Solid Polymer Derived From Unsaturated Hydrocarbon Patents (Class 525/164)
  • Patent number: 4708907
    Abstract: A writable adhesive tape is disclosed, which comprises a polyolefine substrate, having on one side an adhesive layer and on the opposite side a writable anti-adhesive layer. The writable anti-adhesive layer comprises 25% to 55% by weight of a chlorinated polyolefine, 20% to 50% by weight of a polyaldehyde resin together with 5% to 20% by weight of an anti-adhesive agent, and 5% to 25% by weight of a matting charge.
    Type: Grant
    Filed: April 26, 1985
    Date of Patent: November 24, 1987
    Assignee: Boston S.p.A.
    Inventors: Fulvio Flutti, Franco Ghezzi
  • Patent number: 4694042
    Abstract: Elastomeric thermoplastic molding materials contain(A) from 5 to 50 parts by volume of a partially or completely crystalline thermoplastic polymer having a melting point of above 160.degree. C., as a coherent phase, and(B) from 95 to 50 parts by volume of one or more crosslinked elastomeric polymers which are prepared by emulsion polymerization, are dispersed in the component A and have a glass transition temperature Tg of below -10.degree. C., the sum of A and B being 100 parts by volume, with the proviso that the mixture of A and B has a Vicat softening temperature, measured according to DIN 53,460, which is 5.degree.-40.degree. C. lower than that of the component A, with or without(C) effective amounts of conventional assistants.
    Type: Grant
    Filed: January 31, 1985
    Date of Patent: September 15, 1987
    Assignee: BASF Aktiengesellschaft
    Inventors: Graham E. McKee, Hilmar Ohlig, Horst Reimann, Hans-Josef Sterzel
  • Patent number: 4666986
    Abstract: There is disclosed the reaction product of an N-(substituted oxymethyl)melamine and a 2-mercaptoarylthiazole and its use as an adhesion promoter to improve rubber to metal wire adhesion.
    Type: Grant
    Filed: November 21, 1985
    Date of Patent: May 19, 1987
    Assignee: The Goodyear Tire & Rubber Company
    Inventor: William W. Schloman, Jr.
  • Patent number: 4663392
    Abstract: A process for the preparation of oil-soluble Mannich condensation products wherein an amine is prereacted with a sulfonic acid or ammonium sulfonate, oleic acid, and an oxidized olefin polymer and the prereaction product is reacted with an aldehyde.
    Type: Grant
    Filed: May 16, 1986
    Date of Patent: May 5, 1987
    Assignee: Amoco Corporation
    Inventors: Yoon S. Song, Henry A. McCandless
  • Patent number: 4632960
    Abstract: A resin composition comprising 100 parts by weight of a thermosetting resin and 1 to 100 parts by weight of a functional, rubbery copolymer containing among the monomer units which constitute the copolymer, at least one monomer containing a substituent selected from the group consisting of epoxy, hydroxyl, carboxyl and amino groups, said copolymer being prepared by one of three emulsion polymerization processes in which a nonionic surface active agent and/or ionic surface active agent is employed as the emulsifying agent.
    Type: Grant
    Filed: August 16, 1985
    Date of Patent: December 30, 1986
    Assignee: Japan Synthetic Rubber Co., Ltd.
    Inventors: Hozumi Sato, Tatsuaki Matsunaga, Shin-ichiro Iwanaga, Hiroji Enyo, Yoshiaki Kawamura, Yasuhiko Takemura
  • Patent number: 4628073
    Abstract: Provided is a method for producing and a soft-rubbery matrix material composed of 0.3-70 micron particles of a 50,000-300,000 molecular weight cross-linkable polymer dispersed in a fluxable elastomer where the polymer's softening point temperature exceeds the elastomer's fluxing temperature and the polymer and elastomer are combined and mixed at a temperature maintained above the fluxing temperature of the elastomer but below the softening point temperature of the polymer.
    Type: Grant
    Filed: October 3, 1984
    Date of Patent: December 9, 1986
    Assignee: Monsanto Company
    Inventor: W. Keith Fisher
  • Patent number: 4609709
    Abstract: A glass fiber binder consisting of a urea-formaldehyde resin, a styrene-butadiene latex copolymer and a fully methylated melamine-formaldehyde copolymer.
    Type: Grant
    Filed: August 19, 1985
    Date of Patent: September 2, 1986
    Assignee: Owens-Corning Fiberglas Corporation
    Inventor: Ben J. Yau
  • Patent number: 4605703
    Abstract: This invention relates to radically hardening adhesives, which contain polymerisable isocyanates and which are distinguished by high adhesive capacity on plastics materials.
    Type: Grant
    Filed: May 23, 1985
    Date of Patent: August 12, 1986
    Assignee: Bayer Aktiengesellschaft
    Inventors: Wolfgang Fischer, Gerhard Klein, Rudoph Hombach, Wilfried Kniege
  • Patent number: 4599382
    Abstract: A rubber composition consisting essentially of 5-99 parts by weight of a thermosetting resin and 94-1 parts by weight of one of the following functional rubber-like copolymers (I) to (III) having a Mooney viscosity ML.sub.1+4.sup.
    Type: Grant
    Filed: March 20, 1985
    Date of Patent: July 8, 1986
    Assignee: Japan Synthetic Rubber Co., Ltd.
    Inventors: Hozumi Sato, Shin-ichiro Iwanaga, Hiroji Enyo, Yasuhiko Takemura, Yoshiaki Kawamura
  • Patent number: 4578450
    Abstract: There is disclosed the reaction product of an N-(substituted oxymethyl)melamine and a 2-mercaptoarylthiazole and its use as an adhesion promoter to improve rubber to metal wire adhesion.
    Type: Grant
    Filed: September 4, 1984
    Date of Patent: March 25, 1986
    Assignee: The Goodyear Tire & Rubber Company
    Inventor: William W. Schloman, Jr.
  • Patent number: 4552803
    Abstract: Fire retardant compositions in the form of a powder are produced from the following components:______________________________________ Component Parts by Weight ______________________________________ Aldehyde 70-140 Ammonium phosphate 50-250 Ammonium, alkali metal or 50-250 alkaline earth metal compound or salt Urea reactant 70-190 Hydroxy reactant 20-60 Phosphoric acid 150-250 ______________________________________Also provided are retardant compositions containing the powder and methods for treating substrates, such as paper or wood, as well as cotton, wool, and synthetic textiles to impart fire retardant properties thereto.
    Type: Grant
    Filed: August 21, 1984
    Date of Patent: November 12, 1985
    Inventor: Glenn A. Pearson
  • Patent number: 4551492
    Abstract: A polyester composition in organic solvents with about 40% polyester, 26% melamine crosslinker and 16% cellulose acetate butyrate provides a coating composition with 18% binder solids.
    Type: Grant
    Filed: December 27, 1984
    Date of Patent: November 5, 1985
    Assignee: E. I. Du Pont de Nemours and Company
    Inventor: Armand Aerts
  • Patent number: 4496694
    Abstract: Storage stable curing agents for acrylate adhesives, which curing agents are miscible with an acrylate resin adhesive, are produced by the mixing together of a polymerizable monomer, a thermoplast or elastomer soluble therein, and a liquid aldehyde/amine condensation product, and subsequent homogenisation of the mixture at elevated temperature. The curing agents, which optionally contain also stabilizers and curing accelerators, can be mixed with acrylate resin adhesives in any chosen quantity ratio between 2:1 and 1:2.
    Type: Grant
    Filed: April 18, 1983
    Date of Patent: January 29, 1985
    Assignee: Ciba-Geigy Corporation
    Inventors: Imre Forgo, Jacques Francois
  • Patent number: 4471087
    Abstract: A highly efficient formaldehyde-free coating composition insolubilizer is prepared by reacting about 3 moles of glyoxal with 1 mole of urea resulting in a formation of a low molecular weight oligomer in a yield of 95-96%. The molar ratio of glyoxal to urea is very critical in obtaining the highest efficiency and is kept within narrow limits. The coating compositions of the present invention possess 2 till 4 times higher wet-rub resistance than the prior art compositions.
    Type: Grant
    Filed: February 28, 1983
    Date of Patent: September 11, 1984
    Assignee: Diamond Shamrock Chemicals Company
    Inventor: Stanley A. Lipowski
  • Patent number: 4468495
    Abstract: Fire retardant compositions in the form of a powder are produced from the following components:______________________________________ Component Parts by Weight ______________________________________ Aldehyde 70-110 Ammonium phosphate 120-180 Ammonium sulfate 120-180 Urea 120-180 Alkanolamine 35-50 Phosphoric acid 100-150 ______________________________________Also provided are fire retardant compositions containing the powder, and methods for treating substrates such as paper or wood to impart fire retardant properties thereto.
    Type: Grant
    Filed: January 28, 1983
    Date of Patent: August 28, 1984
    Inventor: Glenn A. Pearson
  • Patent number: 4459386
    Abstract: For the production of acrylonitrile polymers containing phosphonic acid groups and having phosphorus contents of 1-17% by weight, homo- or copolymers of acrylonitrile having molecular weights of 1,000-200,000 are reacted at temperatures of 120.degree.-220.degree. C. with 0.2-8 moles of phosphorous acid per mole of nitrile group. Preferably, a melt is prepared from phosphorous acid, and the acrylonitrile polymer is added thereto in metered quantities.
    Type: Grant
    Filed: December 14, 1982
    Date of Patent: July 10, 1984
    Assignee: Chemische Werke Huels Aktiengesellschaft
    Inventor: Raban Grundmann
  • Patent number: 4444956
    Abstract: A process for the preparation of oil-soluble Mannich condensation products wherein an amine is prereacted with a sulfonic acid or ammonium sulfonate, and the prereaction product is reacted with an aldehyde and an oxidized olefin polymer.
    Type: Grant
    Filed: November 8, 1982
    Date of Patent: April 24, 1984
    Assignee: Standard Oil Company (Indiana)
    Inventors: John G. Schaffhausen, Adel B. Abdul-Malek
  • Patent number: 4339359
    Abstract: A method for adhering rubber to reinforcing materials which comprises embedding a textile fiber or metal reinforcing material in a vulcanizable rubber composition comprising rubber, a sulfur vulcanizing agent, high surface area silica and an N-(substituted oxymethyl) melamine compound.
    Type: Grant
    Filed: February 17, 1981
    Date of Patent: July 13, 1982
    Assignee: American Cyanamid Company
    Inventor: Rao S. Bezwada
  • Patent number: 4330642
    Abstract: Polymer bound multidentate complexes are prepared by reacting pendant benzyl chloride and benzyl iodide groups on a variety of polymer supports, including crosslinked polystyrene, with 3,3'-iminodiproprionitrile and reducing the nitrile groups by treatment with, for example, a boron hydride-tetrahydrofuran complex to form the amine. The amine is a precursor for other ligand systems; for example, the primary amine groups formed condense with an aldehyde or ketone to yield five coordinate Schiff base ligands. The polydentate amine ligand systems are useful for synthesis of chelating agents for sequestering metal ions from solution for purification or concentration purposes. Metal complexes of these ligands with manganese, iron, cobalt, nickel, copper, and zinc can be prepared which are useful as heterogeneous oxidation catalysts.
    Type: Grant
    Filed: March 20, 1981
    Date of Patent: May 18, 1982
    Assignee: University of Illinois Foundation
    Inventors: John H. Gaul, Jr., Russell S. Drago
  • Patent number: 4284536
    Abstract: A vulcanizable rubber composition comprising a rubber, a vulcanizing agent and various imidazolidinones is disclosed.
    Type: Grant
    Filed: June 23, 1980
    Date of Patent: August 18, 1981
    Assignee: American Cyanamid Co.
    Inventor: Rao S. Bezwada
  • Patent number: 4277529
    Abstract: There is disclosed bonded lightweight tissue paper having improved wet and dry tensile strength and excellent softness and absorbency. The paper is produced by a process which comprises applying a binder composition to a dry web of lightweight soft and absorbent tissue paper, wherein the binder composition comprises an aqueous mixture containing a cross-linkable latex, a cross-linking agent, urea, and a specific combination of inorganic salts.
    Type: Grant
    Filed: February 1, 1978
    Date of Patent: July 7, 1981
    Assignee: Johnson & Johnson
    Inventor: Norman J. Friedman
  • Patent number: 4267285
    Abstract: Composites formed of an organic polymeric matrix and cured thermosetting resinous fibers and/or particles dispersed therein and a method for preparing the same.
    Type: Grant
    Filed: August 20, 1979
    Date of Patent: May 12, 1981
    Inventor: Lawrence J. Broutman
  • Patent number: 4258098
    Abstract: A glass fiber mat having excellent tensile strength and flexibility is provided herein. The mat includes a plurality of glass fibers and a binder therefor which is characterized by comprising about 25% to 90% by weight of a urea-formaldehyde resin and about 10% to 75% by weight of a styrene-butadiene latex copolymer containing about 0.1% to 5% by weight of an acrylamide type monomer.
    Type: Grant
    Filed: June 6, 1979
    Date of Patent: March 24, 1981
    Assignee: GAF Corporation
    Inventors: Alfredo A. Bondoc, Philip A. Cautilli
  • Patent number: 4251410
    Abstract: The reaction between (a) a polymerisate of acrylamide and/or methacrylamide and optionally of one or more further types of polymerizable ethylenic-unsaturated monomers, (b) formaldehyde, (c) a secondary amine and (d) a functional derivative of an acid having stabilizing properties against further polymerization of (a) and containing in the functional radical at least one NH group capable of entering into equilibrium reaction with formaldehyde under the reaction conditions used, e.g. urea, under neutral or basic conditions and in certain molar ratios, produces products, which in free base, acid addition salt or quaternary ammonium salt form are useful as flocculation agents, and particularly as retention aids for paper manufacture.
    Type: Grant
    Filed: November 24, 1978
    Date of Patent: February 17, 1981
    Assignee: Sandoz Ltd.
    Inventors: Bernard Danner, Hans Gerber, Helmut Pummer
  • Patent number: 4246368
    Abstract: A powder coating composition for forming multi layer coatings comprising:(1) at least one of finely divided thermosetting addition copolymers having a glass transition temperature of 35.degree. to 75.degree. C. and comprising as comonomers a wt. % of a hardness imparting monomer and b wt. % of a softness imparting monomer based on the copolymer wherein a+b.ltoreq.60, b.ltoreq.a and b.ltoreq.20, and(2) at least one of finely divided thermosetting resinous materials having incompatibility or low compatibility with the copolymer and a substantially greater surface tension than the copolymer when melted at the same temperature and substantially differing from the copolymer in composite parameter.
    Type: Grant
    Filed: May 5, 1978
    Date of Patent: January 20, 1981
    Assignee: Kansai Paint Company, Limited
    Inventor: Heihachi Murase
  • Patent number: 4230828
    Abstract: Polymer bound multidentate complexes are prepared by reacting pendant benzyl chloride and benzyl iodide groups on a variety of polymer supports, including crosslinked polystyrene, with 3,3'-iminodiproprionitrile and reducing the nitrile groups by treatment with, for example, a boron hydride-tetrahydrofuran complex to form the amine. The amine is a precursor for other ligand systems; for example, the primary amine groups formed condense with an aldehyde or ketone to yield five coordinate Schiff base ligands. The polydentate amine ligand systems are useful for synthesis of chelating agents for sequestering metal ions from solution for purification or concentration purposes. Metal complexes of these ligands with manganese, iron, cobalt, nickel, copper, and zinc can be prepared which are useful as heterogeneous oxidation catalysts.
    Type: Grant
    Filed: December 11, 1978
    Date of Patent: October 28, 1980
    Assignee: The University of Illinois Foundation
    Inventors: John H. Gaul, Jr., Russell S. Drago
  • Patent number: 4206093
    Abstract: A process for the preparation of chlorinated aliphatic polymers wherein chlorine-free polymers are chlorinated by using gaseous chlorine in chlorinated hydrocarbons as solvents and the chlorinated aliphatic polymers are recovered from the chlorinating solution by steam distillation in which process from 15 to 50% by weight of a lacquer resin is added to the chlorinating solution before steam distillation. The chlorinated polymers contain less residual solvent.
    Type: Grant
    Filed: April 27, 1977
    Date of Patent: June 3, 1980
    Assignee: Bayer Aktiengesellschaft
    Inventors: Klaus Hoehne, Johann Jelen, Diez Heine, Rolf Baatz
  • Patent number: 4203874
    Abstract: This invention is directed to a method, a rubber skim stock and a product containing the skim stock having improved adhesion between a metal member and contiguous rubber skim stock. The invention lies in the discovery that improved rubber-to-metal adhesion can be obtained by adding to an otherwise conventional rubber skim stock composition appropriate amounts of a transition salt of p-aminobenzoic acid.The method of this invention comprises the steps of mixing the transition salt of p-aminobenzoic acid into a rubber composition, bringing this composition into contiguous relationship with a metal member in an unvulcanized product and vulcanizing the product to yield the end product.
    Type: Grant
    Filed: September 8, 1978
    Date of Patent: May 20, 1980
    Assignee: The Firestone Tire & Rubber Company
    Inventors: Adel F. Halasa, Frederick J. Ravagnani, Steven E. Schonfeld
  • Patent number: 4198493
    Abstract: Self-extinguishing polymeric compositions, including a thermoplastic polymer and a flameproof additive whose essential components are:(A) an ammonium phosphate or an amine phosphate;(B) one or more organic compounds capable of providing, by thermal decomposition, uninflammable gaseous products and carbonaceous residues; and(C) an ester of the isocyanuric acid of general formula: ##STR1## in which R.sub.1, R.sub.2, R.sub.3, either like or unlike one another, are linear or ramified alkylene groups having 1 to 6 chain-linked carbon atoms, and Z.sub.1, Z.sub.2, Z.sub.3 are --OH or ##STR2## the (B)/(C) ratio by weight varying from 10:1 to 1:10, and components (A) and (B)+(C) being employed each at the rate of 5 to 30% by weight on the total composition.
    Type: Grant
    Filed: September 11, 1978
    Date of Patent: April 15, 1980
    Assignee: Montedison S.p.A.
    Inventor: Franco Marciandi
  • Patent number: 4198471
    Abstract: The combination of a thermoplastic polymer and a thermosetting polymer, provides a pigment system for producing coated printing papers. The thermoplastic polymer and thermosetting polymer, suspended in well-known coating binders and carriers, is applied to the web substrate on a standard paper machine. The amount of thermoset, preferably at least about 25% by weight of the pigment solids, improves ink receptivity and allows adjustable control of finished paper gloss. The amount of thermoset added to the pigment system is limited, however, preferably below about 75% by weight of the pigment solids, so that the finished printing paper obtains a Gardner 75.degree. gloss of at least about 40, at calendering pressures of less than 500 PLI.
    Type: Grant
    Filed: April 4, 1978
    Date of Patent: April 15, 1980
    Assignee: Weyerhaeuser Company
    Inventor: George R. Nelson