Carboxylic Acid Or Derivative Not Containing A Heavy Metal Atom As Dnrm, E.g., Anhydride, Acyl Halide, Ester Or Salt, Etc. Patents (Class 524/773)
  • Patent number: 5147927
    Abstract: A primerless, one-component, moisture-curable polyurethane-based adhesive composition useful for affixing glass panels directly to electrocoat painted metal substrates comprises a polyurethane base polymer containing an electrocoat adhesion promoter. The sealant composition has fast cure times at ambient temperatures and forms a strong bond directly to electrocoat painted metal substrates without the need for a sealant primer.
    Type: Grant
    Filed: March 29, 1991
    Date of Patent: September 15, 1992
    Assignee: BASF Corporation
    Inventors: Jamil Baghdachi, Keith H. Mahoney, Glenn E. Martin
  • Patent number: 5137966
    Abstract: The present invention is directed to a novel internal mold release agent for use in a polyurethane(urea) RIM process. The release agent broadly consists of the transesterification product of a fatty acid and a lower alkyl acetoacetate.
    Type: Grant
    Filed: February 25, 1991
    Date of Patent: August 11, 1992
    Assignee: Miles Inc.
    Inventor: Neil H. Nodelman
  • Patent number: 5112921
    Abstract: An impact-resistant thermoplastic molding material which contains, based in each case on A+B, from 80 to 50% by weight of a hard matrix A of polystyrene having a molecular weight M.eta. of from 150,000 to 200,000 and from 50 to 20% by weight of a soft phase B which is uniformly distributed in the hard matrix and has a median particle diameter d.sub.50 (volume average) of from 1 to 10 .mu.m, and can be obtained by polymerizing styrene in the presence of an elastomeric grafting base, advantageously has a molecular weight of the grafted branches of from 1.1 to 1.35 times the molecular weight of the hard matrix, and the degree of grafting is from 50 to 100%.
    Type: Grant
    Filed: December 7, 1989
    Date of Patent: May 12, 1992
    Assignee: BASF Aktiengesellschaft
    Inventors: Hans-Dieter Schwaben, Rainer Schlichtmann, Hubert Kindler, Peter Klaerner, Hans Mittnacht
  • Patent number: 5104928
    Abstract: Thermosetting coating compositions are based on a binder comprising carboxyl functional polyurethane, acrylic copolymer, and if desired a carbodiimide crosslinker. The binder is produced by synthesizing an isocyanate terminated, carboxyl functional urethane prepolymer in the absence of water and organic solvent but in the presence of ethylenic monomers. The organic phase urethane prepolymer dispersed in ethylenic monomers is inverted into water whereupon the urethane prepolymer is extended by reaction with a primary or secondary polyamine such as diamine to produce a high molecular weight polyurethane-urea. Thereafter, the ethylenic monomers are copolymerized to form an aqueous dispersed polyurethane-urea and acrylic copolymer mixture. The resulting polymeric binder is useful in protective surface coatings applied to plastic substrates. A carbodiimide can be added to provide thermosetting crosslinking with the carboxyl functional polyurethane.
    Type: Grant
    Filed: January 12, 1990
    Date of Patent: April 14, 1992
    Assignee: The Glidden Company
    Inventors: Gary P. Craun, David L. Trumbo, Frank A. Wickert
  • Patent number: 5104923
    Abstract: A non-polymerizable polycarboxylate imparts greater wet strength to nonwovens bound by an emulsion polymer containing a polymerizable cross-linker.
    Type: Grant
    Filed: March 31, 1989
    Date of Patent: April 14, 1992
    Assignee: Union Oil Company of California
    Inventors: Paul J. Steinwand, Dennis P. Stack
  • Patent number: 5097006
    Abstract: Carboxyl-terminated and hydroxyl-terminated aliphatic polyester compositions derived from 1,4-cyclohexane-dicarboxylic acid, and a glycol component comprising primarily of cycloaliphatic diols and modifying aliphatic glycols, said polyesters being optionally stabilized by the presence of ultraviolet light absorbing compounds and/or hindered amine light stabilizers and being used in powder coating formulations to provide improved weatherability thereto.
    Type: Grant
    Filed: November 21, 1990
    Date of Patent: March 17, 1992
    Assignee: U C B S.A.
    Inventors: Lorraine Kapilow, Joseph S. Puglisi, Chi-Wen F. Cheng
  • Patent number: 5091468
    Abstract: An antistatic coating composition comprising: (a) a first organosilane compound having at least one epoxy group and at least one hydrolyzable alkoxy group; (b) a second organosilane compound having no epoxy group and two or more hydrolyzable alkoxy groups; (c) 2 to 20 wt %, based on the total weight of said first and second organosilane compounds, of aluminum dihydrogenphosphate; and (d) 50 to 500 parts by weight, based on the total weight of said first and second organosilane compounds, of an organic solvent for said first and second organosilane compounds.The coating composition has a long pot life to be stably stored for a long period of time, and may be coated on any of usual materials including metallic, inorganic and organic materials to form a cured coating film which is excellent in resistance to heat, durability, water-proof property and resistance to chemicals by heating at a relatively low temperature for a short time.Also provided is an improved process for preparing such a coating composition.
    Type: Grant
    Filed: January 29, 1990
    Date of Patent: February 25, 1992
    Assignee: T.S.B. Ltd.
    Inventor: Eizi Takeuchi
  • Patent number: 5081181
    Abstract: A primer composition comprising:(A) an organosilicon compound formed by binding an organosilicon compound represented by the general formula (I): ##EQU1## wherein R.sup.1 represents a monovalent hydrocarbon group; X represents a hydrogen atom, a lower alkyl group, etc.; and 0.ltoreq.a<0.2, 0.ltoreq.b<0.2 and 1<c<4,with an organopolysiloxane represented by the general formula (II): ##EQU2## wherein R.sup.2 represents a monovalent hydrocarbon group containing no aliphatic unsaturated group; R.sup.3 represents an alkenyl group; Y represents a hydrogen atom, a lower alkyl group, etc.; and 1.8<d<2.2, 0.004<e<0.2 and 0.ltoreq.f<0.2,in a particular proportion;(B) an organic titanate; and(C) an organic solvent.This primer composition achieves adhesion with good durability at high temperatures, particularly in high temperature oils.
    Type: Grant
    Filed: January 25, 1990
    Date of Patent: January 14, 1992
    Assignee: Shin-Etsu Chemical Co., Ltd.
    Inventors: Masaharu Takahashi, Jun Hatakeyama
  • Patent number: 5079312
    Abstract: The invention provides a process for preparing a polysiloxane-containing resin which comprises copolymerizing a polysiloxane-type macromonomer with a vinyl monomer, characterized in that the polysiloxane-type macromonomer is one prepared by reacting about 70 to about 99.999 mole % of a compound (A) represented by the formula ##STR1## wherein R.sub.1 represents aliphatic hydrocarbon group having 1 to 8 carbon atoms or phenyl group, and R.sub.2, R.sub.3 and R.sub.4 each represent alkoxyl group having 1 to 4 carbon atoms or hydroxyl group with about 30 to about 0.001 mole % of a compound (B) represented by the formula ##STR2## wherein R.sub.5 represents hydrogen atom or methyl group, R.sub.6, R.sub.7 and R.sub.8 each represent hydroxyl group, alkoxyl group having 1 to 4 carbon atoms or aliphatic hydrocarbon group having 1 to 8 carbon atoms with the proviso that R.sub.6, R.sub.7 and R.sub.
    Type: Grant
    Filed: May 11, 1990
    Date of Patent: January 7, 1992
    Assignee: Kansai Paint Company, Limited
    Inventors: Osamu Isozaki, Noboru Nakai, Koichiro Murata
  • Patent number: 5064928
    Abstract: The present invention provides an isocyanate prepolymer prepared by reacting an organic di-isocyanate with an unsaturated alcohol dimer having 16 to 24 carbon atoms and/or a hydrogen addition product of the unsaturated alcohol dimer and a process for preparing the same.
    Type: Grant
    Filed: March 27, 1990
    Date of Patent: November 12, 1991
    Assignee: Dainippon Ink and Chemicals, Inc.
    Inventors: Mitsuo Kase, Kazue Tsuyuzaki, Yoichi Kawasaki, Shunji Arimoto
  • Patent number: 5063270
    Abstract: A curable composition. The composition contains(A) 100 parts of an oxyalkylene polymer having at least one silicon-containing group containing a hydroxyl group and/or hydrolyzable group bound to a silicon atom and capable of crosslinking through the formation of a siloxane bond;(B) 1 to 150 parts of a high molecular weight and/or high viscosity plasticizer; and(c) 0.1 to 20 parts of a compound having one silanol group per molecular and/or a compound capable of reacting with moisture to thereby form one silanol group per molecule. When an alkyd paint is applied onto the surface of a cured material formed from this curable composition excellent coating properties can be obtained, the other physical characteristics of the cured material being maintained.
    Type: Grant
    Filed: June 7, 1989
    Date of Patent: November 5, 1991
    Assignee: Kanegafuchi Kagaku Kogyo Kabushiki Kaisha
    Inventors: Sadao Yukimoto, Toshifumi Hirose, Hiroshi Wakabayashi, Katsuhiko Isayama
  • Patent number: 5047466
    Abstract: Amino resin solutions having an electrical conductivity of <100 .mu.S/cm for impregnating paper are obtainable byA) methylolation of melamine with aqueous formaldehyde in a molar ratio of from 1:2 to 1:5 in the presence of a tertiary organic amine at a pH of from 7 to 12,B) etherification with a molar excess, based on the methylol groups, of a C.sub.1 -C.sub.4 -alcohol in the presence of an unsubstituted or substituted dicarboxylic acid and/or polycarboxylic acid at a pH of from 3 to 6,C) neutralization of the reaction mixture with an inorganic base and removal of the volatile components by distillation, except for a water content of <10% by weight, based on the reaction mixture, andD) addition of a C.sub.1 -C.sub.4 -alcohol to give a solids content of from 40 to 90% by weight, based on the amino resin solution, and removal of insoluble components by filtration.
    Type: Grant
    Filed: February 8, 1990
    Date of Patent: September 10, 1991
    Assignee: BASF Aktiengesellschaft
    Inventors: Gerd Busse, Jakob Decher, Wolfgang Eisele, Edgar Haeussler, Otto Wittmann
  • Patent number: 5045592
    Abstract: The present invention provides a relatively simple synthesis procedure for the formation of silane hydrolyzate compositions of the formula ##EQU1## where R is hydrogen or a methyl group, n is an integer greater than about 8, and x is a number between 0 and 2. The hydrolyzate compositions are metastable in solvent solution, but become insoluble after coating on a substrate. The resins are useful as planarizing coatings for substrates such as electronic devices and can be ceramified by subjecting them to an oxidizing atmosphere at a temperature of between about 100.degree. to 1000.degree. C. to form ceramic or ceramic-like coatings on such substrates.
    Type: Grant
    Filed: October 1, 1990
    Date of Patent: September 3, 1991
    Assignee: Dow Corning Corporation
    Inventors: Keith D. Weiss, Cecil L. Frye
  • Patent number: 5030699
    Abstract: Disclosed is a ladder silicone oligomer composition which comprises [A] 100 weight parts of a ladder silicone oligomer containing 1 to 10 weight % of hydroxyl groups and 1 to 10 weight % of ethoxy groups, [B] 1 to 200 weight parts of at least one silicon-containing compound selected from (a) silicone oligomers and polymers having a number average molecular weight of 500 to 100,000, which are obtained by reacting a compound of the following formula (I): ##STR1## wherein R.sub.1 is lower alkyl or phenyl, and R.sub.2 is lower alkyl, with a compound of the following formula (II): ##STR2## wherein R.sub.3 is lower alkyl, or phenyl, and R.sub.4 is lower alkyl, the molar ratio of the compound (I) to the compound (II) being from 1/0.3 to 1/9, and (b) ethyl silicates having a silica content of 28.8 to 45 weight % and hydrolysis products thereof, and [C] an organic solvent. The ladder silicone oligomer composition is useful as a coating material and an adhesive.
    Type: Grant
    Filed: June 6, 1989
    Date of Patent: July 9, 1991
    Assignee: Showa Denko K.K.
    Inventors: Takahiko Motoyama, Yoshio Miyata, Fumio Matsui, Yoichi Namba, Noritoshi Kamoi, Yukari Ohwaki
  • Patent number: 5011647
    Abstract: Active hydrogen-containing compositions having internal mold release components are used in a process in preparing molded polymeric products. In the process, the active hydrogen-containing composition contains (a) a primary or secondary amine, (b) a carboxylic acid or amido carboxylic acid salt of a group II metal or of aluminum, lithium, copper, iron, cobalt or nickel, and optionally (c) a carboxylic acid or amido carboxylic acid.
    Type: Grant
    Filed: June 21, 1989
    Date of Patent: April 30, 1991
    Assignee: The Dow Chemical Company
    Inventors: Louis W. Meyer, Robert Carswell, J. Alan Vanderhider
  • Patent number: 5010114
    Abstract: Method for polymerizing a monomer suspended in water which comprises:Preparing a polymerization mixture of a water immiscible, liquid, ethylenically unsaturated monomer, a polyisocyanate and an oil soluble free radical initiator, dispersing said mixture in a solution of water and a surfactant, and effecting polymerization of said monomer.
    Type: Grant
    Filed: January 16, 1990
    Date of Patent: April 23, 1991
    Assignee: The Mead Corporation
    Inventors: Rong-Chang Liang, Emerson K. Colyer, Jing-Den Chen, Karl A. Kintz, Chih-Her Suen
  • Patent number: 5008033
    Abstract: Active hydrogen-containing compositions having internal mold release components for use in preparing molded polymeric products are disclosed which contain (a) a primary or secondary amine, (b) a carboxylic acid or amido carboxylic acid salt of a group II metal or of aluminum, lithium, copper, iron, cobalt or nickel, and optionally (c) a carboxylic acid or amido carboxylic acid.
    Type: Grant
    Filed: June 12, 1989
    Date of Patent: April 16, 1991
    Assignee: The Dow Chemical Company
    Inventors: Louis W. Meyer, J. Alan Vanderhider, Robert Carswell
  • Patent number: 5008300
    Abstract: A visible light ray-curable monomeric composition for fastening loose teeth, comprising: a filler component consisting of fine, solid particles having an average size of 0.01 to 100 .mu.m and in an amount of 40% to 85% based on the weight of the total weight of the composition; a polyfunctional monomer component consisting of a radical-polymerizable, polyfunctional monomer; a monofunctional monomer consisting of a radical-polymerizable, monofunctional monomer; and a photopolymerization initiator; having a viscosity of 1,000 to 500,000 cps at a temperature of 25.degree. C., and contained in a light-shielded container.
    Type: Grant
    Filed: September 11, 1989
    Date of Patent: April 16, 1991
    Assignee: Mitsubishi Rayon Company Ltd.
    Inventors: Takayuki Makino, Nobuhiro Mukai, Hitoshi Ige
  • Patent number: 4999397
    Abstract: The present invention provides a relatively simple synthesis procedure for the formation of silane hydrolyzate compositions of the formula ##EQU1## where R is hydrogen or a methyl group, n is an integer greater than about 8, and x is a number between 0 and 2. The hydrolyzate compositions are metastable in solvent solution but become insoluble after coating on a substrate. The resins are useful as planarizing coatings for substrates such as electronic devices and can be ceramified by subjecting them to an oxidizing atmosphere at a temperature of between about 100.degree. to 1000.degree. C. to form ceramic or ceramic-like coatings on such substrates.
    Type: Grant
    Filed: July 28, 1989
    Date of Patent: March 12, 1991
    Assignee: Dow Corning Corporation
    Inventors: Keith D. Weiss, Cecil L. Frye
  • Patent number: 4996112
    Abstract: Organopolysiloxane compositions that are storage-stable under anhydrous conditions, but curable into elastomeric state in the presence of moisture and, thus, are well suited as sealants and coatings and which particularly strongly adhere to substrates used in the construction industry, contain at least one .alpha., .omega.-dihydroxydiorganopolysiloxane polymer; at least one ketiminoxysilane crosslinking agent therefor; a bonding agent including admixture, or reaction product of, (i) an aminoorganosilicon compound containing a primary amine group, with (ii) an organosilicon compound containing an epoxy functional group; and, advantageously, a filler material and a curing catalyst.
    Type: Grant
    Filed: April 7, 1989
    Date of Patent: February 26, 1991
    Assignee: Rhone-Poulenc Chimie
    Inventors: Patrice Perrin, Andre Pierron
  • Patent number: 4980396
    Abstract: A primar composition comprising(A) 100 parts by weight of an organo-polysiloxane represented by the formula (1) ##EQU1## wherein R.sup.1 represents a substituted or unsubstituted monovalent hydrocarbon group, and a is a number of from 1.98 to 2.01, provided that 25 to 50 mol % of the hydrocarbon group is a perfluoroalkyl group and 0.01 to 10 mol % of the hydrocarbon group is a vinyl group, said organo-polysiloxane having a viscosity as measured at 25.degree. C. of 1,000,000 centistokes or more;(B) 5 to 100 parts by weight of a silica type filler;(C) 0.5 to 50 parts by weight of isocyanurate-type organosilicon compound represented by the formula (2) ##STR1## wherein R.sup.2 represents an alkyl group, a fluoroalkyl group or an alkoxyalkyl group, each having 1 to 5 carbon atoms in the alkyl moiety, and n is an integer of 1 to 5; and(D) a desired amount of an organic solvent.
    Type: Grant
    Filed: June 1, 1989
    Date of Patent: December 25, 1990
    Assignee: Toshiba Silicone Co., Ltd.
    Inventor: Hirofumi Yoshida
  • Patent number: 4980413
    Abstract: Organopolysiloxane compositions curable by a hydrosilylation reaction contain a novel adhesion promoter consisting essentially of (1) a carboxylic acid ester containing an acryloyloxy or methacryloyloxy group and an alcoholic functional group and (2) an organosilicon compound containing a silicon-bonded vinyloxy or substituted vinyloxy group. The compositions exhibit excellent adhesion to both organic and inorganic substrates that are in contact with the compositions during curing. The adhesion on plastics is especially good.
    Type: Grant
    Filed: January 29, 1990
    Date of Patent: December 25, 1990
    Assignee: Dow Corning Toray Silicone Company, Ltd.
    Inventor: Akira Kasuya
  • Patent number: 4978704
    Abstract: Organopolysiloxane compositions that are storage-stable under anhydrous conditions, but curable into elastomeric state in the presence of moisture and, thus, are well suited as sealants and coatings and which particularly strongly adhere to substrate used in the construction industry, contain at least one .alpha., .omega.-dihydroxydiorganopolysiloxane polymer; at least one acyloxysilane crosslinking agent therefor; a bonding agent including admixture, or reaction product of, (i) an aminoorganosilicon compound containing a primary amine group, with (ii) an organosilicon compound containing an epoxy functional group; and, advantageously, a filler material and a curing catalyst.
    Type: Grant
    Filed: April 7, 1989
    Date of Patent: December 18, 1990
    Assignee: Rhone-Poulenc Chimie
    Inventor: Patrice Perrin
  • Patent number: 4968776
    Abstract: The sizing agent according to the present invention contains as the essential component a high molecular compound having an weight-average molecular weight of not less than 20,000 prepared by reacting(A) a polyhydroxy compound having an weight-average molecular weight of not less than 1,000, which is prepared by an addition polymerization of ethylene oxide or alkylene oxides comprising ethylene oxide to an organic compound having two active hydrogens, with(B) a polycarboxylic acid, a polycarboxylic acid anhydride or a lower ester of a polycarboxylic acid.
    Type: Grant
    Filed: October 24, 1989
    Date of Patent: November 6, 1990
    Assignee: Dai-Ichi Kogyo Seiyaku Co., Ltd.
    Inventors: Takeshi Fujita, Tadayuki Sugimoto, Kazuyo Aketa
  • Patent number: 4957997
    Abstract: A facile process for converting polyketones containing pendant functional groups to polyesters is provided. The process involves reacting the polyketone with an organic peroxyacid oxidizing agent in an inert liquid medium at a temperature from -20.degree. C. to 150.degree. C. to convert substantially all or only a portion of the keto functionality to ester moieties. The polyketones are obtained by copolymerizing carbon monoxide and a vinyl or vinylidene monomer having at least one functional group containing one or more oxygen, nitrogen, sulfur or halogen atoms.
    Type: Grant
    Filed: February 16, 1990
    Date of Patent: September 18, 1990
    Assignee: Quantum Chemical Corporation
    Inventors: Biau-Hung Chang, Jack Kwiatek
  • Patent number: 4954539
    Abstract: Aqueous silicone emulsions, especially useful for rendering a wide variety of substrates nonadhesive/water-repellent by polycondensation crosslinking, contain (a) an .alpha.,.omega.-dihydroxydiorganopolysiloxane, (b) an organohydropolysiloxane containing at least 3 hydrogen atoms bonded to silicon atoms per molecule, (c) a polyvinyl alcohol, (d) a nonionic emulsifying agent, and (e) a crosslinking catalytically effective amount of a monochelate of pentacoordinated tin of valency IV.
    Type: Grant
    Filed: June 23, 1989
    Date of Patent: September 4, 1990
    Assignee: Rhone-Poulenc Chimie
    Inventors: Jacques Cavezzan, Michel Peignier
  • Patent number: 4943613
    Abstract: The photocurable organopolysiloxane composition is curable by irradiation with ultraviolet light into a rubbery elastomer which is excellently adhesive to the surface of the substrate on which it has been cured. The composition comprises an organopolysiloxane having, in a molecule, at least one acryloxy-functional group represented by the general formula[CH.sub.2 .dbd.CR.sup.1 --CO--O--(CH.sub.2).sub.a --SiR.sub.2 --O--].sub.b (R).sub.3-b Si--R.sup.2 --,in which R.sup.1 is a hydrogen atom or a methyl group, each R is a monovalent hydrocarbon group, R.sup.2 is an oxygen atom or a divalent hydrocarbon group and each of the subscripts a and b is 1, 2 or 3, as the principal ingredient together with an acryloxy-containing trialkoxy silane represented by the general formula(R.sup.3 O).sub.3 Si--R.sup.4 --(NH--CO--O--R.sup.4).sub.c --O--CO--CR.sup.1 .dbd.CH.sub.2,in which each R.sup.3 is a monovalent hydrocarbon group, each R.sup.4 is a divalent hydrocarbon group having 1 to 20 carbon atoms, R.sup.
    Type: Grant
    Filed: May 26, 1989
    Date of Patent: July 24, 1990
    Assignee: Shin-Etsu Chemical Co., Ltd.
    Inventors: Masatoshi Arai, Kazutoshi Fujioka, Masaharu Satou
  • Patent number: 4933413
    Abstract: Organosilicon compounds containing at least one acylamino-substituted hydrocarbon radical are prepared by reacting an organohydroxysilicon compound containing at least one silicon-bonded hydroxy radical with a base to yield a silanolate. The silanolate is reacted with a cyclic aminosilane compound to form a siloxyalkylamide that is then reacted with an acyl chloride to give the desired product. All reactions can be carried out in a single reaction vessel using a nonaqueous solvent.
    Type: Grant
    Filed: April 10, 1989
    Date of Patent: June 12, 1990
    Assignee: Dow Corning Corporation
    Inventor: Sudarsanan Varaprath
  • Patent number: 4931483
    Abstract: Polymer/polyol compositions, obtained by polymerizing, in situ in a polyol, one or more ethylenically unsaturated monomers comprising an alpha-olefin containing at least 5 carbon atoms and/or an acrylate or methacrylate ester of an alcohol containing at least 9 carbon atoms, which are of relatively low viscosity and which afford polyurethanes having improved properties.
    Type: Grant
    Filed: December 5, 1988
    Date of Patent: June 5, 1990
    Assignee: Sanyo Chemical Industries, Ltd.
    Inventors: Masahiro Matsuoka, Keiichi Akimoto, Takeshi Sumita, Tsuyoshi Tomosada, Isao Ishikawa
  • Patent number: 4919878
    Abstract: A process for the production of optionally foamed moldings having a compact surface by the reaction in closed molds of a mixture of(a) organic polyisocyanates,(b) compounds containing isocyanate-reactive groups and having a molecular weight of 62 to about 10,000 and(c) mold release agents based on salts of (i) saturated or unsaturated aliphatic or cycloaliphatic carboxylic acids or carboxylic acid mixtures containing (on a statistical average) at least 8 carbon atoms per molecule and (ii) tertiary amines,characterized in that the release agents (c) used are salts in which the amine component (ii) is based on tertiary monoamines or mixtures of tertiary monoamines corresponding to the following formula ##STR1## in which R.sub.1 represents a saturated or unsaturated aliphatic hydrocarbon radical containing at least 12 carbon atoms and R.sub.2 and R.sub.
    Type: Grant
    Filed: August 3, 1987
    Date of Patent: April 24, 1990
    Assignee: Bayer Aktiengesellschaft
    Inventors: Friedhelm Pilger, Richard Kopp, Otto Ganster
  • Patent number: 4894412
    Abstract: A process for preparing a self-crosslinkable aminosiloxane emulsion, comprising:dispersing by emulsification in water in the presence of a cationic surface active agent and a nonionic surface active agent:(A) a specific organosilicon compound that may have a hydroxyl group and/or an alkoxy group;(B) a specific organosilicon compound having a nitrogen-containing monovalent hydrocarbon group; and(C) a specific organosilane having a hydroxyl group and/or an alkoxy group, and or a partial hydrolysis-condensation product thereof;subsequently carrying out emulsion polymerization in the presence of an alkaline catalyst; andthereafter neutralizing the reaction product.The resulting emulsion is useful as softening agents, smoothing agents or feeling improver for all sorts of textiles, and binders between fibers.
    Type: Grant
    Filed: May 18, 1988
    Date of Patent: January 16, 1990
    Assignee: Shin-Etsu Chemical Co., Ltd.
    Inventors: Fumio Okada, Masaki Tanaka, Hiroshi Ohashi
  • Patent number: 4880869
    Abstract: This invention relates to .beta.-amino-.beta.-propiolactam derivativatives, moisture curable polyurethane compositions and their applications.The products of this invention have excellent characteristics such as good storage stability, rapid curing with atmospheric moisture and freedom from foaming.More particularly, condensed compounds are obtained by reacting specific secondary diamines such as piperazine and 1,3-(4,4'-dipiperidyl)propane with monoaldehyde having at least 3 carbon atoms, for example, isobutylaldehyde and .beta.-phenylpropylaldehyde. The .beta.-amino-.beta.-propiolactam derivatives are prepared by reacting the condensed compounds with monoisocyanate such as phenyl isocyanate and equimolar reaction products of diisocyanate with lower monohydric alcohol.In addition, the moisture curable polyurethane compositions contain said derivatives and polyisocyanate and/or polyurethane prepolymer having terminal isocyanato radicals.
    Type: Grant
    Filed: September 14, 1988
    Date of Patent: November 14, 1989
    Assignee: Mitsui Toatsu Chemicals, Inc.
    Inventors: Masaaki Aoki, Mayumi Tani, Masayuki Kamiyama, Kiyotsugu Asai
  • Patent number: 4879339
    Abstract: A room temperature-curable organopolysiloxane composition is proposed which is useful as a material for imprinting or blocking of forms of, for example, medical and dental prostheses without the problem of curing retardation or incomplete curing. The composition comprises a vinyl-containing organopolysiloxane, organohydrogenpolysiloxane, platinum catalyst, inorganic filler, liquid paraffin or petrolatum and antioxidant. The antioxidant serves to protect the liquid paraffin or petrolatum from oxidation to produce oxidized compounds which may deactivate the platinum catalyst to cause curing retardation or incomplete curing.
    Type: Grant
    Filed: March 3, 1988
    Date of Patent: November 7, 1989
    Assignee: Shin-Etsu Chemical Co., Ltd.
    Inventors: Masachika Yoshino, Nobuyuki Hasebe, Hironao Fujiki, Hiroshi Inomata
  • Patent number: 4857582
    Abstract: Colloidal suspensions of organopolysiloxanes are prepared by mixing an organosilicon compound selected from the group consisting of mixtures of alkoxysilanes and/or partial hydrolysates thereof and an organo(poly)siloxane which is optionally free of alkoxy groups and contains a maximum of 8 siloxane units, which is mixed with at least one alkoxysilane and/or a partial hydrolysate thereof, with water in the presence of an emulsifier, at a maximum rate of 5 moles of organosilicon compound per hour per liter of water, in which the organosilicon compound and the water is fed continuously, but separately from one another, into a reactor, in which at least one of the two substances contains an emulsifier, while the alkanol is being continuously removed by distillation from the aqueous suspension continuously emerging from the reactor. The aqueous suspension from which the alkanol has been removed by distillation is, if desired, recycled back into the reactor.
    Type: Grant
    Filed: May 18, 1988
    Date of Patent: August 15, 1989
    Assignee: Wacker-Chemie GmbH
    Inventors: Matthias Wolfgruber, Bernward Deubzer, Volker Frey
  • Patent number: 4855352
    Abstract: Stable finely-divided dispersions of polyureas and/or polyhydrazodicarbonamides in a hydroxyl-group-containing material are made by reacting (i) an isocyanate with (ii) a compound selected from polyamines, hydrazines, hydrazides and mixtures thereof in the presence of (iii) a hydroxyl compound selected from polyethers, polyesters, polyester amides, polycarbonates and mixtures thereof and (iv) a catalyst. The catalyst is a compound which catalyzes the reaction of isocyanate groups with hydroxyl groups. The catalyst is used in a quantity of at least 50 parts per million parts of (i), (ii) and (iii). These dispersions are particularly useful in the production of polyurethanes.
    Type: Grant
    Filed: July 28, 1988
    Date of Patent: August 8, 1989
    Assignee: Mobay Corporation
    Inventors: Michael K. Lowery, Richard E. Keegan, Mark A. Koshute
  • Patent number: 4855348
    Abstract: A storage stable water-based paint comprising a solid silicone resin and an ammonium salt of a drying oil modified acrylic copolymer provide a coating for barbecue grills and other appliances that are subjected to temperatures as high as 1300.degree. F. A smooth and continuous coating remains on the metal after burning off of the acrylic resin and firing of the metal at 1300.degree. F. The paint is redispersible and may be drawn down to 1.5 mils after storage at 120.degree. F. for more than 3 months when the pH is at least about 8.
    Type: Grant
    Filed: July 14, 1988
    Date of Patent: August 8, 1989
    Assignee: DAP Inc.
    Inventor: Hartzel G. Strader
  • Patent number: 4855378
    Abstract: Organosilicon compounds and organopolysiloxane compositions which are crosslinked by the addition of Si-bonded hydrogen with SiC-bonded vinyl groups and contain the organosilicon compounds as additives for improving the adhesion of the resultant elastomers on the substrates on which they are formed.
    Type: Grant
    Filed: September 4, 1987
    Date of Patent: August 8, 1989
    Assignee: Wacker-Chemie GmbH
    Inventors: Ferdinand Pradl, Carlos Weise, Karl-Heinrich Wegehaupt
  • Patent number: 4847307
    Abstract: The present invention is directed to a process for the production of optionally cellular, polyurethane elastomer moldings or optionally cellular, rigid structural polyurethanes by reacting a reaction mixture containing(i) a polyisocyanate,(ii) a high molecular weight polymer having at least two hydroxy groups and having a molecular weight of 400 to about 10,000,(iii) about 5 to 50% by weight, based on the weight of component (ii) of a chain-extender having at least two hydroxy groups and(iv) about 0.05 to 10 weight percent, based on the weight of components (ii) and (iii) of a salt based on a carboxy functional siloxane and an amidine group-containing compound of the formula ##STR1## wherein R.sub.1, R.sub.2 and R.sub.
    Type: Grant
    Filed: August 8, 1988
    Date of Patent: July 11, 1989
    Assignee: Mobay Corporation
    Inventors: John E. Dewhurst, Stephen J. Harasin
  • Patent number: 4847320
    Abstract: The present invention relates to a process for the production of stable dispersions of polyureas and/or polyhydrazodicarbonamides in a hydroxyl-group-containing material by reacting an organic di- or polyisocyanate with a composition selected from the group consisting of polyamines containing primary and/or secondary amine groups, hydrazines, hydrazides, and mixtures thereof, in said hydroxyl-group containing material, in the presence of a dispersion stabilizing compound.
    Type: Grant
    Filed: July 28, 1988
    Date of Patent: July 11, 1989
    Assignee: Mobay Corporation
    Inventors: Michael K. Lowery, Richard E. Keegan, Mark A. Koshute
  • Patent number: 4812356
    Abstract: A one-component coating composition of35 to 60 wt.-% isocyanate prepolymer8 to 15 wt.-% plasticizer0.3 to 2 wt.-% antisettling agent2 to 10 wt.-% flaky extender5 to 25 wt.-% colorant pigments1 to 3 wt.-% moisture-binding agent, and10 to 20 wt.-% aliphatic estersprovides, on a flexible substrate such as artifical leather, plastic film, paper, roofing felt, polyurethane hard and soft foams, metal foils, concrete and the like, an extraordinarily elastic, tightly adherent coating film of high covering power and light resistance. Furthermore, it has good resistance to abrasion and to weathering, even to aggressive media such as sea water and chemicals.
    Type: Grant
    Filed: March 11, 1987
    Date of Patent: March 14, 1989
    Assignees: BGB-Gesellschaft Reinmar John, Rainer-Leo Meyer, Meyer geb. Kloffer
    Inventors: Rainer-Leo Meyer, Reinmar John, Rolf Nagel, Gunter Muller
  • Patent number: 4810748
    Abstract: A silicone sealant composition which bonds to dolomite containing concrete after exposure to moisture is obtained by adding a silicone fluid having greater than 2 mole percent epoxy functionality to a sealant of the type containing a hydroxyl endblocked polydiorganosiloxane, acetamidosilane chain extender, and crosslinking agent selected from the group consisting of triacetamidosilane and aminoxysilicon compound.
    Type: Grant
    Filed: April 15, 1988
    Date of Patent: March 7, 1989
    Assignee: Dow Corning Corporation
    Inventor: Sherwood Spells
  • Patent number: 4789688
    Abstract: The present invention is directed to a process for the production of optionally cellular, polyurethane elastomer moldings or optionally cellular, rigid structural polyurethanes by reacting a reaction mixture containing(i) a polyisocyanate,(ii) a high molecular weight polymer having at least two hydroxy groups and having a molecular weight of 400 to about 10,000,(iii) about 5 to 50% by weight, based on the weight of component (ii) of a chain-extender having at least two hydroxy groups and(iv) about 0.05 to 10 weight percent, based on the weight of components (ii) and (iii) of a salt based on a carboxy functional siloxane and an amidine group-containing compound of the formula ##STR1## wherein R.sub.1, R.sub.2 and R.sub.
    Type: Grant
    Filed: January 20, 1988
    Date of Patent: December 6, 1988
    Assignee: Mobay Corporation
    Inventors: John E. Dewhurst, Stephen J. Harasin
  • Patent number: 4786681
    Abstract: The invention provides a process for producing a water-in-oil emulsion of a water-soluble polyacrylamide or polyacrylic acid polymer or copolymer by the inverse emulsion process characterized in that there is used as the emulsifying agent for the water-in-oil emulsion a water-insoluble, oil-soluble surface active agent of the formula (I):X--Y--Z Ior a functional derivative thereof, wherein X- represents a saturated or unsaturated hydrocarbon chain containing from 30 to 500 carbon atoms, --Y-- represents a succinic anhydride residue carried terminally upon the group X--, and --Z represents a hydrophilic group carried by the group --Y--.
    Type: Grant
    Filed: August 12, 1986
    Date of Patent: November 22, 1988
    Assignee: Imperial Chemical Industries PLC
    Inventors: Alan S. Baker, Stephen J. Butterworth, Ravinder K. Jheeta
  • Patent number: 4778845
    Abstract: A one-component adhesive and/or sealing mass which is stable and pumpable at temperatures up to 30.degree. C. containsat least one prepolymer on the basis of a polyurethane, which contains from 0.1 to 15 percent by weight, referred to the prepolymer, of free, reactive isocyanate groups, andat least one with heat activatable hardener.Thereby the stoichiometric ratio between said prepolymer and said hardener is chosen in such a way that only a partial cross-linkage is possible during heating said mass to temperatures from 60.degree. C. to 180.degree. C., and that a product is obtained having from high viscous to plastic characteristics.The inventive masses may be used for bonding and/or sealing of one or more materials of the same or different origin to a composite.
    Type: Grant
    Filed: June 4, 1987
    Date of Patent: October 18, 1988
    Assignee: Sika AG, vorm. Kaspar Winkler & Co.
    Inventors: Hans-Peter Tschan, Lutz-Dieter Zabel, Ueli Pfenninger
  • Patent number: 4758622
    Abstract: A protective composition which comprises at least one aliphatic polyisocyanate, at least one aromatic polyisocyanate and a solvent.
    Type: Grant
    Filed: February 11, 1987
    Date of Patent: July 19, 1988
    Inventor: Claude Gosselin
  • Patent number: 4753966
    Abstract: The present invention is directed to a mold release composition which is a solution, liquid at room temperature, of(A) at least one zinc salt of a straight chain or branched, saturated or unsaturated aliphatic carboxylic acid containing 8 to 24 carbon atoms in(B) at least one organic compound containing nitrogen which is liquid at room temperature, the solution containing the zinc salt in a quantity of about 10 to 75% by weight, based on the total weight of the composition.The present invention is additionally directed to an isocyanate reactive mixture containing isocyanate reactive compounds and the above described mold release composition. The present invention is further directed to a process for the preparation of molded products based on the above mixture and to the molded products obtained according to this process.
    Type: Grant
    Filed: November 12, 1987
    Date of Patent: June 28, 1988
    Assignee: Bayer Aktiengesellschaft
    Inventors: Peter Haas, Christian Weber
  • Patent number: 4746693
    Abstract: A composition suitable for forming polyalkylsilsesquioxane coatings is prepared by emulsion hydrolysis of one or more silanes in the presence of a nonvolatile, nonionic catalyst, a nonionic fluorochemical surfactant and sufficient water to only partially hydrolyze the silanes. The resulting stable composition will form the final resin upon exposure to atmospheric moisture. A novel resin, polymethyl/isobutylsilsesquioxane, is particularly suitable for such coatings.
    Type: Grant
    Filed: December 12, 1986
    Date of Patent: May 24, 1988
    Assignee: RCA Corporation
    Inventor: Martin G. Meder
  • Patent number: 4742112
    Abstract: Polyol mixtures having about 10 to 60 weight percent of a ricinoleate compound and 90 to 40 weight percent of a C.sub.2 -C.sub.6 hydrocarbon polymer having at least one hydroxyl group. Polyurethane compositions comprising the reaction product of this polyol mixture with an organic isocyanate compound. These compositions may optionally include certain extender compounds. Also, a method for lowering the viscosity of C.sub.2 -C.sub.6 hydrocarbon polymer having at least one hydroxyl group by adding a ricinoleate compound thereto.
    Type: Grant
    Filed: January 23, 1987
    Date of Patent: May 3, 1988
    Assignee: CasChem, Inc.
    Inventors: Melvin Brauer, William J. Downey
  • Patent number: RE33755
    Abstract: A plasticized polyurethane gel system comprising the reaction product of an isocyanate compound and a polyol in the presence of a plasticizer compound having a total solubility parameter of .[.between about 8.3 and 8.9 or.]. between about 9.1 and 9.7.
    Type: Grant
    Filed: October 30, 1989
    Date of Patent: November 26, 1991
    Assignee: CasChem, Inc.
    Inventors: William J. Downey, Melvin Brauer, Jerry C. Chao
  • Patent number: RE33761
    Abstract: A plasticized polyurethane gel system comprising the reaction product of an isocyanate compound and a polyol in the presence of a ricinoleate plasticizer compound having a total solubility parameter of .[.between about 8.3 and 8.9 or.]. between about 9.1 and 9.7 .Iadd.to 10.1. .Iaddend.
    Type: Grant
    Filed: October 30, 1989
    Date of Patent: December 3, 1991
    Assignee: CasChem, Inc.
    Inventors: Melvin Brauer, William J. Downey, Frank C. Naughton