With Additional Solid Polymer Derived From At Least One Nonethylenic Reactant Patents (Class 525/185)
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Patent number: 6013719Abstract: Low melt viscosity polytetrafluorethylene (PTFE), i.e. having a melt viscosity of 50 to 1.times.10.sup.5 Pa.multidot.s at 372.degree. C., is combined with non-fluorinated thermally stable polymer such as polyarleneetherketone to provide melt-fabricability application for the low MV PTFE and provide improved properties for the thermally stable polymer.Type: GrantFiled: June 15, 1998Date of Patent: January 11, 2000Assignee: E. I. du Pont de Nemours and CompanyInventor: Jacob Lahijani
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Patent number: 6008297Abstract: A polyamide resin composition superior in the shock resitance, especially low temperature shock resistence, in the rigidity and in the water absorption resistance, which comprises(A) 98-50 % by weight of a polyamide,(B) 1-40 % by weight of a modified ethylene/.alpha.-olefin copolymer having an MFR (190.degree. C.) of 0.05-50 g/10 min., obtained by a graft-copolymerization of 100 parts by weight of an ethylene/.alpha.-olefin copolymer (B-1) having an ethylene content of 40-93 mole % and a density of lower than 0.900 g/cm.sup.3, with, grafted thereon, 0.01-5 parts by weight of an unsaturated dicarboxylic acid or its derivative (B-2), and(C) 1-40 % by weight of at least one ethylenic copolymer selected from the group consisting of an ethylene/.alpha.-olefin copolymer (C-1) having an .alpha.-olefin content of 10 mole % or less, an Mw/Mn of 2.5 or lower and an MFR (190.degree. C.) of 0.05-50 g/10 min. and a modified ethylen/.alpha.Type: GrantFiled: May 15, 1998Date of Patent: December 28, 1999Assignee: Mitsui Chemicals, Inc.Inventors: Yasuo Tanaka, Youji Hayakawa
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Patent number: 5998019Abstract: A multiple layer structure comprising a skin layer composed of a polypropylene copolymer with styrene ethylene-butene styrene block copolymer within a range of 0-20% by weight skin layer, and, a radio frequency ("RF") susceptible layer adhered to the skin layer. The RF layer has a first component of a propylene based polymer, a second component of a nonpropylene polyolefin, a third component of a radio frequency susceptible polymer, and a fourth component of a polymeric compatibilizing agent.Type: GrantFiled: November 16, 1993Date of Patent: December 7, 1999Assignee: Baxter International Inc.Inventors: Larry A. Rosenbaum, William Anderson, Lecon Woo, Dean Laurin, Angeles Lillian Buan, Michael T.K. Ling, Yuan Pang Samuel Ding, Denise S. Hayward, Joseph P. Hoppesch, Gregg Nebgen, Stanley Westphal
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Patent number: 5986006Abstract: Homo- or copolymers A composed ofA.sub.1) 40-100% by weight of monomers of the general formula I ##STR1## A.sub.2) 0-60% by weight of monomers of the general formula II ##STR2## and A.sub.3) 0-10% by weight of further monomers capable of free radical polymerization,the percentages by weight of the monomers A.sub.1) to A.sub.3) summing to 100% andR.sup.1 and R.sup.4 being identical or different radicals and each being hydrogen or C.sub.1 -C.sub.4 -alkyl,R.sup.2, R.sup.3, R.sup.5, R.sup.6 being identical or different radicals and each being hydrogen or C.sub.1 -C.sub.4 -alkyl,with the proviso that at least two radicals from the group consisting of R.sup.1, R.sup.2 and R.sup.3 and from the group consisting of R.sup.4, R.sup.5 and R.sup.6 are hydrogen, andR.sup.7 is alkyl, cycloalkyl, aryl or aralkyl,are used as branching agents for amino-containing thermoplastic polymers.Type: GrantFiled: January 29, 1998Date of Patent: November 16, 1999Assignee: BASF AktiengsellschaftInventors: Alexander Gluck, Walter Gotz, Gregor Ley
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Patent number: 5977201Abstract: Polymer systems having reversibly temperature-dependent radiation transmission which are crosslinked with radiation induction, a process for their production, and their use for reversibly temperature-dependent control of the radiation transmission of glazing systems and solar-energy devices.Type: GrantFiled: January 6, 1998Date of Patent: November 2, 1999Assignee: BASF AktiengesellschaftInventors: Ekkehard Jahns, Hubertus Kroner, Wolfgang Schrof, Utz Klodwig
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Patent number: 5945484Abstract: A water-in-oil dispersed ink comprising:(A) a water-insoluble dispersion medium comprising 20% by weight--50% by weight of a water-insoluble polar solvent of an aromatic alcohol and/or an aliphatic glycol phenyl ether, 0.5% by weight--5.0% by weight of a water-insoluble organic amine, and 3% by weight--30% by weight of an oil-soluble dye, all percentages being based on the total weight of the ink; and(B) a particulate dispersion phase including a dispersion stabilizing phase comprising a polyhydric alcohol that is formed on the surface of dispersed particles, the particulate dispersion phase comprising 20% by weight--50% by weight of the polyhydric alcohol, and a water-based dispersoid comprising 3% by weight--20% by weight of water, 0.3% by weight--2.0% by weight of a cross-linking acrylic acid polymer, and 0.5% by weight--4.0% by weight of triethanol amine, all percentages being based on the total weight of the ink, and wherein the dispersed particles are uniformly dispersed in the dispersion medium.Type: GrantFiled: November 26, 1997Date of Patent: August 31, 1999Assignee: Kabushiki Kaisha PilotInventor: Teruaki Fukasawa
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Patent number: 5929137Abstract: The invention relates to a process for the production of a material having an improved dielectric strength and use of said material in the manufacture of power transmission cables.The object of the invention is to obtain mixtures remaining macroscopically very insulating and which locally, at a scale below 1 micron, can have conductivity levels of approximately 10.sup.-9 S.cm.sup.-1.This object is achieved with the aid of a process comprising the following stages:dissolving at least one conductive polymer in an organic solvent, to form an impregnation solution and impregnating granules constituted by an insulating polymer or a mixture of insulating polymers,evaporating the solvent to obtain insulating polymer granules covered with a conductive polymer,drying said granules,hot mixing or extruding said granules to form a homogeneous mixture, which can be restored to granule form.Type: GrantFiled: September 29, 1997Date of Patent: July 27, 1999Assignee: Commissariat A L'Energie AtomiqueInventors: Didier Marsac, Patrick Hourquebie
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Patent number: 5925442Abstract: Olefin/carbon monoxide alternating polymers are flash-spun to form plexifilamentary products, pulp products, and foam products from alcohol or halogenated hydrocarbon solvents having 1 to 3 carbon atoms.Type: GrantFiled: September 15, 1997Date of Patent: July 20, 1999Assignee: E. I. du Pont de Nemours and CompanyInventor: Hyunkook Shin
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Patent number: 5919845Abstract: The present invention relates to a powder coating having improved surface properties which contains from 0.05 to 5% by weight, preferably 0.5 to 1.5% by weight, of aliphatic polyvinyl ethers.Type: GrantFiled: April 23, 1998Date of Patent: July 6, 1999Assignee: BASF Coatings AGInventors: Richard Foukes, Klaus Cibura, Rolf Boysen, Josef Rademacher
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Patent number: 5910543Abstract: Thermoplastic elastomer compositions which have good high temperature end use and good oil swell resistance are made by blending a high melting thermoplastic polymer containing a non-polar rubber and a polar rubber. Alternatively, a high melting thermoplastic polymer containing a non-polar rubber or a polar rubber or both is blended with a polyolefin thermoplastic polymer containing a non-polar rubber, or a polar rubber, or both. The composition is dynamically vulcanized. The cured multi-component thermoplastic elastomer compositions exhibit good end use properties such as hardness, tensile strength, modulus, flexibility.Type: GrantFiled: December 18, 1996Date of Patent: June 8, 1999Assignees: Advanced Elastomer Systems, L.P., Exxon Chemical Patents IncInventors: Raman Patel, Sabet Abdou-Sabet, Hsien-Chang Wang
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Patent number: 5908898Abstract: Electrically conductive polymer blends are produced from an insulating thermoplastic polymer phase and a conductivity enhancing composition that forms a continuous conductive phase and includes an intrinsically conductive polymer salt that is incompatible with the thermoplastic polymer, a thermoplastic conductive phase polymer and a plasticizer that is capable of compatibilizing the conductive phase polymer and the intrinsically conductive polymer salt. The intrinsically conductive polymer salt is concentrated in the continuous conductive phase Methods are also provided for the preparation of these conductive polymer blends.Type: GrantFiled: February 12, 1998Date of Patent: June 1, 1999Assignee: Monsanto CompanyInventors: Lucy Ka Po Wan-Cheng, Lawrence W. Shacklette, Chien-Chung Han
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Patent number: 5891956Abstract: Water-soluble polymers including functionalization from the group of amino groups, carboxylic acid groups, phosphonic acid groups, phosphonic ester groups, acylpyrazolone groups, hydroxamic acid groups, aza crown ether groups, oxy crown ethers groups, guanidinium groups, amide groups, ester groups, aminodicarboxylic groups, permethylated polyvinylpyridine groups, permethylated amine groups, mercaptosuccinic acid groups, alkyl thiol groups, and N-alkylthiourea groups are disclosed.Type: GrantFiled: May 30, 1995Date of Patent: April 6, 1999Assignee: The Regents of the University of California, Office of Technology TransferInventors: Barbara F. Smith, Thomas W. Robison, Joel W. Gohdes
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Patent number: 5869568Abstract: A one-part cold crosslinking emulsion composition containing, in an aqueous medium, a double-structure fine grain comprising the following Component (A) 1 and the following Component (B) 2 covering the same, wherein the following Component (C) is contained in Component (B) 2:(A) a copolymer comprising an epoxy group-containing monomer and an ethylenic unsaturated monomer;(B) a copolymer comprising an unsaturated carboxylic acid and an ethylenic unsaturated monomer; and(C) a low molecular weight monofunctional epoxy compound.Type: GrantFiled: November 12, 1997Date of Patent: February 9, 1999Assignee: National Starch and Chemical Investment Holding CorporationInventor: Norihisa Maeda
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Patent number: 5863963Abstract: Disclosed is a process which comprises the steps of (a) providing a polymer containing at least some monomer repeat units with halomethyl group substituents which enable crosslinking or chain extension of the polymer upon exposure to a radiation source which is electron beam radiation, x-ray radiation, or deep ultraviolet radiation, said polymer being of the formula ##STR1## wherein x is an integer of 0 or 1, A is one of several groups as specified in the claims, B is one of several groups as specified in the claims, and n is an integer representing the number of repeating monomer units, and (b) causing the polymer to become crosslinked or chain extended through the photosensitivity-imparting groups. Also disclosed is a process for preparing a thermal ink jet printhead by the aforementioned curing process.Type: GrantFiled: August 29, 1996Date of Patent: January 26, 1999Assignee: Xerox CorporationInventors: Ram S. Narang, Timothy J. Fuller
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Patent number: 5859129Abstract: A polymer blend comprises a polyketone and a high density polyethylene (HDPE) optionally grafted with at least one polymerisable ethylenically unsaturated carboxylic acid or derivative thereof. Such blends have good barrier properties and are suitable for packaging applications.Type: GrantFiled: October 30, 1996Date of Patent: January 12, 1999Assignee: BP Chemicals LimitedInventor: James Graham Bonner
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Patent number: 5859174Abstract: Ethylenically unsaturated compounds are provided having Structure I and from which polymers with a plurality of groups of Structure II are derived. ##STR1## In Structures I and II, R.sub.1 is hydrogen or methyl, and R.sub.3 is hydrogen or lower alkyl having 1 to 4 carbon atoms, and when R.sub.3 is hydrogen and R.sub.2 has two carbon atoms R.sub.2 is methyl methylene. In Structure I, R.sub.2 and in Structure II R'.sub.2 is a divalent linking group having 2 to 20 carbon atoms. When R.sub.3 is hydrogen and R'.sub.2 has two carbon atoms, R'.sub.2 is methyl methylene. The compounds of Structure I may be used as monomers and reacted with other ethylenically unsaturated monomers via addition polymerization to arrive at the polymer with groups of Structure II.Type: GrantFiled: July 22, 1996Date of Patent: January 12, 1999Assignee: PPG Industries, Inc.Inventors: Steven V. Barancyk, Neil D. McMurdie, James B. O'Dwyer
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Patent number: 5859138Abstract: A polymer blend comprised of a polyketone and linear low density polyethylene (LLDPE). The blend is suitable for use with foodstuffs and liquid hydrocarbons. In a preferred form of the invention, the polyketone has an alternating structure of (a) units derived from carbon monoxide and (b) units derived from one or more olefinically unsaturated compounds.Type: GrantFiled: February 20, 1997Date of Patent: January 12, 1999Assignee: BP Chemicals LimitedInventors: James Graham Bonner, Anthony Keith Powell
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Patent number: 5852100Abstract: A thermoplastic resin composition with improved low-temperature impact strength and rigidity against heat, comprising (I) 10-40% by weight of a mixture of (a) 10-50% by weight of a propylene homopolymer and/or an ethylene-propylene block copolymer (an isotactic pentad fraction of a propylene homopolymer portion being 0.98 or above) and (b) 50-90% by weight of an olefin-based copolymer rubber, said mixture having been dynamically heat treated in the presence of an organic peroxide and a crosslinking agent, (II) 20-85% by weight of a propylene homopolymer and/or an ethylene-propylene block copolymer (an isotactic pentad fraction of a propylene homopolymer portion being 0.98 or above and a melt index of the propylene homopolymer portion being 30-150 g/10 min), and (III) 5-40% by weight of an inorganic filler.Type: GrantFiled: April 23, 1996Date of Patent: December 22, 1998Assignees: Sumitomo Chemical Company, Limited, Toyota Jidosha Kabushiki KaishaInventors: Hajime Sadatoshi, Haruyuki Suzuki, Yuichi Miyake, Takao Nomura, Takeyoshi Nishio
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Patent number: 5843581Abstract: A copolymer blend comprising vinylidene chloride-vinyl chloride copolymer, vinylidene chloride-methyl acrylate copolymer or a mixture thereof, from 2 to 20% by weight of CO-modified ethylene vinyl acetate copolymer or CO-modified ethylene alkyl acrylate copolymer and preferably up to 5%, of a plasticizer and/or stabiliser, relative to the total weight of the blend is useful as a barrier layer in a multi-layer film for packaging food such as cheese. A multi-layer film comprising such a blend, a method of producing such a blend or multi-layer film and a package or bag formed from the film.Type: GrantFiled: August 4, 1997Date of Patent: December 1, 1998Assignee: Cryovac, Inc.Inventors: Mario Paleari, Tito Fornasiero
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Patent number: 5830945Abstract: Rigid-rod macromonomers, and methods for preparing such macromonomers, having a polyaromatic backbone, solubilizing side groups, and reactive side groups are provided. The macromonomers are chemically incorporated into polymer systems to provide stronger, stiffened polymers.Type: GrantFiled: August 23, 1996Date of Patent: November 3, 1998Assignee: Maxdem, IncorporatedInventors: Robert R. Gagne, Matthew Louis Marrocco, III, Mark Steven Trimmer, Neil H. Hendricks
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Patent number: 5824742Abstract: An objective of the invention is to provide a polyacetal resin composition which has excellent resistance to heat aging and grease resistance, has welded sections with no decrease in physical properties, and has improved friction characteristics, and molded articles therefrom. A polyacetal resin composition comprising per 100 parts by weight of a polyacetal resin, 2-7 parts by weight of a polymer composition based on an olefinic polymer having glycidyl-group-containing pendant chains and 0.5-2.5 parts by weight of a dimethyl siloxane polymer of a plasticity of at least one; a polyacetal resin composition further comprising 100 parts by weight of the preceding resin composition along with 0.05-0.5 parts by weight of carbon black; and molded articles therefrom.Type: GrantFiled: September 10, 1997Date of Patent: October 20, 1998Assignee: E. I. du Pont de Nemours and CompanyInventor: Kenichi Shinohara
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Patent number: 5795923Abstract: A photo-degradable, molded, high strength plastic shotshell component having a degradation composition comprising as its combination of active ingredients linear polyethylene having a melt index of 0.1 to 5.0 and an ethylene-vinyl acetate-carbon monoxide terpolymer, the ratios by weight of which to said linear polyethylene is approximately 0.115:1 to 0.261:1 The ethylene-vinyl acetate-carbon monoxide terpolymer in its preferred composition has about 65% by weight of ethylene, 25% by weight of vinyl acetate, and 10% by weight of carbon monoxide.Type: GrantFiled: October 17, 1995Date of Patent: August 18, 1998Assignee: Federal Cartridge CompanyInventor: Mohammed Shahid
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Patent number: 5792530Abstract: Food packaging comprises a blend of polyketone and PVC. The blends show good oxygen barrier properties without serious deterioration of moisture barrier performance. Terpolymers of ethylene, propylene and CO are preferred. PVC having a K-value of 50 to 80 are preferred.Type: GrantFiled: August 13, 1996Date of Patent: August 11, 1998Assignee: BP Chemicals LimitedInventors: James Graham Bonner, Anthony Keith Powell
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Patent number: 5780523Abstract: The present invention relates to a pressure sensitive adhesive foam with a percentage of theoretical density less than 90 wherein the foam has an intrinsic adhesion of greater than about 1 N/cm and a compression set under constant deflection of less than about 60%. The present invention further includes a pressure sensitive adhesive foam comprising a thermoplastic block copolymer; a tackifying resin; an isocyanate terminated monomer or oligomer; a polymer comprising a backbone of selected from the group consisting of polybutadiene, polyester and polyether, wherein the polymer contains at least 2 active hydrogens capable of reacting with the isocyanate terminated monomer; and expandable particulate materials. The invention finally further comprises a method of forming the above film.Type: GrantFiled: June 17, 1997Date of Patent: July 14, 1998Assignee: Norton Performance Plastics CorporationInventors: Dominique Petit, Michel Ladang
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Patent number: 5767222Abstract: Disclosed are degradable materials including molded products, laminates, foams, nonwoven materials, adhesives, coatings and films, and particularly packaging films. The materials are made using polydioxaneone polymers comprising at least two different dioxaneone-based repeating units. Preferred polymers are polydioxanediones. First repeating units have less carbon atoms in constituent groups extending from the polymer backbone than second repeating units. Physical characteristics and degradation of the materials can be varied by varying the choice and/or relative proportions of first and second repeating units in the polydioxaneone polymers. Methods for preparing polydioxaneone polymers that can be used in the manufacture of the materials are also discussed, as are suitable monomers and methods for preparing such monomers.Type: GrantFiled: September 29, 1993Date of Patent: June 16, 1998Assignee: Chronopol, Inc.Inventors: Edward S. Lipinsky, Richard G. Sinclair, James D. Browning, Alex Cheung, Kevin H. Schilling, Dan W. Verser
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Patent number: 5760131Abstract: Rigid-rod and segmented rigid-rod polymers, methods for preparing the polymers and useful articles incorporating the polymers are provided. The polymers incorporate rigid-rod backbones with pendant solubilizing groups attached thereto for rendering the polymers soluble.Type: GrantFiled: June 2, 1995Date of Patent: June 2, 1998Assignee: Maxdem IncorporatedInventors: Matthew Louis Marrocco, III, Robert R. Gagne, Mark Steven Trimmer
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Patent number: 5756213Abstract: A curable coating composition is described comprising(A) a compound comprising a plurality of functional crosslinking groups, at least one of which is a carbamate or urea functional group, which compound also includes at least one carbonate group having the structure: ##STR1## and (B) a curing agent comprising a plurality of groups that are reactive with the functional groups on compound (A).Type: GrantFiled: August 15, 1996Date of Patent: May 26, 1998Assignee: BASF CorporationInventors: Walter H. Ohrbom, John W. Rehfuss, John D. McGee, Gregory G. Menovcik, Paul J. Harris
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Patent number: 5750732Abstract: Disclosed is a novel integrated process for production of cyclic esters which includes recovery of starting materials, such as lactic acid from a dilute aqueous lactic acid-containing solution, by solvent extraction. The starting materials are then formed into cyclic esters by removal of water wherein the concentration of higher molecular weight oligomers is maintained below about 20 wt % of the reaction composition. The process further includes providing a recovery solvent for the reaction composition and separating the cyclic esters from the starting materials and higher molecular weight oligomers by liquid-liquid equilibrium separation. The present invention is further directed toward independent novel unit operations of the overall process. The present invention provides for the efficient production and recovery of cyclic esters due to integration of the various unit operations by use of appropriate solvents and recycle streams.Type: GrantFiled: May 19, 1995Date of Patent: May 12, 1998Assignee: Chronopol, Inc.Inventors: Dan W. Verser, Alex Cheung, Timothy J. Eggeman, William A. Evanko, Kevin H. Schilling, Manfred Meiser, Anthony E. Allen, Melville E. D. Hillman, George E. Cremeans, Edward S. Lipinsky
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Patent number: 5714563Abstract: A one-part, low viscosity, moisture curable composition which exhibits excellent shelf stability in the absence of water, but which quickly cures at ambient conditions upon exposure to moisture in the air is a substantially anhydrous mixture containing an acetoacetate functional compound and a polyisocyanate functional compound. The composition can be suitably formulated for use as an ambient temperature, moisture curable adhesive, sealant or coating composition. The acetoacetate functional compounds have a relatively low viscosity as compared with conventional isocyanate functional compounds and thereby reduce or eliminate the need for plasticizers, organic solvents, or both. The cure chemistry of the composition simultaneously consumes and generates moisture at approximately the same rate thereby facilitating rapid cure under even low humidity conditions, and allows for efficient and facile curing of even thick layers of the composition.Type: GrantFiled: January 16, 1996Date of Patent: February 3, 1998Inventors: Michael Frederick DePompei, Ronald John Janoski
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Patent number: 5700885Abstract: An extruder screw having a plurality of plasticating sections sufficient for plasticating polymeric materials of different bulk density.Type: GrantFiled: October 27, 1995Date of Patent: December 23, 1997Assignee: The Dow Chemical CompanyInventors: Hoang T. Pham, Chad A. Strait, Richard O. Kirk
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Patent number: 5698663Abstract: Powder coatings made from a blend of one or more polymers of carbon monoxide and at least one ethylenically unsaturated hydrocarbon (polyketone), and a compatible material are presented. The compatible materials can comprise another polyketone or novolac resins.Type: GrantFiled: September 26, 1995Date of Patent: December 16, 1997Assignee: Shell Oil CompanyInventor: Peter Kinneberg
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Patent number: 5693715Abstract: A copolymer of linseed oil and dicyclopentadiene provides a new polymeric vehicle and formulated coating composition which are low in volatile organic compounds (VOCs), yet provide low viscosities which facilitate application to a substrate with existing equipment.Type: GrantFiled: April 24, 1995Date of Patent: December 2, 1997Assignee: Cargill, IncorporatedInventor: Dharma Rao Kodali
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Patent number: 5674579Abstract: The invention relates to a translucent and flexible polyamide-based composition, which is easy to process, in particular by extrusion, comprising: (A) from 50 weight-% to 95 weight-% 1) of at least one polyamide resin (I), 2) of various additives (IV) such as stabilizers, mould-release agents, lubricants, crystallization accelerators, pigments, organic and/or inorganic fillers or dyes, or antioxidizing agents, 3) optionally of at least one plasticizing agent (V), and (B) from 5 weight-% to 50 weight-%: (a) of at least one ethylene-alkyl (meth)acrylate-unsaturated dicarboxylic acid anhydride terpolymer (II), (b) of at least one ethylene-alkyl (meth)acrylate copolymer (III) with 1/30.ltoreq.(b)/(a).ltoreq.2. In accordance with the present invention, the flexural modulus of the composition, measured according to ISO standard 178, is less than or equal to 2/3 of the flexural modulus of the PA resin (I) alone and is strictly less than 750 MPa.Type: GrantFiled: November 20, 1995Date of Patent: October 7, 1997Assignee: Elf Atochem S.A.Inventors: Beatrice Ladouce, Thibaut Montanari, Alain Bouilloux, Christelle Guibouin, Patrice Perret
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Patent number: 5674972Abstract: This invention relates to polyamide-based formulations flame retarded with synergized brominated flame retardants and having good thermal stability.Type: GrantFiled: July 27, 1995Date of Patent: October 7, 1997Assignee: Albemarle CorporationInventors: Luc Van Wabeeke, Daniel De Schryver
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Patent number: 5665822Abstract: Thermoplastic elastomers (TPEs) containing side chain crystalline (SCC) blocks. The SCC blocks my be hard (A) blocks or the soft (B) blocks (or both) in the TPE. Some of these TPEs are novel, e.g. those in which A blocks are SCC blocks, and the B blocks are polyethers, polyacrylates, polyamides, polyurethanes or polysiloxanes. The SCC-containing TPEs are particularly useful as matrix materials for other components which are dispersed therein, e.g. energetic solids and other thermally responsive materials.Type: GrantFiled: April 14, 1993Date of Patent: September 9, 1997Assignee: Landec CorporationInventors: Steven P. Bitler, Ray F. Stewart, David A. Kamp, Robert G. Freelin, Valentine Y. Yoon
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Patent number: 5665824Abstract: The present invention relates to degradable thermoplastic compositions comprising at least one polycaprolactone property modifier blended with at least one water soluble polymer and/or at least one alkaline soluble polymer. Articles produced with this composition have a long and useful life under dry or aqueous conditions. When such articles are exposed to a hot aqueous alkaline solution, the composition dissolves and is readily disposed.Type: GrantFiled: January 31, 1995Date of Patent: September 9, 1997Assignee: Tredegar Industries, Inc.Inventors: Peter I. Chang, Carl D. Ray
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Patent number: 5648416Abstract: This invention relates to an improved anti-corrosion paint of the type comprising one or more polymeric binders dispersed in a liquid medium, said improvement comprising an anti-corrosion effective amount of one or more non-conductive conjugated polymers.Type: GrantFiled: May 26, 1995Date of Patent: July 15, 1997Assignee: Monsanto CompanyInventors: Granville G. Miller, Lawrence W. Shacklette, Ronald L. Elsenbaumer, Bernhard Wessling, Peter Whang, Vaman G. Kulkarni
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Patent number: 5639825Abstract: When a thermosetting composition comprising(A) a resin having hydroxyl group,(B) a hydrolyzable silyl group-containing polymer,(C) a hydrolyzable silicon compound and(D) a curing catalyst is used, coating materials having no problem as to bad-smelling can be obtained and the coating films formed therefrom are improved in physical properties such as adhesion, solvent resistance and hardness.Type: GrantFiled: October 4, 1994Date of Patent: June 17, 1997Assignee: Kanegafuchi Kagaku Kogyo Kabushiki KaishaInventors: Toshiro Nanbu, Hirotoshi Kawaguchi, Hisao Furukawa, Yasushi Kato
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Patent number: 5635563Abstract: This invention provide a novel cross-linked polyaniline derivative soluble or capable of swelling in general organic solvents, which forms an elastic self-standing film or fibers. The polyaniline derivative substantially comprises a polyaniline having number average molecular weight in a range of from 2,000 to 500,000 represented by the following formula (I) as the main polymer chain, ##STR1## wherein m and n is 0 or an integer of at least 1, m/(m+n)=0-1, and m+n=10-5,000, and cross-linking units represented by the following formula (II) ##STR2## wherein X is a direct bond, a substituted or unsubstituted divalent C.sub.1 -C.sub.30 aliphatic hydrocarbon group, a substituted or unsubstituted divalent aromatic hydrocarbon group, a divalent polysiloxane group or a group derived therefrom, or a divalent group derived from a compound having 2 or more repeating structural unit, Y.sup.1 and Y.sup.Type: GrantFiled: September 30, 1993Date of Patent: June 3, 1997Assignee: Tomoegawa Paper Co., Ltd.Inventor: Osamu Oka
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Patent number: 5623020Abstract: This invention provides a novel cross-linked polyaniline derivative soluble or capable of swelling in general organic solvents, which forms an elastic self-standing film or fibers. The polyaniline derivative substantially comprises a polyaniline having number average molecular weight in a range of from 2,000 to 500,000 represented by the following formula (I) as the main polymer chain, ##STR1## wherein m and n are 0 or an integer of at least 1, m/(m+n)=0-1, and m+n=10-5,000, and cross-linking units represented by the following formula (II) ##STR2## wherein X is a direct bond, a substituted or unsubstituted divalent C.sub.1 -C.sub.30 aliphatic hydrocarbon group, a substituted or unsubstituted divalent aromatic hydrocarbon group, a divalent polysiloxane group or a group derived therefrom, or a divalent group derived from a compound having 2 or more repeating structural units, y.sup.1 and y.sup.Type: GrantFiled: March 26, 1992Date of Patent: April 22, 1997Assignee: Tomoegawa Paper Co., Ltd.Inventor: Osamu Oka
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Patent number: 5621053Abstract: This invention provides a novel cross-linked polyaniline derivative soluble or capable of swelling in general organic solvents, which forms an elastic self-standing film or fibers. The polyaniline derivative substantially comprises a polyaniline having number average molecular weight in a range of from 2,000 to 500,000 represented by the following formula (I) as the main polymer chain, ##STR1## wherein m and n are 0 or an integer of at least 1, m/(m+n)=0-1, and m+n=10-5,000, and cross-linking units represented by the following formula (II) ##STR2## wherein X is a direct bond, a substituted or unsubstituted divalent C.sub.1 -C.sub.30 aliphatic hydrocarbon group, a substituted or unsubstituted divalent aromatic hydrocarbon group, a divalent polysiloxane group or a group derived therefrom, or a divalent group derived from a compound having 2 or more repeating structural units, Y.sup.1 and Y.sup.Type: GrantFiled: May 10, 1995Date of Patent: April 15, 1997Assignee: Tomoegawa Paper Co., Ltd.Inventor: Osamu Oka
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Patent number: 5610234Abstract: Polar thermoplastic polyolefin blends are provided which are flexible and are particularly useful in replacing polyvinyl-chloride sheeting used as liners, folders, etc. The blends comprise, in general, a non-polar thermoplastic polyolefin, a polar ethylene copolymer, and an acid grafted olefin polymer as a compatibilizing agent, all of which are chlorine-free.Type: GrantFiled: March 21, 1995Date of Patent: March 11, 1997Assignee: E. I. Du Pont de Nemours and CompanyInventor: Heinz H. Spelthann
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Patent number: 5610236Abstract: A polymer blend composition comprises a polyketone and PVC provided that the polyketone is not a propylene/CO copolymer having a molecular weight of less than 10,000. The softening point of PVC can be increased by blending with polyketones. Blends of polyketones and unplasticised PVC are particularly preferred.Type: GrantFiled: February 23, 1995Date of Patent: March 11, 1997Assignee: BP Chemicals LimitedInventor: James G. Bonner
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Patent number: 5607995Abstract: The present invention relates to a paint composition which comprises a binder to impart film forming properties compounded with quasi transparent polyolefin filler particles having a particle size below 110 micrometers, said polyolefin being selected from the group consisting of a polyethylene, a polypropylene, copolymers of ethylene and propylene and mixtures thereoof, said polyolefin filler particles being present in an amount between 0.1% to 10% by weight of the composition. These paint compositions were found to possess low gloss and matte properties at visible and high reflectance in the thermal infra-red wavelengths.Type: GrantFiled: January 4, 1996Date of Patent: March 4, 1997Assignee: State of Israel- Ministry of DefenceInventor: Shulamit Wassermann
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Patent number: 5605966Abstract: Microcapsules comprise a polymeric wall material and a polymeric core material which is suitable as a leveling agent for film formation by film-forming oligomers and polymers.Type: GrantFiled: December 13, 1993Date of Patent: February 25, 1997Assignee: BASF AktiensellschaftInventors: Bernhard Schuler, Georg Bobar, Tilmann Korth, Ottokar Flocken, Peter Gleich
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Patent number: 5596027Abstract: The present invention provides jet ink compositions that produce on glass, metal, plastic, and rubber surfaces messages having high visual intensity, and condensation and water resistance. The inventive compositions comprise a polyamine, a colorant, and an acidic resin. The present invention further provides jet ink compositions further comprising water as the ink carrier. The colorant used in the ink composition of the present invention includes a dye, a pigment, or a polymeric hollow microsphere. The polyamine used in the ink composition of the present invention includes a dendrimer. The ink composition of the present invention may additionally include pH adjusting agents, humectants, biocides, defoamers. The present invention further provides an improved process of jet printing on glass, metal, plastic, and rubber surfaces messages having improved condensation and water resistance, and improved visual intensity, the improvement comprising using the ink composition of the present invention.Type: GrantFiled: July 13, 1995Date of Patent: January 21, 1997Assignee: Videojet Systems International, Inc.Inventors: Sharon B. Mead, Susan J. Brennan, Arsenia Morelos, Josephine Aguilar
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Patent number: 5593701Abstract: Hydrocarbon polymers with grafts of polyethers, polylactones, or polyesters from the reaction of phosgene with glycols having from 1 to 4 carbon atoms are disclosed as having good release properties or low adhesion to hydrocarbon rubber materials. The hydrocarbon backbone polymers include EPDM, hydrogenated polybutadiene, and hydrogenated poly(styrene-butadiene) all said polymers having pendant succinic anhydride groups or brominated p-methylstyrene-isobutylene copolymers. The above-referenced graft copolymers along with butadiene-acrylonitrile rubber or epichlorohydrin polymers or copolymers are described as useful polymers to make self-release curing bladders or sleeves for use in making molded articles such as pneumatic tires.Type: GrantFiled: March 28, 1996Date of Patent: January 14, 1997Assignee: Bridgestone CorporationInventors: Daniel F. Graves, William L. Hergenrother
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Patent number: 5587429Abstract: A processing aid system composition containing fluoropolymer processing aid, polar-side-group-containing extrusion adjuvant, and poly(oxyalkylene) polymer enhances extrusion of polyolefins.Type: GrantFiled: April 4, 1995Date of Patent: December 24, 1996Assignee: E. I. DuPont de Nemours and CompanyInventor: Donnan E. Priester
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Patent number: 5585439Abstract: An unsaturated polyester resin and low profile additive containing diketo groups.Type: GrantFiled: March 29, 1996Date of Patent: December 17, 1996Assignee: Ohio State UniversityInventors: L. James Lee, Reiko Saito, Debbie Y. Chiu
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Patent number: 5580932Abstract: A light scattering light guide, which is capable of converting a light flux of a relatively small cross-sectional area into a light flux of a relatively large area with high efficiency and uniformity, manufacturing method thereof, and applied optical apparatuses such as backlight light source apparatuses and light branching/mixing devices which make effective use of the characteristics of said light scattering light guide. Such light scattering light guide is obtained by utilizing various structures with irregular refraction indexes generated in the process of polymerization of organic materials.Type: GrantFiled: March 18, 1994Date of Patent: December 3, 1996Inventor: Yasuhiro Koike