Two Or More Carboxylic Acids Or Derivatives Patents (Class 524/833)
  • Patent number: 4388438
    Abstract: The method of preparing aqueous dispersions of copolymers of styrene dibutyl maleate and acrylic or methacrylic acid or monobutyl maleate consists in adding a monomer mixture comprising styrene in the amount of 40-90% by weight, dibutyl maleate in the amount of 10-60% by weight acrylic or methacrylic acid or monobutyl maleate in the amount of 1.0-10.0% by weight in relation to the sum of styrene monomer and dibutyl maleate into the emulsion water known constituents such as:ionic emulsifier - non-ionic emulsifier, buffer, sodium acrylate, N-methylolmethacrylamide to which, prior to polymerization, an alkylene glycol comprising 2-6 carbon atoms in the alkylene group is added. The alkylene glycol is added in the amount of 1-6% by weight in relation to the sum of styrene monomer and dibutyl maleate while, the ratio of alkylene glycol to the methacrylic acid or monobutyl maleate contained in the monomer mixture is 1:0.2-2. The polymerization process is conducted at a temperature of 70.degree.-90.degree. C.
    Type: Grant
    Filed: January 6, 1981
    Date of Patent: June 14, 1983
    Assignee: Osrodek Badaw Cze-Rozwojowy Kauczukow I Tworzyw Winylowych
    Inventors: Maria Knypl, Eugeniusz Knypl, Marian Starzak, Ewa Mieczkowska, Urszula Pawlus, Romuald Palubicki, Mieczyslaw Ficek, Jozef Goldynia
  • Patent number: 4371636
    Abstract: A process for the preparation of copolymer dispersions having a narrow particle size distribution, and exhibiting dilatant flow over a broad range of concentrations, by emulsion copolymerization of from 1 to 10% by weight, based on total monomers, of .alpha.,.beta.
    Type: Grant
    Filed: July 1, 1981
    Date of Patent: February 1, 1983
    Assignee: BASF Aktiengesellschaft
    Inventors: Dieter Distler, Hans Wolf, Gerhard Welzel
  • Patent number: 4365040
    Abstract: Strongly adhering aqueous plastic dispersions based on copolymers of olefinically unsaturated compounds, which are particularly suitable as binding agents for paints and lacquers and as adhesives, and which are distinguished by their good wet adhesion are described. This is achieved by the inclusion by polymerization of from 0.2% to 7% by weight, based on the total weight of the monomers, of vinyl and/or allyl diacetylacetate having the formula:CH.sub.2 .dbd.CH--(CH.sub.2).sub.n --O--CO--CH(CO--CH.sub.3).sub.2wherein n is 0 or 1, in the production of copolymers of the invention in an aqueous emulsion.
    Type: Grant
    Filed: October 1, 1980
    Date of Patent: December 21, 1982
    Assignee: Wacker-Chemie GmbH
    Inventors: Herbert Eck, Robert Singer
  • Patent number: 4356229
    Abstract: This invention concerns a nonwoven fabric particularly adapted for use as a diaper coverstock. The fabric consists essentially of fibers and a binder wherein at least 50%, by weight, of the fibers are hydrophobic fibers. The binder comprises a water insoluble, hydrophobic, emulsion copolymer of ethylenically unsaturated monomers comprising (A) 1 to 8% by weight of a monoethylenically unsaturated carboxylic acid, or a mixture thereof, (B) 50 to 75% by weight of a C.sub.4 to C.sub.8 alkyl acrylate or a mixture thereof, and (C) 20 to 49% by weight of methyl methacrylate, styrene, .alpha.-methyl styrene or a mixture thereof. The fabric has sufficient wet tensile strength for use as a diaper coverstock.
    Type: Grant
    Filed: October 20, 1980
    Date of Patent: October 26, 1982
    Assignee: Rohm and Haas Company
    Inventors: John G. Brodnyan, Walter G. De Witt, III, Robert A. Gill, Gary D. Stelling
  • Patent number: 4350622
    Abstract: An aqueous dispersion of a vinylidene chloride copolymer resin which, when coated onto a synthetic resinous film substrate, has the combined properties of: (1) good adhesion to the substrate; (2) good adhesion of a printing ink to the coating; (3) excellent barrier to gases (especially oxygen) and water vapor; and (4) a high resistance to a boiling water treatment. The dispersion must contain methacrylic acid in an amount of from about 1.times.10.sup.-4 to about 3.times.10.sup.-4 moles per gram of polymer solids content. The dispersion must also have a molar ratio of acrylonitrile to methyl methacrylate of from about 0 to 1 to about 1 to 1. A limited portion of the amount of methacrylic acid is contained in the aqueous phase. The remaining amount of methacrylic acid is polymerized with the vinylidene chloride.
    Type: Grant
    Filed: August 10, 1981
    Date of Patent: September 21, 1982
    Assignee: Asahi-Dow Limited
    Inventors: Kazuhiko Hiyoshi, Norio Matsuura, Michiharu Matsugichi, Norio Onofusa, Tadao Nishikage
  • Patent number: 4342676
    Abstract: A method for producing latices of copolymers of butyl acrylate and 1-methyacrylate-1-tert-butyl peroxy ethane resides in the emulsion copolymerization of butyl acrylate and 1-methacrylate-1-tert-butyl peroxy ethane carried out by prepolymerizing of butyl acrylate up to a conversion degree of 90-100% followed by introducing 1-methacrylate-1-tert-butyl peroxy ethane into the reaction mass. For a redox system, use is made of potassium persulfate and sodium metabisulfate.
    Type: Grant
    Filed: November 10, 1980
    Date of Patent: August 3, 1982
    Inventors: Sergei S. Ivanchev, Valery N. Pavljuchenko, Zinaida M. Pessina, Elena D. Vasilieva
  • Patent number: 4341679
    Abstract: An aqueous latex of a copolymer derived from defined relative proportions of (i) vinylidene chloride, (ii) vinyl chloride, (iii) an alkyl acrylate or methacrylate and (iv) an unsaturated carboxylic acid forms stable protective films on a variety of substrates.
    Type: Grant
    Filed: December 12, 1977
    Date of Patent: July 27, 1982
    Assignee: Imperial Chemical Industries Limited
    Inventors: Anthony J. Burgess, David L. Gardner
  • Patent number: 4340648
    Abstract: Single-package coating or ink composition of pH 7 to 12 comprising a reaction product of a binder resin and a scavenging agent which reacts with anions of the initiator used to prepare the binder resin, the binder resin has a Tg of 20.degree. to 70.degree. C., is prepared in an aqueous medium devoid of emulsifiers, and is a polymer of an ethylenically unsaturated acid of 3 to 10 carbon atoms and an acrylic monomer(s) selected from alkyl acrylates and methacrylates containing 4 to 24 carbon atoms, amount of the acid being 0 to 5 parts per 100 parts of the acrylic monomer(s).
    Type: Grant
    Filed: June 30, 1980
    Date of Patent: July 20, 1982
    Assignee: The B. F. Goodrich Company
    Inventors: James A. Conrady, William J. Driscoll
  • Patent number: 4336177
    Abstract: A process is described for making sterically stabilized non-aqueous dispersions of composite polymer microparticles, in which (1) monomers including at least one crosslinking monomer are polymerized in an aqueous medium at a temperature at least 10.degree. higher than the glass transition temperature of the polymer to be formed, in the presence of a block or graft copolymer stabilizing agent, under conditions such that there is at no time present a separate monomer phase, (2) further monomers, not including any crosslinking monomer, are polymerized in the dispersion thus obtained, the presence of a separate monomer phase again being avoided, and (3) the microparticles are transferred from the resulting dispersion into a non-aqueous medium which is a solvent for the non-crosslinked polymer generated in (2). The microparticles are of value for incorporation into coating compositions the main film-forming constituent of which is compatible with the non-crosslinked component of the particles.
    Type: Grant
    Filed: December 4, 1980
    Date of Patent: June 22, 1982
    Assignee: Imperial Chemical Industries Limited
    Inventors: Alan J. Backhouse, Charles Bromley, Morice W. Thompson
  • Patent number: 4336172
    Abstract: Aqueous dispersions containing from 30% to 70% by weight of cross-linkable copolymers based on esters of (meth)acrylic acid comprising esters of (meth)acrylic acid and/or styrene, and other ethylenically-unsaturated compounds copolymerizable therewith and from 1% to 15% by weight based on the total weight of the copolymer, of allyl esters of .alpha.-hydroxycarboxylic acids. These dispersions can be used as a base of stoving enamels, which can be hardened to obtain coats of great surface hardness and great flexibility on metals.
    Type: Grant
    Filed: June 11, 1980
    Date of Patent: June 22, 1982
    Assignee: Wacker-Chemie GmbH
    Inventors: Klaus Marquardt, Herbert Eck, Werner Bathelt
  • Patent number: 4322328
    Abstract: Sterically stabilized aqueous polymer dispersions of at least 20% solids content are made by free radical-initiated polymerization of monomers in an aqueous medium at a temperature at least 10.degree. C. higher than the glass transition temperature of the polymer to be formed, in the presence of a compound which is soluble in the aqueous medium and contains in the molecule a polymeric component of molecular weight at least 1000 which is solvatable by the aqueous medium and an unsaturated grouping which can copolymerize with the monomers, the conditions being such that there is at no time present a separate monomer phase. The dispersions are useful as a basis of improved coating compositions.
    Type: Grant
    Filed: December 7, 1979
    Date of Patent: March 30, 1982
    Assignees: Imperial Chemical Industries Limited, Dulux Australia Limited
    Inventors: Clive W. Graetz, Morice W. Thompson