Ester Reactant Derived From An Unsaturated Carboxylic Acid Is Reacted In The Presence Of A Solid Polymer Substrate Derived From A Polyene Hydrocarbon Patents (Class 525/310)
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Patent number: 12006390Abstract: The present invention relates to a latex composition for dip molding, and such latex composition includes: a carboxylic acid-modified nitrile-based copolymer latex; and a reactive compound having three or more branched chains and a reactive group at a terminal of each of the branched chains, wherein the reactive group is one or more selected from the group consisting of an amine group, a hydroxy group, an epoxy group, a glycidyl group, and an isocyanate group.Type: GrantFiled: August 12, 2020Date of Patent: June 11, 2024Assignee: LG Chem, Ltd.Inventors: Won Sang Kwon, Tae Shik Yoon, Jung Su Han, Myung Su Jang
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Patent number: 11945885Abstract: A vinyl-containing copolymer is copolymerized from (a) first compound, (b) second compound, and (c) third compound. (a) First compound is an aromatic compound having a single vinyl group. (b) Second compound is polybutadiene or polybutadiene-styrene having side vinyl groups. (c) Third compound is an acrylate compound. The vinyl-containing copolymer includes 0.003 mol/g to 0.010 mol/g of benzene ring, 0.0005 mol/g to 0.008 mol/g of vinyl group, and 1.2*10?5 mol/g to 2.4*10?4 mol/g of ester group.Type: GrantFiled: December 29, 2022Date of Patent: April 2, 2024Assignee: INDUSTRIAL TECHNOLOGY RESEARCH INSTITUTEInventors: Cheng-Po Kuo, Shin-Liang Kuo, Shu-Chuan Huang, Yan-Ting Jiang, Jian-Yi Hang, Wen-Sheng Chang
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Patent number: 11261277Abstract: Provided are a method of preparing a graft copolymer, a graft copolymer, and a thermoplastic resin molded article. The method of preparing a graft copolymer includes 1) adding a conjugated diene-based monomer and performing polymerization to prepare a conjugated diene-based polymer; and 2) adding the conjugated diene-based polymer, an aromatic vinyl monomer, and a vinyl cyan monomer and performing polymerization to prepare a graft copolymer, wherein an emulsifier having an APHA color value of 50 or less and a critical micelle concentration of 1 to 50 g/l is added, so that excellent polymerization stability, colorability, light resistance, and surface clarity are exhibited.Type: GrantFiled: September 20, 2018Date of Patent: March 1, 2022Assignee: LG CHEM, LTD.Inventors: Yoo Vin Kim, Young Min Kim, Jin Hyoung Lee, Su Jeong Han, Young Hwan Jeong, Jae Min Suk, Jae Won Heo
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Patent number: 10792621Abstract: A preparation method of separation membrane is provided. First, a polyimide composition including a dissolvable polyimide, a crosslinking agent, and a solvent is provided. The dissolvable polyimide is represented by formula 1: wherein B is a tetravalent organic group derived from a tetracarboxylic dianhydride containing aromatic group, A is a divalent organic group derived from a diamine containing aromatic group, A? is a divalent organic group derived from a diamine containing aromatic group and carboxylic acid group, and 0.1?X?0.9. The crosslinking agent is an aziridine crosslinking agent, an isocyanate crosslinking agent, an epoxy crosslinking agent, a diamine crosslinking agent, or a triamine crosslinking agent. A crosslinking process is performed on the polyimide composition. The polyimide composition which has been subjected to the crosslinking process is coated on a substrate to form a polyimide membrane. A dry phase inversion process is performed on the polyimide membrane.Type: GrantFiled: March 29, 2017Date of Patent: October 6, 2020Assignee: Taiwan Textile Research InstituteInventors: Shang-Chih Chou, Chun-Hung Chen, Chun-Hung Lin, Kueir-Rarn Lee
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Patent number: 10675590Abstract: A preparation method of separation membrane is provided. First, a polyimide composition including a dissolvable polyimide, a crosslinking agent and a solvent is provided. The dissolvable polyimide is represented by formula 1: wherein B is a tetravalent organic group derived from a tetracarboxylic dianhydride containing aromatic group, A is a divalent organic group derived from a diamine containing aromatic group, A? is a divalent organic group derived from a diamine containing aromatic group and carboxylic acid group, and 0.1?X?0.9. The crosslinking agent is an aziridine crosslinking agent, an isocyanate crosslinking agent, an epoxy crosslinking agent, a diamine crosslinking agent, or a triamine crosslinking agent. A crosslinking process is performed on the polyimide composition. The polyimide composition which has been subjected to the crosslinking process is coated on a substrate to form a polyimide membrane. A wet phase inversion process is performed on the polyimide membrane.Type: GrantFiled: March 29, 2017Date of Patent: June 9, 2020Assignee: Taiwan Textile Research InstituteInventors: Shang-Chih Chou, Chun-Hung Chen, Chun-Hung Lin, Kueir-Rarn Lee
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Patent number: 10208223Abstract: A fluoropolymer coating composition is described comprising an aqueous liquid medium, fluoropolymer particles dispersed in the aqueous liquid medium, and at least one aziridine compound. The aziridine compound comprises at least two aziridine groups (i.e. polyaziridine) or at least one aziridine group and at least one alkoxy silane group. In another embodiment, an article is described comprising a substrate wherein a surface of the substrate comprises a coating comprising fluoropolymer particles; and a reaction product of at least one aziridine compound comprising at least two aziridine groups or at least one aziridine group and at least one alkoxy silane group. The coating can be utilized as a primer for bonding a non-fluorinated substrate to a fluoropolymer film and/or the coating can be used as an (e.g. outer exposed) surface layer. In some embodiments, the article may be the (e.g. backside) film of a photovoltaic module.Type: GrantFiled: April 13, 2018Date of Patent: February 19, 2019Assignee: 3M Innovative Properties CompanyInventors: Naiyong Jing, Kai H. Lochhaas, Kevin M. Hamer, Thomas J. Blong, Timothy D. Fletcher, Zhigang Yu, Michael Juergens
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Patent number: 10072126Abstract: A composition may include a resin and a plurality of polymer nanoparticles in the resin to form a resin mixture. The polymer nanoparticles may be soluble or semi-soluble in the resin. At least partial dissolution of the polymer nanoparticles may result in the alteration of one or more of the properties of the resin.Type: GrantFiled: September 23, 2014Date of Patent: September 11, 2018Assignee: The Boeing CompanyInventors: Michael P. Kozar, Mark S. Wilenski, Samuel J. Meure
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Patent number: 9181448Abstract: Latex emulsions are disclosed which can be used in the formation of coating compositions that are not water sensitive, have good blush resistance and retortability. In some embodiments, the coating compositions are used to coat substrates such as cans and packaging materials for the storage of food and beverages. Coating compositions of the invention may be prepared by polymerizing at least one ethylenically unsaturated monomer component, a stabilizer comprising a strong acid and an initiator in a carrier to form an emulsion, polymerizing the emulsion with at least one different ethylenically unsaturated monomer component to prepare the composite latex emulsion, and reacting the composite latex emulsion with a neutralizer to form the coating composition. Methods of coating substrates with the coating compositions, and substrates coated with the coating compositions are also disclosed.Type: GrantFiled: December 28, 2011Date of Patent: November 10, 2015Assignee: AKZO NOBEL COATINGS INTERNATIONAL B.V.Inventors: Cathy Li, Tiffany Weidendorf, Timothy I. Memmer, Daniel Bode
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Patent number: 9068105Abstract: Described herein is a heat-seal coating which, when going through the recycled paper making process, will readily break down without any major amount of by-product that needs to be landfilled; can be made into paper again; breaks down in a commercial composting facility; and decomposes into basic materials such as carbon dioxide, carbon monoxide and water. The heat seal coating or top coat comprises three components: (1) a barrier polymer; (2) a polymer that provides some barrier properties and softness to the formulation; and, (3) a heat-curable adhesive.Type: GrantFiled: May 16, 2013Date of Patent: June 30, 2015Assignee: True Partners Financial Services, PLLCInventors: Robert VonFelden, John Kokoszka
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Publication number: 20150030836Abstract: In relation to a polymerizable composition for forming a transparent optical resin layer to be interposed between an image display section of an image display device and a light-transmissive protective section thereof, the present invention provides a polymerizable composition that does not give rise to display defects caused by the deformation of the image display section, enables high-luminance, high-contrast image displaying, has excellent heat resistance, and also has a low dielectric constant. This polymerizable composition comprises: (1) a urethane (meth)acrylate obtained by reacting a hydrogenated polyolefin polyol and a compound having an isocyanato group and a (meth)acryloyl group; (2) a (meth)acryloyl-group-containing compound having a hydrocarbon group with a carbon number of 6 or greater; and (3) a photopolymerization initiator.Type: ApplicationFiled: February 28, 2013Publication date: January 29, 2015Applicant: SHOWA DENKO K.K.Inventors: Kazuhiko Ooga, Hiroto Kouka, Kenichi Nakanishi, Daigo Ito, Kazuhiro Sasaki, Yuta Takeuchi
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Patent number: 8912288Abstract: The present invention discloses a new type of polyimide membrane with high permeances and high selectivities for gas separations and particularly for CO2/CH4 and H2/CH4 separations. The polyimide membranes have CO2 permeability of 50 Barrers or higher and single-gas selectivity for CO2/CH4 of 15 or higher at 50° C. under 791 kPa for CO2/CH4 separation. The polyimide membranes have UV cross-linkable functional groups and can be used for the preparation of UV cross-linked polyimide membranes having CO2 permeability of 20 Barrers or higher and single-gas selectivity for CO2/CH4 of 35 or higher at 50° C. under 791 kPa for CO2/CH4 separation.Type: GrantFiled: October 21, 2011Date of Patent: December 16, 2014Assignee: UOP LLCInventors: Chunqing Liu, Travis C. Bowen, Emily G. Harbert, Raisa Minkov, Syed A. Faheem, Zara Osman
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Publication number: 20130274416Abstract: Disclosed is a graft monomer composition for thermoplastic transparent resins, a composition for thermoplastic transparent resins using the same and a thermoplastic transparent resin that exhibits superior transparency and color at low rubber contents. According to the graft monomer composition, the composition for thermoplastic transparent resins and the thermoplastic transparent resin, although the content of rubber in final products increases or the content of rubber in graft copolymers in the preparation of final products increases, the copolymer surrounds the surface of rubber well, thus reducing haze, considerably improving transparency and exhibiting excellent natural color.Type: ApplicationFiled: December 23, 2011Publication date: October 17, 2013Applicant: LG Chem, Ltd.Inventors: Jeong-Su Choi, Keun-Hoon Yoo, Hyong-Min Bahn, Won-Seok Lee, Seok-Goo Jang
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Patent number: 8557923Abstract: Disclosed herein is a thermoplastic resin composition having excellent scratch resistance and a method for preparing the same. The thermoplastic resin composition comprises (A) about 80 to about 95% by weight of a terpolymer of (meth)acrylic acid alkyl ester-aromatic vinyl-cyanide vinyl compound; and (B) about 5 to about 20% by weight of a butadiene rubber.Type: GrantFiled: December 29, 2008Date of Patent: October 15, 2013Assignee: Cheil Industries Inc.Inventors: Young Sub Jin, Hwan Seok Park, Jae Keun Hong, Sung Kwan Kim, Ho Ryong Sun, Byeong Do Lee, Kyung Jong Lee
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Patent number: 8513349Abstract: A binder composition for the positive electrode of an electric storage device. The composition contains polymer alloy particles composed of: a polymer (A) having a recurring unit derived from vinylidene fluoride, ethylene tetrafluoride, propylene hexafluoride, or mixtures thereof; a polymer (B) having a recurring unit derived from an unsaturated carboxylic acid ester; and water. The average diameter of the polymer alloy particles is 50 to 400 nm. The polymer alloy particles are synthesized by absorbing a monomer (b) to the polymer (A) and polymerizing the monomer (b) to synthesize the polymer (B).Type: GrantFiled: December 28, 2011Date of Patent: August 20, 2013Assignee: JSR CorporationInventors: Yoshiharu Ootsuka, Hironori Kitaguchi, Nobuyuki Fujihara
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Patent number: 8415425Abstract: Provided is a method for protecting the surface of a member to be processed, which comprises providing a protective film made of a photocurable resin composition for surface protection on the surface of the member to be processed, processing the member to be processed, and removing the protective film from the member to be processed, wherein the photocurable resin composition comprises (A) a polyfunctional (meth)acrylate, (B) a monofunctional (meth)acrylate, (C) a resin having a cyclopentadiene skeleton and (D) a photopolymerization initiator, which comprises from 1 to 50 parts by weight of (A), from 5 to 95 by mass of (B) and from 0.1 to 50 parts by mass of (C).Type: GrantFiled: March 30, 2012Date of Patent: April 9, 2013Assignee: Denki Kagaku Kogyo Kabushiki KaishaInventors: Tomoyuki Kanai, Kazuhiro Oshima
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Patent number: 8338526Abstract: To provide an environmentally-friendly curable resin composition for surface protection, having a high adhesive strength and being capable of forming a protective film which will readily be removed in the film form without adhesive residue in water on a member to be processed, a photocurable adhesive using it, a method for temporarily fixing a member, and a method for removing a protective film. A curable resin composition for surface protection, comprising (A) a polyfunctional (meth)acrylate, (B) a monofunctional (meth)acrylate, and (C) a resin having a cyclopentadiene skeleton. Further, a curable resin composition for surface protection, comprising (A) a polyfunctional (meth)acrylate, (B) a monofunctional (meth)acrylate, (C) a resin having a cyclopentadiene skeleton, and (D) a photopolymerization initiator.Type: GrantFiled: July 12, 2011Date of Patent: December 25, 2012Assignee: Denki Kagaku Kogyo Kabushiki KaishaInventors: Tomoyuki Kanai, Kazuhiro Oshima
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Publication number: 20120157629Abstract: The present invention relates to new impact modifiers and a process for making these new impact modifiers and their use in polymeric compositions. More particularly the present invention relates to a new polymeric impact modifier with a core-shell structure made by a multistage polymerization process comprising at least one gradient polymer. The present invention relates as well to a process preparing such an impact modifier, especially its recovery process after the end of the polymerization. The present invention also relates to a thermoplastic composition comprising the new impact modifier.Type: ApplicationFiled: December 14, 2011Publication date: June 21, 2012Applicant: Arkema FranceInventors: Christophe Navarro, Stephane Girois, Elisabeth Bay, Jean-Claude Saint-Martin
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Patent number: 8143571Abstract: A method for fractionating a target fraction from a sample is disclosed herein. The method includes providing a polymer brush having a substrate and a polymer chain attached to and extending outwardly from the substrate. The method further comprising contacting the polymer brush with the sample to allow for sorption of the target fraction by the polymer chain. The polymer chain is then stimulated with a stimulus to contract and release the target fraction.Type: GrantFiled: June 3, 2009Date of Patent: March 27, 2012Assignee: Southern Illinois UniversityInventors: Daniel J. Dyer, Gary R. Kinsel
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Patent number: 8119740Abstract: The invention describes curable liquid acryloyl group containing compositions, which are produced by reacting monofunctional vinyl compounds and multifunctional acrylic esters with ?-dicarbonyl group containing compounds having two activated hydrogen atoms in its methylene position. These material can be polymerized or crosslinked by free radical polymerization, UV (ultraviolet) or electron-beam radiation. The curable liquid compositions are suitable for producing curable coatings, printing inks, adhesives, or molding compositions.Type: GrantFiled: December 19, 2003Date of Patent: February 21, 2012Assignee: Sun Chemical CorporationInventors: Artur Lachowicz, Kai-Uwe Gaudl, Steven H. Nahm, Gerwald F. Grahe
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Publication number: 20110269868Abstract: To provide an environmentally-friendly curable resin composition for surface protection, having a high adhesive strength and being capable of forming a protective film which will readily be removed in the film form without adhesive residue in water on a member to be processed, a photocurable adhesive using it, a method for temporarily fixing a member, and a method for removing a protective film. A curable resin composition for surface protection, comprising (A) a polyfunctional (meth)acrylate, (B) a monofunctional (meth)acrylate, and (C) a resin having a cyclopentadiene skeleton. Further, a curable resin composition for surface protection, comprising (A) a polyfunctional (meth)acrylate, (B) a monofunctional (meth)acrylate, (C) a resin having a cyclopentadiene skeleton, and (D) a photopolymerization initiator.Type: ApplicationFiled: July 12, 2011Publication date: November 3, 2011Applicant: Denki Kagaku Kogyo Kabushiki KaishaInventors: Tomoyuki KANAI, Kazuhiro Oshima
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Publication number: 20110224351Abstract: Provided are a method of producing a graft copolymer, the method involving subjecting a radically polymerizable monomer to living radical graft polymerization with a rubber component formed of a natural rubber and/or a synthetic diene-based rubber in an aqueous medium in the presence of a polymerization control agent, a rubber composition containing the graft copolymer obtained by the method, and a tire obtained by using the rubber composition in any one of its tire members.Type: ApplicationFiled: October 1, 2009Publication date: September 15, 2011Applicants: BRIDGESTONE CORPORATION, OTSUKA CHEMICAL CO., LTD.Inventors: Noriko Mori, Hajime Tokyo, Takashi Kameshima
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Publication number: 20110213092Abstract: UV-cured pressure sensitive adhesive including one or more UV-curable acrylic oligomers, one or more tack control components, and, optionally, an elastomeric material is described herein. The adhesive includes an adhesive component ratio of the various adhesive components effective to provide desired first peel adhesions and subsequent peel adhesions.Type: ApplicationFiled: February 25, 2011Publication date: September 1, 2011Inventors: Jeffrey James Boyce, Michael Clingerman, Colleen Marie Henry, David Chris Masterson, Vincent Daniel McGinniss
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Publication number: 20110190451Abstract: A photocurable liquid resin which comprises (A) a step of producing a conjugated diene-based polymer or a conjugated diene/aromatic vinyl-based copolymer, which has a weight-average molecular weight of 5,000 to 40,000 and a molecular weight distribution of 3.Type: ApplicationFiled: April 18, 2011Publication date: August 4, 2011Applicant: BRIDGESTONE CORPORATIONInventors: Toshiki TAKIZAWA, Naoyuki OHMORI
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Patent number: 7910659Abstract: Disclosed is an acrylic syrup containing a vinyl monomer (A) of methyl methacrylate and a polymerized solid component (B) which is a high polymer of said vinyl monomer and has a weight average molecular weight of from 30,000 to 2,000,000 as measured by the GPC and a viscosity at 25° C. of from 0.1 to 50 Pa·s, wherein at least part of said polymerized solid component (B) is a grafted rubber obtained by graft-polymerizing said vinyl monomer with a rubbery polymer, and said grafted rubber has a large branching coefficient. The acrylic resin molded articles obtained from the acrylic syrup exhibit excellent impact resistance.Type: GrantFiled: October 24, 2005Date of Patent: March 22, 2011Assignee: Mitsubishi Gas Chemical Company, Inc.Inventors: Tadashi Kawabata, Shojiro Kuwahara, Masahiro Kurokawa
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Patent number: 7867433Abstract: Methods for making a crosslinked elastomeric composition and articles made of the same are provided. In at least one specific embodiment, an elastomeric composition comprising at least one propylene-based polymer is blended with at least one component selected from the group consisting of multifunctional acrylates, multifunctional methacrylates, functionalized polybutadiene resins, functionalized cyanurate, and allyl isocyanurate; and blended with at least one component selected from the group consisting of hindered phenols, phosphites, and hindered amines. The propylene-based polymer can include propylene derived units and one or more dienes, and have a triad tacticity of from 50% to 99% and a heat of fusion of less than 80 J/g. The blended composition can then be extruded and crosslinked. The extruded polymer can be crosslinked using electron beam radiation having an e-beam dose of about 100 KGy or less. The crosslinked polymers are particularly useful for making fibers and films.Type: GrantFiled: May 30, 2008Date of Patent: January 11, 2011Assignee: ExxonMobil Chemical Patents Inc.Inventors: Sunny Jacob, Alistair D. Westwood, Tonson Abraham
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Patent number: 7776971Abstract: The inventive subject matter relates to novel synthetic processes which use a multifunctional compound (the “TERMINI compound”) having a masked or protected functional group, wherein the TERMINI compound is capable of quantitatively and irreversibly interrupting a living polymerization or a chain organic reaction. After deprotection or demasking of the functional group of the TERMINI compound, the same living polymerization or organic reaction resumes with 100% efficiency, or a different living polymerization or organic reaction resumes with 100% chemoselectivity, respectively. Once incorporated into a growing molecule, the TERMINI compound generates a branching point upon resumption of the polymerization or reaction.Type: GrantFiled: May 6, 2004Date of Patent: August 17, 2010Assignee: The Trustees Of The University Of PennslyvaniaInventor: Virgil Percec
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Patent number: 7763681Abstract: Process for the preparation of polyalkenyl acylating agents which comprises: a. reacting at a temperature higher than 180° C. a reactive polyalkene, having a number average molecular weight Mn ranging from 500 to 5000 and having a content of terminal vinylidene groups greater than or equal to 30%, with an enophile; b. thermally carrying out the reaction for a time sufficient for having a conversion of the terminal vinylidene groups higher than 15%; c. completing the reaction always under heat in the presence of a reaction accelerator consisting of a Lewis acid selected from a tin, zinc, aluminum or titanium halide.Type: GrantFiled: July 11, 2007Date of Patent: July 27, 2010Assignee: ENI S.p.A.Inventors: Riccardo Rausa, Andrea Pucci, Luigi D'Elia, Francesco Ciardelli
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Patent number: 7714038Abstract: Polyolefin waxes bearing (meth)acrylate groups, process for preparing them and their use.Type: GrantFiled: March 2, 2006Date of Patent: May 11, 2010Assignee: BASF AktiengesellschaftInventors: Dietmar Haering, Bernhard Hauer, Thomas Pfeiffer, Andreas Fechtenkoetter, Harald Larbig, Erich Beck
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Patent number: 7671129Abstract: The present invention provides a thermoplastic resin composition capable of demonstrating impact strength, and high resistance to hydrolysis and heat discoloration without impairing the essential properties of the thermoplastic resin. The present invention provides a thermoplastic resin composition containing: 70 to 99% by mass of thermoplastic resin (A) containing a polycarbonate resin as an essential component; and 1 to 30% by mass of graft copolymer (B) which is a graft copolymer obtained by emulsion graft polymerization of a monomer or monomer mixture containing at least alkyl methacrylate in the presence of a latex containing a butadiene rubber polymer, wherein the amount of the butadiene rubber polymer included is in the range of 55 to 90% by mass, and the graft copolymer (B) is obtained by using 0.05 to 10 parts by mass of sodium alkylphenylether disulfonate with respect to 100 parts by mass of the graft copolymer (B).Type: GrantFiled: March 9, 2004Date of Patent: March 2, 2010Assignee: Mitsubishi Rayon Co., Ltd.Inventors: Takashi Miura, Keiji Nakamura, Mari Sekita, Masahiro Osuka
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Patent number: 7585924Abstract: The present invention is directed to a novel high temperature polymerization process operating at high pressures for producing a polymer. The process includes conveying hybrid reactor mixtures, which include one or more hybrid reactor monomers and one or more hybrid reactor initiators to one or more hybrid reactors. The hybrid reactors are maintained at effective hybrid polymerization temperatures and sub-reflux polymerization gage pressures to cause polymerization of a portion of the hybrid reactor monomers into the polymer. The process further includes conveying hybrid reactor contents from the hybrid reactors to one or more batch reactors maintained at effective batch polymerization temperatures and reflux polymerization pressures to cause polymerization of a remaining portion of the hybrid reactor monomers into the polymer. The hybrid reactors are smaller in volume than the batch reactors.Type: GrantFiled: July 10, 2003Date of Patent: September 8, 2009Assignee: E. I. du Pont de Nemours and CompanyInventor: Michael Charles Grady
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Patent number: 7361727Abstract: A polymerization process to derive a thermal-stabilized poly(1,4-dioxan-2-one) and cyclic ester monomer copolymer using a coordination-insertion catalyst/initiator. 1,4-dioxan-2-one and cyclic ester monomer, each containing less than 100-ppm water and having an acid value less than 0.5 mg KOH/g, and preferably less than 0.2 mg KOH/g, are copolymerized. Preferably the cyclic ester monomer is ?-caprolactone and the reaction is in an extruder.Type: GrantFiled: August 8, 2005Date of Patent: April 22, 2008Assignee: Board of Trustees of Michigan State UniversityInventors: Ramani Narayan, Jean-Marie Raquez, Sunder Balakrishnan, Philippe Dubois, Philippe Degee
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Patent number: 7196141Abstract: The present invention provides a vinyl polymer with an epoxy group terminally introduced therein and an epoxy resin composition comprising (A) an epoxy resin and (B) a vinyl polymer which has a main chain produced by living-radical polymerization and has a reactive functional group at a main chain terminus. A flexible epoxy resin composition can be obtained using these compounds. The invention further provides an epoxy resin composition-having an epoxy group at a main chain terminus thereof.Type: GrantFiled: September 7, 2006Date of Patent: March 27, 2007Assignee: Kaneka CorporationInventors: Kenichi Kitano, Yoshiki Nakagawa, Masayuki Fujita
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Patent number: 7101937Abstract: Macromolecules in the shape of three-dimensional kites, barbells, and other shapes are disclosed. The shaped macromolecules are prepared the reaction of one or more dendritic polymers and a linear polymer. The kite-shaped macromolecules are dendritic polymers attached at either their focal points or at an outer to a long carbon chain group. The barbell macromolecules have dendritic polymers at either end of the molecule, which polymers are connected together through the focal points of each by a suitable connecting substituent such as a linear polymer. The shaped macromolecules are used in specialty medical and technological applications including such as drug delivery agents, imaging materials, molecular devices, thin film devices, surface modifiers, transport agents, compatibilizers, rheology control agents, molecular ball bearings, molecular dipoles, non-linear optical materials, medical imaging agents, membrane and cell modifiers, complexing agents, adhesives, interface strengthening agents, and the like.Type: GrantFiled: April 14, 1995Date of Patent: September 5, 2006Inventors: Jean M. J. Frechet, Craig J. Hawker, Karen Wooley
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Patent number: 7094832Abstract: The present invention suggests thermoplastic polymer particles for molding, which can solve all at once the problem of fine powder caused by suspension polymerization process, the problem of reducing energy consumption when drying caused by emulsion polymerization process and the problem of the compounding process for processors, and a process for preparing the same. 100 parts by weight of polymer particles having an average particle size of 50 to 500 ?m prepared by suspension polymerization are coated with 22 to 100 parts by weight of an emulsion polymer prepared by emulsion polymerization. A polymer suspension comprising the polymer having an average particle size of 50 to 500 ?m prepared by suspension polymerization and a polymer latex prepared by emulsion polymerization are mixed in a proportion of 22 to 100 parts by weight of the emulsion polymer based on 100 parts by weight of the suspension polymer.Type: GrantFiled: April 28, 2003Date of Patent: August 22, 2006Assignee: Kaneka CorporationInventors: Takashi Ueda, Yoshinori Takeda
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Patent number: 7056984Abstract: Disclosed is an acrylic syrup containing a vinyl monomer (A) of methyl methacrylate and a polymerized solid component (B) which is a high polymer of said vinyl monomer and has a weight average molecular weight of from 30,000 to 2,000,000 as measured by the GPC and a viscosity at 25° C. of from 0.1 to 50 Pa·s, wherein at least part of said polymerized solid component (B) is a grafted rubber obtained by graft-polymerizing said vinyl monomer with a rubbery polymer, and said grafted rubber has a large branching coefficient. The acrylic resin molded articles obtained from the acrylic syrup exhibit excellent impact resistance.Type: GrantFiled: May 15, 2002Date of Patent: June 6, 2006Assignee: Mitsubishi Gas Chemical Co., Inc.Inventors: Tadashi Kawabata, Shojiro Kuwahara, Masahiro Kurokawa
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Patent number: 7015282Abstract: The invention relates to an impact additive of the core/shell type for thermoplastic polymers. This impact additive comprises a crosslinked elastomeric core based on n-alkyl acrylate and a shell made of poly(alkyl methacrylate) grafted onto said core.Type: GrantFiled: June 2, 1998Date of Patent: March 21, 2006Assignee: Arkema Inc.Inventors: Chris Bertelo, Gilles Meunier, André Lermite, Pascale Dargelos, Xavier Drujon
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Patent number: 6927273Abstract: Processes for preparing polymers of the formula wherein m is 0 or 1, X is chlorine, bromine, or iodine, and n, e, and f are each, independently of the others, integers wherein e may be 0 and n and f are each at least 1 by providing a first reaction mixture containing a first solvent, a compound of the formula wherein Y is a chlorine or fluorine atom, a compound of the formula and optionally, a compound of the formula heating the first reaction mixture and removing generated water therefrom, thereby forming an intermediate polymer of the formula providing a second reaction mixture containing a second solvent, the intermediate polymer, and a N-halosuccinimide, wherein the halogen atom in the N-halosuccinimide is the same as the halogen atom that is X; and heating the second reaction mixture, thereby forming the polymer.Type: GrantFiled: December 17, 2002Date of Patent: August 9, 2005Assignee: Xerox CorporationInventor: Timothy P. Bender
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Patent number: 6852799Abstract: Product, method and use of a copolymer AB as a compatibilizing agent between a polar thermoplastic polymer C and a polyolefine D. The method of making AB comprise the steps of: a) melting a copolymer (A) comprising a larger amount of methylmethacrylate units and a smaller amount of functional vinyl or (meth)acrylate units wherein functional moiety is selected in the group consisting of (a hydroxyl, a carboxylic, a glycidyl or an amine functional group); together with maleic anhydride grafted polypropylene (B) allowing condensation reaction to occur between the functions under “A” and the anhydride under “B”; b) the condensation copolymer obtained under a) is further melt together with the two polymers C and D to be homogenized, or melt processed as an interlayer between the two molten polymers.Type: GrantFiled: September 10, 2001Date of Patent: February 8, 2005Assignee: Universite de LiegeInventors: Alexandre Baidak, Christine Brassine, Jean-Marie Liegeois, Trazollah Ouhadi
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Patent number: 6822052Abstract: A toughened cyanoacrylate adhesive composition including a cyanoacrylate monomer and an elastomeric copolymer soluble in the monomer, the copolymer being the reaction product of an olefin C2-20 and a (meth)acrylate ester. The invention further discloses novel elastomeric copolymers which do not contain additives or functional groups which can interfere with the cure rate or stability of the adhesive composition in which they are included. Benefits of the copolymers include improved toughness of the cured adhesive composition as measured by Dynamic Mechanical Analysis.Type: GrantFiled: September 20, 2002Date of Patent: November 23, 2004Assignee: Henkel CorporationInventors: John Woods, Susanne Morrill
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Patent number: 6803423Abstract: An (meth)acryloyl group-modified ethylene-&agr;-olefin copolymer (A) which has (meth)acryloyl group as a the side-chain thereof, wherein the intrinsic viscosity [&eegr;] was 0.01 to 10 dl/g measured in decalin at a temperature of 135° C.; and a rubber composition which comprises said (meth)acryloyl group-modified ethylene-&agr;-olefin copolymer, a vulcanizing agent, and/or a crosslinking agent; in addition, a liquid curable rubber composition which comprises, component (A), reactive diluent (D), and if necessary, photopolymerization initiator (E).Type: GrantFiled: June 17, 2002Date of Patent: October 12, 2004Assignee: JSR CorporationInventors: Toshiyuki Hayakawa, Toshihiro Nishimura, Motoharu Higuchi, Minoru Tanaka, Shoei Tsuji
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Patent number: 6765058Abstract: A crosslinkable composition of a polymeric thermoplastic and/or elastomeric material which is susceptible to scorching when processed at elevated temperatures, prior to crosslinking, in the presence of a free radical initiator, is protected against such scorching by the incorporation therein of a mixture of at least one hydroquinone compound and a sulfur accelerator. This mixture may also contain at least one monomeric allylic, methacrylic, acrylic or diene type coagent. The mixture exhibits a synergistic effect resulting in improved scorch protection for peroxide cured systems when compared with the protection afforded by the components singly.Type: GrantFiled: June 7, 1995Date of Patent: July 20, 2004Assignee: Atofina Chemicals, Inc.Inventors: Michael Fred Novits, Chester Joseph Kmiec, Edward Phillip Hibbard
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Patent number: 6750297Abstract: The present invention relates to an artificial pigment and a method of preparing the same, specifically, to an artificial pigment with excellent dry pick resistance and to a method of preparing the same. In order to accomplish the present invention, there is provided an artificial pigment of inverted core-shell structure comprising: a) a shell of butadiene polymer including: i) a seed of butadiene polymer having glass transition temperature of −10 to 50° C.; and ii) a seed covering of butadiene polymer having a glass transition temperature of −10 to 20° C.; and b) a core of styrene polymer having a glass transition temperature of 40 to 120° C. Also provided is method of preparing artificial pigment comprising: a) preparing a shell of butadiene polymer; and b) preparing a core of styrene polymer on the inner side of said shell of step a).Type: GrantFiled: July 29, 2002Date of Patent: June 15, 2004Assignee: LG Chem, Ltd.Inventors: Seung-Uk Yeu, Ho-Yeul Choi, Chang-Sun Han, Wan-Sik Cha
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Patent number: 6734230Abstract: A procedure for the production of a modified acrylic sheet with high impact resistance, of the type in which a prepolymerization is done of a mix of monomers with a polymer of dissolved dienic monomers. The procedure is done in batches at low temperatures without there being a separation of the polymer of dienic monomers from the rest of the mix. The procedure facilitates obtaining a modified acrylic sheet with high impact resistance whose transmittance is kept after being subjected to an accelerated degradation, and whose impact properties are not reduced more than 50% after said accelerated degradation.Type: GrantFiled: July 8, 2002Date of Patent: May 11, 2004Assignee: Plastiglas de Mexico, S.A. de C.V.Inventors: Sergio Colin Escobar, Manuel Ahumada Romero, José Luis Pe{overscore (n)}a Rosas, Maria Sonia Limon Rodriguez, Luis Enrique Mille Loera, Leopoldo Vilchis Ramirez
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Patent number: 6723796Abstract: Methods are disclosed for making graft copolymers. The methods comprise the steps of: (a) providing (i) an ethylene/propylene (EP) copolymer or other graftable polymer, (ii) an ethylenically unsaturated sulfur-, nitrogen- and/or oxygen-containing monomer, and (iii) an amount of an initiator sufficient to graft said monomer and EP copolymer or other graftable polymer, (b) introducing said EP copolymer or other graftable polymer into an extruder; (c) introducing said monomer into the extruder; (d) introducing said initiator into the extruder, wherein at least one of the above-identified reactants in (a) is introduced in the presence of a polar solvent; and (e) reacting said EP copolymer or other graftable polymer, monomer and initiator by operating said extruder, thereby forming the graft copolymer. This invention also relates to methods of making a dispersant viscosity index improver and methods for making a lubricating oil.Type: GrantFiled: March 11, 2002Date of Patent: April 20, 2004Assignee: Castrol LimitedInventors: Irwin L. Goldblatt, Richard P Sauer
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Patent number: 6716956Abstract: Disclosed is a process for preparing a polymer of the formula wherein x is an integer of 0 or 1, A is one of several specific groups, such as B is one of several specified groups, such as or mixtures thereof, and n is an integer representing the number of repeating monomer units, said process comprising (A) providing a reaction mixture which comprises (i) a solvent, (ii) a compound of the formula (iii) a compound of the formula (iv) a compound of the formula wherein a is an integer of from 1 to 5, R′ is a hydrogen atom, an alkyl group, an aryl group, an arylalkyl group, an alkylaryl group, an alkoxy group, an aryloxy group, an arylalkyloxy group, an alkylaryloxy group, a polyalkyleneoxy group, or a mixture thereof, and (v) a carbonate base; and (B) heating the reaction mixture and removing generated water from the reaction mixture, thereby effecting a polymerization reaction.Type: GrantFiled: January 9, 2002Date of Patent: April 6, 2004Assignee: Xerox CorporationInventors: Timothy P. Bender, Christine J. DeVisser, Richard A. Burt, Paul F. Smith, Marko D. Saban
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Patent number: 6706821Abstract: Adducts of polyfunctional acrylates and amine terminated polyolefins are provided. The adducts are prepared via a Michael addition reaction of the acrylate and the amine terminated polyolefin. The resultant adducts can be further polymerized with acrylic monomers via free radical or radiation curing mechanisms or quaternized to improve dispersion in aqueous systems.Type: GrantFiled: July 18, 2001Date of Patent: March 16, 2004Assignee: FMC CorporationInventor: Robert J. Letchford
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Publication number: 20040048982Abstract: The present invention relates to a method of preparing rubber-modified styrene copolymer resin with excellent transparency and impact resistance, specifically to a method of preparing transparent resin of rubber-modified styrene copolymer comprising graft-copolymerizing styrene monomer and (meth)acrylate monomer in the presence of block or random styrene-butadiene copolymer which has 30-50% of styrene skeleton content and 20-40 cp of 5% toluene solution viscosity at 25 ié. According to the method of the present invention, the transparent resin containing the rubber particles of a double structure comprising onion and core-shell structure can provide transparent resin of rubber-modified styrene copolymer resin with excellent transparency and impact resistance as well as good gloss.Type: ApplicationFiled: June 12, 2003Publication date: March 11, 2004Inventors: Chang-Hun Han, Oh-Jin Kwon, Dae-Woo Lee
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Patent number: 6663953Abstract: A Fresnel lens base sheet is provided which is suitable for the formation of a lens layer of an ultraviolet-cured resin and has excellent impact resistance and environmental resistance. The Fresnel lens base sheet comprises a specific rubber-modified styrene resin comprising a rubber-like elastic material as dispersed particles and a copolymer of a styrene monomer with an acrylic (methacrylic) ester monomer as a continuous phase.Type: GrantFiled: February 14, 2002Date of Patent: December 16, 2003Assignees: Asahi Kasei Kabushiki Kaisha, Dai Nippon Printing Co., Ltd.Inventors: Shunji Kamiya, Makoto Honda, Keiji Hanamoto
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Patent number: 6645562Abstract: A method of preparing a curable coating and a method of curing the curable coating are disclosed. The curable composition from which the curable coating is prepared may be applied to the surface of a substrate in neat form or in aqueous medium to produce the coating. Curing of the curable coating may be accomplished by chemical generation of free radicals, by electrochemical generation of free radicals, by electron beam, by photochemical generation of free radicals, or by other electromagnetic irradiation.Type: GrantFiled: June 27, 2002Date of Patent: November 11, 2003Inventors: Gary David Greenblatt, Ward Thomas Brown, Michael Damian Bowe, Richard Foster Merritt, Ronald Scott Beckley, Barry Clifford Lange, Robert Wilczynski, David William Whitman, Martha Harbaugh Wolfersberger
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Patent number: 6639012Abstract: A powdery high rubber impact modifier composition containing two or more populations of polymer particles having a total rubbery weight fraction of greater than 90 weight percent is provided. Aqueous polymer particle dispersions for preparing these high rubber impact modifiers which can be spray dried to a powder are also provided. Also provided are polymeric compositions having a matrix resin component and the powdery high-rubber impact modifiers.Type: GrantFiled: October 17, 2001Date of Patent: October 28, 2003Assignee: Rohm and Haas CompanyInventors: Morris Christopher Wills, Chuen-Shyong Chou, Karen Casey, Joseph Robert Adamo, Fanwen Zeng