Solid Polymer Derived From Ethylene Or Propylene Patents (Class 525/240)
  • Patent number: 9683096
    Abstract: A polypropylene impact copolymer is disclosed. The propylene impact copolymer composition comprises from 60 to 90 percent by weight of the impact copolymer composition of a matrix phase, which can be a homopolymer polypropylene or random polypropylene copolymer having from 0.1 to 7 mol percent of units derived from ethylene or C4-C10 alpha olefins. The propylene impact copolymer composition also comprises from 10 to 40 percent by weight of the impact copolymer composition of a dispersed phase, which comprises a propylene/alpha-olefin copolymer having from 6 to 40 mol percent of units derived from ethylene or C4-C10 alpha olefins, wherein the dispersed phase has a comonomer content which is greater than the comonomer content in the matrix phase. The propylene impact copolymer composition is further characterized by having the ratio of the dispersed phase intrinsic viscosity (IV) to the matrix phase IV being 0.95 or less.
    Type: Grant
    Filed: August 19, 2010
    Date of Patent: June 20, 2017
    Assignee: Braskem America, Inc.
    Inventors: John Kaarto, Alechia Crown, Li-Min Tau, Gert J. Claasen
  • Patent number: 9676883
    Abstract: The present disclosure relates to propylene-ethylene copolymers comprising an ethylene content of 0.1-10% by weight, a molecular weight distribution (MWD), expressed in terms of Mw/Mn, of greater than 3.0 and a xylene soluble (XS) fraction content defined by values that fall below the line given by the equation XS=1.0296·e0.435C2. The propylene-ethylene copolymers advantageously exhibit high transparency and low melting temperatures.
    Type: Grant
    Filed: May 6, 2015
    Date of Patent: June 13, 2017
    Assignee: Basell Poliolefine Italia S.r.l.
    Inventors: Fabrizio Piemontesi, Caroline Cathelin, Simona Guidotti, Dario Liguori, Giampiero Morini, Davide Tartari, Gianni Vitale
  • Patent number: 9670353
    Abstract: The present disclosure provides a composition comprising or obtained from a reaction mixture comprising a first propylene-based polymer, an olefin block copolymer, and a cure component. The cure component comprises (i) a second propylene/?-olefin copolymer, (ii) a scorch retardant, and (iii) a crosslinking agent.
    Type: Grant
    Filed: December 31, 2012
    Date of Patent: June 6, 2017
    Assignee: Dow Global Technologies LLC
    Inventors: Shuwen Peng, Yabin Sun, Mahalia Soediono, Shih-Yaw Lai
  • Patent number: 9670347
    Abstract: Polypropylene composition comprising comonomer units derived from ethylene in an amount of from 9.0 to 52.0 mol-% and comonomer units derived from a higher a-olefin in an amount of from 0.4 to 3.0 mol-%, wherein said polypropylene composition has an amount of xylene cold solubles of at least 30 wt.-%, wherein further the xylene cold soluble fraction has an ethylene content of from 20.0 to 80.0 mol-% and a higher a-olefin content from 0.1 to 1.5 mol-%.
    Type: Grant
    Filed: July 14, 2014
    Date of Patent: June 6, 2017
    Assignee: BOREALIS AG
    Inventors: Wilfried Töltsch, Luigi Resconi, Kristin Reichelt
  • Patent number: 9670342
    Abstract: An injection stretch blow molded article may include a Ziegler-Natta catalyzed polyethylene resin having a multimodal molecular weight distribution and including at least two polyethylene fractions A and B. Fraction A may have a higher molecular weight and a lower density than fraction B. Each fraction may be prepared in different reactors of at least two reactors connected in series. Fraction A may have a melt index HL275 of at least 11 g/10 min and of at most 20 g/10 min, and a density of at least 941 kg/m3 and of at most 946 kg/m3. The polyethylene resin may have a melt index MI2 of at least 1.5 g/10 min and of at most 3.0 g/10 min, and a density of at least 950 kg/m3 and of at most 965 kg/m3.
    Type: Grant
    Filed: August 12, 2014
    Date of Patent: June 6, 2017
    Assignee: Total Research & Technology Feluy
    Inventors: Jean-Marie Boissiere, Aurélien Vantomme, Jurjen Meeuwissen
  • Patent number: 9663647
    Abstract: A process for producing a propylene impact copolymer (ICOP), the process comprising the steps of feeding propylene and optionally one or more first comonomers into a first reactor; feeding into the first reactor a catalyst mixture; contacting the propylene with the catalyst mixture under first polymerization conditions to form an active propylene-based polymer; transferring at least a portion of the first reactor contents to a second reactor; feeding additional activity limiting agent, additional selectivity control agent and, optionally additional cocatalyst and one or more second comonomers into the second reactor; and maintaining the second reactor at a second reactor temperature in a range that is sufficient to allow copolymerization to form the propylene impact copolymer (ICOP), wherein the second reactor temperature is below 70° C.
    Type: Grant
    Filed: November 26, 2014
    Date of Patent: May 30, 2017
    Assignee: W. R. Grace & Co.-Conn.
    Inventors: Jan W. Van Egmond, Jeffrey D. Goad
  • Patent number: 9657163
    Abstract: The present invention provides a single-layer shape retaining material which is a fibrous, band-like, or sheet-like stretched formed material comprising 100 parts by weight of a high-density polyethylene resin having a weight-average molecular weight of 100,000 to 500,000 and a density of 0.945 to 0.960 g/cm3 and 3 to 50 parts by weight of an ethylene-?-olefin copolymer obtained by copolymerizing ethylene with an ?-olefin having 4 to 10 carbon atoms, the copolymer having a density of 0.935 to 0.960 g/cm3, the difference in density between the copolymer and the high-density polyethylene resin being ±0.020 g/cm3 or less and a method for producing same.
    Type: Grant
    Filed: February 26, 2015
    Date of Patent: May 23, 2017
    Assignee: SEKISUI SEIKEI, LTD.
    Inventors: Atsuhito Tadokoro, Shinichi Tokudome, Tomoyuki Hishida
  • Patent number: 9650465
    Abstract: The present invention concerns heterophasic propylene copolymers, comprising a propylene homopolymer (PPH) and an ethylene-propylene rubber (EPR), having a very broad molecular weight distribution, a well-defined total ethylene content and a specific intrinsic viscosities of the ethylene-propylene rubber (EPR). The invention further concerns the process to produce such heterophasic propylene copolymers. The heterophasic propylene copolymers of the present invention are particularly suited for pails, pallets, IBCs and crates. In particular, the heterophasic propylene copolymers of the present invention are characterized by an improved resistance to creep.
    Type: Grant
    Filed: December 18, 2008
    Date of Patent: May 16, 2017
    Assignee: Total Research & Technology Feluy
    Inventors: Kristien Roegiers, Geert Snellings, Alain Standaert
  • Patent number: 9645066
    Abstract: A method of preparing a polymer article comprising determining a zero-shear viscosity for a polymer sample; sieving the polymer sample to produce a plurality of sieved polymer samples; determining a molecular weight distribution for each of the plurality of sieved polymer samples; determining a zero-shear viscosity for each of the plurality of sieved polymer samples; determining a compositional diversity of each of the plurality of sieved polymer samples based on a ratio of the zero shear viscosity for each of the plurality of sieved polymer samples to the zero shear viscosity for the polymer sample; identifying a polymer sample having a ratio of the zero shear viscosity to zero shear viscosity for the polymer sample of from about 0.5 to equal to or greater than about 3; and preparing a polymer article from the identified polymer sample.
    Type: Grant
    Filed: December 4, 2015
    Date of Patent: May 9, 2017
    Assignee: Chevron Phillips Chemical Company LP
    Inventors: Youlu Yu, Qing Yang, Paul J. Deslauriers, Mark J. Lamborn, Yongwoo Inn
  • Patent number: 9645131
    Abstract: A method of preparing a polymer article comprising preparing a plurality of polymer samples having a lower molecular weight (LMW) component and a higher molecular weight (HMW) component; sieving each of the plurality polymer samples to produce a corresponding plurality of sieved polymer samples; determining a heterogeneity value for each of the plurality of polymer samples; identifying at least one polymer sample from the plurality of polymer samples having a predicted gel count of less than 100 gels/ft2 wherein the predicted gel count is a function of the heterogeneity value; and fabricating a film from the identified polymer sample having a predicted gel count of less than about 100 gels/ft2.
    Type: Grant
    Filed: December 4, 2015
    Date of Patent: May 9, 2017
    Assignee: Chevron Phillips Chemical Company LP
    Inventors: Paul J. Deslauriers, Jerry Stark
  • Patent number: 9644049
    Abstract: A virgin granular polymer comprising polymer particles wherein at least 90% by weight of the granular polymer particles, have an I21 that is within two standard deviations of a mean I21 of the granular polymer, the ratio of the standard deviation of I21 to the mean of the granular polymer is less than 0.2 and the ratio of the standard error of a linear fit to the mean of the granular polymer is less than 0.1, and further wherein the virgin granular polymer has an I21 less than or equal to 70 and/or further wherein at least 90% by weight of the granular polymer particles, have a density that is within two standard deviations of a mean density of the granular polymer, the ratio of the standard deviation of the mean density of the granular polymer to the mean density of the granular polymer is less than 0.002 and the ratio of the standard error of a linear fit to the mean of the density is less than 0.001, and further wherein the virgin granular polymer has an I21 less than or equal to 70 is provided.
    Type: Grant
    Filed: December 29, 2011
    Date of Patent: May 9, 2017
    Assignee: Union Carbide Chemicals & Plastics Technology LLC
    Inventor: Robert J. Jorgensen
  • Patent number: 9636895
    Abstract: A polymeric film for labeling articles comprises a core layer (A), a print skin layer (B) comprising a polypropylene homopolymer, a polypropylene copolymer, a high density polyethylene, or a mixture of any of the foregoing polymers and at least 10% by weight based on the weight of the layer (B) of a polyolefin elastomer, an alkene-unsaturated carboxylic acid or acid derivative copolymer, or a mixture of any of the foregoing polymers, and an adhesive skin layer (C) comprising a polypropylene homopolymer, where the polymeric film is oriented. An adhesive containing label stock and an adhesive label die-cut from the adhesive containing label stock comprise the polymeric film which is especially useful for pressure sensitive hot melt adhesive applications.
    Type: Grant
    Filed: June 20, 2007
    Date of Patent: May 2, 2017
    Assignee: Avery Dennison Corporation
    Inventors: Christopher J. Blackwell, Kevin O. Henderson
  • Patent number: 9631059
    Abstract: The instant invention provides a polyolefin composition suitable for packaging applications, films, multilayer structures and packaging devices made therefrom. The polyolefin composition according to the present invention comprises: an ethylene/?-olefin interpolymer composition comprising (a) from 50 to 75 percent by weight of a first ethylene/?-olefin copolymer fraction having a density in the range of 0.894 to 0.908 g/cm3, a melt index (I2) in the range of from 0.2 to 1 g/10 minutes, and (b) from 25 to 50 percent by weight of a second ethylene/?-olefin copolymer fraction, and wherein said ethylene/?-olefin interpolymer composition has a density in the range of 0.910 to 0.924 g/cm3, a melt index (I2) in the range of from 0.5 to 2 g/10 minutes, a zero shear viscosity ratio (ZSVR) in the range of from 1.15 to 2.5, a molecular weight distribution, expressed as the ratio of the weight average molecular weight to number average molecular weight (Mw/Mn) in the range of from 2.0 to 4.0, and tan delta at 0.
    Type: Grant
    Filed: December 27, 2013
    Date of Patent: April 25, 2017
    Assignee: Dow Global Technologies LLC
    Inventors: Mehmet Demirors, Mridula Kapur, Pradeep Jain, Philip P. Fontaine, Douglas S. Ginger, David T. Gillespie, Mustafa Bilgen
  • Patent number: 9624323
    Abstract: The present disclosure provides a process. In an embodiment, the process includes producing a propylene-based polymer in a gas-phase polymerization reactor (10) under polymerization conditions. The polymerization conditions include a combined propylene-plus-propane partial pressure from 290 psia to 450 psia. The process further includes maintaining the combined propylene-plus-propane partial pressure in the range from 290 psia to 450 psia while simultaneously: (i) reducing propylene partial pressure in the gas-phase polymerization reactor; (ii) adding propane to the gas-phase polymerization reactor; (iii) introducing at least one C4-C10 comonomer into the gas-phase polymerization reactor (26); and forming a propylene/C4-C10 interpolymer in the gas-phase polymerization reactor (44).
    Type: Grant
    Filed: March 13, 2014
    Date of Patent: April 18, 2017
    Assignee: W. R. Grace & Co.-Conn.
    Inventors: Sharon E. Peterson, Mark W. Blood, Theodore Duncan
  • Patent number: 9617397
    Abstract: Methods for improving the degradability of synthetic resins and/or synthetic resin mixtures and reducing the toxicity associated with the degradation process are disclosed herein with one such method involving the determination of a desired product lifespan and based on such lifespan, producing a mixture of a compatible degradation salt with a first compatible resin based on an algorithm, pre-mixing the compatible degradation inducing salt with the first synthetic resin to create a pre-mixed batch, and adding the pre-mixed batch to a second synthetic resin to create a master batch from which products may be manufactured with a known degradation timeline.
    Type: Grant
    Filed: November 25, 2013
    Date of Patent: April 11, 2017
    Inventors: Sugianto Tandio, Eman Suryana, Jon Mogck, David Melander
  • Patent number: 9593177
    Abstract: The present invention relates to a low density polyethylene having a molecular weight distribution Mw/Mn which is greater than 15, a storage modulus G? (5 kPa) which is above 3000 and a vinylidene content which is at least 15/100 k C, compositions, a process for production of the low density polyethylene, a continuous ethylene polymerization method for introducing vinylidene in a low density polyethylene, a method for an extrusion coating process, an article, e.g. an extrusion article, and use in extrusion coating.
    Type: Grant
    Filed: December 7, 2012
    Date of Patent: March 14, 2017
    Assignee: Borealis AG
    Inventors: Auli Nummila-Pakarinen, Bernt-Ake Sultan, Bjorn Voigt, Martin Anker, Mattias Bergqvist, Thomas Gkourmpis, Thomas Hjertberg
  • Patent number: 9593171
    Abstract: A porous solid catalyst component comprising a magnesium halide, a titanium compound having at least a Ti-halogen bond and at least two electron donor compounds one of which being selected from 1,3-diethers and the other being selected from succinates, characterized by the fact that the molar ratio ID/Ti is from 0.30 to 0.90, where ID is the total molar amount of succinate and 1,3-diether, the molar ratio of the 1,3-diether donor to the succinate donor is higher than, or equal to, 0.60.
    Type: Grant
    Filed: March 29, 2012
    Date of Patent: March 14, 2017
    Assignee: Basell Poliolefine Italia S.r.l.
    Inventors: Simona Guidotti, Giampiero Morini, Simona Esposito, Alessandro Mignogna, Joachim T. M. Pater, Fabrizio Piemontesi, Diego Brita
  • Patent number: 9595388
    Abstract: Polypropylene composition comprising a polypropylene and an ?-nucleating agent, wherein the polypropylene composition has • a comonomer content of equal or below 1.0 wt.- %, •<2,1> erythro regiodefects of more than 0.1 mol.- %, and • at least 9.0 wt- % of a crystalline fraction crystallizing in the temperature range of above 160 to 170° C., wherein said fraction is determined by the stepwise isothermal segregation technique (SIST).
    Type: Grant
    Filed: August 1, 2011
    Date of Patent: March 14, 2017
    Assignee: Borealis AG
    Inventors: Dietrich Gloger, Katja Klimke, Joachim Fiebig, Christelle Grein, Robert Persson
  • Patent number: 9580583
    Abstract: The present disclosure relates to a polyethylene composition with improved swell ratio and mechanical properties for use in preparing blow-moulded articles and having the following features: 1) a density from 0.945 to less than 0.952 g/cm3; 2) an MIF/MIP ratio from 15 to 30; 3) a Shear-Induced Crystallization Index (SIC) from 2.5 to 5.5.
    Type: Grant
    Filed: July 20, 2016
    Date of Patent: February 28, 2017
    Assignee: Basell Polyolefine GmbH
    Inventors: Iakovos Vittorias, Jens Wiesecke, Bernd Lothar Marczinke, Gerhardus Meier, Ulf Schüller, Volker Dolle, Johannes-Friedrich Enderle, Dieter Lilge, Barbara Gall
  • Patent number: 9574025
    Abstract: A solution polymerization process that consumes less energy comprising: injecting feeds into one or more reactors to form a polyethylene in a single liquid phase, or optionally two liquid phases; deactivating the single or dual liquid phase; a first V/L separator separates the deactivated phase into a first bottom stream and a first overhead stream; the first overhead stream passes to a distillation column and the first bottom stream enters a second V/L separator, forming a second overhead stream and a second bottom stream; the second bottom stream enters a third V/L separator, forming a third overhead stream and a third bottom stream; the third bottom stream passes to polymer recovery; the second and third overhead streams are combined, condensed and purified, forming a purified solvent that is recycled to said reactors.
    Type: Grant
    Filed: September 8, 2014
    Date of Patent: February 21, 2017
    Assignee: NOVA Chemicals (International) S.A.
    Inventors: Terri A. Price, Fazle Sibtain, Eric Cheluget
  • Patent number: 9540506
    Abstract: Propylene copolymer having a melt flow rate MFR2 (230° C.) in the range of more than 1.0 to below 2.5 g/10 min, a xylene cold soluble content (XCS) in the range of 25.0 to 35.0 wt.-%, a comonomer content in the range of more than 7.5 to 12.0 wt.-%, wherein further the xylene cold soluble (XCS) fraction of the propylene copolymer has comonomer content in the range of 16.0 to 28.0 wt.-% and an intrinsic viscosity (IV) in the range of more than 1.2 to below 2.5 dl/g.
    Type: Grant
    Filed: November 6, 2013
    Date of Patent: January 10, 2017
    Assignee: Borealis AG
    Inventors: Markus Gahleitner, Katja Klimke, Klaus Bernreitner, Martina Sandholzer
  • Patent number: 9534711
    Abstract: A single site catalysed ethylene polymer including ethylene and optionally at least one comonomer having a Mw/Mn of less than 5 and wherein the total amount of unsaturations of the ethylene polymer is at least 0.8.
    Type: Grant
    Filed: October 26, 2011
    Date of Patent: January 3, 2017
    Assignee: Borealis AG
    Inventors: Magnus Palmlöf, Espen Ommundsen, Anne Britt Bjåland, Alexander Krajete
  • Patent number: 9527994
    Abstract: An object of the present invention is to provide a methacrylic resin composition which exhibits excellent flexibility, elasticity, impact resistance, and plasticity and moldability while transparency inherent to methacrylic resins is maintained. A methacrylic resin composition to be produced is composed of 10 to 99 parts by mass of a methacrylic resin (A) containing not less than 80 mass % of a methyl methacrylate unit and 90 to 1 part by mass of a block copolymer (B) containing 10 to 60 mass % of a methyl methacrylate polymer block (b1) and 90 to 40 mass % of an acrylate polymer block (b2) and having a refractive index of 1.485 to 1.495 (the total of (A) and (B) is 100 parts by mass).
    Type: Grant
    Filed: October 24, 2011
    Date of Patent: December 27, 2016
    Assignee: KURARAY CO., LTD.
    Inventors: Hiroshi Ozawa, Toru Takahashi, Atsushi Matsumura, Kenichi Hamada, Yoshihiro Morishita, Toyoaki Kurihara
  • Patent number: 9527228
    Abstract: Even when a mixture resin of virgin resin and recovered resin material is used as a resin material for molding, a stable, high-quality foam-molded article with excellent impact resistance is produced at low cost. For this, the resin material that is used includes a mixture resin of recovered resin material obtained by pulverizing a resin material solidified after melting, and virgin resin without thermal history of melting, and a foaming agent added to the mixture resin. The resin material is a mixture of a polypropylene-based resin and a polyethylene-based elastomer.
    Type: Grant
    Filed: January 21, 2013
    Date of Patent: December 27, 2016
    Assignee: KYORAKU CO., LTD.
    Inventors: Takeru Sano, Yu Igarashi, Yuki Arita, Takashi Nomura
  • Patent number: 9512308
    Abstract: The present disclosure relates to a polyethylene composition with improved swell ratio and mechanical properties, particularly suited for preparing blow-moulded articles, said composition having the following features: 1) a density from 0.952 to 0.960 g/cm3; 2) an MIF/MIP ratio from 17 to 30; and 3) a Shear-Induced Crystallization Index SIC from 2.5 to 5.0.
    Type: Grant
    Filed: April 27, 2016
    Date of Patent: December 6, 2016
    Assignee: Basell Polyolefine GmbH
    Inventors: Iakovos Vittorias, Jens Wiesecke, Bernd Lothar Marczinke, Gerhardus Meier, Ulf Schüller, Volker Dolle, Johannes-Friedrich Enderle, Dieter Lilge, Barbara Gall
  • Patent number: 9512282
    Abstract: This disclosure relates to ethylene interpolymer compositions. Specifically, ethylene interpolymer products having: a Dilution Index (Yd) greater than 0; total catalytic metal?3.0 ppm; ?0.03 terminal vinyl unsaturations per 100 carbon atoms, and; optionally a Dimensionless Modulus (Xd) greater than 0. The disclosed ethylene interpolymer products have a melt index from about 0.3 to about 500 dg/minute, a density from about 0.869 to about 0.975 g/cm3, a polydispersity (Mw/Mn) from about 2 to about 25 and a CDBI50 from about 20% to about 97%. Further, the ethylene interpolymer products are a blend of at least two ethylene interpolymers; where one ethylene interpolymer is produced with a single-site catalyst formulation and at least one ethylene interpolymer is produced with a heterogeneous catalyst formulation.
    Type: Grant
    Filed: October 21, 2015
    Date of Patent: December 6, 2016
    Assignee: NOVA Chemicals (International) S.A.
    Inventors: Tieqi Li, XiaoChuan Wang, Christopher John Brooke Dobbin, Fazle Sibtain, Kenneth Edward Taylor, Hamidreza Khakdaman
  • Patent number: 9505892
    Abstract: This disclosure relates to manufactured articles containing ethylene interpolymers. Specifically, films, containers and lids comprising at least one layer of an ethylene interpolymer product, or a blend containing an ethylene interpolymer product, where the ethylene interpolymer product has: a Dilution Index (Yd) greater than 0; total catalytic metal ?3.0 ppm; ?0.03 terminal vinyl unsaturations per 100 carbon atoms, and; optionally a Dimensionless Modulus (Xd) greater than 0. The ethylene interpolymer products have a melt index from about 0.4 to about 100 dg/minute, a density from about 0.950 to about 0.970 g/cm3, a polydispersity (Mw/Mn) from about 2 to about 25 and a CDBI50 from about 55% to about 97%. Further, the ethylene interpolymer products are a blend of at least two ethylene interpolymers; where one ethylene interpolymer is produced with a single-site catalyst formulation and at least one ethylene interpolymer is produced with a heterogeneous catalyst formulation.
    Type: Grant
    Filed: October 21, 2015
    Date of Patent: November 29, 2016
    Assignee: NOVA Chemicals (International) S.A.
    Inventors: Patrick Lam, Tieqi Li, XiaoChuan Wang, Christopher John Brooke Dobbin, Fazle Sibtain, Kenneth Edward Taylor, Hamidreza Khakdaman
  • Patent number: 9505893
    Abstract: This disclosure relates to caps and closures manufactured from an ethylene interpolymer product, or a blend containing an ethylene interpolymer product, where the ethylene interpolymer product has: a Dilution Index (Yd) greater than 0; total catalytic metal ?3.0 ppm; ?0.03 terminal vinyl unsaturations per 100 carbon atoms, and; optionally a Dimensionless Modulus (Xd) greater than 0. The ethylene interpolymer products have a melt index from about 0.4 to about 20 dg/minute, a density from about 0.948 to about 0.968 g/cm3, a polydispersity (Mw/Mn) from about 2 to about 25 and a CDBI50 from about 54% to about 98%. Further, the ethylene interpolymer products are a blend of at least two ethylene interpolymers; where one ethylene interpolymer is produced with a single-site catalyst formulation and at least one ethylene interpolymer is produced with a heterogeneous catalyst formulation.
    Type: Grant
    Filed: October 21, 2015
    Date of Patent: November 29, 2016
    Assignee: NOVA Chemicals (International) S.A.
    Inventors: XiaoChuan Wang, Tieqi Li, Christopher John Brooke Dobbin, Fazle Sibtain, Kenneth Edward Taylor, Hamidreza Khakdaman
  • Patent number: 9487606
    Abstract: Propylene copolymer having a melt flow rate MFR2 (230° C.) in the range of more than 0.8 to below 2.5 g/10 min, a xylene cold soluble content (XCS) in the range of 25.0 to 35.0 wt.-%, a comonomer content in the range of more than 4.5 to 10.0 wt.-%, wherein further the xylene cold soluble (XCS) fraction of the propylene copolymer has comonomer content in the range of 12.0 to 22.0 wt.-% and the xylene cold insoluble (XCI) fraction of the propylene copolymer has a Mw/Mn of more than 4.9 to 10.0.
    Type: Grant
    Filed: November 6, 2013
    Date of Patent: November 8, 2016
    Assignee: Borealis, AG
    Inventors: Markus Gahleitner, Katja Klimke, Klaus Bernreitner, Martina Sandholzer
  • Patent number: 9481772
    Abstract: Film formed from a polyethylene composition having a density of 948-956 kg/m3, a high load melt index HLMI of 7-15 and a melt storage modulus G? at a dynamic frequency where the loss modulus G?=3000 Pa. G?(G?=3000) of 1400-1800 Pa. The composition has a value of Mz/G?(G?=3000) of at least 900 DA/PA, where Mz is z-average molecular weight.
    Type: Grant
    Filed: June 25, 2013
    Date of Patent: November 1, 2016
    Assignee: INEOS EUROPE AG
    Inventor: Isabelle Cermelli
  • Patent number: 9464148
    Abstract: Vinyl terminated polyolefins with long chain branching produced with Salan catalysts having carbazole moieties.
    Type: Grant
    Filed: May 1, 2015
    Date of Patent: October 11, 2016
    Assignees: ExxonMobil Chemical Patents Inc., Ramot at Tel-Aviv University Ltd.
    Inventors: Garth R. Giesbrecht, Matthew W. Holtcamp, Moshe Kol
  • Patent number: 9458312
    Abstract: Polyethylene composition with improved balance of environmental stress cracking resistance (FNCT) and impact resistance (Charpy), particularly suited for preparing pipes, said composition having the following features: 1) density from 0.945 to 0.955 g/cm3; 2) ratio MIF/MIP from more than 30 to 45; 3) Shear-Induced Crystallization Index SIC from 1.0 to 2.5; 4) Long Chain Branching index equal to or greater than 0.85.
    Type: Grant
    Filed: October 22, 2013
    Date of Patent: October 4, 2016
    Assignee: Basell Polyolefine GmbH
    Inventors: Iakovos Vittorias, Jens Wiesecke, Bernd Lothar Marczinke, Gerhardus Meier, Ulf Schüller, Volker Dolle, Johannes-Friedrich Enderle, Dieter Lilge, Barbara Gall
  • Patent number: 9447206
    Abstract: The present invention relates to a process for the preparation of ethylene polymers using a number of reactors arranged in series comprising the steps in which a) ethylene, a diluent, a catalyst, a co-catalyst and optionally comonomers and hydrogen are introduced into a first reactor, b) polymerization of ethylene and optionally comonomers is carried out in the reaction mixture of said first reactor to make ethylene polymers, c) reaction mixture is discharged from said first reactor, d) said reaction mixture and fresh ethylene and optionally comonomers and hydrogen are introduced into the consecutive reactor to make additional ethylene polymers, e) said reaction mixture is discharged from said consecutive reactor and introduced into the further consecutive reactor, if any, with fresh ethylene and optionally comonomers and hydrogen to make additional ethylene polymers, steps c) and d) are repeated until the last reactor of the series, f) reaction mixture is discharged from last reactor of the series and ethyl
    Type: Grant
    Filed: March 29, 2007
    Date of Patent: September 20, 2016
    Assignee: Total Research & Technology Feluy
    Inventors: Mieke Dams, Daniel Siraux
  • Patent number: 9434806
    Abstract: A method is provided for producing a propylene polymeric material containing a propylene polymer component high in content of ?-olefin units. The material can be produced stably without stopping of the operation due to clogging of a pipe. The method is one for producing a propylene polymeric material composed of a propylene polymer component (A) and a propylene polymer component (B) via at least two steps, including a first step of producing the component (A) and a second step of producing the component (B) in a gas phase. The partial pressure of the ?-olefin having four or more carbon atoms in the gas phase in the second step reactor is 0.10 MPa or more. A formula, X?0.0025×Y+0.2850, is satisfied, wherein the partial pressure is X MPa, and the content of the propylene polymer component (A) in the propylene polymeric material is Y % by weight.
    Type: Grant
    Filed: August 27, 2015
    Date of Patent: September 6, 2016
    Assignee: Sumitomo Chemical Company, Limited
    Inventor: Satoshi Itoguchi
  • Patent number: 9428623
    Abstract: Polyethylene composition with improved swell ratio and mechanical properties, particularly suited for preparing blow-molded articles, said composition having the following features: 1) density from 0.945 to less than 0.952 g/cm3; 2) ratio MIF/MIP from 15 to 30; 3) Shear-Induced Crystallization Index SIC from 2.5 to 5.5.
    Type: Grant
    Filed: October 22, 2013
    Date of Patent: August 30, 2016
    Assignee: Basell Polyolefine GmbH
    Inventors: Iakovos Vittorias, Jens Wiesecke, Bernd Lothar Marczinke, Gerhardus Meier, Ulf Schüller, Volker Dolle, Johannes-Friedrich Enderle, Dieter Lilge, Barbara Gall
  • Patent number: 9428657
    Abstract: A radical polymerizable composition includes a siloxane compound represented by a formula (HO)2(R)Si.O[—Si(R)(OH).O-]n-Si(R)(OH)2 in which R represents a methacryloyl group; and n represents 0 or 1; and a monomer having a viscosity lower than that of the siloxane compound.
    Type: Grant
    Filed: May 4, 2015
    Date of Patent: August 30, 2016
    Assignee: Ricoh Company, Ltd.
    Inventor: Takao Hiraoka
  • Patent number: 9422497
    Abstract: This disclosure relates to vinyl terminated macromer (VTM) based synthetic basestocks and their methods of preparation, lubricant compositions, methods of lubrication and products so lubricated. The VTM based synthetic basestocks useful for fuels and lubricants include oligomerization or polymerization products of one or more allylic vinyl terminated macromers (VTMs) having a molecular weight from 84 to 10080. The one or more allylic VTMs are oligomerized or polymerized in the presence of a catalyst under oligomerization or polymerization conditions sufficient to give the VTM based synthetic basestock. The catalyst can be a metallocene catalyst or an acid catalyst, e.g., Lewis acid. The one or more allylic vinyl terminated macromers (VTMs) can be one or more allylic vinyl terminated atactic polypropylene macromers (VTM aPP) having a molecular weight from 84 to 2250 and having a terminal allylic vinyl olefin content of at least 90%.
    Type: Grant
    Filed: September 4, 2013
    Date of Patent: August 23, 2016
    Assignee: ExxonMobil Research and Engineering Company
    Inventors: Abhimanyu Onkar Patil, Satish Bodige
  • Patent number: 9422385
    Abstract: This invention relates to polyethylene copolymers comprising ethylene and vinyl terminated macromonomers. The polyethylene copolymers are achieved by copolymerization of ethylene and vinyl terminated macromonomers in a polymerization reactor, particularly in high yields and with a wide range of VTM molecular weights, that can be made at commercial rates.
    Type: Grant
    Filed: January 17, 2014
    Date of Patent: August 23, 2016
    Assignee: ExxonMobil Chemical Patents Inc.
    Inventor: Peijun Jiang
  • Patent number: 9416201
    Abstract: Mixtures of different polyolefins may be made by direct, preferably simultaneous, polymerization of one or more polymerizable olefins using two or more transition metal containing active polymerization catalyst systems, at least one of which contains cobalt or iron complexed with selected ligands. The polyolefin products may have polymers that vary in molecular weight, molecular weight distribution, crystallinity, or other factors, and are useful as molding resins and for films.
    Type: Grant
    Filed: January 28, 2011
    Date of Patent: August 16, 2016
    Assignee: E I DU PONT DE NEMOURS AND COMPANY
    Inventors: Alison Margaret Anne Bennett, Edward Bryan Coughlin, Joel David Citron
  • Patent number: 9416263
    Abstract: Propylene random copolymer composition containing (A) 60-85 wt % of a copolymer of propylene and from 0.1 to 2 wt % of units derived from ethylene and having a melt flow rate value according to ISO 1130 (230° C., 2.16 kg) of from 80 to 200 g/10 min; and (B) 15-40 wt % of a copolymer of propylene and from 7 to 17 wt % of units derived from ethylene. The composition has a total ethylene content of from 3 to 4.5 wt %, and a melt flow rate value according to ISO 1133 (230° C., 2.16 kg) of greater than 60 to 150 g/10 min, the composition having not been subject to any form of post-reactor treatment which increases its melt flow rate by more than 5 g/10 min.
    Type: Grant
    Filed: September 17, 2013
    Date of Patent: August 16, 2016
    Assignee: INEOS EUROPE AG
    Inventor: Jean-Marc Roland Ghislain Vion
  • Patent number: 9382454
    Abstract: A paint film-protecting sheet (1) that effectively prevents adhesive transfer to the paint film is provided. The paint film-protecting sheet (1) includes a pressure-sensitive adhesive (PSA) layer (20), which is comprised of a non-crosslinking PSA, disposed on a polyolefin-based resin film serving as a supporting substrate (10). At least a surface portion (12) of the supporting substrate which adjoins the PSA layer is formed of a resin material that satisfies both of the following conditions: (1) it contains W wt % of a LLDPE having a density d of 0.925 g/cm3 or less, wherein W is greater than or equal to 20; and (2) it has a LLDPE content index ? of 400 or more, the LLDPE content index ? being defined as (0.935?d)×W×1000.
    Type: Grant
    Filed: November 22, 2010
    Date of Patent: July 5, 2016
    Assignees: NITTO DENKO CORPORATION, KANSAI PAINT CO., LTD.
    Inventors: Toshitaka Suzuki, Takeshi Igarashi, Hiroko Ikenaga, Yuki Saitou, Shinji Inokuchi, Koji Yamaguchi, Yoshikuni Hirano
  • Patent number: 9376513
    Abstract: Disclosed is a solid catalyst component for olefin polymerization. The catalyst component comprises a dialkoxy magnesium carrier, a titanium compound, and a product from an internal electron donor reacting in an inert solvent. The internal electron donor compound comprises a 2,3-di-non-linear-alkyl-2-cyano succinic acid diester compound as presented in formula I.
    Type: Grant
    Filed: January 19, 2012
    Date of Patent: June 28, 2016
    Assignees: China Petroleum & Chemical Corporation, Beijing Research Institute of Chemical Industry, China Petroleum & Chemical Corporation
    Inventors: Zhong Tan, Lunjia Xie, Xiudong Xu, Yu Tian, Qilong Zhou, Zaixing Feng, Li'an Yan, Siyuan Zhao, Jinhua Yu, Zhufang Sun, Fengkui Li, Shanshan Yin, Weiwei Song
  • Patent number: 9353283
    Abstract: The present invention relates to an article coated with a composition comprising (A) an ethylene homo- or copolymer resin which has been prepared by using a single-site catalyst further characterized in that component (A) has an MFR21, measured according to ISO 1133 at 190° C. and under a load of 21.6 kg, from 0.01 to 20 g/10 min. The present invention further relates to an article coated with a composition comprising (A) an ethylene homo- or copolymer resin which has been prepared by using a single-site catalyst further characterized in that component (A) has an impact strength at ?40° C. of at least 80 kJ/m2 in a Charpy notched test according to ISO ISO 179-1/1eA:2000 with a pendulum energy of 15 J. The invention is furthermore directed to the use of the composition for the coating of an article.
    Type: Grant
    Filed: November 25, 2009
    Date of Patent: May 31, 2016
    Assignee: BOREALIS AG
    Inventors: Björn Voigt, Martin Anker, Magnus Palmlöf, Solveig Johansson
  • Patent number: 9336927
    Abstract: A halogen-free, flame retardant composition comprises: A. A polymer blend comprising: 1. Polypropylene, and 2. Thermoplastic elastomer (TPE) other than the polypropylene of (A)(1), and B. An intumescent flame retardant comprising at least one of: 1. A compound of Formula 1 where M is at least one of melamine, morpholine, piperazine, piperidine, alkyl hydroxyl and a triazine polymer of Formula 2 where D is a heterocyclic or polyamine moiety, and m and n are independently integers the sum (m+n) of which is less than 1000, and 2. A piperazine phosphate.
    Type: Grant
    Filed: December 17, 2010
    Date of Patent: May 10, 2016
    Assignee: Dow Global Technologies LLC
    Inventors: Yabin Sun, Journey Lu Zhu, David Hong Fei Guo, Xiangyang Tai, Yurong Cao, Xiaorong A. He, Leon Bin Li
  • Patent number: 9334374
    Abstract: Polymer blends of polypropylene homopolymer and propylene-?-olefin interpolymer. Processes for producing polymeric compositions comprising control-cooling heated blends of polypropylene and propylene-?-olefin interpolymer. Such polymeric compositions can be employed in forming coated wires and cables.
    Type: Grant
    Filed: February 22, 2013
    Date of Patent: May 10, 2016
    Assignees: Dow Global Technologies LLC, Dow Chemical Company Limited, University of Southhampton, GnoSys Global Ltd.
    Inventors: Simon Sutton, Theo E. Geussens, Alun Vaughan, Gary Stevens
  • Patent number: 9322175
    Abstract: A mixture comprising a bitumen (A), and a polymer composition (B) comprising the following components, all percent amounts being by weight: I) from 1 to 30% of a butene-1 polymer having a Melt Flow Rate (MFR), measured according to ASTM D 1238, at 190° C./2.16 kg, from 0.1 to 1000 g/10 min.; and II) from 70 to 99% of a heterophasic polyolefm composition comprising the following polymer fractions: a) 4-45% of a propylene homopolymer or copolymer; b) 0-20% of a of a copolymer fraction containing ethylene, insoluble in xylene at room temperature; c) 40-95% of a copolymer of ethylene with propylene and/or a CH2?CHR ?-olefin, where R is a C2-C8 alkyl radical, containing ethylene in a quantity lower than 40% and being soluble in xylene at room temperature.
    Type: Grant
    Filed: October 22, 2008
    Date of Patent: April 26, 2016
    Assignee: Basell Poliolefine Italia S.r.l.
    Inventor: Gian Luigi Rigosi
  • Patent number: 9321865
    Abstract: Resins suitable for rotomolded articles comprise a bimodal polyethylene copolymer comprising from 0.1 to 5 weight % of one or more C6-8 alpha olefins and the balance ethylene, comprising from 20 to 50 weight % of a higher molecular weight polymer component having an Mw greater than 120,000 and correspondingly from 80 to 50 weight % of a lower molecular weight polymer component having an Mw less than 100,000 having a density greater than 0.942 g/cc [but less than 0.965 g/cc] and a bent strip ESCR as determined by ASTM D 1693 in 100% Igepal® CO-630 (ethoxylated nonylphenols) for conditions A and B of greater than 1000 hours. The resulting articles have a very good balance of properties and significant ESCR.
    Type: Grant
    Filed: September 4, 2015
    Date of Patent: April 26, 2016
    Assignee: NOVA Chemicals (International) S.A.
    Inventors: Celine Bellehumeur, Yves Lacombe, Mark Hoidas
  • Patent number: 9309396
    Abstract: A thermoplastic vulcanizate composition comprising from 5 wt % to 95 wt %, based on the total weight of the thermoplastic vulcanizate composition, of a first component comprising a first propylene-based polymer selected from the group consisting of (i) propylene/?-olefin copolymers comprising from 1 to 20 wt % ?-olefin and characterized by a g? ratio of less than 1, measured at interpolymer number average molecular weight (Mn), an MFR (2.16 kg @ 230° C.) greater than or equal to 0.01, a density greater than or equal to 0.850 g/cc, and a molecular weight distribution, Mw/Mn, less than or equal to 3.5, and (ii) combinations thereof; and from 5 wt % to 95 wt %, based on the total weight of the thermoplastic vulcanizate composition, of a second component selected from the group consisting of curable or vulcanizable rubbers, having a density from 0.85 to 0.88 g/cc, I2 from 0.
    Type: Grant
    Filed: December 30, 2010
    Date of Patent: April 12, 2016
    Assignee: Dow Global Technologies LLC
    Inventors: Yabin Sun, Morgan M. Hughes, Xiangyang Tai, Arnis U. Paeglis, Gary R. Marchand
  • Patent number: 9309340
    Abstract: An object of the present invention is to provide a polyethylene-based resin composition excellent in the moldability and at the same time, excellent in the balance between impact strength and stiffness as well as in the transparency, and a molded product and a film, which are obtained by the molding of the polyethylene-based resin composition. The polyethylene-based resin composition of the present invention comprises from 41 to 99 wt % of (A) an ethylene-based polymer satisfying specific conditions and from 1 to 59 wt % of (B) an ethylene-based polymer satisfying specific conditions, wherein MFR of the composition as a whole is from 0.05 to 50 g/10 min and the density is from 0.910 to 0.960 g/cm3.
    Type: Grant
    Filed: March 29, 2012
    Date of Patent: April 12, 2016
    Assignee: JAPAN POLYETHYLENE CORPORATION
    Inventors: Yoshiyuki Ishihama, Ryousuke Asakawa, Tsutomu Sakuragi, Tetsurou Fukuda, Kazuya Sakata, Masaru Aoki, Kenji Kawagishi, Keiichi Yoshimoto
  • Patent number: 9309337
    Abstract: Provided are blends of branched hydrocarbon comb polymers having tailored branching and molecular weight parameters, with substantially linear polymers. Such blends have been found to have improved extensional rheological properties, while maintaining nearly the viscosity of the substantially linear polymers. The blends of the hydrocarbon comb polymers with the substantially linear polymers thus maintain the extrusion processing characteristics of the linear polymer alone, but have improved extensional flow processability, with strain hardening ratios (SHR) greater than 1. The blends are effective in blown film processing. Also disclosed are related methods for improving extensional flow processability using the branched hydrocarbon comb polymers, as well as the branched hydrocarbon comb polymers themselves, including as a property enhancing additive for such substantially linear polymers.
    Type: Grant
    Filed: April 2, 2013
    Date of Patent: April 12, 2016
    Assignee: EXXONMOBIL RESEARCH AND ENGINEERING COMPANY
    Inventors: Johannes Matthieu Soulages, David John Lohse, Andy Haishung Tsou, Thomas Sun, Pamela Jean Wright, Nikos Hadjichristidis, Pradeep Pandurang Shirodkar