Solid Polymer Derived From Ethylenically Unsaturated Hydrocarbon Patents (Class 525/184)
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Patent number: 7300978Abstract: This invention relates to a process for stabilising and at the same time phase compatibilising plastics or plastic compositions by incorporating polymeric compounds obtainable by reacting a compound selected from the group consisting of the sterically hindered phenols, sterically hindered amines, lactones, sulfides, phosphites, benzotriazoles, benzophenones and 2-(2-hydroxyphenyl)-1,3,5-triazines, which compounds contain at least one reactive group, with a compatibilisator.Type: GrantFiled: February 23, 2004Date of Patent: November 27, 2007Assignee: Ciba Specialty Chemicals CorporationInventors: Rudolf Pfaendner, Heinz Herbst, Kurt Hoffmann, Samuel Evans, Alfred Steinmann
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Patent number: 7275574Abstract: Thermoplastic elastomer composition dynamically vulcanized with a 50 to 95% gelation rate has superior heat resistance, durability, and air permeation prevention, is flexible and usable as a pneumatic tire air permeation preventive layer. A composition having reduced domain rubber particle size is produced from a high rubber ratio material by mixing composition (C) under melt viscosities ratio of rubber composition (A)/resin (B) of 0.8 to 1.2 and formula (?A/?B)×(?B/?A)<1.0 under melt viscosities ratio of rubber composition (D)/composition (C) of 0.8 to 1.2 and formula (?D/?C)×(?C/?D)<1.0, wherein ?A, ?B, ?C and ?D are volume fractions of rubber composition (A) and resin (B), composition (C) and rubber composition (D), respectively, ?A ?B, ?C, and ?D are melt viscosities of rubber composition (A), resin (B), composition (C), and rubber composition (D), respectively.Type: GrantFiled: December 13, 2004Date of Patent: October 2, 2007Assignee: The Yokohama Rubber Co., Ltd.Inventors: Jiro Watanabe, Yuichi Hara, Shigeru Yamauchi, Hideo Nemoto
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Patent number: 7270862Abstract: The present invention relates to polyamide (A) and polyolefin (B) blends containing nanofillers in which the polyamide forms the matrix. These blends can also be referred to as “polyamide (A), polyolefin (B) and nanofiller blends in which the polyamide forms the matrix”. The invention also relates to structures with barrier properties comprising at least one layer of these blends and optionally at least one layer of another material. These structures are a barrier to numerous fluids, and in particular to oxygen, to styrene, to fumigation fluids, to pentane and to air conditioning fluids. These structures can be made into bottles, reservoirs, containers, pipes and vessels of all sorts. They can also be converted to films which are used to make packagings.Type: GrantFiled: December 12, 2005Date of Patent: September 18, 2007Assignee: Arkema FranceInventors: Jean-Jacques Flat, Benoît Barriere, Benoît Brule
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Patent number: 7256236Abstract: Disclosed are methods for advantageously producing maleated polypropylenes having a relatively high percentage of bound maleic anhydride, based on the total amount of maleic anhydride moieties present in the grafting reaction product, and the maleated polypropylenes produced therefrom. The methods produce maleated polypropylenes wherein at least about 60% of the maleic anhydride moieties in the grafting reaction product are bound to the polypropylene.Type: GrantFiled: May 6, 2002Date of Patent: August 14, 2007Assignee: Honeywell International Inc.Inventor: Scott M. Hacker
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Patent number: 7247366Abstract: The object of the present invention is to provide a masking member which has good heat resistance and can be used repeatedly. To attain this object, the present invention provide a masking member made of a polymer alloy including one or more kinds of engineering plastics selected from a group consisting of methylpentene copolymer, polysulphone, polyethersulphone, polyphenylene, sulphide, polyphenylene ether, polyamideimide, polyetherimide, polyether-etherketone; and polyamide and/or polystyrene, and styrenic thermoplastic elastomer wherein said engineering plastics and said polyamide and/or polystyrene are mixed together in a weight ratio between 30:70 to 70:30, and 2 to 20 parts by weight of said styrenic thermoplastic elastomer is added in 100 parts by weight of said engineering plastics and polyamide and/or polystyrene. Said masking member has excellent moldability, a high level of mechanical strength and a good affinity with the coating film.Type: GrantFiled: October 4, 2001Date of Patent: July 24, 2007Assignee: Nagoya Oilchemical, Co., Ltd.Inventors: Masanori Ogawa, Kuninori Ito
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Patent number: 7217765Abstract: A composite composition is disclosed that comprises the reaction product of a mixture of a styrenic polymer, as defined herein, a polar component having nucleophilic functional groups, and from 0.5 to 10 wt % of a compatibilizer having the formula: Ry(I)-(styrene)n-[(styrene)m(X)]p—I(Ry) wherein: R is the residue of a nitroxide used to regulate the polymerization of the compatibilizer; I is the residue of a radical initiator used to initiate polymerization of the compatibilizer; n is an integer from 50 to 750; m is an integer from 0 to 10; p is an integer from 1 to 50; and y is an integer from 0 to 1; and X is any polymerized monomeric moiety having at least one functional group capable of reacting with the nucleophilic functional groups present in the polar component of the composite at the temperature at which the composite components are mixed.Type: GrantFiled: December 17, 2003Date of Patent: May 15, 2007Assignee: Crompton CorporationInventors: Sung Chul Hong, Qinggao Ma, Paul Edwin Stott, John M. Wefer, Leigh Cameron Allen
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Patent number: 7195818Abstract: A sealable multi-layer opaque film. In particular, a sealable multi-layer opaque film that is moisture permeable and water resistant. The sealable multi-layer opaque film is an oriented multilayer film with a core layer comprising an orientation-enhancing polymer, a polypropylene homopolymer and a beta crystal nucleator of polypropylene and at least one sealable skin layer.Type: GrantFiled: May 1, 2002Date of Patent: March 27, 2007Assignee: ExxonMobil Oil CorporationInventors: Dan-Cheng Kong, Michael D. Cleckner
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Patent number: 7144956Abstract: The present invention relates to adhesive and sealant compositions in non-flowable form. More particularly, the present invention relates to non-flowable adhesive and sealant compositions which are particularly useful in the threadlocking and sealing applications and which can be packaged in a convenient pocket-sized applicator dispenser.Type: GrantFiled: March 1, 2005Date of Patent: December 5, 2006Assignee: Henkel CorporationInventors: Shabbir Attarwala, Zhu Qinyan, Matthew P. Burdzy
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Patent number: 7122233Abstract: The invention relates to a transparent composition comprising, by weight, the total being 100%: 5 to 40% of an amorphous polyamide (B) which results essentially from the condensation: either of at least one diamine chosen from cycloaliphatic diamines and aliphatic diamines and of at least one diacid chosen from cycloaliphatic diacids and aliphatic diacids, at least one of these diamine or diacid units being cycloaliphatic, or of a cycloaliphatic ?,?-aminocarboxylic acid, or of a combination of these two possibilities, and optionally of at least one monomer chosen from ?,?-aminocarboxylic acids or the possible corresponding lactams, aliphatic diacids and aliphatic diamines, 0 to 40% of a supple polyamide (C) chosen from copolymers containing polyamide blocks and polyether blocks and copolyamides, 0 to 20% of a compatabilizer (D) for (A) and (B), 0 to 40% of a supple modifier (M), with the condition that (C)+(D)+(M) is between 0 and 50%, the remainder to 100% being a semi-crystalline polyamide (A).Type: GrantFiled: January 26, 2005Date of Patent: October 17, 2006Assignee: AtofinaInventors: Thibaut Montanari, Christelle Recoquille
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Patent number: 7071262Abstract: According to a first form, the present invention relates to a compatibilizer composed of a polyolefin backbone and of polyamide grafts in which: the grafts are attached to the backbone via the residues of an unsaturated monomer (A) having a functional group which acts as activator in the polymerization of lactains and which is not an isocyanate functional group, the residues of the unsaturated monomer (A) are fixed to the backbone by grafting from its double bond. The invention also relates to a process for the preparation of these compatibilizers in which, after the preparation of the backbone comprising the monomer having an activating functional group, the precursor lactam of the grafts and a catalyst are added and heating is carried out in order to obtain anionic polymerization of the lactam which spreads starting from the activating functional group. Subsequently, the compatibilizer and the polyamide which has formed apart from the grafts are optionally separated.Type: GrantFiled: July 27, 2001Date of Patent: July 4, 2006Assignee: AtofinaInventors: Guo-Hua Hu, Huxi Li, Heike Faulhammer, Nicola Hoogen, Thierry Vivier
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Patent number: 7067582Abstract: The invention is directed to golf ball core compositions comprising at least one natural or synthetic rubber and at least one high Vicat softening temperature thermoplastic material, methods of preparing the compositions, and golf ball cores and golf balls including the compositions. The compositions of the invention are made by mixing at least one natural or synthetic rubber and at least one thermoplastic or thermoplastic elastomer at a first temperature; cooling the mixture to a second temperature which is below an activation temperature of a free-radical initiator; adding the free-radical initiator to the first mixture to form a second mixture; and heating the second mixture to a third temperature that to facilitate crosslinking. The golf ball cores are incorporated into multilayer balls including dual cover balls with thin outer layers.Type: GrantFiled: November 25, 2003Date of Patent: June 27, 2006Assignee: Acushnet CompanyInventors: Murali Rajagopalan, Derek A. Ladd
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Patent number: 7056975Abstract: A thermoplastic resin composition composed of a thermoplastic resin and a polyamide elastomer in which the polyamide elastomer contains at least 50 weight % of a polyetheramide elastomer prepared by polymerization of a tri-block polyetherdiamine compound, a polyamide-forming monomer is an aminocarboxylic acid and/or a lactam compound, and a dicarboxylic acid compound, in which the tri-block polyetherdiamine compound has the formula (1): [each of x and y is an integer of 1 to 20, and y is an integer of 4 to 50].Type: GrantFiled: May 26, 2004Date of Patent: June 6, 2006Assignee: Ube Industries, Ltd.Inventors: Hideki Fujimura, Toshio Moriyama, Shinya Matsuda
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Patent number: 7053155Abstract: A vibration damping rubber composition capable of exhibiting an excellent vibration damping property comprising: (A) a diene rubber; (B) a bismaleimide compound represented by the following general formula (1); wherein n denotes an integer of 4 to 12; and (C) a vulcanization accelerator; wherein said rubber composition does not contain elemental sulfur as a raw material for a vulcanizing agent.Type: GrantFiled: December 8, 2004Date of Patent: May 30, 2006Assignee: Tokai Rubber Industries, Ltd.Inventors: Norihito Kimura, Fumihiko Jinno, Takehiko Taguchi
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Patent number: 7048712Abstract: A combination of polymeric components provides desired characteristics in forming medical instruments such as catheters and balloons for dilatation catheters. For example, a balloon material is formed from a blend of polymeric components, including a first crystalline polymeric component and a second softening polymeric component. Where the first two components are generally incompatible, the balloon material can also include a third compatibilizing agent to facilitate blending the first two polymeric components together.Type: GrantFiled: March 14, 2003Date of Patent: May 23, 2006Assignee: Advanced Cardiovascular Systems, Inc.Inventors: Ziyun Chen, Tai Cheng, Ketan Muni, Udayan Patel, Robert Saltman
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Patent number: 7049371Abstract: A material for an insulating film which comprises a copolymer obtained by reacting a polyamide having a specific structure and a reactive oligomer as a component forming the film; a coating varnish for an insulating film which comprises this material and an organic solvent; an insulating film which comprises a layer of a resin comprising as a main structure a polybenzoxazole which is obtained by treating the above material or the above coating varnish by heating so that condensation reaction and crosslinking reaction take place and has fine pores; and a semiconductor device which comprises an insulating interlayer film for multi-layer wiring comprising the insulating film and/or a surface protective film comprising the insulating film. Excellent electrical, thermal and mechanical properties are exhibited and a low permittivity can be achieved.Type: GrantFiled: September 20, 2001Date of Patent: May 23, 2006Assignee: Sumitomo Bakelite Company, Ltd.Inventors: Takashi Enoki, Hidenori Saito, Nobuhiro Higashida, Yuichi Ishida
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Patent number: 7030190Abstract: A thermoplastic resin composition material 1 includes a resin portion (a) 2 made of a thermoplastic resin (A); elastomer portions (b) 3 made of a thermoplastic elastomer (B) having substantially no compatibility with the thermoplastic resin (A) and having a glass transition temperature of lower than or equal to ?40° C.; and polymer portions (c) 4 made of a high polymer (C) having substantially no compatibility with the thermoplastic resin (A) and the thermoplastic elastomer (B), having a glass transition temperature or crystallization temperature of lower than or equal to ?50° C., and having a viscosity at 40° C. of 0.1 to 200000 cP. The material has a structure in which the elastomer portions (b) 3 are dispersed in the resin portion (a) 2, and the polymer portions (c) 4 are dispersed in the elastomer portions (b) 3. Accordingly, low-temperature impact resistance can significantly be improved without deterioration in the other inherent excellent physical properties of the thermoplastic resin.Type: GrantFiled: February 26, 2002Date of Patent: April 18, 2006Assignee: Daicel-Degussa Ltd.Inventors: Naoki Wakita, Hiroaki Arita
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Patent number: 7029735Abstract: The present invention relates to polyamide (A) and polyolefin (B) blends containing nanofillers in which thc polyamide forms the matrix. These blends can also be referred to as “polyamide (A), polyolefin (B) and nanofiller blends in which the polyamide fonns the matrix”. The invention also relates to structures with barrier properties comprising at least one layer of these blends and optionally at least one layer of another material. These structures are a barrier to numerous fluids, and in particular in oxygen, to styrene, to furnigation fluids, to pentane and to air conditioning fluids. These structures can be made into bottles, reservoirs, containers, pipes and vessels of all sorts. They can also be converted to films which are used to make packagings.Type: GrantFiled: March 17, 2004Date of Patent: April 18, 2006Assignee: ArkemaInventors: Jean-Jacques Flat, Benoît Barriere, Benoît Brule
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Patent number: 7014919Abstract: A composition comprising, by weight, the total being 100%: a semi-crystalline polyamide (A); 5 to 40% of an amorphous polyamide (B) which results from the condensation: of (B1) at least one cycloaliphatic diamine or aliphatic diamine, with at least one cycloaliphatic diacid or aliphatic diacid, at least one of the diamine or diacid units being cycloaliphatic, or (B2) of a cycloaliphatic ?,?-aminocarboxylic acid, or (B3) of a combination of (B1), and (B2), and optionally at least one of (B1), (B2) and (B) being condensed with at least one monomer selected from the group consisting of a ?,?-aminocarboxylic acid or the corresponding lactam, an aliphatic diacid, and an aliphatic diamine; 0 to 40% of a supple polyamide (C) selected from the group consisting of (C1) copolymers containing polyamide blocks and polyether blocks, and (C2) copolyamides; 0 to 20% of a compatabilizer (D) for (A) and (B); 0 to 40% of a supple modifier (M); with the condition that (C)+(D)+(M) is between 0 and 50%, the remainder to 100% bType: GrantFiled: January 28, 2002Date of Patent: March 21, 2006Assignee: RKEMAInventors: Thibaut Montanari, Christelle Recoquille
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Patent number: 6998438Abstract: The present invention provides plastics with high toughness and the preparation thereof. The plastics with high toughness, which have the balance of stiffness and toughness, stable properties and good processability, are obtained by blending the rubber particles having an average particle size of 20 to 200 nm with the pseudoductile plastics, wherein the weight ratio of the rubber particles to the plastics is from 0.5:99.5 to 70:30. The present invention also provides plastics with both high stiffness and high toughness and the preparation thereof. The plastics with both high stiffness and high toughness, which have also an improved heat resistance and good processability, are prepared by blending the rubber particles having an average particle size of 20 to 500 nm and the crystalline plastics, wherein the amount of the rubber particles added in the plastics matrix is from 0.3 to 5 weight parts.Type: GrantFiled: April 18, 2002Date of Patent: February 14, 2006Assignees: China Petroleum & Chemical Corporation, Beijing Research Institute of Chemical IndustryInventors: Jinliang Qiao, Shijun Zhang, Xiaohong Zhang, Yiqun Liu, Jianming Gao, Wei Zhang, Genshuan Wei, Jingbo Shao, Hua Yin, Renli Zhai, Zhihai Song, Fan Huang, Jiuqiang Li
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Patent number: 6953541Abstract: The present invention provides a method for preparing flexible thermoplastic compositions that may be used separately or combined with up to fifty percent thermoplastic scrap. One embodiment of the invention comprises creating a melt-blend of blending composition, up to 50% by weight thermoplastic scrap and up to 15% by weight poly(ethyl-co-vinyl) acetate wherein the blending composition comprises an impact polypropylene, impact modifier and plasticizer. The polypropylene, impact modifier and plasticizer are selected to meet requirements of flexible thermoplastic compositions useful in vehicle interiors. In another embodiment of the invention a random polypropylene is used.Type: GrantFiled: April 4, 2001Date of Patent: October 11, 2005Assignee: Sunoco Inc. (R&M)Inventor: Sehyun Kim
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Patent number: 6919410Abstract: There is provided a process for producing a modified polypropylene resin, which comprises the steps of mixing the following components (A) to (D), and reacting them with one another: (A) 100 parts by weight of a polypropylene resin, (B) 0.1 to 30 parts by weight of a compound having a bond or a functional group selected from the group consisting of a non-aromatic carbon-carbon multiple bond, an oxirane group and a derived carboxyl group, (C) 0.001 to 30 parts by weight of a compound having at least two functional groups reactive to a carboxyl group, and (D) 0.01 to 20 parts by weight of an organic peroxide having a decomposition temperature of from 50 to 120° C., at which temperature a half-life of the organic peroxide is 1 minute.Type: GrantFiled: October 24, 2002Date of Patent: July 19, 2005Assignee: Sumitomo Chemical Company, LimitedInventors: Katsuhisa Kitano, Takashi Sanada
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Patent number: 6907911Abstract: The invention generally relates to thermoplastic blends having improved properties. Optionally, these blends may be dynamically vulcanized. More specifically, this invention is directed to a composition comprising a blend of chloromethylated(styrene-isobutylene) polymer and a thermoplastic resin selected from the group consisting of polyamides, polyesters, polycarbonates, polysulfones, polyacetals, polyacetones, acrylonitrile-butadiene styrene resins, polyphenylene oxide, polyphenylene sulfide, styrene-acrylonitrile resins, styrene-maleic anhydride resins, polyamides, aromatic polyketones, ethylene vinyl alcohol polymer and mixtures thereof. Tires and tire components such as air permeation prevention films comprising these compositions are also provided.Type: GrantFiled: June 29, 2004Date of Patent: June 21, 2005Assignee: ExxonMobil Chemical Patents Inc.Inventor: Hsien-Chang Wang
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Patent number: 6872775Abstract: A compound for a composite body having a hard and a soft component, and to a process for producing such a composite body is provided. The compound comprises a hard component (a) of a polyoxymethylene and a soft component (b) of one or more hydrogenated styrene block copolymers, molded directly onto component (a). The styrene block copolymers are from the group of poly-isoprene/butadiene polymer (SEEPS), poly-isoprene polymer (SEPS); poly-butadiene polymer (SEBS), and combinations thereof. The styrene block copolymer is adhesion-modified by the addition of a compound selected from styrene/butadiene copolymer (SBS); ethylene/vinyl acetate copolymer (EVA); olefinic polymers, polystyrene (PS), and combinations thereof.Type: GrantFiled: January 15, 2002Date of Patent: March 29, 2005Assignees: E.I. du Pont de Nemours and Company, Plastolen GmbHInventors: Stefan Greulich, Karl-Wilhelm Kirberg, Norbert Eickhoff, Olaf Stelzer
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Patent number: 6872778Abstract: Disclosed is a method for forming a gasket seal or transition fitting affixed to one of two parts to be joined in a gasketed joint by use of the gasket. The method includes the step of providing a mold having a walled mold cavity of the shape desired for the gasket, at least one wall of the mold cavity being a junction surface of the one part and the remaining walls of the mold cavity being formed in a mold piece. The mold is closed by placing the mold piece over the junction surface of the one part to establish the mold cavity as a closed generally toroidal volume. Then a molten gasket-forming thermoplastic material is injected into the mold cavity to form the gasket, the thermoplastic material including a bonding agent for establishing an adhesive bond between the junction surface and the gasket. The thermoplastic material is cooled to solidify the gasket and affix it to the junction surface and the mold piece is removed away from the junction surface.Type: GrantFiled: November 12, 2001Date of Patent: March 29, 2005Assignee: Q'SO, Inc.Inventor: Larry F. Leicht
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Patent number: 6870005Abstract: A polymeric composition and process for making the same suitable for injection molding processes and procedures containing an olefinic polymer component selected from at least one a group which includes polyalkylenes, copolymers of polyalkylenes and a non-olefinic thermoplastic. The non-olefinic and olefinic polymeric components are present in random orientable locations in the initial polymeric composition. When injection molded against a temperature gradient, the resulting workpiece composed of the composition has distinctive regions of elevated non-olefinic concentration proximate the outwardly oriented surface and distinctive regions of elevated olefinic polymeric concentration proximate to interior regions of the workpiece. The non-olefinic thermoplastic may be at least one of thermoplastic polyamides, thermoplastic polyolefins and thermoplastic polycarbonates.Type: GrantFiled: February 28, 2002Date of Patent: March 22, 2005Assignee: ACI Technologies, LLCInventor: Mark Lieberman
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Patent number: 6861470Abstract: A thermoplastic elastomer composition dynamically vulcanized to a gelation rate of 50 to 95% which is superior in heat resistance and durability while maintaining flexibility and superior in air permeation preventive property which can be efficiently used as, for example, a pneumatic tire as an air permeation preventive layer. The method includes mixing a composition (C) mixed under conditions of a ratio of melt viscosities of the rubber composition (A)/resin (B) of 0.8 to 1.2 and the formula (?A/?B)×(?B/?A)<1.0 under conditions of a ratio of melt viscosities of the rubber composition (D)/composition (C) of 0.8 to 1.2 and the formula (?D/?C)×(?C/?D)<1.0, wherein ?A: volume fraction of rubber composition (A), ?B: volume fraction of resin (B), ?A: melt viscosity of rubber composition (A), ?B: melt viscosity of resin (B), ?C: volume fraction of composition (C), ?D: volume fraction of rubber composition (D), ?C: melt viscosity of composition (C), ?D: melt viscosity of rubber composition (D).Type: GrantFiled: January 21, 2003Date of Patent: March 1, 2005Assignee: The Yokohama Rubber Co., Ltd.Inventors: Jiro Watanabe, Kazuto Yamakawa, Daisuke Kanenari, Noriaki Kuroda, Gou Kawaguchi, Yuichi Hara, Tetsuji Kawazura, Shigeru Yamauchi, Hideo Nemoto
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Patent number: 6846879Abstract: A golf ball providing resistance to abrasion and resistance to wear generally in an excellent balance is formed of a core and a cover arranged to cover the core, the cover being formed of a compound containing relative to 100 parts by mass of a polymer component thereof composed mainly of polybutadiene rubber 1-40 parts by mass of a reinforcement material formed of organic short fiber and 10-40 parts by mass of a metallic salt of ?,?-ethylene unsaturated carboxylic acid. It is characterized in that the organic short fiber is suitably a ternary composite formed of a rubber component, a polyolefin component and a nylon component and the metallic salt of ?,?-ethylene unsaturated carboxylic acid is suitably zinc acrylate, zinc methacrylate, magnesium acrylate or magnesium methacrylate.Type: GrantFiled: January 16, 2003Date of Patent: January 25, 2005Assignee: Sumitomo Rubber Industries, Ltd.Inventor: Satoshi Iwami
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Patent number: 6843292Abstract: The invention generally relates to thermoplastic blends having improved properties. Optionally, these blends may be dynamically vulcanized. More specifically, this invention is directed to a composition comprising a blend of chloromethylated(styrene-isobutylene) polymer and a thermoplastic resin selected from the group consisting of polyamides, polyesters, polycarbonates, polysulfones, polyacetals, polyacetones, acrylonitrile-butadiene styrene resins, polyphenylene oxide, polyphenylene sulfide, styrene-acrylonitrile resins, styrene-maleic anhydride resins, polyamides, aromatic polyketones, ethylene vinyl alcohol polymer and mixtures thereof. Tires and tire components such as air permeation prevention films comprising these compositions are also provided.Type: GrantFiled: June 8, 2001Date of Patent: January 18, 2005Assignee: ExxonMobil Chemical Patents Inc.Inventor: Hsien-Chang Wang
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Patent number: 6817954Abstract: A golf grip is formed by the crosslinking of a rubber composition obtained through the kneading of a base rubber and a rubber-polyolefin-nylon ternary copolymer. This ternary copolymer is obtained by the graft polymerization of a rubber component, a polyolefin component and a nylon component. This ternary copolymer is a fine fiber reinforced composite having fine nylon fibers dispersed in a matrix composed of the rubber component and the polyolefin component. The amount of the rubber-polyolefin-nylon ternary copolymer to be blended is from 1 part by weight to 50 parts by weight on the basis of 100 parts by weight of the base rubber.Type: GrantFiled: January 29, 2003Date of Patent: November 16, 2004Assignee: Sumitomo Rubber Industries, Ltd.Inventor: Yoshinori Sano
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Publication number: 20040225066Abstract: The present invention relates to polyamide (A) and polyolefin (B) blends containing nanofillers in which the polyamide forms the matrix. These blends can also be referred to as “polyamide (A), polyolefin (B) and nanofiller blends in which the polyamide forms the matrix”.Type: ApplicationFiled: March 17, 2004Publication date: November 11, 2004Inventors: Jean-Jacques Flat, Benoit Barriere, Benoit Brule
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Patent number: 6815079Abstract: The invention relates to an opaque biaxially oriented film made of at least one layer that contains COC. This layer contains a cycloolefin copolymer (COC) in a concentration of 0.5 to 30 wt. % with regard to this layer and contains a polymer made from aliphatic hydroxycarboxylic acid units.Type: GrantFiled: March 29, 2004Date of Patent: November 9, 2004Assignee: Treofan Germany GmbH & Co. KGInventors: Sonja Rosenbaum, Petra Hade, Detlef D. Busch, Karl-Heinz Kochem
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Publication number: 20040204545Abstract: Rubber-toughened and ionomer-toughened polyamide compositions are provided which exhibit decreased molecular weight in comparison with conventional systems but without compromising the toughness of the system. Processes for their preparation are also provided, in which excess organic acid is incorporated into the polyamide-functionalized rubber system.Type: ApplicationFiled: April 28, 2004Publication date: October 14, 2004Inventors: Rolando Umali Pagilagan, Robert Benham Fish
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Patent number: 6796958Abstract: A combination of polymeric components provides desired characteristics in forming medical instruments such as catheters and balloons for dilatation catheters. For example, a balloon material is formed from a blend of polymeric components, including a first crystalline polymeric component and a second softening polymeric component. Where the first two components are generally incompatible, the balloon material can also include a third compatibilizing agent to facilitate blending the first two polymeric components together.Type: GrantFiled: December 2, 1999Date of Patent: September 28, 2004Assignee: Advanced Cardiovascular Systems, Inc.Inventors: Ziyun Chen, Tai Cheng, Ketan Muni, Udayan Patel, Robert Saltman
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Patent number: 6794048Abstract: A multilayer composite comprising the following layers bound directly to one another: I. a layer I of a polyamide molding composition; II. a layer II of a bonding agent comprising at least 50% by weight of a mixture of a) from 30 to 70 parts by volume of polyamide and b) from 70 to 30 parts by volume of polyolefin, where the sum of the parts by volume is 100 and in addition at least some of the polyamide is present either in the form of a polyamide-polyolefin graft copolymer or as a highly branched polyamine-polyamide copolymer; III. if desired a layer III of a polyolefin molding composition, displays good adhesion between layers which remains largely intact even on prolonged contact with alcohol-containing or aqueous media at elevated temperature.Type: GrantFiled: December 26, 2001Date of Patent: September 21, 2004Assignee: Degussa AGInventors: Guido Schmitz, Harald Haeger
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Patent number: 6777496Abstract: We have developed a process and product which provide thermoplastic articles featuring a permanent outer surface which has selectively varied chemical functionality while maintaining the inherent mechanical properties of the base fiber.Type: GrantFiled: February 7, 2001Date of Patent: August 17, 2004Assignee: Honeywell International Inc.Inventors: Kundan M. Patel, Charles Jay Nelson, Frank Mares, Conor Twomey, Yousef Mohajer
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Patent number: 6750288Abstract: The present invention relates to an isotactic polypropylene obtained by metallocene catalysis, onto which is grafted a functional monomer. The invention also relates to a composition which may form part of the composition of a coextrusion binder. This composition according to the invention comprises isotactic polypropylene obtained by metallocene catalysis, grafted and then optionally diluted with at least one polyolefin (C1) and/or in at least one polymer of elastomeric nature (D). The invention also relates to a multilayer structure comprising a layer (L) comprising the above binder, and, directly attached thereto, a layer (E): which is polar, nitrogenous or oxygenated, such as a layer of polyamide resin, of ethylene/saponified vinyl acetate copolymer (EVOH) or of polyester; or of a mineral oxide deposited on a polymer such as polyethylene (PE), polyethylene terephthalate (PET) or EVOH; or which is metallic or metalloplastic.Type: GrantFiled: July 31, 2002Date of Patent: June 15, 2004Assignee: AtofinaInventor: Jean-Laurent Pradel
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Patent number: 6730378Abstract: In the resin-molded articles comprising polyolefin resins (a) and thermoplastic resins other than the polyolefin resins (b), when thickness is defined as one along a direction vertical to the surface of the article, as morphology observed under an electron microscope in the article, a portion where the polyolefin resin (a) forms a continuous phase (A), a portion where the resin other than the polyolefin resin (b) forms the continuous phase and the polyolefin resin (a) forms a discontinuous phase (B), and a portion where the polyolefin resin (a) forms the continuous phase (A) are successively observed in order from the surface toward the inside along the thickness direction, such molded articles having nature such as toughness and fabrication quality inherent to the polyolefin resins and improved appreciably in resistance to permeation of liquid chemicals and gases.Type: GrantFiled: March 15, 2002Date of Patent: May 4, 2004Assignee: Toray Industries, Inc.Inventors: Hideo Matsuoka, Mitsushige Hamaguchi, Kazuhiko Kobayashi
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Patent number: 6727320Abstract: The present invention relates to adhesive and sealant compositions in non-flowable form. More particularly, the present invention relates to non-flowable adhesive and sealant compositions which are particularly useful in the threadlocking and sealing applications and which can be packaged in a convenient pocket-sized applicator dispenser.Type: GrantFiled: January 18, 2002Date of Patent: April 27, 2004Assignee: Henkel Loctite CorporationInventors: Shabbir Attarwala, Zhu Qinyan, Matthew P. Burdzy
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Patent number: 6703446Abstract: Hetero-telechelic polymers having the formula: FG—(Q)d—Z—J—[A(R1R2R3)]x (I) wherein FG is a protected or non-protected functional group; Q is a saturated or unsaturated hydrocarbyl group derived by incorporation of a compound selected from the group consisting of conjugated diene hydrocarbons, alkenylsubstituted aromatic hydrocarbons, and mixtures thereof; d is an integer from 10 to 200; Z is a branched or straight chain hydrocarbon group which contains 3-25 carbon atoms, optionally containing aryl or substituted aryl groups; J is oxygen, sulfur, or nitrogen; [A(R1R2R3)]x is a protecting group, wherein A is an element selected from Group IVa of the Periodic Table of Elements; R1, R2, and R3 are each independently selected from the group consisting of hydrogen, alkyl, substituted alkyl groups containing lower alkyl, lower alkylthio, and lower dialkylamino groups, aryl or substituted aryl groups containing lower alkyl, lower alkylthio, and lower dialkylamType: GrantFiled: June 21, 2002Date of Patent: March 9, 2004Assignee: FMC Corporation, Lithium DivisionInventors: James A. Schwindeman, Robert J. Letchford, Conrad W. Kamienski, Roderic P. Quirk
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Patent number: 6699939Abstract: Hetero-telechelic polymers having the formula: FG—(Q)d—Z—J—[A(R1R2R3)]x (I) wherein FG is a protected or non-protected functional group; Q is a saturated or unsaturated hydrocarbyl group derived by incorporation of a compound selected from the group consisting of conjugated diene hydrocarbons, alkenylsubstituted aromatic hydrocarbons, and mixtures thereof; d is an integer from 10 to 200; Z is a branched or straight chain hydrocarbon group which contains 3-25 carbon atoms, optionally containing aryl or substituted aryl groups; J is oxygen, sulfur, or nitrogen; [A(R1R2R3)]x is a protecting group, wherein A is an element selected from Group IVa of the Periodic Table of Elements; R1, R2, and R3 are each independently selected from the group consisting of hydrogen, alkyl, substituted alkyl groups containing lower alkyl, lower alkylthio, and lower dialkylamino groups, aryl or substituted aryl groups containing lower alkyl, lower alkylthio, and lower dialkylamType: GrantFiled: June 21, 2002Date of Patent: March 2, 2004Assignee: FMC Corporation, Lithium DivisionInventors: James A. Schwindeman, Robert J. Letchford, Conrad W. Kamienski, Roderic P. Quirk
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Patent number: 6696165Abstract: The invention provides a weatherable low gloss styrene copolymer composition which requires the addition of from 0.1 to 20% by weight of the total composition, of a partially crystalline polymer such as a polyalkylterephthalate, especially polybutyleneterephthalate or polyethyleneterephthalate, or polyethylenenaphthalate to a styrene copolymer (A). The low gloss styrene copolymer composition of the invention has a graft copolymer resin which results from polymerizing one or more monomers (A1) selected from the group consisting of (i) aromatic vinyl compounds, (ii) ethylenically unsaturated compounds, and (iii) mixtures thereof, in the presence of an elastomeric rubber (A2) in particulate form.Type: GrantFiled: June 28, 2000Date of Patent: February 24, 2004Assignee: BASF CorporationInventors: James H. Bennett, Klaus Mühlbach, Gary Kogowski, Heiner Görrissen, Graham Edmund Mc Kee
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Publication number: 20040024127Abstract: The present invention relates to a hot-melt adhesive composition comprising:Type: ApplicationFiled: February 26, 2003Publication date: February 5, 2004Applicant: ATOFINAInventors: Martin Baumert, Francois Court, Christian Laurichesse
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Patent number: 6679754Abstract: Polyolefin fibers, filaments and fabrics made therefrom which comprise a melt blend which comprises (A) a polyolefin; and (B) at least one polyetheresteramide which contains aromatic diol-derived sections, exhibit excellent durable dyeability. The fabrics are useful in woven garments, carpeting, furniture and automobile upholstery, woven industrial fabrics, non-woven absorbents used in disposable diapers, non-woven garments including disposable medical garments, filter media, synthetic paper and the like.Type: GrantFiled: December 6, 2001Date of Patent: January 20, 2004Assignee: Ciba Specialty Chemicals CorporationInventors: Sheng-Shing Li, Andrew J. Leggio, Nadi Ergenc
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Patent number: 6673867Abstract: A heat-resistant engineering-plastic composition that satisfies a soldering-heat resistance of 260° C. for 10 to 60 secs., that is less costly, that is free of problems in injection molding process, and that is excellent in heat-aging resistance. A heat-resistant molded product made with the heat-resistant engineering-plastic composition, such as a connector mounted on printed circuit board. The heat-resistant molded product is produced by (a) melt-kneading (a1) an engineering plastic either having or introduced an active site for reacting with a specific functional group and (a2) either an organic compound that has both the said specific functional group and a polymerizing functional group in the same molecule or polyolefin that has the said specific functional group described in (a1) to obtain a resin composition, (b) melt-molding the resin composition comprising of (a), and (c) irradiating the melt-molded resin composition with ionizing radiation.Type: GrantFiled: November 13, 2001Date of Patent: January 6, 2004Assignee: Sumitomo Electric Fine Polymer, Inc.Inventors: Hiroshi Hayami, Shinya Nishikawa
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Patent number: 6657008Abstract: Flame retardant resin composition comprising (a) an SPS, (b) a thermoplastic resin having a reactive polar group, (c) a compatibilizing agent having compatibility with the component (a) and a polar group capable of reacting with the component (b), (d) a flame retardant and (e) a flame retardant auxiliary, a weight ratio of the component (a)/the component (b) being less than 1.5, the amount of the component (c) being in the range of 0.5 to 10% by weight with respect to 100% by weight of the total of the components (a), (b) and (c), the amount of the component (d) being 10 parts by weight or more and the amount of the component (e) being 3 parts by weight or more with respect to 100 parts by weight of the total of the components (a), (b) and (c).Type: GrantFiled: October 27, 1997Date of Patent: December 2, 2003Assignee: Idemitsu Kosan Co., Ltd.Inventors: Tohru Iwashita, Shinichi Miura
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Publication number: 20030181592Abstract: A thermoplastic elastomer composition dynamically vulcanized to a gelation rate of 50 to 95% which is superior in heat resistance and durability while maintaining flexibility and superior in air permeation preventive property which can be efficiently used as, for example, a pneumatic tire as an air permeation preventive layer. In particular, a thermoplastic elastomer composition having a reduced particle size of the domain rubber is produced by a material having a high rubber ratio by mixing a composition (C) mixed under conditions of a ratio of melt viscosities of the rubber composition (A)/resin (B) of 0.8 to 1.2 and the formula (&phgr;A/&phgr;B)×(&eegr;B/&eegr;A)<1.0 under conditions of a ratio of melt viscosities of the rubber composition (D)/composition (C) of 0.8 to 1.2 and the formula (&phgr;D/&phgr;C)×(&eegr;C/&eegr;D)<2.Type: ApplicationFiled: January 21, 2003Publication date: September 25, 2003Applicant: THE YOKOHAMA RUBBER CO., LTD.Inventors: Jiro Watanabe, Yuichi Hara, Shigeru Yamauchi, Hideo Nemoto
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Publication number: 20030158340Abstract: A golf ball providing rebound performance, spin performance, resistance to abrasion and anti-wearability in an excellent balance is formed of a core and a cover arranged to cover the core and formed mainly of diene rubber having a smaller trans structure content before it is crosslinked than after it is crosslinked, in particular by 2 to 20%. The diene rubber is preferably polybutadiene rubber and as the cover's co-crosslinking agent a metallic salt of &agr;,&bgr;-ethylene unsaturated carboxylic acid is used.Type: ApplicationFiled: December 27, 2002Publication date: August 21, 2003Inventor: Satoshi Iwami
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Publication number: 20030130140Abstract: This invention is directed to a new low molecular weight copolymer (The PIB/UAR copolymer) that may be prepared by reacting a low molecular weight polyisobutene (PIB) having less than about 32 carbon atoms with an unsaturated acidic reagent in the presence of a free radical initiator. No chain transfer agent is required to prepare the low molecular weight PIB/UAR copolymer. The PIB/UAR copolymer may be useful as is, or as an intermediate for (1) polysuccinimides, (2) detergents or dispersants for lube oil or fuels, (3) pour point depressants and (4) surface sizing agents for paper. The PIB/UAR copolymer may be used by itself or as the ester, amide, imide or metal salt derivative of the PIB/UAR copolymer. The PIB/UAR copolymer may be liquid at ambient temperature.Type: ApplicationFiled: November 9, 2001Publication date: July 10, 2003Inventors: James J. Harrison, William R. Ruhe, Kenneth D. Nelson
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Patent number: 6576705Abstract: The objective of the present invention lies in providing a resin composition which enables water vapor permeability to be controlled over a broad range while maintaining a high gas permeability, together with molded articles or packaging materials comprising said composition, in particular a packaging material for foodstuffs like fruit and vegetables. A thermoplastic resin composition which is characterized in that a polymer (A) containing polyether chains as structural units, polyethylene (B) of density as specified in JIS K6760 of less than 0.91 g/cm3 and a compatibilizing agent (C) are blended together in proportions by weight of A/B/C=99.5 to 0.5/0.5 to 99.5/0 to 30 (where A+B+C=100); and molded articles comprising said composition, in particular a packaging material for vegetables and fruit cultivation or foodstuffs storage.Type: GrantFiled: February 9, 1999Date of Patent: June 10, 2003Assignee: Elf Atochem S.A.Inventors: Jerome Maillet, Takatoshi Kuratsuji, Alain Bouilloux, Yves Germain
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Patent number: RE39617Abstract: Hydrogenated butadiene polymers having terminal functional groups have minimum viscosity at any molecular weight when the 1,2-addition is between 30% and 70% Hydrogenated butadiene polymers having about two terminal hydroxyl groups per molecule have surprisingly lower viscosities at 30% to 70% 1,2-addition than similar polymers having either higher or lower amounts of 1,2-addition. The polymers are useful in making coatings, sealants, binders, and block copolymers with polyesters, polyamides, and polycarbonates.Type: GrantFiled: September 5, 2003Date of Patent: May 8, 2007Assignee: Kraton Polymers US LLCInventors: Dale L. Handlin, Jr., Daniel E. Goodwin, Carl L. Willis, David J. St. Clair, John D. Wilkey, Michael J. Modic, Craig A. Stevens