Solid Polymer Derived From Ethylene Or Propylene Patents (Class 525/240)
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Patent number: 9296884Abstract: A propylene composition comprising (percent by weight): A) 60%-90%, of a crystalline propylene copolymer containing from 3.5% to 10% of ethylene derived units and having a melting temperature Tm (measured by DSC on the as-reactor polymer) ranging from 146° to 160° C.; B) 10%-40%, of a copolymer of propylene containing from 15% to 30%, of ethylene derived units.Type: GrantFiled: April 29, 2010Date of Patent: March 29, 2016Assignee: Basell Poliolefine Italia S.r.l.Inventors: Paola Massari, Marco Ciarafoni, Gisella Biondini, Tiziana Caputo
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Patent number: 9290630Abstract: Polyolefin compositions, comprising (percent by weight): 1) 55-80% of a homopolymer or copolymer of propylene, said copolymer containing up to 15% of ethylene and/or C4-C10 ?-olefin(s). 2) 20-45% of a copolymer of ethylene with one or more C4-C10 ?-olefin(s) containing from 10 to 40% of said C4-C10 ?-olefin(s); said compositions having values of MFR (230° C., 2.16 kg) up to 20 g/10 min, a total content of ethylene of 20% or more, a total content of C4-C10 ?-olefin(s) of 4.5% or more, a ratio of the total content of ethylene to the total content of C4-C10 ?-olefin(s) of 2.3 or more, a total fraction soluble in xylene at room temperature of 18 wt % or higher and flexural modulus, referred to the composition as a reactor grade, of more than 700 MPa.Type: GrantFiled: October 10, 2007Date of Patent: March 22, 2016Assignee: Basell Poliolefine Italia S.r.l.Inventors: Roberta Marzolla, Marco Ciarafoni, Michele Grazzi, Paola Massari, Jean News
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Patent number: 9290680Abstract: The present invention relates to an adhesive, comprising at least one polymer system obtained by a process for reducing the melt viscosity of at least one polymer blend starting material, wherein the process comprises the step of treating at least one polymer blend with at least one radical donor under shear stress at a temperature above the softening point of said polymer blend.Type: GrantFiled: September 2, 2014Date of Patent: March 22, 2016Assignees: HENKEL AG & CO. KGAA, HENKEL IP & HOLDING GMBHInventors: Dirk Kasper, Thomas Mueller, Gunter Hoffmann, Knut Hoffmann, Andy Swain, Claudia Yaacoub, Maria Cristina Barbosa DeJesus
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Patent number: 9284442Abstract: The present invention relates to caps and closures comprising a specific propylene random copolymer, obtained by polymerization with a metallocene-based polymerization catalyst.Type: GrantFiled: December 1, 2011Date of Patent: March 15, 2016Assignee: TOTAL RESEARCH & TECHNOLOGY FELUYInventors: Philippe Hoslet, Patrizio Andriolo
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Patent number: 9273199Abstract: Disclosed is a high-density polyethylene (HDPE) composition that comprises at least a first high density polyethylene component having a density of 0.940-0.968 g/cm3 and a melt index I2.16 of 0.5-10.0 dg/min and a melt flow ratio (flow index I21.6 at 190° C. divided by melt index I2.16 at 190° C.) of at least 25. A second HDPE component may be included in the composition with melt index I2.16 of greater than 10 dg/min and melt flow ratio of 30 or less. The disclosed compositions are suitable for use in living hinge closure applications.Type: GrantFiled: June 10, 2013Date of Patent: March 1, 2016Assignees: Dow Global Technologies LLC, Conopco, Inc.Inventors: Brett Christopher Domoy, Barrett Albert Unger, Mark T. Jablonka
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Patent number: 9273168Abstract: A novel polyethylene is devised which polyethylene is particularly advantageous for manufacturing rotomoulded articles.Type: GrantFiled: August 20, 2010Date of Patent: March 1, 2016Assignee: Basell Polyolefine GmbHInventors: Gerd Mannebach, Heinz Vogt, Fabiana Fantinel, Shahram Mihan, Peter Bisson, Cees Besems, Gerhardus Meier, Ulf Schüller, Barbara Gall, Iakovos Vittorias, Manfred Hecker, Michael Olmscheid
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Patent number: 9272795Abstract: Propylene polymer based packaging films for encapsulating hot melt adhesives are disclosed. The packaging films are readily miscible with the various hot melt adhesive chemistries during the melting stage without deleteriously affecting the adhesive properties, making the packaging film particularly well suited for packaging hot melt adhesives in a pillow, cylinder, pouch, block, cartridge and like forms.Type: GrantFiled: March 13, 2013Date of Patent: March 1, 2016Assignee: HENKEL IP & HOLDING GMBHInventors: Jinyu Chen, Yuhong Hu, Darshak Desai
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Patent number: 9273219Abstract: The instant invention provides a polyolefin blend composition suitable for extrusion coating or extrusion lamination applications, and multilayer structure and articles made therefrom. The polyolefin blend composition suitable for extrusion coating or extrusion lamination applications according to the present invention comprises (a) a linear low density polyethylene composition comprising: less than or equal to 100 percent by weight of the units derived from ethylene; less than 35 percent by weight of units derived from one or more ?-olefin comonomers; wherein said polyethylene composition has a density in the range of 0.890 to 0.940 g/cm3, a molecular weight distribution (Mw/Mn) in the range of 2.5 to 4.5, a melt index (I2) in the range of 4 to 30 g/10 minutes, a molecular weight distribution (Mz/Mw) in the range of from 2.0 to 3, vinyl unsaturation of less than 0.Type: GrantFiled: October 1, 2013Date of Patent: March 1, 2016Assignee: Dow Global Technologies LLCInventors: Jian Wang, Mridula Kapur, James L. Cooper
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Patent number: 9266910Abstract: This invention relates to unsymmetrical metallocenes, catalyst systems therefrom and their use to make highly isotactic polypropylene.Type: GrantFiled: October 10, 2014Date of Patent: February 23, 2016Assignee: ExxonMobil Chemical Patents Inc.Inventor: Laughlin G. McCullough
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Patent number: 9255168Abstract: A highly branched polyolefin having olefin derived units; wherein the highly branched polyolefin has: (i) a branching index, g?(vis), of less than about 0.9; (ii) a phase angle, ?, of less than about 55 degrees at a complex modulus of 10 kPa, measured at 190° C.; (iii) a gel content of less than or equal to about 10%; and (iv) a melting point of less than about 135° C.; wherein the highly branched polyolefin is obtained by contacting one or more polyolefins with a free radical generator. The highly branched polyolefin may also comprise a modifying polymer, wherein the modifying polymer may be the similar or dissimilar to the polyolefin. Methods of producing these highly branched polyolefins and blends of these highly branched polyolefins are also disclosed.Type: GrantFiled: July 30, 2013Date of Patent: February 9, 2016Assignee: ExxonMobil Chemical Patents Inc.Inventor: Mun F. Tse
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Patent number: 9249271Abstract: The invention provides a composition comprising the following: A) a first polymer selected from the following: i) an ethylene/?-olefin interpolymer; or ii) an ethylene/?-olefin multi-block interpolymer; B) a second polymer selected from the following: iii) an ethylene/?-olefin interpolymer; iv) an ethylene/?-olefin/non-conjugated diene interpolymer; or v) an ethylene/?-olefin multi-block interpolymer; and wherein the first polymer has a density from 0.880 to 0.910 g/cc, and the second polymer has a density less than, or equal to, 0.867 g/cc, and wherein the weight ratio of the first polymer to the second polymer is from 0.5 to 9.Type: GrantFiled: March 4, 2013Date of Patent: February 2, 2016Assignee: Dow Global Technologies LLCInventor: Bee Tin Low
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Patent number: 9228068Abstract: The invention relates to a process for preparing polypropylene films, a polypropylene film obtained by such a process, use of said polypropylene film as packaging material, an article comprising said polypropylene film as well as to the use of a polypropylene composition to improve the processability of a film production process.Type: GrantFiled: November 28, 2012Date of Patent: January 5, 2016Assignee: Borealis AGInventors: Nina Ackermans, Bert Broeders
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Patent number: 9221966Abstract: A dual reactor solution process gives high density polyethylene compositions containing a first ethylene copolymer and a second ethylene copolymer and which have good processability, toughness, and environmental stress crack resistance combined with good organoleptic properties. The polyethylene compositions are suitable for compression molding or injection molding applications and are particularly useful in the manufacture of caps and closures for bottles.Type: GrantFiled: December 2, 2014Date of Patent: December 29, 2015Assignee: NOVA Chemicals (International) S.A.Inventors: XiaoChuan Wang, Yves Lacombe, Mark Edmund Weber
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Patent number: 9206303Abstract: A multilayer film is disclosed, having at least two layers. A first layer includes a first interpolymer of ethylene and at least one alpha-olefin. The first interpolymer has a density of less than 0.925 g/cm3, and an average Mv and a valley temperature between the interpolymer and high crystalline fraction, The, such that the average Mv for a fraction above The from ATREF divided by average Mv of the whole polymer from ATREF (Mhc/Mhp) is less than about 1.95 and the first interpolymer has a CDBI of less than 60%. At least one other second layer includes a second inter-polymer of ethylene and at least one alpha-olefin, the second interpolymer having a density from 0.925 to 0.965 g/cm3. The interpolymer of ethylene and at least one alpha-olefin can have a high density fraction and an overall density such that % HD fraction <0.0168x2?29.636x+13036 where x=density in g/cm3.Type: GrantFiled: December 16, 2009Date of Patent: December 8, 2015Assignee: Dow Global Technologies LLCInventors: Xiao Bing Yun, Risdianti Wastiani, Hwee Lun Goh, Chang Wu, Mehmet Demirors
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Patent number: 9181368Abstract: Group 4 metal complexes comprising a polyvalent, heteroaryl donor ligand and their use as components of olefin polymerization catalysts, especially suited for preparing propylene copolymer products having high isotacticity and low molecular weight, are disclosed.Type: GrantFiled: November 7, 2013Date of Patent: November 10, 2015Assignee: Dow Global Technologies LLCInventors: Harold W. Boone, Kevin A. Frazier, Daniel D. VanderLende, Paul C. Vosejpka
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Patent number: 9181424Abstract: Propylene polymer compositions comprising: A) from 70 wt % to 95 wt %, of a random copolymer of propylene with ethylene, containing from 1.5 wt % to 4.5 wt %, of ethylene derived units, having a content of fraction insoluble in xylene at 25° C. of not less than 93%; B) from 5 wt % to 35 wt %, of a copolymer of propylene with ethylene, containing from 7.0 wt % to 17.0 wt % of ethylene derived units; the sum A+B being 100; wherein the melt flow rate, MFR. (Melt Flow Rate according to ASTM 1238, condition L, i.e. 230° C. and 2.16 kg load) ranges from 40 g/10 min and 130 g/10 min; and wherein the relation (I) is fulfilled: 10<XS*C2A?MFR/C2B<30??(I) wherein XS is the wt % of xylene soluble content at 25° C. of the total composition; C2A is the wt % of ethylene derived units content of component A; MFR is the melt flow rate of the total composition; C2B is the wt % of ethylene derived units content of component B.Type: GrantFiled: October 5, 2012Date of Patent: November 10, 2015Assignee: Basell Poliolefine Italia S.r.l.Inventors: Gisella Biondini, Marco Ciarafoni, Paola Massari, Roberto Pantaleoni
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Ethylene-based polymer compositions, methods of making the same, and articles prepared from the same
Patent number: 9175111Abstract: The invention provides a composition comprising a blend, which comprises a high molecular weight ethylene-based polymer, and a low molecular weight ethylene-based polymer, and wherein the high molecular weight ethylene-based polymer has a density less than, or equal to, 0.955 g/cm3, and wherein the blend has a high load melt index (I21) greater than, or equal to, 15 g/10 min, and wherein the blend has a molecular weight distribution (Mw/Mn) greater than, or equal to, 15. The invention also provides a composition comprising a blend, which comprises a high molecular weight ethylene-based polymer and a low molecular weight ethylene-based polymer, and wherein the high molecular weight ethylene-based polymer component has a density less than, or equal to, 0.945 g/cm3, and a melt index (I2) less than, or equal to, 0.Type: GrantFiled: December 18, 2008Date of Patent: November 3, 2015Assignee: Dow Global Technologies LLCInventors: Mridula (Babli) Kapur, Robert J. Jorgensen, Burkhard E. Wagner, William J. Michie, Jr. -
Patent number: 9174914Abstract: The invention relates to a method for producing a dispersion of nanoscale dicarboxylic acid salts, to the use of these dispersions for producing a compound, and to the use for producing films. The invention further relates to the use of the compounds for producing films.Type: GrantFiled: October 13, 2010Date of Patent: November 3, 2015Assignee: Treofan Germany GmbH & Co. KGInventors: Detlef Busch, Dominic Klein, Bertram Schmitz
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Patent number: 9156971Abstract: Resins suitable for rotomolded articles comprise a bimodal polyethylene copolymer comprising from 0.1 to 5 weight % of one or more C6-8 alpha olefins and the balance ethylene, comprising from 20 to 50 weight % of a higher molecular weight polymer component having an Mw greater than 120,000 and correspondingly from 80 to 50 weight % of a lower molecular weight polymer component having an Mw less than 100,000 having a density greater than 0.942 g/cc [but less than 0.965 g/cc] and a bent strip ESCR as determined by ASTM D 1693 in 100 % Igepal® CO-630 (ethoxylated nonylphenols) for conditions A and B of greater than 1000 hours. The resulting articles have a very good balance of properties and significant ESCR.Type: GrantFiled: November 7, 2014Date of Patent: October 13, 2015Assignee: NOVA Chemicals (International) S.A.Inventors: Celine Bellehumeur, Yves Lacombe, Mark Hoidas
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Patent number: 9139725Abstract: Disclosed is a polypropylene resin composition for automobile interior trim parts with superior paint adhesivity and low specific gravity. More specifically, a polypropylene resin composition for automobile interior trim parts having superior paint adhesivity and low specific gravity is disclosed, wherein a base resin including polypropylene, a propylene-ethylene copolymer or a mixture thereof is mixed with a reinforcer including magnesium hydroxide and an ethylene-butene elastomer. The present polypropylene resin composition allows for direct painting of an automobile interior trim part surface without primer treatment and provides excellent resistance to damage caused by impact.Type: GrantFiled: May 21, 2013Date of Patent: September 22, 2015Assignees: Hyundai Motor Company, Kia Motor Corporation, Daeha Co., Ltd.Inventors: Jung Gyun Noh, Kyeong Hoon Jang, Hak Soo Kim, Han Ki Lee, Kyung Beom Seo, Han Pyol Kim, Im Taek Sung
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Patent number: 9132615Abstract: Retortable, flexible essentially polyolefin composition, mono- or multi-layer structures including at least one layer comprising such a composition, containers made from such structures and specific applications thereof.Type: GrantFiled: March 30, 2007Date of Patent: September 15, 2015Assignee: SOLVAY INDUSTRIAL FOILS MANAGEMENT AND RESEARCH SAInventors: Petrus Karsten, Piet De Vries
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Patent number: 9109105Abstract: A process for preparing a multimodal polyethylene product with at least two different polyethylene resins can include producing a first polyethylene resin in the presence of a Ziegler-Natta catalyst in a reactor. The Ziegler-Natta catalyst used for the production of the first polyethylene resin has an average particle size (D50) of at most 15 ?m. The HLMI of the first polyethylene resin is between 0.01 and 5 g/10 min. The process can include separately producing a second polyethylene resin in the presence of a Ziegler-Natta catalyst in a reactor. The MI2 of the second polyethylene resin is between 1 and 150 g/10 min. The process can include physically blending together the first and second polyethylene resins to produce a multimodal polyethylene product. The physical blending can be performed in a device for continuously melting and blending the first and second polyethylene resins.Type: GrantFiled: March 2, 2012Date of Patent: August 18, 2015Assignee: TOTAL RESEARCH & TECHNOLOGY FELUYInventors: Daan Dewachter, Eric Damme
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Patent number: 9102823Abstract: Methods for preparing an impact copolymer by selecting a continuous phase polymer having a first melt flow rate and selecting a rubber phase polymeric material such that the final melt flow rate of the impact copolymer is within 2 g/10 min of the first melt flow rate. Impact copolymers made from such methods and films and molded articles produced from such impact copolymers are also included.Type: GrantFiled: December 12, 2013Date of Patent: August 11, 2015Assignee: FINA TECHNOLOGY, INC.Inventor: Mark Leland
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Patent number: 9096751Abstract: Heterophasic propylene copolymer comprising (a) a matrix (M) being a polypropylene (PP), said polypropylene (PP) has a polydispersity index (PI) of at least 5.0, and (b) an elastomeric propylene copolymer (EC) dispersed in said matrix (M), wherein (i) said heterophasic propylene copolymer has a melt flow rate MFR2 (230° C.) of equal or below 1.0 g/10 min, (ii) the amorphous phase (AM) of the xylene cold soluble fraction (XCS) of the heterophasic propylene copolymer has an intrinsic viscosity (IV) of at least 3.5 dl/g.Type: GrantFiled: March 14, 2011Date of Patent: August 4, 2015Assignee: BOREALIS AGInventors: Michiel Bergstra, Pauli Leskinen, Bo Malm, Cornelia Kock
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Patent number: 9096745Abstract: A polymer blend comprising first and second polyethylene copolymers is presented which has good processability, and which when made into film shows good toughness-stiffness balance, reasonable MD tear, as well as good optical properties.Type: GrantFiled: December 16, 2013Date of Patent: August 4, 2015Assignee: NOVA Chemicals (International) S.A.Inventors: Patrick Lam, Victoria Ker, Karen Grabow
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Patent number: 9058918Abstract: TRXLPE-type cable sheaths are prepared by a method in which a solid polymer is mixed with a liquid water tree-resistant agent either by dosing or direct injection. In the dosing method, the solid polymer, e.g., high pressure LDPE, is sprayed or otherwise contacted with the liquid agent, e.g., PEG, the agent is allowed to absorb into the polymer, and the polymer with absorbed agent is then fed to an extrusion apparatus for extrusion over a sheathed or unsheathed wire or optic fiber. In the direct injection method, the solid polymer is first fed to an extrusion apparatus, and the liquid agent is sprayed or otherwise contacted with the polymer before the two are blended with one another through the action of the mixing elements of the apparatus.Type: GrantFiled: May 18, 2009Date of Patent: June 16, 2015Assignee: Union Carbide Chemicals & Plastics Technology LLCInventors: Paul J. Caronia, Robert F. Eaton, Jeffrey M. Cogen, Laurence H. Gross, Timothy J. Person, Alfred Mendelsohn, Scott H. Wasserman
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Patent number: 9045504Abstract: Compounds 1,3,4-(SiMe3)(C6F5)(alkyl)C5H3 are made using a simplified synthetic strategy which is readily scalable. On reaction with a suitable transition metal species, a 1,3,4-(SiMe3)(C6F5)(alkyl)C5H3 molecule provides an organotransition metal complex comprising a 1,2-(C6F5)(alkyl) substituted cyclopentadienyl ligand, which is active toward olefin polymerization.Type: GrantFiled: April 25, 2013Date of Patent: June 2, 2015Assignee: Nova Chemicals (International) S.A.Inventors: Xiaoliang Gao, Darryl J. Morrison, Charles Ashton Garret Carter
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Patent number: 9045629Abstract: A polypropylene composition comprising 65-77 wt % of a crystalline propylene polymer, 8 to less than 13 wt % of an elastomeric copolymer and 10-23 wt % of polyethylene. The said composition exhibits a flexural modulus value higher than 1300 MPa, stress-whitening resistance values corresponding to a diameter of the whitened area of at most 1.7 cm caused by a ram falling from a 76 cm height and a diameter of the whitened area of at most 1.2 cm caused by a ram falling from a 20 cm height, and a value of Izod impact resistance at 23° C. more than 14 kJ/m2 and the one at ?20° C. at least 5 kJ/m2.Type: GrantFiled: May 5, 2006Date of Patent: June 2, 2015Assignee: Basell Poliolefine Italia S.r.l.Inventors: Paola Massari, Marco Ciarafoni, Jean News
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Publication number: 20150148490Abstract: The instant invention provides a polyolefin composition suitable for packaging applications, films, multilayer structures and packaging devices made therefrom. The polyolefin composition according to the present invention comprises: an ethylene/?-olefin interpolymer composition comprising (a) from 50 to 75 percent by weight of a first ethylene/?-olefin copolymer fraction having a density in the range of 0.894 to 0.908 g/cm3, a melt index (I2) in the range of from 0.2 to 1 g/10 minutes, and (b) from 25 to 50 percent by weight of a second ethylene/?-olefin copolymer fraction, and wherein said ethylene/?-olefin interpolymer composition has a density in the range of 0.910 to 0.924 g/cm3, a melt index (I2) in the range of from 0.5 to 2 g/10 minutes, a zero shear viscosity ratio (ZSVR) in the range of from 1.15 to 2.5, a molecular weight distribution, expressed as the ratio of the weight average molecular weight to number average molecular weight (Mw/Mn) in the range of from 2.0 to 4.0, and tan delta at 0.Type: ApplicationFiled: December 27, 2013Publication date: May 28, 2015Applicant: DOW GLOBAL TECHNOLOGIES LLCInventors: Mridula Kapur, Mehmet Demirors, Pradeep Jain, Philip P. Fontaine, Douglas S. Ginger, David T. Gillespie, Mustafa Bilgen
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Publication number: 20150147583Abstract: Disclosed are films which can provide seal strengths suited for both peelable and nonpeelable seals in a package.Type: ApplicationFiled: October 17, 2014Publication date: May 28, 2015Inventors: Fang Bao, Becky Jin Na Zhao, Achiel J. Van Loon
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Publication number: 20150147552Abstract: This invention relates to processes to prepare impact copolymers having an ethylene content of greater than 20 wt % using a process where ethylene polymer is made in the first stage and propylene polymer is made in the second stage.Type: ApplicationFiled: October 28, 2014Publication date: May 28, 2015Inventors: Matthew W. Holtcamp, Laughlin G. McCullough, Celestino M. Perez, JR., Sarah J. Mattler
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Publication number: 20150148491Abstract: The instant invention provides a polyolefin composition suitable for injection molding applications, and method of making such injection molded articles. The polyolefin composition suitable for injection molding applications comprises: an ethylene/?-olefin interpolymer composition comprising: (a) from 25 to 50 percent by weight of a first ethylene/?-olefin copolymer fraction having a density in the range of from 0.924 to 0.937 g/cm3, a melt index (I2) in the range of from 0.03 to 0.3 g/10 min, (b) from 50 to 75 percent by weight of a second ethylene homopolymer fraction having a density in the range of from greater than 0.960 g/cm3, a melt index (I2) in the range of from 100 to 180 g/10 minutes, wherein said ethylene/?-olefin interpolymer composition has a density in the range of from 0.950 to 0.958 g/cm3, a melt index (I2) in the range of from 1.0 g/10 min to 3.5 g/10 min, a zero shear viscosity ratio (ZSVR) in the range of from 1.01 to 2.5, a molecular weight distribution (Mw/Mn) in the range of from 2.Type: ApplicationFiled: December 27, 2013Publication date: May 28, 2015Applicant: Dow Global Technologies LLCInventors: Mridula Kapur, Mehmet Demirors, Philip P. Fontaine, Douglas S. Ginger, David T. Gillespie
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Publication number: 20150148492Abstract: A stretch film including at least a first layer and a second layer, in which the first layer includes a metallocene linear low density polyethylene (m-LLDPE) with incorporated long chain branching resin and a lower density m-LLDPE resin; and the second layer includes a lower melt index m-LLDPE resin.Type: ApplicationFiled: November 24, 2014Publication date: May 28, 2015Applicant: PARAGON FILMS, INC.Inventor: Shaun Eugene Pirtle
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Patent number: 9040633Abstract: The present invention relates to a polymer composition, comprising: (i) a polypropylene matrix; (ii) a first elastomeric phase dispersed within the matrix and having a glass transition temperature Tg1, measured with dynamical mechanical thermal analysis according to ISO 6721-2, wherein the first elastomeric phase comprises an ethylene copolymer having comonomer units derived from C3 to C8 olefins; (iii) a second elastomeric phase dispersed within the matrix, wherein the second elastomeric phase is crosslinked and has a glass transition temperature Tg2, measured with dynamical mechanical thermal analysis according to ISO 6721-2, within the range of ?70° C. to ?90° C., wherein the difference between Tg1 and Tg2 is at least 15° C. and Tg1 is higher than Tg2.Type: GrantFiled: October 27, 2008Date of Patent: May 26, 2015Assignee: Borealis Technology OyInventors: Klaus Bernreitner, Tung Pham, Jens Reussner
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Publication number: 20150141579Abstract: The present disclosure provides a resin suitable for use in rotational molding having an environmental stress crack resistance of greater than 1000 hours. The resin has a density from 0.937 to 0.942 g/cm3, a melt index I2 determined according to ASTM D 1238 (2.16 kg/190° C.?I2) from 4.0 to 7.0 g/10 min, an I21 determined according to ASTM D 1238 (21.6 kg/190° C.?I21) from 160 to 200 g/10 min, an I21/I2 from 30 to 40 and a terminal vinyl unsaturation greater than 0.06, per 1000 carbon atoms; and a primary structure parameter (PSP2) of from 4 to 7, and an overall Mw/Mn from 2.7 to 3.5 comprising from 2 to 5 weight % of one or more C4-8 alpha olefin comonomers.Type: ApplicationFiled: November 7, 2014Publication date: May 21, 2015Applicant: NOVA CHEMICALS (INTERNATIONAL) S.A.Inventors: Marie Therese Celine Bellehumeur, Mark Hoidas
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Patent number: 9034990Abstract: Injection molded articles and process of forming the same are described herein. The processes generally include providing a polyolefin including one or more propylene heterophasic copolymers, the polyolefin having an ethylene content of at least 10 wt. % based on the total weight of the polyolefin; contacting the polyolefin with a polylactic acid and a reactive modifier to form a compatiblized polymeric blend, wherein the reactive modifier is produced by contacting a polypropylene, a multifunctional acrylate comonomer, and an initiator under conditions suitable for the formation of a glycidyl methacrylate grafted polypropylene (PP-g-GMA) having a grafting yield in a range from 1 wt. % to 15 wt. %; and injection molding the compatibilized polymeric blend into an article.Type: GrantFiled: August 1, 2013Date of Patent: May 19, 2015Assignee: FINA TECHNOLOGY, INC.Inventors: Fengkui Li, John Ashbaugh, Gabriel Desille, Caroline Schils
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Patent number: 9034991Abstract: A polymer reactor-blend comprising at least a first component having a polydispersity index of greater than about 20 and is present in an amount of from about 1 wt. % to about 99 wt. % based on the total weight of the polymer and a second component having a polydispersity index of less than about 20 and is present in an amount of from about 1 wt. % to about 99 wt. % based on the total weight of the polymer wherein a molecular weight distribution of the second component lies within a molecular weight distribution of the first component.Type: GrantFiled: January 29, 2013Date of Patent: May 19, 2015Assignee: CHEVRON PHILLIPS CHEMICAL COMPANY LPInventors: Mark L. Hlavinka, Qing Yang, William B. Beaulieu, Paul J. Deslauriers
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Publication number: 20150133608Abstract: The present invention relates to a moulded article comprising a polypropylene composition, wherein the polypropylene composition comprises comonomer units derived from ethylene in an amount of from 0.5 wt % to 35 wt %, and from at least one C5-12 alpha-olefin in an amount of from 1.0 mol % to 3.0 mol %, wherein the polypropylene composition has an amount of xylene solubles XS of from 20 wt % to 39 wt %, and the xylene solubles have an amount of ethylene-derived comonomer units of from 4.0 wt % to 70 wt %.Type: ApplicationFiled: May 8, 2013Publication date: May 14, 2015Inventor: Kristin Reichelt
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Publication number: 20150132514Abstract: The instant invention provides a polyethylene blend-composition suitable for blown films, and films made therefrom. The polyethylene blend-composition suitable for blown films comprises the melt blending product of: (a) from 0.5 to 4 percent by weight of a low density polyethylene having a density in the range of from 0.915 to 0.935 g/cm3, and a melt index (I2) in the range of from greater than 0.8 to less than or equal to 5 g/10 minutes, and a molecular weight distribution (Mw/Mn) in the range of from 6 to 10; (b) 90 percent or greater by weight of an ethylene/?-olefin interpolymer composition, wherein ethylene/?-olefin interpolymer composition has a Comonomer Distribution Constant (CDC) in the range of from 75 to 200, a vinyl unsaturation of less than 0.1 vinyls per one thousand carbon atoms present in the backbone of the ethylene/?-olefin interpolymer composition; a zero shear viscosity ratio (ZSVR) in the range from 2 to 20; a density in the range of from 0.903 to 0.Type: ApplicationFiled: May 22, 2013Publication date: May 14, 2015Applicant: DOW GLOBAL TECHNOLOGIES LLCInventors: Jian Wang, Nilesh R. Savargaonkar, Mehmet Demirors, John W. Garnett, IV
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Patent number: 9029478Abstract: A film comprising a polymer blend of: (a) 0.15 to 0.8 wt % of an LDPE having an MI of 0.1 to 0.6 dg/min; and (b) 99.2 to 99.85 wt % of an LLDPE produced with a single-site catalyst comprising a metallocene and having a haze (HZlldpe), dart impact (DIlldpe), MD-Tear (MDTlldpe), and a slice long chain branching index of at least 0.90 for any portion of the composition having a molecular weight of 100,000 or above, wherein the film has a haze (HZblend), a dart impact (DIblend), and an MD-Tear (MDTblend), and HZblend=a*HZlldpe, where a is 0.20 to 0.70; DIblend=b*DIlldpe, where b is 0.9 to 1.3; and MDTblend=c*MDTlldpe, where c is 0.8 to 1.1.Type: GrantFiled: February 7, 2011Date of Patent: May 12, 2015Assignee: Equistar Chemicals, LPInventor: Harilaos Mavridis
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Patent number: 9023945Abstract: Embodiments of the present disclosure relate to a method of preparing polyethylene compositions comprising polymerizing ethylene in a first gas-phase reactor and polymerizing ethylene in a second gas-phase reactor in the presence of hydrogen; wherein at least one of the first or second gas-phase reactors comprises a first and second polymerization zone; wherein a hydrogen pressure of the first and second polymerization zones are different such that at least a portion of the second ethylene cycles through the first and second polymerization zones and a gas mixture of each polymerization zone is partially or totally prevented from entering the other zone.Type: GrantFiled: February 26, 2014Date of Patent: May 5, 2015Assignee: Basell Polyolefine GmbHInventors: Harilaos Mavridis, Gerhardus Meier, Ulf Schueller, Diana Doetsch, Bernd Marczinke, Iakovos Vittorias
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Publication number: 20150118469Abstract: Novel polymer blends comprise (a) 90-97% by weight of a copolymer of ethylene and an alpha olefin having from 3 to 10 carbon atoms, said copolymer having (i) a density in the range of 0.910 to 0.940 g cm?3, (ii) a melt index (190° C./2.16 kg), MI2<5, and (iii) molecular weight distribution Mw-cc/Mn-cc, by classical GPC) in the range 2.0-5.0, and (b) from 3-10% by weight of a low density polyethylene polymer having (i) a density from 0.910 to 0.920 g cm?3, (ii) a melt index (190° C./2.16 kg), MI2>2, and (iii) a melt elastic modulus G? (G?=500 Pa)>140 Pa at 190° C., wherein the sum of (a) and (b) is 100%. The copolymer component (a) may be prepared by use of metallocene catalyst systems and the novel blends exhibit an improved balance of processability and mechanical properties and are particularly useful for film applications.Type: ApplicationFiled: November 30, 2012Publication date: April 30, 2015Inventors: Choon Kooi Chai, Dominique Jan
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Publication number: 20150119817Abstract: A thermoplastic elastomer stopper that meets the desired material properties of a stopper for a syringe assembly is disclosed. The compression set of the thermoplastic elastomer stopper of the present disclosure is ?50% when measured at 25% compression for 22 hrs at 70 degree C. The hardness of the thermoplastic elastomer stopper of the present disclosure is 40-70 Shore A. The viscosity of a thermoplastic elastomer stopper of the present disclosure is ?70 Pa·s at 1,000 s?1 shear rate, ?12.0 Pa·s at 10,000 s?1 shear rate, and ?3.0 Pa·s at 50,000 s?1 shear rate when measured using a capillary rheometer at 205 degree C. (Die: Roundhole 20 mm length/1 mm diameter/180 degree inlet, Piston: d=15 mm, and melting time=7 min). The present non-lubricated stopper exhibits the required functional performance of a lubricated stopper.Type: ApplicationFiled: October 28, 2014Publication date: April 30, 2015Inventors: Shishir Prasad, Gheorghe Cojocariu, Sathya Kaliyamoorthy, Chad Smith, Ankur Kulshrestha, Richard G. Giddes, Gerald Bonczynski, Kweku Addae-Mensah
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Publication number: 20150119515Abstract: A composition including, as polymer basis: about 40 to 75% by weight of at least one polypropylene-based elastomer; and about 25 to 60% by weight of at least one random polypropylene copolymer.Type: ApplicationFiled: December 29, 2014Publication date: April 30, 2015Applicant: SIKA TECHNOLOGY AGInventors: Fabian FREI, Jean-Luc SCHLÄPFER
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Patent number: 9018310Abstract: A polymer blend composition, in an exemplary embodiment, includes an impact modified polypropylene copolymer, and a low density polyethylene polymer. The ratio of an amount, by weight, of the impact modified polypropylene copolymer to an amount, by weight, of the low density polyethylene polymer is between about 6:4 to about 9:1.Type: GrantFiled: April 6, 2009Date of Patent: April 28, 2015Assignee: Polyone Designed Structures and Solutions LLCInventor: Michael J. Palama
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Publication number: 20150111053Abstract: The present invention relates to a low density polyethylene having a molecular weight distribution Mw/Mn which is 15 or less, a storage modulus G?, measured at a loss modulus G? of 5 kPa, which is above 3000 Pa, a weight average molecular weight (Mw) which is between 192000 and 250000 g/mol and has a melt flow rate (MFR) according to ISO 1133 (190° C., 2.16 kg) which is higher than 3.0 g/10 min, compositions, a process for production of the low density polyethylene, a low density polyethylene which is obtainable by the process, a continuous ethylene polymerization method for introducing vinylidene in a low density polyethylene, a method for an extrusion coating process or a method for an extrusion lamination process, an article, e.g. an extrusion article, an extrusion lamination article, film blowing article, film casting article, wire and cable extrusion article, injection moulding article, blow moulding article or pipe extrusion article, and uses of the low density polyethylene.Type: ApplicationFiled: December 7, 2012Publication date: April 23, 2015Inventors: Auli Nummila-Pakarinen, Bernt-Ake Sultan, Bjorn Voigt, Gabriel Ruess, Martin Anker, Mattias Bergqvist, Thomas Gkourmpis, Thomas Hjertberg
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Publication number: 20150112026Abstract: The invention relates to certain mixtures made of PE and COC, in particular for use in medical materials, so as to reduce the frictional forces.Type: ApplicationFiled: May 16, 2013Publication date: April 23, 2015Inventor: Alwin Schwitzer
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Publication number: 20150108127Abstract: The instant invention provides a polyethylene blend-composition suitable for blown films, and films made therefrom. The polyethylene blend-composition suitable for blown films comprises the melt blending product of: (a) from 0.5 to 5 percent by weight of a high density polyethylene having a density in the range of from 0.950 to 0.970 g/cm3, and a melt flow rate (I2) in the range of from less than 0.5 g/10 minutes, and a molecular weight distribution (Mw/Mn) in the range of from 10 to 40, and Mz in the range of from 800,000 to 5,000,000 g/mol; (b) 90 percent or greater by weight of a linear low density polyethylene having a density in the range of from 0.910 to 0.950 g/cm3, and a melt index (I2) in the range of from 0.1 to less than or equal to 5 g/10 minutes; (c) optionally a hydrotalcite based neutralizing agent; (d) optionally one or more nucleating agents; (e) and optionally one or more anti-oxidants.Type: ApplicationFiled: May 22, 2013Publication date: April 23, 2015Inventors: Jian Wang, Nilesh R. Savargaonkar, Mehmet Demirors
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Patent number: 9012564Abstract: A film containing an interpolymer of ethylene and a 3-substituted C4-10 alkene is prepared using a catalyst system comprising a Ziegler Natta or chromium oxide catalyst.Type: GrantFiled: January 12, 2010Date of Patent: April 21, 2015Assignee: Evonik Degussa GmbHInventors: Ted M Pettijohn, Michael Grass, Stefan Buchholz, Gerhard Ellermann, Anne Britt Bjaland, Arild Follestad, Jarmo Lindroos
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Patent number: 9006342Abstract: The invention relates to a polyethylene composition with a bimodal molecular weight distribution and articles made therefrom, such as high topload blow moldings and transmission and distribution pipes. The composition comprises a low-molecular-weight (LMW) ethylene homopolymer component and a homogeneous, high-molecular-weight (HMW) ethylene interpolymer component, wherein the LMW component is characterized as having a molecular weight distribution, MWDL, of less than about 8. The composition is characterized as having a bimodal molecular weight distribution, and a ductile-brittle transition temperature, Tdb, of less than ?20° C. In some embodiments, the HMW component is characterized by a reverse comonomer distribution.Type: GrantFiled: December 5, 2012Date of Patent: April 14, 2015Assignee: Dow Global Technologies LLCInventors: Jozef J. Van Dun, Patrick J. C. Schouterden, Kalyan Sehanobish, Peter F. van den Berghen, Noorallah Jivraj, Johan Vanvoorden, Ruddy A. J. Nicasy, Ravindra S. Dixit, Frederik E. Gemoets