With Water Nrm Patents (Class 524/767)
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Patent number: 5962570Abstract: A process for the preparation of an aqueous solution or dispersion containing a cationic polymer, which comprises the steps of: polymerizing a monomer including an N-vinylcarboxylic acid amide represented by the general formula CH.sub.2 .dbd.CHNHCOR, wherein R represents a hydrogen atom or methyl group, in an aqueous medium in the presence of either or both of a polyethylene glycol and polypropylene glycol; and then modifying the resulting polymer with an acid or base. Furthermore, an aqueous composition containing a cationic polymer, which comprises (A) a modified N-vinylcarboxylic acid amide polymer, (B) either or both of a polyethylene glycol and polypropylene glycol, and (C) water is disclosed.Type: GrantFiled: December 13, 1996Date of Patent: October 5, 1999Assignee: Mitsubishi Chemical CorporationInventors: Shin-ichi Sato, Takahiro Oshida, Takashi Ono, Kiyoji Kuma, Yasuharu Mori, Atsuo Takeuchi
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Patent number: 5905138Abstract: A process for the preparation of a copolymer of carbon monoxide with an olefinically unsaturated compound in which a powder of a copolymer of carbon monoxide with an olefinically unsaturated compound is suspended in a liquid diluent. The suspension is contacted with a catalyst composition which is soluble in the diluent and which is based on a Group VIII metal and a bidentate ligand. The catalyst composition is used in such a quantity that in the polymerization mixture more than 0.1 mmoles of the Group VIII metal is present per liter of liquid phase.Type: GrantFiled: February 19, 1997Date of Patent: May 18, 1999Assignee: Shell Oil CompanyInventor: Johannes Adrianus Maria Van Broekhoven
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Patent number: 5854341Abstract: An anti-fogging coating composition contains (a) an inorganic alkoxide and/or a hydroxyl group-containing polymer formed therefrom by hydrolysis and polycondensation, the inorganic alkoxide being represented by the formula (I):M(OR).sub.n (X).sub.a-n (I),wherein M is an inorganic element selected from the group consisting of Si, Al, Ti, Zr, Ca, Fe, V, Sn, Li, Be, B and P; R is an alkyl group; X is an alkyl group with or without functional groups or a halogen atom; a is a number representing the valence of M; and n is an integer from 1 to a; (b) a polyalkylene oxide, a weight ratio of the polyalkylene oxide to the inorganic alkoxide and/or the hydroxyl group-containing polymer being 100/1-100/150; (c) 0.5 parts by weight or less of an acid catalyst per 100 parts by weight of (a); (d) 0.Type: GrantFiled: December 8, 1995Date of Patent: December 29, 1998Assignees: Nakato Laboratory, Inc., Canon Kabushiki KaishaInventors: Tohru Yamamoto, Shigeo Yoshida, Hatsumi Ikari
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Patent number: 5824737Abstract: The invention relates to the use of a mixture of(a1) a naturally occurring, zwitterionic phosphatide or a mixture of naturally occurring zwitterionic phosphatides and(a2) cholic acid and/or a salt of cholic acid and/or deoxycholic acid and/or a salt of deoxycholic acid and/or ricinoleic acid and/or a salt of ricinoleic acid and/or oleic acid and/or a salt of oleic acidas an emulsifier for the preparation of aqueous polymer dispersions which can be prepared by free radical emulsion polymerization of monomers which can be polymerized by free radicals or mixtures of monomers which can be polymerized by free radicals.Type: GrantFiled: April 8, 1996Date of Patent: October 20, 1998Assignee: BASF Lacke + Farbem AGInventor: Markus Antonietti
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Patent number: 5821299Abstract: The present invention relates to a process for separating polyhydroxyalkanoate (PHA) from a biomass comprising the PHA, the process comprising: a) treating the biomass with a PHA solvent and a marginal nonsolvent for PHA; b) removing any insoluble biomass, thereby leaving behind a solution of PHA and marginal nonsolvent for PHA; and c) removing the PHA solvent from the solution, thereby resulting in a suspension of precipitated PHA in the marginal nonsolvent for PHA. Optionally, the process further comprises removing the marginal nonsolvent for PHA, thereby leaving behind the PHA. The present invention further relates to the suspension and the PHA produced by the process.Type: GrantFiled: February 21, 1997Date of Patent: October 13, 1998Assignee: The Proctor & Gamble CompanyInventor: Isao Noda
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Patent number: 5731368Abstract: Aqueous dispersions of vinyl polymers are disclosed. The polymers are copolymers of a vinyl halide, a vinyl ester, e.g., vinyl acetate, and a poly(alkylene glycol)-based macromonomer, e.g., poly(ethylene glycol)-maleic anhydride. Also disclosed are processes for the preparation of the aqueous dispersions which comprise forming the copolymer by solution polymerization, converting the dissolved polymer into an aqueous dispersion and removing the solvent from the aqueous dispersion.Type: GrantFiled: September 1, 1995Date of Patent: March 24, 1998Assignee: Union Carbide Chemicals & Plastics Technology CorporationInventors: James Preston Stanley, Eric Jay Nagel, Richard Jude Burns, Walter Paul Mayer, Steven Nicholas Semerak
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Patent number: 5698627Abstract: A novel additive for papermaking is disclosed. The additive comprises an aqueous solution of a copolymer obtained by reacting (a) an acrylamide, (b) a vinyl monomer which is copolymerizable with component (a) and has a cationic group, (c) at least one of vinyl monomers which are copolymerizable with component (a) and (b) and have 2, 3 or 4 carboxyl groups in a molecule thereof and/or a salt thereof, optionally (e) a nonionic monomer which is copolymerizable with components (a), (b) and (c) if desired, and (d) a cross-linking compound, in the presence of (f) at least one of ethylene glycol, diethylene glycol, diethanolamine and glycerin.This novel additive for papermaking is able to achieve excellent freeness and retention in the process of papermaking and provides paper with increased strength.Type: GrantFiled: March 29, 1996Date of Patent: December 16, 1997Assignee: Japan PMC CorporationInventors: Tadayoshi Oguni, Satoshi Takizawa, Kiyoshi Iwai
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Patent number: 5681891Abstract: A method for producing a polychloroprene latex, which comprises copolymerizing chloroprene and an ethylenically unsaturated carboxylic acid in the presence of a polyvinyl alcohol, wherein a glycol ether is also present during the copolymerization.Type: GrantFiled: January 19, 1996Date of Patent: October 28, 1997Assignees: Denki Kagaku Kogyo Kabushiki Kaisha, Konishi Co., Ltd.Inventors: Mikitoshi Satoh, Masao Koga, Shigeru Nagasawa, Kunihiko Asano, Toshiyuki Uenoyama, Kunihiro Onishi
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Patent number: 5670611Abstract: A process for the copolymerization of carbon monoxide with an olefinically unsaturated compound in which a solid particulate material is suspended in a liquid diluent in which the polymer to be produced forms a suspension. The monomers are contracted in the liquid diluent containing the suspended solid particulate material with a catalyst composition which is based on a source of a Group VIII metal and a boron hydrocarbyl compound.Type: GrantFiled: March 13, 1996Date of Patent: September 23, 1997Assignee: Shell Oil CompanyInventors: Frank Baardman, Arleen Marie Bradford, Jayne Jubb, Pieter Scheerman, Rudolf Jacobus Wijngaarden, Erwin Paulus Petrus Bleeker, Johannes Adrianus Maria Van Broekhoven
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Patent number: 5668249Abstract: A process for the copolymerization of carbon monoxide with an olefinically unsaturated compound in which the monomers are contacted in the presence of a liquid diluent and a protic compound with a catalyst composition which is based on a source of a Group VIII metal and a hydrocarbylborane. A stirring power is transmitted to the polymerization mixture of at least 0.25 kW/m.sup.3.Type: GrantFiled: March 13, 1996Date of Patent: September 16, 1997Assignee: Shell Oil CompanyInventors: Frank Baardman, Arleen Marie Bradford, Jayne Jubb, Pieter Scheerman, Rudolf Jacobus Wijngaarden, Erwin Paulus Petrus Bleeker, Johannes Adrianus Maria Van Broekhoven
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Patent number: 5661205Abstract: A method for producing a polychloroprene latex, which comprises copolymerizing chloroprene and an ethylenically unsaturated carboxylic acid in the presence of a polyvinyl alcohol, wherein a glycol ether is also present during the copolymerization.Type: GrantFiled: January 18, 1996Date of Patent: August 26, 1997Assignees: Denki Kagaku Kogyo Kabushiki Kaisha, Konishi Co., Ltd.Inventors: Mikitoshi Satoh, Masao Koga, Shigeru Nagasawa, Kunihiko Asano, Toshiyuki Uenoyama, Kunihiro Onishi
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Patent number: 5633314Abstract: An aqueous aerosol coating composition, which includes a thermoplastic acrylic polymer solubilized in an aqueous solution of a monohydric alcohol. The coating composition may further be blended with a controlling amount of a water soluble or water reducible acrylic polymer for imparting a desired degree of gloss and alkali resistance to a coating made from the aqueous aerosol coating composition. The compositions of this invention provide for improved drying rates, hardness and alkali resistance over current aqueous systems.Type: GrantFiled: June 6, 1995Date of Patent: May 27, 1997Assignee: Rohm and Haas CompanyInventor: Homayoun Jamasbi
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Patent number: 5608030Abstract: Process for continuous preparation of homo- and copolyoxymethylenes with stable end groups in a homogeneous phase, in which in a tubular reactor with static mixing elements cyclic formaldehyde oligomers are polymerized in the presence of protonic acids as initiators in amounts of 0.005 to 500 ppm in a polymerization zone, in which the residence time of the reaction components in this zone is 0.1 to 10 min and in which the initiator is deactivated immediately after polymerization, there being a fluid transition between the polymerization and deactivator zones which is determined solely by the addition of deactivator, and in which, besides deactivation, stabilization of the chain ends is carried out in the presence of residual monomers, with the volatile constituents being removed from the reaction mixture in a subsequent vent unit. Stabilization is carried out in the presence of alkaline substances, either at temperatures of 150.degree. C. to 250.degree. C.Type: GrantFiled: August 15, 1994Date of Patent: March 4, 1997Assignee: Hoechst AktiengesellschaftInventors: Michael Hoffmockel, Karl-Friedrich M uck, Helmut Schlaf, Karlheinz Burg
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Patent number: 5574081Abstract: This invention relates to a paint composition comprising a clay-containing pigment system, a latex binder, a polysaccharide thickener, and 0.005% to 2%, based upon the weight of the pigment, of a blocking agent which serves to prevent more than 20% of the polysaccharide thickener from being adsorbed onto the clay pigment surface, whereby the paint composition exhibits improved appearance and application performance.Type: GrantFiled: October 11, 1994Date of Patent: November 12, 1996Assignee: Aqualon CompanyInventor: Gijsbert Kroon
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Patent number: 5565517Abstract: A process for preparing an organic polysulfide polymer, such as polyethylene trisulfide, is provided which comprises contacting a dimercaptan such as 1,2-ethanedithiol with elemental sulfur using a basic catalyst wherein the dimercaptan, elemental sulfur, and basic catalyst are each present in an effective amount to effect the preparation of the organic polysulfide polymer. A process for controlling the molecular weight of an organic polysulfide polymer is also provided which comprises contacting a mercaptan with a dimercaptan and sulfur, in the presence of a basic catalyst, under conditions sufficient to prepare an organic polysulfide polymer.Type: GrantFiled: November 16, 1994Date of Patent: October 15, 1996Assignee: Phillips Petroleum CompanyInventors: Howard F. Efner, James E. Shaw
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Patent number: 5539022Abstract: Water-dilutable dispersions of acrylate copolymers having a hydroxyl number of from 40 to 200 mg KOH/g and an acid number of from 15 to 50 mg of KOH/g, obtained by free-radical copolymerization ofa) from 5 to 40 parts by weight of at least one glycidyl ester of an .alpha.-branched aliphatic saturated monocarboxylic acid,b) from 0 to 30 parts by weight of at least one diester of an .alpha.,.beta.-olefinically unsaturated dicarboxylic acid,c) from 0 to 70 parts by weight of at least one vinyl aromatic hydrocarbon, the molar quantity of component c) always being greater than or equal to the molar quantity of component b),d) from 0 to 60 parts by weight of an alkyl ester of an .alpha.,.beta.-olefinically unsaturated carboxylic acid,e) from 2 to 40 parts by weight of at least one .alpha.,.beta.-olefinically unsaturated carboxylic acid, the molar quantity of component e) always being greater than the molar quantity of component a),f) from 5 to 40 parts by weight of at least one hydroxyalkyl ester of an .alpha.,.Type: GrantFiled: April 4, 1994Date of Patent: July 23, 1996Assignee: Hoechst AktiengesellschaftInventors: Holger Schmidt, Tanja R. Brueck, Uwe Kubillus, Harald Oswald, Petra Schaub, Andrea Travers-Hemmer
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Patent number: 5494947Abstract: A joint compound which remains flexible upon curing and therefore tailored for manufactured housing processes, comprising an acrylate, a biocide, a reinforcing agent, a latex, a first surfactant, a plasticizer, a coalescent agent, a fungicide, a filler, and a second coalescent, all materials being present in predetermined weight percents. A method for producing flexible joints is also provided whereby joints formed by abutting panels are sealed with a joint compound, said joint compound having the characteristic of remaining flexible upon curing or setting.Type: GrantFiled: October 28, 1994Date of Patent: February 27, 1996Assignee: Lynxx International Inc.Inventor: James C. Kaplan
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Patent number: 5417744Abstract: An optically clear hydrophobic coating is prepared by combining in the presence of water fluorinated polysiloxane having multiple hydrolyzable side groups selected from the group including alkyl, aryl, or alkoxy groups having from one to four carbon atoms, with polysiloxane, with polyester modified polysiloxane, with acid, and with alcohol. The polysiloxane ingredients are combined and blended together. The acid and alcohol ingredients are combined together and mixed with the polysiloxane ingredients. The polysiloxane ingredients undergo hydrolysis and polycondensation/polymerization reactions to form a fluorinated polyester modified polysiloxane polymer that when applied to a substrate surface cures at ambient temperatures to form a durable, weather, chemical and heat resistant, optically clear hydrophobic protective coating.Type: GrantFiled: December 29, 1993Date of Patent: May 23, 1995Assignee: Ameron, Inc.Inventor: Roland L. Gasmena
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Patent number: 5416157Abstract: Provided is a process useful for making acrylic polymers of methacrylic acid having improved shear stability. The process provides polymers useful as enteric coatings for medicaments having improved coating efficiency of pharmaceutical forms. Also provided are medicaments in solid form coated with said polymers.Type: GrantFiled: September 9, 1993Date of Patent: May 16, 1995Assignee: Eastman Chemical CompanyInventors: Robert G. Chen, Nancy M. Clipse
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Patent number: 5399616Abstract: Lubricant-containing aqueous preparations of copolymers are obtainable by polymerisation of(A) 70 to 95% by weight of a monomer mixture of(a) 20 to 90% by weight of an ethylenically unsaturated carboxylic acid, in particular of a monocarboxylic acid, or of a corresponding amide,(b) 10 to 80% by weight of a sulfonated, aliphatic or aromatic monovinyl compound, and(c) 0 to 25% by weight of N-vinylpyrrolidone or of an N-vinyl-substituted amide of a saturated aliphatic monocarboxylic acid in the presence of(B) 5 to 30% by weight of a polyol whose hydroxyl groups have been esterified with a fatty acid of 8 to 26 carbon atoms, the sum totals of (A) and (B) on the one hand and (a), (b) and (c) on the other each adding up to 100%.Type: GrantFiled: April 8, 1993Date of Patent: March 21, 1995Assignee: Ciba-Geigy CorporationInventors: Martin Kuhn, Philippe Ouziel, Hans-Ulrich Berendt, deceased
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Patent number: 5380790Abstract: Provided is a process useful for preparing acrylic polymers of methacrylic acid and ethyl acrylate. The process provides polymers useful as enteric coatings for medicaments in solid form, said coatings having improved effectiveness, reproducibility and coating efficiency. Also provided are medicaments in solid form coated with such polymers.Type: GrantFiled: September 9, 1993Date of Patent: January 10, 1995Assignee: Eastman Chemical CompanyInventors: Robert G. Chen, Stephen H. Wu
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Patent number: 5378735Abstract: An ultraviolet-curing covering composition comprising Component A which is obtained by reacting a hydroxyl group-containing polyfunctional acrylate with a silane coupling agent containing an isocyanate group(s), Component B of a polyfunctional acrylate having 3 or more acryloyl groups in the molecule, Component C of a silica sol in an organic solvent, and Component D of a photopolymerization initiator. This composition forms a coating film shows excellent hardwearing properties and adhesion to plastic substrates after ultraviolet-curing. Blending Component E of an acrylic resin and Component F of a solvent to the composition forms a coating film which can be processed before curing.Type: GrantFiled: April 6, 1993Date of Patent: January 3, 1995Assignee: Mitsubishi Petrochemical Company, Ltd.Inventors: Noritaka Hosokawa, Kazuhide Hayama
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Patent number: 5366808Abstract: A water reducible weatherstrip coating comprising a three component system including a silicone emulsion base, an adhesion promoter and a catalyst. The coating provides slippery films having good freeze release properties and abrasion resistant properties while avoiding the problems associated with solvent based coatings.Type: GrantFiled: June 17, 1993Date of Patent: November 22, 1994Assignee: General Electric CompanyInventor: Chak-Kai Yip
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Patent number: 5362830Abstract: Crosslinkable copolymers of (a) 80-99% by wt. vinylpyrrolidone (VP) and 1-20% by wt. of a tertiary-amine-containing polymerizable monomer, e.g. vinylimidazole (VI) or 4-vinylpyridine (VPy), and (b) 80-99% by wt. VP and 1-20% by wt. of an epoxide-containing polymerizable monomer, e.g. allyl glycidyl ether (AGE) or glycidyl acrylate (GA), are reacted in solution, e.g. water, alcohol, or mixtures thereof, at a predetermined temperature, e.g. 50.degree.-70.degree. C., in a wt. ratio (solids basis) of (a):(b) of about 2:1 to 1:2, preferably about 1:1, in a solution concentration of about 10-30% of each, to provide a crosslinked PVP product, in gel form, suitable for use as an electrolead on a conductive foilbacking, or for bandages and wound dressings, and as a controlled release media for pharmaceuticals.Type: GrantFiled: September 15, 1993Date of Patent: November 8, 1994Assignee: ISP Investments Inc.Inventors: Jui-Chang Chuang, Jenn S. Shih, Robert B. Login
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Patent number: 5336715Abstract: Organopolysiloxane compositions which comprise (A) a salt of a water-soluble organic or inorganic acid and an organopolysiloxane which has at least one SiC-bonded organic radical containing basic nitrogen, and (B) an alkoxylated alcohol and also, optionally, (C) a salt of a water-insoluble organic acid and an organopolysiloxane, which has at least one SiC-bonded organic radical containing basic nitrogen.Type: GrantFiled: February 8, 1993Date of Patent: August 9, 1994Assignee: Wacker-ChemieInventors: Johann Sejpka, Dieter Gerhardinger, Franz Wimmer
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Patent number: 5310780Abstract: Low VOC penetrating compositions for staining and protecting porous substrates such as wood, concrete, cement, brick and the like, comprising aqueous dispersions of polyurethane-ureas.Type: GrantFiled: August 26, 1993Date of Patent: May 10, 1994Assignee: The Sherwin-Williams CompanyInventors: Revathi Tomko, Sanford L. Hertz, Buckel, Jr. Charles T., Mitchell R. Draving
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Patent number: 5304425Abstract: A chemical composition is provided for protecting, preserving, restoring and enhancing the appearance of rubber and polymer surfaces of de-icing boots on aircraft, particularly pneumatic de-icers. The chemical composition comprises the main elements of styrene acrylic emulsion polymer, polyethylene emulsion and polyolefin polymer emulsion, all mixed in distilled water. The preferred composition also includes 1,4 butanediol, polymethylsiloxane emulsion, potassium fluoroalkyl carboxylate, 12 benzisohiazolin 1-3, and ethylene glycol. A method of applying the composition to de-icer surfaces.Type: GrantFiled: March 19, 1992Date of Patent: April 19, 1994Inventor: Timothy A. Padgett
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Patent number: 5200459Abstract: A butadiene heteropolymer latex is prepared by emulsion polymerizing appropriate monomers in the presence of polyvinyl alcohol and a stabilizing solvent. The butadiene heteropolymer can be a butadiene copolymer or terpolymer prepared from butadiene monomers and comonomers such as .alpha.-haloacrylonitrile and acrylic acid. The butadiene heteropolymer latices can be prepared without problems of coagulation and can be utilized effectively in adhesive compositions without the use of volatile solvents. Adhesive bonds prepared from the butadiene heteropolymer latices also avoid the side effect problems associated with polymers prepared utilizing conventional surfactant-based emulsion polymerization techniques.Type: GrantFiled: May 31, 1991Date of Patent: April 6, 1993Assignee: Lord CorporationInventors: Mark A. Weih, Helmut W. Kucera
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Patent number: 5116945Abstract: A resinous substance obtained by reacting a rosin compound containing 1 to 10 equivalents of carboxylic groups per kilogram with triglycidyl isocyanurate. A process for producing it is also disclosed.Type: GrantFiled: February 12, 1990Date of Patent: May 26, 1992Assignee: Nissan Chemical Industries, Ltd.Inventors: Ken'ichi Osawa, Hisao Ikeda, Fumio Mizuochi, Hiroyuki Uehara
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Patent number: 5110863Abstract: Solutions and preparation methods necessary for the fabrication of metal oxide cross-linked polysiloxane coating films are disclosed. The films are useful in provide heat resistance against oxidation, wear resistance, thermal insulation, and corrosion resistance of substrates. The sol-gel precursor solution comprises a mixture of a monomeric organoalkoxysilane, a metal alkoxide M(OR).sub.n (wherein M is Ti, Zr, Ge or Al; R is CH.sub.3, C.sub.2 H.sub.5 or C.sub.3 H.sub.7 ; and n is 3 or 4), methanol, water, HCl and NaOH. The invention provides a sol-gel solution, and a method of use thereof, which can be applied and processed at low temperatures (i.e., <1000.degree. C.). The substrate can be coated by immersing it in the above mentioned solution at ambient temperature. The substrate is then withdrawn from the solution. Next, the coated substrate is heated for a time sufficient and at a temperature sufficient to yield a solid coating.Type: GrantFiled: October 1, 1990Date of Patent: May 5, 1992Assignee: Associated Universities, Inc.Inventor: Toshifumi Sugama
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Patent number: 5093440Abstract: A method for producing a vinyl chloride resin, which comprises suspension-polymerizing vinyl chloride, or a mixture of vinyl chloride with a co-monomer copolymerizable therewith, in an aqueous medium in the presence of an oil-soluble polymerization catalyst, a dispersant and an emulsifier by means of a homogenizer under an emulsifying pressure within a range of from 5 to 50 kg/cm.sup.2 in such a state that the organic phase is dispersed in the aqueous phase.Type: GrantFiled: March 1, 1990Date of Patent: March 3, 1992Assignee: Mitsubishi Kasei Vinyl CompanyInventor: Katsunori Takeuchi
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Patent number: 5073593Abstract: According to this invention, a microemulsion of an organopolysiloxane containing cyclohexylamino groups is prepared as follows: component (A), an organopolysiloxane containing cyclohexylamino groups and component (B), a nonionic surfactant and component (C), ethylene glycol or propylene glycol are blended. Formic acid or acetic acid, component (D) and water, component (E), are then added. The mixture is then stirred to form an emulsion precursor liquid, which is then dispersed in a prescribed amount of water. The microemulsion of the organopolysiloxane containing cyclohexylamino groups prepared using the method of this invention has an excellent shelf stability.Type: GrantFiled: June 13, 1990Date of Patent: December 17, 1991Assignee: Dow Corning Toray Silicone Company, LTD.Inventors: Masaru Ozaki, Isao Ona
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Patent number: 5013788Abstract: The invention provides a liquid coating composition for forming a transparent and hard coating film on a plastic member such as a polycarbonate or polymethyl methacrylate plate. The liquid composition comprises 100 parts by weight of an organotrialkoxysilane R.sup.1 Si(OR.sup.2).sub.3, where R.sup.1 is a C.sub.1 - or C.sub.2 -alkyl group and R.sup.2 is a C.sub.1 -, C.sub.2 - or C.sub.3 -alkyl group, 5-20 parts by weight of an organotrialkoxysilane R.sup.3 Si(OR.sup.2).sub.3, where R.sup.3 is an organic group containing epoxy group, 50-200 parts by weight of an aqueous colloidal silica sol in which the content of SiO.sub.2 is 10-40 wt %, and 0.5-3 parts by weight of a dicarboxylic acid (CF.sub.2).sub.n (COOH).sub.2, where n is an integer from 1 to 5, preferably hexafluoroglutaric acid. On a surface of a plastic member a coating film of this composition is partially cured at 70.degree.-150.degree. C. to turn into a fairly hard but still pliable film.Type: GrantFiled: December 14, 1989Date of Patent: May 7, 1991Assignee: Central Glass Company, LimitedInventors: Toshikazu Nagashima, Haruki Kuramashi, Yoshihiro Nishida, Masahiro Hirukawa
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Patent number: 5008328Abstract: This invention provides an aqueous organosilicon resin coating composition comprising:(I) an aqueous organosilicon resin which is a condensation product and which contains a quaternary ammonium base, the condensation product being prepared from (i) an organosilicon compound represented by the formulaR.sup.1.sub.a Si(OR.sup.2).sub.4-a (A)wherein R.sup.1 is hydrocarbon group having 1 to 12 carbon atoms, R.sup.2 is hydrocarbon group having 1 to 8 carbon atoms and a is 0, 1 or 2, and/or a low condensate thereof and (ii) an organosilicon compound represented by the formula ##STR1## wherein R.sup.3 is hydrogen atom or methyl group, R.sup.4 is bivalent hydrocarbon group having 1 to 8 carbon atoms and R.sup.2 is as defined above, and/or a low condensate thereof and,(II) an aqueous medium.Type: GrantFiled: February 21, 1989Date of Patent: April 16, 1991Assignee: Kansai Paint Co., Ltd.Inventors: Noboru Nakai, Osamu Isozaki
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Patent number: 5008329Abstract: A process for producing an aqueous copolymer dispersion is disclosed, which comprises emulsion polymerizing 100 parts by weight of a vinyl monomer mixture comprising (A) from 60 to 99.8% by weight of an acrylic ester of an aliphatic saturated alcohol having from 4 to 8 carbon atoms, (B) from 0.2 to 10% by weight of a monomer selected from the group consisting of an .alpha.,.beta.-unsaturated carboxylic acid, an .alpha.,.beta.-unsaturated carboxylic acid anhydride, a 2-hydroxyalkyl acrylate, a 2-hydroxyalkyl methacrylate, acrylamide, methacrylamide, methylolacrylamide, and methylolmethacrylamide, and (C) up to 30% by weight of a vinyl monomer other than the monomers (A) and (B) in the presence of from 0.01 to 10 parts by weight of a compound having an allyl hydrogen atom, with a total amount of the monomers (A), (B) and (C) being 100% by weight.Type: GrantFiled: October 10, 1989Date of Patent: April 16, 1991Assignee: Mitsubishi Yuka Badische Co., Ltd.Inventors: Tadashi Abe, Masahiro Aoki, Tsunenori Takahashi, Takeshi Awata
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Patent number: 4992508Abstract: Cross-linked aqueous dispersions and emulsions and method for producing casts of any desirable shape therefrom the dispersions comprising a water dissipatable polymer in an amount from 18 to 30 percent by weight based on the total weight of the composition; water in an amount from 67 to 30 percent by weight based on the total weight of the composition; a source of multivalent metallic ions in an amount of 0.1 to 5 percent by weight based on the total weight of the composition; and humectant in an amount from 0.1 to 40 percent by weight based on the total weight of the composition and the emulsions comprising a water dissipatable polymer in an amount from 18 to 30 percent by weight based on the total weight of the composition; water in an amount from 67 to 80 percent by weight based on the total weight of the comosition; emollient oils in an amount from 0.1 to 25 percent by weight based on the total weight of the composition; a source of multivalent metallic ions in an amount from 0.Type: GrantFiled: June 16, 1989Date of Patent: February 12, 1991Assignee: Imaginative Research Associates, Inc.Inventors: Mohan Vishnupad, Jose Ramirez
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Patent number: 4960811Abstract: Fluorosilicone heat cured rubber compositions are prepared using a chain modifier mixture comprising vinyl terminated polysiloxanes and silanol terminated siloxanes which allow vinyl-on-chain-ends functionality to easily crosslink unhindered by perfluoroalkyl groups.Type: GrantFiled: June 16, 1989Date of Patent: October 2, 1990Assignee: General Electric CompanyInventor: Edwin R. Evans
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Patent number: 4921900Abstract: The acidic crumb of poly(paraphenylene terephthalamide) formed from the reaction of terephthaloyl chloride with para-phenylene diamine in an N-alkyl-pyrrolidone with an alkali or alkaline earth metal salt, is dissolved in a defined mixture of a base, a solvent and co-solvent for use in the direct preparation of fibrous products.Type: GrantFiled: December 14, 1988Date of Patent: May 1, 1990Assignee: E. I. Du Pont De Nemours and CompanyInventor: James E. Van Trump
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Patent number: 4921895Abstract: A preparation for finishing textile fibers or products comprising textile fibers is disclosed. The preparation is liquid and contains 0.5 to 80% by weight of a mixture of modified organopolysiloxane A and B in a ratio of A:B by weight of 10:1 to 1:1, with the proviso that organpolysiloxane A is a linear siloxane containing polyether groups and having at least 40 dialkylsiloxy units, to which are linked at least 2 polyether groups, each of which has a molecular weight of 600 to 4,000 and which comprises 40 to 100 mole percent of oxyethylene units, the remainder being oxypropylene units, the ratio of the number of dialkylsiloxy units to the number of polyether groups being greater than or equal to 8.Type: GrantFiled: January 17, 1989Date of Patent: May 1, 1990Assignee: Th. Goldschmidt AGInventors: Dietmar Schaefer, Friedhelm Nickel
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Patent number: 4900778Abstract: The invention relates to a coating liquid composition useful to form a hard and transparent coating film on plastics. The novel liquid composition comprises a partial polycondensation product of a trialkoxysilane R.sup.1 Si(OR.sup.2).sub.3, wherein R.sup.1 is a C.sub.1 or C.sub.2 alkyl group and R.sup.2 is a C.sub.1 -C.sub.3 alkyl group, a colloidal silica, water, an aliphatic lower alcohol and anhydride of a polybasic carboxylic acid having a cyclic structure. The content of the acid anhydride must be at least 0.005 wt % when pH of the coating liquid composition is adjusted to 6.0-7.0. The primary merit of using such an acid anhydride is improved storage stability of the coating liquid composition.Type: GrantFiled: March 24, 1987Date of Patent: February 13, 1990Assignee: Central Glass Company, LimitedInventor: Toshikazu Nagashima
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Patent number: 4855348Abstract: A storage stable water-based paint comprising a solid silicone resin and an ammonium salt of a drying oil modified acrylic copolymer provide a coating for barbecue grills and other appliances that are subjected to temperatures as high as 1300.degree. F. A smooth and continuous coating remains on the metal after burning off of the acrylic resin and firing of the metal at 1300.degree. F. The paint is redispersible and may be drawn down to 1.5 mils after storage at 120.degree. F. for more than 3 months when the pH is at least about 8.Type: GrantFiled: July 14, 1988Date of Patent: August 8, 1989Assignee: DAP Inc.Inventor: Hartzel G. Strader
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Patent number: 4786681Abstract: The invention provides a process for producing a water-in-oil emulsion of a water-soluble polyacrylamide or polyacrylic acid polymer or copolymer by the inverse emulsion process characterized in that there is used as the emulsifying agent for the water-in-oil emulsion a water-insoluble, oil-soluble surface active agent of the formula (I):X--Y--Z Ior a functional derivative thereof, wherein X- represents a saturated or unsaturated hydrocarbon chain containing from 30 to 500 carbon atoms, --Y-- represents a succinic anhydride residue carried terminally upon the group X--, and --Z represents a hydrophilic group carried by the group --Y--.Type: GrantFiled: August 12, 1986Date of Patent: November 22, 1988Assignee: Imperial Chemical Industries PLCInventors: Alan S. Baker, Stephen J. Butterworth, Ravinder K. Jheeta
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Patent number: 4771086Abstract: Finely divided water insoluble solid particles free of ionic charges and ranging in size from about 0.01 to several hundred microns or higher, including but not limited to paint pigment particles, are given a generally uniform polymeric encapsulation by admixing such particles in an aqueous reaction medium with a water insoluble monomer polymerizable to form a generally water insoluble polymer free of ionic charges in the presence of a nonionic surface active stabilizing agent, preferably a polyethoxylated alkyl phenol containing at least about eight carbon atoms in the alkyl group thereof and preferably at least about 40-50 ethylene oxide groups per molecule, and polymerization of the monomer is then initiated, usually with heating, with a redox polymerization initiating system which is free of ionic groups and does not decompose to release ionic groups in the reaction medium.Type: GrantFiled: August 22, 1986Date of Patent: September 13, 1988Assignee: Union Carbide CorporationInventor: Robert W. Martin
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Patent number: 4749506Abstract: A microgel dispersion characterized by that an oil-soluble surface active agent is adsorbed or adhered onto a gel consisting of a fine particle substance and a polymer, and said gel is dispersed in a non-aqueous organic solvent.Type: GrantFiled: September 19, 1985Date of Patent: June 7, 1988Assignee: Ricoh Co., Ltd.Inventors: Ayao Kitahara, Kijiro Konno
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Patent number: 4737543Abstract: Process for the preparation of polymer dispersions with particle diameters of 50 to 1000 nm, wherein there are employed, as emulsifiers for the emulsion polymerization citric acid derivatives of the general formula (I) ##STR1## in which, independently of one another, R.sub.1, R.sub.2 and R.sub.3 denote C.sub.6 -C.sub.20 -alkyl, (including cycloalkyl) hydrogen, sodium, potassium, lithium or ammonium andR.sub.4 denotes hydrogen or acetyl,with the proviso that at least one of the radicals R.sub.1 to R.sub.3 denotes alkyl, and as initiators water-soluble agents which form free radicals or redox systems with at least one water-soluble component.Type: GrantFiled: February 11, 1987Date of Patent: April 12, 1988Assignee: Bayer AktiengesellschaftInventors: Udo W. Hendricks, Adolf Schmidt
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Patent number: 4692493Abstract: Stable aqueous, colloidal dispersions, having a high shear stability, of copolymers of tetrafluoroethylene and ethylene, which may also contain at least one further comonomer, are described. Such dispersions are prepared in the presence of a mixture of perfluorooctanoic acid and perfluorononanoic or perfluorodecanoic acids or salts thereof.Type: GrantFiled: April 3, 1986Date of Patent: September 8, 1987Assignee: Hoechst AktiengesellschaftInventors: Reinhard A. Sulzbach, Konrad von Werner
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Patent number: RE32459Abstract: An acrylamide polymer comprising acrylamide and a sufficient amount of cinnamic acid to substantially reduce the viscosity of the acrylamide polymer and solution.Type: GrantFiled: August 5, 1985Date of Patent: July 14, 1987Assignee: Akzo N.V.Inventor: Donald N. Van Eenam
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Patent number: RE34145Abstract: Finely divided water insoluble solid particles free of ionic charges and ranging in size from about 0.01 to several hundred microns or higher, including but not limited to paint pigment particles, are given a generally uniform polymeric encapsulation by admixing such particles in an aqueous reaction medium with a water insoluble monomer polymerizable to form a generally water insoluble polymer free of ionic charges in the presence of a nonionic surface active stabilizing agent, preferably a polyethoxylated alkyl phenol containing at least about eight carbon atoms in the alkyl group thereof and preferably at least about 40-50 ethylene oxide groups per molecule, and polymerization of the monomer is then initiated, usually with heating, with a redox polymerization initiating system which is free of ionic groups and does not decompose to release ionic groups in the reaction medium.Type: GrantFiled: September 12, 1990Date of Patent: December 15, 1992Assignee: Union Carbide Chemicals & Plastics Technology CorporationInventor: Robert W. Martin
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Patent number: RE34682Abstract: Cross-linked aqueous dispersions and emulsions and method for producing casts of any desirable shape therefrom the dispersions comprising a water dissipatable polymer in an amount from 18 to 30 percent by weight based on the total weight of the composition: water in an amount from .[.67 to 130.]. .Iadd.30-80 .Iaddend.percent by weight based on the total weight of the composition; a source of multivalent metallic ions in an amount of 0.1 to 5 percent by weight based on the total weight of the composition; and humectant in an amount from 0.1 to 40 percent by weight based on the total weight of the composition and the emulsions comprising a water dissipatable polymer in an amount from 18 to 30 percent by weight based on the total weight of the composition; water in an amount from .[.67.]. .Iadd.30 .Iaddend.to 80 percent by weight based on the total weight of the comosition; emollient oils in an amount from 0.Type: GrantFiled: February 11, 1993Date of Patent: August 2, 1994Assignee: Imaginative Research Associates, Inc.Inventors: Mohan Vishnupad, Jose Ramirez
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Patent number: RE34716Abstract: Cross-linked aqueous dispersions and emulsions and method for producing casts of any desirable shape therefrom the dispersions comprising a water dissipatable polymer in an amount from 18 to 30 percent by weight based on the total weight of the composition; water in an amount from .[.67 to 30.]. .Iadd.30 to 80 .Iaddend.percent by weight based on the total weight of the composition; a source of multivalent metallic ions in an amount of 0.1 to 5 percent by weight based on the total weight of the composition; and humectant in an amount from 0.1 to 40 percent by weight based on the total weight of the composition and the emulsions comprising a water dissipatable polymer in an amount from 18 to 30 percent by weight based on the total weight of the composition; water in an amount from .[.67.]. .Iadd.30 .Iaddend.to 80 percent by weight based on the total weight of the composition; emollient oils in an amount from 0.Type: GrantFiled: February 11, 1993Date of Patent: September 6, 1994Assignee: Imaginative Research Associates, Inc.Inventors: Mohan Vishnupad, Jose Ramirez