Solid Polymer From Ethylenic Monomer Only, Said Polymer Formed In The Presence Of A Nonreactant Material Patents (Class 524/849)
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Publication number: 20110081541Abstract: A one part, storage stable polymerizable formulation is provided that includes an ethenically unsaturated polymerizable compound intermixed with a free radical polymerization initiator and an organic solvent. The organic solvent provides storage stability and upon evaporation of the solvent, the rate of polymerization of the compound accelerates independent of addition of a second part. The formulation includes at least 30 total weight percent solids upon cure. Optional additives to the formulation include at least one of a cure accelerator, a filler, a plasticizer, a colorant, and a cure inhibitor. A process for forming a polymerized coating on an article involves the application of this formulation to the substrate of an article and allowing sufficient time for the solvent to evaporate to form the polymerized coating on the article. The substrate of the article forms a corrosion barrier even without prior removal of a native corrosion layer on a surface of the substrate of the article.Type: ApplicationFiled: October 5, 2010Publication date: April 7, 2011Inventor: Ron Lewarchik
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Patent number: 7901501Abstract: The invention provides an inkjet ink composition comprising: a white pigment; a polymerizable compound; and a polymerization initiator. The white pigment includes at least one of inorganic hollow particles or inorganic-organic hybrid hollow particles. A ratio of an average inside diameter of cavities in the at least one of inorganic hollow particles or inorganic-organic hybrid hollow particles to an average outside diameter of the at least one of inorganic hollow particles or inorganic-organic hybrid hollow particles is in a range of from 0.4 to 0.95. Further, a volume average particle diameter of the at least one of inorganic hollow particles or inorganic-organic hybrid hollow particles is in a range of from 0.01 to 1.0 ?m.Type: GrantFiled: February 8, 2007Date of Patent: March 8, 2011Assignee: FUJIFILM CorporationInventor: Yukari Kobayashi
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Patent number: 7875686Abstract: Polymeric compositions for semiconductor applications comprising 10 to 99 wt. % of norbornene-type cycloolefin monomers represented by one or more of Formula I(a), I(b), and optionally I(c) and/or I(d), 0.0005 to 0.5 wt. % of an addition polymerization procatalyst, and optionally: up to 0.5 wt. % of a cocatalyst, up to 59 wt. % of a crosslinking monomer, up to 50 wt. % of a viscosifier, up to 20 wt. % of a thixotropic additive(s), up to 80 wt. % of a filler, up to 10 wt. % of an antioxidant, and up to 0.6 wt. % of an antioxidant synergist, the total of the components of the formulation adding up to 100%. Such formulations are mass polymerized, or cured, to form polymeric compositions that have properties desirable for a variety of specific electronic, microelectronic, optoelectronic and micro-optoelectronic applications such as die attach adhesives, underfill materials, prepreg binders, encapsulants, protective layers, and other related applications.Type: GrantFiled: August 16, 2005Date of Patent: January 25, 2011Assignee: Promerus LLCInventors: Ramakrisha Ravikiran, Hendra Ng, Rajesh Raja Puthenkovilakom, Linda Zhang, Dino Amoroso, Brian Knapp, Andrew Bell, Larry F. Rhodes
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Patent number: 7863362Abstract: Polymer slurries of ultrahigh molecular weight polyalpha-olefins are made stable toward settling, separation and agglomeration by surface treatment with a combination of wax and optional relatively high-density particulates. The selection of the surface coating acts not only as an anti-blocking agent, or partitioning aid to keep the tacky polymer particles separated, but also provides the suspended polymer particle with a density that matches the carrier. This prevents separation of the slurry components over time. Such materials, ultimately used as pipeline additives to reduce the fluid drag and increase the volumetric throughput, can be stored and shipped for extended periods of time without degradation of the slurry quality. Upon injection into the pipeline, the polymer particle dissolves quickly, unhindered by the coating.Type: GrantFiled: September 14, 2004Date of Patent: January 4, 2011Assignee: Baker Hughes IncorporatedInventors: Thomas J. Martin, Lu Chien Chou
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Publication number: 20100298493Abstract: Disclosed is a catalyst injection nozzle that comprises an outer tube with an open end, a nozzle tip with a diameter connected to the outer tube open end, an orifice connected to the nozzle tip internal to the outer tube, an internal mixing zone connected to the orifice internal to the outer tube, an inner tube residing within the outer tube further comprising an open end connected to the internal mixing zone, where a steady-state, uniform two-phase flow regime between an atomizing gas and at least one liquid catalyst feed does not form in the internal mixing zone at an atomizing gas to liquid catalyst feed flow ratio of about 0.05 to about 10.Type: ApplicationFiled: January 23, 2009Publication date: November 25, 2010Applicant: Dow Global Technologies Inc.Inventors: Charles W. Lipp, David Denton, Bruce J. Gertner
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Publication number: 20100267894Abstract: A polymer modified pigment having a polymer (P-1) on the surface of a pigment (A), wherein the polymer (P-1) is obtained by copolymerizing a copolymer (B-1) of a polymerizable unsaturated monomer containing at least one polymerizable unsaturated group soluble in a non-aqueous solvent, and at least one kind of polymerizable unsaturated monomer (C), which is soluble in the non-aqueous solvent and either insoluble or poorly soluble following polymerization: and a polymer modified pigment having a polymer (P-2) on the surface of a pigment (A), wherein the polymer (P-2) is obtained by polymerizing at least one kind of polymerizable unsaturated monomer (C) soluble in the non-aqueous solvent and either insoluble or poorly soluble following polymerization, in the presence of an alkyd resin (B-2) soluble in a non-aqueous solvent.Type: ApplicationFiled: April 16, 2009Publication date: October 21, 2010Applicant: DIC CorporationInventor: Hiroshi Kinoshita
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Patent number: 7812091Abstract: Electrophoretic particles are constituted by pigment particles provided with a polymer chain connected with a polymerization initiation group at a surface of pigment particle. The resultant electrophoretic particles are excellent particle size uniformity and dispersibility.Type: GrantFiled: January 25, 2010Date of Patent: October 12, 2010Assignee: Canon Kabushiki KaishaInventor: Masato Minami
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Patent number: 7803870Abstract: Disclosed are a cycloolefin resin molded product having excellent flame retardance and a polymerizable composition used for producing such a molded product. A polymerizable composition comprising the cycloolefin monomer, a flame retardant and a metathesis polymerization catalyst is characterized in that a monomer having a condensed ring formed of an aliphatic ring having one or more carbon-carbon double bonds and a ring with aromatic characteristics is used as the cycloolefin monomer. A molded product can be produced through bulk polymerization of this polymerizable composition.Type: GrantFiled: July 8, 2009Date of Patent: September 28, 2010Assignee: Zeon CorporationInventor: Tomoo Sugawara
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Patent number: 7794755Abstract: A process for producing microspheres was developed that provides microspheres with new combined properties of high density, low fracture, high swell capacity, rapid swell, and deformability following swell. The process is reliable and high yielding, and makes use of a low temperature azo initiator and a small molecule chlorinated solvent as the organic phase. The microsphere preparation made using the process is particularly useful in medical treatments such as embolization.Type: GrantFiled: April 5, 2007Date of Patent: September 14, 2010Assignee: E.I. du Pont de Nemours and CompanyInventors: Garret D. Figuly, Surbhi Mahajan, Rinaldo S. Schiffino
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Publication number: 20100227975Abstract: The invention provides a method for preparing an aqueous dispersion of polymer particles comprising the following steps: (i) preparing a dispersion having a continuous aqueous phase, a dispersed organic phase comprising one or more ethylenically unsaturated monomers, and an amphiphilic RAFT agent as a stabiliser for said organic phase, and (ii) polymerising said one or more ethylenically unsaturated monomers under the control of said amphiphilic RAFT agent to form said aqueous dispersion of polymer particles, novel amphiphilic RAFT agents for use in this method, novel RAFT agents useful in making these amphiphilic RAFT agents and methods for their manufacture.Type: ApplicationFiled: May 14, 2010Publication date: September 9, 2010Applicant: UNIVERSITY OF SYDNEYInventors: Christopher Henry SUCH, Ezio RIZZARDO, Algirdas Kazimieras SERELIS, Brian Stanley HAWKETT, Robert Goulston GILBERT, Christopher James FERGUSON, Robert John HUGHES, Edna Olejnik
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Publication number: 20100222507Abstract: A method for producing a fine-particle-dispersed polyol (I) is provided, the method including the steps (1) and (n?1): the step (1) of polymerizing an ethylenically unsaturated monomer (b) in a polyol (a), in the presence of fine particles (P1) and a radical polymerization initiator (c), so as to obtain a fine-particle-dispersed polyol intermediate (B2); and the step (n?1) of polymerizing (b) in a fine-particle-dispersed polyol intermediate (B(n?1)), in the presence of (c), so as to obtain a fine-particle-dispersed polyol intermediate (Bn) or the fine-particle-dispersed polyol (I), where n represents an integer of 3 to 7, wherein (P1) have a volume-average particle diameter (R1) of 0.01 ?m to 1.0 ?m, and a concentration of (b) in the step (1) is 7 wt % to 40 wt %.Type: ApplicationFiled: October 1, 2008Publication date: September 2, 2010Applicant: SANYO CHEMICAL INDUSTRIES, LTD.Inventors: Shigekuni Nakada, Takayuki Tsuji, Yukiya Kobayashi
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Publication number: 20100210788Abstract: This invention relates to novel electron deficient olefins, such as certain 2-cyanoacrylates and methylidene malonates, prepared using an imine or an iminium salt.Type: ApplicationFiled: April 23, 2010Publication date: August 19, 2010Applicant: Loctite (R&D) LimitedInventors: Ciaran B. McArdle, Ligang Zhao, Stefano Gherardi, Kevin Murnaghan
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Patent number: 7728066Abstract: A conductive resin molding for use in the separator of a fuel cell and its producing method in which lowering of production yield and increase of machining cost, which are the most important problems with the spread of fuel cell, can be suppressed. The conductive resin molding is characterized by containing 1-9 vol % of high boiling point oil against the entire resin composition. Alternatively, high density expanded graphite prepared to have a specific gravity of 1.8 or above is employed as a conductive compounding agent. Alternatively, the conductive resin molding can be molded by flash flow compression molding.Type: GrantFiled: March 18, 2002Date of Patent: June 1, 2010Assignee: NTN CorporationInventors: Masaki Egami, Eiichirou Shimazu
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Patent number: 7714061Abstract: The present invention relates to a process for postcrosslinking water-absorbing polymeric particles in the absence of oxidizing gases, to the water-absorbing polymers preparable by the process and to their use in hygiene articles and packaging materials.Type: GrantFiled: November 28, 2005Date of Patent: May 11, 2010Inventors: Ulrich Riegel, Thomas Daniel, Uwe Stueven, Mark Elliott
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Patent number: 7714038Abstract: Polyolefin waxes bearing (meth)acrylate groups, process for preparing them and their use.Type: GrantFiled: March 2, 2006Date of Patent: May 11, 2010Assignee: BASF AktiengesellschaftInventors: Dietmar Haering, Bernhard Hauer, Thomas Pfeiffer, Andreas Fechtenkoetter, Harald Larbig, Erich Beck
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Publication number: 20100071863Abstract: Methods for making a heterogeneous polymer blend comprising one or more anionic polymers, one or more cationic polymers, and one or more non-ionic polymers, which method comprises (a) adding to a non-neutral solution a first amount of polymerization initiator and one or more anionic or cationic monomers, wherein each monomer has the same charge; (b) adding a second amount of the polymerization initiator and one or more non-ionic monomers; (c) adding a third amount of the polymerization initiator and one or more ionic monomers that are oppositely charged from the monomers of (a); adding stepwise, a fourth amount of the polymerization initiator to react any residual monomer, and (e) neutralizing the resulting polymer blend. Also claimed are heterogeneous polymer blends containing polymers formed from one or more anionic, cationic, and non-ionic monomers, either polymerized in situ or separately and then combined.Type: ApplicationFiled: September 18, 2009Publication date: March 25, 2010Applicants: Hercules Inc., Specialty Minerals (Michigan) Inc.Inventors: Frank J. Sutman, Joseph M. Mahoney, Robert Anthony Gill, Daniel Bruce Evans
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Patent number: 7678862Abstract: Electrophoretic particles are constituted by pigment particles provided with a polymer chain connected with a polymerization initiation group at a surface of pigment particle. The resultant electrophoretic particles are excellent particle size uniformity and dispersibility.Type: GrantFiled: May 27, 2005Date of Patent: March 16, 2010Assignee: Canon Kabushiki KaishaInventor: Masato Minami
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Publication number: 20100021754Abstract: Aqueous polymer dispersion obtainable by emulsion polymerization of monomers in the presence of inorganic polymer particles (inorganic particles for short) which are dispersible in the aqueous phase without surface-active assistants.Type: ApplicationFiled: December 11, 2007Publication date: January 28, 2010Applicant: BASF SEInventors: Peter Schlichting, Marc Schroeder, Hermann Seyffer
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Publication number: 20100022697Abstract: The invention relates to a process for microencapsulation of phase change materials based on free radicals polymerization comprising: a) the preparation of i) a solution with, at least, a hydrophilic liquid and a stabilizer (continuous phase) and ii) a solution with, at least, a phase change material, a free radical initiator and a polymerizable material (discontinuous phase); b) the preparation of an emulsion by dispersing the discontinuous phase in the continuous phase under vigorous stirring; and c) the polymerization of monomers until the phase change material becomes microencapsulated. This process is simple and effective and avoids the use of hazardous compounds. The invention also relates to microcapsules obtainable by said process and to the use thereof in the thermal protection and storage of heat.Type: ApplicationFiled: March 23, 2006Publication date: January 28, 2010Applicant: UNVERSIDAD DE CASTILLA-LA MANCHAInventors: Juan Francisco Rodriguez Romero, Maria Luz Sanchez Silva, Paula Sanchez Paredes, Antonio De Lucas Martinez, Martha Liliana Torres Barreto
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Publication number: 20100016505Abstract: A process for producing polymer particles by polymerizing liquid droplets in a gas phase surrounding the droplets, said droplets comprising at least one monomer and being coated with particulate solids during the polymerization.Type: ApplicationFiled: February 4, 2008Publication date: January 21, 2010Applicant: BASF SEInventors: Dennis Lösch, Annemarie Hillebrecht, Marco Krüger, Stefan Blei, Matthias Weismantel, Wilfried Heide
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Publication number: 20090318617Abstract: Aqueous polymer dispersions, the dispersed particles of which comprise at least one effect substance from the group consisting of UV absorbers, antistatics, antioxidants and antifogging agents and have a mean particle size of at most 500 nm and a glass transition temperature of at least 85° C. and which can be obtained by emulsion polymerization of ethylenically unsaturated monomers in the presence of at least one effect substance, and to the use of the polymer dispersions comprising effect substances or of the polymer powders obtained therefrom for the finishing and for the stabilizing of polymers, in particular for the stabilizing of thermoplastic polymers, against the effect of UV radiation.Type: ApplicationFiled: March 9, 2007Publication date: December 24, 2009Applicant: BASF SEInventors: Rainer Dyllick-Brenzinger, Alban Glaser
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Patent number: 7601765Abstract: The present invention relates to processes for preparing actinic-radiation-curable and/or dual-cure poly(meth)acrylates by preparing a poly(meth)acrylate containing hydroxy-functional side chains and transesterifying or esterifying the poly(meth)acrylate containing hydroxy-functional side chains with a (meth)acrylate or (meth)acrylic acid. The present invention further relates to the actinic-radiation-curable and/or dual-cure poly(meth)acrylates themselves and to the use of the actinic-radiation-curable and/or dual-cure poly(meth)acrylates in the preparation of dispersions or as a component in coating formulations and topcoats comprising at least one actinic-radiation-curable and/or dual-cure poly(meth)acrylate.Type: GrantFiled: November 5, 2003Date of Patent: October 13, 2009Assignee: BASF Coatings AGInventors: Heinz-Peter Rink, Susanne Neumann, Uwe Meisenburg, Karl-Heinz Joost, Dietmar Häring, Bernhard Hauer
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Patent number: 7579404Abstract: Disclosed are a cycloolefin resin molded product having excellent flame retardance and a polymerizable composition used for producing such a molded-product. A polymerizable composition comprising the cycloolefin monomer, a flame retardant and a metathesis polymerization catalyst is characterized in that a monomer having a condensed ring formed of an aliphatic ring having one or more carbon-carbon double bonds and a ring with aromatic characteristics is used as the cycloolefin monomer. A molded product can be produced through bulk polymerization of this polymerizable composition.Type: GrantFiled: August 9, 2004Date of Patent: August 25, 2009Assignee: Zeon CorporationInventor: Tomoo Sugawara
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Publication number: 20090203832Abstract: A description is given of a process of emulsion polymerization of free-radically polymerizable ethylenically unsaturated monomers selected from the group of the monoesters or diesters of ethylenically unsaturated monocarboxylic or dicarboxylic acids with alkanols, vinyl esters and/or vinylaromatics and, if desired, further monomers copolymerizable therewith, at least 60% of the total conversion in the polymerization taking place at a temperature of 100° C. to 160° C., the polymerization being performed in the presence of emulsifiers and an amount of 0% to 1% by weight, based on the total amount of the monomers used, of protective colloid. The process can be used to obtain significantly faster conversions for comparable quality of the process products. The dispersions obtained can be employed in a wide variety of different applications, such as binders for paints or as adhesives.Type: ApplicationFiled: February 6, 2009Publication date: August 13, 2009Applicant: Celanese Emulsions GmbHInventors: Harmin Muller, Harald Petri, Thomas Drechsel
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Publication number: 20090198014Abstract: A mixture of compounds useful to make a polymer or a prepolymer, the mixture of compounds including compounds having the formula I; wherein R1 is H, acryloyl, methacryloyl or vinyl, wherein R2 is acryloyl, methacryloyl or vinyl, wherein compounds having the formula I consist of a mixture of cis and trans-1,3- and 1,4-substituted cyclohexane and wherein the trans-1,4-substituted cyclohexane content of the compounds having the formula I is less than forty mole percent. A process for producing a mixture of compounds including compounds having the formula II: wherein compounds having the formula II consist of a mixture of cis and trans-1,3- and 1,4-methanol substituted cyclohexane and wherein the trans-1,4-methanol substituted cyclohexane content of the compounds having the formula II is less than twenty five mole percent.Type: ApplicationFiled: December 7, 2006Publication date: August 6, 2009Inventors: Kiran K. Baikerikar, Michael L. Tulchinsky, John N. Argyropoulos
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Publication number: 20090182092Abstract: A purpose of the present invention is to reduce odor of a water-absorbent resin during absorption of water. Such the invention is attained by a process for production of a water-absorbent resin by subjecting a water-soluble ethylenically unsaturated monomer to reversed-phase suspension polymerization. The process comprises the following steps (A) to (C): (A) adding an aqueous solution of water-soluble ethylenically unsaturated monomer to a petroleum hydrocarbon dispersion medium to disperse the aqueous solution in the dispersion medium; (B) adding a surfactant to the emulsion to further disperse the emulsion; and (C) performing the reversed-phase suspension polymerization using a water-soluble radical polymerization initiator, optionally in the presence of an internal-crosslinking agent.Type: ApplicationFiled: April 26, 2007Publication date: July 16, 2009Applicant: Sumitomo Seika Chemicals Co., Ltd.Inventors: Hideki Yokoyama, Yasuhiro Nawata
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Publication number: 20090137715Abstract: Disclosed herein is a copolymer (A) of olefinically unsaturated monomers (a), prepared by single-stage or multistage controlled free-radical copolymerization in an aqueous medium of monomers comprising: (a1) an olefinically unsaturated monomer comprising a chelate-forming group; and (a2) an olefinically unsaturated monomer different from the olefinically unsaturated monomer (a1), and selected from the group consisting of: (a21) monomers of the general formula I: R1R2C?CR3R4 (I), wherein R1, R2, R3, and R4 are independently hydrogen atoms or substituted or unsubstituted alkyl, cycloalkyl, alkylcycloalkyl, cycloalkylalkyl, aryl, alkylaryl, cycloalkylaryl, arylalkyl or arylcycloalkyl radicals, with the proviso that at least two of R1, R2, R3, and R4 are substituted or unsubstituted aryl, arylalkyl or arylcycloalkyl radicals; (a22) an olefinically unsaturated terpene hydrocarbon; and (a23) a dimeric alpha-alkylvinylaromatic.Type: ApplicationFiled: January 25, 2007Publication date: May 28, 2009Applicant: BASF COATINGS AGInventors: Horst Hintze-Bruning, Dirk Schmelter
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Publication number: 20090131584Abstract: The present invention provides a resin-coated metal pigment capable of achieving both of water resistance of a water base paint and chemical resistance of a film at a high level, and a water base paint using the resin-coated metal pigment. The present invention provides a method for producing a resin-coated metal pigment including an adsorption step of bringing a solution or a dispersion liquid of a phosphate ester component (A) into contact with a metal pigment to prepare a phosphate ester adsorbing metal pigment, a slurry preparation step of preparing a slurry for polymerization obtained by dissolving a polymerization component (B) therein, and a coating step of polymerizing the polymerization component (B) to form a resin coating layer on the surface of the phosphate ester adsorbing metal pigment; a resin-coated metal pigment obtained by the method; and a water base paint using the resin-coated metal pigment.Type: ApplicationFiled: October 11, 2006Publication date: May 21, 2009Inventors: Wataru Terao, Yasushi Takano, Shunichi Setoguchi
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Publication number: 20090062462Abstract: An object of the present invention is to provide an encapsulated product having excellent properties, for example, the core substance is not limited. An encapsulated product comprising a core substance encapsulated with a wall material mainly comprising a polymer, wherein the polymer contacts the core substance through an ionic surfactant a and comprises at least (1) a repeating structural unit derived from an ionic polymerizable surfactant B and/or ionic monomer and (2) a repeating structural unit derived from an ionic polymerizable surfactant C having an electric charge the same as or opposite the electric charge of the ionic surfactant; or an encapsulated product comprising a core substance encapsulated with a wall material mainly comprising a polymer, wherein the polymer comprises a repeating structural unit comprising a hydrophobic monomer and is present between (1) an ionic surfactant b and (2) an ionic surfactant c.Type: ApplicationFiled: October 18, 2005Publication date: March 5, 2009Inventor: Toshiyuki Miyabayashi
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Patent number: 7297739Abstract: This invention relates to a polymer precursor dispersion for use in making a polymer that is a solid at room temperature and further relates to a method of making same where the dispersion comprises a polymer precursor comprising an addition monomer, a condensation monomer, a prepolymer, or a polymer modifier and 0.01 to 50 weight percent of a micropulp having a volume average length of from 0.01 to 100 micrometers.Type: GrantFiled: December 13, 2005Date of Patent: November 20, 2007Assignee: E.I. du Pont de Nemours and CompanyInventors: John Chu Chen, Arnold Frances, Sam Louis Samuels
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Patent number: 6946516Abstract: A rubber-modified flame resistant styrene resin composition, which has superior heat stability and weather resistance to prevent discoloration and deterioration due to heat or light and is processed under various molding condition, is provided. The rubber-modified flame resistant styrene resin composition includes a rubber-modified styrene resin, flame retardant comprising compounds selected from a group consisting of tetrabromobisphenol-A-bis(2,3-dibromopropylether), hexabromocyclododecane and a mixture thereof, and brominated epoxy oligomer, and calcium stearate as a lubricant.Type: GrantFiled: July 7, 2003Date of Patent: September 20, 2005Assignee: LG Chem, Ltd.Inventors: Dae-San Jung, Yong-Yeon Hwang, Su-Yeon Na, Jong-Kuk Choi, Chan-Hong Lee
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Patent number: 6893583Abstract: A flame-retardant curable resin composition which comprises (1) a polymerizable vinyl monomer having a glass transition temperature of its homopolymer of at most 0° C., (2) a polymerization initiator, (3) a reducing agent and (4) a flame retardant in an amount of from 25 to 75 parts by mass based on 100 parts by mass of the total of (1) the polymerizable vinyl monomer having a glass transition temperature of its homopolymer of at most 0° C., (2) the polymerization initiator and (3) the reducing agent.Type: GrantFiled: March 7, 2002Date of Patent: May 17, 2005Assignee: Denki Kagaku Kogyo Kabushiki KaishaInventors: Tetsuya Sakurai, Hidehiro Mihara, Kohichi Taguchi
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Patent number: 6740703Abstract: A thickened aqueous coating composition (preferably paints and the like or adhesives) containing a film-forming polymeric binder which produces dried coatings having less sensitivity to water by using a thickener which is autoxidizable. Preferred autoxidizable moieties are provided by long chain fatty acids of the type used in alkyd paints and association is the preferred thickener mechanism. The moieties may form part of a compound which can take part in a copolymerization to form a cellulose-free polymeric backbone for the thickener and if the compound is not very soluble in water, the copolymerization mixture is subjected to intensive agitation to form droplets of less than 500 nm number average diameter which compensates for the lack of solubility. The thickener may serve as a binder if sufficient amounts are used.Type: GrantFiled: February 6, 2002Date of Patent: May 25, 2004Assignee: Imperial Chemical Industries PLCInventors: Manish Sarkar, Stephane Patrick Belmudes
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Patent number: 6716914Abstract: An expanded cellular ethylenic polymer product is provided from an irradiated, noncross-linked linear ethylenic polymer. Linear ethylenic polymers can be irradiated at ambient conditions sufficient to introduce branching in the polymer in the absence of detectable cross-linking as indicated by the absence of gels. The irradiated linear ethylenic polymer is compatible with highly branched low density polyethylene and, when mixed therewith, produces a resin having a single broad based melting temperature range as determined by direct scanning calorimetry, which indicates that the polymers in the mixture have similar crystallization behavior suitable for producing low density foams by extrusion foaming. The linear polymers can be obtained from recycled shrink wrap film. Low densities of from 0.7 to less than 4 pcf can be achieved. The foams typically have improved tear resistance as compared to previous products prepared from low density polyethylene, at comparable low densities.Type: GrantFiled: June 4, 2003Date of Patent: April 6, 2004Assignee: Sealed Air Corporation (U.S.)Inventors: Nelson E. Malwitz, Natarajan S. Ramesh, Shau-Tarng Lee
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Publication number: 20040001962Abstract: The present invention discloses a composition of matter consisting of a high impact polystyrene exhibiting improved environmental stress crack resistance. The composition can comprise a rubber-modified polymer formed by the polymerization of a monovinylaromatic monomer in the presence of a rubber selected from the group consisting of natural rubbers, polybutadienes, polyisoprenes, and copolymers of butadienes or isoprene with styrene. At least one ESCR enhancing additive is added chosen from the group consisting of polyisobutylene, polymerized alpha-olefins of at least 10 carbons, atactic polypropylene, or polyolefin copolymers.Type: ApplicationFiled: June 27, 2003Publication date: January 1, 2004Inventors: B. Raghava Reddy, Kenneth P. Blackmon
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Patent number: 6649708Abstract: To provide a process for producing polymer particles which are spherical and have smooth surfaces and small contents of oil- and the solvent-soluble at the time of being compounded. Polymer particles are produced by adding 0.099 to 47 parts by mass of a crosslinking vinyl monomer to 100 parts by mass of a vinyl monomer (referred to hereinafter as the monomer) during polymerization reaction at a degree of monomer polymerization of 1 to 100% in order to polymerize the monomer in a solvent in the presence of a dispersant and a polymerization initiator to give polymer particles.Type: GrantFiled: December 17, 2001Date of Patent: November 18, 2003Assignee: Kao CorporationInventors: Makoto Tsuji, Yasushi Sasaki
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Patent number: 6617372Abstract: What is described is a polymeric hydrogel product of a stable, aqueous polymeric composition which composition forms a clear to translucent film upon application to a substrate, and includes, by weight, 5-75% of (a) a water-soluble polymer having (b) in situ-formed, substantially water-insoluble resinous particles of said polymer substantially uniformly dispersed therein, and (c) 25-95% of water, made by irradiating the composition with high energy electron beam or gamma-radiation.Type: GrantFiled: October 23, 2001Date of Patent: September 9, 2003Assignee: ISP Investments Inc.Inventor: Laurence Senak
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Patent number: 6613837Abstract: The present invention discloses a composition of matter consisting of a high impact polystyrene exhibiting improved environmental stress crack resistance. The HIPS material is formed utilizing polybutadiene, polyisoprene, and copolymers thereof with styrene, having a Mooney viscosity exceeding about 35 and a gel content of up to about 28%. The present invention discloses the use of a combination of lubricant additives to obtain a HIPS material with higher ESCR values than either additive alone could provide, and also discloses the optimum level of each additive.Type: GrantFiled: August 23, 1999Date of Patent: September 2, 2003Assignee: Fina Technology, Inc.Inventors: B. Raghava Reddy, Kenneth P. Blackmon
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Publication number: 20030144415Abstract: Process for the preparation of a thermoplastic elastomer by melt mixing a partially vulcanized rubber concentrate, a thermoplastic polymer and/or additives, optionally oil and a curing agent. The partially vulcanized rubber concentrate is prepared by melt mixing at least one elastomer and optionally oil with a thermoplastic polymer and a curing agent. The elastomer may be EPDM or EPM. The thermoplastic polymer may be chosen from a thermoplastic polyolefine. Usefull curing agents are for example sulfur, sulfurous compounds, metal oxides, maleimides, phenol resins or peroxides.Type: ApplicationFiled: January 29, 2002Publication date: July 31, 2003Applicant: DSM N.V.Inventors: Yundong Wang, Ryszard Brzoskowski
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Patent number: 6593405Abstract: Methods for elastifying and extending polymers with EVA copolymers, PVC homopolymers or PVC copolymers in gel form are described. The elastified and extended polymers are useful as sealing materials, adhesives and sealants.Type: GrantFiled: July 25, 2000Date of Patent: July 15, 2003Assignee: Henkel Kommanditgesellschaft auf AktienInventors: Michael Schaetzle, Gabriele Bride, Gisbert Kern, Wolfgang Lepka
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Publication number: 20030119984Abstract: This invention relates to a process for making polymer-dye particles comprising, in order:Type: ApplicationFiled: December 14, 2001Publication date: June 26, 2003Applicant: Eastman Kodak CompanyInventors: Xiaoru Wang, Huijuan D. Chen
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Patent number: 6533503Abstract: A mortar composition, curable by frontal polymerization after heat initiation, is described, wherein are contained a) at least one polymerizable monomer and/or at least one curable resin, b) at least one polymerization initiator, which can be activated and/or released thermally at a temperature above 30° C., for the polymerizable monomers and/or curing accelerator for the curable resin and c) optionally at least one filler, the nature and amount of polymerizable monomer or curable resin and polymerization initiator or curing accelerator being selected so that a polymerization front velocity of at least 10 cm/min results after the polymerization is initiated, as well as a method for fastening tie bars, reinforcing steel or the like in solid substrates.Type: GrantFiled: December 21, 2000Date of Patent: March 18, 2003Assignee: Hilti AktiengesellschaftInventors: Armin Pfeil, Thomas Bürgel, Massimo Morbidelli, Anny Rosell
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Patent number: 6461735Abstract: In a coated article comprising an undercoat and an overcoat on a substrate, the undercoat comprising a compound having a hydrolyzable group-bearing silyl group represented by SiX3−a wherein X is a hydrolyzable group and “a” is equal to 0, 1 or 2; and the overcoat is based on a composition comprising a silicone resin-containing emulsion resulting from emulsion polymerization of a mixed solution containing (A-1) a silanol group-bearing silicone resin comprising 30-100 mol % of T units and based on the T units, 30-80 mol % of T-2 units, and having a Mn of at least 500, and (A-2) a radical-polymerizable vinyl monomer. Due to a firm bond between the overcoat and the undercoat, the coated article exhibits a weather and water resistance sufficient to withstand long-term outdoor exposure.Type: GrantFiled: January 11, 2001Date of Patent: October 8, 2002Assignee: Shin-Etsu Chemical Co., Ltd.Inventors: Masahiro Furuya, Yuji Yoshikawa, Satoshi Iwasaki, Masaaki Yamaya, Akira Yamamoto
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Patent number: 6403711Abstract: A high elongation, low 100% modulus composition comprises a copolymer dispersed in a continuous phase polysiloxane. The copolymer is made from high amounts of at least a monomer which is capable of forming a low Tg polymer and relatively low amounts of at least a monomer which is capable of forming a high Tg polymer. The monomer forming the low Tg polymer can be an alkyl acrylate whereas the monomers forming the high Tg polymer can be a vinyl ester, an acrylonitrile or derivatives thereof, a vinyl substituted aromatic such as styrene, an alkyl methacrylate, and the like. The composition has good adhesion to substrates as well as good viscosity aging, and can be utilized in caulks or sealants.Type: GrantFiled: January 10, 2000Date of Patent: June 11, 2002Assignee: Noveon IP Holdings Corp.Inventors: Wei-Yeih Yang, Melvin Dale Beers, Ta-Min Feng
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Patent number: 6391449Abstract: This invention relates to a polymer-clay intercalates, exfoliates, nanocomposites and methods of manufacturing comprising (i) a melt-processible matrix polymer, and incorporated therein (ii) a mixture of at least two layered clay materials. The invention also relates to articles produced from a nanocomposite and a process for preparing a nanocomposite.Type: GrantFiled: December 1, 1999Date of Patent: May 21, 2002Assignee: AMCOL International CorporationInventors: Tie Lan, Vasiliki Psihogios, Robert Boyd Barbee, James Christopher Matayabas, Jr., John Walker Gilmer
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Patent number: 6388006Abstract: A pressure sensitive adhesive composition which comprises the following two components: (A) a vinyl polymer having at least one alkenyl group represented by the general formula (1): CH2═C(R1)— (1) wherein R1 represents a hydrogen atom or a methyl group; (B) a hydrosilyl group-containing compound is provided. The composition can give cured products having a high gel fraction and can be cured rapidly since the degree of alkenyl group introduction is high.Type: GrantFiled: May 22, 2000Date of Patent: May 14, 2002Assignee: Kaneka CorporationInventors: Masayuki Fujita, Yoshiki Nakagawa, Masato Kusakabe
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Patent number: 6376600Abstract: Aqueous dispersion of copolymers formed by the polymerization of a monomer mixture containing 0.05% to less than 4.5% by weight of certain terminally unsaturated oligomers are useful for improving the scrub resistance, corrosion resistance, opacifying capacity and/or efflorescence resistance of a coating.Type: GrantFiled: December 11, 2000Date of Patent: April 23, 2002Assignee: Rohm and Haas CompanyInventors: Robert David Solomon, Bradley Keith Hageman, Leo Joseph Procopio, Margo Raate Schaefer, Gary David Greenblatt, Stephen Scott Edwards, Gary Robert Larson, Alvin Michael Maurice, Stewart Orlyn Williams, Patricia Marie Lesko, Peter Reeves Sperry
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Publication number: 20020022678Abstract: This invention relates to a polymer-clay intercalates, exfoliates, nanocomposites and methods of manufacturing comprising (i) a melt-processible matrix polymer, and incorporated therein (ii) a mixture of at least two layered clay materials. The invention also relates to articles produced from a nanocomposite and a process for preparing a nanocomposite.Type: ApplicationFiled: December 1, 1999Publication date: February 21, 2002Inventors: TIE LAN, VASILIKI PSHIHOGIOS, ROBERT BOYD BARBEE, JAMES CHRISTOPHER MATAYABAS, JOHN WALKER GILMER
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Publication number: 20020013416Abstract: The present invention provides a mineral filled thermoplastic olefin (MFTPO) composition comprising a polymer mixture, a mineral and a flexural modulus modifying agent and/or a heat deflection temperature modifying agent, and a method for producing the same. The flexural modulus modifying agent and/or a heat deflection temperature modifying agent significantly increases the flexural modulus and/or a heat deflection temperature of the MFTPO without substantially affecting the falling weight impact resistance of the MFTPO relative to a similar MFTPO composition which lacks the flexural modulus modifying agent and/or a heat deflection temperature modifying agent.Type: ApplicationFiled: June 14, 2001Publication date: January 31, 2002Inventor: Oscar French Noel
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Patent number: 6333386Abstract: A relatively small amount of a plasticizer having an SP value of at least 8.8 and a molecular weight of at most 550 is added to blend rubber of NBR-PVC in which NBR has an AN content of from 43 to 50% by weight. The fuel impermeability and the low-temperature flexibility of the resulting rubber composition are improved to be comparable to those of FKM, and the amount of the plasticizer and its reaction product to be released from the rubber composition in fuel is reduced. Adding a controlled amount of carbon black to the rubber composition makes the composition have favorable electroconductivity. The rubber composition is formed into hoses or electroconductive hoses of low fuel permeation.Type: GrantFiled: June 27, 2000Date of Patent: December 25, 2001Assignee: Tokai Rubber Industries, Ltd.Inventors: Takahiro Nishiyama, Shinobu Kanbe, Atsuo Miyajima, Kazuhiro Kato