Acyclic Hydrocarbon Contains Five Or More Carbon Atoms Patents (Class 525/320)
  • Patent number: 11829031
    Abstract: A multilayer light diffuser plate and a method for manufacturing the same are disclosed. The multilayer light diffusion plate comprises a main layer and a partially-transmissive and partially-reflective layer located under the main layer. The top surface of the main layer is the light-emitting surface, and the light-incident surface is the bottom surface of the partially-transmissive and partially-reflective layer. The partially-transmissive and partially-reflective layer comprises a plurality of first base material layers and a plurality of second base material layers stacked alternately. The materials of the first and second base material layers have different refractive indices. The partially-transmissive and partially-reflective layer formed by alternately stacking the first and second base material layers with different refractive indices is arranged on the light-incident surface of the light diffuser plate by means of extrusion, which is simpler and less expensive to manufacture.
    Type: Grant
    Filed: August 4, 2022
    Date of Patent: November 28, 2023
    Inventors: Chih Wen Yang, Yu Wei Chang, Mao Hsing Lin
  • Patent number: 11702521
    Abstract: Polymer compositions and films are provided. The polymer compositions include (A) 10-50 wt % heterogeneously branched Ziegler-Natta-catalyzed LLDPE polymer having a composition distribution breadth index (CBDI) <50.0%; and (B) 90-50 wt % metallocene-catalyzed LLDPE polymer having melt index 0.5 g/10 min to 5.0 g/10 min; melt index ratio from 20 to 40; weight average molecular weight (Mw) of from 20,000 to 200,000 g/mol; a molecular weight distribution (Mw/Mn) from 2.0 to 4.5; density 0.910 to 0.925 g/cm3; CDBI less than 35.0%; and comonomer distribution such that a first peak and a second peak in a comonomer distribution analysis, wherein the first peak has a maximum at a log(Mw) value of 4.3 to 4.7 and a TREF elution temperature of 85.0° C. to 95.0° C. and the second peak has a maximum at a log(Mw) value of 5.1 to 5.6 and a TREF elution temperature of 60.0° C. to 70.0° C.
    Type: Grant
    Filed: November 18, 2021
    Date of Patent: July 18, 2023
    Assignee: ExxonMobil Chemical Patents Inc.
    Inventors: Zhenyu Zhu, Jianya Cheng
  • Patent number: 11466147
    Abstract: The present disclosure provides a composition containing a polymeric blend. The polymeric blend contains (A) from 50 wt % to 90 wt % of a first ethylene-based polymer having a density from 0.895 g/cc to 0.905 g/cc; and a melt index from 0.1 g/10 min to 50 g/10 min; (B) from 8 wt % to 48 wt % of a second ethylene-based polymer having a density from 0.935 g/cc to 0.967 g/cc; and a melt index from 0.1 g/10 min to 180 g/10 min; and from 0.01 wt % to 2.0 wt % of a slip agent, based on the total weight of the polymeric blend. The polymeric blend has (i) an overall density from 0.900 g/cc to 0.925 g/cc; and (ii) a coefficient of friction (COF) after aging for 1 week at 60° C. from 0.001 to 0.400. The present disclosure also provides a multilayer film with a first layer containing the composition.
    Type: Grant
    Filed: June 4, 2018
    Date of Patent: October 11, 2022
    Assignee: Dow Global Technologies LLC
    Inventors: Rahul Sharma, Jong-Young Lee, Jeffrey D. Weinhold, Mridula Babli Kapur
  • Publication number: 20150057415
    Abstract: The present invention relates to a thermoplastic elastomer composition which comprises a branched olefin copolymer comprising: a main chain of an ethylene/?-olefin copolymer; and a side chain derived from a crystalline propylene polymer containing a vinyl group at one end, wherein the content of ?-olefin in the main chain is 70 mol % or less, the composition has an elongation at break of 500% or higher, and has an elastic recovery rate of 70% or more when recovering from an extension to 300% elongation, and a process for manufacturing the same.
    Type: Application
    Filed: April 24, 2014
    Publication date: February 26, 2015
    Applicants: MITSUBISHI CHEMICAL CORPORATION, CORNELL UNIVERSITY
    Inventors: Hisashi OHTAKI, Fumihiko SHIMIZU, Geoffrey W. COATES, Glenn H. FREDRICKSON
  • Publication number: 20140242015
    Abstract: Antiperspirant/deodorant compositions have lower, or even zero amounts of aluminium and/or zirconium antiperspirant actives. A polymer having one or more anhydride and/or diacid moieties, such as succinic (maleic) anhydride and/or diacid. The antiperspirant/deodorant compositions comprise a polymer with a non-zero acid value and a cationic species, which may be a cationic polymer, cationic molecule, cation, and/or a cationic carrier. Product are formed for the antiperspirant/deodorant composition, as well as a method of treating perspiration.
    Type: Application
    Filed: October 2, 2012
    Publication date: August 28, 2014
    Applicant: ISP INVESTMENTS INC.
    Inventors: Hani M. Fares, Donald I. Prettypaul
  • Patent number: 8772395
    Abstract: The present invention makes public a type of car vibration damping products using high damping rubber compound materials, involving the rubber technical field, whose features are the following ones: chloride butyl, 100; carbon black N220, 10-40; carbon black N330, 20-50; naphthenic oil H-3107, 20-40; age resister RD, 1-3; age resister 4010NA, 1-3; homogenizing agent 40MSF, 3-6; indirect zinc oxide, 5-10; magnesium oxide, 0.1-0.5; accelerating agent BZ, 1-5. By the above deployed car vibration damping products which use high dumping rubber, you get excellent heat and age resisting properties, and also high dumping properties.
    Type: Grant
    Filed: February 10, 2011
    Date of Patent: July 8, 2014
    Inventor: Lei Zhang
  • Publication number: 20130338316
    Abstract: In one aspect the invention provides a melt process for preparing a functionalized olefin multiblock interpolymer, said process comprising grafting onto the backbone of the olefin multiblock interpolymer at least one compound comprising at least one “amine-reactive” group to form a grafted olefin multiblock interpolymer, and reacting a primary-secondary diamine or an alkanolamine with the grafted olefin multiblock interpolymer, without the isolation of the grated olefin multiblock interpolymer.
    Type: Application
    Filed: May 24, 2013
    Publication date: December 19, 2013
    Applicant: Dow Global Technologies LLC
    Inventors: H. Craig Silvis, Stephen F. Hahn, David F. Pawlowski, Patricia Ansems, Laura K. Mergenhagen, Hamed Lakrout
  • Publication number: 20110262671
    Abstract: A multimodal ethylene polymer with a density of less than 950 kg/m3 obtained by polymerization with a single-site catalyst and having an MFR21 in the range of 10 to 20 g/10 min; a shear thinning index SHI2.7/210 of at least 4; and preferably a crosslinkability of at least 60%.
    Type: Application
    Filed: October 30, 2009
    Publication date: October 27, 2011
    Applicant: Borealis AG
    Inventors: Anneli Pakkanen, Markku Vahteri, Magnus Palmlof, Jeroen Oderkerk
  • Patent number: 8012558
    Abstract: Release agent more particularly for an adhesive with an ethylene multi-block copolymer, the ethylene multi-block copolymer being composed of hard segment blocks, comprising at least 95% (w/w) ethylene and a comonomer, and of soft segment blocks, comprising ethylene and a comonomer, the fraction of comonomer in the soft segment blocks being between 10 and 20 mol %, and the fraction of the hard segment blocks in the ethylene multi-block copolymer being not more than 45% (w/w).
    Type: Grant
    Filed: August 12, 2008
    Date of Patent: September 6, 2011
    Assignee: tesa SE
    Inventor: Nicole Behrens
  • Patent number: 7868097
    Abstract: A hybrid polymer has a structure in which a polyolefin segment and a polar polymer segment are connected not via a bonding group containing a heteroatom. A method of the invention produces the hybrid polymer with industrial advantages. The hybrid polymer includes a polyolefin segment (A) and a polar polymer segment (B), the polar polymer segment being obtained by radical polymerization of a radically polymerizable monomer.
    Type: Grant
    Filed: February 21, 2006
    Date of Patent: January 11, 2011
    Assignee: Mitsui Chemicals, Inc.
    Inventors: Hideyuki Kaneko, Shinichi Kojoh, Nobuo Kawahara, Shingo Matsuo, Tomoaki Matsugi, Norio Kashiwa
  • Patent number: 7858706
    Abstract: A composition for use in forming a multi-block copolymer, said copolymer containing therein two or more segments or blocks differing in chemical or physical properties, a polymerization process using the same, and the resulting polymers, wherein the composition comprises the admixture or reaction product resulting from combining: (A) a first metal complex olefin polymerization catalyst, (B) a second metal complex olefin polymerization catalyst capable of preparing polymers differing in chemical or physical properties from the polymer prepared by catalyst (A) under equivalent polymerization conditions, and (C) a chain shuttling agent.
    Type: Grant
    Filed: March 17, 2005
    Date of Patent: December 28, 2010
    Assignee: Dow Global Technologies Inc.
    Inventors: Daniel J. Arriola, Edmund M. Carnahan, Yunwa Wilson Cheung, David D. Devore, David D. Graf, Phillip D. Hustad, Roger L. Kuhlman, Colin Li Pi Shan, Benjamin C. Poon, Gordon R. Roof, James C. Stevens, Pamela J. Stirn, Timothy T. Wenzel
  • Patent number: 7696266
    Abstract: The present invention relates to select elastomeric blends including at least one halogenated random copolymer. In particular, the present invention relates to compositions including at least one halogenated random copolymer of isobutylene and methylstyrene, preferably para-methylstyrene; wherein the at least one halogenated random copolymer includes at least 9.0 wt % methylstyrene, preferably para-methylstyrene, based upon the weight of the at least one halogenated random copolymer; and at least one general purpose rubber. The invention also relates to articles made from these compositions and processes for making the same.
    Type: Grant
    Filed: September 30, 2005
    Date of Patent: April 13, 2010
    Assignee: ExxonMobil Chemical Patents Inc.
    Inventors: Walter H. Waddell, Donald S. Tracey, Stuart W. Botfeld
  • Patent number: 7615591
    Abstract: A rubber composition comprises a diene rubber component, a filler and a softening agent, in which a given amount of a filler is compounded based on 100 parts by mass of a diene rubber component, and a softening agent is included in a given amount per the filler, and not less than 60% by mass of the diene rubber component is a solution-polymerized styrene-butadiene copolymer rubber having a mass average molecular weight of not less than 1,000,000, and the filler is selected from the group consisting of carbon black, silica and an inorganic agent of a formula (I): mM.xSiOy.zH2O (wherein M is at least one metal selected from the group consisting of aluminum, magnesium, titanium and calcium, or an oxide of such a metal or a hydroxide of such a metal, m is a number of 1-5, x is a number of 0-10, y is a number of 2-5 and z is a number of 0-10), wherein each of the filler and the softening agent is charged in at least two fractions.
    Type: Grant
    Filed: February 2, 2005
    Date of Patent: November 10, 2009
    Assignee: Bridgestone Corporation
    Inventor: Hideki Matsui
  • Patent number: 7589152
    Abstract: The invention relates to an adhesive composition comprising (i) one or more styrenic block copolymer compositions, (ii) a tackifier resin, and (iii) one or more plasticizers, wherein said styrenic block copolymer composition comprises: a. a tetra-branched block copolymer (IV) represented by the general formula (A-B)4X; b. a tri-branched block copolymer (III) represented by the general formula (A-B)3X; c. a di-branched block copolymer (II) represented by the general formula (A-B)2X; and d. a linear diblock copolymer (I) represented by the general formula A-B; where: i. A represents a polymer block of a mono alkenyl arene; ii. B represents a polymer block of a mixture of isoprene and 1,3-butadiene in a weight ratio of isoprene to butadiene from about 70:30 to about 40:60; iii. X represents the residue of a multi-functional coupling agent; iv. the weight percent of A blocks is from about 14% to about 22%; v.
    Type: Grant
    Filed: December 13, 2004
    Date of Patent: September 15, 2009
    Assignee: Kraton Polymers U.S. LLC
    Inventor: Donn A. DuBois
  • Publication number: 20090105407
    Abstract: An adhesive composition comprising a copolymer of propylene and at least one comonomer selected from the group consisting of ethylene and C4-20?-olefins, the copolymer having (i) a content of units derived from propylene of greater than about 50 mole percent, (ii) a Brookfield viscosity at 190 C from about 50 to about 100,000 cP, (iii) an MWD from about 1.5 to about 15, and (iv) containing less than about 50 ppm residual catalyst metal.
    Type: Application
    Filed: December 21, 2005
    Publication date: April 23, 2009
    Inventors: Teresa P. Karjala, Patricia Ansems, Charles F. Diehl, Selim Yalvac, Cynthia L. Rickey, Seema V. Karande, Angela N. Taha
  • Publication number: 20080125521
    Abstract: The present invention relates to select elastomeric blends including at least one halogenated random copolymer. In particular, the present invention relates to compositions including at least one halogenated random copolymer of isobutylene and methylstyrene, preferably para-methylstyrene; wherein the at least one halogenated random copolymer includes at least 9.0 wt % methylstyrene, preferably para-methylstyrene, based upon the weight of the at least one halogenated random copolymer; and at least one general purpose rubber. The invention also relates to articles made from these compositions and processes for making the same.
    Type: Application
    Filed: September 30, 2005
    Publication date: May 29, 2008
    Inventors: Walter H. Waddell, Donald S. Tracey, Stuart W. Botfeld
  • Patent number: 7160950
    Abstract: A modified olefin-based copolymer produced by graft-polymerizing an alkenyl aromatic hydrocarbon and/or an unsaturated carboxylic acid or derivative thereof to an olefin-based copolymer containing repeating units derived from a linear ?-olefin and/or ethylene copolymer of ethylene and repeating units derived from a vinyl compound (I) or (II) described below, and an adhesive containing the product as an effective ingredient, in which an adhesiveness to an adherend such as olefin resins (e.g. polyethylene, polypropylene) is further improved, are provided. Vinyl compound (I): a vinyl compound represented by the general formula CH2?CH—R, wherein steric parameters Es and B1 of the substituent R are respectively ?1.64 or less and 1.53 or more. Vinyl compound (II): a vinyl compound represented by the general formula CH2?CH—R?, wherein a substituent R? is a secondary or tertiary alkyl group.
    Type: Grant
    Filed: August 6, 2002
    Date of Patent: January 9, 2007
    Assignee: Sumitomo Chemical Company, Limited
    Inventors: Toshiki Mori, Nobuo Oi
  • Patent number: 7101936
    Abstract: A method of lowering MFR response of a high-melt-flow-rate-polymer-producing metallocene catalyst is provided. The method includes contacting the metallocene catalyst with a sufficient quantity of ?,?-diene monomer such that when the catalyst composition is contacted with polymerizable reactants under suitable polymerization conditions, the resulting polymer has an MFR rate in the range of 0.1 to 1000. Hydrogen and ethylene may also be present in the polymerization. Additionally a catalyst composition is provided which includes a high-melt-flow-rate-polymer-producing metallocene catalyst and a sufficient quantity of ?,?-diene monomers such that when the catalyst composition is contacted with a monomer under polymerization conditions, the resulting polymer has an MFR rate in the range of 0.1 to 1000.
    Type: Grant
    Filed: December 18, 2001
    Date of Patent: September 5, 2006
    Assignee: ExxonMobil Chemical Patents Inc.
    Inventors: Weiqing Weng, Aspy K. Mehta, Pawan K. Agarwal, Armenag Dekmezian
  • Publication number: 20040102579
    Abstract: The present invention relates to a thermoplastic styrenic resin composition comprises a styrenic copolymer comprising 15-100 parts by weight of a unit derived from a styrenic monomer (i-1), 0-45 parts by weight of a unit derived from a vinyl cyanide monomer (i-2), 0-40 parts by weight of a unit derived from a copolymerizable vinyl monomer (i-3) other than the above monomers, and 0.0005-1.0 parts by weight of a unit derived from a polyfunctional maleimide monomer, all based on 100 parts by weight of the total amount of (i-1) to (i-3). The thermoplastic styrenic resin composition manufactured in the present invention is excellent in processability. The rubber modified thermoplastic styrenic resin composition of the present invention gives a good heat stability, impact strength, fluidity and other mechanical properties. In addition, it also gives a uniform wall thickness, and the gloss on the surface of injected products after painting process is excellent.
    Type: Application
    Filed: November 7, 2003
    Publication date: May 27, 2004
    Inventor: Wen-Yi Su
  • Patent number: 6437048
    Abstract: A plastic molded product of olefin (co)polymer composition comprises 0.01-5.0 weight parts high molecular weight polyethylene with an intrinsic viscosity &eegr;E in the range of 15-100 dl/g measured in 135° C. tetralin and preferably 100 weight parts polypropylene. The high molecular weight polyethylene has an average particle size in the range of 1-5000 nm and is finely dispersed as fine granules in the polypropylene, so that high melt strength and high crystallization temperature are attained, enabling various molding methods to be performed with high speed productivity. Using the polymer composition, plastics such as a resin foam, a film, a sheet, a layered plastic article with a coated substrate surface, a hollow plastic article, an injection molded plastic article, a fiber, a nonwoven web or a continuous tube-shaped plastic are provided. The olefin (co)polymer composition is obtained by preparing high molecular weight polyethylene granules using e.g.
    Type: Grant
    Filed: July 7, 1998
    Date of Patent: August 20, 2002
    Assignee: Chisso Corporation
    Inventors: Jun Saito, Hideo Nobuhara, Shingo Kikukawa, Hitoshi Sato, Akira Yamauchi, Kazuhiro Kimura, Tadashi Tanaka, Yoichi Kugimiya, Yoshitaka Morimoto, Hiroaki Ito, Tooru Fukazawa, Hiroyuki Maehara, Yasuhiro Shiraishi, Yuichi Yamanaka, Masataka Sugimoto, Hirohisa Ishii, Masahiko Taniguchi, Toshiki Yamamoto, Yasuhiko Nakagawa, Junichiro Yokota, Shouji Kawano
  • Patent number: 6417281
    Abstract: The invention is directed to essentially saturated hydrocarbon polymer composition comprising essentially saturated hydrocarbon polymers having A) a backbone chain; B) a plurality of essentially hydrocarbyl sidechains connected to A), said sidechains each having a number-average molecular weight of from 2500 Daltons to 125,000 Daltons and a MWD by SEC of 1.0-3.5; and having A) a Newtonian limiting viscosity (&eegr;0) at 190° C. at least 50% greater than that of a linear olefinic polymer of the same chemical composition and weight average molecular weight, preferably at least twice as great as that of said linear polymer, B) a ratio of the rubbery plateau modulus at 190° C. to that of a linear polymer of the same chemical composition less than 0.5, preferably <0.3, C) a ratio of the Newtonian limiting viscosity (&eegr;0) to the absolute value of the complex viscosity in oscillatory shear (&eegr;*)at 100 rad/sec at 190° C.
    Type: Grant
    Filed: August 23, 2001
    Date of Patent: July 9, 2002
    Assignee: ExxonMobil Chemical Patents Inc.
    Inventors: Cesar A. Garcia-Franco, David J. Lohse, Robert A. Mendelson, Lewis J. Fetters, Scott T. Milner, Nikos Hadjichristidis, David W. Mead
  • Patent number: 6414102
    Abstract: The invention relates to polyolefin copolymers (I) and to graft copolymers (II) which are prepared from the copolymers (I), wherein the copolymers (I) are linear copolymers containing divinylbenzene comonomer units selected from the group consisting of 1,4-divinylbenzene units, mixtures of 1,4- and 1,3-divinylbenzene units and mixtures of 1,4-, 1,3- and 1,2-divinylbenzene units, wherein R, in formulas I and II, is a C1 to C10 linear or branched alkyl group or a C6 to C10 substituted or unsubstituted aromatic group; and wherein G and G′, independently, are selected from —H, —OH, epoxy, —NH2, —COOH, anhydride, —Cl, —Br, —M, —COOM (M=metal) or a polymer chain having the molecular weight of at least about 500, which can be derived from both step and chain polymerization reactions. In the graft copolymer (II), the combined alpha-olefin mole % (x+y) is from about 50 and 99.
    Type: Grant
    Filed: March 19, 2001
    Date of Patent: July 2, 2002
    Assignee: The Penn State Research Foundation
    Inventors: Tze-Chiang Chung, Jin Yong Dong
  • Patent number: 6399683
    Abstract: A resin composition for extruded forms that has improved workability, and excellent properties with respect to transparency, heat resistance, low-temperature resistance, etc. The composition contains 50 to 99% by weight of component A, which is a copolymer of ethylene and &agr;-olefin, and 1 to 50% by weight of component B, which is an ethylene-containing polymer. The component A has: (a) a melt flow rate (MFR) of 0.1 to 5 g/10 min.; (b) a density D of 0.88 to 0.
    Type: Grant
    Filed: November 10, 1997
    Date of Patent: June 4, 2002
    Assignee: Mitsubishi Chemical Corporation
    Inventors: Koji Yamamoto, Hajime Ikeno, Keiko Shichijo
  • Patent number: 6388020
    Abstract: Structurally isomeric poly(alkyl ethylenes) with H and Y structures, polymeric bridging segments and a Y index of 2×10−3 to 8×10−3 (kJ/mole/degree), have decreased instability in the melt and more advantageous processing properties. The structurally isomeric poly(alkyl ethylenes) with H and Y structures are synthesized by an irradiating method, a melt reaction method or a solid phase reaction method by reacting poly(alkyl ethylenes) with 0.05 to 5% by weight of monofunctional, difunctional and polyfunctional monomers, optionally in the presence of peroxides. The structurally isomeric poly(alkyl ethylenes) are suitable for producing films, sheets, panels, coatings, pipes, hollow objects and foams.
    Type: Grant
    Filed: January 27, 1997
    Date of Patent: May 14, 2002
    Assignee: Borealis GmbH
    Inventors: Manfred Raetzsch, Achim Hesse, Hartmut Bucka, Norbert Reichelt, Ulf Panzer, Konrad Buehler
  • Publication number: 20020042472
    Abstract: A class of relatively high molecular weight, high density ethylene polymers (HMW-HDPE) is disclosed capable of being formed into thin films of high strength, such polymers having a density of at least about 0.935 g/cc, a flow index (I21) no higher than about 15 g/10 min., a melt flow ratio (MFR) of at least about 65, and a dynamic elasticity at 0.1 rad./sec. of no higher than about 0.7 at a corresponding complex viscosity at 0.1 rad./sec. no higher than about 14E5, i.e., about 14×105 poises.
    Type: Application
    Filed: October 2, 2001
    Publication date: April 11, 2002
    Inventors: S. Christine Ong, Sandra D. Schregenberger, Pradeep P. Shirodkar
  • Patent number: 6355735
    Abstract: A semi-interpenetrating polymer network including at least one epoxy monomer, at least one olefin monomer forming a co-monomer mixture with the epoxy monomer and a catalytic amount of at least one palladium compound uniformly distributed in said co-monomer mixture to promote formation of the semi-interpenetrating polymer network under ambient conditions.
    Type: Grant
    Filed: August 17, 1999
    Date of Patent: March 12, 2002
    Assignee: 3M Innovative Properties Company
    Inventors: Mark I. Wagner, Stephen D. Meyer
  • Patent number: 6316549
    Abstract: Fibers made from formulated ethylene polymer compositions are disclosed. The ethylene polymer compositions have at least one homogeneously branched linear ethylene/&agr;-olefin interpolymer and at least one heterogeneously branched ethylene polymer. The homogeneously branched linear ethylene/&agr;-olefin interpolymer has a density from about 0.905 to about 0.92 g/cm3 and a slope of strain hardening coefficient greater than or equal to about 1.3.
    Type: Grant
    Filed: November 26, 1997
    Date of Patent: November 13, 2001
    Assignee: The Dow Chemical Company
    Inventors: Pak-Wing Steve Chum, Ronald P. Markovich, George W. Knight, Shih-Yaw Lai
  • Patent number: 6316546
    Abstract: A class of relatively high molecular weight, high density ethylene polymers (HMW-HDPE) is disclosed capable of being formed into thin films of high strength, such polymers having a density of at least about 0.925 g/cc, a flow index (I21) no highier than about 15 g/10 min., a melt flow ratio (MFR) of at least about 65, and a dynamic elasticity at 0.1 rad./sec. of no higher than about 0.7 at a corresponding complex viscosity at 0.1 rad./sec. no highier than about 14E5, i.e., about 14×105 poises. The ethylene polymer is a bimodal blend of relatively high molecular weight (HMW) and low molecular weight (LMW) ethylene polymers.
    Type: Grant
    Filed: June 28, 1993
    Date of Patent: November 13, 2001
    Assignee: ExxonMobil Oil Corporation
    Inventors: S. Christine Ong, Sandra D. Schregenberger, Pradeep P. Shirodkar
  • Patent number: 6313228
    Abstract: A process peroxidically treats olefin polymers with di-tert-butyl peroxide in an extruder. The olefin polymers together with di-tert-butyl peroxide under an inert gas are fed to an extruder. The olefin polymers are used in a finely divided form at from 55 to 110° C. The use of peroxidically treated olefin polymers for producing moldings, fibers, films or nonwoven spunbond fabrics is described, as is a process for producing moldings, fibers, films or nonwoven spunbond fabrics.
    Type: Grant
    Filed: November 17, 1999
    Date of Patent: November 6, 2001
    Assignee: Basell Polyolefine GmbH
    Inventors: Karl Huber, Jürgen Schwind, Klaus Lehr, Hermann Elser, Horst Klassen, Karl-Heinz Kagerbauer
  • Patent number: 6265493
    Abstract: The invention relates to a process for preparing polyolefin graft copolymers (II) from linear and well defined polyolefin copolymers (I) containing divinylbenzene comonomer units, wherein R, in formulas I and II, is a C1 to C10 linear or branched alkyl group or a C6 to C10 substituted or unsubstituted aromatic group; and wherein G and G′, independantly, are selected from —H, —OH, epoxy, —NH2, —COOH, anhydride, —Cl, —Br, —M, —COOM (M=metal, e.g., Li, Na, K and Ca) or a polymer chain having the molecular weight of at least about 500, which can be derived from both step and chain polymerization reactions. G and G′ can be selected singly or in a combination of two or more thereof. In the graft copolymer composition, the combined alpha-olefin mole .% (x+y) is from about 50 to 99.9 mole %. Preferably, x+y is from 85 to 99.9 mole %, and most preferably x+y is from 95 to 99.9 mole %.
    Type: Grant
    Filed: May 18, 2000
    Date of Patent: July 24, 2001
    Assignee: The Penn State Research Foundation
    Inventors: Tze-Chiang Chung, Jinyong Dong
  • Patent number: 6204422
    Abstract: A rational technical process for producing dialkylnaphthalenes from petroleum-derived starting materials which exist in abundance is established.
    Type: Grant
    Filed: November 4, 1998
    Date of Patent: March 20, 2001
    Assignee: Fuji Oil Company, Ltd.
    Inventors: Toshio Tsutsui, Takumi Sasaki, Yoshitaka Satou, Osamu Kubota, Shinichi Okada, Masaki Fujii
  • Patent number: 6194520
    Abstract: A class of relatively high molecular weight, high density ethylene polymer blends is disclosed capable of being blow molded with excellent processability into articles, e.g., bottles, of superior mechanical and other properties, such blends having a density of at least about 0.930 g/cc, a flow index (I21) of at least about 2 g/10 min., a melt flow ratio (MFR) of at least about 60, and a polydispersity index of at least about 8, the polymers of said blend consisting essentially of at least about 0.3 weight fraction of a relatively high molecular weight (HMW) component having a density of at least about 0.900 g/cc, a flow index or high load melt index (I21) of at least about 0.2 g/10 min., and a flow ratio (FR) at least about 10, and a relatively low molecular weight (LMW) component having a density of at least about 0.930 g/cc and a melt index (I2) no greater than about 1000 g/10 min.
    Type: Grant
    Filed: June 28, 1993
    Date of Patent: February 27, 2001
    Assignee: Mobil Oil Corporation
    Inventors: Subrahmanyam Cheruvu, Thomas E. Nowlin, S. Christine Ong, Giyarpuram N. Prasad, Paul P. Tong
  • Patent number: 6156845
    Abstract: An olefin (co-)polymer composition including 0.01 to 5.0 weight parts of high molecular weight polyethylene which is an ethylene homopolymer or an ethylene-olefin copolymer containing 50 weight % or more of an ethylene polymerization unit; and 100 weight parts of an olefin (co-)polymer other than the high molecular weight polyethylene, wherein said high molecular weight polyethylene has an intrinsic viscosity [.eta..sub.E ] of 15 to 100 dl/g measured in tetralin at 135.degree. C. or more, and said high molecular weight polyethylene exists as dispersed fine particles having a numerical average particle size of 1 to 5000 nm.
    Type: Grant
    Filed: April 2, 1997
    Date of Patent: December 5, 2000
    Assignee: Chisso Corporation
    Inventors: Jun Saito, Hideo Nobuhara, Shingo Kikukawa, Hitoshi Sato, Akira Yamauchi
  • Patent number: 6140425
    Abstract: A graft copolymer containing anhydride groups is made by (1) making a graft copolymer comprising a backbone of a propylene polymer material having graft polymerized thereto polymerized monomers selected from the group consisting of (a) at least one acrylic acid substituted with a 1-3 C alkyl group and (b) a mixture of at least one of these substituted acrylic acids and a vinyl compound capable of copolymerizing therewith, wherein the total amount of polymerized monomers is about 20 parts to about 240 parts per hundred parts of the propylene polymer material and the amount of the substituted acrylic acid is 60 mole % or more of the polymerized monomers, and (2) heating the graft copolymer to a temperature of about 170.degree. C. to about 300.degree. C. to dehydrate the acid groups in the graft copolymer to form anhydride groups.
    Type: Grant
    Filed: August 25, 1997
    Date of Patent: October 31, 2000
    Assignee: Montell North America Inc.
    Inventors: Anthony J. DeNicola, Jr., Abuzar Syed
  • Patent number: 6114457
    Abstract: The invention is a polyethylene composition having a polydispersity index of less than or equal to 3, an average branching index (g') as measured by GPC/Vis.gtoreq.0.9, and a melt strength (MS) (centiNewton, 190.degree. C.) that satisfies the relationship: ##EQU1## In a preferred embodiment these polyethylene compositions comprise A) branched polyethylene copolymers prepared by insertion polymerization of ethylene, ethylene-containing macromers, and optionally, additional copolymerizable monomers, and B) essentially linear ethylene copolymers. Improved melt strength without sacrificing the benefits of narrow polydispersity index are exhibited by the invention compositions.
    Type: Grant
    Filed: February 6, 1998
    Date of Patent: September 5, 2000
    Assignee: Exxon Chemical Patents Inc.
    Inventors: Eric J. Markel, Carlos U. DeGracia, Armen H. Dekmezian
  • Patent number: 6111023
    Abstract: Fabricated articles made from formulated ethylene polymer compositions are disclosed. Films made from such formulated compositions have surprisingly good impact and tensile properties, and an especially good combination of modulus and toughness. The ethylene polymer compositions have at least one homogeneously branched substantially linear ethylene/.alpha.-olefin interpolymer and at least one heterogeneously branched ethylene polymer. The homogeneously branched substantially linear ethylene/.alpha.-olefin interpolymer has a density from about 0.89 to about 0.92 g/cm.sup.3 and a slope of strain hardening coefficient greater than or equal to about 1.3.
    Type: Grant
    Filed: August 27, 1997
    Date of Patent: August 29, 2000
    Assignee: The Dow Chemical Company
    Inventors: Pak-Wing Steve Chum, George W. Knight, Ronald P. Markovich, Shih-Yaw Lai
  • Patent number: 6087456
    Abstract: A curable composition comprising the components (A), (B), (C) and (D), viz.(A) an isobutylene polymer which contains in a molecule, at least one alkenyl group capable of hydrosilylation reaction;(B) a curing agent which contains at least two hydrosilyl groups in a molecule;(C) a hydrosilylation catalyst; and(D) an organic compound which contains in a molecule, at least one alkenyl or alkynyl group capable of hydrosilylation reaction.This composition is excellent in workability because of its low viscosity, and has such advantages that the cured product thereof has large strength and further that the weight loss by heating is small. Since a large amount of an inorganic filler can be blended with this composition, it is possible to obtain a composition having high thixotropy and little sagging.
    Type: Grant
    Filed: November 25, 1997
    Date of Patent: July 11, 2000
    Assignee: Kaneka Corporation
    Inventors: Masashi Sakaguchi, Yoshimichi Yamanaka, Makoto Chiba, Toshihiko Okamoto, Yuriko Asai, Jyunji Takase
  • Patent number: 6057397
    Abstract: There is provided a silica-containing diene rubber composition superior in resiliene (which is an indication of rolling resistance), at least equal, in tensile strength and abrasion resistance, to carbon black-containing diene rubber compositions, and good in processability and hardness property. The silica-containing diene rubber composition is characterized by containing, as the diene rubber component, a hydroxyl group-containing diene rubber having a weight-average molecular weight of 50,000 or more, or a blend of the hydroxyl group-containing diene rubber and other diene rubber.
    Type: Grant
    Filed: November 13, 1997
    Date of Patent: May 2, 2000
    Assignee: Nippon Zeon Co., Ltd.
    Inventors: Yukio Takagishi, Masao Nakamura
  • Patent number: 6015862
    Abstract: Functionalized terpolymers of two different .alpha.-olefin and para-alkylstyrene are disclosed, wherein the functionalized terpolymers have a substantially homogeneous compositional distribution represented by the formula: ##STR1## in which R.sub.1, R.sub.2, R' and R" independently, are hydrogen or a primary or secondary alkyl group; X is a functional group, such as --COOH, --OH, --SH, --NH.sub.2, --Cl, --Br, --M, --COOM (M =metals, e.g. Li, Na, K and Ca) and anhydrides; P is a polymer having a molecular weight of at least 500; Y is chemical linkage between polymer P and para-alkystyrene side chain; and the combination of a+b+c+d+e represents the empirical formula of a substantially random functional polymer; where both a and b are greater than 0; where the sum of a+b ranges from about 50 to 100,000; where each of c, d and e range from 0 to 10,000; where both d and e can not be 0; and where the sum of c+d+e is at least 1.
    Type: Grant
    Filed: October 23, 1998
    Date of Patent: January 18, 2000
    Assignee: The Penn State Research Foundation
    Inventors: Tze-Chiang Chung, Honglan Lu
  • Patent number: 5942580
    Abstract: An acrylic rubber composition comprising a halogen-containing acrylic rubber, a vulcanizing agent and at least one unsaturated compound selected from the group consisting of (1) .alpha.-olefins having at least 4 carbon atoms, (2) carboxylic acid vinyl esters, (3) alkyl vinyl ethers, (4) lower alkyl cyclohexenes or cyclohexenecarboxylic acid caprolactone esters and (5) unsaturated dicarboxylic acid diesters can give vulcanization products having an improved compression set without any substantial deterioration of normal state physical properties and resistance to heat ageing of the vulcanization products, where the unsaturated compound gives off no unpleaseant odor without any skin irritation when vulcanized and without lowering the mold releasability.
    Type: Grant
    Filed: March 5, 1996
    Date of Patent: August 24, 1999
    Assignee: Nippon Mektron, Limited
    Inventors: Tamotsu Yoshida, Jun Okabe
  • Patent number: 5741861
    Abstract: A resin composition containing 50 to 99% by weight of component A, which is a copolymer of ethylene and .alpha.-olefin, and 1 to 50% by weight of component B, which is a high-pressure low-density polyethylene. The component A has (a) a melt flow rate (MFR) of 2 to 30 g/10 min., (b) a density of not more than 0.935 g/cm.sup.3, and (c) a single peak of elution volume indicated by an elution curve obtained by temperature rising elution fractionation, the peak corresponding to a temperature within a range of from 20.degree. C. to 85.degree. C., and the elution curve satisfying a relationship in which the ratio H/W is not less than 1 when H represents the height of the peak and W represents the width of the elution curve at half of the height H. The component B has (a') a melt flow rate of 0.1 to 20 g/10 min., (b') a density of 0.915 to 0.93 g/cm.sup.3, ('c) a memory effect (ME) of not less than 1.6, and (d') a melt tension (MT) of not less than 1.5 g.
    Type: Grant
    Filed: March 23, 1995
    Date of Patent: April 21, 1998
    Assignee: Mitsubishi Chemical Corporation
    Inventors: Koji Yamamoto, Hajime Ikeno, Keiko Shichijo
  • Patent number: 5731082
    Abstract: A cable comprising one or more electrical conductors or a core of one or more electrical conductors, each conductor or core being surrounded by a layer of insulation comprising a multimodal copolymer of ethylene and one or more alpha-olefins, each alpha-olefin having 3 to 8 carbon atoms, the copolymer having a broad comonomer distribution as measured by TREF with a value for the percent of copolymer, which elutes out at a temperature of greater than 90 degrees C., of greater than about 5 percent; a WTGR value of less than about 20 percent; a melt index in the range of about 0.1 to about 30 grams per 10 minutes; and a density in the range of 0.880 to 0.950 gram per cubic centimeter, and being prepared by a low pressure process.
    Type: Grant
    Filed: June 24, 1996
    Date of Patent: March 24, 1998
    Assignee: Union Carbide Chemicals & Plastics Technology Corporation
    Inventors: Laurence Herbert Gross, Alfred Mendelsohn
  • Patent number: 5677375
    Abstract: A gas phase process for the production of an in situ polyethylene blend comprising contacting ethylene and at least one alpha-olefin comonomer having 3 to 8 carbon atoms with a magnesium/titanium based catalyst system including an activator and a cocatalyst in each of two fluidized bed reactors corrected in series, under polymerization conditions, with the provisos that:(a) the mixture of ethylene copolymer matrix and active catalyst formed in the first reactor in the series is transferred to the second reactor in the series;(b) other than the active catalyst referred to in proviso (a) and the cocatalyst referred to in proviso (f), no additional catalyst is introduced into the second reactor;(c) in the first reactor in which a relatively high molecular weight copolymer is made:(1) the alpha-olefin is present in a ratio of about 0.01 to about 0.4 mole of alpha-olefin per mole of ethylene; and(2) optionally, hydrogen is present in a ratio of about 0.001 to about 0.
    Type: Grant
    Filed: March 29, 1996
    Date of Patent: October 14, 1997
    Assignee: Union Carbide Chemicals & Plastics Technology Corporation
    Inventors: Mahmoud R. Rifi, Carlo F. Martino
  • Patent number: 5677383
    Abstract: Fabricated articles made from formulated ethylene polymer compositions are disclosed. Films made from such formulated compositions have surprisingly good impact and tensile properties, and an especially good combination of modulus and toughness. The ethylene polymer compositions have at least one homogeneously branched substantially linear ethylene/.alpha.-olefin interpolymer and at least one heterogeneously branched ethylene polymer. The homogeneously branched substantially linear ethylene/.alpha.-olefin interpolymer has a density from about 0.89 to about 0.92 g/cm.sup.3 and a slope of strain hardening coefficient greater than or equal to about 1.3.
    Type: Grant
    Filed: October 18, 1995
    Date of Patent: October 14, 1997
    Assignee: The Dow Chemical Company
    Inventors: Pak-Wing Steve Chum, Ronald P. Markovich, George W. Knight, Shih-Yaw Lai
  • Patent number: 5665800
    Abstract: Substantially linear olefin polymers having a melt flow ratio I.sub.10 /I.sub.2,.gtoreq.5.63, a molecular weight distribution, M.sub.w /M.sub.n, defined by the equation: M.sub.w /M.sub.n .ltoreq.(I.sub.10 /I.sub.2)-4.63, and a critical shear stress at onset of gross melt fracture of greater than about 4.times.10.sup.6 dyne/cm.sup.2 and their method of manufacture are disclosed. The substantially linear olefin polymers preferably have at least about 0.01 long chain branches/1000 carbons and a molecular weight distribution from about 1.5 to about 2.5. The new polymers have improved processability over conventional olefin polymers and are useful in producing fabricated articles such as fibers, films, and molded parts.
    Type: Grant
    Filed: October 16, 1996
    Date of Patent: September 9, 1997
    Assignee: The Dow Chemical Company
    Inventors: Shih-Yaw Lai, John R. Wilson, George W. Knight, James C. Stevens
  • Patent number: 5605969
    Abstract: In accordance with the present invention, there is provided a method for the preparation of an ethylene polymer composition having a density of 0.86-0.94 g/cm.sup.3 and an intrinsic viscosity [.eta.] of 1-6 dl/g using an olefin polymerization catalyst composed of a transition metal compound containing a ligand having a cycloalkadienyl skeleton and an organoaluminium oxy-compound, and there is also provided a method for the preparation of an ethylene polymer composition having density of 0.87-0.93 g/cm3 and an intrinsic viscosity [.eta.] of 0.5-6 dl/g.
    Type: Grant
    Filed: October 25, 1993
    Date of Patent: February 25, 1997
    Assignee: Mitsui Petrochemical Industries, Ltd.
    Inventors: Toshiyuki Tsutsui, Takashi Ueda
  • Patent number: 5589549
    Abstract: Multistage process for the polymerization of olefins CH.sub.2 .dbd.CHR, where R is hydrogen or an alkyl, cycloalkyl or aryl radical with 1-10 carbon atoms, comprising two stages of polymerization. In a first stage, in the presence of a titanium or a vanadium catalyst and working in one or more reactors, an olefinic polymer with particular values of porosity is prepared; in a second stage, in the presence of the said porous polymer and a metallocene compound and/or their reaction products, one or more olefins, that are equal to or different from those polymerized in the first stage, are polymerized in one or more reactors.
    Type: Grant
    Filed: June 5, 1995
    Date of Patent: December 31, 1996
    Assignee: Montell Technology Company bv
    Inventors: Gabriele Govoni, Mario Sacchetti, Stefano Pasquali
  • Patent number: 5561195
    Abstract: Polymeric compositions based on Linear Low Density Polyethylene (LLDPE) comprising: (A) from 75 to 95% by weight of an ethylene copolymer with an .alpha.-olefin CH.sub.2 =CHR, wherein R is an alkyl radical having from 1 to 10 carbon atoms, and (B) from 5 to 25% by weight of a copolymer of propylene with ethylene and an .alpha.-olefin CH.sub.2 =CHR.sup.I, wherein R.sup.I is an alkyl radical having from 2 to 10 carbon atoms. Copolymer (B) is characterised by a relatively high insolubility in xylene. The polymeric compositions of the invention are endowed with improved processability and improved mechanical properties with respect to the LLDPE of the conventional type.
    Type: Grant
    Filed: January 20, 1995
    Date of Patent: October 1, 1996
    Assignee: Montell Technology Company bv
    Inventors: Gabriele Govoni, Massimo Covezzi, Claudio Cometto
  • Patent number: 5519091
    Abstract: In accordance with the present invention, there is provided a method for the preparation of an ethylene polymer composition having a density of 0.86-0.94 g/cm.sup.3 and an intrinsic viscosity [.eta.] of 1-6 dl/g using an olefin polymerization catalyst composed of a transition metal compound containing a ligand having a cycloalkadienyl skeleton and an organoaluminium oxy-compound, and there is also provided a method for the preparation of an ethylene polymer composition having density of 0.87-0.93 g/cm3 and an intrinsic viscosity [.eta.] of 0.5-6 dl/g.
    Type: Grant
    Filed: May 31, 1995
    Date of Patent: May 21, 1996
    Assignee: Mitsui Petrochemical Industries, Ltd.
    Inventors: Toshiyuki Tsutsui, Takashi Ueda
  • Patent number: 5514455
    Abstract: A film comprising a blend of copolymers, which has been (i) extruded to a gauge in the range of about 0.3 to about 0.9 mil, said film having an Elmendorf Tear Strength in the machine direction of at least about 25 grams per mil greater than the Elmendorf Tear Strength in the machine direction of the same blend of copolymers, which has been extruded to a gauge of one mil, or (ii) extruded to a heavy gauge of at least about 5 mils and then biaxially oriented and reduced to a gauge of about 1.5 mils or less, first in the machine direction at a gauge reduction ratio of at least about 2:1, and then in the transverse direction at a gauge reduction ratio of at least about 1.5:1, said blend having been produced in situ by contacting ethylene and at least one alpha-olefin comonomer having 3 to 8 carbon atoms with a magnesium/titanium based catalyst system in each of two reactors connected in series, under polymerization conditions.
    Type: Grant
    Filed: July 8, 1994
    Date of Patent: May 7, 1996
    Assignee: Union Carbide Chemicals & Plastics Technology Corporation
    Inventors: William J. Michie, Jr., Guylaine St. Jean