Solid Polymer Derived From Unsaturated Hydrocarbon Patents (Class 525/164)
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Patent number: 12215205Abstract: An elastomeric article having a rubber component comprising polyisoprene and an aldehyde aniline condensate, the elastomeric article having less than 1 ppm diisopropyl xanthogen polysulfide residue.Type: GrantFiled: September 5, 2023Date of Patent: February 4, 2025Assignee: Allegiance CorporationInventors: Seong Fong Chen, Wei Cheong Wong
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Patent number: 11780972Abstract: An elastomeric article having a rubber component comprising polyisoprene and an aldehyde aniline condensate, the elastomeric article having less than 1 ppm diisopropyl xanthogen polysulfide residue.Type: GrantFiled: February 1, 2022Date of Patent: October 10, 2023Assignee: ALLEGIANCE CORPORATIONInventors: Seong Fong Chen, Wei Cheong Wong
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Patent number: 11473156Abstract: A method for forming chrome-free retanned leather including: (a) contacting wet white (chrome-free tanned hide) with a retanning mixture comprising from 2% to 15%, by solids weight, based on the wet weight of the wet white, of an amphoteric polymer composition comprising amine functional units and acid functional units; and (b) applying a polymeric overcoat containing an acrylic copolymer with one or more metal transition elements, with a thickness of no greater than 100 microns, to the retanned wet white, is provided. The present invention also provides a chrome-free retanned leather formed by the method.Type: GrantFiled: December 18, 2015Date of Patent: October 18, 2022Assignee: Rohm and Haas CompanyInventors: Edwin Nungesser, Andrew Hejl, Caiyun Li, Pu Luo
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Patent number: 11242435Abstract: An elastomeric article having a rubber component comprising polyisoprene and an aldehyde aniline condensate, the elastomeric article having less than 1 ppm diisopropyl xanthogen polysulfide residue.Type: GrantFiled: July 9, 2020Date of Patent: February 8, 2022Assignee: ALLEGIANCE CORPORATIONInventors: Seong Fong Chen, Wei Cheong Wong
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Patent number: 10759913Abstract: This invention relates generally to vulcanization compounds and relates more specifically to vulcanization compositions with reduced allergenic potential that include accelerator compositions for vulcanizing elastomeric articles. Vulcanization compositions are disclosed that include a single fugitive dihydrocarbyl xanthogen polysulfide accelerator and a single aldehyde-aniline condensate accelerator.Type: GrantFiled: December 11, 2018Date of Patent: September 1, 2020Assignee: Allegiance CorporationInventors: Seong Fong Chen, Wei Cheong Wong
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Patent number: 9056980Abstract: A substrate having a flame retardant polymer chemically bonded to at least a portion of the substrate. The use of a substrate possessing at least a partially coated outer surface of a flame retardant polymer enables the manufacturing of polymer composites, containing the coated substrate, that possess very effective flame retardant performance while reducing the loading levels over conventional flame retardant additives.Type: GrantFiled: February 3, 2012Date of Patent: June 16, 2015Assignee: SACO POLYMERS, INC.Inventors: Jeffrey Jacob Cernohous, Adam R. Pawloski, Kent A. Kaske, David Geraint Roberts
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Patent number: 9023947Abstract: An adsorptive carrier includes one or more high-molecular-weight compounds each of which includes two or more aromatic ring-containing repeating units, the aromatic rings being covalently bound to each other via a structure represented by Formula (I): wherein R1 represents hydrogen or an organic group, and R2 represents an organic group.Type: GrantFiled: August 8, 2012Date of Patent: May 5, 2015Assignee: Toray Industries, Inc.Inventors: Naotoshi Tomita, Yoshiyuki Ueno
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Publication number: 20150119527Abstract: The invention relates to a rubber composition comprising a rubber and a processing additive wherein the processing additive is a functional reactive diluent having at least one functional group in the molecule which is not an olefinic unsaturation, to a process of compounding such rubber compositions, and to the use thereof.Type: ApplicationFiled: April 28, 2013Publication date: April 30, 2015Applicant: ALLNEX GERMANY GmbHInventor: Ralph Schäfer
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Publication number: 20140206818Abstract: An adsorptive carrier includes one or more high-molecular-weight compounds each of which includes two or more aromatic ring-containing repeating units, the aromatic rings being covalently bound to each other via a structure represented by Formula (I): wherein R1 represents hydrogen or an organic group, and R2 represents an organic group.Type: ApplicationFiled: August 8, 2012Publication date: July 24, 2014Applicant: TORAY INDUSTRIES, INC.Inventors: Naotoshi Tomita, Yoshiyuki Ueno
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Publication number: 20140163171Abstract: A substrate having a flame retardant polymer chemically bonded to at least a portion of the substrate. The use of a substrate possessing at least a partially coated outer surface of a flame retardant polymer enables the manufacturing of polymer composites, containing the coated substrate, that possess very effective flame retardant performance while reducing the loading levels over conventional flame retardant additives.Type: ApplicationFiled: February 3, 2012Publication date: June 12, 2014Applicant: INTERFACIAL SOLUTIONS IP, LLCInventors: Jeffrey Jacob Cernohous, Adam R. Pawloski, Kent A. Kaske, David Garaint Roberts
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Publication number: 20130237665Abstract: A product is provided having a biobased component where the biobased component includes recycle polyester resin and the recycle polyester resin includes polyethylene terephthalate, polybutylene, or polypropylene terephthalate. The biobased component includes a polyester resin where the polyester resin is the co-reaction product of an aliphatic polyester having renewable components and a recycle polyester resin. Included is a composition having a filler and a polymeric binder. The filler includes inorganic biobased filler or recycle thermoset resin based filler.Type: ApplicationFiled: May 2, 2013Publication date: September 12, 2013Applicant: ARMSTRONG WORLD INDUSTRIES, INC.Inventors: Dong TIAN, Gary A. SIGEL, Fang QIAO, Rebecca L. WINEY, Jeffrey S. ROSS
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Publication number: 20120196081Abstract: The invention relates to a new binder composition which is particularly suitable for the manufacture of composite materials utilizing such new binder composition in the required nonwoven materials. Composite materials using such new binder composition in their nonwoven part are suitable, in particular, for composites materials for interior construction, for linings, floor coverings, and for the manufacture of furniture and similar products.Type: ApplicationFiled: September 24, 2010Publication date: August 2, 2012Inventors: Klaus Friedrich Gleich, Philip Francis Miele, Michael Ketzer
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Patent number: 8034876Abstract: There are provided an organic fiber-reinforced composite resin composition which is good in fiber dispersion, excellent in appearance, excellent in mechanical properties such as tensile elongation at break or impact strength and easy in thermal recycle; and a molded article obtained therefrom. An organic fiber-reinforced composite resin composition comprising (a) 60 to 95% by weight of a polyolefin resin (provided that an acid-modified polyolefin resin is excluded) and (b) 40 to 5% by weight (provided that (a)+(b)=100% by weight) of organic fiber to which a polar resin (provided that an acid-modified polyolefin resin is excluded) is attached, or an organic fiber-reinforced composite resin composition comprising organic fiber in an amount of 10 to 200 parts by weight based on 100 parts by weight of a polyolefin resin and having an Izod impact strength at ?40° C. of 10 kJ/m2 or more, and further, an organic fiber-reinforced composite resin molded article obtained therefrom.Type: GrantFiled: November 6, 2007Date of Patent: October 11, 2011Assignees: Mitsubishi Chemical Corporation, Teijin Fibers LimitedInventors: Masatoshi Oomori, Takayuki Itou, Takakazu Yoshihara, Taku Kitade
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Patent number: 8017695Abstract: This invention relates to a method for producing functionalized cis-1,4-polydienes having a combination of a high cis-1,4-linkage content and a high functionality, the resulting polymers and the vulcanized products containing the polymers. The functionalized cis-1,4-polydienes of the present invention are produced by a method comprising the steps of: (1) preparing a reactive polymer by polymerizing conjugated diene monomer with a lanthanide-based catalyst in the presence of less than 20% by weight of organic solvent based on the total weight of monomer, organic solvent, and resulting polymer, where the lanthanide-based catalyst is the combination of or reaction product of (a) a lanthanide compound, (b) an aluminoxane, (c) an organoaluminum compound other than an aluminoxane, and (d) a halogen-containing compound; and (2) contacting the reactive polymer with a functionalizing agent.Type: GrantFiled: December 27, 2007Date of Patent: September 13, 2011Inventors: Steven Luo, Junko Kurazumi, Yoichi Ozawa, Timothy L. Tartamella, Mark Smale, Kevin McCauley
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Patent number: 7829610Abstract: The present invention relates to a polyoxymethylene molding composition comprising: (A) from 0.1 to 5.0% by weight of a compatibilizer, (B) from 5 to 50% by weight of an impact modifier, (C) the remainder to 100% by weight of a polyoxymethylene. The molding compositions of the invention have substantially improved mechanical properties, in particular impact resistance.Type: GrantFiled: August 13, 2007Date of Patent: November 9, 2010Assignee: Ticona GmbHInventor: Nicolai Papke
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Patent number: 7759436Abstract: Film-forming materials include nonionic metal coordinating structures. Nonionic metal coordinating structures can coordinate metals, such as metal catalysts and metal substrates. Example film-forming materials can be the product of a poly-functional epoxide and a nucleophilic ligand having a nonionic metal coordinating structure, or the product of a poly-functional alcohol and an electrophilic ligand having a nonionic metal coordinating structure.Type: GrantFiled: October 26, 2006Date of Patent: July 20, 2010Assignee: BASF Coatings GmbHInventors: Timothy S. December, Sergio Gonzalez, Günther Ott, Karl-Heinz Grosse-Brinkhaus
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Patent number: 6992140Abstract: The present invention provides a curable unsaturated resin composition, which has less odor characteristics and high safety and is also superior in thin film coating characteristics in a coating film. The curable unsaturated resin composition contains a polymerizable unsaturated resin (A) having two or more polymerizable unsaturated double bonds in a molecule, a hydroxyalkyl (meth)acrylate (B), and an unsaturated compound (C) having one or more cyclohexene rings and two or more allyl ether groups in a molecule, which is liquid at normal temperature.Type: GrantFiled: May 17, 2002Date of Patent: January 31, 2006Assignee: Dainippon Ink and Chemicals, Inc.Inventors: Makoto Kosono, Katsuhiro Doi, Koji Kirisawa, Youko Kawasaki
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Patent number: 6766108Abstract: A lens-fitted photo film unit of a waterproof type comprises a unit body covered with a case body and a lid member. A front window and a top window of the case body are made of transparent plastic. The lid member is also made of the transparent plastic. Methacrylate styrene resin is utilized as the transparent plastic, which is used for a taking lens, a viewfinder lens, and an underwater case constituted of the case body and the lid member. This transparent plastic is hardly clouded even if cosmetics of suntan lotion and so forth adhere thereto. Moreover, a poisonous gas causing photographic-film fog is prevented from rising so that photographic properties are not damaged.Type: GrantFiled: June 11, 2002Date of Patent: July 20, 2004Assignee: Fuji Photo Film Co., Ltd.Inventor: Keiji Uchiyama
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Patent number: 6686418Abstract: A process for reducing the heat evolution on dynamic stressing of vulcanised rubber products, using for this purpose, in vulcanizable rubber mixtures, mixtures made from non-selfcuring novolaks A and from unetherified or partially etherified triazine resins B, as a combination of reinforcing resin and curing agent.Type: GrantFiled: May 22, 2001Date of Patent: February 3, 2004Assignee: Solutia Germany GmbH & Co. KGInventors: Siegfried Wallenwein, Frank Scholl, Helmut Eckes
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Patent number: 6329450Abstract: The present invention relates to a blend of polymeric materials comprising; (A) of from about 1 to about 80 percent by weight (based on the combined weights of Components A and B) of at least one substantially random interpolymer; wherein said interpolymer; (1) contains of from about 0.5 to about 50 mole percent of polymer units derived from; a) at least one vinyl or vinylidene aromatic monomer, or b) at least one hindered aliphatic or cycloaliphatic vinyl or vinylidene monomer, or c) a combination of at least one vinyl or vinylidene aromatic monomer and at least one hindered aliphatic or cycloaliphatic vinyl or vinylidene monomer; (2) contains of from about 50 to about 99.5 mole percent of polymer units derived from at least one aliphatic &agr;-olefin having from 2 to 20 carbon atoms; (3) has a melt index (I2) of from about 0.01 to about 100 g/10 min; and (4) has a molecular weight distribution (Mw/Mn) of from about 1.Type: GrantFiled: March 2, 1999Date of Patent: December 11, 2001Assignee: The Dow Chemical CompanyInventors: Samuel A. Ogoe, Charles F. Diehl, Leo A. Novak, Wendy D. Hoenig, Shaofu Wu, Donna C. Scott
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Patent number: 5773511Abstract: The present invention relates to a coating composition which is excellent in handling and safety, enables the curing of the resultant coating composition at low temperature, and provides an excellent adhesion to polyolefin resin moldings. The coating composition comprises (1) 40-90 wt. % of a grafted and chlorinated polyolefin oligomer obtained by graft polymerizing a vinyl polymerizable monomer to a chlorinated polyolefin, the grafted and chlorinated polyolefin oligomer having a primary or blocked primary hydroxyl group at a position of 15 to 40 atoms away from the vinyl graft polymer chain grafted to the chlorinated polyolefin, a number average molecular weight of 5,000 to 50,000, 0.4 to 2.5 mole/kg-resin of a primary or blocked primary hydroxyl group, 50 to 95 wt. % of said vinyl graft polymer chain, and 5 to 50 wt. % of the chlorinated polyolefin used as a starting material, and (2) 60 to 10 wt. % of an imino-type, methylol-type or complete alkoxy-type melamine resin.Type: GrantFiled: November 20, 1995Date of Patent: June 30, 1998Assignee: Mazda Motor CorporationInventors: Yoshiaki Marutani, Mika Ohsawa
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Patent number: 5726248Abstract: This invention relates to a novel class of polymeric compositions which have molecular weights ranging from 300 to 10,000 and are the reaction product of (a) an N-aryl or N-alkaryl substituted diphenyldiamine and (b) a conjugated or nonconjugated diene. These polymeric N-aryl substituted and N-alkaryl diphenyldiamine compounds are particularly useful as an antioxidant in diene containing polymers.Type: GrantFiled: January 22, 1997Date of Patent: March 10, 1998Assignee: The Goodyear Tire & Rubber CompanyInventors: Lawson Gibson Wideman, Paul Harry Sandstrom, Denise Jeannette Keith
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Patent number: 5721317Abstract: A crosslinkable waterborne dispersion of a hydroxy functional polydiene polymer composition which comprises: (a) 10 to 65% w of a hydroxy functional polydiene polymer, (b) 0.2 to 25% w of a compatible amino resin, (c) 0.1 to 10% w of a surfactant which is nonionic or anionic and has a volatile cation, and (d) the balance water. The invention also describes a water-continuous process and an inversion processes for making such dispersions.Type: GrantFiled: July 12, 1996Date of Patent: February 24, 1998Assignee: Shell Oil CompanyInventors: David John St. Clair, James Robert Erickson
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Patent number: 5629382Abstract: Self-extinguishing polymeric compositions comprising ammonium polyphosphate aving the general formula (I):(NH.sub.4).sub.n+2 P.sub.n O.sub.3n+1 (I)microencapsulated with condensation compounds obtained by means of the polymerization of polyaminic compositions essentially constituted by derivatives of 2,4,6-triamino-1,3,5-triazine, having the general formula (II): ##STR1## with aldehydes, preferably formaldehyde.Type: GrantFiled: September 16, 1994Date of Patent: May 13, 1997Assignee: Ministero Dell'Universita'e Della Ricerca Scientifica e TecnologicaInventors: Roberto Cipolli, Roberto Oriani, Enrico Masarati, Gilberto Nucida
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Patent number: 5587418Abstract: The present invention intends to provide a thermosetting coating composition provided with workability, excellent adhesion, weatherability, good appearance, etc. capable of use in a primerless colored base coat and top clear coat by a 2-coat, 1-bake method on a polyolefinic substrate. Moreover, the present invention intends to provide a coated body having excellent adhesion, weatherability, good appearance, etc. realized by a 2-coat, 1-bake method. This thermosetting coating composition is a composition comprising a graft copolymer obtained by copolymerizing acrylic monomer, unsaturated carboxylic acids, acrylic monomers containing hydroxyl group with chlorinated polyolefin containing anhydride in the presence of organic solvents. This coating composition is available for use as a primerless colored base coat 2-coat, 1-bake coating on the polyolefinic substrates.Type: GrantFiled: June 5, 1995Date of Patent: December 24, 1996Assignees: Nissan Motor Co., Ltd, TBL Co., Ltd.Inventors: Ryo Sasaki, Toshiro Ina
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Patent number: 5556920Abstract: An at least monoaxially stretched polypropylene film made of a composition comprising a crystalline polypropylene and a monocyclic olefin polymer (e.g. a polycyclobutene or a polycyclopentene), wherein the content of the monocyclic olefin polymer is 0.1-1,000 ppm by weight.The polypropylene film is superior not only in transparency but also in image clarity by which an image is clearly seen through the film.The polypropylene film, when further comprising talc having an average particle diameter of 0.1-10 .mu.m in an amount of 50-4,000 ppm by weight, can prevent the surface roughening or edge roughening of sheet during the sheet formation conducted before stretched film production.The polypropylene film, when further comprising an anti-blocking agent and a polyethylene together, can prevent the generation of voids caused by the anti-blocking agent.Type: GrantFiled: July 7, 1995Date of Patent: September 17, 1996Assignee: Tokuyama CorporationInventors: Shinsuke Tanaka, Manabu Kaminaka, Isao Masada, Junichi Fujii, Naoki Ueda
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Patent number: 5504159Abstract: The present invention relates to a composition which exhibits antiozonant activity in diene containing rubbers comprising the reaction product of a multi-step process comprising:(1) reacting under condensation conditions an aldehyde and an amine containing compound to form a condensation product, whereinsaid aldehyde is selected from the group consisting of formaldehyde, acetaldehyde or mixtures thereof; andsaid amine containing compound is selected from the group consisting of: N,N'-di-substituted-p-phenylene diamines of the structural formula: ##STR1## wherein R.sup.1 and R.sup.2 are independently selected from the group of radicals consisting of alkyls having 3 to 12 carbon atoms, aryls having 6 to 12 carbon atoms and aralkyls having 7 to 12 carbon atoms; and wherein said condensation conditions include:(i) the presence of an acid catalyst,(ii) a mole ratio of aldehyde to amine containing compound ranging from about 1.Type: GrantFiled: January 11, 1995Date of Patent: April 2, 1996Assignee: The Goodyear Tire & Rubber CompanyInventors: Budd H. Sturm, Joseph A. Kuczkowski, Paul H. Sandstrom, George F. Balogh
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Patent number: 5376650Abstract: Provided are light-absorbing polymers which contain backbone unsaturations and which are produced by knoevenagel condensation and which are useful for imparting color and/or ultraviolet light screening properties to thermoplastic resins. The polymeric colorants or UV absorbers may be added during the formation of the uncolored thermoplastic polymer or melt or solution blended with other thermoplastic polymers.Type: GrantFiled: March 3, 1994Date of Patent: December 27, 1994Assignee: Eastman Chemical CompanyInventors: Max A. Weaver, James J. Krutak, Clarence A. Coates, Wayne P. Pruett, Samuel D. Hilbert
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Patent number: 5356970Abstract: A process for making polymers of conjugated dienes which contain hydroxyl groups in the diene blocks which comprises(a) making a precursor polymer by polymerizing at least one conjugated diene which leaves 1,2 disubstituted, 1,1 disubstituted, 1,1,2 trisubstituted or tetrasubstituted olefinic unsaturation in the polymer,(b) optionally partially hydrogenating said precursor polymer,(c) epoxidizing said precursor polymer such that epoxy groups form at said substituted sites and the amount of epoxy functionality in the polymer is from 0.1 to 5 Meq/g polymer, and(d) reacting the epoxidized polymer with an alcohol solution of hydrochloric acid.A diene polymer containing 0.1 to 10 Meq/g polymer of hydroxyl group and comprised of alcohol units of the formula ##STR1## where R.sub.1 and R.sub.2 are hydrogen or alkyl radicals and X and X' are either --OH or --Cl and at least one of them is --OH.Type: GrantFiled: March 24, 1994Date of Patent: October 18, 1994Assignee: Shell Oil CompanyInventors: Robert C. Bening, James R. Erickson, David J. St. Clair, Carma J. Gibler, Joe J. Flores
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Patent number: 5331052Abstract: Curable composition based on branched acrylates with COOH groups and/or branched acrylates with epoxide groups, and aminoplast resins.The present invention relates to a curable composition consisting ofA) a polymer with at least 2 COOH groups,B) a polymer with at least 2 epoxide groups andC) an aminoplast resin.At least one of components A) or B) is based on a branched soluble acrylate copolymer, more than 3 to 30% by weight, based on the total weight of the monomers, of a monomer with at least two polymerizable, olefinically unsaturated double bonds being used in the preparation of these branched acrylate copolymers and the proportions of the individual components relative to one another being chosen so that a molar ratio of 3:1 to 1:3 prevails between the carboxyl groups of component A) and the epoxide groups of component B) and a weight ratio of 65:35% by weight to 98:2% by weight prevails between the epoxy resin component and the aminoplast resin component.Type: GrantFiled: September 29, 1989Date of Patent: July 19, 1994Assignee: BASF Lacke + Farben AGInventor: Werner A. Jung
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Patent number: 5298560Abstract: A partially crosslinked thermoplastic resin composition is prepared by dynamically heat-treating a thermoplastic resin (A) in the presence of a carbon radical inducing agent (B) comprising a charge transfer complex or a combination of a hydrogen donating compound and a hydrogen accepting compound.Type: GrantFiled: May 14, 1991Date of Patent: March 29, 1994Assignee: Nippon Petrochemicals Company, LimitedInventors: Fuyuki Aida, Masaaki Miyazaki, Mamoru Nagai
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Patent number: 5298539Abstract: New additives in rubber compositions improve tire cord adhesion without need to use resorcinol. The new additives are derivatives of melamine, aceto guanamine, benzoguanamine, cyclohexylguanamine, and glycoluril, substituted with at least two vinyl-terminated radicals. Preferred compounds may also be substituted with at least one radical having a carbamylmethyl group.Type: GrantFiled: September 5, 1990Date of Patent: March 29, 1994Assignee: Cytec Industries, Inc.Inventors: Balwant Singh, John A. Sedlak
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Patent number: 5283292Abstract: The invention provides acrylic-based heat-resistant bicomponent structural adhesives comprising:a) a first adhesive component consisting of:an elastomer;a monofunctional acrylic monomer;a free radical generator;a solution stabilizer;an adhesion promoter;a cross-linking agent;a heat stabilizer for the adhesive, chosen from maleimide derivates containing acrylic residues; andb) a second component activating the first adhesive component and consisting of:a mixture of aldehyde-amine condensation products;an organic salt of a metal of the first transition series of low oxidation state.Type: GrantFiled: October 27, 1992Date of Patent: February 1, 1994Assignee: Ministero dell'Universita' e della Ricerca Scientifica e TecnologicaInventors: Vittorio Di Ruocco, Liliana Gila, Fabio Garbassi
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Patent number: 5280071Abstract: The present invention relates to a composition which exhibits antiozonant activity in diene containing rubbers comprising the reaction product of a multi-step process comprising:(1) reacting under condensation conditions an aldehyde and an amine containing compound to form a condensation product, whereinsaid aldehyde is selected from the group consisting of formaldehyde, acetaldehyde or mixtures thereof; andsaid amine containing compound is selected from the group consisting of:N,N'-di-substituted-p-phenylene diamines of the structural formula: ##STR1## wherein R.sup.1 and R.sup.2 are independently selected from the group of radicals consisting of alkyls having 3 to 12 carbon atoms, aryls having 6 to 12 carbon atoms and aralkyls having 7 to 12 carbon atoms; and wherein said condensation conditions include:(i) the presence of an acid catalyst,(ii) a mole ratio of aldehyde to amine containing compound ranging from about 1.Type: GrantFiled: April 5, 1991Date of Patent: January 18, 1994Assignee: The Goodyear Tire & Rubber CompanyInventors: Budd H. Sturm, Joseph A. Kuczkowski, Paul H. Sandstrom, George F. Balogh
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Patent number: 5274022Abstract: This invention relates to compositions of polyarylene sulphides (PAS), melamine resins and rubbers. The compositions are distinguished by very great toughness.Type: GrantFiled: February 20, 1992Date of Patent: December 28, 1993Assignee: Bayer AktiengesellschaftInventors: Wolfgang Ruesseler, Burkhard Koehler
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Patent number: 5258457Abstract: This invention is a method of curing unsaturated polymers which do not have a significant amount of functional groups which undergo a cross-linking reaction with amino resins and which preferably comprise at least one conjugated diolefin monomer, said method comprising mixing said polymer with an amino resin in the presence of a proton-donating acid catalyst.Type: GrantFiled: March 23, 1992Date of Patent: November 2, 1993Assignee: Shell Oil CompanyInventor: James R. Erickson
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Patent number: 5247014Abstract: This invention is a method of curing unsaturated polymers which do not have a significant amount of functional groups which undergo a crosslinking reaction with amino resins and which preferably comprise at least one conjugated diolefin monomer, said method comprising mixing said polymer with an amino resin in the presence of a proton-donating acid catalyst.Type: GrantFiled: March 23, 1992Date of Patent: September 21, 1993Assignee: Shell Oil CompanyInventor: James R. Erickson
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Patent number: 5239003Abstract: A process for preparing a styrene resin composition which comprises subjecting to bulk or bulk-suspension polymerization a solution obtained by dissolving (A) a modified styrene polymer obtained by introducing directly or through another atomic group at least one functional group represented by the general formula>C.dbd.N.sup.+ <into the polymer chain of a styrene polymer obtained by polymerizing 90 to 100% by weight of a styrene monomer with 0 to 10% by weight if a monomer copolymerizable with the styrene monomer, if desired together with (B) a rubber-like polymer in (C) a styrene monomer.Type: GrantFiled: November 27, 1991Date of Patent: August 24, 1993Assignee: Nippon Zeon Co., Ltd.Inventors: Hidenori Onishi, Hiroyuki Watanabe
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Patent number: 5237008Abstract: Incorporation of 0.2 to 3.0 weight percent of linear low density polyethylene into polyoxymethylene compositions results in improved elongation for such compositions.Type: GrantFiled: December 13, 1991Date of Patent: August 17, 1993Assignee: E. I. Du Pont de Nemours and CompanyInventor: Leonard E. R. Kosinski
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Patent number: 5182335Abstract: The addition of elastomeric thermoplastic polymers and melamine resin to the polymer matrix of composite materials for the moulding of fibre-reinforced unsaturated polyester resin improves the surface characteristics, resilience, and mouldabilty and heat resistance thereof.Type: GrantFiled: December 4, 1990Date of Patent: January 26, 1993Assignee: Fiat Auto SpAInventor: Mario Da Re'
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Patent number: 5159016Abstract: A thermoplastic resin composition is prepared by heat-treating a mixture of a thermoplastic resin substantially containing no olefinic unsaturated carbon-carbon bond and an elastomer having an olefinic unsaturated carbon-carbon bond, dynamically in the presence of a crosslinking agent, characterized in that as said elastomer there is used at least one member selected from the group consisting of styrene-butadiene-styrene block copolymer (SBS), styrene-iosprene-styrene block copolymer (SIS), 1,2-polybutadiene rubber and ethylene-propylene-diene random copolymer (EPDM), and that as said crosslinking agent there is used a dihydroaromatic compound or a polymer thereof.Type: GrantFiled: December 27, 1988Date of Patent: October 27, 1992Assignee: Nippon Petrochemicals Company, LimitedInventors: Toshio Inoue, Shiyuji Kashiwase, Masaaki Miyazaki, Toshitsune Yoshikawa, Masaaki Kobayashi
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Patent number: 5131922Abstract: Oxidized polyisobutenes, that is polyisobutenes containing ketonic and carboxylic acid carbonyl groups, are produced by passing through a column of the polyisobutene maintained at a temperature in the range from 140.degree. to 200.degree. C. and at atmospheric or elevated total pressure a molecular oxygen-containing gaseous oxidant at a gas flow rate greater than 10 liters cm.sup.-2 h.sup.-1 measured at the operating pressure. The oxidized polyisobutenes can be reacted for example with an aliphatic polyamine to produce a lubricating oil additive or with an aliphatic polyamide and formaldehyde to produce a fuels additive.Type: GrantFiled: October 7, 1991Date of Patent: July 21, 1992Assignee: BP Chemicals (Additives) LimitedInventor: Michael J. Clarke
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Patent number: 5124405Abstract: This invention is a method of curing unsaturated polymers which do not have a significant amount of functional groups which undergo a cross-linking reaction with amino resins and which preferably comprise at least one conjugated diolefin monomer, said method comprising mixing said polymer with an amino resin in the presence of a proton-donating acid catalyst.Type: GrantFiled: July 27, 1990Date of Patent: June 23, 1992Assignee: Shell Oil CompanyInventor: James R. Erickson
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Patent number: 5086115Abstract: Oxidised polyisobutenes, that is polyisobutenes containing ketonic and carboxylic acid carbonyl groups, are produced by passing through a column of the polyisobutene maintained at a temperature in the range from 140.degree. to 200.degree. C. and at atmospheric or elevated total pressure a molecular oxygen-containing gaseous oxidant at a gas flow rate greater than 10 liters cm.sup.-2 h.sup.-1 measured at the operating pressure. The oxidized polysisobutenes can be reacted for example with an aliphatic polyamine to produce a lubricating oil additive or with an aliphatic polyamine and formaldehyde to product a fuels additive.Type: GrantFiled: April 26, 1991Date of Patent: February 4, 1992Assignee: BP Chemicals (Additives) LimitedInventor: Michael J. Clarke
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Patent number: 5068287Abstract: A primer composition usable for steel sheets and plastic sheets in vehicle bodies consists essentially of a component (A) consisting essentially of at least one resin having a glass transition temperature of not higher than -20.degree. C., preferably not lower than -75.degree. C., and an elongation at break of not less than 400% preferably not greater than 900%, at 20.degree. C. and a component (B) consisting essentially of at least one crosslinking resin, the weight ratio of solid content of (A) to (B) being 70-99:30-1.Type: GrantFiled: November 9, 1990Date of Patent: November 26, 1991Assignee: Nippon Oil and Fats Co., Ltd.Inventors: Shosaku Yamamoto, Kazuo Kakinuma
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Patent number: 5019617Abstract: Rubber compositions are disclosed which exhibit enhanced dynamic modulus and tensile strength characteristics. A selected type of carbon black, resorcinsol and/or its precondensate and hexamethoxymethyl melamine are combined in specified amounts with a selected class of starting rubbers. The carbon black has specified nitrogen adsorption surface area, dibutyl phthalate adsorptivity and Dst mode of diameter.Type: GrantFiled: September 21, 1989Date of Patent: May 28, 1991Assignee: The Yokohama Rubber Co., Ltd.Inventors: Hiroyuki Kaidoo, Takao Muraki
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Patent number: 4985500Abstract: A primer composition usable for steel sheets and plastic sheets in vehicle bodies consists essentially of a component (A) consisting essentially of at least one resin having a glass transition temperature of not higher than -20.degree. C., preferably not lower than -75.degree. C., and an elongation at break of not less than 400%, preferably not greater than 900%, at 20.degree. C. and a component (B) consisting essentially of at least one crosslinking resin, the weight ratio of solid content of (A) to (B) being 70-99:30-1.Type: GrantFiled: May 23, 1988Date of Patent: January 15, 1991Assignee: Nippon Oil and Fats Co., Ltd.Inventors: Shosaku Yamamoto, Kazuo Kakinuma
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Patent number: 4952637Abstract: Fuel oils and lubricants of improved properties contain ethylene-propylene copolymers bearing units derived from N-vinyl pyrrolidone and phenothiazine.Type: GrantFiled: July 22, 1988Date of Patent: August 28, 1990Assignee: Texaco Inc.Inventors: Maria M. Kapuscinski, Larry D. Grina, Ronald E. Jones, Rodney Lu-Dai Sung
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Patent number: 4892908Abstract: A vulcanizable rubber composition and method for making the same in which the rubber component is mixed with a methylene donor and acceptor and the methylene acceptor is a compound of the general structural formula ##STR1## wherein R may be the same or different radicals and is consisting of hydrogen, alkyl of 1 to about 20 carbon atoms, aryl of about 6 to about 12 carbon atoms, R.sub.1 is --H, --OH, --O--CO--R.sub.3 or --O--R.sub.4 and R.sub.3 and R.sub.4 are each an alkyl or aryl group having 1 to about 12 carbon atoms, andWherein R.sub.2 is a hydrogen radical, saturated or unsaturated of 1 to about 20 carbon atoms, naphtyl or an aromatic radical of the formula ##STR2## wherein R may be the same of different and is defined as above.Type: GrantFiled: July 5, 1988Date of Patent: January 9, 1990Assignee: Indspec Chemical CorporationInventors: Bojayan Durairaj, Alex P. Peterson, Jr., Gideon Salee
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Patent number: 4780508Abstract: The extrudability of linear polymers of ethylene such as low density copolymers of ethylene and C.sub.4 -C.sub.10 olefins (LLDPE) into thin films is improved by adding small amounts, e.g., 0.02 to 1 weight percent polyacetal fluoride to reduce melt fracture, head pressure and extruder torque.Type: GrantFiled: December 30, 1987Date of Patent: October 25, 1988Assignee: Mobil Oil CorporationInventors: Theresa L. Cunningham, Richard G. Shaw, Tien-Kuei Su