Solid Polymer Derived From Ethylene Or Propylene Patents (Class 525/240)
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Patent number: 11505725Abstract: The present invention provides an adhesive composition including an ethylene/alpha-olefin copolymer; and a tackifier, wherein the ethylene/alpha-olefin copolymer has narrow molecular weight distribution together with a low density and an ultra low molecular weight, minimized number of unsaturated functional groups, uniform crystallinity, thereby showing excellent physical properties.Type: GrantFiled: May 3, 2019Date of Patent: November 22, 2022Inventors: Rae Keun Gwak, Eun Jung Lee, Jin Sam Gong, Jung Ho Jun, Tae Su Kim
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Patent number: 11499027Abstract: The present invention can provide a fiber-reinforced expanded particle molded article having a reinforcing material fused and integrated with the surface of an expanded molded article, wherein the reinforcing material is a fabric or a braided product produced by weaving a linear composite material produced by melting and integrating a thermoplastic fiber comprising a low-melting component fiber and a high-melting component fiber, as two or more threads selected from the group consisting of a warp, a weft and a slant thread, the fiber-reinforced expanded particle molded article exhibiting an excellent reinforcing effect; and a method for economically producing the molded article by in-mold molding with a small number of steps.Type: GrantFiled: February 27, 2018Date of Patent: November 15, 2022Assignee: UBE EXSYMO CO., LTD.Inventor: Masahiko Yokokita
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Patent number: 11492430Abstract: Catalyst compositions containing a metallocene compound, a solid activator, and a co-catalyst, in which the solid activator or the supported metallocene catalyst has a d50 average particle size of 15 to 50 ?m and a particle size distribution of 0.5 to 1.5, can be contacted with an olefin in a loop slurry reactor to produce an olefin polymer. A representative ethylene-based polymer produced using the catalyst composition has excellent dart impact strength and low gels, and can be characterized by a HLMI from 4 to 10 g/10 min, a density from 0.944 to 0.955 g/cm3, a higher molecular weight component with a Mn from 280,000 to 440,000 g/mol, and a lower molecular weight component with a Mw from 30,000 to 45,000 g/mol and a ratio of Mz/Mw ranging from 2.3 to 3.4.Type: GrantFiled: February 3, 2022Date of Patent: November 8, 2022Assignee: Chevron Phillips Chemical Company LPInventors: Max P. McDaniel, Carlton E. Ash, Kathy S. Clear, Eric D. Schwerdtfeger, Carlos A. Cruz, Jeremy M. Praetorius
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Patent number: 11485842Abstract: A composition that includes: (a) from 65 to 85% by weight of polypropylene homopolymer in powder form, the average particle size of which is micrometric, (b) from 14 to 30% by weight, preferably 14 to 25% by weight, of natural fibers less than or equal to 2 mm in length, and (c) from 1 to 3% by weight of compatibilizer, its uses for the preparation of a composite material by extrusion, wherein this composite material is useful for preparing a part by injection, in particular a vehicle part whose rigidity is improved.Type: GrantFiled: June 21, 2019Date of Patent: November 1, 2022Assignee: FAURECIA INTERIEUR INDUSTRIEInventors: Jean-Michel Monzo, Hassane Boudhani, Laurence Dufrancatel
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Patent number: 11472951Abstract: Provided is a heterophasic propylene polymer material having excellent low temperature impact resistance, tensile strength, and tensile elongation. A heterophasic propylene polymer material contains a propylene homopolymer component (A), and an ethylene-propylene copolymer component (B1) and an ethylene-propylene copolymer component (B2) having different formulations from each other, wherein a content of the propylene homopolymer component (A), a content of the ethylene-propylene copolymer component (B1), and a content of the ethylene-propylene copolymer component (B2) are 40 to 70 parts by mass, 15 to 54 parts by mass, and 6 to 15 parts by mass, respectively, with respect to 100 parts by mass of a total content of the propylene homopolymer component (A) and the ethylene-propylene copolymer components (B1) and (B2).Type: GrantFiled: December 21, 2020Date of Patent: October 18, 2022Assignee: SUMITOMO CHEMICAL COMPANY, LIMITEDInventors: Shun Takahashi, Masahiro Yanagisawa
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Patent number: 11459454Abstract: A polypropylene composition made from or containing a polymer made from or containing: (i) component (1) made from or containing a propylene homopolymer having MFR of 100 to 300 (at a temperature of 230° C. under a load of 2.16 k(g) and containing more than 97.5% by weight of xylene insolubles (XI), wherein XI has a Mw/Mn of 4 to 10; (ii) component (2) made from or containing an ethylene/propylene copolymer containing 15 to 50% by weight of an ethylene-derived unit; wherein 1) relative proportions of component (1) and component (2) are, respectively, not less than 50 parts by weight but less than 70 pbw and more than 30 pbw but not more than 50 pbw, 2) intrinsic viscosity of xylene solubles (XSIV) of the polymer is in the range of 1.5 to 4.0 dl/g, 3) MFR of the polymer is in the range of 20 to 100 g/10 min.Type: GrantFiled: April 25, 2019Date of Patent: October 4, 2022Assignee: Basell Poliolefine Italia S.r.l.Inventors: Yutaka Yokoyama, Akihiro Kamimura, Hiroshi Kajioka
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Patent number: 11459450Abstract: A resin composition for injection forming containing a high-density polyethylene, an ethylene-vinyl alcohol copolymer and an acid-modified linear low-density polyethylene, characterized in that the ethylene-vinyl alcohol copolymer is contained in an amount of 35 to 90 parts by mass and the acid-modified linear low-density polyethylene is contained in an amount of 10 to 35 parts by mass per 100 parts by mass of the high-density polyethylene.Type: GrantFiled: May 22, 2019Date of Patent: October 4, 2022Assignee: NIPPON CLOSURES CO., LTD.Inventors: Daisuke Tsuchimoto, Go Oota, Katsumi Hashimoto
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Patent number: 11459408Abstract: Methods for scale-up from a pilot plant to full production of a bimodal polymer product having a density, melt index, and a melt index ratio are provided herein. The methods provide for adjusting reactor conditions and catalyst ratio of a bimodal catalyst system to optimize the transition from single catalyst to bimodal polymer compositions on a full-scale process plant consistent with pilot plant development.Type: GrantFiled: May 1, 2019Date of Patent: October 4, 2022Assignee: ExxonMobil Chemical Patents Inc.Inventors: Bruce J. Savatsky, Ryan W. Impelman, David F. Sanders
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Patent number: 11447587Abstract: Methods for scale-up from a pilot plant to a larger production facility of a bimodal polymer product having a density, a melt index and melt index ratio are provided herein.Type: GrantFiled: May 1, 2019Date of Patent: September 20, 2022Assignee: ExxonMobil Chemical Patents Inc.Inventors: Bruce J. Savatsky, Ryan W. Impelman, David F. Sanders
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Patent number: 11427703Abstract: Disclosed are ethylene polymer compositions containing a homogeneously-branched first ethylene polymer component and 15-35 wt. % of a homogeneously-branched second ethylene polymer component of higher density than the first ethylene polymer component. The ethylene polymer composition can be characterized by a density from 0.912 to 0.925 g/cm3, a ratio of Mw/Mn from 2 to 5, a melt index less than 2 g/10 min, and a CY-a parameter at 190° C. from 0.35 to 0.7. These polymer compositions have the excellent dart impact strength and optical properties of a metallocene-catalyzed LLDPE, but with improved machine direction tear resistance, and can be used in blown film and other end-use applications. Further, methods for improving film Elmendorf tear strength also are described.Type: GrantFiled: March 25, 2019Date of Patent: August 30, 2022Assignee: Chevran Phillips Chemical Company LPInventors: Jeremy M. Praetorius, Chung Ching Tso, Ashish M. Sukhadia, Yongwoo Inn, Qing Yang, John T. Blagg
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Patent number: 11421101Abstract: An aqueous resin dispersion with which excellent adhesiveness to a polyolefin base material such as a polypropylene base material can be easily obtained, which can be baked at low temperature, and which is for producing an aqueous coating material; and an aqueous coating material and an adhesive which contain the aqueous resin dispersion, are provided. In an aqueous resin dispersion (C) of the present invention, an olefin polymer (A) and a polymer (B) containing a constitutional unit derived from a radically polymerizable monomer (b1) having a reactive functional group are dispersed in an aqueous medium, a median diameter of the aqueous resin dispersion (C) measured by a dynamic light scattering method is 300 nm or less, and a dry product of the aqueous resin dispersion (C) contains 1 mass % or more of an insoluble component (D) that is insoluble in tetrahydrofuran.Type: GrantFiled: June 1, 2020Date of Patent: August 23, 2022Assignee: Mitsubishi Chemical CorporationInventors: Akira Harada, Shinsuke Haraguchi, Motomi Tanaka, Jun Itou
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Patent number: 11401406Abstract: The present disclosure relates to a polyethylene resin composition exhibiting excellent processability and bubble stability, which can provide a film or fiber having excellent physical properties through various processes. The polyethylene resin composition includes a first polyethylene resin having a density of 0.950 g/cm3 to 0.960 g/cm3, a weight average molecular weight of 80000 g/mol to 100000 g/mol and a molecular weight distribution of 3.3 to 4.0; and a second polyethylene resin having a density of 0.950 g/cm3 to 0.960 g/cm3, a weight average molecular weight of 500000 g/mol to 600000 g/mol and a molecular weight distribution of 1.3 to 2.0.Type: GrantFiled: February 18, 2020Date of Patent: August 2, 2022Inventors: Jisoo Song, Chang Hwan Jang, Hyojoon Lee, Yi Young Choi, Sun Mi Kim
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Patent number: 11390700Abstract: The present invention deals with a new unimodal propylene-ethylene random copolymer providing improved resistance against gamma irradiation as well as compositions comprising the new unimodal propylene-ethylene random copolymer and final articles made therefrom.Type: GrantFiled: May 16, 2018Date of Patent: July 19, 2022Assignee: BOREALIS AGInventors: Jingbo Wang, Markus Gahleitner, Andreas Albrecht, Satu Rintakari, Friedrich Berger, Martina Sandholzer
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Patent number: 11376829Abstract: A multilayer film made from or containing a core layer made from or containing a polypropylene composition made from or containing: A) from 90 wt % to 50 wt %; of a propylene homopolymer; and B) from 10 wt % to 50 wt %; of a propylene ethylene copolymer having: i) xylene soluble fraction at 25° C. ranging from 14 wt % to 27 wt %; ii) intrinsic viscosity of the fraction soluble in xylene at 25° C. ranging from 1.0 to 2.4 dl/g; iii) melt flow rate ranging from 1.0 g/10 min to 4.0 g/10 min; iv) an ethylene content ranging from 5.0 wt % to 12.0 wt %; v) the ethylene derived units content on the fraction insoluble in xylene at 25° C. ranging from 2.5 wt % to 6.0 wt %; vi) the ethylene derived units content on the fraction soluble in xylene at 25° C. ranging from 15.2. wt % to 30.2 wt %, the sum of A) and B) being 100 wt %.Type: GrantFiled: February 13, 2019Date of Patent: July 5, 2022Assignee: Basell Poliolefine Italia S.r.l.Inventors: Paola Massari, Andrea Felisati, Marco Izzi, Claudio Cavalieri, Davide Tartari, Isabella Maria Vittoria Camurati, Tiziana Caputo
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Patent number: 11345802Abstract: The present disclosure provides a composition comprising: (A) a polypropylene polymer; (B) a polyolefin elastomer; (C) a polymer comprising an acetoacetyl functional group; and (D) a compatibilizer component. The present disclosure also provides an article made from the composition.Type: GrantFiled: May 22, 2018Date of Patent: May 31, 2022Assignee: Dow Global Technologies LLCInventors: Yahong Zhang, Tao Wang, Jian Zou
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Patent number: 11332601Abstract: Disclosed are ethylene polymer compositions containing a homogeneously-branched first ethylene polymer component and 15-35 wt. % of a homogeneously-branched second ethylene polymer component of higher density than the first ethylene polymer component. The ethylene polymer composition can be characterized by a density from 0.912 to 0.925 g/cm3, a ratio of Mw/Mn from 2 to 5, a melt index less than 2 g/10 min, and a CY-a parameter at 190° C. from 0.35 to 0.7. These polymer compositions have the excellent dart impact strength and optical properties of a metallocene-catalyzed LLDPE, but with improved machine direction tear resistance, and can be used in blown film and other end-use applications. Further, methods for improving film Elmendorf tear strength also are described.Type: GrantFiled: April 2, 2020Date of Patent: May 17, 2022Assignee: Chevron Phillips Chemical Company LPInventors: Jeremy M. Praetorius, Chung Ching Tso, Ashish M. Sukhadia, Yongwoo Inn, Qing Yang, John T. Blagg
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Patent number: 11305034Abstract: Provided is a stretchable film having excellent stretchability and excellent air permeability. Also provided is an article including such stretchable film. The stretchable film of the present invention includes an olefin-based resin and a filler.Type: GrantFiled: April 12, 2016Date of Patent: April 19, 2022Assignee: NITTO DENKO CORPORATIONInventors: Kohei Takeda, Shou Uchida, Muneshige Nakagawa, Shinsuke Ikishima, Yasuhiro Takeda, Yoshitake Shigematsu
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Patent number: 11306198Abstract: A polypropylene composition made from or containing (i) component (1) made from or containing a propylene/ethylene copolymer containing 2 to 4% by weight of an ethylene-derived unit, based upon the total weight of the propylene/ethylene copolymer; and (ii) component (2) made from or containing an ethylene/propylene copolymer containing 65 to 87% by weight of an ethylene-derived unit, based upon the total weight of the ethylene/propylene copolymer; wherein the polypropylene composition has 1) a weight ratio of component (1) to component (2) in the range of 65:35 to 77:23, 2) an intrinsic viscosity of xylene solubles (XSIV) in the range of 0.8 to 1.4 dl/g, 3) a MFR (at 230° C. under a load of 2.16 kg) in the range of 15 to 40 g/10 min., and 4) the absence of a crystal nucleating agent.Type: GrantFiled: March 15, 2019Date of Patent: April 19, 2022Assignee: Basell Poliolefine Italia S.r.l.Inventors: Takeshi Tsukahara, Nobuyuki Tsurumi, Shitoshi Kanno, Kunio Yamamoto, Takeshi Nakajima
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Patent number: 11299609Abstract: A polyethylene blend comprising a uniform dispersion of constituents (A) and (B): (A) a Ziegler-Natta catalyst-made linear low density polyethylene and (B) a metallocene catalyst-made linear low density polyethylene, a composition comprising the polyethylene blend and at least one additive, methods of making and using same, and manufactured articles and films comprising or made from same.Type: GrantFiled: May 29, 2018Date of Patent: April 12, 2022Assignee: Univation Technologies, LLCInventors: Swapnil B. Chandak, Nitin Borse
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Patent number: 11286379Abstract: Rotomolded articles, especially flexible rotomolded articles are made from an ethylene interpolymer product having a melt index, I2 of from 2.5 to 8.0 g/10 min, a density of from 0.905 to 0.920 g/cm3; and a Dilution Index, Yd, greater than 0. The ethylene interpolymer product comprises: (I) a first ethylene interpolymer; (II) a second ethylene interpolymer, and; (III) optionally a third ethylene interpolymer.Type: GrantFiled: October 8, 2019Date of Patent: March 29, 2022Assignee: NOVA Chemicals (International) S.A.Inventors: Celine Bellehumeur, Maryam Fereydoon, Amy Phinney
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Patent number: 11230641Abstract: Disclosed herein is a film comprising a polymer blend, the polymer blend comprising a first polyolefin elastomer having a weight average molecular weight of 120,000 to 350,000 grams per mole; and a second polyolefin elastomer having a weight average molecular weight of 15,000 to 75,000 grams per mole; wherein the overall melt index of the polymer blend is less than 8 g/10 minutes when measured as per ASTM D1238 at 2.16 kilograms at 190° C. Disclosed herein too is a method of manufacturing a film comprising blending a first polyolefin elastomer having a weight average molecular weight of 120,000 to 350,000 grams per mole; and a second polyolefin elastomer having a weight average molecular weight of 15,000 to 75,000 grams per mole to form a polymer blend; wherein the overall melt index of the polymer blend is less than 8 g/10 minutes when measured as per ASTM D1238 at 2.16 kilograms at 190° C.; and forming the polymer blend into a film.Type: GrantFiled: July 21, 2016Date of Patent: January 25, 2022Assignee: DOW GLOBAL TECHNOLOGIES LLCInventors: Jacquelyn A. Degroot, Thor E. Gardarsson, Lisa S. Madenjian
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Patent number: 11214669Abstract: The present invention provides polyolefin resin composition exhibiting excellent long term durability as well as improved properties, and an article prepared using the same.Type: GrantFiled: March 20, 2019Date of Patent: January 4, 2022Inventors: Daehwan Kim, Yi Young Choi, Hyunsup Lee, Soon Ho Sun, Jong Young Bae
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Patent number: 11208245Abstract: A packaging is provided including: a base layer including at least one layer of a biaxially oriented resin film; and a sealant layer including at least a first thermoplastic resin layer and a second thermoplastic resin layer, in which the base layer, the first thermoplastic resin laser, and the second thermoplastic resin layer are laminated in this order, a density of a first resin forming the first thermoplastic resin layer is higher than a density of a second resin forming the second thermoplastic resin layer, the density of the first resin is 0.90 g/cm3 or higher, the density of the second resin is 0.92 g/cm3 or lower, and the second thermoplastic resin layer contains 200 to 2000 ppm of a lubricant including at least one of a fatly acid amide lubricant and a fatty acid ester lubricant.Type: GrantFiled: May 28, 2019Date of Patent: December 28, 2021Assignee: TOPPAN PRINTING CO., LTD.Inventors: Shigeki Kudo, Nobuhiko Imai, Minoru Kawasaki, Osamu Takemoto
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Patent number: 11203683Abstract: The present invention relates to a polyolefin composition, the use of the polyolefin composition in a compound with one or more virgin polymers for automotive articles or applications, pipes or profiles for construction applications, the use of a heterophasic polypropylene (HECO) as compatibilizer for polyolefin blends A) between a copolymer of ethylene and one or more C4 to C19 alpha olefin B) and a reinforcing mineral filler D) as well as a process for producing the polyolefin composition.Type: GrantFiled: May 2, 2018Date of Patent: December 21, 2021Assignee: BOREALIS AGInventors: Susanne Kahlen, Markus Gahleitner, Cornelia Tranninger, Bhawna Kulshreshtha
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Patent number: 11180586Abstract: The present invention deals with a process for producing a multimodal ethylene polymer composition suitable for producing films by blow moulding and comprising the steps of (i) homopolymerising ethylene or copolymerising ethylene and an alpha-olefin comonomer in a first polymerisation step in the presence of a silica supported Ziegler-Natta catalyst to produce a first ethylene homo- or copolymer (PEI) having a density of from 940 to 980 kg/m3 and a melt flow rate MFR2 of from 2 to 1000 g/10 min, provided that if the first ethylene homo- or copolymer (PE1) is a copolymer, MFR2 thereof is in the range of 2 to 100 g/10 min; (ii) homopolymerising ethylene or copolymerising ethylene and an alpha-olefin comonomer in a second polymerisation step in the presence of the first ethylene homo- or copolymer to produce a first ethylene polymer mixture (PEM1) comprising the first ethylene homo- or copolymer and a second ethylene homo- or copolymer (PE2), said first ethylene polymer mixture having a density of from 940 to 98Type: GrantFiled: November 16, 2017Date of Patent: November 23, 2021Assignee: Borealis AGInventors: Jari Äärilä, Auli Nummila-Pakarinen, Jarmo Kela, Anh Tuan Tran
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Patent number: 11174379Abstract: A polyolefin composition made from or containing: T1) 70-95 wt %, of a polyolefin component containing: a1) from 30 wt % to 70 wt % of a propylene based polymer; and a2) from 30 wt % to 70 wt % of an ethylene based polymer; and T2) 5-30 wt % of a polyolefin component containing: A) 5-35% by weight of a propylene homopolymer or a propylene ethylene copolymer; B) 25-50% by weight of a copolymer of ethylene and a C3-C8 alpha-olefin containing 0.1-20% by weight of C3-C8 alpha-olefin units; and C) 30-60% by weight of a copolymer of ethylene and propylene containing 25-75% by weight of ethylene units.Type: GrantFiled: November 5, 2018Date of Patent: November 16, 2021Assignee: Basell Poliolefine Italia S.r.l.Inventors: Roberto De Palo, Claudio Cavalieri
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Patent number: 11174356Abstract: A polymer composition of polypropylene copolymer and 1 to 50% by weight of hard resin. The polypropylene copolymer is either an impact copolymer or a random copolymer. The polymer composition can be used to make injection stretch blow molded articles having improved top load strength.Type: GrantFiled: October 27, 2016Date of Patent: November 16, 2021Assignee: FINA TECHNOLOGY, INC.Inventors: Luyi Sun, Tim Coffy, Leland Daniels
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Patent number: 11149102Abstract: A film including a resin component is provided. The resin density is 900 kg/m3 or more and 930 kg/m3 or less. The load length ratio (Tp(50)) at cutting level 50% of the surface roughness curve of at least one film surface is 0.01% or more and 29.0% or less.Type: GrantFiled: March 7, 2018Date of Patent: October 19, 2021Assignee: SUMITOMO CHEMICAL COMPANY, LIMITEDInventors: Naoko Ochi, Tomokazu Yasunaga
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Patent number: 11142600Abstract: An ethylene/1-hexene copolymer has a density from 0.9541 to 0.9600 gram per cubic centimeter (g/cm3), a molecular mass dispersity (DM=Mw/Mn) from greater than 2.0 to 3.5; and a Z-average molecular weight (Mz) from 120,000 to 240,000 grams per mole (g/mol). Methods of making and using same. Articles containing same.Type: GrantFiled: March 11, 2019Date of Patent: October 12, 2021Assignee: Univation Technologies, LLCInventors: Swapnil B. Chandak, Peter S. Martin, Yi Zhang
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Patent number: 11123953Abstract: Embodiments disclosed herein include multilayer films having a cling layer and a release layer, wherein the cling layer comprises (i) an ethylene/alpha-olefin elastomer, and (ii) a polyethylene polymer selected from ultra-low density polyethylene, a very low density polyethylene, or combinations thereof, and the release layer comprises a low density polyethylene (LDPE) having a density of from 0.915 to 0.930 g/cc, a melt index, I2, of from 1.0 to 30.0 g/10 min, and a molecular weight distribution, (Mw/Mn), as measured by the conventional calibration of triple detector gel permeation chromatography, of from 3.0 to less than 7.0.Type: GrantFiled: August 10, 2016Date of Patent: September 21, 2021Assignee: Dow Global Technologies LLCInventors: Jong Young Lee, Teresa P. Karjala
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Patent number: 11111367Abstract: A resin molded body includes: a polyolefin element formed of polyolefin, including a crystalline region and an amorphous region; and a hydrophilic copolymer contained in at least part of a surface of the polyolefin element, the hydrophilic copolymer including a copolymer of 2-methacryloyloxyethyl phosphorylcholine (MPC) of 45% or greater on a mole fraction basis and at least one other monomer. In the resin molded body, the MPC polymer is immersed through the surface by applying heat treatment.Type: GrantFiled: March 20, 2018Date of Patent: September 7, 2021Assignees: KYOCERA CORPORATION, THE UNIVERSITY OF TOKYOInventors: Masayuki Kyomoto, Kazuhiko Ishihara
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Patent number: 11097305Abstract: The present invention relates to the use of a at least a part of a polymer layer comprising a composition (Co), the composition comprising a low density polyethylene (LDPE) produced in a tubular reactor which composition is free of additives as a thermoplastic surface of an extrusion coated structure comprising the polymer layer and a first substrate for preparing heat-sealed articles by heat-sealing of said thermoplastic surface with a second substrate; and The use of a at least a part of a polymer layer comprising a composition (Co), the composition comprising a low density polyethylene (LDPE) having a melt flow rate (MFR) according to ISO 1133 (190° C., 2.16 kg) higher than 3.Type: GrantFiled: December 17, 2014Date of Patent: August 24, 2021Assignee: BOREALIS AGInventors: Auli Nummila-Pakarinen, Mikko Peltovuori, Mattias Bergqvist
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Patent number: 11098137Abstract: The present invention relates to a continuous vapor phase olefin polymerization process comprising polymerization of at least one olefin monomer in at least two serial polymerization reactors containing an agitated bed of forming polymer particles, wherein forming polymer particles are transferred from an upstream reactor to a downstream reactor, wherein the upstream reactor is a horizontal stirred reactor containing multiple reaction zones, each reaction zone having at least one inlet for a gaseous stream and optionally additionally an inlet for a liquid stream, wherein said process reduces the carry over of undesired reactive gases from the upstream reactor to the downstream reactor. The present invention further relates to a system suitable for the present continuous vapor phase olefin polymerization process. The present invention further relates to the use of the present process and system for producing heterophasic polypropylene.Type: GrantFiled: December 5, 2017Date of Patent: August 24, 2021Assignee: SABIC GLOBAL TECHNOLOGIES B.V.Inventors: Arjen Van Miltenburg, Rita Ferreira Tavares
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Patent number: 11078353Abstract: The present disclosure provides a composition comprising: (A) a polypropylene polymer; (B) a polyolefin elastomer; (C) a polyacetoacetate compound having the Formula (I); and (D) an additive component. The present disclosure also provides an article made from the composition.Type: GrantFiled: May 22, 2018Date of Patent: August 3, 2021Assignee: Dow Global Technologies LLCInventors: Yahong Zhang, Jian Zou, Shaoguang Feng
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Patent number: 11066492Abstract: A process for producing ethylene polymer including compressing ethylene monomer in one or more compressors to a pressure from 1000 bar to 3000 bar; introducing the compressed ethylene monomer into one or more reactors; introducing a blend comprising an initiator and a modifier into the reactor where the ethylene monomer polymerizes forming a reaction mixture comprising unreacted ethylene monomer and ethylene polymer; and separating the ethylene polymer from the reaction mixture.Type: GrantFiled: June 25, 2015Date of Patent: July 20, 2021Assignee: ExxonMobil Chemical Patents Inc.Inventor: Paul J. Clymans
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Patent number: 11067204Abstract: Polymer compositions comprising at least two polyethylene polymers, for example, recycled polymer compositions, methods for the production thereof, the use of functional fillers in said compositions, and articles formed from the polymer compositions. Pipe having at least one wall, the pipe having a nominal inside diameter of at least about 400 mm and a SN of at least about 4, and wherein the at least one wall comprises at least about 25% by weight of recycled polymer, based on the total weight of the at least one wall.Type: GrantFiled: September 9, 2015Date of Patent: July 20, 2021Assignee: ImerTech SASInventors: Jean-Benoit Papillon, John Slater, Fatima Rebih
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Patent number: 11059921Abstract: Disclosed herein are ethylene-based polymers generally characterized by a Mw ranging from 70,000 to 200,000 g/mol, a ratio of Mz/Mw ranging from 1.8 to 20, an IB parameter ranging from 0.92 to 1.05, and an ATREF profile characterized by one large peak. These polymers have the dart impact, tear strength, and optical properties of a metallocene-catalyzed LLDPE, but with improved processability, melt strength, and bubble stability, and can be used in blown film and other end-use applications.Type: GrantFiled: August 20, 2019Date of Patent: July 13, 2021Assignee: Chevron Phillips Chemical Company LPInventors: Mark L. Hlavinka, Chung Ching Tso, Yongwoo Inn, Deloris R. Gagan, Randy S. Muninger
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Patent number: 11053380Abstract: The present invention is directed to a heterophasic polypropylene composition (HECO1) and the use thereof to reduce the amount of flow marks of an injection moulded polyolefin composition. Further, the present invention is directed to a polyolefin composition (C) comprising a polyolefin (PO), said heterophasic polypropylene composition (HECO1) and optionally a filler as well as an article comprising said polyolefin composition (C).Type: GrantFiled: June 26, 2018Date of Patent: July 6, 2021Assignee: BOREALIS AGInventors: Pavel Shutov, Susanne Kahlen, Daniela Mileva, Renate Eckmayr, Claudia Kniesel
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Patent number: 11056710Abstract: An electrode assembly and a rechargeable battery including the same are provided. An electrode assembly for a rechargeable battery includes: a first electrode including a first coating part and a first uncoated region at at least one side of the first coating part; a second electrode including a second coating part and a second uncoated region at at least one side of the second coating part; a separator between the first electrode and the second electrode; and at least one of a first stress buffering part on at least a partial region of the first uncoated region and a second stress buffering part on at least a partial region of the second uncoated region, the at least one of the first stress buffering part and the second stress buffering part being configured as a film including an ethylene propylene copolymer, a hydrogenated hydrocarbon polymer, and polyethylene.Type: GrantFiled: December 6, 2018Date of Patent: July 6, 2021Assignee: Samsung SDI Co., Ltd.Inventors: Sol Choi, Hyeri Eom, Seungjae Lee, Da-Un Han
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Patent number: 11028196Abstract: A composition comprising vinyl-terminated polyethylene having an Mn from about 200 g/mol to about 10,000 g/mol; and a comb polyolefin having polyethylene arms attached to a random copolymer backbone, said backbone including units derived from an alpha-olefin having 3 or more carbon atoms, where the polyethylene arms have an Mn from about 200 g/mol to about 10,000 g/mol, and where the comb polyolefin has an Mp from about 7,500 to about 400,000 g/mol.Type: GrantFiled: November 16, 2018Date of Patent: June 8, 2021Assignee: ExxonMobil Chemical Patents Inc.Inventors: Andy H. Tsou, Narayanaswami Dharmarajan, Crisita Carmen H. Atienza, Jian Yang
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Patent number: 11028259Abstract: A multilayer film made from or containing a skin layer made from or containing a polyolefin composition made from or containing: A) from 19 wt % to 50 wt % of a propylene ethylene copolymer having an ethylene derived units content ranging from 1.5 wt % to 6.0 wt % and B) from 50 wt % to 81 wt % of a propylene ethylene 1-butene terpolymer having an ethylene derived units content ranging from 1.5 wt % to 6.0 wt % and 1-butene derived units content of between 4.8 wt % to 12.4 wt %; the sum of the amount of component A) and B) being 100; the composition being characterized by the following features: molecular weight distribution (MWD), expressed in terms of Mw/Mn, greater than 4.0; the creep and recovery curve measured on the polymer fuse at 200° C. shows a maximum value between 600 and 1200 seconds, lower than 53×10?5 1/Pa.Type: GrantFiled: July 19, 2016Date of Patent: June 8, 2021Assignee: Basell Poliolefine Italia S.r.l.Inventors: Paola Massari, Caroline Cathelin, Claudio Cavalieri, Marco Ciarafoni, Andrea Felisati, Angelo Ferraro, Giampiero Morini, Fabrizio Piemontesi, Gianni Vitale
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Patent number: 11008439Abstract: The present invention relates to a three-dimensional solid polymeric article having surface effects comprising a polymer composition and 0.1 to 20% by weight of a hydrophobic compound, based on the total weight of the solid polymeric article, where the hydrophobic compound is intermixed throughout the polymer composition and throughout three-dimensional solid polymeric article; and where the hydrophobic compound is selected from a cyclic alcohol which is substituted with at least two hydrophobic groups.Type: GrantFiled: September 30, 2016Date of Patent: May 18, 2021Assignee: THE CHEMOURS COMPANY FC, LLCInventors: Gerald Oronde Brown, John Christopher Sworen
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Patent number: 10995158Abstract: The invention relates to a process for the preparation of a heterophasic propylene copolymer consisting of a propylene-based matrix and a dispersed ethylene-a-olefin copolymer, comprising the steps of a) preparing the propylene-based matrix from propylene and optionally a C2 or C4-C12 ?-olefin by contacting at least propylene and optionally C2 or C4-C12 a-olefin with a catalyst in a first gas-phase reactor at a temperature T1 and a pressure P1, b) subsequently preparing the dispersed ethylene-?-olefin copolymer from ethylene and a C3-C12 ?-olefin by contacting the ethylene and the C3-C12 ?-olefin with a catalyst in a second gas-phase reactor at a temperature T2 and a pressure P2, wherein T1-T2 is in the range from 6 to 25° C., wherein T1>T2, wherein PI and P2 are in the range from 22 to 30 bar to prepare a heterophasic propylene copolymer (A?).Type: GrantFiled: December 12, 2017Date of Patent: May 4, 2021Assignee: SABIC GLOBAL TECHNOLOGIES B.V.Inventors: Benoit Therese Philippe Lecouvet, Christelle Marie Helene Grein
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Patent number: 10988592Abstract: It is an object of the present invention to provide a foam molding resin containing LDPE capable of enhancing foaming magnification. According to the present invention, there is provided a foam molding resin containing low-density polyethylene, wherein the low-density polyethylene has a melt tension of 100 to 250 mN and a shear viscosity of 350 to 450 Pa·s.Type: GrantFiled: August 16, 2016Date of Patent: April 27, 2021Assignee: KYORAKU CO., LTD.Inventors: Takaaki Someya, Takeru Sano
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Patent number: 10954320Abstract: The invention is directed to polyethylene having a density in the range?940 and ?960 kg/m3, Melt Flow Rate 190/21.6?1.5 and ?4.0 g/10 min at 190 degrees Celsius and MWD?3 and ?12. The polyethylene is applied in the production of pipes.Type: GrantFiled: November 21, 2016Date of Patent: March 23, 2021Assignee: SABIC GLOBAL TECHNOLOGIES B.V.Inventors: Priya Garg, Nicolaas Hendrika Friederichs, Eric Johannes Cornelia Janssen
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Patent number: 10954366Abstract: The present invention relates to a polypropylene-based resin composition which exhibits mechanical properties such as excellent strength, etc. and has an improved impact strength, and to a molded article including the same. The olefin-based copolymer includes: a polypropylene-based resin; and an olefin-based copolymer, wherein the olefin-based copolymer includes polymeric fractions defined by three different peaks at a given temperature when analyzed by cross-fractionation chromatography (CFC).Type: GrantFiled: September 18, 2017Date of Patent: March 23, 2021Inventors: Seul Ki Kim, Eun Jung Lee, Choong Hoon Lee, Ki Won Han, Jae Kwon Jang, Hyo Jung Han, In Sung Park
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Patent number: 10934421Abstract: The present invention concerns a polyethylene composition comprising a blend of between 5 and 40 wt/% of first polyethylene produced with a chromium based catalyst and having an MFR2 between 0.01 and 1 g/10 min, wherein the first polyethylene is a high density polyethylene with a density between 940 and 965 kg/m3, and between 60 and 95 wt % of a second polyethylene with an MFR2 between >1 and 12 g/10 min. Such a blend may thereby be advantageously used especially for example in cable and wire applications.Type: GrantFiled: July 27, 2017Date of Patent: March 2, 2021Assignee: SABIC GLOBAL TECHNOLOGIES B.V.Inventors: Mohammed Abdulaziz Bin Rusayyis, Husam Allan, Abdulhameed Al-Sheneper
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Patent number: 10927202Abstract: Polyethylene compositions including at least 65 wt % ethylene derived units and from 0 to 35 wt % of C3-C12 olefin comonomer derived units, based upon the total weight of the polyethylene composition are provided. The polyethylene compositions have a) an RCI,m of 100 kg/mol or greater and one or both of: b) a Tw1-Tw2 value of from ?16 to ?38° C.; and c) an Mw1/Mw2 value of at least 0.9. The polyethylene compositions may be used to manufacture articles such as films.Type: GrantFiled: October 5, 2018Date of Patent: February 23, 2021Assignee: ExxonMobil Chemical Patents Inc.Inventors: Ching-Tai Lue, Adriana S. Silva, Matthew W. Holtcamp, David F. Sanders, Ryan W. Impelman, Richard E. Pequeno, Charles J. Harlan, Xuan Ye, Dongming Li, Matthew S. Bedoya
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Patent number: 10913041Abstract: The present invention relates to a multimodal polyethylene composition comprising: (A) 35 to 65 parts by weight, preferably 45 to 65 parts by weight, most preferred 50 to 60 parts by weight, of the low molecular weight polyethylene having a weight average molecular weight (Mw) of 20,000 to 90,000 g/mol; (B) 5 to 40 parts by weight, preferably 5 to 30 parts by weight, most preferred 5 to 20 parts by weight, of the first high molecular weight polyethylene having a weight average molecular weight (Mw) of more than 150,000 to 1,000,000 g/mol or the first ultra high molecular weight polyethylene having a weight average molecular weight (Mw) of more than 1,000,000 to 5,000,000 g/mol; and (C) 20 to 60 parts by weight, preferably 25 to 60 parts by weight, most preferred 35 to 55 parts by weight, of the second high molecular weight polyethylene having a weight average molecular weight (Mw) of more than 150,000 to 1,000,000 g/mol or the second ultra high molecular weight polyethylene having a weight average molecular wType: GrantFiled: September 8, 2017Date of Patent: February 9, 2021Assignees: Thai Polyethylene Co., Ltd., SCG Chemicals Co., Ltd.Inventors: Saranya Traisilanun, Watcharee Cheevasrirungruang, Warachad Klomkamol
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Patent number: 10882287Abstract: A multilayer film made from or containing at least one layer made from or containing a polyolefin composition made from or containing: A) 5-35% by weight, based upon the total weight of the polyolefin composition, of a propylene homopolymer or a propylene ethylene copolymer; B) 25-50% by weight, based upon the total weight of the polyolefin composition, of a copolymer of ethylene and a C3-C8 alpha-olefin containing 0.1-20% by weight of C3-C8 alpha-olefin units; and C) 30-60% by weight, based upon the total weight of the polyolefin composition, of a copolymer of ethylene and propylene containing 25-75% by weight of ethylene units.Type: GrantFiled: May 3, 2018Date of Patent: January 5, 2021Assignee: Basell Poliolefine Italia S.r.l.Inventors: Gianni Perdomi, Monica Galvan, Claudio Cavalieri