Solid Polymer Derived From Ethylene Or Propylene Patents (Class 525/240)
  • Patent number: 9296884
    Abstract: A propylene composition comprising (percent by weight): A) 60%-90%, of a crystalline propylene copolymer containing from 3.5% to 10% of ethylene derived units and having a melting temperature Tm (measured by DSC on the as-reactor polymer) ranging from 146° to 160° C.; B) 10%-40%, of a copolymer of propylene containing from 15% to 30%, of ethylene derived units.
    Type: Grant
    Filed: April 29, 2010
    Date of Patent: March 29, 2016
    Assignee: Basell Poliolefine Italia S.r.l.
    Inventors: Paola Massari, Marco Ciarafoni, Gisella Biondini, Tiziana Caputo
  • Patent number: 9290630
    Abstract: Polyolefin compositions, comprising (percent by weight): 1) 55-80% of a homopolymer or copolymer of propylene, said copolymer containing up to 15% of ethylene and/or C4-C10 ?-olefin(s). 2) 20-45% of a copolymer of ethylene with one or more C4-C10 ?-olefin(s) containing from 10 to 40% of said C4-C10 ?-olefin(s); said compositions having values of MFR (230° C., 2.16 kg) up to 20 g/10 min, a total content of ethylene of 20% or more, a total content of C4-C10 ?-olefin(s) of 4.5% or more, a ratio of the total content of ethylene to the total content of C4-C10 ?-olefin(s) of 2.3 or more, a total fraction soluble in xylene at room temperature of 18 wt % or higher and flexural modulus, referred to the composition as a reactor grade, of more than 700 MPa.
    Type: Grant
    Filed: October 10, 2007
    Date of Patent: March 22, 2016
    Assignee: Basell Poliolefine Italia S.r.l.
    Inventors: Roberta Marzolla, Marco Ciarafoni, Michele Grazzi, Paola Massari, Jean News
  • Patent number: 9290680
    Abstract: The present invention relates to an adhesive, comprising at least one polymer system obtained by a process for reducing the melt viscosity of at least one polymer blend starting material, wherein the process comprises the step of treating at least one polymer blend with at least one radical donor under shear stress at a temperature above the softening point of said polymer blend.
    Type: Grant
    Filed: September 2, 2014
    Date of Patent: March 22, 2016
    Assignees: HENKEL AG & CO. KGAA, HENKEL IP & HOLDING GMBH
    Inventors: Dirk Kasper, Thomas Mueller, Gunter Hoffmann, Knut Hoffmann, Andy Swain, Claudia Yaacoub, Maria Cristina Barbosa DeJesus
  • Patent number: 9284442
    Abstract: The present invention relates to caps and closures comprising a specific propylene random copolymer, obtained by polymerization with a metallocene-based polymerization catalyst.
    Type: Grant
    Filed: December 1, 2011
    Date of Patent: March 15, 2016
    Assignee: TOTAL RESEARCH & TECHNOLOGY FELUY
    Inventors: Philippe Hoslet, Patrizio Andriolo
  • Patent number: 9273199
    Abstract: Disclosed is a high-density polyethylene (HDPE) composition that comprises at least a first high density polyethylene component having a density of 0.940-0.968 g/cm3 and a melt index I2.16 of 0.5-10.0 dg/min and a melt flow ratio (flow index I21.6 at 190° C. divided by melt index I2.16 at 190° C.) of at least 25. A second HDPE component may be included in the composition with melt index I2.16 of greater than 10 dg/min and melt flow ratio of 30 or less. The disclosed compositions are suitable for use in living hinge closure applications.
    Type: Grant
    Filed: June 10, 2013
    Date of Patent: March 1, 2016
    Assignees: Dow Global Technologies LLC, Conopco, Inc.
    Inventors: Brett Christopher Domoy, Barrett Albert Unger, Mark T. Jablonka
  • Patent number: 9273168
    Abstract: A novel polyethylene is devised which polyethylene is particularly advantageous for manufacturing rotomoulded articles.
    Type: Grant
    Filed: August 20, 2010
    Date of Patent: March 1, 2016
    Assignee: Basell Polyolefine GmbH
    Inventors: Gerd Mannebach, Heinz Vogt, Fabiana Fantinel, Shahram Mihan, Peter Bisson, Cees Besems, Gerhardus Meier, Ulf Schüller, Barbara Gall, Iakovos Vittorias, Manfred Hecker, Michael Olmscheid
  • Patent number: 9272795
    Abstract: Propylene polymer based packaging films for encapsulating hot melt adhesives are disclosed. The packaging films are readily miscible with the various hot melt adhesive chemistries during the melting stage without deleteriously affecting the adhesive properties, making the packaging film particularly well suited for packaging hot melt adhesives in a pillow, cylinder, pouch, block, cartridge and like forms.
    Type: Grant
    Filed: March 13, 2013
    Date of Patent: March 1, 2016
    Assignee: HENKEL IP & HOLDING GMBH
    Inventors: Jinyu Chen, Yuhong Hu, Darshak Desai
  • Patent number: 9273219
    Abstract: The instant invention provides a polyolefin blend composition suitable for extrusion coating or extrusion lamination applications, and multilayer structure and articles made therefrom. The polyolefin blend composition suitable for extrusion coating or extrusion lamination applications according to the present invention comprises (a) a linear low density polyethylene composition comprising: less than or equal to 100 percent by weight of the units derived from ethylene; less than 35 percent by weight of units derived from one or more ?-olefin comonomers; wherein said polyethylene composition has a density in the range of 0.890 to 0.940 g/cm3, a molecular weight distribution (Mw/Mn) in the range of 2.5 to 4.5, a melt index (I2) in the range of 4 to 30 g/10 minutes, a molecular weight distribution (Mz/Mw) in the range of from 2.0 to 3, vinyl unsaturation of less than 0.
    Type: Grant
    Filed: October 1, 2013
    Date of Patent: March 1, 2016
    Assignee: Dow Global Technologies LLC
    Inventors: Jian Wang, Mridula Kapur, James L. Cooper
  • Patent number: 9266910
    Abstract: This invention relates to unsymmetrical metallocenes, catalyst systems therefrom and their use to make highly isotactic polypropylene.
    Type: Grant
    Filed: October 10, 2014
    Date of Patent: February 23, 2016
    Assignee: ExxonMobil Chemical Patents Inc.
    Inventor: Laughlin G. McCullough
  • Patent number: 9255168
    Abstract: A highly branched polyolefin having olefin derived units; wherein the highly branched polyolefin has: (i) a branching index, g?(vis), of less than about 0.9; (ii) a phase angle, ?, of less than about 55 degrees at a complex modulus of 10 kPa, measured at 190° C.; (iii) a gel content of less than or equal to about 10%; and (iv) a melting point of less than about 135° C.; wherein the highly branched polyolefin is obtained by contacting one or more polyolefins with a free radical generator. The highly branched polyolefin may also comprise a modifying polymer, wherein the modifying polymer may be the similar or dissimilar to the polyolefin. Methods of producing these highly branched polyolefins and blends of these highly branched polyolefins are also disclosed.
    Type: Grant
    Filed: July 30, 2013
    Date of Patent: February 9, 2016
    Assignee: ExxonMobil Chemical Patents Inc.
    Inventor: Mun F. Tse
  • Patent number: 9249271
    Abstract: The invention provides a composition comprising the following: A) a first polymer selected from the following: i) an ethylene/?-olefin interpolymer; or ii) an ethylene/?-olefin multi-block interpolymer; B) a second polymer selected from the following: iii) an ethylene/?-olefin interpolymer; iv) an ethylene/?-olefin/non-conjugated diene interpolymer; or v) an ethylene/?-olefin multi-block interpolymer; and wherein the first polymer has a density from 0.880 to 0.910 g/cc, and the second polymer has a density less than, or equal to, 0.867 g/cc, and wherein the weight ratio of the first polymer to the second polymer is from 0.5 to 9.
    Type: Grant
    Filed: March 4, 2013
    Date of Patent: February 2, 2016
    Assignee: Dow Global Technologies LLC
    Inventor: Bee Tin Low
  • Patent number: 9228068
    Abstract: The invention relates to a process for preparing polypropylene films, a polypropylene film obtained by such a process, use of said polypropylene film as packaging material, an article comprising said polypropylene film as well as to the use of a polypropylene composition to improve the processability of a film production process.
    Type: Grant
    Filed: November 28, 2012
    Date of Patent: January 5, 2016
    Assignee: Borealis AG
    Inventors: Nina Ackermans, Bert Broeders
  • Patent number: 9221966
    Abstract: A dual reactor solution process gives high density polyethylene compositions containing a first ethylene copolymer and a second ethylene copolymer and which have good processability, toughness, and environmental stress crack resistance combined with good organoleptic properties. The polyethylene compositions are suitable for compression molding or injection molding applications and are particularly useful in the manufacture of caps and closures for bottles.
    Type: Grant
    Filed: December 2, 2014
    Date of Patent: December 29, 2015
    Assignee: NOVA Chemicals (International) S.A.
    Inventors: XiaoChuan Wang, Yves Lacombe, Mark Edmund Weber
  • Patent number: 9206303
    Abstract: A multilayer film is disclosed, having at least two layers. A first layer includes a first interpolymer of ethylene and at least one alpha-olefin. The first interpolymer has a density of less than 0.925 g/cm3, and an average Mv and a valley temperature between the interpolymer and high crystalline fraction, The, such that the average Mv for a fraction above The from ATREF divided by average Mv of the whole polymer from ATREF (Mhc/Mhp) is less than about 1.95 and the first interpolymer has a CDBI of less than 60%. At least one other second layer includes a second inter-polymer of ethylene and at least one alpha-olefin, the second interpolymer having a density from 0.925 to 0.965 g/cm3. The interpolymer of ethylene and at least one alpha-olefin can have a high density fraction and an overall density such that % HD fraction <0.0168x2?29.636x+13036 where x=density in g/cm3.
    Type: Grant
    Filed: December 16, 2009
    Date of Patent: December 8, 2015
    Assignee: Dow Global Technologies LLC
    Inventors: Xiao Bing Yun, Risdianti Wastiani, Hwee Lun Goh, Chang Wu, Mehmet Demirors
  • Patent number: 9181368
    Abstract: Group 4 metal complexes comprising a polyvalent, heteroaryl donor ligand and their use as components of olefin polymerization catalysts, especially suited for preparing propylene copolymer products having high isotacticity and low molecular weight, are disclosed.
    Type: Grant
    Filed: November 7, 2013
    Date of Patent: November 10, 2015
    Assignee: Dow Global Technologies LLC
    Inventors: Harold W. Boone, Kevin A. Frazier, Daniel D. VanderLende, Paul C. Vosejpka
  • Patent number: 9181424
    Abstract: Propylene polymer compositions comprising: A) from 70 wt % to 95 wt %, of a random copolymer of propylene with ethylene, containing from 1.5 wt % to 4.5 wt %, of ethylene derived units, having a content of fraction insoluble in xylene at 25° C. of not less than 93%; B) from 5 wt % to 35 wt %, of a copolymer of propylene with ethylene, containing from 7.0 wt % to 17.0 wt % of ethylene derived units; the sum A+B being 100; wherein the melt flow rate, MFR. (Melt Flow Rate according to ASTM 1238, condition L, i.e. 230° C. and 2.16 kg load) ranges from 40 g/10 min and 130 g/10 min; and wherein the relation (I) is fulfilled: 10<XS*C2A?MFR/C2B<30??(I) wherein XS is the wt % of xylene soluble content at 25° C. of the total composition; C2A is the wt % of ethylene derived units content of component A; MFR is the melt flow rate of the total composition; C2B is the wt % of ethylene derived units content of component B.
    Type: Grant
    Filed: October 5, 2012
    Date of Patent: November 10, 2015
    Assignee: Basell Poliolefine Italia S.r.l.
    Inventors: Gisella Biondini, Marco Ciarafoni, Paola Massari, Roberto Pantaleoni
  • Patent number: 9175111
    Abstract: The invention provides a composition comprising a blend, which comprises a high molecular weight ethylene-based polymer, and a low molecular weight ethylene-based polymer, and wherein the high molecular weight ethylene-based polymer has a density less than, or equal to, 0.955 g/cm3, and wherein the blend has a high load melt index (I21) greater than, or equal to, 15 g/10 min, and wherein the blend has a molecular weight distribution (Mw/Mn) greater than, or equal to, 15. The invention also provides a composition comprising a blend, which comprises a high molecular weight ethylene-based polymer and a low molecular weight ethylene-based polymer, and wherein the high molecular weight ethylene-based polymer component has a density less than, or equal to, 0.945 g/cm3, and a melt index (I2) less than, or equal to, 0.
    Type: Grant
    Filed: December 18, 2008
    Date of Patent: November 3, 2015
    Assignee: Dow Global Technologies LLC
    Inventors: Mridula (Babli) Kapur, Robert J. Jorgensen, Burkhard E. Wagner, William J. Michie, Jr.
  • Patent number: 9174914
    Abstract: The invention relates to a method for producing a dispersion of nanoscale dicarboxylic acid salts, to the use of these dispersions for producing a compound, and to the use for producing films. The invention further relates to the use of the compounds for producing films.
    Type: Grant
    Filed: October 13, 2010
    Date of Patent: November 3, 2015
    Assignee: Treofan Germany GmbH & Co. KG
    Inventors: Detlef Busch, Dominic Klein, Bertram Schmitz
  • Patent number: 9156971
    Abstract: Resins suitable for rotomolded articles comprise a bimodal polyethylene copolymer comprising from 0.1 to 5 weight % of one or more C6-8 alpha olefins and the balance ethylene, comprising from 20 to 50 weight % of a higher molecular weight polymer component having an Mw greater than 120,000 and correspondingly from 80 to 50 weight % of a lower molecular weight polymer component having an Mw less than 100,000 having a density greater than 0.942 g/cc [but less than 0.965 g/cc] and a bent strip ESCR as determined by ASTM D 1693 in 100 % Igepal® CO-630 (ethoxylated nonylphenols) for conditions A and B of greater than 1000 hours. The resulting articles have a very good balance of properties and significant ESCR.
    Type: Grant
    Filed: November 7, 2014
    Date of Patent: October 13, 2015
    Assignee: NOVA Chemicals (International) S.A.
    Inventors: Celine Bellehumeur, Yves Lacombe, Mark Hoidas
  • Patent number: 9139725
    Abstract: Disclosed is a polypropylene resin composition for automobile interior trim parts with superior paint adhesivity and low specific gravity. More specifically, a polypropylene resin composition for automobile interior trim parts having superior paint adhesivity and low specific gravity is disclosed, wherein a base resin including polypropylene, a propylene-ethylene copolymer or a mixture thereof is mixed with a reinforcer including magnesium hydroxide and an ethylene-butene elastomer. The present polypropylene resin composition allows for direct painting of an automobile interior trim part surface without primer treatment and provides excellent resistance to damage caused by impact.
    Type: Grant
    Filed: May 21, 2013
    Date of Patent: September 22, 2015
    Assignees: Hyundai Motor Company, Kia Motor Corporation, Daeha Co., Ltd.
    Inventors: Jung Gyun Noh, Kyeong Hoon Jang, Hak Soo Kim, Han Ki Lee, Kyung Beom Seo, Han Pyol Kim, Im Taek Sung
  • Patent number: 9132615
    Abstract: Retortable, flexible essentially polyolefin composition, mono- or multi-layer structures including at least one layer comprising such a composition, containers made from such structures and specific applications thereof.
    Type: Grant
    Filed: March 30, 2007
    Date of Patent: September 15, 2015
    Assignee: SOLVAY INDUSTRIAL FOILS MANAGEMENT AND RESEARCH SA
    Inventors: Petrus Karsten, Piet De Vries
  • Patent number: 9109105
    Abstract: A process for preparing a multimodal polyethylene product with at least two different polyethylene resins can include producing a first polyethylene resin in the presence of a Ziegler-Natta catalyst in a reactor. The Ziegler-Natta catalyst used for the production of the first polyethylene resin has an average particle size (D50) of at most 15 ?m. The HLMI of the first polyethylene resin is between 0.01 and 5 g/10 min. The process can include separately producing a second polyethylene resin in the presence of a Ziegler-Natta catalyst in a reactor. The MI2 of the second polyethylene resin is between 1 and 150 g/10 min. The process can include physically blending together the first and second polyethylene resins to produce a multimodal polyethylene product. The physical blending can be performed in a device for continuously melting and blending the first and second polyethylene resins.
    Type: Grant
    Filed: March 2, 2012
    Date of Patent: August 18, 2015
    Assignee: TOTAL RESEARCH & TECHNOLOGY FELUY
    Inventors: Daan Dewachter, Eric Damme
  • Patent number: 9102823
    Abstract: Methods for preparing an impact copolymer by selecting a continuous phase polymer having a first melt flow rate and selecting a rubber phase polymeric material such that the final melt flow rate of the impact copolymer is within 2 g/10 min of the first melt flow rate. Impact copolymers made from such methods and films and molded articles produced from such impact copolymers are also included.
    Type: Grant
    Filed: December 12, 2013
    Date of Patent: August 11, 2015
    Assignee: FINA TECHNOLOGY, INC.
    Inventor: Mark Leland
  • Patent number: 9096751
    Abstract: Heterophasic propylene copolymer comprising (a) a matrix (M) being a polypropylene (PP), said polypropylene (PP) has a polydispersity index (PI) of at least 5.0, and (b) an elastomeric propylene copolymer (EC) dispersed in said matrix (M), wherein (i) said heterophasic propylene copolymer has a melt flow rate MFR2 (230° C.) of equal or below 1.0 g/10 min, (ii) the amorphous phase (AM) of the xylene cold soluble fraction (XCS) of the heterophasic propylene copolymer has an intrinsic viscosity (IV) of at least 3.5 dl/g.
    Type: Grant
    Filed: March 14, 2011
    Date of Patent: August 4, 2015
    Assignee: BOREALIS AG
    Inventors: Michiel Bergstra, Pauli Leskinen, Bo Malm, Cornelia Kock
  • Patent number: 9096745
    Abstract: A polymer blend comprising first and second polyethylene copolymers is presented which has good processability, and which when made into film shows good toughness-stiffness balance, reasonable MD tear, as well as good optical properties.
    Type: Grant
    Filed: December 16, 2013
    Date of Patent: August 4, 2015
    Assignee: NOVA Chemicals (International) S.A.
    Inventors: Patrick Lam, Victoria Ker, Karen Grabow
  • Patent number: 9058918
    Abstract: TRXLPE-type cable sheaths are prepared by a method in which a solid polymer is mixed with a liquid water tree-resistant agent either by dosing or direct injection. In the dosing method, the solid polymer, e.g., high pressure LDPE, is sprayed or otherwise contacted with the liquid agent, e.g., PEG, the agent is allowed to absorb into the polymer, and the polymer with absorbed agent is then fed to an extrusion apparatus for extrusion over a sheathed or unsheathed wire or optic fiber. In the direct injection method, the solid polymer is first fed to an extrusion apparatus, and the liquid agent is sprayed or otherwise contacted with the polymer before the two are blended with one another through the action of the mixing elements of the apparatus.
    Type: Grant
    Filed: May 18, 2009
    Date of Patent: June 16, 2015
    Assignee: Union Carbide Chemicals & Plastics Technology LLC
    Inventors: Paul J. Caronia, Robert F. Eaton, Jeffrey M. Cogen, Laurence H. Gross, Timothy J. Person, Alfred Mendelsohn, Scott H. Wasserman
  • Patent number: 9045504
    Abstract: Compounds 1,3,4-(SiMe3)(C6F5)(alkyl)C5H3 are made using a simplified synthetic strategy which is readily scalable. On reaction with a suitable transition metal species, a 1,3,4-(SiMe3)(C6F5)(alkyl)C5H3 molecule provides an organotransition metal complex comprising a 1,2-(C6F5)(alkyl) substituted cyclopentadienyl ligand, which is active toward olefin polymerization.
    Type: Grant
    Filed: April 25, 2013
    Date of Patent: June 2, 2015
    Assignee: Nova Chemicals (International) S.A.
    Inventors: Xiaoliang Gao, Darryl J. Morrison, Charles Ashton Garret Carter
  • Patent number: 9045629
    Abstract: A polypropylene composition comprising 65-77 wt % of a crystalline propylene polymer, 8 to less than 13 wt % of an elastomeric copolymer and 10-23 wt % of polyethylene. The said composition exhibits a flexural modulus value higher than 1300 MPa, stress-whitening resistance values corresponding to a diameter of the whitened area of at most 1.7 cm caused by a ram falling from a 76 cm height and a diameter of the whitened area of at most 1.2 cm caused by a ram falling from a 20 cm height, and a value of Izod impact resistance at 23° C. more than 14 kJ/m2 and the one at ?20° C. at least 5 kJ/m2.
    Type: Grant
    Filed: May 5, 2006
    Date of Patent: June 2, 2015
    Assignee: Basell Poliolefine Italia S.r.l.
    Inventors: Paola Massari, Marco Ciarafoni, Jean News
  • Publication number: 20150148490
    Abstract: The instant invention provides a polyolefin composition suitable for packaging applications, films, multilayer structures and packaging devices made therefrom. The polyolefin composition according to the present invention comprises: an ethylene/?-olefin interpolymer composition comprising (a) from 50 to 75 percent by weight of a first ethylene/?-olefin copolymer fraction having a density in the range of 0.894 to 0.908 g/cm3, a melt index (I2) in the range of from 0.2 to 1 g/10 minutes, and (b) from 25 to 50 percent by weight of a second ethylene/?-olefin copolymer fraction, and wherein said ethylene/?-olefin interpolymer composition has a density in the range of 0.910 to 0.924 g/cm3, a melt index (I2) in the range of from 0.5 to 2 g/10 minutes, a zero shear viscosity ratio (ZSVR) in the range of from 1.15 to 2.5, a molecular weight distribution, expressed as the ratio of the weight average molecular weight to number average molecular weight (Mw/Mn) in the range of from 2.0 to 4.0, and tan delta at 0.
    Type: Application
    Filed: December 27, 2013
    Publication date: May 28, 2015
    Applicant: DOW GLOBAL TECHNOLOGIES LLC
    Inventors: Mridula Kapur, Mehmet Demirors, Pradeep Jain, Philip P. Fontaine, Douglas S. Ginger, David T. Gillespie, Mustafa Bilgen
  • Publication number: 20150147583
    Abstract: Disclosed are films which can provide seal strengths suited for both peelable and nonpeelable seals in a package.
    Type: Application
    Filed: October 17, 2014
    Publication date: May 28, 2015
    Inventors: Fang Bao, Becky Jin Na Zhao, Achiel J. Van Loon
  • Publication number: 20150147552
    Abstract: This invention relates to processes to prepare impact copolymers having an ethylene content of greater than 20 wt % using a process where ethylene polymer is made in the first stage and propylene polymer is made in the second stage.
    Type: Application
    Filed: October 28, 2014
    Publication date: May 28, 2015
    Inventors: Matthew W. Holtcamp, Laughlin G. McCullough, Celestino M. Perez, JR., Sarah J. Mattler
  • Publication number: 20150148491
    Abstract: The instant invention provides a polyolefin composition suitable for injection molding applications, and method of making such injection molded articles. The polyolefin composition suitable for injection molding applications comprises: an ethylene/?-olefin interpolymer composition comprising: (a) from 25 to 50 percent by weight of a first ethylene/?-olefin copolymer fraction having a density in the range of from 0.924 to 0.937 g/cm3, a melt index (I2) in the range of from 0.03 to 0.3 g/10 min, (b) from 50 to 75 percent by weight of a second ethylene homopolymer fraction having a density in the range of from greater than 0.960 g/cm3, a melt index (I2) in the range of from 100 to 180 g/10 minutes, wherein said ethylene/?-olefin interpolymer composition has a density in the range of from 0.950 to 0.958 g/cm3, a melt index (I2) in the range of from 1.0 g/10 min to 3.5 g/10 min, a zero shear viscosity ratio (ZSVR) in the range of from 1.01 to 2.5, a molecular weight distribution (Mw/Mn) in the range of from 2.
    Type: Application
    Filed: December 27, 2013
    Publication date: May 28, 2015
    Applicant: Dow Global Technologies LLC
    Inventors: Mridula Kapur, Mehmet Demirors, Philip P. Fontaine, Douglas S. Ginger, David T. Gillespie
  • Publication number: 20150148492
    Abstract: A stretch film including at least a first layer and a second layer, in which the first layer includes a metallocene linear low density polyethylene (m-LLDPE) with incorporated long chain branching resin and a lower density m-LLDPE resin; and the second layer includes a lower melt index m-LLDPE resin.
    Type: Application
    Filed: November 24, 2014
    Publication date: May 28, 2015
    Applicant: PARAGON FILMS, INC.
    Inventor: Shaun Eugene Pirtle
  • Patent number: 9040633
    Abstract: The present invention relates to a polymer composition, comprising: (i) a polypropylene matrix; (ii) a first elastomeric phase dispersed within the matrix and having a glass transition temperature Tg1, measured with dynamical mechanical thermal analysis according to ISO 6721-2, wherein the first elastomeric phase comprises an ethylene copolymer having comonomer units derived from C3 to C8 olefins; (iii) a second elastomeric phase dispersed within the matrix, wherein the second elastomeric phase is crosslinked and has a glass transition temperature Tg2, measured with dynamical mechanical thermal analysis according to ISO 6721-2, within the range of ?70° C. to ?90° C., wherein the difference between Tg1 and Tg2 is at least 15° C. and Tg1 is higher than Tg2.
    Type: Grant
    Filed: October 27, 2008
    Date of Patent: May 26, 2015
    Assignee: Borealis Technology Oy
    Inventors: Klaus Bernreitner, Tung Pham, Jens Reussner
  • Publication number: 20150141579
    Abstract: The present disclosure provides a resin suitable for use in rotational molding having an environmental stress crack resistance of greater than 1000 hours. The resin has a density from 0.937 to 0.942 g/cm3, a melt index I2 determined according to ASTM D 1238 (2.16 kg/190° C.?I2) from 4.0 to 7.0 g/10 min, an I21 determined according to ASTM D 1238 (21.6 kg/190° C.?I21) from 160 to 200 g/10 min, an I21/I2 from 30 to 40 and a terminal vinyl unsaturation greater than 0.06, per 1000 carbon atoms; and a primary structure parameter (PSP2) of from 4 to 7, and an overall Mw/Mn from 2.7 to 3.5 comprising from 2 to 5 weight % of one or more C4-8 alpha olefin comonomers.
    Type: Application
    Filed: November 7, 2014
    Publication date: May 21, 2015
    Applicant: NOVA CHEMICALS (INTERNATIONAL) S.A.
    Inventors: Marie Therese Celine Bellehumeur, Mark Hoidas
  • Patent number: 9034990
    Abstract: Injection molded articles and process of forming the same are described herein. The processes generally include providing a polyolefin including one or more propylene heterophasic copolymers, the polyolefin having an ethylene content of at least 10 wt. % based on the total weight of the polyolefin; contacting the polyolefin with a polylactic acid and a reactive modifier to form a compatiblized polymeric blend, wherein the reactive modifier is produced by contacting a polypropylene, a multifunctional acrylate comonomer, and an initiator under conditions suitable for the formation of a glycidyl methacrylate grafted polypropylene (PP-g-GMA) having a grafting yield in a range from 1 wt. % to 15 wt. %; and injection molding the compatibilized polymeric blend into an article.
    Type: Grant
    Filed: August 1, 2013
    Date of Patent: May 19, 2015
    Assignee: FINA TECHNOLOGY, INC.
    Inventors: Fengkui Li, John Ashbaugh, Gabriel Desille, Caroline Schils
  • Patent number: 9034991
    Abstract: A polymer reactor-blend comprising at least a first component having a polydispersity index of greater than about 20 and is present in an amount of from about 1 wt. % to about 99 wt. % based on the total weight of the polymer and a second component having a polydispersity index of less than about 20 and is present in an amount of from about 1 wt. % to about 99 wt. % based on the total weight of the polymer wherein a molecular weight distribution of the second component lies within a molecular weight distribution of the first component.
    Type: Grant
    Filed: January 29, 2013
    Date of Patent: May 19, 2015
    Assignee: CHEVRON PHILLIPS CHEMICAL COMPANY LP
    Inventors: Mark L. Hlavinka, Qing Yang, William B. Beaulieu, Paul J. Deslauriers
  • Publication number: 20150133608
    Abstract: The present invention relates to a moulded article comprising a polypropylene composition, wherein the polypropylene composition comprises comonomer units derived from ethylene in an amount of from 0.5 wt % to 35 wt %, and from at least one C5-12 alpha-olefin in an amount of from 1.0 mol % to 3.0 mol %, wherein the polypropylene composition has an amount of xylene solubles XS of from 20 wt % to 39 wt %, and the xylene solubles have an amount of ethylene-derived comonomer units of from 4.0 wt % to 70 wt %.
    Type: Application
    Filed: May 8, 2013
    Publication date: May 14, 2015
    Inventor: Kristin Reichelt
  • Publication number: 20150132514
    Abstract: The instant invention provides a polyethylene blend-composition suitable for blown films, and films made therefrom. The polyethylene blend-composition suitable for blown films comprises the melt blending product of: (a) from 0.5 to 4 percent by weight of a low density polyethylene having a density in the range of from 0.915 to 0.935 g/cm3, and a melt index (I2) in the range of from greater than 0.8 to less than or equal to 5 g/10 minutes, and a molecular weight distribution (Mw/Mn) in the range of from 6 to 10; (b) 90 percent or greater by weight of an ethylene/?-olefin interpolymer composition, wherein ethylene/?-olefin interpolymer composition has a Comonomer Distribution Constant (CDC) in the range of from 75 to 200, a vinyl unsaturation of less than 0.1 vinyls per one thousand carbon atoms present in the backbone of the ethylene/?-olefin interpolymer composition; a zero shear viscosity ratio (ZSVR) in the range from 2 to 20; a density in the range of from 0.903 to 0.
    Type: Application
    Filed: May 22, 2013
    Publication date: May 14, 2015
    Applicant: DOW GLOBAL TECHNOLOGIES LLC
    Inventors: Jian Wang, Nilesh R. Savargaonkar, Mehmet Demirors, John W. Garnett, IV
  • Patent number: 9029478
    Abstract: A film comprising a polymer blend of: (a) 0.15 to 0.8 wt % of an LDPE having an MI of 0.1 to 0.6 dg/min; and (b) 99.2 to 99.85 wt % of an LLDPE produced with a single-site catalyst comprising a metallocene and having a haze (HZlldpe), dart impact (DIlldpe), MD-Tear (MDTlldpe), and a slice long chain branching index of at least 0.90 for any portion of the composition having a molecular weight of 100,000 or above, wherein the film has a haze (HZblend), a dart impact (DIblend), and an MD-Tear (MDTblend), and HZblend=a*HZlldpe, where a is 0.20 to 0.70; DIblend=b*DIlldpe, where b is 0.9 to 1.3; and MDTblend=c*MDTlldpe, where c is 0.8 to 1.1.
    Type: Grant
    Filed: February 7, 2011
    Date of Patent: May 12, 2015
    Assignee: Equistar Chemicals, LP
    Inventor: Harilaos Mavridis
  • Patent number: 9023945
    Abstract: Embodiments of the present disclosure relate to a method of preparing polyethylene compositions comprising polymerizing ethylene in a first gas-phase reactor and polymerizing ethylene in a second gas-phase reactor in the presence of hydrogen; wherein at least one of the first or second gas-phase reactors comprises a first and second polymerization zone; wherein a hydrogen pressure of the first and second polymerization zones are different such that at least a portion of the second ethylene cycles through the first and second polymerization zones and a gas mixture of each polymerization zone is partially or totally prevented from entering the other zone.
    Type: Grant
    Filed: February 26, 2014
    Date of Patent: May 5, 2015
    Assignee: Basell Polyolefine GmbH
    Inventors: Harilaos Mavridis, Gerhardus Meier, Ulf Schueller, Diana Doetsch, Bernd Marczinke, Iakovos Vittorias
  • Publication number: 20150118469
    Abstract: Novel polymer blends comprise (a) 90-97% by weight of a copolymer of ethylene and an alpha olefin having from 3 to 10 carbon atoms, said copolymer having (i) a density in the range of 0.910 to 0.940 g cm?3, (ii) a melt index (190° C./2.16 kg), MI2<5, and (iii) molecular weight distribution Mw-cc/Mn-cc, by classical GPC) in the range 2.0-5.0, and (b) from 3-10% by weight of a low density polyethylene polymer having (i) a density from 0.910 to 0.920 g cm?3, (ii) a melt index (190° C./2.16 kg), MI2>2, and (iii) a melt elastic modulus G? (G?=500 Pa)>140 Pa at 190° C., wherein the sum of (a) and (b) is 100%. The copolymer component (a) may be prepared by use of metallocene catalyst systems and the novel blends exhibit an improved balance of processability and mechanical properties and are particularly useful for film applications.
    Type: Application
    Filed: November 30, 2012
    Publication date: April 30, 2015
    Inventors: Choon Kooi Chai, Dominique Jan
  • Publication number: 20150119817
    Abstract: A thermoplastic elastomer stopper that meets the desired material properties of a stopper for a syringe assembly is disclosed. The compression set of the thermoplastic elastomer stopper of the present disclosure is ?50% when measured at 25% compression for 22 hrs at 70 degree C. The hardness of the thermoplastic elastomer stopper of the present disclosure is 40-70 Shore A. The viscosity of a thermoplastic elastomer stopper of the present disclosure is ?70 Pa·s at 1,000 s?1 shear rate, ?12.0 Pa·s at 10,000 s?1 shear rate, and ?3.0 Pa·s at 50,000 s?1 shear rate when measured using a capillary rheometer at 205 degree C. (Die: Roundhole 20 mm length/1 mm diameter/180 degree inlet, Piston: d=15 mm, and melting time=7 min). The present non-lubricated stopper exhibits the required functional performance of a lubricated stopper.
    Type: Application
    Filed: October 28, 2014
    Publication date: April 30, 2015
    Inventors: Shishir Prasad, Gheorghe Cojocariu, Sathya Kaliyamoorthy, Chad Smith, Ankur Kulshrestha, Richard G. Giddes, Gerald Bonczynski, Kweku Addae-Mensah
  • Publication number: 20150119515
    Abstract: A composition including, as polymer basis: about 40 to 75% by weight of at least one polypropylene-based elastomer; and about 25 to 60% by weight of at least one random polypropylene copolymer.
    Type: Application
    Filed: December 29, 2014
    Publication date: April 30, 2015
    Applicant: SIKA TECHNOLOGY AG
    Inventors: Fabian FREI, Jean-Luc SCHLÄPFER
  • Patent number: 9018310
    Abstract: A polymer blend composition, in an exemplary embodiment, includes an impact modified polypropylene copolymer, and a low density polyethylene polymer. The ratio of an amount, by weight, of the impact modified polypropylene copolymer to an amount, by weight, of the low density polyethylene polymer is between about 6:4 to about 9:1.
    Type: Grant
    Filed: April 6, 2009
    Date of Patent: April 28, 2015
    Assignee: Polyone Designed Structures and Solutions LLC
    Inventor: Michael J. Palama
  • Publication number: 20150111053
    Abstract: The present invention relates to a low density polyethylene having a molecular weight distribution Mw/Mn which is 15 or less, a storage modulus G?, measured at a loss modulus G? of 5 kPa, which is above 3000 Pa, a weight average molecular weight (Mw) which is between 192000 and 250000 g/mol and has a melt flow rate (MFR) according to ISO 1133 (190° C., 2.16 kg) which is higher than 3.0 g/10 min, compositions, a process for production of the low density polyethylene, a low density polyethylene which is obtainable by the process, a continuous ethylene polymerization method for introducing vinylidene in a low density polyethylene, a method for an extrusion coating process or a method for an extrusion lamination process, an article, e.g. an extrusion article, an extrusion lamination article, film blowing article, film casting article, wire and cable extrusion article, injection moulding article, blow moulding article or pipe extrusion article, and uses of the low density polyethylene.
    Type: Application
    Filed: December 7, 2012
    Publication date: April 23, 2015
    Inventors: Auli Nummila-Pakarinen, Bernt-Ake Sultan, Bjorn Voigt, Gabriel Ruess, Martin Anker, Mattias Bergqvist, Thomas Gkourmpis, Thomas Hjertberg
  • Publication number: 20150112026
    Abstract: The invention relates to certain mixtures made of PE and COC, in particular for use in medical materials, so as to reduce the frictional forces.
    Type: Application
    Filed: May 16, 2013
    Publication date: April 23, 2015
    Inventor: Alwin Schwitzer
  • Publication number: 20150108127
    Abstract: The instant invention provides a polyethylene blend-composition suitable for blown films, and films made therefrom. The polyethylene blend-composition suitable for blown films comprises the melt blending product of: (a) from 0.5 to 5 percent by weight of a high density polyethylene having a density in the range of from 0.950 to 0.970 g/cm3, and a melt flow rate (I2) in the range of from less than 0.5 g/10 minutes, and a molecular weight distribution (Mw/Mn) in the range of from 10 to 40, and Mz in the range of from 800,000 to 5,000,000 g/mol; (b) 90 percent or greater by weight of a linear low density polyethylene having a density in the range of from 0.910 to 0.950 g/cm3, and a melt index (I2) in the range of from 0.1 to less than or equal to 5 g/10 minutes; (c) optionally a hydrotalcite based neutralizing agent; (d) optionally one or more nucleating agents; (e) and optionally one or more anti-oxidants.
    Type: Application
    Filed: May 22, 2013
    Publication date: April 23, 2015
    Inventors: Jian Wang, Nilesh R. Savargaonkar, Mehmet Demirors
  • Patent number: 9012564
    Abstract: A film containing an interpolymer of ethylene and a 3-substituted C4-10 alkene is prepared using a catalyst system comprising a Ziegler Natta or chromium oxide catalyst.
    Type: Grant
    Filed: January 12, 2010
    Date of Patent: April 21, 2015
    Assignee: Evonik Degussa GmbH
    Inventors: Ted M Pettijohn, Michael Grass, Stefan Buchholz, Gerhard Ellermann, Anne Britt Bjaland, Arild Follestad, Jarmo Lindroos
  • Patent number: 9006342
    Abstract: The invention relates to a polyethylene composition with a bimodal molecular weight distribution and articles made therefrom, such as high topload blow moldings and transmission and distribution pipes. The composition comprises a low-molecular-weight (LMW) ethylene homopolymer component and a homogeneous, high-molecular-weight (HMW) ethylene interpolymer component, wherein the LMW component is characterized as having a molecular weight distribution, MWDL, of less than about 8. The composition is characterized as having a bimodal molecular weight distribution, and a ductile-brittle transition temperature, Tdb, of less than ?20° C. In some embodiments, the HMW component is characterized by a reverse comonomer distribution.
    Type: Grant
    Filed: December 5, 2012
    Date of Patent: April 14, 2015
    Assignee: Dow Global Technologies LLC
    Inventors: Jozef J. Van Dun, Patrick J. C. Schouterden, Kalyan Sehanobish, Peter F. van den Berghen, Noorallah Jivraj, Johan Vanvoorden, Ruddy A. J. Nicasy, Ravindra S. Dixit, Frederik E. Gemoets