Ester Contains An Oxygen Atom Other Than As A Carboxylic Acid Ester Group Patents (Class 525/303)
  • Patent number: 5461087
    Abstract: A UV curable adhesive composition contains a C4 to C14 alkyl alcohol-acrylic acid ester monomer and a monofunctional oligoester acrylate. The composition is cured with UV rays to produce an adhesive the glass transition temperature of which is to be lower than -20.degree. C. Preferably, the composition also contains glass powders and/or polyolefin powders. A double-face adhesive tape includes two porous base sheets in an adhesive layer produced on curing a UV curable adhesive composition.
    Type: Grant
    Filed: July 29, 1993
    Date of Patent: October 24, 1995
    Assignee: Sony Corporation
    Inventors: Satoshi Takahashi, Ikuo Mitushima
  • Patent number: 5455306
    Abstract: An aqueous coating composition constitutes an aqueous graft copolymer and an amino resin, the graft copolymer being obtained by neutralizing, with a base, the carboxyl groups of a copolymer which is obtained by copolymerizing the following components (a), (b), (c) and (d) and which contains 3-30% of component (a), 3-20% of component (b), 5-40% of component (c) and 10-89% of component (d):(a) a radical-polymerizable compound, preferably a macromolecular monomer which is a copolymer of a hydroxyalkyl (meth)acrylate and another .alpha.,.beta.-ethylenically unsaturated monomer, having a radical-polymerizable group at one end,(b) an .alpha.,.beta.-ethylenically unsaturated carboxylic acid,(c) a hydroxyalkyl (meth)acrylate, and(d) another vinyl monomer.
    Type: Grant
    Filed: February 28, 1994
    Date of Patent: October 3, 1995
    Assignee: Toagosei Chemical Industry Co., Ltd.
    Inventors: Yoshio Mori, Shiro Kojima
  • Patent number: 5453458
    Abstract: There is disclosed a core-shell polymer which comprises:(a) a core layer polymerized from a core forming monomer mainly comprising an aromatic monovinyl monomer; and(b) a shell layer polymerized from a shell forming monomer which comprises:(b1) 25-95% by weight of an aromatic monovinyl monomer as a first monomer;(b2) 5-40% by weight of at least one monomer selected from the group consisting of an .alpha., .beta.-ethylenically unsaturated carboxylic acid and a hydroxyalkyl ester of .alpha., .beta.-ethylenically unsaturated carboxylic acid as a second monomer; and(b3) 0-70% by weight of a third monomer which is other than the first and second monomers and is copolymerizable therewith,wherein the shell layer is contained in an amount of 5-70% by weight based on the core-shell polymer, and the core-shell polymer having a weight average particle size of 0.1-50 micrometers.There is further disclosed a plastisol which comprises the core-shell polymer dispersed in a liquid plasticizer.
    Type: Grant
    Filed: May 13, 1994
    Date of Patent: September 26, 1995
    Assignee: Takeda Chemical Industries, Ltd.
    Inventors: Hiroshi Takeuchi, Susumu Okatani, Junji Oshima
  • Patent number: 5438099
    Abstract: Abstract of the disclosure: A particulate graft copolymer comprises 30 to 90% by weight of at least one elastomeric grafting base A having a weight average particle size of from 30 to 1,000 nm comprising, based on A, 85 to 99.8% by weight of at least one alkyl acrylate A11 having 1 to 8 carbon atoms in the alkyl radical, 0.1 to 5% by weight of at least one polyfunctional, crosslinking monomer A12, and 0.1 to 10% by weight of at least one hydroxyalkyl acrylate or hydroxyalkyl methacrylate A13 or at least 50% by weight of one or more dienes A111, up to 50% by weight of one or more ethylenically unsaturated monomers A112, and 0.1 to 10% by weight of at least one hydroxyalkyl acrylate or hydroxyalkyl methacrylate A113 and10 to 70% by weight of a graft sheath B comprising, based on B, up to 99.9% by weight of at least one aromatic vinyl monomer B1, up to 99.9% by weight of at least one polar, copolymerizable, ethylenically unsaturated monomer B2, and 0.
    Type: Grant
    Filed: December 13, 1993
    Date of Patent: August 1, 1995
    Assignee: BASF Aktiengesellschaft
    Inventors: Wolfgang Fischer, Norbert Guentherberg
  • Patent number: 5430107
    Abstract: A binding-agent composition for coating agents which can be cured at low temperature contains:A. 4-72% by weight of an acidic CH-compound, obtained by transesterification of an aliphatic .beta.-ketocarboxylic acid ester with one or several monomers and/or polymers containing hydroxyl groups and which contain at least two hydroxyl groups in the molecule,B. 4-72% by weight of an .alpha.,.beta.-unsaturated compound with at least two groups of the general formulaR.sub.1 R.sub.2 C.dbd.CR.sub.3 --CO--attached via the residue of a divalent or polyvalent alcohol, a diamine or polyamine or amino alcohol to at least one additional R.sub.1 R.sub.2 C.dbd.CR.sub.3 --CO--group, where R.sub.1, R.sub.2 and R.sub.3 independently of each other are a hydrogen atom or a straight or branched alkyl residue with 1 to 10 carbon atoms,C. 10-80% by weight of one or several polyamines with, by way of curing agents, at least two amine functions, which can be primary and/or secondary and can be blocked, in the molecule, andD. 0.
    Type: Grant
    Filed: April 29, 1994
    Date of Patent: July 4, 1995
    Assignee: Herberts GmbH
    Inventors: Klaus Bederke, Hermann Kerber, Walter Schubert, Thomas Brock, Helmut Loffler
  • Patent number: 5424370
    Abstract: Disclosed are polymer having antistatic properties and having a multilayered structure comprising an innermost layer, a second layer, a third layer and an outermost layer; processes for preparing the multilayered polymer; and an antistatic resin composition comprising a thermoplastic resin and the multilayered polymer.
    Type: Grant
    Filed: February 1, 1994
    Date of Patent: June 13, 1995
    Assignee: Sumitomo Chemical Company, Ltd.
    Inventors: Kanki Matsumoto, Shinji Date
  • Patent number: 5424369
    Abstract: A self-crosslinking resin comprising a resin containing a blocked isocyanate group, and a resin containing a hydroxyl group, and a tertiary amino group and/or a quaternary ammonium group and attached to the resin by a urethane bond.The self-crosslinking resins are useful for adhesive compositions and coating compositions of the aqueous type.
    Type: Grant
    Filed: June 17, 1992
    Date of Patent: June 13, 1995
    Assignee: Kansai Paint Company, Limited
    Inventors: Yoshiyuki Yukawa, Motoshi Yabuta, Yasushi Nakao
  • Patent number: 5416162
    Abstract: A method for making compatibilizer for a concentrated viscosity index improving polymer blend includes polymerizing a mixture of (meth)acrylate monomers in the presence of a polyolefin polymer. A concentrated blend of viscosity index improving polymers includes a non-nitrogenous dispersant poly(meth)acrylate copolymer, a polyolefin copolymer, the compatibilizer and a hydrocarbon diluent.
    Type: Grant
    Filed: September 20, 1993
    Date of Patent: May 16, 1995
    Assignee: Rohm and Haas Company
    Inventors: Robert H. Gore, Chung Y. Lai
  • Patent number: 5412038
    Abstract: A process for crosslinking a polymer containing hydroxyl groups which process comprises:(a) forming a mixture of said polymer and crosslinking amount of a poly(alpha, beta-alkenylcarboxylate), and(b) maintaining the mixture at conditions under which the polymer cures by reaction of the hydroxyl groups of the polymer with the poly(alpha, beta-alkenylcarboxylate) to produce a crosslinked polymer.
    Type: Grant
    Filed: June 28, 1993
    Date of Patent: May 2, 1995
    Assignee: Union Carbide Chemicals & Plastics Technology Corporation
    Inventors: Rex E. Murray, Robert F. Eaton, Thomas A. Upshaw, James W. Taylor, David R. Bassett, David M. Lincoln
  • Patent number: 5409967
    Abstract: Impact modifiers which produce transparent, high notched Izod impact strength blends with amorphous, aromatic polyesters are described. The impact modifiers are core-shell polymers with cores comprised mainly of rubbery polymers of diolefins and vinyl aromatic monomers and shells comprised mainly of styrene copolymers (e.g. styrene and hydroxyalkyl (meth)acrylate).
    Type: Grant
    Filed: March 22, 1994
    Date of Patent: April 25, 1995
    Assignee: Rohm and Haas Company
    Inventors: William G. Carson, Choung-Houng Lai, Edward J. Troy
  • Patent number: 5409776
    Abstract: A multi-shell emulsion particle of dry state structure having one or more of penetrating pore(s) connecting the surface layer of the particle with the interior of the particle and having a particle diameter of from 0.1 to 5.0.mu. preferably from 0.1 to 1.2.mu..
    Type: Grant
    Filed: February 1, 1994
    Date of Patent: April 25, 1995
    Assignee: Mitsui Tomatsu Chemicals, Incorporated
    Inventors: Kousuke Someya, Akihiro Yamazaki, Futoshi Hoshino, Takeshi Yanagihara
  • Patent number: 5403894
    Abstract: Redispersible polymer powders made by core-shell polymers having an alkali-soluble emulsion polymer shell and an aqueous-insoluble emulsion polymer core wherein the core and the shell polymers are chemically grafted by utilizing a polyfunctional compound. The core-shell polymers are produced by a two-stage sequential emulsion polymerization process in which an alkali-insoluble emulsion polymer core is polymerized in the presence of an alkali-solubilized emulsion polymer. When the core-shell polymer powders of this invention are employed as a cement modifier, improvements in the powder physical properties and cement mortar properties are realized.
    Type: Grant
    Filed: July 11, 1991
    Date of Patent: April 4, 1995
    Assignee: Rohm and Haas Company
    Inventors: Min-Chi Tsai, George A. Papsin, Jr., Shang-Jaw Chiou
  • Patent number: 5399611
    Abstract: This invention relates to novel hydroxy-functional polyester diluents, and more particularly, to acrylic-modified hydroxy-functional polyester reactive diluents useful for blending with a variety of thermosetting or thermoplastic film-forming polymers. More specifically, the hydroxy-functional polyester reactive diluents are essentially low molecular weight polyesters derived from triols, and a combination of unsaturated monocarboxylic acids and saturated monocarboxylic acids. These hydroxy-functional polyester diluents may be copolymerized with one or more acrylic monomers, i.e. hydroxy-functional acrylic monomers, and blended with a variety of thermosetting or thermoplastic film-forming polymers. These blends of the film-forming polymers and the hydroxy-functional polyester diluents can be crosslinked with conventional crosslinking agents such as isocyanates and used in the formulation of low VOC paint compositions particularly useful as automotive topcoats.
    Type: Grant
    Filed: September 27, 1993
    Date of Patent: March 21, 1995
    Assignee: The Sherwin-Williams Company
    Inventor: John Mathai
  • Patent number: 5391631
    Abstract: A vinyl polymer is obtainable by polymerizing vinyl monomers in at least two stages by a procedure in which, in a first stage, from 5 to 95% by weight of vinyl monomers are polymerized in an organic solvent or in the absence of a solvent and, in the second stage, from 5 to 95% by weight of the vinyl monomers are polymerized in the presence of the vinyl polymer obtained in the first stage, likewise in an organic solvent or in the absence of a solvent, with the proviso that the polymerization in the second stage is carried out under conditions under which an average molecular weight M.sub.n, which is at least 1,000 higher compared with that of the vinyl polymer, the first stage of results for the vinyl monomers of the second stage in the absence of the vinyl polymer obtained in the first stage.
    Type: Grant
    Filed: May 27, 1993
    Date of Patent: February 21, 1995
    Assignee: BASF Aktiengesellschaft
    Inventors: Bettina Porsch, Hans Renz
  • Patent number: 5385676
    Abstract: A method of dewatering paint spray booth sludge by adding to the water system of a paint spray booth a water soluble graft copolymer having the structure: ##STR1## wherein E is the repeat unit obtained after polymerization of an, ethylenically unsaturated compound, the molar percentage of a:b is from about 95:5 to 5:95, with the proviso that the sum of a and b equals 100%; G comprises the structure: ##STR2## wherein d is a cationic monomer, R.sub.1, R.sub.2 and R.sub.3 are the same or different and are hydrogen or a lower alkyl group having C.sub.1 to C.sub.3, F is the salt of an ammonium cation and the molar percentage of c:d is from 95:5 to 5:95 with the proviso that the sum of c and d equals 100%.
    Type: Grant
    Filed: August 3, 1993
    Date of Patent: January 31, 1995
    Assignee: Betz Laboratories, Inc.
    Inventors: Wen P. Liao, Deborah L. Purnell
  • Patent number: 5382634
    Abstract: The object of the present invention is to provide such a polyolefin that only the terminal of polypropylene or ethylene-propylene random copolymer is modified with a (meth)acrylic derivative unit to give a substantially monodipersed system. The feature thereof consists in such a polyolefin that the terminal of polypropylene or ethylene-propylene random copolymer obtained by living polymerization is modified with a (meth)acrylic derivative unit. As the (meth)acrylic derivative, there are used vinyl methacrylate, allyl methacrylate, trimethylsiloxyethyl methacrylate, 2-trimethylsiloxypropyl methacrylate, N, N-dimethylaminoethyl methacrylate, N,N-diethylaminoethyl methacrylate, glycidyl methacrylate, acrylic acid chloride and like.
    Type: Grant
    Filed: April 25, 1994
    Date of Patent: January 17, 1995
    Assignee: Tonen Corporation
    Inventors: Naomi Koyama, Miyuki Usui, Hiroyuki Furuhashi, Satoshi Ueki
  • Patent number: 5382633
    Abstract: A modified polymer is described comprising a thermoplastic polymer composition comprising a graft copolymer between (1) a preformed thermoplastic polymer and (2) a monomer composition comprising (a) at least one polymerisable monomer containing a polymerisable group and at least one functional polymer-modifying group and (b) at least one comonomer containing at least two polymerisable groups, said copolymer being substantially free of unbound monomer. Such polymers can be produced by reacting together, in a melt and in the presence of free radicals whilst applying shear to the melt, the preformed thermoplastic polymer to be modified, the polymerisable monomer, and the comonomer, thereby to graft said monomer to said preformed polymer leaving substantially no unbound monomer, the reaction being continued for a period of time sufficient to produce a graft copolymer that is thermoplastic and can be blended with an unmodified polymer. A free radical generator can be added, if desired.
    Type: Grant
    Filed: April 8, 1991
    Date of Patent: January 17, 1995
    Assignee: 3i Research Exploitation Limited
    Inventors: Gerald Scott, Sahar Al-Malaika
  • Patent number: 5374336
    Abstract: A water soluble graft copolymer useful as retention and drainage aids in papermaking processes having the structure: ##STR1## wherein E is the repeat unit obtained after polymerization of an .alpha.,.beta. ethylenically unsaturated compound, the molar percentage of a:b is from about 95:5 to 5:95, with the proviso that the sum of a and b equals 100%; G comprises the structure: ##STR2## wherein d is a cationic monomer, R.sub.1, R.sub.2 and R.sub.3 are the same or different and are hydrogen or a lower alkyl group having C.sub.1 to C.sub.3, F is the salt of an ammonium cation and the molar percentage of c:d is from 95:5 to 5:95 with the proviso that the sum of c and d equals 100%.
    Type: Grant
    Filed: August 3, 1993
    Date of Patent: December 20, 1994
    Assignee: Betz Laboratories, Inc.
    Inventors: John T. Lin, Wen P. Liao, Fu Chen
  • Patent number: 5374684
    Abstract: Clusters of water-swellable polymer particles, having high rates of absorbency without gel-blocking are prepared by suspending water-swellable polymer particles in an inert hydrophobic liquid, such as hydrocarbon, and slowly adding to the particles a suspension of an aqueous solution optionally containing an .alpha.,.beta.-ethylenically unsaturated monomer in an inert hydrophobic liquid.
    Type: Grant
    Filed: September 1, 1993
    Date of Patent: December 20, 1994
    Assignee: The Dow Chemical Company
    Inventor: Eva F. Tai
  • Patent number: 5371147
    Abstract: The present invention relates to novel preformed silicone-containing acrylic copolymers including silicone-containing acrylic star polymers, graft copolymers and macromonomers. Described are linear diblock macromomomers, graft copolymers and star polymers comprising a substantially hydrophilic block or block and a substantially hydrophobic, permeable block or block, said hydrophilic block preferably comprising at least about 25% by weight of a hydrophilic acrylic-type monomer and said hydrophobic, permeable block comprising at least about 50% by weight of at least one or more polysiloxanylalkylesters of an alpha, beta unsaturated acid.
    Type: Grant
    Filed: August 16, 1993
    Date of Patent: December 6, 1994
    Assignee: Permeable Technologies, Inc.
    Inventors: Harry J. Spinelli, Waifong L. Anton, Henry D. Coleman
  • Patent number: 5367029
    Abstract: Particulate graft copolymers for matt thermoplastic molding materials contain a base and a graft sheath. The base contains 75 to 99.8% of at least one alkyl acrylate, from 0.1 to 5% of at least one polyfunctional, crosslinking monomer having at least two ethylenic double bonds which are not conjugated in the 1,3-position, and from 0.1 to 20% of at least one ethylenically unsaturated monomer having one or more acidic groups. Alternatively, the base may contain at least 50% of one or more dienes, up to 50% of at least one further ethylenically unsaturated monomer, and up to 15% of at least one ethylenically unsaturated monomer having one or more acidic groups. The sheath contains from 0 to 99.8% of at least one aromatic vinyl monomer, from 0 to 99.8% of at least one polar, copolymerizable, ethylenically unsaturated monomer, from 0.1 to 20% of at least one ethylenically unsaturated monomer having one or more basic groups, and from 0.1 to 10% of at least one hydroxyalkyl (meth)acrylate.
    Type: Grant
    Filed: October 18, 1993
    Date of Patent: November 22, 1994
    Assignee: BASF Aktiengesellschaft
    Inventors: Wolfgang Fischer, Norbert Guentherberg, Norbert Niessner
  • Patent number: 5362813
    Abstract: A polymer dispersion of a star polymer dispersed in an organic liquid; wherein the star polymer has a crosslinked core having attached thereto at least three macrononomer arms; where(1) the core is formed of monomers having at least two ethylenically unsaturated double bonds which are crosslinked with each other and the core has at least 3 free radical polymerizable sites each of which are reacted with the macromonomer; and(2) the macromonomer that forms the arms of the star polymer is formed of ethylenically unsaturated monomers that have been polymerized by free radical polymerization in the presence of a free radical polymerization initiator and a catalytic chain transfer agent containing CO.sup.+2 to provide the macromonomer with a terminal ethylenically unsaturated group that is polymerized with the free radical polymerizable site on the core to form the star polymer. The process for making the star polymer and coating compositions that utilize the star polymer are also part of this invention.
    Type: Grant
    Filed: December 22, 1993
    Date of Patent: November 8, 1994
    Assignee: E. I. Du Pont de Nemours and Company
    Inventors: Joseph A. Antonelli, Christopher Scopazzi
  • Patent number: 5362804
    Abstract: An unsaturated polyester resin composition for the production of cured molded article which comprises:an unsaturated polyester resin; anda core-shell polymer as a low shrinking agent which comprises:(a) a cross-linked core layer polymerized from a first monomer comprising an aromatic vinyl monomer in an amount of not less 50% by weight, the core layer being contained in the core-shell polymer in an amount of 50-90% by weight; and(b) a shell layer polymerized from a monomer comprising methyl methacrylate in an amount of not less 50% by weight;and the core-shell polymer having a refractive index in the range of 1.52-1.58 and within .+-.0.02 from the refractive index of the cured material of the unsaturated polyester resin.
    Type: Grant
    Filed: February 24, 1993
    Date of Patent: November 8, 1994
    Assignee: Takeda Chemical Industries, Ltd.
    Inventors: Junji Oshima, Susumu Okatani, Koichi Akiyama, Masato Sakurai
  • Patent number: 5346964
    Abstract: A hydrogenated diene block copolymer having a polystyrene-reduced number-average molecular weight of 50,000-600,000 which is a hydrogenation product of an (A)-(B) block copolymer in which (A) means an alkenyl aromatic compound polymer block and (B) means a conjugated diene homopolymer block wherein the vinyl content of the conjugated diene portion is more than 60%, or an alkenyl aromatic compound-conjugated diene random copolymer block wherein the vinyl content of the conjugated diene portion is 15% or more, an (A)-(B)-(C) block copolymer in which (A) and (B) are as defined above and (C) means an alkenyl aromatic compound-conjugated diene copolymer tapered block wherein the proportion of the alkenyl aromatic compound increases gradually, or an (A)-(B)-(A) block copolymer in which (A) and (B) are as defined above. Said hydrogenated diene block copolymer is useful as a modifier for polar resins, non-polar resins or both of them.
    Type: Grant
    Filed: June 23, 1993
    Date of Patent: September 13, 1994
    Assignee: Japan Synthetic Rubber Co., Ltd.
    Inventors: Tooru Shibata, Toshio Teramoto, Yoshiharu Hashiguchi, Kunio Goshima
  • Patent number: 5328947
    Abstract: A two-part adhesive consisting of a first liquid comprising 100 parts by weight of a polymerizable vinyl monomer and from 0.1 to 20 parts by weight of an organic peroxide and a second liquid comprising 100 parts by weight of a polymerizable vinyl monomer and from 0.05 to 15 parts by weight of a reducing agent, wherein either one or both of the first and second liquids contain from 0.4 to 5% by weight of water, and the content of water is more than 0.2% by weight based on the total amount of the first and second liquids.
    Type: Grant
    Filed: December 23, 1992
    Date of Patent: July 12, 1994
    Assignee: Denki Kagaku Kogyo Kabushiki Kaisha
    Inventors: Koichi Taguchi, Kinpei Iwata, Hideki Matsudo
  • Patent number: 5324786
    Abstract: The invention provides a method for the production of a solid phase system of the formula F--(--R.sup.3 --Y--CO--CR.sup.2 .dbd.CR.sup.1 --CH.sub.2 --X).sub.m using new allyl esters of the formula:X--CH.sub.2 --CR.sup.1 .dbd.CR.sup.2 --CO--Y--R.sup.3 --A (I).R.sup.1 and R.sup.2 are hydrogen, halogen, alkyl or aryl, R.sup.3 is a spacer, X is acyloxy where acyl is the residue of an aliphatic carboxylic acid or is RCO-- in which R is an organic group. Y is oxygen or sulphur or an --NH-- group and A is a grouping which can react with a solid carrier material F, which contains functional groups B. A and B are groups which react with one another with condensation and/or addition and formation of a linkage between the solid carrier material and X--CH.sub.2 --CR.sup.1 .dbd.CR.sup.2 --CO--Y--R.sup.3 --.
    Type: Grant
    Filed: May 3, 1991
    Date of Patent: June 28, 1994
    Assignee: Orpegen Medizinische-Molekular Biologische Forschungsgesellschaft mbh
    Inventors: Horst Kunz, Winfried Kosch, Joachim Marz
  • Patent number: 5321056
    Abstract: Impact modifiers which produce transparent, high notched Izod impact strength blends with amorphous, aromatic polyesters are described. The impact modifiers are core-shell polymers with cores comprised mainly of rubbery polymers of diolefins and vinyl aromatic monomers and shells comprised mainly of styrene copolymers (e.g. styrene and hydroxyalkyl (meth)acrylate).
    Type: Grant
    Filed: March 17, 1993
    Date of Patent: June 14, 1994
    Assignee: Rohm and Haas Company
    Inventors: William G. Carson, Choung-Houng Lai, Edward J. Troy
  • Patent number: 5321080
    Abstract: A resin composition comprising an olefin resin (A), a copolymer of olefin with non-conjugated diene (B) and at least one polymer (C) selected from the group consisting of the following polymers;C1: diene polymer containing a hydroxyl group or the hydrogenation product thereof,C2: polymer containing a hydroxyl group,C3: polymer containing a carboxyl group (including an acid anhydride group),C4: polymer containing an amino group and/or imino group, andC5: polymer containing an epoxy group; and optionally an elastomer (D), filler (E) and at least one compound (F) selected from the group consisting of the following compounds;F1: organotin compound,F2: tertiary amine compound, andF3: phosphorus oxy compound.The moldings prepared from this resin composition have remarkable adhesive properties for paints, adhesives and printing inks. Thus, paints, etc. may be applied directly to the moldings, without surface treatment or washing thereof.
    Type: Grant
    Filed: July 29, 1992
    Date of Patent: June 14, 1994
    Assignee: Mitsubishi Petrochemical Company, Ltd.
    Inventors: Yuta Kumano, Sadao Kitagawa, Mitsushige Baba, Shiroh Gotoh
  • Patent number: 5314961
    Abstract: The present invention relates to novel copolymers and contact lenses made from these copolymers comprising preformed silicone-containing acrylic star polymers, graft copolymers and macromonomers, preparation of these contact lenses and a therapeutic method for treating patients with visual impairment.Described is a composition comprising at least about 10% by weight of a preformed silicone-containing acrylic copolymer and no more than about 90% by weight of a matrix formed from the random polymerization of a mixture of monomers. The mixture of monomers comprises at least one hydrophilic monomer and at least about 5% by weight of a polysiloxanylalkylester of an alpha, beta unsaturated acid and optionally, monomers selected from the group consisting of esters of alpha, beta-unsaturated acids and crosslinking monomers. The preformed silicone-containing acrylic copolymer is preferably copolymerized throughout the matrix. The final compositions are hydrated to a final water content of at least about 10% by weight.
    Type: Grant
    Filed: April 9, 1992
    Date of Patent: May 24, 1994
    Assignee: Permeable Technologies, Inc.
    Inventors: Waifong L. Anton, Henry D. Coleman, Mohammed I. Ali, Lester Weintraub
  • Patent number: 5314960
    Abstract: The present invention relates to novel copolymers and contact lenses made from these copolymers comprising preformed silicone-containing acrylic star polymers, graft copolymers and macromonomers, preparation of these contact lenses and a therapeutic method for treating patients with visual impairment.Described is a composition comprising at least about 10% by weight of a preformed silicone-containing acrylic copolymer and no more than about 90% by weight of a matrix formed from the random polymerization of a mixture of monomers. The mixture of monomers comprises at least one hydrophilic monomer and optionally, monomers selected from the group consisting of silicone acrylates, esters of alpha, beta-unsaturated acids and crosslinking monomers. The preformed silicone-containing acrylic copolymer is preferably copolymerized throughout the matrix. The final compositions are hydrated to a final water content of at least about 10% by weight.
    Type: Grant
    Filed: October 9, 1991
    Date of Patent: May 24, 1994
    Assignee: Permeable Technologies, Inc.
    Inventors: Harry J. Spinelli, Waifong L. Anton, Leonard Seidner, Henry D. Coleman, Mohammed I. Ali, Lester Weintraub, Paul White
  • Patent number: 5310811
    Abstract: Free radically curable rubbers are crosslinked with the aid of a free radical initiator and a co-curing agent, which is an acrylate or methacrylate ester of a hydroxybenzene or hydroxynaphthalene compound containing two or more hydroxyl groups, at least two of which are esterified. The rubbers which are used in the present invention are natural rubber and synthetic rubbers derived from a diene monomer. Preferred co-curing agents are acrylate and methacrylate esters of hydroxybenzene compounds in which the ester contains two or three acrylate or methacrylate groups per molecule. The amount of co-curing agent may be about 1-50 parts by weight per one hundred parts by weight of rubber (phr). Outstanding abrasion resistance and air oven aging are observed.
    Type: Grant
    Filed: September 22, 1993
    Date of Patent: May 10, 1994
    Assignee: The Goodyear Tire & Rubber Company
    Inventors: Kirkwood S. Cottman, Kevin L. Rollick
  • Patent number: 5310812
    Abstract: A toner for developing electrostatic latent images with a good combination of fixability, anti-offset characteristic, anti-sticking characteristic and pulverizability contains a composition comprising a colorant or magnetic material and a binder resin. The binder resin has 0.1 to 60 wt. % of a chloroform-insoluble or a THF (tetrahydrofuran)-insoluble component and a THF-soluble component, the THF-soluble providing a molecular weight distribution in the chromatogram of GPC (gel permeation chromatography) thereof such that there is a main peak in the molecular weight range of 1,000 to 25,000 and a sub-peak or shoulder in the molecular weight range of 2,000 to 150,000. The binder resin may suitably be obtained through two polymerization steps including a solution polymerization step and a suspension polymerization step.
    Type: Grant
    Filed: December 7, 1992
    Date of Patent: May 10, 1994
    Assignee: Canon Kabushiki Kaisha
    Inventors: Satoshi Yasuda, Kiichiro Sakashita, Yasuo Mitsuhashi, Seiichi Takagi, Shuichi Aita, Yoshinobu Nagai, Toshiaki Nakahara
  • Patent number: 5310807
    Abstract: A polymer dispersion of a star polymer dispersed in an organic liquid; wherein the star polymer has a crosslinked core having attached thereto at least three macromonomer arms; where(1) the core is formed of monomers having at least two ethylenically unsaturated double bonds which are crosslinked with each other and the core has at least 3 free radical polymerizable sites each of which are reacted with the macromonomer; and(2) the macromonomer that forms the arms of the star polymer is formed of ethylenically unsaturated monomers that have been polymerized by free radical polymerization in the presence of a free radical polymerization initiator and a catalytic chain transfer agent containing Co.sup.+2 to provide the macromonomer with a terminal ethylenically unsaturated group that is polymerized with the free radical polymerizable site on the core to form the star polymer.The process for making the star polymer and coating compositions that utilize the star polymer are also part of this invention.
    Type: Grant
    Filed: December 30, 1992
    Date of Patent: May 10, 1994
    Assignee: E. I. Du Pont de Nemours and Company
    Inventors: Joseph A. Antonelli, Christopher Scopazzi
  • Patent number: 5310791
    Abstract: A thermoplastic blend composition is provided containing an aromatic polycarbonate and a hydroxy functional graft copolymer. The compositions exhibit reduced gloss and are useful as molding resins.
    Type: Grant
    Filed: February 28, 1992
    Date of Patent: May 10, 1994
    Assignee: General Electric Company
    Inventor: Shripathy Vilasagar
  • Patent number: 5310813
    Abstract: The present invention provides a thermosetting coating resin consisting of a branched polymer, which branched polymer is obtained by copolymerizing a macromolecular monomer having a radical-polymerizable group at one end in the molecule and having a weight-average molecular weight of 1,000-10,000, with another radical-polymerizable monomer, which branched polymer contains the unit of said macromolecular monomer in a proportion of 40-99.5% by weight based on the amount of total constitutional units, which branched polymer has a cross-linkable functional group, and which branched polymer has a weight-average molecular weight of 5,000-30,000. The present invention further provides a process for producing such a thermosetting coating resin.
    Type: Grant
    Filed: April 5, 1993
    Date of Patent: May 10, 1994
    Assignees: Toagosei Chemical Industry Co., Ltd., Toyota Jidosha Kabushiki Kaisha
    Inventors: Mitsuru Nagasawa, Kazuyuki Kuwano, Masataka Muramatsu, Kishiro Azuma, Hiroshi Hibino, Kazuko Nakanishi
  • Patent number: 5306779
    Abstract: A hydrogenated diene block copolymer having a polystyrene-reduced number-average molecular weight of 50,000-600,000 which is a hydrogenation product of an (A)-(B) block copolymer in which (A) means an alkenyl aromatic compound polymer block and (B) means a conjugated diene homopolymer block wherein the vinyl content of the conjugated diene portion is more than 60%, or an alkenyl aromatic compound-conjugated diene random copolymer block wherein the vinyl content of the conjugated diene portion is 15% or more, an (A)-(B)-(C) block copolymer in which (A) and (B) are as defined above and (C) means an alkenyl aromatic compound-conjugated diene copolymer tapered block wherein the proportion of the alkenyl aromatic compound increases gradually, or an (A)-(B)-(A) block copolymer in which (A) and (B) are as defined above and in which hydrogenation product at least 80% of the double bonds of the conjugated diene portion is saturated by the hydrogenation.
    Type: Grant
    Filed: September 1, 1992
    Date of Patent: April 26, 1994
    Assignee: Japan Synthetic Rubber Co., Ltd.
    Inventors: Tooru Shibata, Toshio Teramoto, Yoshiharu Hashiguchi, Kunio Goshima
  • Patent number: 5306776
    Abstract: Disclosed are polymer having antistatic properties and having a multilayered structure comprising an innermost layer, a second layer, a third layer and an outermost layer; processes for preparing the multilayered polymer; and an antistatic resin composition comprising a thermoplastic resin and the multilayered polymer.
    Type: Grant
    Filed: April 28, 1993
    Date of Patent: April 26, 1994
    Assignee: Sumitomo Chemical Company, Limited
    Inventors: Kanki Matsumoto, Shinji Date
  • Patent number: 5302629
    Abstract: Acrylic pressure sensitive adhesives which exhibit hydrophilicity and moisture permeability can be made by curing or crosslinking low molecular weight acrylic oligomers modified with substantial quantities of a hydroxyl containing monomer. The resultant modified pressure sensitive adhesive acrylic copolymers, upon crosslinking, will then have a hydrophilic hydroxy component incorporated into the copolymer backbone. Such adhesives are particularly useful in skin contact applications, such as the adhesives used on bandages or the adhesives used in transdermal drug delivery systems.
    Type: Grant
    Filed: May 15, 1992
    Date of Patent: April 12, 1994
    Inventor: Anthony J. Berejka
  • Patent number: 5300578
    Abstract: A method for preparing a polyolefine--vinyl polymer composite, wherein about 10-200 parts by weight of vinyl monomer and about 0.01-4.0 parts by weight of a free radical polymerization initiator, based on 100 parts by weight of vinyl monomer, are impregnated in 100 parts of weight of polyolefine particles by slowly mixing these at a temperature of about 20.degree.-130.degree. C. while maintaining the particle structure of the polyolefine. After 50-99% of the amount of the monomer has been absorbed into the polyolefine particles, a water suspension is prepared by adding to the above-mentioned mixture about 80-1000 parts by weight water, based on 100 parts of weight of polyolefine+vinyl monomer, as well as a stabilizing agent. The temperature of the water suspension is then increased for polymerizing the vinyl monomer.
    Type: Grant
    Filed: January 27, 1993
    Date of Patent: April 5, 1994
    Assignee: Neste Oy
    Inventors: Torvald Vestberg, Ismo Lehtiniemi
  • Patent number: 5300571
    Abstract: The invention relates to a hardenable composition containingA) compounds having at least two activated double bonds (I) based on .alpha.,.beta.-unsaturated carbonyl compounds, .alpha.,.beta.-unsaturated carboxylic acid esters or .alpha.,.beta.-unsaturated nitrile groups,B) compounds containing either at least one primary amino group which is blocked by an aldehyde or ketone having not more than 10 C atoms or at least 2 groups which can be hydrolyzed to NH groups, andC) customary additives, if appropriate catalysts, if appropriate pigments and organic solvents.Either component A or component B or components A and B are based on a branched soluble acrylate copolymer P, which is obtainable by copolymerization ofa) 5 to 30% by weight of monomers having at least two ethylenically unsaturated polymerizable double bonds,b) 5 to 60% by weight of monomers having a functional group andc) 5 to 90% by weight of other ethylenically unsaturated monomers,the sum of a, b and c being 100% by weight.
    Type: Grant
    Filed: March 26, 1991
    Date of Patent: April 5, 1994
    Assignee: BASF Lacke+Farben Aktiengesellschaft
    Inventors: Werner A. Jung, Peter Hoffmann
  • Patent number: 5300580
    Abstract: Modified ethylene/n-butyl acrylate copolymers obtained by grafting a half-ester of maleic acid onto a randomly copolymerized ethylene/n-butyl acrylate backbone are provided. The carboxylic functionalized polymers of the invention exhibit superior adhesion to non-polar substrates. They are particularly effective for adhering metals.
    Type: Grant
    Filed: May 22, 1991
    Date of Patent: April 5, 1994
    Assignee: Quantum Chemical Corporation
    Inventors: Leslie Wild, Karl Koch, deceased
  • Patent number: 5298566
    Abstract: A water soluble graft copolymer useful for dewatering wastewater having the structure: ##STR1## wherein E is the repeat unit obtained after polymerization of an .alpha., .beta. ethylenically unsaturated compound, the molar percentage of a:b is from about 95:5 to 5:95, with the proviso that the sum of a and b equals 100% G comprises the structure: ##STR2## wherein d is a cationic monomer, R.sub.1, R.sub.2 and R.sub.3 are the same or different and are hydrogen or a lower alkyl group having C.sub.1 to C.sub.3, F is the salt of an ammonium cation and the molar percentage of c:d is from 95:5 to 5:95 with the proviso that the sum of c and d equals 100%.
    Type: Grant
    Filed: January 5, 1993
    Date of Patent: March 29, 1994
    Assignee: Betz Laboratories, Inc.
    Inventors: Wen P. Liao, Fu Chen
  • Patent number: 5292791
    Abstract: The mixture consists of at least one organic peroxide, at least one hydroquinone derivative of the general formulae I and/or II and/or III ##STR1## wherein R and R.sup.1, which may be identical or different, stand for H or t-alkyl, and X stands, for example, for C.sub.1-18 -alkylene, and a crosslinkage promoter, and permits the crosslinkage of polymers and at the same time extends the scorch time, which must be understood as the processing time.
    Type: Grant
    Filed: June 25, 1993
    Date of Patent: March 8, 1994
    Assignee: ELF Atochem North America, Inc.
    Inventors: Jurgen Groepper, Harald Hofmann
  • Patent number: 5290869
    Abstract: Cement dispersion agents containing a graft copolymer composed of four kinds of constituent unit each having a specified structure can provide improved fluidity to cementing compositions, prevent slump loss after the kneading process and reduce the drying shrinkage of hardened concrete produced at the same time.
    Type: Grant
    Filed: December 16, 1992
    Date of Patent: March 1, 1994
    Assignee: Takemoto Yushi Kabushiki Kaisha
    Inventors: Mitsuo Kinoshita, Yoshimasa Miura, Tsuneo Yamamoto
  • Patent number: 5288808
    Abstract: Polymers containing repeating units of: ##STR1## and optionally random distribution of other units derived from at least one vinyl monomer, R.sub.1 is H; alkyl, cycloalkyl or aryl each of which is unsubstituted or substituted by at least one halogen; ##STR2## (R.sub.7 is H, alkyl, cycloalkyl or aryl); A is a single bond; alkylene, cycloalkylene or arylene; or ##STR3## (B is alkylene, cycloalkylene or arylene); R.sub.2, R.sub.3 and R.sub.4 are alkyl, cycloalkyl or aryl; it being possible for at least one of R.sub.3 and R.sub.4 to contain at least one hydroxyl or carboxylic acid groups or to represent a polyoxyethylene or polyester sequence.These polymers are useful for the preparation of graft copolymers containing the units of the formula: ##STR4## where Po is a vinyl or a diene polymer sequence, and other vinyl units. These graft copolymers are useful especially as compatibility agents.
    Type: Grant
    Filed: November 20, 1992
    Date of Patent: February 22, 1994
    Assignee: ATOCHEM
    Inventor: Gilbert Clouet
  • Patent number: 5288807
    Abstract: This invention relates to vinyl monomer compositions having accelerated surface cure characteristics. These compositions are prepared from a vinyl monomer or monomer mixtures such as blend of isobornyl methacrylate and hydroxypropyl methacrylate, a bulk phase polymerization catalyst system, a polyvalent metal oxidative surface phase catalyst, and a diolefin rubber dispersed in the vinyl monomer as a surface cure accelerator. These compositions are useful as sealers, healers and for polymer concrete.
    Type: Grant
    Filed: July 2, 1991
    Date of Patent: February 22, 1994
    Assignee: Rohm and Haas Company
    Inventor: Frederick P. Hinz
  • Patent number: 5281646
    Abstract: In a process for producing a thermoplastic resin by emulsion polymerization using a conjugated diene rubber, an aromatic vinyl compound and a vinyl cyanide compound, and by successive flocculation and direct pelletizing, the direct pelletizing is effected in the presence of a phenolic compound represented by ##STR1## wherein R.sup.1 and R.sup.4 are each hydrogen or methyl, and R.sup.2 and R.sup.3 are each an alkyl of 1 to 9 carbon atoms. The use of the phenolic compound is effective to prevent the resin from thermal deterioration during the direct pelletizing, thereby producing the thermoplastic resin excellent in properties such as impact resistance.
    Type: Grant
    Filed: September 21, 1992
    Date of Patent: January 25, 1994
    Assignee: Sumitomo Chemical Company, Limited and Sumitomo Dow Limited
    Inventors: Shinichi Yachigo, Kanako Ida, Hiroshi Kojima
  • Patent number: 5274044
    Abstract: Compounds of Formula I ##STR1## wherein Z is an aromatic group, each R is individually selected from the group consisting of alkyl groups of from 1 to about 12 carbon atoms, thioalkyl groups of from 1 to about 12 carbon atoms, and halogen atoms, n is from 1 to about 6, and x is from 0 to 7, are suitable for use in preparing rubber latex particles. The rubbers are useful as substrates in graft copolymers and the resulting graft copolymers are suitable for use in thermoplastic blend compositions, particularly with transparent polymers. The rubber materials are advantageous in that they exhibit low glass transition temperatures and high refractive indices.
    Type: Grant
    Filed: July 28, 1992
    Date of Patent: December 28, 1993
    Assignee: General Electric Company
    Inventors: Ronald L. Jalbert, David V. Howe, Robert E. Harris, Robert R. Gallucci
  • Patent number: 5272213
    Abstract: This invention pertains to scorch retardant systems for peroxide curable elastomers. Polyunsaturated monomers copolymerizable with the elastomer in the presence of peroxides are mixed with hydroquinone and sulfenamides and incorporated into elastomer formulations. The formulations are milled and cured. Excellent Mooney scorch times and hardness values, as well as other physical properties are obtained.
    Type: Grant
    Filed: May 14, 1992
    Date of Patent: December 21, 1993
    Assignee: Air Products and Chemicals, Inc.
    Inventors: Eric Knowles, David A. Cornforth, Francis M. Carney
  • Patent number: 5270120
    Abstract: A data-carrying laminate such as a credit card or identity card comprises a sheet of cellulosic material or synthetic material and a thermoplastic polymeric film, at least one of said sheet and said thermoplastic film carrying data, said sheet and said thermoplastic film being bonded together by a cured adhesive layer obtained by curing a solid film adhesive comprising (A) a solid polymer of a vinyl carboxylic acid and (B) a curable material having at least one acrylate or methacrylate group.
    Type: Grant
    Filed: July 14, 1992
    Date of Patent: December 14, 1993
    Assignee: Ciba-Geigy Corporation
    Inventors: Christopher M. Andrews, Edward Irving