Nitrogen Ring Directly Fused Or Bridged To A Ring System Patents (Class 524/87)
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Patent number: 5916947Abstract: A non-toxic, antifouling coating composition is provided which comprises zinc oxide which has ben surface coated by photosensitizer(s) which increase the capability of zinc oxide to absorb visible light.Type: GrantFiled: September 18, 1996Date of Patent: June 29, 1999Assignee: Cape Cod Research, Inc.Inventors: Robert S. Morris, Myles A. Walsh, IV
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Patent number: 5844025Abstract: 1,2-Bis-adducts of stable hindered nitroxide compounds with substituted ethylenes are prepared by reacting two equivalents of nitroxyl compound with an ethylenically unsaturated compound such as styrene or an acrylate ester. These adducts are very effective inhibitors to prevent the premature polymerization of ethylenically unsaturated monomers when such monomers are distilled, processed or stored.Type: GrantFiled: December 2, 1996Date of Patent: December 1, 1998Assignee: Ciba Specialty Chemicals CorporationInventors: Glen Thomas Cunkle, Thomas F. Thompson, Volker H. von Ahn, Roland A. E. Winter
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Patent number: 5837757Abstract: Disclosed are non-bromine, flame-retardant polycarbonate resin compositions having increased reflectance and improved light shieldability, light fastness and moldability while still having good mechanical properties such as flame retardancy and impact resistance, and light reflectors as produced by molding the compositions. One type of the composition comprises (A) a polycarbonate resin and (B) a titanium oxide powder in a ratio by weight of from 70/30 to 90/10, and contains (C) a stilbene-bisbenzoxazole derivative in an amount of from 1 to 1000 ppm by weight and optionally (D) a non-halogen phosphate compound in an amount of from 0.05 to 1.00% by weight in term of phosphorus element, relative to the total weight of the component (A) and the component (B). The other type of the composition comprises (A) from 99.9 to 70% by weight of a polycarbonate resin and (B) from 0.1 to 30% by weight of a titanium oxide powder, and contains (D) a non-halogen phosphate compound in an amount of from 0.05 to 1.Type: GrantFiled: June 3, 1997Date of Patent: November 17, 1998Assignee: Idemitsu Petrochemical Co., Ltd.Inventors: Akio Nodera, Hiroshi Itagaki
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Patent number: 5834080Abstract: Controllably conductive polymer compositions may be used in electrophotographic imaging developing systems, such as scavengeless or hybrid scavengeless systems or liquid image development systems. The conductive polymer compositions includes a charge-transporting material (particularly a charge-transporting, thiophene-containing polymer or an inert elastomeric polymer, such as a butadiene- or isoprene-based copolymer or an aromatic polyether-based polyurethane elastomer, that additionally comprises charge transport molecules) and a dopant capable of accepting electrons from the charge-transporting material. The invention also relates to an electrophotographic printing machine, a developing apparatus, and a coated transport member, an intermediate transfer belt, and a hybrid compliant photoreceptor comprising a composition of the invention.Type: GrantFiled: October 18, 1994Date of Patent: November 10, 1998Assignee: Xerox CorporationInventors: Joseph Mort, Bing R. Hsieh, Mary A. Machonkin, Joseph Mammino, John F. Yanus
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Patent number: 5773491Abstract: The object of the present invention is polycarbonate molding compositions containing polycarbonates, stabilizers of the general formula (I)R.sub.1 --X--CZ--Y--R.sub.2and optionally polypropylene glycols. The object of the present invention is also use of these molding compositions to produce items for medical applications.Type: GrantFiled: March 7, 1996Date of Patent: June 30, 1998Assignee: Bayer AGInventors: Wolfgang Ebert, Ralf Hufen, Ru digerart, Gerhard Fennhoff
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Patent number: 5755875Abstract: Compounds selected from the series consisting of the perylenecarboximide, quinacridone, isoindoline, indigoid, azo, benzodipyrrolone, benzodifuranone, furanofuran, pyrrolo?2,5-b!pyrrole and bianthraquinone chromophores containing at least one grouping of formula ##STR1## wherein each A may be N--CN or O, with the proviso that at least one A must be N--CN, X is --N(R)--, --O-- or --S--, R is hydrogen, C.sub.1 -C.sub.18 alkyl, unsubstituted or halogen- or C.sub.1 -C.sub.4 alkyl-substituted phenyl, benzyl or phenethyl, and m and n are each independently of the other 0 or 1.Depending on the nature of their substituents, these compounds can be used as polymer-soluble dyes or as pigments for coloring high molecular weight organic material. They are distinguished by a surprisingly high solid-state fluorescence.Type: GrantFiled: March 22, 1996Date of Patent: May 26, 1998Assignee: Ciba Specialty Chemicals CorporationInventors: John S. Zambounis, Zhimin Hao, Abul Iqbal
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Patent number: 5741837Abstract: A syndiotactic polystyrene composition is improved which exhibits improved crystallization rate. The improved syndiotactic polystyrene composition contains (a) a syndiotactic polystyrene; and (b) a nucleating agent which is selected from the group consisting of two types of compounds represented by the following formulas, respectively: ##STR1## In Formulas I and II, the radicals R.sub.1 and R.sub.2, which can be the same of different, are C.sub.1 to C.sub.5 alkyl groups, X is a halogen group, preferably a bromide group, and n is an integer from 1 to 5. In the present invention, the nucleating agent is provided at 0.01 to 5 part, by weight, per 100 parts, also by weight, of the syndiotactic polystyrene resin. An example of Formula I compound is 2-hydroxybenimidiazole, and an example of the Formula II compound is bis(phenylbromide) methane.Type: GrantFiled: March 27, 1997Date of Patent: April 21, 1998Assignee: Industrial Technology Research InstituteInventors: Chung-Jen Wu, Chien-Ming Chen, Hsien-Ming Chen, Hurng-Rern Lee
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Patent number: 5714530Abstract: A synergistic stabilizer composition for polymers is described containing (i) a hydroxy-group containing triazine, and (ii) a 2,2,6,6-tetraalkyl piperidine compound. Also, described is a method of stabilizing polymers.Type: GrantFiled: June 7, 1995Date of Patent: February 3, 1998Assignee: Cytec Technology Corp.Inventor: Paul Sheldon Waterman
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Patent number: 5684073Abstract: The cap tread portion composed of a rubber composition having a tan.delta. (0.degree. C.) of at least 0.45 and a tan.delta. (60.degree. C.) of at least 0.25 comprising (i) a p-phenylenediamine type antioxidant, 2,2,4-trimethyl-1,2-dihydroquinoline etc, and carbon black having a nitrogen specific surface area of at least 70 m.sup.2 /g and a 24M4DBP of at least 80 ml/100 g or (ii) a p-phenylenediamine based antioxidant, a 2,2,4-trimethyl-1,2-dihydroquinoline or other polymer mixture of a specific polymer content, and carbon black having a nitrogen specific surface area of at least 70 m.sup.2 /g and a 24M4DBP of at least 80 ml/100 g, blended with a rubber.Type: GrantFiled: May 1, 1995Date of Patent: November 4, 1997Assignee: The Yokohama Rubber Co., Ltd.Inventors: Shingo Midorikawa, Kinya Kawakami, Yasushi Kikuchi, Motoji Fujita
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Patent number: 5684070Abstract: Tris-aryl-s-triazines of formula VI ##STR1## which contain from one to three resorcinol derived moieties have UV spectra which are red-shifted to the near UV range and provide excellent stabilization to polymeric substrates against the deleterious effects of actinic light.Type: GrantFiled: July 15, 1996Date of Patent: November 4, 1997Assignee: Ciba Specialty Chemicals CorporationInventor: Tyler Arthur Stevenson
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Patent number: 5665799Abstract: A rubber composition (1) which comprises:a rubber (A) such as natural rubber, isoprene rubber and the like;a hydroxy flavan compound (B1) represented by the formula (I): ##STR1## wherein R.sup.1, R.sup.2, R.sup.3, R.sup.4 and R.sup.5 are hydrogen or an aliphatic group and X and Y are hydrogen hydroxy or an aliphatic group, such as 2,4,4-trimethyl-2',4',7-trihydroxyflavan (B2); and2,2,4-trimethyl-1,2-dihydroquinoline polymer (C1) containing 1% or less by weight of a primary amine, 3% or less by weight of the monomer and 30% or more by weight of the dimer based on the total weight of the polymer, or a cromane compound (C2) which may be a novel cromane compound.Type: GrantFiled: September 7, 1995Date of Patent: September 9, 1997Assignee: Sumitomo Chemical Company, LimitedInventors: Naoki Inui, Hironobu Iyama, Kyoko Tsuta, Hideo Nagasaki
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Patent number: 5645767Abstract: Described are novel photochromic indeno-fused naphthopyran compounds, examples of which are naphthopyran compounds having a substituted or unsubstituted indeno group, the 2,1 positions of which are fused to the f side of the naphtho portion of the naphthopyran, and certain substituents at the 3-position of the pyran ring. Certain substituents may also be present at the number 5, 6, 7, 8, 9, 10, 11, 12, or 13 carbon atoms of the compounds. These compounds may be represented by the following graphic formula: ##STR1## Also described are polymeric organic host materials that contain or that are coated with such compounds. Optically clear articles such as ophthalmic lenses or other plastic transparencies that incorporate the novel naphthopyran compounds or combinations thereof with complementary photochromic compounds, e.g., certain other naphthopyrans, benzopyrans, and spiro(indoline)type compounds, are also described.Type: GrantFiled: October 13, 1995Date of Patent: July 8, 1997Assignee: Transitions Optical, Inc.Inventor: Barry Van Gemert
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Patent number: 5605761Abstract: An article exhibiting durable fluorescent properties comprising a polymeric matrix, dye, and hindered amine light stabilizer, wherein the polymeric matrix is comprised of polycarbonate and the dye is comprised of a dye selected from the group consisting essentially of thioxanthone, perylene imide and/or thioindigoid compounds. The article exhibits durable fluorescence which resists degradation by ultraviolet or visible radiation. The invention is optionally combined with retroreflective elements so that the resultant article has durable fluorescent properties when exposed to sunlight and is also retroreflective. A method of manufacturing an article exhibiting durable fluorescent properties is also disclosed along with a method of increasing the durability of polycarbonate in a dyed system.Type: GrantFiled: May 21, 1996Date of Patent: February 25, 1997Assignee: Minnesota Mining and Manufacturing CompanyInventors: David M. Burns, Lee A. Pavelka
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Patent number: 5605754Abstract: A thermoplastic article having on the outer surface thereof a protective layer having in admixture a trihydricphenol-benzotriazole ultra violet light absorber and a thermoplastic resin preferably a polycarbonate. The protective layer may be coated on the thermoplastic substrate or it may be co-extruded with the thermoplastic substrate.Type: GrantFiled: November 30, 1995Date of Patent: February 25, 1997Assignee: General Electric CompanyInventors: Josef G. Berndsen, Luca P. Fontana
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Patent number: 5553714Abstract: Provided is a method for tagging thermoplastic containers using near infrared fluorescing compounds or copolymerized residues readily capable of detection. Also provided is a method for identifying a thermoplastic container. Also provided are thermoplastic polymer compositions comprised of the near infrared fluorescing compounds or residues and articles comprised of such compositions.Type: GrantFiled: November 14, 1994Date of Patent: September 10, 1996Assignee: Eastman Chemical CompanyInventors: Michael R. Cushman, James J. Krutak, William W. Parham, Clarence A. Coates, Max A. Weaver, Gabor Patonay
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Patent number: 5493011Abstract: Water-insoluble azo colorants, their preparation and use The invention relates to monoazo and disazo compounds of the formula (I) ##STR1## in which D is the radical of a carbocyclic or heterocyclic diazo or bisdiazo component, R.sup.1 and R.sup.2, independently of one another, are each a substituted or unsubstituted aryl or heteroaryl radical, X.sup.1 and X.sup.2, independently of one another, are each ring-forming ether oxygen or a substituted or unsubstituted imide grouping and n has the value 0 or 1, in which rings A and B, independently of one another, can each be additionally substituted and/or carry substituted or unsubstituted fused rings.These new compounds of the formula (I) are obtained by coupling diazotized amines or diamines of the type D--NH.sub.2 or H.sub.2 N--D--NH.sub.2 with (benzoxazol-2-yl)- or (benzimidazol-2-yl)-arylacetamides.Depending on the presence and length of alkyl chains, the compounds of the formula (I) are suitable for use as pigments, disperse dyes or oil-soluble dyes.Type: GrantFiled: November 6, 1992Date of Patent: February 20, 1996Assignee: Hoechst AGInventors: Rudiger Jung, Reinhold Deubel
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Patent number: 5480926Abstract: This invention relates to a photo-stabilized polymer blend comprising:(a) at least one polyethylene terephthalate-based (PET) copolymer comprising 1,4-cyclohexanedimethanol, and(b) an ultraviolet absorber, at least one compound selected from the group consisting of cyclic imino esters.Type: GrantFiled: April 28, 1995Date of Patent: January 2, 1996Assignee: Eastman Chemical CompanyInventors: David R. Fagerburg, Michael E. Donelson
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Patent number: 5461151Abstract: A hydroxy group-containing aryl triazine ultraviolet absorber represented by the formula: ##STR1## wherein the R moiety of the OR group is a linear or branched aliphatic alkyl group containing 3 carbon atoms substituted by one or more alkoxy groups of 1 to 12 carbon atoms, said moiety being further substituted by one or more hydroxy groups, andwherein R.sup.19, R.sup.20, R.sup.21, R.sup.22, R.sup.23, R.sup.24 and R.sup.25 are independently selected from the group consisting of hydrogen, hydroxy, alkyl of 1 to 12 carbon atoms, alkoxy of 1 to 12 carbon atoms, sulfonic, halo, carboxy, haloalkyl and acrylamino.Type: GrantFiled: February 18, 1994Date of Patent: October 24, 1995Assignee: Cytec Technology CorporationInventor: Paul S. Waterman
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Patent number: 5430096Abstract: Stable aqueous size of ammonia-and/or amine-neutralized poly(amide-acid) of certain aromatic dianhydrides with certain aromatic diamines.Type: GrantFiled: April 28, 1994Date of Patent: July 4, 1995Assignee: E. I. Du Pont de Nemours and CompanyInventors: Sang-Hak Hwang, Thomas J. Proffitt, Jr.
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Patent number: 5397819Abstract: Provided is a method for tagging thermoplastic containers using near infrared fluorescing compounds or copolymerized residues readily capable of detection. Also provided is a method for identifying a thermoplastic container. Also provided are thermoplastic polymer compositions comprised of the near infrared fluorescing compounds or residues and articles comprised of such compositions. Also provided are new compounds useful as near infrared fluorophoric markers in the practice of this invention. The methods, compositions, and compounds of the present invention thus provide a total system useful for marking, for identification purposes, the various classes of thermoplastic wastes, so that they can be identified, sorted, and subsequently recycled.Type: GrantFiled: November 24, 1993Date of Patent: March 14, 1995Assignee: Eastman Chemical CompanyInventors: James J. Krutak, Michael R. Cushman, Clarence A. Coates, William W. Parham, Max A. Weaver, Gabor Patonay
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Patent number: 5391598Abstract: Solutions are described containing polyarylene sulfide and, as solvent, quinoline and/or isoquinoline and/or substituted derivatives thereof, the solvent being liquid at 25.degree. C. These solutions are processed at temperatures above 170.degree. C. and are used to produce shaped objects, such as films or fibers, or coatings. In addition they are used to determine the molecular weight of polyarylene sulfides or to purify polyarylene sulfides, or to clean apparatuses which were used in the production or processing of polyarylene sulfides.Type: GrantFiled: December 18, 1992Date of Patent: February 21, 1995Assignee: Hoechst AGInventor: Herbert Zeitler
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Patent number: 5376710Abstract: Compounds which comprise at least one group of the formula I or II ##STR1## and at least one polyalkylpiperidine group of the formula III ##STR2## in which R and R.sub.1 to R.sub.6 have the meaning indicated in claim 1, are effective stabilizers for organic materials against damage by light, oxygen and heat.Type: GrantFiled: March 10, 1993Date of Patent: December 27, 1994Assignee: Ciba-Geigy CorporationInventors: Mario Slongo, Jean-Luc Birbaum, Jean Rody, Andreas Valet
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Patent number: 5371125Abstract: Substituted 1-hydroxy-2,6-diaryl-4-acyloxypiperidines or 1-hydroxy-2,6-diaryl-4-acylaminopiperidines of formula I ##STR1## wherein n is 1-4, Ar.sub.1 and Ar.sub.2 are independently aryl or substituted aryl, R.sub.1, R.sub.2, R.sub.3 and R.sub.4 are independently hydrogen, alkyl, substituted alkyl, alkenyl, aryl or substituted aryl, X is --O-- or --NE--, E is hydrogen, alkyl or cycloalkyl and T is an n-valent aliphatic or aromatic hydrocarbon radical, are effective in stabilizing organic materials against the deleterious effects of oxygen, heat and actinic radiation.Type: GrantFiled: September 8, 1993Date of Patent: December 6, 1994Assignee: Ciba-Geigy CorporationInventors: Glen T. Cunkle, Ramanathan Ravichandran, Donald J. Sabrsula
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Patent number: 5334642Abstract: Stabilized polyaryl ether ketone molding compositions containing as essential componentsA) from 50 to 99.99% by weight of a polyaryl ether ketone prepared by electrophilic polycondensation and composed to an extent of not less than 50 mol % of units of the formula I' ##STR1## where s and t are each 0, 1, 2 or 3, T and T' are each --O-- or --CO-- and Ar is meta-phenylene, paraphenylene or two aromatic rings linked to each other in the meta or para position by a chemical bond, or the ring-substituted C.sub.1 -C.sub.8 -alkyl, C.sub.6 -C.sub.20 -aryl or halogen derivatives thereof,B) from 0.01 to 4% by weight of at least one organic compound which has a base constant pk.sub.b within the range from 2 to 12 and a boiling point of higher than 300.degree. C.,C) from 0 to 50% by weight of a further thermoplastic other than A), andD) from 0 to 45% by weight of fibrous or particulate fillers or mixtures thereof.Type: GrantFiled: December 30, 1992Date of Patent: August 2, 1994Assignee: BASF AktiengesellschaftInventors: Juergen Koch, Gerhard Heinz
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Patent number: 5322734Abstract: An oxidatively stabilized adhesion promoter composition for hot-melt adhesives is disclosed. The oxidatively stabilized adhesion promoter composition comprises a poly(vinylmethylether), said poly(vinylmethylether) having a number average molecular weight of from about 5,000 to about 1000,000, and an oxidative stabilizer antioxidant consisting of polymerized 1,2-dihydro-2,2,4-trimethylquinoline having a number average molecular weight of from about 350 to about 750. The said polymerized 1,2-dihydro-2,2,4-trimethylquinoline can be used with a secondary antioxidant comprising an organic compound of sulfur and trivalent phosphorus. The trivalent phosphorus compound can be a phosphite selected from the group consisting of tris-(2,4-di-tert-butylphenyl) phosphite, tris(mono-nonylphenyl) phosphite, bis(2,4-di-tert-butylphenyl) pentaerythritol diphosphite, distearyl pentaerythritol phosphite, and mixtures thereof. The oxidative stabilizer antioxidant is present in the poly(vinylmethylether) in an amount from about 0.Type: GrantFiled: March 22, 1993Date of Patent: June 21, 1994Assignee: Amoco CorporationInventor: Tsuei-Yun Lynch
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Patent number: 5288777Abstract: ABS copolymers and similar styrene or .alpha.-methylstyrene copolymers which contain an elastomer phase are stabilized against light-induced degradation by a) incorporation of a copolymerizable sterically hindered amine in, and b) addition of a non-copolymerizable sterically hindered amine to, the copolymer. Preferred sterically hindered amines are polyalkylpiperidines.Type: GrantFiled: November 9, 1992Date of Patent: February 22, 1994Assignee: Ciba-Geigy CorporationInventors: Bernard Gilg, Gerhard Rytz, Werner Stauffer, Margot Clauss
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Patent number: 5272192Abstract: Compositions containinga) a chlorine-containing polymer,b) 0.01 to 1% by weight, relative to the chlorine-containing polymer, of a compound of the formula I and/or its hydrochloride, ##STR1## in which R is C.sub.6 -C.sub.20 alkyl, C.sub.3 -C.sub.20 alkyl interrupted by 1 to 5 oxygen atoms, C.sub.1 -C.sub.20 alkyl substituted by 1 to 5 OH, C.sub.3 -C.sub.20 alkenyl, C.sub.3 -C.sub.8 cycloalkyl, C.sub.1 -C.sub.4 alkyl-substituted C.sub.3 -C.sub.8 cycloalkyl, C.sub.7 -C.sub.11 phenylalkyl, C.sub.7 -C.sub.11 phenylalkyl which is substituted on the phenyl by 1 to 3 radicals, these radicals, independently of one another, being hydroxyl, chlorine, C.sub.1 -C.sub.4 alkyl, methoxy or ethoxy, or R is furthermore a group of the formula IIa or IIb, ##STR2## in which X is C.sub.1 -C.sub.20 alkyloxy, C.sub.1 -C.sub.20 alkylthio, phenyloxy, phenylthio, benzyloxy or benzylthio, and R.sub.1, R.sub.2 and R.sub.3, independently of one another, are hydrogen, C.sub.1 -C.sub.20 alkyl, C.sub.1 -C.sub.20 alkyloxy, C.sub.1 -C.sub.Type: GrantFiled: April 13, 1992Date of Patent: December 21, 1993Assignee: Ciba-Geigy CorporationInventors: Wolfgang Wehner, Hans-Gunter Kostler
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Patent number: 5264290Abstract: A highly improved elastomeric composition, process, and articles made thef, wherein the novel composition is characterized by greatly increased wear longevity, thermomechanical stability, highly improved tear and tensile strength at high temperature usage, in addition to high resistance to burning in open flame, as well as high resistance to cutting, chipping, cracking and crack propagation particularly in product use for tank track pads and other related track system elastomeric component products; wherein the improved composition is a unique combination of its respective polymer, filler, curing and antidegradant system, in which the polymer system either consists of about 100 parts by weight of highly saturated nitrile polymer or of various novel blends of the highly saturated usually in majority amounts together with minority amounts of carboxylated nitrile, with or without additional minority or near equal parts of nitrile rubber; and wherein the curing system may include various blends of from between abType: GrantFiled: March 4, 1992Date of Patent: November 23, 1993Assignee: The United States of America as represented by the Secretary of the ArmyInventors: Paul Touchet, Gumersindo Rodriguez, Paul E. Gatza, D. Patrick Butler, Dawn M. Crawford, Alan R. Teets, Henry O. Feuer, David P. Flanagan
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Patent number: 5240980Abstract: An opacified, semi-crystalline thermoplastic resin composition is provided having a poly(alkyleneoxy) substituted organic chromophore distributed throughout in an amount sufficient to color the resin. The resin composition is particularly useful for molding parts with strict dimensional tolerances as shrinkage of the molded part is minimal.Type: GrantFiled: May 22, 1992Date of Patent: August 31, 1993Assignee: Milliken Research CorporationInventors: Todd D. Danielson, David J. Moody, John W. Rekers
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Patent number: 5229442Abstract: Stabilizing compositions for organic polymers, composed of mixtures of at least one liquid phenolic antioxidant and at least one aminic antioxidant, subjected to thermal treatment, are characterized by their stabilizing capacity which is considerably higher than that of either single components or of corresponding untreated mixtures.These stabilizing compositions can be used in all field where the single components of the mixtures are generally used and, preferably, in the stabilization of organic polymers normally subject to deterioration due to oxidation processes.Type: GrantFiled: March 6, 1992Date of Patent: July 20, 1993Assignee: Enichem Synthesis S.p.A.Inventors: Fabio Broussard, Carlo Busetto
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Patent number: 5216049Abstract: The present invention relates to an antidegradant system comprised of (A) an antidegradant selected from the group consisting of phenolic antidegradants, amine antidegradants and mixtures thereof; and (B) a unique polymerizable synergist. In addition, there is disclosed a stabilized polymer comprising (A) a polymer selected from the group consisting of (1) homopolymers and copolymers of monoolefins; (2) natural rubber; and (3) synthetic rubber derived from a diene monomer; (B) from about 0.05 to about 10 parts by weight based upon 100 parts of polymer of an antidegradant selected from the group consisting of phenolic antidegradants, amine antidegradants and mixtures thereof; and (C) from about 0.05 to about 20 parts by weight based upon 100 parts of polymer of a unique polymerizable aromatic sulfide synergist.Type: GrantFiled: September 18, 1992Date of Patent: June 1, 1993Assignee: The Goodyear Tire & Rubber CompanyInventors: Dane K. Parker, Gerald O. Schulz
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Patent number: 5208278Abstract: Stabilized polyaryl ether ketone molding compositions containing as essential componentsA) from 50 to 99.99% by weight of a polyaryl ether ketone prepared by electrophilic polycondensation and composed to an extent of not less than 50 mol % of units of the formula I' ##STR1## where s and t are each 0, 1, 2 or 3, T and T' are each --0-- or --CO-- and Ar is meta-phenylene, paraphenylene or two aromatic rings linked to each other in the meta or para position by a chemical bond, or the ring-substituted C.sub.1 -C.sub.8 -alkyl, C.sub.6 -C.sub.20 -aryl or halogen derivatives thereof,B) from 0.01 to 4% by weight of at least one organic compound which has a base constant pk.sub.b within the range from 2 to 12 and a boiling point of higher than 300.degree. C.,C) from 0 to 50% by weight of a further thermoplastic other than A), andD) from 0 to 45% by weight of fibrous or particulate fillers or mixtures thereof.Type: GrantFiled: March 29, 1991Date of Patent: May 4, 1993Assignee: BASF AktiengesellschaftInventors: Juergen Koch, Gerhard Heinz
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Patent number: 5185391Abstract: The invention is a composition containing a polymer formed by side ring opening of an arylcyclobutene compound and an effective amount of an antioxidant.Type: GrantFiled: November 27, 1991Date of Patent: February 9, 1993Assignee: The Dow Chemical CompanyInventor: Theodore M. Stokich, Jr.
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Patent number: 5173528Abstract: A rheological and mechanical properties and the ageing resistance of the elastomeric thermoplastic copolyesters are remarkably improved by the addition of a synergistic mixture of a polycarbodiimide and a quinolinic antioxidant.The copolyesters containing the above synergistic mixture find use in the extrusion technology.Said copolyesters, when they are subjected to a heat treatment at a temperature lower than 150.degree. C., increase the melt viscosity so that they can be used in the blow-molding technology.Type: GrantFiled: July 5, 1990Date of Patent: December 22, 1992Assignee: Ausimont S.r.l.Inventors: Antonio Chiolle, Gian P. Maltoni, Romolo Stella, Alfio Vecchi
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Patent number: 5137949Abstract: A thermoplastic molding composition is disclosed comprising a polydiorganosiloxane-polycarbonate block cocondensate and 0.5% to 15% by weight of a particular hydroxy benzotriazole. The composition is characterized by its improved protection against UV light.Type: GrantFiled: October 26, 1990Date of Patent: August 11, 1992Assignee: Bayer AktiengesellschaftInventors: Winfried Paul, Hans-Josef Buysch, Wolfgang Nising, Thomas Scholl
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Patent number: 5132028Abstract: Compositions for imparting water- and oil-repellency to fabrics are provided. They contain a fluorochemical water- and oil-repellant agent, a carbodiimide compound, and at least one of the following: plasticizer, metal alcoholate or ester, zirconium salt, alkylketen dimer, aziridine, and alkenyl succinic anhydride. The compositions may also contain a silicone water-repellent.Type: GrantFiled: December 10, 1990Date of Patent: July 21, 1992Assignee: Minnesota Mining and Manufacturing CompanyInventors: Makoto Nagase, Kathy Allewaert, Franceska Fieuws, Dirk Coppens
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Patent number: 5110849Abstract: The present invention concerns a thermoplastic polyester resin composition comprising a thermoplastic polyester and a metal alcoholate salt of an aromatic alcohol containing a hydroxy group directly attached to the aromatic ring as the essential ingredient, having a high crystallization rate, excellent moldability upon molding at low temperature, less molecular weight reduction during production and molding of the resin composition, and satisfactory melt degradation stability and hydrolysis resistance.Type: GrantFiled: August 10, 1990Date of Patent: May 5, 1992Assignee: Toray Industries, Inc.Inventors: Hiroo Karasawa, Kiichi Kometani, Kiyokazu Nakamura
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Patent number: 5093395Abstract: A flame retardant polyester elastomer composition comprising a polyester elastomer, an amine antioxidant, and a hindered amine light stabilizer.Type: GrantFiled: October 2, 1989Date of Patent: March 3, 1992Assignee: Sumitomo Electric Industries, Ltd.Inventor: Shinji Torisu
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Patent number: 5087658Abstract: A heat-resistant resin paste consisting essentially of a first organic liquid (A.sub.1), a second organic liquid (A.sub.2), a heat-resistant resin (B) which is soluble in an organic liquid mixture consisting essentially of the first organic liquid (A.sub.1) and the second organic liquid (A.sub.2), and fine particles of a heat-resistant resin (C) which are soluble in the first organic liquid (A.sub.1), but insoluble in the second organic liquid (A.sub.2). The first organic liquid (A.sub.1), the second organic liquid (A.sub.2), and the heat-resistant resin (B) are brought into a solution in which the fine particles of a heat-resistant resin (C) are dispersed. The heat-resistant resin paste may be suitably used for screen process printing to provide integrated circuit devices with insulator layers or surface protecting layers. The heat-resistant resin paste is suitable for forming insulator layers or surface protecting layers in integrated circuit devices by employing screen process printing.Type: GrantFiled: December 18, 1989Date of Patent: February 11, 1992Assignee: Hitachi Chemical Company, Ltd.Inventors: Hiroshi Nishizawa, Kenji Suzuki, Yoshiyuki Mukoyama, Tohru Kikuchi, Hidetaka Sato
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Patent number: 5084191Abstract: Compositions for imparting water- and oil-repellency to fabrics and provided. The compositions contain a flurochemical water- and oil-repellent agent, an aziridine compound, and a metal alcoholate or ester. The compositions may optionallly contain a silicone water-repellent agent.Type: GrantFiled: December 10, 1990Date of Patent: January 28, 1992Assignee: Minnesota Mining and Manufacturing CompanyInventors: Makoto Nagase, Kathy Allewaert, Franceska Fieuws, Dirk Coppens
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Patent number: 5066695Abstract: High-molecular weight organic material containing at least one metal complex of a ligand of formula I: ##STR1## wherein A is a carbocyclic aromatic or heterocyclic aromatic radical, B is a carbocyclic aromatic radical or a heterocyclic aromatic radical containing at least one N atom, it being necessary for at least one of the radicals A and B to be heterocyclic, and R.sub.1 is --C.sub.1 -C.sub.18 -alkyl, a carbocyclic aromatic radical or a heterocyclic aromatic radical containing at least one N atom, and the metal is a transition metal cation carrying a double positive charge selected from Ni.sup.2+, Cu.sup.2+, Co.sup.2+, Zn.sup.2+, Mn.sup.2+, Fe.sup.2+, Cd.sup.2+ or Pt.sup.2+ or the radical VO.sup.2+.Type: GrantFiled: June 29, 1989Date of Patent: November 19, 1991Assignee: Ciba-Geigy CorporationInventors: Georg Cseh, Paul Lienhard, Walter Wiedemann
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Patent number: 5057562Abstract: A process is disclosed for the photochemical stabilization of undyed and dyed polypropylene fibre material with light stabilizers, which process comprises treating said material with an aqueous solution containing a light stabilizer from the class of the sterically hindered amines.Type: GrantFiled: June 8, 1989Date of Patent: October 15, 1991Assignee: Ciba-Geigy CorporationInventor: Gerhard Reinert
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Patent number: 5047539Abstract: Heterocyclic amidine derivatives of the general formula I ##STR1## in which the variables R.sup.1 are the same or different and denote hydrogen, C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -alkoxy, hydroxyl or chlorine,R.sup.2 to R.sup.5 denote hydrogen or C.sub.1 -C.sub.4 -alkyl and R.sup.3 and R.sup.4 can together form a five-membered or six-membered ring,R.sup.6 denotes hydrogen or C.sub.1 -C.sub.8 -alkyl,R.sup.7 denotes cyano or --COOR.sup.8, --COR.sup.8, --CONHR.sup.8 or --CONR.sup.8.sub.2, in whichR.sup.8 is a straight-chain or branched-chain C.sub.1 -C.sub.12 -alkyl group which may be interrupted by oxygen atoms, a cyclopentyl or cyclohexyl group or a phenylalkyl group having from 1 to 3 carbon atoms in the alkyl moiety,A is a chemical bond or a methylene group which may additionally carry one or two C.sub.1 -C.sub.4 -alkyl radicals, andm and n are each 1 or 2.The said heterocyclic amidine derivatives I serve as UV stabilizers for organic materials.Type: GrantFiled: April 19, 1990Date of Patent: September 10, 1991Assignee: BASF AktiengesellschaftInventors: Peter Spang, Peter Neumann, Hubert Trauth
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Patent number: 5043371Abstract: A resin composition comprises a polybutylene terephthalate, a halogenated bisimide having the formula (1) and a polytetrafluoroethylene resin and is improved in flame retardancy and at the same time moulding properties. It is useful for parts of electric instruments.Type: GrantFiled: February 14, 1989Date of Patent: August 27, 1991Assignee: Polyplastics Co., Ltd.Inventors: Michio Nakano, Hirouki Amono, Hiroshi Nakatsuji
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Patent number: 5017686Abstract: Aromatic polyamides having improved stability with respect to thermal oxidation are produced by adding to the reaction mixture present as a melt, a stabilizing amount, e.g., 0.05-4 mol % based on the sum total of components A and B, of a compound of Formula (I) ##STR1## wherein Q is --O--; --S--; or N--R'";R" and R'" are: --H; C.sub.1 -C.sub.6 -alkyl; or phenyl, e.g., benzimidazole.Type: GrantFiled: January 31, 1990Date of Patent: May 21, 1991Assignee: Huels AktiengesellschaftInventors: Jurgen Finke, Roland Feinauer
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Patent number: 5001171Abstract: It now has been found that uncured modified rubber compositions comprising mixtures of elastomers and a reinforcing filler can be prepared having improved properties.Type: GrantFiled: October 21, 1988Date of Patent: March 19, 1991Assignee: Bridgestone/Firestone, Inc.Inventors: Georg G. Bohm, Daniel F. Graves
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Patent number: 4994323Abstract: Colored, high strength, high modulus p-aramid fibers are prepared by including an organic pigment which is soluble in but not degraded by concentrated sulfuric acid in a p-aramid spinning dope wherein the solvent is concentrated sulfuric acid and spinning the pigment containing dope through an air gap into a coagulation bath and washing and drying the resulting fibers. The dissolved pigment is precipitated by the coagulation bath as particles with a diameter of less than 0.50 microns.Type: GrantFiled: August 1, 1988Date of Patent: February 19, 1991Assignee: E. I. Du Pont de Nemours and CompanyInventor: Kiu-Seung Lee
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Patent number: 4978362Abstract: A thermoplastic resin composition is provided which contains a thermoplastic resin and a colorant in the form of a polyalkyleneoxy-trifluoromethyl aniline colorant provided in said thermoplastic resin in a minor amount sufficient to provide coloration to said resin, said colorant having the formula: ##STR1## wherein R.sub.1 is selected from H, a lower alkyl group containing from 1 to about 10 carbon atoms, CH.sub.2 Cl, CH.sub.2 Br, CH.sub.2 OH, phenyl or ##STR2## wherein R.sub.4 is H or a lower alkyl group containing from 1 to about 9 carbon atoms; R.sub.2 is H, CF.sub.3, a lower alkyl group containing from 1 to about 9 carbon atoms, Cl or Br; R.sub.3 is an aromatic or heteroaromatic containing group, and n is an integer from 2 to about 75.Type: GrantFiled: October 11, 1988Date of Patent: December 18, 1990Assignee: Milliken Research CorporationInventors: Edward W. Kluger, John W. Rekers
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Patent number: 4914145Abstract: As an outline of the invention of the present inventors, the gist of the present invention resides in the following:A polyester composition comprising:(A) 100 parts by weight of a substantially linear polyester comprising, as the main constituent unit, ethylene terephthalate;(B) 0.05 to 15 parts by weight of a crystallization promotor; and(C) 0.1 to 15 parts by weight of at least one plasticizer selected from the group consisting of (C.sub.1), (C.sub.2), (C.sub.3) and (C.sub.4) which are defined as follows:(C.sub.1) a condensation product of a compound of the formula (I):(HQ-R).sub.2 S (I)wherein two R groups may be the same as or different from each other and represent a hydrocarbon group selected from the group consisting of aliphatic, alicyclic, and aromatic hydrocarbon groups and any combination thereof, and two Q groups may be the same as or different from each other and represent oxygen or sulfur, with an organic compound containing two alcoholic or phenolic hydroxyl groups:(C.sub.Type: GrantFiled: June 16, 1987Date of Patent: April 3, 1990Assignee: Mitsui Petrochemical Industries, Ltd.Inventors: Akira Tohdoh, Takashi Nagai, Takayuki Nakano, Takashi Ueda
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Patent number: RE34066Abstract: A primer composition usable for steel sheets and plastic sheets in vehicle bodies consists essentially of a component (A) consisting essentially of at least one resin having a glass transition temperature of not higher than -20.degree. C., preferably not lower than -75.degree. C., and an elongation at break of not less than 400%, preferably not greater than 900%, at 20.degree. C. and a component (B) consisting essentially of at least one crosslinking resin, the weight ratio as solid content of (A) to (B) being 70-99:30-1.Type: GrantFiled: May 2, 1990Date of Patent: September 15, 1992Assignee: Nippon Oil & Fats Co., Ltd.Inventors: Shosaku Yamamoto, Kazuo Kakinuma