polyether during mixing of the latex and the solvent.Type: GrantFiled: November 13, 1997Date of Patent: August 17, 1999Assignee: Dow Corning CorporationInventors: James Anderson Beck, Vicky Sue Cobb, Cassie Emelia Cuthbert, Eric Jude Joffre, Virginia Kay O'Neil, Burt Michael Wrolson
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Patent number: 5908694Abstract: A heat-transfer label that is well-suited for use on untreated polyethylene. In one embodiment, the label includes a support portion, the support portion comprising a paper carrier web. The label also includes a wax release layer overcoating the paper carrier web. The label further comprises a transfer portion printed on top of the wax release layer, the transfer portion including a protective lacquer layer, an ink layer and an adhesive layer. The protective lacquer layer is printed onto the wax release layer and comprises a polyester resin, castor oil and a chlorinated polypropylene capable of immobilizing the ink layer relative to the protective lacquer. The ink layer, which comprises an acrylic ink, is printed onto the protective lacquer layer. The adhesive layer is printed over the ink layer and comprises a polyamide resin, ethyl vinyl acetate, erucamide and a chlorinated polyethylene resin.Type: GrantFiled: December 11, 1996Date of Patent: June 1, 1999Assignee: Avery Dennison CorporationInventors: Onsy Y. Makar, Samuel H. Stein
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Patent number: 5905114Abstract: The present invention relates to low-odor binders which can be processed without solvent and are based on aqueous styrene-acrylate polymer dispersions, having a mean film-forming temperature of below 10.degree. C.The invention also relates to low-emission coating compositions, especially emulsion paints, which comprise these binders.Type: GrantFiled: May 22, 1997Date of Patent: May 18, 1999Assignee: BASF AktiengesellschaftInventors: Roland Baumstark, Rolf Dersch
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Patent number: 5905138Abstract: A process for the preparation of a copolymer of carbon monoxide with an olefinically unsaturated compound in which a powder of a copolymer of carbon monoxide with an olefinically unsaturated compound is suspended in a liquid diluent. The suspension is contacted with a catalyst composition which is soluble in the diluent and which is based on a Group VIII metal and a bidentate ligand. The catalyst composition is used in such a quantity that in the polymerization mixture more than 0.1 mmoles of the Group VIII metal is present per liter of liquid phase.Type: GrantFiled: February 19, 1997Date of Patent: May 18, 1999Assignee: Shell Oil CompanyInventor: Johannes Adrianus Maria Van Broekhoven
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Patent number: 5889108Abstract: Low molecular weight siloxane fluids are thickened by silicone elastomers. The silicone elastomers are made by combining in one pot an .tbd.Si--H containing siloxane, a mono-alkenyl polyether, an alpha, omega-diene, and a low molecular weight siloxane fluid. An elastomer, i.e. gel, with polyether groups is produced. The elastomer can be swollen with the low molecular weight siloxane fluid under shear force, to provide a uniform silicone paste. The silicone paste has excellent spreadability upon rubbing, and possesses unique rheological properties in being thixotropic and shear thinning. The silicone paste can be easily emulsified with water to form a stable uniform emulsion, without using a surfactant to allow normally immiscible materials to become intimately mixed.Type: GrantFiled: June 2, 1997Date of Patent: March 30, 1999Assignee: Dow Corning CorporationInventor: Shizhong Zhang
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Patent number: 5889126Abstract: The invention relates to Amorphous and/or semicrystalline copolyesters containing .beta.-hydroxyalkylamide groups according to formula (I) ##STR1## whereinP=polymer chain of the polyesterR1=alkyl residues with 1-5 atoms or hydrogen or ##STR2## R2=alkyl residues with 1-5 C-atoms or hydrogen, R3=alkyl residues and 1-5 C-atoms or hydrogen, andn.gtoreq.2,with a molecular weight (Mn) of 300 to 15,000 and a hydroxyl value of 10 to 400 ?mg KOH/g!.Type: GrantFiled: July 11, 1997Date of Patent: March 30, 1999Assignee: EMS-Inventa AGInventors: Andreas Kaplan, Rene Gisler, Eberhard Kinkelin
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Patent number: 5886093Abstract: The invention relates to a method for preparing a biodegradable aliphatic polyester, which comprises polymerization of a precursor of the polyester in the presence of a polyesterification catalyst in an amount of up to 0.1% by weight, based on the weight of the cyclic precursor, and a co-catalyst comprising glycerol or butyrolactone in a weight proportion of not more than three times that of the catalyst.The invention also relates to the use of the resulting biodegradable aliphatic polyester in polymer processing, such as injection molding or compression/press molding.Type: GrantFiled: May 28, 1998Date of Patent: March 23, 1999Assignee: Kabushiki Kaisha Kobe Seiko ShoInventors: Martin Thomas Davies, Naseer Mohammed Qureshi, Barry Woodfine, Barry Keane
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Patent number: 5877256Abstract: The instant invention pertains to a liquid silicone rubber coating composition for application to air bags that is comprised of (A) a diorganopolysiloxane having at least 2 alkenyl groups in each molecule, (B) an organopolysiloxane resin, (C) an inorganic filler, (D) an organohydrogenpolysiloxane having at least 2 silicon-bonded hydrogen atoms in each molecule, (E) a platinum group metal catalyst, and (F) an epoxy group-containing organosilicon compound. The liquid silicone rubber coating composition of the instant invention is capable of coating synthetic air bag fabrics without the use of a diluting solvent and at the same time that has an excellent adhesion to and infiltrability into synthetic air bag fabrics.Type: GrantFiled: January 22, 1993Date of Patent: March 2, 1999Assignee: Dow Corning Toray Silicone Co., Ltd.Inventors: Akito Nakamura, Yuichi Tsuji
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Patent number: 5853636Abstract: A fiber treating composition and the emulsion of the composition, containing poly-N-vinylalkylamides and/or copolymers thereof, and polyols and/or derivatives thereof; and a synthetic filament production process with melt-spinning at 1,000 m/min or more spinning speed, wherein the above fiber treating composition is applied.Type: GrantFiled: July 29, 1997Date of Patent: December 29, 1998Assignee: Matsumoto Yushi-Seiyaku Co., Ltd.Inventors: Takeshi Munekiyo, Tamotsu Matsunaga, Hirofumi Ishida
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Patent number: 5830981Abstract: A process for producing a polyethylene terephthalate in which the amount of the oligomers, such as cyclic trimer etc., is lower and which causes metal mold staining to occur difficultly. The process comprises an esterification stage in which dicarboxylicacids including mainly terephthalic acid or ester-forming derivatives of such acids are esterified with glycols including mainly ethylene glycol or with ester-forming derivatives of such glycols; a liquid phase polycondensation stage in which the esterified product obtained in the esterification stage is subjected to a polycondensation in a liquid phase containing a polycondensation catalyst and having a content of an alkaline solubilizing agent of 0.Type: GrantFiled: December 9, 1996Date of Patent: November 3, 1998Assignee: Mitsui Petrochemical Industries, Ltd.Inventors: Hiroshi Koreishi, Yasuhiro Tanaka, Kimiyoshi Miura
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Patent number: 5830991Abstract: The invention provides an economical and efficient process for preparing a dimeric cyclic ester of an .alpha.-hydroxycarboxylic acid by depolymerizing a corresponding .alpha.-hydroxycarboxylic acid oligomer, which comprises the steps of (1) heating a mixture containing the .alpha.-hydroxycarboxylic acid oligomer and at least one high-boiling polar organic solvent having a boiling point within a range of 230.degree.-450.degree. C. to a temperature, at which the depolymerization of the oligomer takes place, under atmospheric pressure or reduced pressure, (2) dissolving the oligomer in the solvent until a residual rate of a melt phase of the oligomer reaches 0.5 or lower, (3) further continuing the heating at the temperature, at which the depolymerization of the oligomer takes place, to depolymerize the oligomer, (4) distilling out the dimeric cyclic ester formed together with the high-boiling polar organic solvent, and (5) recovering the dimeric cyclic ester from the distillate.Type: GrantFiled: January 23, 1997Date of Patent: November 3, 1998Assignee: Kureha Kagaku Kagyo KKInventors: Zenya Shiiki, Yukichika Kawakami
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Patent number: 5821299Abstract: The present invention relates to a process for separating polyhydroxyalkanoate (PHA) from a biomass comprising the PHA, the process comprising: a) treating the biomass with a PHA solvent and a marginal nonsolvent for PHA; b) removing any insoluble biomass, thereby leaving behind a solution of PHA and marginal nonsolvent for PHA; and c) removing the PHA solvent from the solution, thereby resulting in a suspension of precipitated PHA in the marginal nonsolvent for PHA. Optionally, the process further comprises removing the marginal nonsolvent for PHA, thereby leaving behind the PHA. The present invention further relates to the suspension and the PHA produced by the process.Type: GrantFiled: February 21, 1997Date of Patent: October 13, 1998Assignee: The Proctor & Gamble CompanyInventor: Isao Noda
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Patent number: 5789485Abstract: The present invention relates to a curable silicone composition comprising (A) an alkenyl-functional organopolysiloxane, (B) a siloxane-modified acrylic polymer, (C) an organohydrogenpolysiloxane, and (D) a hydrosilylation reaction catalyst. The curable silicone compositions of this invention cure into a highly oil-resistant and highly wear-resistant coating and are useful as base compositions for inks for silicone moldings, and are also useful for imparting release against pressure sensitive adhesives while maintaining a degree of printability.Type: GrantFiled: December 24, 1996Date of Patent: August 4, 1998Assignee: Dow Corning Toray Silicone Co., Ltd.Inventors: Akihiko Kobayashi, Takayoshi Otomo, Hiroaki Yoshida
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Patent number: 5753749Abstract: Urethane-filled compositions are produced by reacting a dicyclohexylmethane diisocyanate residue or a dicyclohexylmethane diisocyanate residue containing mixture with a monofunctional alcohol containing at least one ether group in an amount such that the equivalent ratio isocyanate groups to hydroxyl groups is from about 0.9:1 to about 1:0.9. The diisocyanate residue or residue-containing mixture must contain at least 20% by weight monomeric diisocyanate and have a total NCO content of at least 10%. The diisocyanate residue is produced by phosgenating dicyclohexylmethane diamine in which less than 20% polymeric diamine is present. The urethane filled compositions produced in this manner may then be dissolved in either a polyol or a polyisocyanate and subsequently used to produce polyurethanes in known manner.Type: GrantFiled: December 27, 1996Date of Patent: May 19, 1998Assignee: Bayer CorporationInventor: William E. Slack
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Patent number: 5731402Abstract: A process for the production of biodegradable aliphatic polyester particles by (co)polymerizing 2-oxetanone or a mixture containing at least 80% by weight of 2-oxetanone and up to 20% by weight of a cyclic ester or cyclic ether other than 2-oxetanone in the presence of a polymerization initiator supported on a carrier in which an ion polymerization initiator is supported on poly(2-oxetanone) in a liquid medium having a solubility parameter of about 15 to about 18 MPa.sup.1/2 and being capable of dissolving 2-oxetanone, and in a polymerizing apparatus having an internal surface formed of a material which is free of polarity or whose polarity is very small, to form a particulate aliphatic polyester; and a biodegradable aliphatic polyester melt-extrusion film, which comprises the biodegradable aliphatic polyester having a weight average molecular weight of 20,000 to 2,000,000, and having a water vapor transmission rate of 300 to 700 g/m.sup.2.24 hours.25 .mu.m and heat-fusing strength of 500 to 5,000 gf/15 mm.Type: GrantFiled: April 24, 1996Date of Patent: March 24, 1998Assignee: Tokuyama CorporationInventors: Haruo Nishida, Mitsuhiro Yamashita, Norikazu Hattori
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Patent number: 5731374Abstract: An organic solvent-based paint is provided which has, among other things, a perlitic component. The paint resists thermal loading and loss. A series addition of components provides the paint efficiently. The paint is useful for many substrates, including metals.Type: GrantFiled: April 5, 1994Date of Patent: March 24, 1998Assignee: P.S.A.M.S., Inc.Inventors: John W. Good, Rufus H. Kerry
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Patent number: 5728770Abstract: A surface treatment composition which can form a coating having excellent gas barrier properties, transparency and flexibility, contains at least one silane compound component selected from the group consisting of a silane compound (A) having amino groups and hydrolytic condensation groups in their molecules, a hydrolytic condensation product (B) of the silane compound (A), and a co-hydrolytic condensation product (D) of the silane compound (A) and an organometallic compound (C); a compound (E) having at least two functional groups which can react with an amino group in its molecule; and solvent (F).Type: GrantFiled: January 28, 1997Date of Patent: March 17, 1998Assignee: Nippon Shokubai Co., Ltd.Inventors: Tetsuya Yamamoto, Akio Naka, Yukiko Hori, Daijo Tomihisa, Tadahiro Yoneda
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Patent number: 5723555Abstract: Improved application latitude, including blister resistance, has been found attainable using a coating formulation that includes a water dispersible resin comprising the addition copolymerization reaction product of vinyl monomers including an acid group containing monomer, an N-(alkoxymethyl)acrylamide or N-(alkoxymethyl)methacrylamide monomer, and at least one other vinyl monomer, the reaction being carried out in the presence of a solvent including a polyol, wherein the OH groups of polyol molecule are of unequal reactivity. The copolymer may be blended with an amine modified epoxy resin to form a coating composition particularly suitable for application onto metal surfaces such as can stock.Type: GrantFiled: June 27, 1996Date of Patent: March 3, 1998Assignee: PPG Industries, Inc.Inventors: Shanti Swarup, Ronald R. Ambrose, James B. O'Dwyer, Lawrence J. Fitzgerald
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Patent number: 5719229Abstract: This invention relates to solid elastomeric polyurethanes prepared by reacting, in an open mold at an isocyanate index of 80 to 120,(a) an isocyanate prepolymer having an isocyanate content of 3 to 15% by weight and a number average molecular weight of 550 to 20,000 prepared by the reaction of(1) organic polyisocyanates having 2 to 3 NCO groups, and(2) isocyanate-reactive polyester polyols having two to three isocyanate-reactive hydroxyl groups and a number average molecular weight of 400 to 10,000 and prepared in the presence of an esterification catalyst, and optionally containing other isocyanate-reactive compounds,wherein the equivalent ratio of isocyanate groups to isocyanate-reactive groups is 1.2:1 to 34:1;(b) a diol chain extender, optionally in admixture with a crosslinker and/or an amino-containing chain extender and/or crosslinker;(c) 0.001 to 10% by weight, based on the weight of the isocyanate prepolymer, of a catalyst; and(d) 0.Type: GrantFiled: December 28, 1995Date of Patent: February 17, 1998Assignee: Bayer CorporationInventors: Richard S. Pantone, Ashok M. Sarpeshkar
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Patent number: 5717060Abstract: An improved process is described for the preparation of alternating linear copolymers based on carbon monoxide and at least one compound containing an alkenyl unsaturation which comprises reacting in a liquid solvent under the operating conditions, a mixture of carbon monoxide and one or more compounds containing an alkenyl unsaturation in the presence of:(i) a catalyst having general formula (I)?Pd(chel) (chel') !.sup.++ ?A.sup.- !.sub.2 (I)wherein chel and chel' the same or different, represent a nitrogenated or phosphorated bidentate chelating agent, and A.sup.- represents an essentially non-coordinating, non esterifiable and non labile anion of an acid with pKa less than 2; and(ii) a cocatalyst having general formula (II)?chel"H.sup.+ !?A'.sup.- ! (II)wherein A'.sup.-, the same as or different from A.sup.-, has the same meaning defined above and chel" represents a nitrogenated bidentate chelating agent the same as or different from chel and chel'.Type: GrantFiled: October 31, 1996Date of Patent: February 10, 1998Assignee: Enichem S.p.A.Inventors: Anna Sommazzi, Fabio Garbassi, Giovanni Mestroni, Barbara Milani, Lidia Vicentini
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Patent number: 5714574Abstract: A process for preparing a polyketone is disclosed. This comprises polymerising together carbon monoxide, ethylene and optionally at least one C.sub.3 to C.sub.10 alpha-olefin in the presence of a solvent and a catalyst composition derivable from a palladium salt, an anion which is either non-coordinating or weakly coordinating to palladium and a phosphate ligand characterised in that the solvent is either a C.sub.4 to C.sub.10 tertiary aliphatic alcohol or a mixture of a C.sub.4 to C.sub.10 tertiary alcohol and up to 80% by volume of an aprotic solvent. The preferred tertiary alcohols are tertiary butyl alcohol and tertiary amyl alcohol. The aprotic solvents can be an aliphatic ketone or cyclic aliphatic ether; preferred aprotic solvents are THF and 1,4-dioxane.Type: GrantFiled: May 26, 1994Date of Patent: February 3, 1998Assignee: BP Chemicals LimitedInventor: Neil Andrew Cooley
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Patent number: 5708075Abstract: The present invention relates to a curable silicone release coating composition comprising (A) an organopolysiloxane having at least two alkenyl groups per molecule, (B) an organohydrogensiloxane having at least two silicon-bonded hydrogen atoms per molecule, (C) a siloxane resin having silicon-bonded hydrogen groups, (D) a platinum group metal-containing catalyst, and optionally (E) an inhibitor. The compositions of this invention are useful as release coatings for pressure sensitive adhesives.Type: GrantFiled: December 30, 1996Date of Patent: January 13, 1998Assignee: Dow Corning CorporationInventors: Kyuha Chung, Robert Alan Ekeland, Randall Gene Schmidt
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Patent number: 5698662Abstract: The invention relates to a dendritic macromolecule with branches prepared from halogen cyanide units composed of a monohalogenated hydrocarbon compound comprising 3-50 carbon atoms and at least one cyanide group, the halogen and the cyanide group being separated from one another by at least 3 carbon atoms. The invention also relates to a process for the preparation of a dendritic macromolecule, comprising a core and at least one branch emanating from the core, characterized in that the process comprises the steps a) through c):a) substantially every functional group of the core molecule is reacted with monomeric halogen cyanide unitsb) substantially every incorporated cyanide group is reduced to an aminec) substantially every amine group is reacted with monomeric halogen cyanide units,steps b) and c) being conducted alternately.Type: GrantFiled: July 26, 1996Date of Patent: December 16, 1997Assignee: DSM N.V.Inventors: Christiaan J. C. Stoelwinder, Ellen M. M. de Brabander-van den Berg, Atze J. Nijenhuis
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Patent number: 5698627Abstract: A novel additive for papermaking is disclosed. The additive comprises an aqueous solution of a copolymer obtained by reacting (a) an acrylamide, (b) a vinyl monomer which is copolymerizable with component (a) and has a cationic group, (c) at least one of vinyl monomers which are copolymerizable with component (a) and (b) and have 2, 3 or 4 carboxyl groups in a molecule thereof and/or a salt thereof, optionally (e) a nonionic monomer which is copolymerizable with components (a), (b) and (c) if desired, and (d) a cross-linking compound, in the presence of (f) at least one of ethylene glycol, diethylene glycol, diethanolamine and glycerin.This novel additive for papermaking is able to achieve excellent freeness and retention in the process of papermaking and provides paper with increased strength.Type: GrantFiled: March 29, 1996Date of Patent: December 16, 1997Assignee: Japan PMC CorporationInventors: Tadayoshi Oguni, Satoshi Takizawa, Kiyoshi Iwai
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Patent number: 5676742Abstract: The present invention comprises dipropylene glycol dibenzoate and diethylene glycol dibenzoate, the improvement comprising the addition of dipropylene glycol monobenzoate or diethylene glycol monobenzoate, whereby the plasticizer is resistant to fungal growth.Type: GrantFiled: October 30, 1995Date of Patent: October 14, 1997Assignee: Velsicol Chemical CorporationInventors: William D. Arendt, David Wayne Barrington
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Patent number: 5670611Abstract: A process for the copolymerization of carbon monoxide with an olefinically unsaturated compound in which a solid particulate material is suspended in a liquid diluent in which the polymer to be produced forms a suspension. The monomers are contracted in the liquid diluent containing the suspended solid particulate material with a catalyst composition which is based on a source of a Group VIII metal and a boron hydrocarbyl compound.Type: GrantFiled: March 13, 1996Date of Patent: September 23, 1997Assignee: Shell Oil CompanyInventors: Frank Baardman, Arleen Marie Bradford, Jayne Jubb, Pieter Scheerman, Rudolf Jacobus Wijngaarden, Erwin Paulus Petrus Bleeker, Johannes Adrianus Maria Van Broekhoven
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Patent number: 5668249Abstract: A process for the copolymerization of carbon monoxide with an olefinically unsaturated compound in which the monomers are contacted in the presence of a liquid diluent and a protic compound with a catalyst composition which is based on a source of a Group VIII metal and a hydrocarbylborane. A stirring power is transmitted to the polymerization mixture of at least 0.25 kW/m.sup.3.Type: GrantFiled: March 13, 1996Date of Patent: September 16, 1997Assignee: Shell Oil CompanyInventors: Frank Baardman, Arleen Marie Bradford, Jayne Jubb, Pieter Scheerman, Rudolf Jacobus Wijngaarden, Erwin Paulus Petrus Bleeker, Johannes Adrianus Maria Van Broekhoven
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Patent number: 5656718Abstract: Poly-.epsilon.-caprolactones are produced by continuous polymerization of .epsilon.-caprolactone as a melt in an extruder (reactive extrusion) with the use, as polymerization initiator, of aluminium trialkoxides in which at least one alkoxy radical includes at least one other oxygen atom besides the oxygen atom constituting the aluminoxane (AI--O) bond. This oxygen atom is advantageously present in the form of an ester or ether functional group. These initiators are generally in the liquid state at ambient temperature and are furthermore miscible with .epsilon.-caprolactone, with the result that they can be used in the absence of solvent. The appropriate adjustment of the feed flow rates of .epsilon.-caprolactone and of initiator to the extruder permits the manufacture of custom-made poly-.epsilon.-caprolactones which have predesigned weight-average molecular masses.Type: GrantFiled: March 29, 1996Date of Patent: August 12, 1997Assignee: Solvay (Societe Anonyme)Inventors: Henri Wautier, Lucienne Detournay, Martine Kaszacs
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Patent number: 5652302Abstract: The invention is an improvement in a process for producing silicone resins, to produce a silicone resin that has a high dynamic viscosity of at 293.degree. K. of from about 40 to about 300 mPas, a long shelf life, and a siloxane content of from about 50 to about 70 ma %, by the condensation of oligomeric siloxanes in concentrated solutions, by carrying out the condensation by heating at reflux and in the presence of a metal containing catalyst and dicarboxylic acid.Type: GrantFiled: January 30, 1991Date of Patent: July 29, 1997Assignee: Huls Silicone GmbHInventors: Lothar Heinrich, Helga Sadowski, Gunter Beuschel
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Patent number: 5648446Abstract: Provided by the present invention are novel diguanamine derivatives, led by 2,5/2,6-bis(4,6-diamino-1,3,5-triazin-2-yl)-bicyclo[2.2.1]heptanes and 1,3/1,4-bis(4,6-diamino-1,3,5-triazin-2-yl)-cyclohexanes, and derivatives thereof, applications of these compounds in fields such as adhesives and paints, utilization of these compounds in flame-retarding, thermal stabilization and compatibilization methods of resins, thermosetting molding compositions and thermosetting expansion-molding compositions making use of these compounds, as well as polymeric microspheres also using these compounds. These compounds are expected to find wide spread industrial utility as various excellent properties can be obtained by using them.Type: GrantFiled: March 30, 1995Date of Patent: July 15, 1997Assignee: Mitsui Toatsu Chemicals, Inc.Inventors: Tetsuya Oishi, Jin Suzuki, Kouhei Ohkawa, Hiroshi Ono
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Patent number: 5610231Abstract: Thermoplastic polyesters are prepared by multistage polycondensation of dihydroxy compounds with dicarboxylic acids or esters or ester-forming derivatives thereof by a process in which, in at least one first stage, an alkali metal compound or an alkaline earth metal compound is added in an amount of from 1 to 10 mmol, calculated as alkali metal or alkaline earth metal, per kg of polyester, and at least one further stage is carried out as a solid-phase condensation.Type: GrantFiled: April 17, 1996Date of Patent: March 11, 1997Assignee: BASF AktiengesellschaftInventor: Peter Braune
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Patent number: 5608030Abstract: Process for continuous preparation of homo- and copolyoxymethylenes with stable end groups in a homogeneous phase, in which in a tubular reactor with static mixing elements cyclic formaldehyde oligomers are polymerized in the presence of protonic acids as initiators in amounts of 0.005 to 500 ppm in a polymerization zone, in which the residence time of the reaction components in this zone is 0.1 to 10 min and in which the initiator is deactivated immediately after polymerization, there being a fluid transition between the polymerization and deactivator zones which is determined solely by the addition of deactivator, and in which, besides deactivation, stabilization of the chain ends is carried out in the presence of residual monomers, with the volatile constituents being removed from the reaction mixture in a subsequent vent unit. Stabilization is carried out in the presence of alkaline substances, either at temperatures of 150.degree. C. to 250.degree. C.Type: GrantFiled: August 15, 1994Date of Patent: March 4, 1997Assignee: Hoechst AktiengesellschaftInventors: Michael Hoffmockel, Karl-Friedrich M uck, Helmut Schlaf, Karlheinz Burg
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Patent number: 5605957Abstract: A silicone composition containing: (A) 100 parts by weight of organopolysiloxane; 0.1 to 50 parts by weight of thickening agent (C) 0.01 to 20 parts by weight of fluorine-containing surfactant; and (D) 0.1 to 20 parts by weight of volatile water-soluble solvent.Type: GrantFiled: June 10, 1994Date of Patent: February 25, 1997Assignee: Alps Electric Co., Ltd.Inventor: Yoshiro Yoshida
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Patent number: 5605958Abstract: A composition for surface treatment, which comprises the following components (I), (II) and (III) as essential components:(I) at least one compound capable of forming a coating film with a contact angle of at least 70.degree. against water;(II) a solvent capable of dissolving the component (I); and(III) a solvent having an evaporation rate lower than the component (II).Type: GrantFiled: September 20, 1995Date of Patent: February 25, 1997Assignee: Asahi Glass Company Ltd.Inventors: Takashige Yoneda, Fumiaki Gunji, Takeshi Morimoto, Yukiko Ono
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Patent number: 5596039Abstract: Provided by the present invention are novel diguanamine derivatives, led by 2,5/2,6-bis(4,6-diamino-1,3,5-triazin-2-yl)-bicyclo[2.2.1]heptanes and 1,3/1,4-bis(4,6-diamino-1,3,5-triazin-2-yl)-cyclohexanes, and derivatives thereof, applications of these compounds in fields such as adhesives and paints, utilization of these compounds in flame-retarding, thermal stabilization and compatibilization methods of resins, thermosetting molding compositions and thermosetting expansion-molding compositions making use of these compounds, as well as polymeric microspheres also using these compounds. These compounds are expected to find wide spread industrial utility as various excellent properties can be obtained by using them.Type: GrantFiled: February 24, 1994Date of Patent: January 21, 1997Assignee: Mitsui Toatsu Chemicals, IncorporatedInventors: Tetsuya Oishi, Hiroshi Ozawa, Minato Karasawa, Masamitsu Inomata, Izumi Mega, Atsuyoshi Yamauchi
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Patent number: 5578381Abstract: The present invention relates to a release coating composition comprising an organopolysiloxane having fluorine containing organic groups and alkenyl groups, an organohydrogensiloxane, and a platinum-containing catalyst. The present invention also relates to a release coating composition comprising an organopolysiloxane having fluorine containing organic groups and silicon-bonded hydrogen groups, an alkenyl functional organopolysiloxane, and a platinum-containing catalyst. The curable silicone release coating compositions of this invention have excellent release properties from various tacky substances, especially silicone-based pressure sensitive adhesives, after curing, and also have excellent bonding characteristics when applied to various substrates.Type: GrantFiled: August 30, 1995Date of Patent: November 26, 1996Assignee: Dow Corning Toray Silicone Co., Ltd.Inventors: Yuji Hamada, Hideki Kobayashi, Wataru Nishiumi
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Patent number: 5576383Abstract: A method for production of antistatic polymer materials which includes an introduction of antistatic agent in the form of a solution of the antistatic agent in an organic solvent, compatible during processing thereof is described. The antistatic agent is at least one compound from the group consisting of organic and inorganic salts, complex compounds and bases. The composition is processed at temperatures not exceeding the least of the boiling and decomposition temperatures of antistatic and solvent. An organic acid is additionally introduced into the composition. The organic solvents are glycols, esters and their derivatives.Type: GrantFiled: February 6, 1995Date of Patent: November 19, 1996Inventor: Vitaly I. Kryshtob
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Patent number: 5574083Abstract: Disclosed are certain aromatic polycarbodiimides. Also disclosed is the use of an aromatic polycarbodiimide containing only aromatic carbodiimide groups as a cross-linker for a coating binder polymer bearing carboxyl groups.Type: GrantFiled: April 29, 1994Date of Patent: November 12, 1996Assignee: Rohm and Haas CompanyInventors: Ward T. Brown, James C. Day
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Patent number: 5569726Abstract: Provided by the present invention are novel diguanamine derivatives, led by 2,5/2,6-bis(4,6-diamino-1,3,5-triazin-2-yl)-bicyclo[2.2.1]heptanes and 1,3/1,4-bis(4,6-diamino-1,3,5-triazin-2-yl)-cyclohexanes, and derivatives thereof, applications of these compounds in fields such as adhesives and paints, utilization of these compounds in flame-retarding, thermal stabilization and compatibilization methods of resins, thermosetting molding compositions and thermosetting expansion-molding compositions making use of these compounds, as well as polymeric microspheres also using these compounds. These compounds are expected to find wide spread industrial utility as various excellent properties can be obtained by using them.Type: GrantFiled: March 30, 1995Date of Patent: October 29, 1996Assignee: Mitsui Toatsu Chemicals, Inc.Inventors: Tetsuya Oishi, Jin Suzuki, Kouhei Ohkawa, Satoshi Furusawa, Hiroshi Ono, Kazuo Sugazaki
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Patent number: 5567347Abstract: The present invention relates to fiber treatment compositions comprising an unsaturated acetate, an organohydrogensiloxane, a metal catalyst, an organosilicon compound, and optionally a dispersant. The compositions of the present invention impart beneficial characteristics such as slickness, softness, compression resistance and water repellency to substrates such as fibers and fabrics.Type: GrantFiled: January 29, 1996Date of Patent: October 22, 1996Assignee: Dow Corning CorporationInventors: Jeffrey A. Kosal, Diane M. Kosal, Anthony Revis
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Patent number: 5567764Abstract: The present invention relates to the use of silicone anchorage additives in curable silicone coatings. The silicone anchorage additive of the invention is an alkoxy containing alkenyl functional organopolysiloxane, and these additives can be used in silicone coatings to provide superior anchorage while maintaining fast cure rates especially on films.Type: GrantFiled: July 28, 1995Date of Patent: October 22, 1996Assignee: Dow Corning CorporationInventors: Michael J. Brasseur, Kun-Long Chen
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Patent number: 5565517Abstract: A process for preparing an organic polysulfide polymer, such as polyethylene trisulfide, is provided which comprises contacting a dimercaptan such as 1,2-ethanedithiol with elemental sulfur using a basic catalyst wherein the dimercaptan, elemental sulfur, and basic catalyst are each present in an effective amount to effect the preparation of the organic polysulfide polymer. A process for controlling the molecular weight of an organic polysulfide polymer is also provided which comprises contacting a mercaptan with a dimercaptan and sulfur, in the presence of a basic catalyst, under conditions sufficient to prepare an organic polysulfide polymer.Type: GrantFiled: November 16, 1994Date of Patent: October 15, 1996Assignee: Phillips Petroleum CompanyInventors: Howard F. Efner, James E. Shaw
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Patent number: 5556572Abstract: There are herein disclosed a rubber composition for cleaning a mold which comprises 100 parts by weight of a natural rubber and/or a synthetic rubber, 2 to 30 parts by weight of an amino-alcohol salt in terms of an amino-alcohol content, 5 to 50 parts by weight of a glycol, 30 to 90 parts by weight of an adsorbent and 0.5 to 10 parts by weight of an organic peroxide, and a method for cleaning the mold by the use of this rubber composition.Since the amino-alcohol is fixed as the salt, the generation of ammonia odor at the time of kneading or at room temperature can be prevented to improve a working environment, and the volatilization of the amino-alcohol can be inhibited, whereby a mold cleaning effect can be maintained even after the lapse of a long time.Type: GrantFiled: June 6, 1995Date of Patent: September 17, 1996Assignee: Bridgestone CorporationInventors: Koutaro Nishinaka, Yasuyoshi Kawaguchi
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Patent number: 5538547Abstract: A process for impregnating wood and wood products wherein the wood is treated with a composition comprising;(A) a salt of an organic or inorganic acid and an organopolysiloxane which contains SiC-bonded radicals with basic nitrogen in amounts of at least 0.5% by weight of basic nitrogen, based on the weight of this organopolysiloxane,(B) a water-repellent active compound which is not solid at 20.degree. C. under 1020 hPa, with the proviso that the water-repellent active compound can also be an organosilicon compound which is solid at 20.degree. C. under 1020 hPa and dissolves under these conditions to the extent of more than 50 parts by weight in 100 parts by weight of (A), if appropriate mixed with an organosilicon compound containing basic nitrogen in amounts of 0% to 0.5% by weight, based on the weight of this organosilicon compound, and/or silicic acid esters, and(c) water.Wood and wood products treated with the composition described above exhibit substantially reduced water absorption.Type: GrantFiled: April 19, 1994Date of Patent: July 23, 1996Assignee: Wacker-Chemie GmbHInventors: Dieter Gerhardinger, Hans Mayer, Guenther Kolleritsch
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Patent number: 5539022Abstract: Water-dilutable dispersions of acrylate copolymers having a hydroxyl number of from 40 to 200 mg KOH/g and an acid number of from 15 to 50 mg of KOH/g, obtained by free-radical copolymerization ofa) from 5 to 40 parts by weight of at least one glycidyl ester of an .alpha.-branched aliphatic saturated monocarboxylic acid,b) from 0 to 30 parts by weight of at least one diester of an .alpha.,.beta.-olefinically unsaturated dicarboxylic acid,c) from 0 to 70 parts by weight of at least one vinyl aromatic hydrocarbon, the molar quantity of component c) always being greater than or equal to the molar quantity of component b),d) from 0 to 60 parts by weight of an alkyl ester of an .alpha.,.beta.-olefinically unsaturated carboxylic acid,e) from 2 to 40 parts by weight of at least one .alpha.,.beta.-olefinically unsaturated carboxylic acid, the molar quantity of component e) always being greater than the molar quantity of component a),f) from 5 to 40 parts by weight of at least one hydroxyalkyl ester of an .alpha.,.Type: GrantFiled: April 4, 1994Date of Patent: July 23, 1996Assignee: Hoechst AktiengesellschaftInventors: Holger Schmidt, Tanja R. Brueck, Uwe Kubillus, Harald Oswald, Petra Schaub, Andrea Travers-Hemmer