Solid Polymer Derived From Ethylenically Unsaturated Hydrocarbon Patents (Class 525/184)
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Patent number: 6566449Abstract: A rubber composition comprises at least one rubber ingredient selected from natural rubber and synthetic rubbers, and a polymaleimide synthesized by reacting at least one of anhydrous maleic acid and anhydrous citraconic acid with methylene polyaniline.Type: GrantFiled: October 19, 2001Date of Patent: May 20, 2003Assignee: Bridgestone CorporationInventors: Kenichi Sugimoto, Masahiro Hojo
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Patent number: 6538066Abstract: A thermoplastic elastomer composition dynamically vulcanized to a gelation rate of 50 to 95% which is superior in heat resistance and durability while maintaining flexibility and superior in air permeation preventive property which can be efficiently used as, for example, a pneumatic tire as an air permeation preventive layer.Type: GrantFiled: March 8, 2001Date of Patent: March 25, 2003Assignee: The Yokohama Rubber Co., Ltd.Inventors: Jiro Watanabe, Kazuto Yamakawa, Daisuke Kanenari, Noriaki Kuroda, Gou Kawaguchi, Yuichi Hara, Tetsuji Kawazura, Shigeru Yamauchi, Hideo Nemoto
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Patent number: 6538067Abstract: Interpolymer of a polymer of unsaturated olefinically monomers without carboxylic groups and a polymeric surface active agent.Type: GrantFiled: August 9, 2001Date of Patent: March 25, 2003Assignee: BASF AktiengesellschaftInventors: Katrin Zeitz, Reinhold Dieing, Axel Sanner
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Publication number: 20030045641Abstract: Oxygen scavenging barrier polyamide compositions exhibiting high oxygen scavenging capability as well as good coinjection stretch blow moldability characteristics suitable for making multilayer PET bottles with good clarity and delamination resistance are claimed in this invention. The polyamide compositions of this invention comprise a slow crystallizing polyamide blend comprising (i) an amorphous, semiaromatic polyamide homopolymer, copolymer or mixture thereof and (ii) a semicrystalline, aliphatic polyamide homopolymer, copolymer or mixture thereof wherein in the weight ratio of (i):(ii) ranges from about 99:1 to about 30:70; at least one polyamide-compatible, oxidizable polydiene; and at least one oxidation promoting metal salt catalyst. The multilayer PET bottles, made with the polyamide compositions of this invention as the barrier layer, are suitable for extended shelf-life packaging of oxygen-sensitive food and beverage products such as beer and juices.Type: ApplicationFiled: February 14, 2002Publication date: March 6, 2003Applicant: Honeywell International Inc.Inventors: Murali K. Akkapeddi, Edward P. Socci, Timothy J. Kraft, Darnell C. Worley, Jeffrey D. Pratt, Clark V. Brown
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Publication number: 20030045640Abstract: Oxygen barrier polyamide compositions exhibiting high oxygen scavenging capability suitable for extended shelf-life, packaging applications. Thus a polyamide composition comprises a polyamide homopolymer, copolymer, or blends thereof, and at least one polyamide reactive, oxidizable polydiene or oxidizable polyether. The polyamide products are particularly suited to making barrier packaging articles such as monolayer or multi-layer films, sheets, thermoformed containers and coinjection/coextrusion blow molded bottles comprising PET, polyolefin or polycarbonate as structural layers. Such articles are useful in a variety of oxygen-sensitive food, beverage, pharmaceutical and health care product packaging applications.Type: ApplicationFiled: January 4, 2002Publication date: March 6, 2003Applicant: Honeywell International Inc.Inventors: Murali K. Akkapeddi, Timothy J. Kraft, Edward P. Socci
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Patent number: 6525137Abstract: The invention relates to an improvement to conveyors comprising moving elements which slide over fixed elements such that at least one moving element made of a polyamide-based blend (A) slides over a fixed element made of polyacetal and/or such that at least one moving element made of polyacetal slides over a fixed element made of a polyamide-based blend (A).Type: GrantFiled: December 1, 2000Date of Patent: February 25, 2003Assignee: AtofinaInventors: Patrick Alex, Christian Capion Knudsen, Niels Peter Rosenkrands
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Publication number: 20030036605Abstract: Oxygen scavenging barrier polyamide compositions exhibiting high oxygen scavenging capability as well as good coinjection stretch blow moldability characteristics suitable for making multilayer PET bottles with good clarity and delamination resistance are claimed in this invention. The polyamide compositions of this invention comprise a slow crystallizing polyamide blend comprising (i) an amorphous, semiaromatic polyamide homopolymer, copolymer or mixture thereof and (ii) a semicrystalline, aliphatic polyamide homopolymer, copolymer or mixture thereof wherein in the weight ratio of (i):(ii) ranges from about 99:1 to about 30:70; at least one polyamide-compatible, oxidizable polydiene; and at least one oxidation promoting metal salt catalyst. The multilayer PET bottles, made with the polyamide compositions of this invention as the barrier layer, are suitable for extended shelf-life packaging of oxygen-sensitive food and beverage products such as beer and juices.Type: ApplicationFiled: February 14, 2002Publication date: February 20, 2003Applicant: Honeywell International Inc.Inventors: Murali K. Akkapeddi, Edward P. Socci, Timothy J. Kraft, Darnell C. Worley, Jeffrey D. Pratt, Clark V. Brown
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Patent number: 6521336Abstract: Disclosed is a composition provided with biodegradable property and transparency which is excellent in heat sealing property at low temperatures, peelability and adhesiveness to substrate as well as a film or laminate of the composition. The composition comprises as indispensable components thereof 27-70% by weight of polylactic acid, 70-27% by weight of an aliphatic polyester, and 1-20% by weight of a tackifier selected from the group consisting of: an aliphatic cyclic hydrocarbon resin, a metal salt of a rosin ester, and a rosin ester having an acid number of 10 or less.Type: GrantFiled: September 25, 2001Date of Patent: February 18, 2003Assignee: Tohcello, Co., Ltd.Inventors: Junichi Narita, Tohru Sawai, Ichiro Takeishi, Suekazu Itoh
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Publication number: 20030032746Abstract: Hetero-telechelic polymers having the formula:Type: ApplicationFiled: June 21, 2002Publication date: February 13, 2003Inventors: James A. Schwindeman, Robert J. Letchford, Conrad W. Kamienski, Roderic P. Quirk
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Patent number: 6518334Abstract: This invention relates to polymer blends comprising a polycarboxypolyamide resin with an alkali dispersible resin. This invention also relates to the use of the polymer blends to prepare aqueous dispersions. The aqueous dispersions were obtained by heating polycarboxypolyamide resins with alkali dispersible resins in an aqueous medium. The invention further relates to coating compositions containing the aqueous dispersions. Such coating compositions include inks, floor finishes, overprint varnishes, sizing, paints and adhesives.Type: GrantFiled: March 22, 2000Date of Patent: February 11, 2003Assignee: JohnsonDiversey, Inc.Inventors: Glenn C. Calhoun, Michael T. Sarkis
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Patent number: 6512049Abstract: Sulfonated substantially random interpolymers made from monomer components comprise from 1 to 65 mole percent of (a) at least one vinyl or vinylidene aromatic monomer, or (b) at least one hindered aliphatic or cycloaliphatic vinylidene monomer, or (c) a combination of at least one vinyl or vinylidene aromatic monomer and at lest one hindered aliphatic or cycloaliphatic vinylidene monomer, and from 35 to 99 mole percent of at least one aliphatic &agr;-olefin having from 2 to 20 carbon atoms; and optionally, from 0 to 20 mole percent of a diene containing from 4 to 20 carbon atoms; wherein the sulfonated interpolymer contains at least one mer (or moiety) of a group represented by the formula —SO3M where M is hydrogen or a group 1, 7 or 12 metal in ionic form or combination thereof. Blends of these polymers with polyamides and polyolefins are made.Type: GrantFiled: May 8, 2002Date of Patent: January 28, 2003Assignee: Dow Global Technologies Inc.Inventors: Yunwa W. Cheung, Stephen F. Hahn, James C. Stevens, Francis J. Timmers, Gregory F. Schmidt, Robert H. Terbrueggen, Thoi H. Ho
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Publication number: 20020193523Abstract: Oxygen scavenging barrier polyamide compositions exhibiting high oxygen scavenging capability as well as good coinjection stretch blow moldability characteristics suitable for making multilayer PET bottles with good clarity and delamination resistance are claimed in this invention. The polyamide compositions of this invention comprise a slow crystallizing polyamide blend comprising (i) an amorphous, semiaromatic polyamide homopolymer, copolymer or mixture thereof and (ii) a semicrystalline, aliphatic polyamide homopolymer, copolymer or mixture thereof wherein in the weight ratio of (i):(ii) ranges from about 99:1 to about 30:70; at least one polyamide-compatible, oxidizable polydiene; and at least one oxidation promoting metal salt catalyst. The multilayer PET bottles, made with the polyamide compositions of this invention as the barrier layer, are suitable for extended shelf-life packaging of oxygen-sensitive food and beverage products such as beer and juices.Type: ApplicationFiled: February 14, 2002Publication date: December 19, 2002Applicant: Honeywell International Inc.Inventors: Murali K. Akkapeddi, Edward P. Socci, Timothy J. Kraft, Darnell C. Worley, Jeffrey D. Pratt, Clark V. Brown
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Patent number: 6492462Abstract: The rheological properties of a crosslinkable resin system are modified by the presence of a side chain crystalline (SCC) polymer (or a similar crystalline polymer which melts over a narrow temperature range). The polymer dissolves in the curable system at temperatures above the melting point of the crystalline polymer (Tp), but when the system is then cooled to a temperature below Tp, at least partially forms a separate phase in the curable system. Below Tp, this separate phase substantially increases the viscosity of the curable system (i.e. makes it thicker than the same system without the crystalline polymer). This is particularly valuable for sheet molding composites (SMCs) in which the increase in viscosity makes the composites less tacky, and for dry film resists (DFRs). Above Tp, the curable system containing the dissolved crystalline polymer has a viscosity which is substantially less than its viscosity below Tp.Type: GrantFiled: December 19, 2000Date of Patent: December 10, 2002Assignee: Landec CorporationInventors: Steven P. Bitler, David D. Taft, Ray F. Stewart
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Patent number: 6472475Abstract: A pregellable adhesive containing several polymers, of which at least one is olefinically unsaturated and the other capable of curing by esterification, prepared in such a way that it cures by two different chemical reaction mechanisms which can be activated successively and catalyzed at least substantially independently of one another.Type: GrantFiled: August 3, 1989Date of Patent: October 29, 2002Assignee: Henkel Kommanditgesellschaft auf Aktien (Henkel KGAA) Henkelstrasse 67Inventors: Thierry Lanoye, Anne-Marie Garnault
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Publication number: 20020103298Abstract: A flame retardant resin composition is herein disclosed which comprises (a) an SPS, (b) a thermoplastic resin having a reactive polar group, (c) a compatibilizing agent having compatibility with the component (a) and a polar group capable of reacting with the component (b), (d) a flame retardant and (e) a flame retardant auxiliary, a weight ratio of the component (a)/the component (b) being less than 1.5, the amount of the component (c) being in the range of 0.5 to 10% by weight with respect to 100% by weight of the total of the components (a), (b) and (c), the amount of the component (d) being 10 parts by weight or more and the amount of the component (e) being 3 parts by weight or more with respect to 100 parts by weight of the total of the components (a), (b) and (c).Type: ApplicationFiled: October 27, 1997Publication date: August 1, 2002Inventors: TOHRU IWASHITA, SHINICHI MIURA
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Patent number: 6414102Abstract: The invention relates to polyolefin copolymers (I) and to graft copolymers (II) which are prepared from the copolymers (I), wherein the copolymers (I) are linear copolymers containing divinylbenzene comonomer units selected from the group consisting of 1,4-divinylbenzene units, mixtures of 1,4- and 1,3-divinylbenzene units and mixtures of 1,4-, 1,3- and 1,2-divinylbenzene units, wherein R, in formulas I and II, is a C1 to C10 linear or branched alkyl group or a C6 to C10 substituted or unsubstituted aromatic group; and wherein G and G′, independently, are selected from —H, —OH, epoxy, —NH2, —COOH, anhydride, —Cl, —Br, —M, —COOM (M=metal) or a polymer chain having the molecular weight of at least about 500, which can be derived from both step and chain polymerization reactions. In the graft copolymer (II), the combined alpha-olefin mole % (x+y) is from about 50 and 99.Type: GrantFiled: March 19, 2001Date of Patent: July 2, 2002Assignee: The Penn State Research FoundationInventors: Tze-Chiang Chung, Jin Yong Dong
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Patent number: 6391971Abstract: A short fiber-reinforced rubber composition comprises a master batch (A) comprised of (a) a first diene-based elastomer, (b) a polyolefin having a melting point of 100-150° C. and (c) short fibers of a thermoplastic polymer having amide group in its main chain, and a second diene-based elastomer (B) kneaded with the master batch (A), in which an amount of the component (c) is 5-30 parts by weight based on 100 parts by weight in total of the first diene-based elastomer and the second diene-based elastomer. Further, a rubber sheet made of the short fiber-reinforced rubber composition is inserted in a given zone of the sidewall portion, whereby the stiffness of the sidewall portion is enhanced to simultaneously establish the steering stability and the ride comfort and reduce the rolling resistance.Type: GrantFiled: November 12, 1999Date of Patent: May 21, 2002Assignee: Bridgestone CorporationInventor: Hiroyuki Teratani
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Patent number: 6376598Abstract: The invention generally relates to thermoplastic blends having improved properties. Optionally, these blends may be dynamically vulcanized. More specifically, this invention is directed to a composition comprising a blend of chloromethylated(styrene-isobutylene)copolymer and a thermoplastic resin selected from the group consisting of polyamides, polyesters, polycarbonates, polysulfones, polyacetals, polyacetones, acrylonitrile-butadiene styrene resins, polyphenylene oxide, polyphenylene sulfide, styrene-acrylonitrile resins, styrene-maleic anhydride resins, polyamides, aromatic polyketones, ethylene vinyl alcohol copolymer and mixtures thereof. Tires and tire components such as air permeation prevention films comprising these compositions are also provided.Type: GrantFiled: June 15, 2000Date of Patent: April 23, 2002Assignee: Exxon Mobil Chemical Patents Inc.Inventor: Hsien-Chang Wang
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Patent number: 6368723Abstract: The present invention relates to a film comprising at least one layer (A) of a mixture of polyamide and polyethylene, and optionally a layer (B) of polyethylene, such that if the polyethylene, of the layer (A) is not a metallocene polyethylene then the layer (B) is obligatory and essentially consists of metallocene polyethylene. These films are used for the moulding of polyesters, for fumigation or for the manufacture of packaging.Type: GrantFiled: October 26, 1999Date of Patent: April 9, 2002Assignee: AtoFinaInventors: Alain Bouilloux, Laurent Teze, Jean-Marc Andre
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Publication number: 20020035208Abstract: A flame retardant resin composition is herein disclosed which comprises (a) an SPS, (b) a thermoplastic resin having a reactive polar group, (c) a compatibilizing agent having compatibility with the component (a) and a polar group capable of reacting with the component (b), (d) a flame retardant and (e) a flame retardant auxiliary, a weight ratio of the component (a)/the component (b) being less than 1.5, the amount of the component (c) being in the range of 0.5 to 10% by weight with respect to 100% by weight of the total of the components (a), (b) and (c), the amount of the component (d) being 10 parts by weight or more and the amount of the component (e) being 3 parts by weight or more with respect to 100 parts by weight of the total of the components (a), (b) and (c).Type: ApplicationFiled: September 24, 2001Publication date: March 21, 2002Applicant: Idemitsu Kosan Co., Ltd.Inventors: Tohru Iwashita, Shinichi Miura
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Patent number: 6359071Abstract: A thermoplastic elastomer composition dynamically vulcanized to a gelation rate of 50 to 95% which is superior in heat resistance and durability while maintaining flexibility and superior in air permeation preventive property which can be efficiently used as, for example, a pneumatic tire as an air permeation preventive layer. In particular, a thermoplastic elastomer composition having a reduced particle size of the domain rubber is produced by a material having a high rubber ratio by mixing a composition (C) mixed under conditions of a ratio of melt viscosities of the rubber composition (A)/resin (B) of 0.8 to 1.2 and the formula (&phgr;A/&phgr;B)×(&eegr;B/&eegr;A)<1.0 under conditions of a ratio of melt viscosities of the rubber composition (D)/composition (C) of 0.8 to 1.2 and the formula (&phgr;D/&phgr;C)×(&eegr;C/&eegr;D)<1.Type: GrantFiled: December 7, 1999Date of Patent: March 19, 2002Assignee: The Yokohama Rubber Co., Ltd.Inventors: Jiro Watanabe, Kazuto Yamakawa, Daisuke Kanenari, Noriaki Kuroda, Gou Kawaguchi, Yuichi Hara, Tetsuji Kawazura, Shigeru Yamauchi, Hideo Nemoto
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Patent number: 6359102Abstract: Improvements are disclosed for biphasic polymerization processes in which an aqueous solution of a first monomer that is hydrolytically unstable below a pH of about six or above a pH of about eight is admixed with a water-immiscible organic solvent and there is added to the admixture a catalyst selected from tertiary amine, quaternary amine and phosphonium catalysts, an acid-forming co-monomer for the first monomer, an acid scavenger, after which the resulting polymer is recovered, wherein the improvement includes providing the aqueous solution at a pH between about si and about eight, and adding to the admixture the acid-forming co-monomer and the acid scavenger at relative rates effective to maintain the pH of the admixture between about six and about eight. The catalyst may be added in a molar ratio to the first monomer effective to provide a predetermined weight-average or number-average molecular weight for the resulting polymer.Type: GrantFiled: June 29, 1998Date of Patent: March 19, 2002Assignee: Integra LifeSciences I, Ltd.Inventors: John E. Kemnitzer, George L. Brode, Joachim B. Kohn
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Patent number: 6346571Abstract: A thermoplastic composition which may be unvulcanized or vulcanized is provided which comprises a polymer blend of an elastomeric thermoplastic engineering resin and a halogen-containing copolymer of a C4 to C7 isomonoolefin and a para-alkylstyrene. A process for preparing a dynamically vulcanized composition is also provided.Type: GrantFiled: November 2, 1999Date of Patent: February 12, 2002Assignee: ExxonMobil Chemical Patents Inc.Inventors: Narayanaswami Raja Dharmarajan, Robert Chester Puydak, Hsien Chang Wang, Kenneth William Powers, Thomas Chen-Chi Yu, Donald Ross Hazelton
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Publication number: 20010053819Abstract: This invention is a flame-retardant, anti-dripping polyamide composition comprising a high temperature polyphthalamide, a halogen-containing organic compound, and an anti-drip effective amount of an anti-drip component comprising a polymer formed from at least one ethylenically unsaturated monomer and at least one carboxylic acid containing monomer.Type: ApplicationFiled: December 18, 2000Publication date: December 20, 2001Inventors: Bruce H. Bersted, Mark G. Reichmann
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Patent number: 6329450Abstract: The present invention relates to a blend of polymeric materials comprising; (A) of from about 1 to about 80 percent by weight (based on the combined weights of Components A and B) of at least one substantially random interpolymer; wherein said interpolymer; (1) contains of from about 0.5 to about 50 mole percent of polymer units derived from; a) at least one vinyl or vinylidene aromatic monomer, or b) at least one hindered aliphatic or cycloaliphatic vinyl or vinylidene monomer, or c) a combination of at least one vinyl or vinylidene aromatic monomer and at least one hindered aliphatic or cycloaliphatic vinyl or vinylidene monomer; (2) contains of from about 50 to about 99.5 mole percent of polymer units derived from at least one aliphatic &agr;-olefin having from 2 to 20 carbon atoms; (3) has a melt index (I2) of from about 0.01 to about 100 g/10 min; and (4) has a molecular weight distribution (Mw/Mn) of from about 1.Type: GrantFiled: March 2, 1999Date of Patent: December 11, 2001Assignee: The Dow Chemical CompanyInventors: Samuel A. Ogoe, Charles F. Diehl, Leo A. Novak, Wendy D. Hoenig, Shaofu Wu, Donna C. Scott
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Patent number: 6326084Abstract: The invention relates to a method of high frequency welding of non-polar thermoplastic elastomers characterized in that said elastomers comprise a polar modifier. Furthermore, the invention relates to shaped articles obtainable by said method.Type: GrantFiled: April 21, 1998Date of Patent: December 4, 2001Assignee: Advanced Elastomer Systems, L.P.Inventors: Trazollah Ouhadi, Jacques Horrion, Ernst Van Issum
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Patent number: 6303691Abstract: The invention relates to impact modifiers for polyamide compositions which improve the impact strength of the polyamides without adversely affecting the flexural modulus of the composition. The impact modifiers comprise blends of halogenated copolymers of a C4 to C7 isomonoolefin and an alkyl/styrene with a polyolefin.Type: GrantFiled: June 7, 1993Date of Patent: October 16, 2001Assignee: Exxon Mobil Chemical Patents Inc.Inventors: Thomas Chen-chi Yu, Kenneth William Powers, Hsien Chang Wang
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Patent number: 6300413Abstract: A crosslinkable hot-melt adhesive composition, comprising a reactive powder mixed with a crosslinking component of a crosslinking agent bound in a polyolefin matrix, wherewith the components of the composition do not react by crosslinking until the mixture is melted, said composition being useful for the coating and/or lamination of sheet-like structures.Type: GrantFiled: March 3, 1999Date of Patent: October 9, 2001Assignee: Degussa-Huels AktiengesellschaftInventors: Ulrich Simon, Thorsten Gurke, Hans-Willi Losensky
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Patent number: 6284840Abstract: The invention is directed to golf ball core compositions comprising at least one natural or synthetic rubber and at least one high Vicat softening temperature thermoplastic material, methods of preparing the compositions, and golf ball cores and golf balls including the compositions. The compositions of the invention are made by mixing at least one natural or synthetic rubber and at least one thermoplastic or thermoplastic elastomer at a first temperature; cooling the mixture to a second temperature which is below an activation temperature of a free-radical initiator; adding the free-radical initiator to the first mixture to form a second mixture; and heating the second mixture to a third temperature that to facilitate crosslinking.Type: GrantFiled: April 2, 1999Date of Patent: September 4, 2001Assignee: Acushnet CompanyInventors: Murali Rajagopalan, Derek A. Ladd
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Publication number: 20010018492Abstract: A thermoplastic elastomer composition dynamically vulcanized to a gelation rate of 50 to 95% which is superior in heat resistance and durability while maintaining flexibility and superior in air permeation preventive property which can be efficiently used as, for example, a pneumatic tire as an air permeation preventive layer. In particular, a thermoplastic elastomer composition having a reduced particle size of the domain rubber is produced by a material having a high rubber ratio by mixing a composition (C) mixed under conditions of a ratio of melt viscosities of the rubber composition (A)/resin (B) of 0.8 to 1.2 and the formula (&phgr;A/&phgr;B)×(&eegr;B/&eegr;A)<1.0 under conditions of a ratio of melt viscosities of the rubber composition (D)/composition (C) of 0.8 to 1.2 and the formula (&phgr;D/&phgr;C)×(&eegr;C/&eegr;D)<1.Type: ApplicationFiled: March 8, 2001Publication date: August 30, 2001Applicant: YOKOHAMA RUBBER CO., LTD.Inventors: Jiro Watanabe, Kazuto Yamakawa, Daisuke Kanenari, Noriaki Kuroda, Gou Kawaguchi, Yuichi Hara, Tetsuji Kawazura, Shigeru Yamauchi, Hideo Nemoto
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Patent number: 6265493Abstract: The invention relates to a process for preparing polyolefin graft copolymers (II) from linear and well defined polyolefin copolymers (I) containing divinylbenzene comonomer units, wherein R, in formulas I and II, is a C1 to C10 linear or branched alkyl group or a C6 to C10 substituted or unsubstituted aromatic group; and wherein G and G′, independantly, are selected from —H, —OH, epoxy, —NH2, —COOH, anhydride, —Cl, —Br, —M, —COOM (M=metal, e.g., Li, Na, K and Ca) or a polymer chain having the molecular weight of at least about 500, which can be derived from both step and chain polymerization reactions. G and G′ can be selected singly or in a combination of two or more thereof. In the graft copolymer composition, the combined alpha-olefin mole .% (x+y) is from about 50 to 99.9 mole %. Preferably, x+y is from 85 to 99.9 mole %, and most preferably x+y is from 95 to 99.9 mole %.Type: GrantFiled: May 18, 2000Date of Patent: July 24, 2001Assignee: The Penn State Research FoundationInventors: Tze-Chiang Chung, Jinyong Dong
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Patent number: 6235844Abstract: These novel brominated styrenic polymers have a bromine content in the range of about 60 to about 66 wt % bromine; a total chlorine content, if any, of less than 700 ppm; a GPC weight average molecular weight in the range of about 500,000 to about 800,000; a DSC glass transition temperature of less than 175° C.; and a thermal stability in the Thermal Stability Test of 250 ppm HBr or less. Such flame retardant polymers exhibit superior performance qualities during use, especially in thermoplastics, including improved melt flow characteristics and improved thermal stability.Type: GrantFiled: October 13, 1998Date of Patent: May 22, 2001Assignee: Albemarle CorporationInventors: Billie B. Dadgar, Donald E. Balhoff, Charles H. Kolich, Meng-Sheng Ao, Homer C. Lin
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Patent number: 6232393Abstract: Flame retarded thermoplastic polymer compositions are formed by blending together a thermoplastic polymer and at least a flame retardant amount of a brominated styrenic polymer having, prior to blending, a total bromine content of at least about 50 wt % and in addition specified characteristics pertaining to such properties as (i) TGA temperature for 1% weight loss, (ii) hydrolyzable bromine content, (iii) chlorine content (if any), and/or (iv) thermal stability using a described Thermal Stability Test. Blends made with prior art brominated polystyrenes do not possess the enhanced thermal stability and reduced metal corrosiveness provided by these brominated styrenic polymers.Type: GrantFiled: September 10, 1998Date of Patent: May 15, 2001Assignee: Albemarle CorporationInventors: Billie B. Dadgar, Donald E. Balhoff, Charles H. Kolich, Meng-Sheng Ao, Homer C. Lin
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Patent number: 6232408Abstract: Novel brominated styrenic polymers have an ionic bromine content of 2000 ppm or less, and one or more of the following additional characteristics: (a) a TGA temperature for 1% weight loss which is 340° C. or higher, and a chlorine content, if any, of less than about 700 ppm Cl (b) an actual Mw which is within about 20% of the calculated theoretical Mw, the theoretical Mw being based upon the actual bromine content of the brominated styrenic polymer and the Mw of the styrenic polymer reactant used to produce the brominated styrenic polymer; and (c) essentially no content of impurities selected from the group consisting of ethylene dichloride, bromodichloroethane, dibromochloroethane, dibromodichloroethane, and tribromochloroethane. Such flame retardant polymers exhibit superior performance qualities during use, especially in thermoplastics such as glass-filled polyesters and glass-filled nylons.Type: GrantFiled: September 10, 1998Date of Patent: May 15, 2001Assignee: Albemarle CorporationInventors: Billie B. Dadgar, Donald E. Balhoff, Charles H. Kolich, Meng-Sheng Ao, Homer C. Lin
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Patent number: 6197891Abstract: A process for the preparation of hydrocarbon solutions of monofunctional ether initiators of the following general structure: M—Qn—Z—O—[A(R1R2R3)] wherein M is an alkali metal selected from the group consisting of lithium, sodium and potassium; Q is a saturated or unsaturated hydrocarbyl group derived by incorporation of a compound selected from the group consisting of conjugated diene hydrocarbons, alkenylsubstituted aromatic hydrocarbons, and mixtures thereof into the M—Z linkage; Z is a branched or straight chain hydrocarbon group which contains 3-25 carbon atoms, optionally containing aryl or substituted aryl groups; A is an element selected from carbon and silicon; R1, R2, and R3 are independently selected from hydrogen, alkyl, substituted alkyl groups containing lower alkyl, lower alkylthio, and lower dialkylamino groups, aryl or substituted aryl groups containing lower alkyl, lower alkylthio, and lower dialkylamino groups, and n is an integer from 1 to 5, monofType: GrantFiled: September 26, 1996Date of Patent: March 6, 2001Assignee: FMC CorporationInventors: James Anthony Schwindeman, Eric John Granger, Robert Charles Morrison, Conrad William Kamienski, Robert James Letchford
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Patent number: 6162545Abstract: An agent for providing an electrostatic coating property and improving the water resistance of a coating film comprises 100 weight parts of an aromatic ring-containing polyetheresteramide (A) derived from a polyamide having carboxyl groups at both ends and having a number average molecular weight of 500 to 5,000 and an alkylene oxide adduct of bisphenols having a number average molecular weight of 1,600 to 3,000; and 5 to 100 weight parts of a vinyl copolymer comprising as essential constituent units a vinyl monomer (b1) having a sulfonic acid (or sulfonate) group and at least one monomer (b2) selected from vinyl monomers having a functional group that is reactive with (A).Type: GrantFiled: February 10, 1999Date of Patent: December 19, 2000Assignees: Honda Giken Kogyo Kabushiki Kaisha, Sanyo Chemical Industries, Ltd.Inventors: Shiro Kamiyama, Katsumi Kohama, Hisashi Masuda, Takeo Okada, Eiji Inada
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Patent number: 6160054Abstract: Hetero-telechelic polymers having the formula:FG--(Q).sub.d --Z--J--[A(R.sup.1 R.sup.2 R.sup.3)].sub.x (I)wherein FG is a protected or non-protected functional group; Q is a saturated or unsaturated hydrocarbyl group derived by incorporation of a compound selected from the group consisting of conjugated diene hydrocarbons, alkenylsubstituted aromatic hydrocarbons, and mixtures thereof; d is an integer from 10 to 200; Z is a branched or straight chain hydrocarbon group which contains 3-25 carbon atoms, optionally containing aryl or substituted aryl groups; J is oxygen, sulfur, or nitrogen; [A(R.sup.1 R.sup.2 R.sup.3)].sub.x is a protecting group, wherein A is an element selected from Group IVa of the Periodic Table of Elements; R.sup.1, R.sup.2, and R.sup.Type: GrantFiled: July 18, 1996Date of Patent: December 12, 2000Assignee: FMC CorporationInventors: James A. Schwindeman, Robert J. Letchford, Conrad W. Kamienski, Roderic P. Quirk
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Patent number: 6153706Abstract: This invention provides novel protected, multi-functionalized multi-arm polymers, their optionally hydrogenated analogues and optionally deprotected analogues thereof, and processes for making these compounds. In the invention, monomers are polymerized using a protected functionalized initiator to form living polymer anions, the living anions coupled to form multi-arm polymers, additional monomer added to form additional polymer arms, and the multi-arm polymer functionalized using electrophiles.Type: GrantFiled: July 28, 1998Date of Patent: November 28, 2000Assignee: FMC CorporationInventors: Robert James Letchford, James Anthony Schwindeman
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Patent number: 6133375Abstract: The present invention relates to a vulcanized mixture:(i) of at least one functionalized rubber and(ii) of at least one thermoplastic in an amount which is sufficient to increase the modulus at small elongations but such that the breaking stress is not reduced by more than 10%.The thermoplastic can be chosen from polyamides and copolymers containing polyamide blocks and polyether blocks.Type: GrantFiled: June 3, 1997Date of Patent: October 17, 2000Assignee: Elf Atochem, S.A.Inventors: Isabelle Betremieux, Patrick Alex, Philippe Marcq, Christian Dousson
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Patent number: 6096817Abstract: The invention relates to a polymeric blend having a major amount of an elastomeric material and a minor amount of at least one particulate polyimide. Additionally, the polymeric blend may further contain lubricants.Type: GrantFiled: June 26, 1997Date of Patent: August 1, 2000Assignee: E. I. du Pont de Nemours and CompanyInventor: James Francis Mc Namara
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Patent number: 6087435Abstract: A polystyrene-based resin composition, comprising (A) a styrene-based resin with a mainly syndiotactic configuration, (B) a polyolefin, and (C) rubber polymer particles as main components, exhibits excellent heat resistance and impact resistance.Type: GrantFiled: June 5, 1995Date of Patent: July 11, 2000Assignee: Idemitsu Kosan Co., Ltd.Inventors: Akikazu Nakano, Takashi Sumitomo, Keisuke Funaki, Toshikazu Ijitsu, Michihiro Sawada, Masahiko Kuramoto, Masakazu Suzuki
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Patent number: 6072001Abstract: The present invention uses high molecular weight polyethene glycol copolymer with high antistatic property, and other solubilizer agent to proceed blending and enhancing the co-solublization property of the polyamide. The long-term antistatic plastic particles obtained by blending the modified antistatic composition and the polyamide material are made into different articles according to various composites. The molded articles are divided into three types: (1) an antistatic polyamide article with surface resistance of about 10.sup.10 -10.sup.11 (.OMEGA./sq.), and the dissipation time of electrostatic charge is less than 1.5 sec; (2) an antistatic polyamide fiber with surface resistance of about 6.times.l0.sup.10 -1.2.times.10.sup.12 (.OMEGA./sq.), and the dissipation time of electrostatic charge is less than 60 sec; (3) a polishing resistant antistatic polyamide with surface resistance of about 10.sup.10 -10.sup.11 (.OMEGA./sq.), and the dissipation time of electrostatic charge is less than 1.5 sec.Type: GrantFiled: January 27, 1998Date of Patent: June 6, 2000Assignee: Industrial Technology Research InstituteInventors: Hsin-Herng Wang, Bin-Yuan Lin
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Patent number: 6068934Abstract: The present invention provides a sheet molding compound consisting in a sandwich structure comprising a central layer of reinforced uncured heat hardenable sheet molding compound; and two outer layers of a release film having low permeability to hydrocarbons comprising at least one layer (i) of a polyamide/polyolefin alloy having a polyamide matrix and at least one layer (ii) of a polyolefin.Type: GrantFiled: January 12, 1999Date of Patent: May 30, 2000Assignee: Elf Atochem S.A.Inventors: Franck Vandekerckhove, Alain Bouilloux, Regis Jacquemet, Bruno Echalier
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Patent number: 6063504Abstract: Disclosed is a composite olefin resin laminated sheet comprising a surface layer and an intermediate layer, wherein the surface layer comprises an olefin resin composite material having a melt flow rate of not higher than 20 g/10 min and a density of 1.00 to 1.90 g/cm.sup.3, and the intermediate layer comprising (1) a composite olefin resin composition comprising 100 parts by weight of an olefin resin composite material having a melt flow rate of not higher than 20 g/10 min and a density of 1.00 to 1.90 g/cm.sup.3 and 0.01 to 10 parts by weight of polytetrafluoroethylene or (2) an olefin resin composition comprising 100 parts by weight of an olefin resin having a melt flow rate of 0.3 to 20 g/10 min and a density of not less than 0.890 g/cm.sup.3 and 0.01 to 10 parts by weight of polytetrafluoroethylene.Type: GrantFiled: December 4, 1998Date of Patent: May 16, 2000Assignee: Japan Polychem CorporationInventors: Yoshinobu Nagaoka, Akihiko Egashira, Toshimitsu Hasegawa
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Patent number: 6062283Abstract: A pneumatic tire having an air permeation preventive layer comprising a low permeability thermoplastic elastomer composition comprising a thermoplastic elastomer having a thermoplastic resin composition as a continuous phase and a rubber composition as a dispersed phase, in which a barrier resin composition is contained, which low permeability thermoplastic elastomer composition has a phase structure in which the barrier resin composition is dispersed in the form of a flat state in the thermoplastic elastomer, is abundant in flexibility, is superior in gas permeation preventive property, and enables the tire to be reduced in weight.Type: GrantFiled: January 28, 1998Date of Patent: May 16, 2000Assignee: The Yokohama Rubber Co., Ltd.Inventors: Jiro Watanabe, Noriaki Kuroda, Gou Kawaguchi, Tetsuji Kawazura, Hidekazu Takeyama, Yoshihiro Soeda, Kazuo Suga, Yoshiaki Hashimura, Osamu Ozawa
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Patent number: 6060562Abstract: A thermoplastic composition with improved properties for making fuel containers, e.g. for fuel oil, petrol, diesel oil or alcohol, and specifically for making fuel lines for feeding fuel to a fuel tank or engine. The thermoplastic composition includes a thermoplastic polymer matrix and at least one compound that enhances the resilience of thermoplastic compositions. Said matrix consists of a mixture of: at least one first thermoplastic copolymer produced by copolymerising .epsilon.-caprolactam with at least one monomer selected from the group which includes an amino acid having at least nine carbon atoms, or the corresponding lactam, and a mixture of hexamethylediamine and a diacid having at least nine carbon atoms, the weight ratio of the .epsilon.-caprolactam to the total amount of hexamethylenediamine and diacid being 4-9; and at least one second thermoplastic polymer or copolymer produced by polymerising monomers having at least nine carbon atoms.Type: GrantFiled: June 5, 1998Date of Patent: May 9, 2000Assignee: Nyltech ItaliaInventors: Cesare Guaita, Franco Speroni
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Patent number: 6054209Abstract: A tearable film comprising a resin blend which is: (1) a blend of a first polymer which is a styrenic polymer and a second polymer selected from the group consisting of a polyester and a polyamide; or (2) a first polymer which is a polyester and a second polymer selected from the group consisting of a polycarbonate, an acrylic polymer and a polyamide. The film has an continuous phase and a dispersed phase, thereby forming an islands-sea structure, wherein the continuous phase constitutes 35-98 wt % and the dispersed phase constitutes 2-65 wt % of the film.Type: GrantFiled: March 9, 1998Date of Patent: April 25, 2000Assignee: Daicel Chemical Industries, Ltd.Inventors: Shinichiro Imanishi, Kenji Ueda, Katsuhiko Sumida
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Patent number: 6051655Abstract: A composition amenable to injection molding and extrusion comprises a syndiotactic styrene resin, a thermoplastic resin such as a polyolefin and an inorganic filler optionally contains a rubber.Type: GrantFiled: June 5, 1995Date of Patent: April 18, 2000Assignee: Idemitsu Kosan Co., Ltd.Inventors: Akikazu Nakano, Takashi Sumitomo, Keisuke Funaki, Toshikazu Ijitsu, Michihiro Sawada, Masahiko Kuramoto, Masakazu Suzuki
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Patent number: 6046279Abstract: A novel, continuous process for the manufacture of novel higher molecular weight and higher acid numbered maleated polypropylenes with lower color at higher efficiencies involving specified ratios of polypropylene, maleic anhydride, and free radical initiator is described. The novel maleated polypropylenes have an acid number greater than 4.5, a yellowness index color of no greater than 76, and a number average molecular weight of at least 20,000. The process entails continuously forming an intimate mixture of molten polypropylene and molten maleic anhydride at one end of a reactor, continuously introducing a free radical initiator, and continuously removing high acid number high molecular weight maleated polypropylene of low color from the opposite end of the reactor.Type: GrantFiled: February 24, 1999Date of Patent: April 4, 2000Assignee: Eastman Chemical CompanyInventors: Thomas David Roberts, Stephen Wayne Coe
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Patent number: 6046275Abstract: A composition comprises (A) a syndiotactic styrene-based resin and (C) rubber polymer particles such as graft copolymers, butadiene or isoprene block copolymers optionally hydrogenated and/or modified with maleic anhydride, and other rubbers, and, optionally, (B) a thermoplastic resin such as a polycarbonate, and/or (D) a filler such as glass fibers.Type: GrantFiled: June 5, 1995Date of Patent: April 4, 2000Assignee: Idemitsu Kosan Co., Ltd.Inventors: Akikazu Nakano, Takashi Sumitomo, Keisuke Funaki, Toshikazu Ijitsu, Michihiro Sawada, Masahiko Kuramoto, Masakazu Suzuki