Two Or More Carboxylic Acids Or Derivatives Patents (Class 524/833)
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Patent number: 7812088Abstract: An aqueous multicomponent coating material comprising (I) an aqueous component preparable by mixing at least the following starting products: (A) at least one secondary aqueous dispersion of at least one (meth)acrylate copolymer containing on average per molecule at least one isocyanate-reactive functional group, (B) at least one primary aqueous dispersion of at least one (meth)acrylate copolymer containing no isocyanate-reactive functional group, and (C) at least one pigment and/or one filler; and also (II) a component comprising at least one polyisocyanate as crosslinking agent, and also a process for preparing it, and its use.Type: GrantFiled: February 13, 2002Date of Patent: October 12, 2010Assignee: BASF Coatings GmbHInventors: Bernhard Lettmann, Andreas Jansen, Christella Pudelski
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Patent number: 7789959Abstract: A description is given of coating compositions comprising at least one strongly basic agent to set a pH of at least 10, at least one selected vinyl ester copolymer, if desired, pigment and/or filler, and, if desired, further additives customary per se. The coating compositions can be stored without use of additional preservatives and can be used to coat substrates of all kinds.Type: GrantFiled: May 4, 2005Date of Patent: September 7, 2010Assignee: Celanese Emulsions GmbHInventors: Thomas Fichtner, Ivan Cabrera, Bernhard Momper
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Patent number: 7767753Abstract: A binder resin composition which shows no “stringing” when used in printing and can disappear without leaving any residue upon burning at a relatively low temperature; a glass paste; and a ceramic paste. The binder composition contains as a matrix resin, a copolymer (A) comprising a segment derived from an alkyl(meth)acrylate monomer and a polyalkylene oxide segment composed of repeating units represented by the following chemical formula (1), —(OR)n- wherein R is C3 or higher alkylene and n is an integer.Type: GrantFiled: June 21, 2005Date of Patent: August 3, 2010Assignee: Sekisui Chemical Co., Ltd.Inventors: Hiroji Fukui, Yasuyuki Ieda, Tetsunari Iwade
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Publication number: 20100162490Abstract: Process for the production of leather, wherein pelts, pickled pelts or semifinished products are treated with at least one copolymer (A) which is obtainable by copolymerization of the following comonomers: (a) at least one ethylenically unsaturated C3-C10-carboxylic acid or at least one ethylenically unsaturated C4-C10-dicarboxylic acid or its anhydride, (b) at least one (meth)acrylate of an ?-branched C3-C10-alkanol, (c) at least one (meth)acrylate of a primary C4-C20-alkanol.Type: ApplicationFiled: September 3, 2008Publication date: July 1, 2010Applicant: BASF SEInventors: Markus Brym, Audrey Renoncourt, Stephan Huffer, Gerhard Wolf, Ulrike Mahn, Edward Bohres, Petra Schocker, Hubertus Peter Bell, Peter Danisch
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Publication number: 20100152380Abstract: Process for preparing an aqueous polymer dispersion using alkenes of 5 to 12 carbon atoms.Type: ApplicationFiled: March 28, 2007Publication date: June 17, 2010Applicant: BASF SEInventor: Rajan Venkatesh
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Patent number: 7728068Abstract: The present invention provides coating compositions that include reactive diluents and have high performance, low VOC levels, and low irritation levels.Type: GrantFiled: November 22, 2004Date of Patent: June 1, 2010Assignee: Valspar Sourcing, Inc.Inventors: T. Howard Killilea, James M. Bohannon
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Patent number: 7713674Abstract: An emulsion polymerization process comprising polymerizing monomer in an emulsion in a reaction vessel at a first temperature to form a resin; cooling the reaction vessel to a second temperature that is above the softening point of the resin yet below the temperature required for significant depolymerization reaction to occur; and adding water to the cooled reaction vessel in an amount sufficient to effect phase inversion with mixing for a sufficient time to form an aqueous latex emulsion in the absence of a surfactant.Type: GrantFiled: September 9, 2005Date of Patent: May 11, 2010Assignee: Xerox CorporationInventors: Allan Kwok-Wai Chen, Milan Maric, Tie Hwee Ng, George Liebermann, Enno Eric Agur, Hadi Khan Mahabadi
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Patent number: 7608208Abstract: The current invention relates to water-swellable polymers at least partially comprised of sulfonic acid group containing monomers as additives for fire extinguishing water, which exhibits an elevated NaCl content, used in fire prevention and to combat fire.Type: GrantFiled: February 8, 2002Date of Patent: October 27, 2009Assignee: Evonik Stockhausen GmbHInventors: Jochen Houben, Erich Küster, Martin Tennie
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Patent number: 7605209Abstract: The present invention provides coating compositions that include reactive diluents and have high performance, low VOC levels, and low irritation levels. Certain embodiments of the present invention include water and water-dispersible polymers and other embodiments do not include water.Type: GrantFiled: May 27, 2004Date of Patent: October 20, 2009Assignee: Valspar Sourcing, Inc.Inventors: T. Howard Killilea, James M Bohannon
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Patent number: 7598313Abstract: Polymer capsules from amphiphilic graft copolymers comprising reactive, hydrophobic polyolefin backbones, and hydrophilic poly(ethylene glycol) (PEG) grafts are produced by self-assembly of the polymers at the oil-water interface, and crosslinking the assembly with bis-cyclooctene PEG derivatives in conjunction with ring-open metathesis polymerization catalysts. The use of the graft copolymer architecture in capsule synthesis provides significant opportunities to tune both the surface properties, in terms of recognition, and the membrane properties, in terms of mechanical strength, encapsulation, and release.Type: GrantFiled: September 3, 2004Date of Patent: October 6, 2009Assignee: University of MassachusettsInventors: Todd S. Emrick, Kurt Breitenkamp
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Patent number: 7589129Abstract: The present invention relates to the field of acrylic polymers and in particular to their modification with the purpose of the formation of compounds of still higher molecular masses. Plastic materials of the type of acrylic universal polymer (PAU), e.g. sold under the tradename “POLYGOR”, can be used as starting material. The acrylic starting material is then modified by appropriate modifier compounds. In this way modified polymers can have molecular weights in the range between 2×105 and 15×107 a.u. and are water-soluble. This allows to use them as flocculation, coagulation, ion-exchange means and as additives to surface active agents for raising their washing and foaming capabilities.Type: GrantFiled: February 11, 2005Date of Patent: September 15, 2009Assignee: Waltech, AGInventor: Igor Gubych
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Publication number: 20090181227Abstract: An activator composition for forming an activator-containing region on a substrate for activating a chemical reaction to form a conductive metal region on the substrate, the composition being suitable for thermal inkjet printing, the composition comprising a single phase aqueous composition including one or more curable materials and one or more co-solvents for the curable material(s); and an activator for reaction to form a conductive metal region. Conductive metal regions may be formed on the resulting activator-containing regions by a metallisation reaction such as electroless deposition.Type: ApplicationFiled: July 19, 2007Publication date: July 16, 2009Inventors: Shaun Christopher Hazlewood, Natasha Jeremic
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Patent number: 7560032Abstract: A high molecular weight, water-soluble polymer comprising pendant salicylic acid groups and having a weight average molecular weight of at least about 2,000,000 daltons and use of the polymer for clarifying red mud-containing liquors generated in the Bayer process for the recovery of alumina from bauxite.Type: GrantFiled: August 17, 2006Date of Patent: July 14, 2009Assignee: Nalco CompanyInventors: Murat Quadir, Everett C. Phillips, Larry E. Brammer, Jr., Robert P. Mahoney, John D. Kildea, Manian Ramesh, John T. Malito
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Publication number: 20090171017Abstract: A pressure-sensitive adhesive comprising an aqueous polymer dispersion prepared by emulsion polymerization, wherein the polymer comprises n-butyl(meth)acrylate and hydroxybutyl(meth)acrylate.Type: ApplicationFiled: April 16, 2007Publication date: July 2, 2009Applicant: BASF SEInventors: Cornelis Petrus Beyers, Stefan Kirsch, Petra Schöcker, Ines Pietsch
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Publication number: 20090099305Abstract: Process for preparing an aqueous copolymer dispersion, with specific crosslinker metering.Type: ApplicationFiled: April 16, 2007Publication date: April 16, 2009Applicant: BASF SEInventors: Marc Schroder, Andreas Eipper, Matthias Scheibitz, Jens Assmann, Hiroki Fukuhara
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Patent number: 7498382Abstract: It is an object of the present invention to provide an emulsion which can form a coating excellent in water penetration resistance as well as impregnating adhesion property, its production method, and a structure body using the emulsion. The present invention is directed to an emulsion comprising a hydrophobic resin particle (A) dispersed in a water-based medium as a resin component, wherein 20 to 60% by weight in the entire resin components including the hydrophobic resin particles (A) is a polymer emulsifier (B) and the average particle diameter of the particles contained therein is 50 nm or smaller.Type: GrantFiled: May 31, 2005Date of Patent: March 3, 2009Assignee: Nippon Shokubai Co., Ltd.Inventor: Keiichi Nakamoto
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Patent number: 7479524Abstract: This invention provides a process for producing an aqueous resin dispersion in which the average particle diameter of the dispersed resin is not more than 500 nm, comprising finely dispersing a monomeric mixture (I) containing (A) fatty acid-modified polymerizable unsaturated monomer and (B) other polymerizable unsaturated monomer which is copolymerizable with the monomer (A) in an aqueous medium in such a manner that the dispersed particles have an average particle diameter not more than 500 nm, and polymerizing the resulting emulsified product. The invention also provides aqueous resin compositions which comprise the aqueous resin dispersions, and water-based paint compositions which comprise the aqueous resin compositions.Type: GrantFiled: February 18, 2004Date of Patent: January 20, 2009Assignee: Kansai Paint Co., Ltd.Inventors: Takashi Kitamura, Keiichiro Saikawa, Kenichi Tomita, Takeshi Inoue, Kenya Suzuki, Hiromi Harakawa, Masami Sugishima
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Patent number: 7449223Abstract: A polymerizable liquid crystal composition includes a liquid crystal compound having a polymerizable group, wherein the composition includes from 0.1 to 6.0% by weight of a (meth)acrylic copolymer (H), which 1) has a side chain containing a fluorine group, and a side chain containing a group represented by a general formula (h): 2) has a fluorine group content of 3 to 30% by weight, 3) has a ratio of side chains containing the group represented by the general formula (h) relative to the combined total of all side chains that falls within a range from 9 to 95 mol %, and 4) has a weight average molecular weight within a range from 10,000 to 300,000.Type: GrantFiled: May 26, 2005Date of Patent: November 11, 2008Assignee: Dainippon Ink and Chemicals, Inc.Inventors: Jyoji Kawamura, Yoshiyuki Ono, Yasuyuki Suzuki, Hitoshi Hayakawa, Isa Nishiyama, Yasuyuki Watanabe, Yasuhiro Kuwana
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Publication number: 20080146732Abstract: A process for producing an emulsion pressure-sensitive adhesive comprises (co)polymerizing a main monomer in the presence of a protective colloid, the protective colloid being an acrylic copolymer comprising (A-1) at least one hydrophilic monomer selected from the group consisting of acrylamide, methacrylamide, hydroxyethyl acrylate and hydroxyethyl methacrylate and (B-1) an alkyl (meth)acrylate that is copolymerizable with the hydrophilic monomer (A-1) and whose alkyl group has 4 to 18 carbon atoms, or (A-2) a hydrophilic monomer being acrylic acid and/or methacrylic acid and (B-2) an alkyl (meth)acrylate that is copolymerizable with the hydrophilic monomer (A-2) and whose alkyl group has 4 to 9 carbon atoms; the hydrophilic monomer and the alkyl (meth)acrylate being copolymerized in a weight ratio in the range of 40-70:60-30; the acrylic copolymer having a weight-average molecular weight in the range of 500 to 50000.Type: ApplicationFiled: February 11, 2008Publication date: June 19, 2008Applicant: SOKEN CHEMICAL & ENGINEERING CO., LTD.Inventor: Kiyokuni Takashima
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Patent number: 7384992Abstract: This invention relates to novel rosin-alkyl ester of unsaturated fatty acid vinylic polymer and emulsion compositions and the processes for preparing them. In particular, the invention relates to novel rosin-alkyl ester of unsaturated fatty acid vinylic polymer and emulsion compositions which the polymer exhibit properties that make them useful as support resins for industrial coatings, ink and overprint formulations and as additives for formulating various coating compositions; and the emulsion which exhibits properties that make them useful as water-borne vehicles for coatings on various substrates.Type: GrantFiled: September 24, 2004Date of Patent: June 10, 2008Assignee: MeadWestvaco CorporationInventor: Louis Joseph Tortorelli
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Patent number: 7375173Abstract: The invention relates to cationic water-soluble polyelectrolytes, especially terpolymers, which are obtained by polymerising monomers of (meth)acrylamide, a quaternised (meth)acrylamide derivative, a (meth)acrylic acid derivative and/or hydrolysis-stable cationic monomers. The composition of the polyelectrolytes is characterised by a toxicity index formula Fi=(QTP?2QME)/10?1 wherein QTP represents the total cationic charge of the polymer and QME represents the charge part of the ester type monomer. The invention also relates to the production and use of said polyelectrolytes and water-in-water polymer dispersions which contain said polyelectrolytes.Type: GrantFiled: July 30, 2003Date of Patent: May 20, 2008Assignee: Ashland Licensing and Intellectual Property LLCInventors: Norbert Steiner, Gregor Herth, Werner Fischer, Horst Redlof
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Patent number: 7354972Abstract: The invention is directed to amphipathic polymeric particles that serve as both the dispersant and the binder in water based inks, ink compositions containing these particles, and methods for making the particles. The polymeric particles contain both hydrophilic and hydrophobic moieties with a pre-determined structure, and have an average diameter of 50 to 500 nm. The amphipathic polymeric particles may be prepared by a side-chain conversion method or a polymerization process involving an ATRP step, with or without a cross-linking agent. This invention improves the stability of polymer and inks by both ionic and steric stabilization of the suspended polymer particles.Type: GrantFiled: October 30, 2003Date of Patent: April 8, 2008Assignee: Hewlett-Packard Development Company, L.P.Inventor: Sivapackia Ganapathiappan
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Patent number: 7345111Abstract: The present invention provides an acrylic polymer emulsion containing a polymer formed by polymerizing 100% by weight in total of a monodic mixture comprising 50 to 90% by weight of an alkyl acrylate or an alkyl methacrylate, 9 to 49% by weight of a vinyl monomer of which homopolymer having a glass transition temperature Tg is not lower than 80° C., 0.2 to 10% by weight of a vinyl monomer having a carboxyl group and 0.1 to 5% by weight of a crosslinkable monomer having a molecular weight of not less than 280. The acrylic polymer emulasion of present invention provides gloves for home uses, works, examination operations, medical uses and the like which are superior in practical performances such as tensile strength, elongation, alcohol resistance, detergent resistance, oil resistance, recovering property after a stretch and wearing touch.Type: GrantFiled: September 2, 2005Date of Patent: March 18, 2008Assignee: Showa Glove Co.Inventors: Yutaka Ozawa, Nobuaki Takahashi
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Patent number: 7339002Abstract: Removable, water-whitening resistant pressure sensitive adhesive (PSA) comprising a crosslinked aqueous emulsion polymer comprising (a) at least one hydrophobic monomer; (b) at least about 2 wt. % of at least one hydrophilic monomer; and (c) at least about 5 wt. % of at least one partially hydrophilic monomer; wherein the crosslinked aqueous emulsion polymer is crosslinked with an effective amount of at least one polyfunctional aziridine crosslinker, and the wt. % of monomers (a), (b), and (c) are based on the total weight of monomers (a), (b), and (c).Type: GrantFiled: September 25, 2003Date of Patent: March 4, 2008Assignee: Cytec Surface Specialties, Inc.Inventors: Jong-Shing Guo, Augustin T. Chen, Sharon D. Trembley
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Patent number: 7247671Abstract: Aqueous crosslinkable coating composition suitable for anti-graffiti and heavy duty applications comprising: (A) an aqueous polymer emulsion comprising at least one vinyl fluoropolymer which comprises as a polymerized constituent monomer thereof (i) a fluoromonomer(s) having the formula (1) wherein R1 is CH3 or H, R2 is a per-fluorinated C1-5 alkyl group and n is 1, 2, 3 or 4, (ii) a hydroxyl functional monomer(s) and (iii) a carboxylic acid-functional monomer(s) where the vinyl fluoropolymer has a glass transition temperature Tg within the range of from ?50 to 90° C.Type: GrantFiled: July 22, 2002Date of Patent: July 24, 2007Assignee: DSM IP Assets B.V.Inventors: Gerardus Cornelis Overbeek, Jurgen Scheerder, Tijs Nabuurs
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Patent number: 7232860Abstract: An aqueous binder dispersion that includes at least one copolymer (P) containing carboxylic acid and/or carboxylate groups. The copolymer (P) includes structural units of carboxyl-free (meth)acrylic esters with a cycloaliphatic structure, and at least 25 mol % of the carboxylic acid groups of the copolymer (P) in the dispersion being present in triethanolamine-neutralized form. The aqueous binder can be used in aqueous coating materials, which can be used to coat a substrate.Type: GrantFiled: August 13, 2003Date of Patent: June 19, 2007Assignee: Bayer MaterialScience AGInventors: Martin Melchiors, Ulrich Freudenberg, Robert Reyer, Raul Pires, Sandra Grosskopf
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Patent number: 7220797Abstract: A copolymer latex for chipping-resistant aqueous paint capable of remarkably improving balance of chipping-resistance, strength of adherence with metal, water-resistance and high resistance for cycles of cool and heat is provided. This is achieved by a method for producing a copolymer latex using for chipping-resistant aqueous paint, the method comprising emulsion-polymerizing 20 to 80 parts by weight of a conjugated diene as a monomer, 0.5 to 15 parts by weight of an ethylenically unsaturated carboxylic acid as a monomer, 5 to 40 parts by weight of an aromatic vinyl compound as a monomer, 5 to 40 parts by weight of an unsaturated alkyl carboxylate as a monomer and optionally not more than 69.Type: GrantFiled: August 3, 2004Date of Patent: May 22, 2007Assignee: Nippon A&L IncorporatedInventors: Toshiyasu Nishioka, Akira Kamimura, Makoto Itagaki
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Patent number: 7217443Abstract: A binder composition is provided including a copolymer binder and a hydrophobically modified alkali soluble emulsion polymer. The binder composition is useful as a component of paper coating compositions. As provided is a coating process including the paper coating composition and a paper substrate coated with a paper coating including the binder composition.Type: GrantFiled: May 25, 2005Date of Patent: May 15, 2007Assignee: Rohm and Haas CompanyInventors: Barrett Richard Bobsein, Jin-Chih Chiang, Scott Lind Egolf
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Patent number: 7214737Abstract: The invention concerns an aqueous polymer dispersion, prepared from a monomer composition comprising: (A) 50 to 99.99 parts by weight of at least an acrylic or methacrylic ester derived from acrylic or methacrylic acid and an alcohol having 1 to 12 carbon atoms; (B) 0 to 40 parts by weight of at least a vinylaromatic monomer; (C) 0 to 5 parts by weight of at least a short-chain ?,?-unsaturated mono- or polycarboxylic acid; (D) 0.01 to 5 parts by weight of at least an ethylenically unsaturated alpha-beta monomer compound (D), comprising at least a carbonyl group having at least a hydrogen atom borne in position alpha of said carbonyl (diacetone acrylamide), for 100 parts by weight of monomers (A)+(B)+(C)+(D), 80 to 98 wt. % of monomer components having been added to a reaction medium already containing a totally or partly polymerized pre-emulsion representing 2 to 20 wt. % of the final global proportion of monomer components in the dispersion finally obtained.Type: GrantFiled: September 6, 2002Date of Patent: May 8, 2007Assignee: Cray Valley Kunstharze GmbHInventors: Jordi Albalat Perez, Carme Font Panades, Werner Ullenboom
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Patent number: 7211622Abstract: An object of the present invention is to provide an aqueous resin composition and its uses, wherein the aqueous resin composition combines the blocking resistance and the frost damage resistance and thereby can secure the durability over a long period of time even under circumstances where a severe temperature cycle is present. As a means of achieving this object, the aqueous resin composition according to the present invention is an aqueous resin composition comprising an acrylic resin emulsion and a crosslinking agent as essential components, with the aqueous resin composition being characterized in that, when a coating film is formed from the aqueous resin composition, the formed coating film exhibits an elongation ratio (E (%)) that satisfies a specific relational expression along with the glass transition temperature (TgT (° C.)) of the acrylic resin in the emulsion.Type: GrantFiled: May 7, 2004Date of Patent: May 1, 2007Assignee: Nippon Shokubai Co., Ltd.Inventors: Masaya Uchida, Kanji Nakao, Yoshiyuki Yokota
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Patent number: 7211640Abstract: The present invention relates to an emulsion type adhesive applicable for over-laminating films, the preparation and the use thereof. The emulsion type adhesive comprises: (a) 60 to 99.5 parts per hundred of monomers of one or more alkyl acrylates containing 4-12 carbon atoms on the alkyl group; (b) 0.5 to 40 parts per hundred of monomers of an alkyl acrylate containing 1-3 carbon atoms in the alkyl group or an alkyl methacrylate containing 1-6 carbon atoms in the alkyl group; (c) 0.1 to 5 parts per hundred of monomers of dicarboxylic acids; (d) 1 to 5 parts per hundred of a reactive surfactant; (e) 0.1 to 15 parts per hundred of an organic acid vinyl ester; and (f) 100 parts per hundred of soft water, (a) and (b) are 100 parts by hundred, while (c), (d), (e) and (f) are calculated based on the total weight of (a)+(b). The products of this invention have excellent properties.Type: GrantFiled: December 12, 2003Date of Patent: May 1, 2007Assignee: Four Pillars Enterprise Co., Ltd.Inventors: Bin-Yen Yang, Chi-Lin Kao, Chih-Kuo Wan, Shu-Hei Lin, Shih-Shang Lo
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Patent number: 7199185Abstract: Reactive polymeric surfactants are disclosed, and their use in processes for preparation of microcapsules, and in stabilising emulsions. The surfactants are random graft polymers or block copolymers which contain both hydrophobic and hydrophilic units and in which the hydrophobic unit includes a hydrophilic cross-linking unit which reacts with (a) a wall forming ingredient in a microencapsulation process, or (b) an ingredient in the disperse phase of an emulsion.Type: GrantFiled: June 10, 2002Date of Patent: April 3, 2007Assignee: Syngenta LimitedInventors: Alexander Mark Heming, Patrick Joseph Mulqueen, Herbert Benson Scher, Ian Malcolm Shirley
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Patent number: 7173085Abstract: This invention relates to aqueous emulsions comprising a water-dispersible copolymer which is non-dispersible in aqueous solutions containing 0.5% or more of an inorganic salt, comprising acidic ethylenically unsaturated monomers and ethylenically unsaturated monomers. The acidic ethylenically unsaturated monomers and the ethylenically unsaturated monomers are defined herein. The present invention also pertains to emulsion polymerization methods for making the aqueous emulsions with or without a surfactant.Type: GrantFiled: January 21, 2004Date of Patent: February 6, 2007Assignee: Celanese International CorporationInventor: Michael W. Eknoian
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Patent number: 7169846Abstract: Pressure sensitive adhesive compositions having enhanced resistance to water-whitening comprising an aqueous emulsion polymer are disclosed. The polymer comprises the polymerization reaction product of a polymerizable aqueous emulsion comprising: (i) at least one hydrophobic alkyl acrylate or alkyl methacrylate ester of an alcohol, (ii) at least about 1 wt. % of at least one hydrophilic monomer, (iii) at least about 5 wt. % of at least one partially hydrophilic alkyl acrylate or alkyl methacrylate ester of an alcohol, and (iv) a water-soluble or water-dispersible polymerizable surfactant selected from compounds having a terminal allyl amine moiety, substituted phenyl compounds having at least one alkenyl substituent, polyoxyalkylene-1-(allyloxymethyl) alkyl ether sulfate salts, or mixtures thereof, and the average particle size of the polymer is less than or equal to 200 nm. Also disclosed are processes for preparing same.Type: GrantFiled: May 10, 2002Date of Patent: January 30, 2007Assignee: Cytec Surface Specialties, Inc.Inventors: Augustin T. Chen, Jong-Shing Guo, Tibor Pernecker
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Patent number: 7138472Abstract: A high molecular weight, water-soluble polymer comprising pendant salicylic acid groups and having a weight average molecular weight of at least about 2,000,000 daltons and use of the polymer for clarifying red mud-containing liquors generated in the Bayer process for the recovery of alumina from bauxite.Type: GrantFiled: February 24, 2003Date of Patent: November 21, 2006Assignee: Nalco CompanyInventors: Murat Quadir, Everett C. Phillips, Larry E. Brammer, Jr., Robert P. Mahoney, John D. Kildea, Manian Ramesh, John T. Malito
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Patent number: 7037975Abstract: The invention provides a process for preparing aqueous polymer dispersions having a high solids content of more than 60% by polymerizing one or more ethylenically unsaturated monomers by means of free-radically initiated aqueous emulsion polymerization in the presence of from 0.1 to 5.0% by weight of emulsifier, based on the overall weight of the monomers, and in the presence of initiator, wherein the emulsifier in an amount of from 0.001 to 0.5% by weight, based on the overall weight of the water in the initial charge, is included in the initial charge together with a fraction of from 1 to 10% by weight of the monomers, based on the overall weight of the monomers, before the beginning of polymerization, and the remainder of emulsifier and the remainder of monomers are metered in after the beginning of polymerization.Type: GrantFiled: June 11, 2002Date of Patent: May 2, 2006Assignee: Wacker Chemie AGInventor: Abdulmajid Hashemzadeh
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Patent number: 6995207Abstract: A removable, plasticizer resistant pressure sensitive composition that is particularly useful for PSA applications on plasticizer containing vinyl films is provided. The pressure sensitive adhesive comprises: (a) at least one hydrophobic monomer; (b) about 0.2 to about 10 wt. % of at least one hydrophilic monomer; (c) about 1 to about 40 wt. % of one partially hydrophilic monomer (d) an effective amount of a crosslinker selected from diallyl maleate or a compound represented by the formula: wherein R is selected from hydrogen, methyl, or ethyl, and R? is selected from vinyl, allyl, or methallyl; wherein the pressure sensitive adhesive does not contain a plasticizer.Type: GrantFiled: March 31, 2003Date of Patent: February 7, 2006Inventors: Augustin T. Chen, Hui Liu, Leo Ternorutsky
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Patent number: 6992121Abstract: Aqueous emulsion of a polymodal multistage polymeric material, wherein: (i) at least 50% of the polymodal multistage polymeric material comprises the polymers of at least two polymerisation stages having a Tg difference of ?20° C., more preferably ?40° C., and most preferably ?60° C.; (ii) at least 50% of the polymodal multistage polymeric material comprises the polymers of at least two polymerisation stages having a Dw differing by ?50 nm, preferably ?80 nm and more preferably ?100 nm; and (iii) the means to form at least one of the differing Tg's in (i) and at least one of the differing Dw's in (ii) are carried out in different stages of the multistage polymerisation to form the polymeric material. The polymer emulsion is useful for protective coatings, printing inks, overprint lacquer formulations, polishes, varnishes, sealants, paint formulations and adhesives.Type: GrantFiled: November 16, 2000Date of Patent: January 31, 2006Assignee: DSM IP Assets B.V.Inventors: Antonius Carolus Ida Adrianus Peters, Gerardus Cornelis Overbeek
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Patent number: 6979711Abstract: An improved emulsion polymerization process for producing an oil and water repellent finish for textiles wherein the improvement comprises polymerization in an aqueous solution containing 0.1 to 4.9% by weight of dipropylene-glycol monomethyl ether acetate or propylene glycol diacetate relative to water is disclosed.Type: GrantFiled: October 4, 2004Date of Patent: December 27, 2005Assignee: E. I. du Pont de Nemours and CompanyInventor: Justine Gabrielle Franchina
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Patent number: 6964991Abstract: Pressure sensitive adhesive compositions having enhanced resistance to water-whitening comprising an aqueous emulsion polymer are disclosed. The polymer comprises the polymerization reaction product of a polymerizable aqueous emulsion comprising: (i) a hydrophobic monomer mixture of at least one alkyl acrylate or alkyl methacrylate ester of an alcohol wherein the alkyl portion of the alcohol is linear or branched and contains at least 4 carbon atoms, and at least one styrenic monomer, wherein the styrenic monomer is up to about 30 wt. % of the total hydrophobic monomer mixture, (ii) at least about 1 wt. % of at least one hydrophilic monomer, (iii) at least about 5 wt.Type: GrantFiled: May 23, 2002Date of Patent: November 15, 2005Assignee: Surf Chip, Inc.Inventors: Augustin T. Chen, Jong-Shing Guo, Tibor Pernecker
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Patent number: 6939934Abstract: Terpolymer compositions of vinyl caprolactam (VCL), dimethylaminopropyl methacrylamide (DMAPMA) and hydroxyethyl methacrylate (HEMA) are described to coat substrates for use in computer printers, and provide advantageous print quality thereon.Type: GrantFiled: August 26, 2004Date of Patent: September 6, 2005Assignee: ISP Investments Inc.Inventors: Stephen L. Kopolow, David K. Hood, Drupesh Patel
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Patent number: 6930143Abstract: An acrylic emulsion is disclosed. The emulsion comprises from about 30% to about 90% by weight of water, about 10% to about 70% by weight of an acrylic polymer, about 0.2% to about 10% by weight of a emulsifying agent, and up to 20% by weight of an organic solvent. The acrylic polymer contains from about 20% to about 80% by weight of recurring units of t-butyl acrylate or methacrylate. Latex coatings formulated from the acrylic emulsion show significantly improved resistance to moisture and corrosion.Type: GrantFiled: November 1, 2001Date of Patent: August 16, 2005Assignee: Arco Chemical Technology, L.P.Inventors: Stephen H. Harris, Daniel B. Pourreau
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Patent number: 6897255Abstract: Novel latex or emulsion compositions containing internally plasticizing and crosslinkable long-chain alkenol ester monomers are disclosed and claimed. Preferred embodiments include latex formed from acrylate or methacrylate esters of long-chain alkenols. A process for the synthesis of the latex composition is also disclosed, which involves (a) esterification of a long-chain alkenol with an ethylenically unsaturated carboxylic acid; (b) polymerization of the ethylenically unsaturated ester in an aqueous phase with at least one other copolymerizable monomer; and (b) blending of so formed polymer with at least one drier and a surfactant to form the novel latex or emulsion compositions. These compositions form films at low minimum film forming temperatures (MFT) ranging from ?5 to 10° C. and cure to above ambient glass transition (Tg) polymers without the use of traditional organic cosolvents which contribute to environmental pollution via volatile organic compounds (VOCs) emissions.Type: GrantFiled: December 14, 1999Date of Patent: May 24, 2005Assignee: University of Southern MississippiInventors: Shelby Freland Thames, Kamlesh Gopichand Panjnani, Olan Stanley Fruchey
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Patent number: 6884840Abstract: A process for preparing hot-melt pressure-sensitive adhesives from aqueous dispersions based on polyacrylate, and pressure-sensitively adhesive articles produced therefrom, which comprises producing highly concentrated aqueous dispersions with polymer contents between 68% by weight and 87% by weight of gel-free, molecularly-dispersely meltable polymer particles with an at least bimodal size distribution in size ranges between 0.5 ?m and 1000 ?m Ø.Type: GrantFiled: March 22, 2001Date of Patent: April 26, 2005Assignee: tesa AGInventors: Peter Gleichenhagen, Annemarie Müller
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Patent number: 6864335Abstract: In forming pressure sensitive adhesive microspheres by copolymerizing a non-ionic monomer of an alkyl acrylate or alkyl methacrylate ester of a non-tertiary alcohol and an ionic monomer copolymerizable with said non-ionic monomer, non-free radically polymerizable acid is present during the polymerization to promote formation of solid rather than hollow microspheres and to reduce residual unconverted ionic monomer. These microspheres exhibit reduced adhesive transfer in downstream use as a repositionable pressure sensitive adhesive. A water soluble initiator is optionally added to the polymerization mixture after achieving about 90% conversion of the non-ionic monomer to further reduce residual unconverted ionic monomer.Type: GrantFiled: June 21, 2001Date of Patent: March 8, 2005Assignee: Surf Chip, Inc.Inventors: Jong-Shing Guo, Sharon D. Trembley
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Patent number: 6849685Abstract: A method of making an absorbent binder composition includes combining a first aqueous monomer solution including a reducing polymerization initiator with a second aqueous monomer solution including an oxidizing polymerization initiator to form a binder composition having post application, moisture-induced crosslinking capability. The first aqueous monomer solution includes a monoethylenically unsaturated monomer and an ethylenically unsaturated monomer that contains an alkoxysilane functionality. The second aqueous monomer solution includes a monoethylenically unsaturated monomer. The monoethylenically unsaturated monomer included in the first and second aqueous monomer solutions may be carboxylic, sulphonic, or phosphoric acids or salts or a combination thereof. The ethylenically unsaturated monomer may be an acrylate or methacrylate. Crosslinking of the resulting binder composition is induced by removal of water.Type: GrantFiled: December 20, 2002Date of Patent: February 1, 2005Assignee: Kimberly-Clark Worldwide, Inc.Inventors: Dave Allen Soerens, Jason Matthew Laumer
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Patent number: 6822014Abstract: An aqueous coating composition useful as a floor polishing agent is disclosed. The composition comprises (A) an aqueous dispersion of a copolymer obtained by the emulsion polymerization of (a) an ethylenically unsaturated carboxylic acid monomer, (b) a (meth)acrylic acid alkyl ester monomer, and (c) other monomers polymerizable with the monomers (a) and (b), (B) an unsaturated monomer curable with energy rays, and (C) a photoinitiator. The floor polishing agent containing the aqueous coating composition exhibits excellent delamination properties and dry buff applicability.Type: GrantFiled: April 25, 2002Date of Patent: November 23, 2004Assignee: JSR CorporationInventor: Minoru Katou
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Publication number: 20040192831Abstract: A removable, plasticizer resistant pressure sensitive composition that is particularly useful for PSA applications on plasticizer containing vinyl films is provided. The pressure sensitive adhesive comprises: (a) at least one hydrophobic monomer; (b) about 0.2 to about 10 wt. % of at least one hydrophilic monomer; (c) about 1 to about 40 wt.Type: ApplicationFiled: March 31, 2003Publication date: September 30, 2004Inventors: Augustin T. Chen, Hui Liu, Leo Ternorutsky
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Patent number: RE39936Abstract: The present invention relates to crosslinked, water-soluble or water-dispersible polyurethanes of A) at least one water-soluble or water-dispersible polyurethane prepolymer having terminal isocyanate groups of a) at least one compound having a molecular weight in the range from 56 to 300 which contains two active hydrogen atoms per molecule, b) at least one polymer containing two active hydrogen atoms per molecule, c) at least one compound which contains two active hydrogen atoms and at least one ionogenic or ionic group per molecule, d) at least one diisocyanate, B) at least one polymer containing groups which are reactive toward isocyanate groups, chosen from hydroxyl, and primary and secondary amino and/or carboxyl groups, or the salts thereof.Type: GrantFiled: June 24, 2005Date of Patent: December 4, 2007Assignee: BASF AktiengesellschaftInventors: Son Nguyen Kim, Axel Sanner, Peter Hössel, Volker Schehlmann
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Patent number: RE41615Abstract: The present invention relates to crosslinked, water-soluble or water-dispersible polyurethanes of A) at least one water-soluble or water-dispersible polyurethane prepolymer having terminal isocyanate groups of a) at least one compound having a molecular weight in the range from 56 to 300 which contains two active hydrogen atoms per molecule, b) at least one polymer containing two active hydrogen atoms per molecule, c) at least one compound which contains two active hydrogen atoms and at least one ionogenic or ionic group per molecule, d) at least one diisocyanate, B) at least one polymer containing groups which are reactive toward isocyanate groups, chosen from hydroxyl, and primary and secondary amino and/or carboxyl groups, or the salts thereof.Type: GrantFiled: June 24, 2005Date of Patent: August 31, 2010Assignee: BASF SEInventors: Son Nguyen Kim, Axel Sanner, Peter Hössel, Volker Schehlmann