Group Viii, I.e., Fe, Ru, Os, Co, Rh, Ir, Ni, Pd, Pt Patents (Class 524/785)
  • Patent number: 6060580
    Abstract: The invention relates to a star-shaped branched polyamide that has a high thermal stability and can be produced in existing production facilities for the corresponding linear polyamide. This is achieved by allowing the polyamide branches, at least three, to be formed from a multifunctional core having functional groups chosen from the group comprising amine and carboxyl groups, the amine or carboxyl groups being bound to an acyclic compound in which branching occures, if it is branched, at a carbon atom, or via an acyclic chain to a heterocyclic compound showing point symmetry.The process for the preparation is carried out under the conditions of the preparation of the corresponding linear polyamide. It proves to be possible to obtain, after shorter polymerization times, a product with mechanical properties that are comparable with those of the linear polyamide after significantly longer polymerization times.
    Type: Grant
    Filed: November 3, 1997
    Date of Patent: May 9, 2000
    Assignee: DSM N. V.
    Inventors: Atze J Nijenhuis, Martien Serne, Ellen M. M. de Brabander-van den Berg, Rene Aberson
  • Patent number: 6057039
    Abstract: The present invention relates to a coating composition characterized in that an acetylacetonate having as the central metallic atom thereof Fe, Al, Sn or Ti, or a perchlorate, or a carboxylic acid or an anhydride thereof, and an acetylacetonate having as the central metallic atom thereof Li, Cu or Mn are incorporated in combination as curing catalysts; and to a composite structure characterized in that an antireflection film is provided on the surface of a coating film that is obtained from the above composition.According to the present invention, a coating film which is drastically improved in transparency, optical properties and durability can be obtained. Moreover, this coating film has both high adhesion to an antireflection film made from an inorganic material, and durability. Further, according to the present invention, the pot life of a coating liquid when preserved at room temperature can be prolonged to 3 weeks or longer.
    Type: Grant
    Filed: July 6, 1998
    Date of Patent: May 2, 2000
    Assignee: Seiko Epson Corporation
    Inventors: Katsuyoshi Takeshita, Jun Kinoshita
  • Patent number: 6043335
    Abstract: Polyesters are prepared by the reaction of a dicarboxylic acid, preferably an aromatic acid such as terephthalic acid, or an ester or ester-forming derivative thereof with a dihydroxy compound such as 1,4-butanediol in the presence of a catalyst composition comprising the combination of a titanium-based compound such as tetra-n-butyl titanate, a zirconium-based compound such as zirconium tetrakis(2,4-pentanedionate) and a phosphate-forming compound such as sodium dihydrogen phosphate. This catalyst composition affords polyesters having relatively low melt viscosities in short reaction times and does not produce an excessive level of undesirable reaction by-products.
    Type: Grant
    Filed: October 4, 1999
    Date of Patent: March 28, 2000
    Assignee: General Electric Company
    Inventors: Timothy Edward Banach, Maurizio Fiorini, Bimal Ramesh Patel, Francesco Pilati, Corrado Berti, Elisabetta Marianucci, Massimo Messori, Martino Colonna, Maurizio Toselli
  • Patent number: 6037443
    Abstract: Linear, thermoplastic, elastomneric copolymers of carbon monoxide and olefinically unsaturated compounds have an alternating sequence of repeating units and an average molecular weight Mw of the copolymers of from 80,000 to 1,200,000, binary, linear, alternating carbon monoxide/ethylene copolymers being excluded.
    Type: Grant
    Filed: September 3, 1998
    Date of Patent: March 14, 2000
    Assignee: BASF Aktiengesellschaft
    Inventors: Hans-Joachim Muller, Hans Christoph Horn, Roland Spahl, Bernhard Rieger, Adnan S. Abu-Surrah
  • Patent number: 6025456
    Abstract: Hydroxyl-containing polyurethanes I are composed essentially ofa) a diisocyanate of 6 to 30 carbon atoms (component II),b) a component III comprising.alpha.) an aliphatic diol of 2 to 20 carbon atoms or.beta.) an aromatic-aliphatic or aromatic-cycloaliphatic diol of 8 to 30 carbon atoms having nonphenolic hydroxyl groups as hydroxyl groups of the diol andc) a polyhydric alcohol having at least 3 hydroxyl groups, 3 to 18 carbon atoms and nonphenolic hydroxyl groups as hydroxyl groups of the alcohol (component IV),the amounts of components II to IV being such that the total number of nonphenolic hydroxyl groups is from 1.1 to 5.0 per isocyanate group of II.The polyurethanes can be used as binders or binder components for pigment-containing coatings, in particular for the production of magnetic recording materials.
    Type: Grant
    Filed: March 9, 1998
    Date of Patent: February 15, 2000
    Assignee: EMTEC Magnetics GmbH
    Inventors: Thomas Wunsch, Ria Kress, Werner Loch, August Lehner, Albert Kohl, Norbert Schneider, Uwe Burkhardt
  • Patent number: 6022603
    Abstract: An ethylene terephthalate/ethylene-2,6-naphthalene dicarboxylate copolymer comprising 2,6-naphthalenedicarboxylic acid in an amount of 5 to 20 mol % of the total of all dicarboxylic acid components. This copolymer contains Mn, Mg and Co derived from catalysts and P derived from a phosphorus compound as a stabilizer whose amount is controlled to a specific value and is suitable for use as a raw material for molding a bottle having good color (achromatic) and transparency.
    Type: Grant
    Filed: October 5, 1998
    Date of Patent: February 8, 2000
    Assignee: Teijin Limited
    Inventors: Masami Umeda, Kimihiko Sato, Minoru Suzuki
  • Patent number: 5986046
    Abstract: An oxidant solution for synthesizing a heat-resistant electroconductive polymer, composed of a solution of a non-protonic organic solvent and an oxidant of the organic compound iron salt expressed by the following formula:Fe.sup.3+O [(X)L--(M)m--(Y.sup.-)n]pH.sup.
    Type: Grant
    Filed: March 9, 1998
    Date of Patent: November 16, 1999
    Assignee: NEC Corporation
    Inventors: Toshihiko Nishiyama, Takashi Fukaumi, Atushi Kobayashi, Masashi Ohi, Yoshihiko Saiki, Kazuaki Fukushima, Tomitaro Hara, Shinji Takeoka, Kimihisa Yamamoto, Eishun Tuchida
  • Patent number: 5961876
    Abstract: An organopolysiloxane composition for viscous fluid couplings permits little torque variation even when used at a high temperature for an extended period of time. The organopolysiloxane composition comprises an organopolysiloxane liquid with a viscosity of 100 to 1,000,000 sq. mm/s and a platinum compound in an amount such that the amount of platinum metal relative to the liquid is 0.1 to 1,000 ppm. The organopolysiloxane liquid is typically a trimethylsiloxy-endblocked polydimethylsiloxane.
    Type: Grant
    Filed: March 31, 1998
    Date of Patent: October 5, 1999
    Assignee: Dow Corning Toray Silicone Co., Ltd.
    Inventors: Shoji Akamatsu, Mari Tateishi, Toshinori Watanabe
  • Patent number: 5958283
    Abstract: The invention relates to a thermoplastically processible molding material with a two-phase matrix of a partially aromatic copolyamide and an aliphatic polyamide or copolyamide containing permanently magnetic or magnetizable fillers, as well as to a method for producing this molding material and using it for producing molded parts.
    Type: Grant
    Filed: December 17, 1997
    Date of Patent: September 28, 1999
    Assignee: EMS-Inventa AG
    Inventors: Eduard Schmid, Ivano Laudonia, David Jarvis, Etienne Aepli, Gion Antoni Tuor
  • Patent number: 5948854
    Abstract: Alkoxy-functional room temperature vulcanizing (RTV) compositions, curable in the presence of moisture, comprising polymers containing on average at least 1.2 alkoxysilyl chain terminations per molecule, a tetraalkoxytitanium compound containing on average greater than 90 mole percent of the alkoxy groups as tertiary amyloxy groups, a filler, and an alkoxysilane. The addition of these components in amounts to satisfy defined molar ratios provide alkoxy-functional RTV compositions having both improved storage stability and improved green strength upon curing.
    Type: Grant
    Filed: September 25, 1997
    Date of Patent: September 7, 1999
    Assignees: Dow Corning S.A., Dow Corning Corporation
    Inventors: Francois de Buyl, Robert H. Krahnke, Timothy B. Lueder, Richard A. Palmer
  • Patent number: 5936032
    Abstract: The present invention provides for a two component room temperature vulcanizable silicone compositions wherein both components may be used in approximately equal weights or volumes thereby minimizing the effects of mixture ratio errors.
    Type: Grant
    Filed: February 26, 1997
    Date of Patent: August 10, 1999
    Assignee: General Electric Company
    Inventor: Richard O. Angus, Jr.
  • Patent number: 5929143
    Abstract: The present invention provides novel vinyl containing organopolysiloxane elastomers which possess excellent low compression set and heat aging characteristics and which can advantageously be formulated into liquid silicone elastomer moldable compositions.
    Type: Grant
    Filed: October 16, 1997
    Date of Patent: July 27, 1999
    Assignee: General Electric Company
    Inventors: Brian John Ward, Edward Matthew Jeram, Richard Albert Striker
  • Patent number: 5910525
    Abstract: A silicone rubber composition that cures into a highly flame-retardant silicone rubber with excellent electrical insulation characteristics and that does so without sacrificing mechanical strength. The silicone rubber composition comprises:(A) polyorganosiloxane described by average formula R.sub.a SiO.sub.(4-a)/, where R denotes substituted and unsubstituted monovalent hydrocarbon groups and a is a number from 1.95 to 2.05 and having at least 2 silicon-bonded alkenyl groups in each molecule;(B) microparticulate silica;(C) the reaction mixture of(a) a platinum compound and(b) a compound containing a carbon-carbon double bond and a carbon-carbon triple bond;(D) curing agent, and optionally(E) a triazole compound.
    Type: Grant
    Filed: July 17, 1997
    Date of Patent: June 8, 1999
    Assignee: Dow Corning Toray Silicone Co., Ltd.
    Inventors: Takao Matsushita, Osamu Takuman
  • Patent number: 5905138
    Abstract: A process for the preparation of a copolymer of carbon monoxide with an olefinically unsaturated compound in which a powder of a copolymer of carbon monoxide with an olefinically unsaturated compound is suspended in a liquid diluent. The suspension is contacted with a catalyst composition which is soluble in the diluent and which is based on a Group VIII metal and a bidentate ligand. The catalyst composition is used in such a quantity that in the polymerization mixture more than 0.1 mmoles of the Group VIII metal is present per liter of liquid phase.
    Type: Grant
    Filed: February 19, 1997
    Date of Patent: May 18, 1999
    Assignee: Shell Oil Company
    Inventor: Johannes Adrianus Maria Van Broekhoven
  • Patent number: 5902873
    Abstract: A catalyst composition for use in the preparation of a polyester or copolyester is disclosed. The catalyst composition comprises the combination of (a) a titanium-based compound or zirconium-based compound, and (b) a lanthanide series compound or hafnium. Various titanium-based compounds and lanthanide-based compounds are described. Moreover, in some embodiments, the catalyst composition may further comprise a phosphate-forming compound. Another aspect of this invention is an improved method for preparing a polyester, based, for example, on the two-stage process of ester interchange and polycondensation. The method is carried out in the presence of the catalyst composition described above.
    Type: Grant
    Filed: October 17, 1997
    Date of Patent: May 11, 1999
    Assignee: General Electric Company
    Inventors: Timothy Edward Banach, Francesco Pilati, Martino Colonna, Maurizio Fiorini, Corrado Berti, Maurizio Toselli, Massimo Messori, Elisabetta Marianucci
  • Patent number: 5898060
    Abstract: A copolyester for molding a bottle which comprises 95 to 87 mol % of naphthalenedicarboxylic acid and 5 to 13 mol % of terephthalic acid as dicarboxylic acid components and a diol component consisting essentially of ethylene glycol, has an acetaldehyde content of 20 ppm or less and an intrinsic viscosity of 0.40 to 0.85 dl/g, and produces acetaldehyde in an amount of 30 ppm or less when the copolyester is kept molten with stirring at 300.degree. C. for 5 minutes.
    Type: Grant
    Filed: August 14, 1998
    Date of Patent: April 27, 1999
    Assignee: Teijin Limited
    Inventors: Minoru Suzuki, Kimihiko Sato
  • Patent number: 5895794
    Abstract: A crosslinked polysiloxane dispersion comprising a siloxane polymer, polymer mixture, or polymer/solvent mixture, capable of crosslinking via condensation, addition or free radical reactions, and having a viscosity of greater than 5000 mPa.s but less than 500,000 mPa.s, if required, 0.1 to 10 weight parts of a crosslinking agent, and, if required, depending on the nature of the catalyst and silicon cure system, 0.000001 to 10 weight parts of a catalyst, 0.5 to 10 weight parts of a surfactant or surfactant mixture, and 0.5 to 25 weight parts water per 100 weight parts siloxane polymer. Optionally, adhesion promoters, pigments, reinforcing or non-reinforcing fillers, silicone resins, stabilizers, freeze/thaw additives, etc. may also be added to the dispersion.
    Type: Grant
    Filed: April 27, 1995
    Date of Patent: April 20, 1999
    Assignee: Dow Corning Corporation
    Inventors: Daniel Trent Berg, Donald Taylor Liles, Leon Andre Marteaux, Nick Evan Shephard, Andreas Thomas Franz Wolf, Eric Jude Joffre
  • Patent number: 5880199
    Abstract: A liquid silicone rubber composition that prior to its cure has a suitable fluidity and excellent moldability and that cures into a highly flame retardant silicone rubber molding with excellent electrical properties. The liquid silicone rubber composition comprises(A) polyorganosiloxane,(B) microparticulate silica,(C) aluminum hydroxide powder,(D) zinc carbonate powder,(E) polyorganohydrogensiloxane,(F) benzotriazole,(G) the reaction mixture of(a) a platinum compound and(b) 3,5-dimethyl-1-hexyn-3-ol, and(H) hydrosilylation reaction catalyst.
    Type: Grant
    Filed: May 22, 1997
    Date of Patent: March 9, 1999
    Assignee: Dow Corning Toray Silicone Co., Ltd.
    Inventors: Takao Matsushita, Yasumichi Shigehisa, Yuichi Tsuji
  • Patent number: 5872204
    Abstract: The present invention provides a novel poly(1,3-propylene terephthalate), which is prepared from reacting terephthalic acid and 1,3-propanediol in the presence of an effective catalytic amount of ethylene glycol titanate to undergo esterification to form a monomer; and polymerizing the monomer in the presence of an effective catalytic amount of antimony acetate to obtain poly(1,3-propylene terephthalate). The obtained poly(1,3-propylene terephthalate) (PPT) has an intrinsic viscosity (IV) of 0.65-0.91 dl/g, acid number (--COOH amount) of less than 40 meq/kg, and L*>60. Without adding a pigment, the yellowness b* of PPT is below 9, even below 5. The yellowness b* of PPT even reaches below 3 when a pigment is incorporated.
    Type: Grant
    Filed: March 6, 1998
    Date of Patent: February 16, 1999
    Assignee: Industrial Technology Research Institute
    Inventors: Tung-Ying Kuo, Jih-Chen Huang, Chien-Shiun Liao, I-Min Tseng, Chyuan Juang, Long-Shuen Jean
  • Patent number: 5869558
    Abstract: The present invention are dielectric black particles for use in electrophoretic images displays, electrostatic toner or the like, and the corresponding method of manufacturing the same. The present invention black particles are latex particles formed by a polymerization technique, wherein the latex particles are stained to a high degree of blackness with a metal oxide.
    Type: Grant
    Filed: May 27, 1997
    Date of Patent: February 9, 1999
    Assignee: Copytele, Inc.
    Inventor: Wei-Hsin Hou
  • Patent number: 5851612
    Abstract: A container formed from a copolyester composition which comprises a copolyester containing 80 to 95 mol % of terephthalic acid and 20 to 5 mol % of 2,6-naphthalenedicarboxylic acid as acid components and ethylene glycol as a glycol component, wherein catalyst metals of a calcium compound, magnesium compound and cobalt compound are contained in the copolyester in such amounts that satisfy all the following expressions (1) to (4) based on the total of the whole acid component of the polymer:0<Ca.ltoreq.35(mmol %) (1)0<Mg.ltoreq.80(mmol %) (2)40.ltoreq.(Mg+Ca).ltoreq.90(mmol %) (3)0.ltoreq.Co.ltoreq.15(mmol %) (4).The above polyester container is excellent in gas barrier property, ultraviolet light screening property, hot water resistance, hue and transparency, is not whitened and has a small content of aldehyde.
    Type: Grant
    Filed: December 24, 1997
    Date of Patent: December 22, 1998
    Assignee: Teijin Limited
    Inventors: Masami Umeda, Kimihiko Sato
  • Patent number: 5852164
    Abstract: A polyester comprises a dicarboxylic acid moiety comprising terephthalic acid or its ester forming derivative and a diol moiety comprising ethylene glycol and 1,4-cyclohexanedimethanol of 10 to 60 mol % based on the whole diol moiety, the intrinsic viscosity of the polyester being 0.68 to 0.95 dl/g, the "b" value of color tone of the produced pellets of polyester being -5 to 5, the number of the carboxylic acid terminals being not more than 30 eq/ton, and the sum of the numbers of the vinyl terminals, the vinylidene terminals and the methylcyclohexene terminals being not more than 25 eq/ton.
    Type: Grant
    Filed: April 15, 1997
    Date of Patent: December 22, 1998
    Assignee: Mitsubishi Chemical Corporation
    Inventors: Hideko Akai, Katsuji Tanaka, Masahiko Fujimoto, Noboru Sato
  • Patent number: 5849864
    Abstract: The present invention is addressed a formulation curable in the presence of an amine and containing one or more of a polyol or polymercapto resin, a polyisocyanate cross-linking agent, optionally a organic vehicle, and a tin catalyst complex. The present invention comprises the catalyst complex being formed from a metal catalyst and a complexing sulfonic acid in an equivalent ratio of complexing sulfonic acid to metal catalyst of greater than 2:1. Such curable formulation may be compounded into a coating, an adhesive (including a structural adhesive), a caulk, a foundry binder, or the like. Besides having excellent shelf life, long periods of open time are experienced with the novel catalyzed formulation. However, upon exposure to an amine, the catalyst complex becomes activated and then is effective to catalyze the NCO--OH reaction or the NCO--SH reaction to effect cure of the formulation.
    Type: Grant
    Filed: August 1, 1996
    Date of Patent: December 15, 1998
    Assignee: Ashland Chemical Company
    Inventors: Gary M. Carlson, Laurence G. Dammann
  • Patent number: 5840805
    Abstract: A highly storage-stable room-temperature-curable organopolysiloxane composition that cures to yield a product whose surface resists staining and that does not cause staining of the neighboring regions of the substrate in contact with said cured product. The organopolysiloxane composition is made from a polydiorganosiloxane, an imidazolinyl-functional organosiloxane, a filler, and a crosslinking compound which is a Si-bonded hydrolyzable group-containing organosilane or organosiloxane oligomer.
    Type: Grant
    Filed: October 25, 1995
    Date of Patent: November 24, 1998
    Assignee: Dow Corning Toray Silicone Co., Ltd.
    Inventors: Hisataka Nakashima, Shigeki Sugiyama
  • Patent number: 5804631
    Abstract: A curable organosiloxane composition useable as a silicone die attach adhesive, an electrically conductive silicone rubber composition each comprising a composition that cures through both addition and condensation reactions, that will not impair wire bondability to a semiconductor chip or lead frame after the semiconductor chip has been bonded to a substrate or package; and semiconductor devices in which the semiconductor chip is bonded to its substrate or package using the curable organosiloxane composition and in which the semiconductor device that evidences high reliability by virtue of the use of the curable organosiloxane composition.
    Type: Grant
    Filed: July 30, 1996
    Date of Patent: September 8, 1998
    Assignee: Dow Corning Toray Silicone Co., Ltd.
    Inventors: Katsutoshi Mine, Osamu Mitani, Kazumi Nakayoshi, Rikako Tazawa
  • Patent number: 5798433
    Abstract: The present invention provides a method of synthesizing polypropylene terephthalate with no more than 5 ppm acrolein and no more than 3 ppm allyl alcohol. The method comprises direct esterification of terephthalic acid with 1,3-propanediol in the presence of 30 to 200 ppm titanium in the form of an inorganic esterification catalyst containing at least 50 mol % TiO.sub.2 precipitate, blocking the esterification catalyst after esterification by adding 10 to 100 ppm phosphorus in the form of a phosphorus-oxygen compound, and then performing precondensation and polycondensation in the presence of 100 to 300 ppm antimony in the form of a conventional antimony polycondensation catalyst and optional conventional coloring agent.
    Type: Grant
    Filed: October 1, 1997
    Date of Patent: August 25, 1998
    Assignees: Zimmer Aktiengesellschaft, Degussa Aktiengesellschaft
    Inventors: Wolfgang Schmidt, Ulrich Thiele, Stephanie Schauhoff, Dahai Yu
  • Patent number: 5789485
    Abstract: The present invention relates to a curable silicone composition comprising (A) an alkenyl-functional organopolysiloxane, (B) a siloxane-modified acrylic polymer, (C) an organohydrogenpolysiloxane, and (D) a hydrosilylation reaction catalyst. The curable silicone compositions of this invention cure into a highly oil-resistant and highly wear-resistant coating and are useful as base compositions for inks for silicone moldings, and are also useful for imparting release against pressure sensitive adhesives while maintaining a degree of printability.
    Type: Grant
    Filed: December 24, 1996
    Date of Patent: August 4, 1998
    Assignee: Dow Corning Toray Silicone Co., Ltd.
    Inventors: Akihiko Kobayashi, Takayoshi Otomo, Hiroaki Yoshida
  • Patent number: 5783311
    Abstract: CVE polyorganosiloxane compositions crosslinkable into silicone elastomeric state, well suited for the protective coating of a wide variety of substrates and supports, notably vehicular airbags, are improvedly adhered thereto by including in said CVE silicone compositions an adhesiveness promoter comprising (1) at least one alkoxylated organosilane containing, per molecule, at least one C.sub.2 -C.sub.6 alkenyl radical, (2) at least one organosilicon compound containing at least one epoxy radical, and (3) at least one chelate of metal M and/or a metal alkoxide having the formula: M(OJ).sub.n, wherein n is the valency of M, J is a linear or branched C.sub.1 -C.sub.8 alkyl radical, and M is selected from among Ti, Zr, Ge, Li, Mn, Fe, Al and Mg.
    Type: Grant
    Filed: January 27, 1997
    Date of Patent: July 21, 1998
    Assignee: Rhone-Poulenc Chimie
    Inventors: Dominique Lorenzetti, Pierre-Michel Peccoux
  • Patent number: 5770659
    Abstract: Processes for making storage-stable epoxy-capped polyetherester resins are disclosed. In one process, a polyetherester resin is first made by inserting a carboxylic acid derivative into a polyether. Reacting the resin with a capping agent gives an intermediate resin with a reduced content of free carboxylic acid groups. Finally, the intermediate resin reacts with an epoxy compound in the presence of a finishing catalyst under conditions effective to give an epoxy-capped resin. The resins have low weight average molecular weights (less than about 8000), narrow molecular weight distributions (less than 6), and low viscosities, making them an excellent choice for low-VOC formulations. The finishing catalyst helps to minimize resin viscosity drift and improves shelf stability. Curing the resins with a vinyl monomer gives thermosets with an excellent balance of physical properties, including excellent water resistance.
    Type: Grant
    Filed: November 10, 1997
    Date of Patent: June 23, 1998
    Assignee: Arco Chemical Technology, L.P.
    Inventors: Gangfeng Cai, Daniel M. Trauth, Lau S. Yang
  • Patent number: 5770640
    Abstract: Finishing agents comprise the combination of an alkoxysilane surface active agent, a silanol condensing catalyst, and a nonaqueous liquid or solid medium, or the combination of an alkoxysilane surface active agent, an acid catalyst and a liquid or solid medium. In the latter embodiment, it is preferred that at least one of the alkoxysilane surface active agent and the acid catalyst be microencapsuled. The finishing agent permits formation of chemically adsorbed protecting films. Such protecting films are used for substrates of such equipments as electronics products, electric domestic products, automobiles, industrial equipment, mirrors, lenses for glasses and the like. The protecting films have a durability and heat, weather and abrasion resistance, and also water and oil repellent properties.
    Type: Grant
    Filed: January 2, 1997
    Date of Patent: June 23, 1998
    Assignee: Matsushita Electric Industrial Co., Ltd.
    Inventor: Kazufumi Ogawa
  • Patent number: 5750610
    Abstract: The present invention is hydrophobic organosilicate-modified silica gels and a method for their preparation. The method comprises two steps, where in the first step an organosilicate-modified silica hydrosol is heat treated in the presence of a strong mineral acid at a pH less than about pH 1 to form an organosilicate-modified silica hydrogel. In the second step the organosilicate-modified silica hydrogel is contacted with an organosilicon compound in the presence of a catalytic amount of a strong acid to effect hydrophobing of the organosilicate-modified silica hydrogel thereby forming a hydrophobic organosilicate-modified silica hydrogel having a surface area within a range of about 100 m.sup.2 /g to 750 m.sup.2 /g as measured in the dry state.
    Type: Grant
    Filed: February 24, 1997
    Date of Patent: May 12, 1998
    Assignee: Dow Corning Corporation
    Inventors: Gary Thomas Burns, James Richard Hahn, Clifford Carlton Reese
  • Patent number: 5750642
    Abstract: A process for the preparation of copolymers of carbon monoxide with an olefinically unsaturated compound comprising copolymerizing the monomers in the presence of a catalyst composition based upon(a) a salt of a Group VIII metal, and(b) a cation which is selected from cationic oxidants and cations of the general formulae R.sub.n H.sub.4-n N.sup.+, R.sub.m H.sub.3-m C.sup.+ and R.sub.m H.sub.3-m O.sup.+, wherein n is 0, 1, 2, 3 or 4, m is 2 or 3, and R represents a hydrocarbyl group and/or two or three of R together with the atom carrying a positive charge represent a ring structure, on the understanding that when n is 3, at most two of R together with nitrogen represent a heterocyclic ring structure, and when n is 4, three of R together with nitrogen represent an aromatic heterocyclic ring structure.
    Type: Grant
    Filed: February 19, 1997
    Date of Patent: May 12, 1998
    Assignee: Shell Oil Company
    Inventors: Frank Baardman, Jayne Jubb
  • Patent number: 5744571
    Abstract: This invention relates to a process of producing a moldable polyethylene terephthalate or modified polyethylene terephthalate having an inherent viscosity greater than 0.6 dL/g comprising reacting the diacid component with the diol component such that a combination of a titanium-based catalyst and a phosphorus-based catalyst is used during the polycondensation steps.
    Type: Grant
    Filed: October 15, 1996
    Date of Patent: April 28, 1998
    Assignee: Eastman Chemical Company
    Inventors: Samuel D. Hilbert, Thomas G. Davis
  • Patent number: 5741882
    Abstract: A process to prepare a high molecular weight aliphatic polyester is disclosed, where a catalyst is portionwise added, and a radical scavenger is also added. The aliphatic polyester obtained has a number average molecular weight larger than 70,000.
    Type: Grant
    Filed: September 21, 1995
    Date of Patent: April 21, 1998
    Assignee: Tonen Corporation
    Inventors: Takeaki Fujii, Kenji Kobayashi, Sadakatsu Suzuki, Hiroshi Ueno
  • Patent number: 5733969
    Abstract: A zeolite polycondensation catalyst comprising an alkali- or alkaline earth metal aluminum silicate zeolite having an original water content of 12 to 30 weight % and a solubility, measured at 260.degree. C., in an esterification mixture consisting essentially of bis(hydroxy ethylene)terephthalate, of over 8.0 weight %, and an average particle size of less than 1.0.mu.. The present invention is also a process for the production of polyester using this catalyst.
    Type: Grant
    Filed: December 24, 1996
    Date of Patent: March 31, 1998
    Assignee: Zimmer Aktiengesellschaft
    Inventor: Ulrich Thiele
  • Patent number: 5723572
    Abstract: A process for the preparation of a linear alternating copolymer of carbon monoxide with ethene and another olefinically unsaturated compound (A) wherein a copolymer of which the molar ratio (r.sub.1) of the monomer units originating in the olefinically unsaturated compound A to the monomer units originating in ethene is in the range of from 1:100 to 1:3, is prepared by contacting the monomers in the presence of a liquid diluent with a catalyst composition which is based on(a) a source of a Group VIII metal, and(b) a bidentate ligand of the general formula R.sup.1 R.sup.2 M.sup.1 --R--M.sup.2 R.sup.3 R.sup.4 (I) wherein M.sup.1 and M.sup.2 independently represent a phosphorus, arsenic or antimony atom, R.sup.1, R.sup.2, R.sup.3 and R.sup.4 independently represent unsubstituted or substituted hydrocarbyl groups and R represents a bivalent bridging group which consists of three atoms in the bridge of which the middle atom is a carbon or silicon atom which carries two monovalent substituents R.sup.5 and R.sup.
    Type: Grant
    Filed: June 17, 1996
    Date of Patent: March 3, 1998
    Assignee: Shell Oil Company
    Inventors: Erwin Paulus Petrus Bleeker, Johannes Adrianus Maria Van Broekhoven, Maria Barbara Hendrica Crijnen-Beers Van
  • Patent number: 5717009
    Abstract: An adhesive composition which comprises:(A) 100 parts by weight of a polyorganosiloxane represented by the formula (I): ##STR1## (wherein R.sup.1 s may be the same or different from each other and each represent a monovalent hydrocarbon group or a halogen-substituted hydrocarbon group; and n is a positive integer);(B) 0.5 to 10 parts by weight of a tetraalkoxysilane represented by the following formula:R.sup.2.sub.a Si(OR.sup.3).sub.4-a (II)(wherein R.sup.2 represents an alkyl group having 1 to 3 carbon atoms, a phenyl group or a vinyl group; R.sup.3 represents an alkyl group having 1 to 4 carbon atoms or an alkoxy-substituted alkyl group having 3 to 6 carbon atoms; and a is 0 or 1),or a partially hydrolyzed condensate thereof; and(C) 0.1 to 15 parts by weight of a trialkoxysilane represented by the formula (III):R.sup.4 (R.sup.5).sub.b Si(OR.sup.6).sub.3-b (III)(wherein R.sup.4 represents a substituted or unsubstituted aminoalkyl group; R.sup.
    Type: Grant
    Filed: July 17, 1996
    Date of Patent: February 10, 1998
    Assignee: Toshiba Silicone Co., Ltd.
    Inventors: Shigeki Matsushita, Fumihiko Kobayashi
  • Patent number: 5714574
    Abstract: A process for preparing a polyketone is disclosed. This comprises polymerising together carbon monoxide, ethylene and optionally at least one C.sub.3 to C.sub.10 alpha-olefin in the presence of a solvent and a catalyst composition derivable from a palladium salt, an anion which is either non-coordinating or weakly coordinating to palladium and a phosphate ligand characterised in that the solvent is either a C.sub.4 to C.sub.10 tertiary aliphatic alcohol or a mixture of a C.sub.4 to C.sub.10 tertiary alcohol and up to 80% by volume of an aprotic solvent. The preferred tertiary alcohols are tertiary butyl alcohol and tertiary amyl alcohol. The aprotic solvents can be an aliphatic ketone or cyclic aliphatic ether; preferred aprotic solvents are THF and 1,4-dioxane.
    Type: Grant
    Filed: May 26, 1994
    Date of Patent: February 3, 1998
    Assignee: BP Chemicals Limited
    Inventor: Neil Andrew Cooley
  • Patent number: 5710203
    Abstract: Disclosed are compositions which can be used to form tamper-proof coatings on electronic devices. These compositions contain a silica precursor resin and a filler which reacts in an oxidizing atmosphere to liberate heat. Such compositions form coatings which, when oxidized by techniques such as plasma etching, wet etching, or cross-sectioning, liberate heat which causes destruction of the underlying substrate and, thus, inhibits further examination.
    Type: Grant
    Filed: November 7, 1994
    Date of Patent: January 20, 1998
    Assignee: Dow Corning Corporation
    Inventors: Robert Charles Camilletti, Loren Andrew Haluska, Keith Winton Michael
  • Patent number: 5708076
    Abstract: A room temperature-curable organopolysiloxane composition with excellent extrudability and self-extinguishing properties is made from a hydroxyl endblocked polydiorganosiloxane, aluminum hydroxide having an average particle size not exceeding 50 micrometers, colloidal calcium carbonate, platinum or a platinum compound, and a crosslinking silane or siloxane having at least three hydrolyzable groups.
    Type: Grant
    Filed: January 27, 1997
    Date of Patent: January 13, 1998
    Assignee: Dow Corning Toray Silicone Co., Ltd.
    Inventors: Yuichi Tsuji, Miyoji Fukayama
  • Patent number: 5698662
    Abstract: The invention relates to a dendritic macromolecule with branches prepared from halogen cyanide units composed of a monohalogenated hydrocarbon compound comprising 3-50 carbon atoms and at least one cyanide group, the halogen and the cyanide group being separated from one another by at least 3 carbon atoms. The invention also relates to a process for the preparation of a dendritic macromolecule, comprising a core and at least one branch emanating from the core, characterized in that the process comprises the steps a) through c):a) substantially every functional group of the core molecule is reacted with monomeric halogen cyanide unitsb) substantially every incorporated cyanide group is reduced to an aminec) substantially every amine group is reacted with monomeric halogen cyanide units,steps b) and c) being conducted alternately.
    Type: Grant
    Filed: July 26, 1996
    Date of Patent: December 16, 1997
    Assignee: DSM N.V.
    Inventors: Christiaan J. C. Stoelwinder, Ellen M. M. de Brabander-van den Berg, Atze J. Nijenhuis
  • Patent number: 5693722
    Abstract: A process is disclosed whereby a polymeric resin (containing ester and/or carbonate bonds) is readily converted into a resin having a modified molecular structure. Accordingly, a polycyclic carbonate (a monomer or oligomer) is transesterified with the polymer resin in the melt, preferably upon extrusion, optionally in the presence of a catalyst. Significantly, the cyclic carbonates are, by the inventive process, inserted into the structure of the polymer, effecting branching of the molecular structure, a branching which manifests itself in the modified properties of the resin.
    Type: Grant
    Filed: December 13, 1996
    Date of Patent: December 2, 1997
    Assignees: Bayer Corporation, Bayer Aktiengesellschaft
    Inventors: Duane B. Priddy, Jr., Burkhard Kohler, Robert J. Kumpf, Harald Pielartzik
  • Patent number: 5688909
    Abstract: A catalyst composition which is based upon(a) a source of nickel cations, and(b) a bidentate ligand of the general formula R.sup.1 R.sup.2 M.sup.1 --R--M.sup.2 R.sup.3 R.sup.4 (I) wherein M.sup.1 and M.sup.2 represent independently phosphorus, nitrogen, arsenic or antimony, R.sup.1, R.sup.2, R.sup.3 and R.sup.4 represent independently optionally polar substituted hydrocarbyl groups on the understanding that at least one of R.sup.1, R.sup.2, R.sup.3 and R.sup.4 represent a substituted aryl group, and R represents a bivalent bridging group of which the bridge consists of at most two bridging atoms, and a process for the preparation of copolymers of carbon monoxide and an olefinically unsaturated compound comprising ontacting the monomers in the presence of the said catalyst composition.
    Type: Grant
    Filed: June 12, 1996
    Date of Patent: November 18, 1997
    Assignee: Shell Oil Company
    Inventors: Eit Drent, Mirjam Catharina Theodora De Kock
  • Patent number: 5688862
    Abstract: In a semiconductive silicone elastomer composition comprising an organopolysiloxane containing at least two aliphatic unsaturated hydrocarbon groups attached to a silicon atom, an organohydrogenpolysiloxane containing at least two hydrogen atoms attached to a silicon atom, and a conductive agent, the conductive agent consists of 1-10 wt % of conductive carbon and 99-90 wt % of a conductive filler having a volume resistivity of 10.sup.1 -10.sup.8 .OMEGA.-cm other than the conductive carbon. The conductive agent is blended in an amount of 20-60 wt % of the entire composition. The composition having the conductive agent uniformly dispersed therein yields a semiconductive silicone elastomer having a volume resistivity of 10.sup.5 -10.sup.10 .OMEGA.-cm with a dispersity of 1 to 10.
    Type: Grant
    Filed: October 10, 1995
    Date of Patent: November 18, 1997
    Assignee: Shin-Etsu Chemical Co., Ltd.
    Inventors: Takashi Kondou, Takeo Yoshida, Hajime Saito
  • Patent number: 5684060
    Abstract: The present invention provides an addition-curable composition containing an inorganic, organic or organometalic compound of palladium in an amount effective to reduce the amount of hydrogen gas evolved in the reaction of the composition. A preferred embodiment is a dental impression material composition comprising: (a) an addition-curable compound; (b) a crosslinker; (c) a platinum-containing catalyst; and (d) a palladium compound. This generally provides a positive gypsum model of, for example, a dental impression that is substantially free of pits.
    Type: Grant
    Filed: April 9, 1996
    Date of Patent: November 4, 1997
    Assignee: Minnesota Mining and Manufacturing Company
    Inventors: Mark S. Konings, Joel D. Oxman
  • Patent number: 5670611
    Abstract: A process for the copolymerization of carbon monoxide with an olefinically unsaturated compound in which a solid particulate material is suspended in a liquid diluent in which the polymer to be produced forms a suspension. The monomers are contracted in the liquid diluent containing the suspended solid particulate material with a catalyst composition which is based on a source of a Group VIII metal and a boron hydrocarbyl compound.
    Type: Grant
    Filed: March 13, 1996
    Date of Patent: September 23, 1997
    Assignee: Shell Oil Company
    Inventors: Frank Baardman, Arleen Marie Bradford, Jayne Jubb, Pieter Scheerman, Rudolf Jacobus Wijngaarden, Erwin Paulus Petrus Bleeker, Johannes Adrianus Maria Van Broekhoven
  • Patent number: 5670559
    Abstract: A primer composition for the treatment of a tooth surface, which comprises a) at least one metal compound selected from the group consisting of an iron compound, a copper compound and a cobalt compound, b) a polymerizable monomer having an acidic group, and c) water or water and an organic solvent miscible with water; and a method of forming an adhesive layer on a tooth surface, which comprises applying this primer composition to the tooth surface and then applying a curable composition containing trialkylborane or partial oxide thereof and a polymerizable monomer. According to the present invention, both the enamel and the dentin of a tooth can be simultaneously surface-treated without acid treatment or washing with water, and adhesion dental treatment can be reliably carried out by a simple operation without causing pains on a patient.
    Type: Grant
    Filed: May 23, 1995
    Date of Patent: September 23, 1997
    Assignee: Sun Medical Co., Ltd.
    Inventors: Weiping Zeng, Masami Arata, Tsuyoshi Banba
  • Patent number: 5668249
    Abstract: A process for the copolymerization of carbon monoxide with an olefinically unsaturated compound in which the monomers are contacted in the presence of a liquid diluent and a protic compound with a catalyst composition which is based on a source of a Group VIII metal and a hydrocarbylborane. A stirring power is transmitted to the polymerization mixture of at least 0.25 kW/m.sup.3.
    Type: Grant
    Filed: March 13, 1996
    Date of Patent: September 16, 1997
    Assignee: Shell Oil Company
    Inventors: Frank Baardman, Arleen Marie Bradford, Jayne Jubb, Pieter Scheerman, Rudolf Jacobus Wijngaarden, Erwin Paulus Petrus Bleeker, Johannes Adrianus Maria Van Broekhoven
  • Patent number: 5658674
    Abstract: CVE polyorganosiloxane compositions crosslinkable into silicone elastomeric state, well suited for the protective coating of a wide variety of substrates and supports, notably vehicular airbags, are improvedly adhered thereto by including in said CVE silicone compositions an adhesiveness promoter comprising (1) at least one alkoxylated organosilane containing, per molecule, at least one C.sub.2 -C.sub.6 alkenyl radical, (2) at least one organosilicon compound containing at least one epoxy radical, and (3) at least one chelate of metal M and/or a metal alkoxide having the formula: M(OJ).sub.n, wherein n is the valency of M, J is a linear or branched C.sub.1 -C.sub.8 alkyl radical, and M is selected from among Ti, Zr, Ge, Li, Mn, Fe, Al and Mg.
    Type: Grant
    Filed: May 3, 1995
    Date of Patent: August 19, 1997
    Assignee: Rhone-Poulenc Chimie
    Inventors: Dominique Lorenzetti, Pierre-Michel Peccoux
  • Patent number: 5652033
    Abstract: A cobalt/aluminum catalyst is used in the polymerization reaction to form polyesters of terephthalic acid and an ethylene glycol.
    Type: Grant
    Filed: August 14, 1996
    Date of Patent: July 29, 1997
    Assignee: E. I. Du Pont de Nemours and Company
    Inventor: George Richard Goodley