Hetero Ring Contains Sulfur And At Least One Diverse Hetero Atom Patents (Class 524/83)
  • Patent number: 4465829
    Abstract: Addition of particular low molecular weight polyisobutylene to natural rubber compounds reduces hysteresis, increases blow-out time and lowers compression set.
    Type: Grant
    Filed: September 6, 1983
    Date of Patent: August 14, 1984
    Assignee: The Firestone Tire & Rubber Company
    Inventor: Daniel F. Graves
  • Patent number: 4444676
    Abstract: Polyoxyalkylene polyether polyols are stabilized against oxidative degradation by incorporating therein a synergistic stabilizing composition containing (1) a mixture of butylated phenols consisting of 2-tertiary butyl phenol, 3,5-ditertiary butyl-4-hydroxyhydrocinnamate and 1,6-hexamethylene bis(3,5-ditertiary-butyl-4-hydroxyhydrocinnamate) or tetrakis [methylene(3,5-ditertiary butyl-4-hydroxyhydrocinnamate)] methane (2) a p,p'-dialkyldiphenylamine such as p,p'-dioctyldiphenylamine and (3) a phenothiazine compound. Polyurethane foams are stabilized against scorching when the stabilized polyols are utilized in the foam preparation or the stabilizing composition is added with other reactants.
    Type: Grant
    Filed: April 1, 1983
    Date of Patent: April 24, 1984
    Assignee: Atlantic Richfield Company
    Inventors: Gary L. Statton, James M. Gaul
  • Patent number: 4433085
    Abstract: A triazolidine-3,5-dione/formaldehyde/amine condensate is disclosed of the formula ##STR1## in which wherein the terms R.sup.1, R.sup.2 and R.sup.5 are defined hereinafter in the specificationa process for the preparation of such condensate by reaction of a triazolidine-3,5-dione with formaldehyde and a suitable nitrogen compound and the use of the condensate as a flame-proofing agent for thermoplastics, especially polyamide and as an auxiliary for modifying polymeric substances.
    Type: Grant
    Filed: June 29, 1981
    Date of Patent: February 21, 1984
    Assignee: Bayer Aktiengesellschaft
    Inventors: Ludwig Rottmaier, Rudolf Merten
  • Patent number: 4430466
    Abstract: In a sulfur-curable conjugated diene rubber compound formulation containing a silica reinforcing filler and a mercaptoalkyltrialkoxysilane coupling agent, the improvement which comprises increasing time-to-scorch by employing benzothiazyl sulfenamide accelerators at levels of above at least 1.5 phr.
    Type: Grant
    Filed: June 10, 1982
    Date of Patent: February 7, 1984
    Assignee: Phillips Petroleum Company
    Inventor: William T. Cooper
  • Patent number: 4427817
    Abstract: The use of open-chain acetals or ketals corresponding to the following general formula ##STR1## as non-discoloring anti-ozonants for natural and/or synthetic rubber.
    Type: Grant
    Filed: April 6, 1982
    Date of Patent: January 24, 1984
    Assignee: Bayer Aktiengesellschaft
    Inventors: Dieter W. Bruck, Werner Jeblick, Heinrich Konigshofen, Ernst Roos, Lother Ruetz
  • Patent number: 4420577
    Abstract: Self-extinguishing polyolefin compositions consisting of:(1) from 52 to 96.55% by weight of at least one olefin polymer or copolymer;(2) from 3 to 30% by weight of a nitrogenous compound selected from amongst 1,3,5-triazines, urea and dicyandiamide;(3) from 0.3 to 3% by weight of a free-radical promoting compound selected from amongst 2,3-dimethyl-2,3-diphenylbutane and 2,3-dimethyl-2,3-diphenyl-hexane;(4) from 0.15 to 15% by weight of a compound of formula(R.sub.1 --S).sub.n R.sub.3 or (II) R.sub.2 .dbd.S, (I)wherein R.sub.1 and R.sub.2 are imidazol, uracyl, alkyleneurea or benzotriazol radicals, R.sub.3 =H, or a metal of Group II (A) or (B), or aluminum.
    Type: Grant
    Filed: April 27, 1982
    Date of Patent: December 13, 1983
    Assignee: Montedison S.p.A.
    Inventors: Guido Bertelli, Renato Locatelli
  • Patent number: 4417012
    Abstract: Additives for rubber compositions, giving vulcanisates having improved retention of optimum physical properties, are compounds containing two or more groups of the formula --S--SO.sub.2 R linked by an organic bridging group, or polymers containing two or more groups of the formula --S--SO.sub.2 R attached to an organic polymer chain, where R represents (a) a radical OM where M is a monovalent metal, the equivalent of a multivalent metal, a monovalent ion derived by the addition of a proton to a nitrogenous base, or the equivalent of a multivalent ion derived by the addition of two or more protons to a nitrogenous base, or (b) an organic radical selected from aliphatic, cycloaliphatic, aromatic and heterocyclic radicals, and radicals which are combinations of any two or more such radicals.
    Type: Grant
    Filed: June 30, 1982
    Date of Patent: November 22, 1983
    Assignee: Monsanto Europe S.A.
    Inventor: Philippe G. Moniotte
  • Patent number: 4409346
    Abstract: Compounds of the formula I ##STR1## wherein R.sub.1 is hydrogen, C.sub.1 -C.sub.18 alkyl, C.sub.5 -C.sub.12 cycloalkyl, phenyl or C.sub.7 -C.sub.9 phenylalkyl and R.sub.2 is hydrogen or C.sub.1 -C.sub.18 alkyl, or, if R.sub.1 is hydrogen, R.sub.2 is a divalent 1,1,3,3-tetramethylpropylene radical fused in the 2-position and 3-position or the 9-position and 10-position, and X is sulfur or a group --CH(R).sub.3 --, in which R.sub.3 is hydrogen or a radical of the formula II --CH(R.sub.4)--CH(R.sub.5)SR.sub.6, and each of R.sub.4 and R.sub.5 independently is hydrogen or C.sub.1 -C.sub.6 alkyl and R.sub.6 is C.sub.1 -C.sub.20 alkyl, while the alkyl group can be interrupted by one or more sulfur atoms, and A is a primary or secondary aliphatic or alicyclic, aromatic or araliphatic amine which contains substituents of the same type or mixed substituents, or a heterocyclic amine or a hydrazine derivative. These compounds are useful stabilizers for organic material.
    Type: Grant
    Filed: December 15, 1980
    Date of Patent: October 11, 1983
    Assignee: Ciba-Geigy Corporation
    Inventor: Michael Rasberger
  • Patent number: 4407991
    Abstract: Oxalic acid, alone or in combination with phenothiazine or with phenothiazine and 4-chloro-2-nitrophenol, increases the storage life of vinyl ester resins or unsaturated polyesters without adversely suppressing the exotherm or affecting their curability.
    Type: Grant
    Filed: September 29, 1982
    Date of Patent: October 4, 1983
    Assignee: The Dow Chemical Company
    Inventor: Virginia B. Messick
  • Patent number: 4405732
    Abstract: Nylon polymer compositions are rendered flame retardant by incorporating therein an effective flame retardant amount of a salt of 2,5-dimercapto-1,3,4-thiadiazole and a metal from the group consisting of Zn, Mn, Ba, Ni, Co, Fe, Cu, Mo, and Cr.
    Type: Grant
    Filed: March 15, 1982
    Date of Patent: September 20, 1983
    Assignee: Occidental Chemical Corporation
    Inventors: Li-Chung Chao, Daniel J. Scharf
  • Patent number: 4366270
    Abstract: A method for the uniform blending of additives into thermoplastic synthetic resins. A solution or finely divided dispersion of the additive is produced in a polymerizable cyclic ester of the general formula: ##STR1## wherein R represents respectively hydrogen or an alkyl group of 1-18 carbon atoms,A represents a --O-- or --COO-- group,x and y represent integers from 1 to 15, andz represents 0 or 1.This solution or dispersion, optionally after polymerization of the cyclic ester, is admixed to the thermoplastic synthetic resin at the end of its manufacturing process or in a subsequent processing stage.
    Type: Grant
    Filed: November 21, 1979
    Date of Patent: December 28, 1982
    Assignee: Chemische Werke Huls A.G.
    Inventor: Jorn Ruter
  • Patent number: 4356274
    Abstract: Smoke suppressed rigid polyurethane foams are prepared from a reaction mixture comprising as the smoke suppressant additive a metal salt of a: dialkyl dithiocarbamate, a mercaptobenzothiazole, a 2,5-dimercapto-1,3,4-thiadiazole, a mercaptotriazine, a hydroxy thiophenol or an aliphatic dimercapto compound of 2 to 10 carbons.
    Type: Grant
    Filed: April 16, 1979
    Date of Patent: October 26, 1982
    Assignee: Pennwalt Corporation
    Inventors: Stanley R. Sandler, Jeffrey D. Miano
  • Patent number: 4346187
    Abstract: Trityl compounds wherein a triphenylmethyl group is attached to oxygen, divalent sulfur, trivalent nitrogen or a halogen are effective synergists for organic bromine flame retardants in polypropylene compositions.
    Type: Grant
    Filed: March 8, 1979
    Date of Patent: August 24, 1982
    Assignee: Borg-Warner Chemicals, Inc.
    Inventor: George M. Nichols
  • Patent number: 4341896
    Abstract: 1-Hydroxy-4-heteroarylaminoanthraquinones of the formula ##STR1## wherein Q is for example one of the two groups of the formulae ##STR2## are most suitable for the mass coloration of polyester. They are distinguished in particular by good lightfastness and purity of shade. Further definitions of Q will be found in claim 1.
    Type: Grant
    Filed: May 19, 1980
    Date of Patent: July 27, 1982
    Assignee: Ciba-Geigy Corporation
    Inventor: Max Jost
  • Patent number: 4340735
    Abstract: Isoindoline colorants of the formula ##STR1## where R.sup.1 is the radical of a 5-membered or 6-membered heterocyclic unsaturated ring, which may or may not be fused to a benzo ring, X is ##STR2## R.sup.2 and R.sup.3 independently of one another are hydrogen, C.sub.1 -C.sub.4 -alkyl, benzyl, phenyl or 1-naphthyl, and R.sup.1, the phenyl and naphthyl radicals, and the ring A may or may not be substituted by groups which do not confer solubility.In surface coatings, printing inks and plastics the novel colorants give yellow to red or brown very deep colorations which have good lightfastness, and fastness to weathering and to overspraying.
    Type: Grant
    Filed: January 22, 1981
    Date of Patent: July 20, 1982
    Assignee: BASF Aktiengesellschaft
    Inventors: Wolfgang Lotsch, Reinhard Kemper
  • Patent number: 4336323
    Abstract: A light insensitive imageable layer comprising a synthetic polymeric binder, a dye, a nitrate salt, and an acid.
    Type: Grant
    Filed: October 22, 1980
    Date of Patent: June 22, 1982
    Assignee: Minnesota Mining and Manufacturing Company
    Inventor: John M. Winslow
  • Patent number: 4325851
    Abstract: This invention relates to water-activatable hot-melt adhesives. More specifically, it relates to such adhesives having non-blocking qualities at high humidity at higher pressures than have been used heretofor.
    Type: Grant
    Filed: October 24, 1980
    Date of Patent: April 20, 1982
    Inventors: Herman Colon, Albert Maletsky
  • Patent number: 4320046
    Abstract: Ethylene or propylene polymers are dyed by dispersing a small quantity of a copolymer of a C-14 or higher alpha-olefin and maleic anhydride therein and subsequently treating the composition with an aqueous solution of a basic dye stuff such as Malachite Green.
    Type: Grant
    Filed: September 15, 1980
    Date of Patent: March 16, 1982
    Assignee: Gulf Oil Corporation
    Inventor: Richard H. Havens