Block Copolymer Derived From Acyclic Hydrocarbon Containing Five Or More Carbon Atoms Patents (Class 525/321)
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Patent number: 11292899Abstract: An object of the present invention is to provide a highly heat resistant and highly rigid propylene-based polymer having unprecedentedly high stereoregularity. The propylene-based polymer of the present invention satisfies requirements (1) to (4) and preferably requirement (5): (1) an average meso chain length is 800 to 100,000; (2) a MFR is 0.5 to 1,000 g/10 minutes; (3) a ratio of Mw to Mn, Mw/Mn, as measured by GPC is 4.2 to 20; (4) when the ratio of a component which elutes at a temperature of 122° C. or more as measured by temperature rising elution fractionation (TREF) is A % by weight and the melt flow rate of the requirement (2) is B g/10 minutes, 100?A?20×EXP(?0.01×B); (5) an amount of a component soluble in n-decane at 23° C. is 0.01 to 2% by weight.Type: GrantFiled: June 29, 2018Date of Patent: April 5, 2022Assignees: MITSUI CHEMICALS, INC., PRIME POLYMER CO., LTD.Inventors: Yasuhiro Kai, Naoya Noda, Kenji Michiue, Keita Itakura
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Patent number: 11242684Abstract: A thermoplastic roofing membrane including a planar thermoplastic sheet, optionally having more than one layer, where at least one layer of the membrane includes an ethylene-based olefinic block copolymer, and where the sheet is characterized by a storage modulus of less than 450 MPa at 0° C.Type: GrantFiled: February 8, 2016Date of Patent: February 8, 2022Assignee: Firestone Building Products Company, LLCInventors: Hao Wang, Michael John Hubbard, Dwayne Wacenske, Donna C. Tippmann
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Patent number: 10865302Abstract: A resin composition including a hydrogenated block copolymer product [D] and a plasticizer, wherein: the hydrogenated product [D] is a hydrogenated product obtained by hydrogenating a block copolymer [C] composed of a polymer block [A] containing a repeating unit [I] derived from an aromatic vinyl compound as a main component, and a polymer block [B] containing the repeating unit [I] derived from an aromatic vinyl compound and a repeating unit [II] derived from a chain conjugated diene compound as main components; a ratio of the block [A] and the block [B], and a ratio of the unit [I] and the unit [II] are in specific ranges, and, in the hydrogenated product [D], 90% or more of all unsaturated bonds in the block copolymer [C] are hydrogenated.Type: GrantFiled: January 10, 2017Date of Patent: December 15, 2020Assignee: ZEON CORPORATIONInventors: Hiromu Mashima, Takamichi Inomata
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Patent number: 9994653Abstract: Provided are a novel metallocene compound, a catalyst composition including the same, and a method of preparing an olefin-based polymer using the same. The metallocene compound according to the present invention or the catalyst composition including the same may be used for the preparation of an olefin-based polymer, may have excellent polymerization ability, and may produce an olefin-based polymer having a high molecular weight. In particular, when the metallocene compound according to the present invention is employed, an olefin-based polymer having a high molecular weight may be polymerized because the metallocene compound shows high polymerization activity even when it is supported on a support and maintains high activity even in the presence of hydrogen because of its low hydrogen reactivity.Type: GrantFiled: January 28, 2015Date of Patent: June 12, 2018Assignee: LG CHEM, LTD.Inventors: Yong Ho Lee, Kyung Jin Cho, Jin Young Park, Ki Soo Lee, Min Seok Cho, Se Young Kim, Sung Min Lee, Chang Woan Han
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Patent number: 9994652Abstract: Provided are a novel metallocene compound, a catalyst composition including the same, and a method of preparing a polyolefin using the same. The metallocene compound according to the present invention and the catalyst composition including the same may be used for the preparation of a polyolefin, may have excellent polymerization ability, and may produce a polyolefin having an ultra-high molecular weight. In particular, when the metallocene compound according to the present invention is employed, an olefin-based polymer having an ultra-high molecular weight may be polymerized because the metallocene compound shows high polymerization activity even when it is supported on a support.Type: GrantFiled: January 28, 2015Date of Patent: June 12, 2018Assignee: LG CHEM, LTD.Inventors: Jin Young Park, Yong Ho Lee, Kyung Jin Cho, Ki Soo Lee, Bog Ki Hong, Min Seok Cho, Dae Hwan Kim, Se Young Kim, Sung Min Lee, Chang Woan Han, Sung Ho Park
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Patent number: 9956203Abstract: The present invention provides and a plastic container and multilayered films, which comprises a heat-sealable seal layer, a cyclic polyolefin layer, and an outermost layer, wherein the seal layer comprises polypropylene, the cyclic polyolefin layer comprises a cyclic polyolefin polymer or a cyclic polyolefin copolymer, and the outermost layer comprises a layer containing polypropylene, and which further comprises a resin composition layer comprises a blended product of a propylene polymer and a styrene elastomer. The plastic container of the present invention can suppresses a reduction in the medicament content of a liquid-state medicament and is excellent in terms of shock resistance, handling ability during the filling of the container with the medicament, and the moldability and transparency of the container.Type: GrantFiled: November 29, 2010Date of Patent: May 1, 2018Assignee: Mitsubishi Tanabe Pharma CorporationInventors: Kazuhiko Ozaki, Munetomo Matsuda, Tetsurou Nishimura, Kenjiro Takayanagi
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Publication number: 20130324669Abstract: A dry adhesive comprising a micro-featured and nano-featured surface, and a compliant surface having a hardness of about 60 Shore A or less, the micro-featured and nano-featured surface and the compliant surface being capable of forming upon contact a dry adhesive bond with each other.Type: ApplicationFiled: August 8, 2013Publication date: December 5, 2013Applicant: MYLAN GROUPInventors: My T. Nguyen, Loc Vinh Bui
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Publication number: 20130303704Abstract: The present description relates to an olefin block copolymer preferably useful to form nonslip pads due to excellences in elasticity and heat resistance, and a sheet-shaped molded body comprising the olefin block copolymer The olefin block copolymer includes a plurality of blocks or segments, each of which includes an ethylene or propylene repeating unit and an ?-olefin repeating unit at different weight fractions. The olefin block copolymer satisfies a defined relationship when a load of 5 to 10 kg is applied to a sheet-shaped molded body of the block copolymer for 12 hours or longer at a temperature of 60° C. or higher, and then removed.Type: ApplicationFiled: January 19, 2012Publication date: November 14, 2013Applicant: LG CHEM, LTD.Inventors: Sang-Jin Jeon, Seung-Ki Park, Kyung-Seop Noh, Nan-Young Lee, Won-Hee Kim, Sang-Eun An
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Publication number: 20130296497Abstract: The present description relates to an olefin block copolymer with excellences in elasticity, heat resistance, and processability. The olefin block copolymer comprises a plurality of blocks or segments, each comprising an ethylene or propylene repeating unit and an ?-olefin repeating unit at different mole fractions. The olefin block copolymer comprises polymer chains containing 20 to 100 short-chain branches (SCBs) per 1,000 carbon atoms. A point where a first derivative of the number Y of the SCBs per 1,000 carbon atoms of each polymer chain with respect to the molecular weight X of the polymer chain is 0 exists between the minimum and maximum values of the molecular weight X.Type: ApplicationFiled: January 27, 2012Publication date: November 7, 2013Applicant: LG CHEM, LTD.Inventors: Man-Seong Jeong, Ki-Soo Lee, Yong-Ho Lee, Heon-Yong Kwon, Min-Seok Cho, Seon-Kyoung Kim, Kyoung-Chan Lim, Dae-Sik Hong
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Patent number: 8557920Abstract: The present invention relates to a polymer composition, comprising (i) a polypropylene homopolymer, (ii) a polypropylene random copolymer, prepared by copolymerization of propylene with an olefin comonomer and having an amount of olefin comonomer units of 0.2 to 5 wt %, and (iii) an elastomeric copolymer of propylene and at least one olefin comonomer, the polymer composition having a tensile modulus, determined according to ISO 527-2/1 B at 1 mm/min. and 230 C, of at least 1200 MPa.Type: GrantFiled: May 11, 2006Date of Patent: October 15, 2013Assignee: Borealis Technology OyInventors: Kauno Alastalo, Carl-Gustaf Ek, Bo Malm, Ulf Torgersen, Olli Tuominen
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Patent number: 8420759Abstract: It has been found that certain cells in culture can convert more than about 0.002 percent of the carbon available in the cell culture medium into isoprene. These cells have a heterologous nucleic acid that (i) encodes an isoprene synthase polypeptide and (ii) is operably linked to a promoter. The isoprene produced in such a cultured medium can then be recovered and polymerized into synthetic rubbers and other useful polymeric materials. The synthetic isoprene containing polymers of this invention offer the benefit of being verifiable as to being derived from non-petrochemical based resources. They can also be analytically distinguished from rubbers that come from natural sources. The present invention more specifically discloses a polyisoprene polymer which is comprised of repeat units that are derived from isoprene monomer, wherein the polyisoprene polymer has ?13C value of greater than ?22‰.Type: GrantFiled: June 30, 2009Date of Patent: April 16, 2013Assignees: The Goodyear Tire & Rubber Company, Danisco US, Inc.Inventors: Frank J. Feher, Gregory M. Whited, Gopal K. Chotani, Fernando Valle, Carol Fioresi, Karl J. Sanford, Joseph C. McAuliffe, Marguerite Cervin, Aaron S. Puhala, Andrei Miasnikov, Ilana S. Aldor
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Patent number: 8415434Abstract: A polymerization process and the resulting polymer composition, said process comprising polymerizing one or more addition polymerizable monomers and a polymerizable shuttling agent in the presence of at least one addition polymerization catalyst comprising a metal compound or complex and a cocatalyst under conditions characterized by the formation of a branched polymer, preferably comprising pseudo-block molecular architecture.Type: GrantFiled: December 23, 2010Date of Patent: April 9, 2013Assignee: Dow Global Technologies LLCInventors: Daniel J. Arriola, Edmund M. Carnahan, David D. Devore, Phillip D. Hustad, Brian A. Jazdzewski, Roger L. Kuhlman, Francis J. Timmers, Timothy T. Wenzel
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Patent number: 8349912Abstract: Crosslink agents used to copolymerize at least one hydrophilic monomer with at least one lens monomer typically used to prepare polymeric materials for ophthalmic lenses. The crosslink agents have a relatively high selectivity for the hydrophilic monomer and limited reactivity with the crosslink agent used to polymerize the lens monomer. Accordingly, the invention is also directed to a hydrophilic crosslinked polymer that comprises at least two monomeric units and at least two different crosslink units. The use of the dual crosslink system provides an improved means to control the final chemical, physical and structural characteristics of the resulting polymer.Type: GrantFiled: September 12, 2011Date of Patent: January 8, 2013Assignee: Bausch & Lomb IncorporatedInventors: Ivan M. Nunez, Joseph A. McGee, David E. Seelye
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Patent number: 8324317Abstract: The present invention is directed to golf balls having at least one layer which comprises a polymer produced by a process wherein one or more monomers are contacted with a composition comprising the admixture or reaction product resulting from combining (A) a first olefin polymerization catalyst, (B) a second olefin polymerization catalyst capable of preparing polymers differing in chemical or physical properties from the polymer prepared by the first olefin polymerization catalyst under equivalent polymerization conditions, and (C) a chain shuttling agent. Golf balls of the present invention include one-piece, two-piece, and multi-layer golf balls. In two-piece and multi-layer golf balls of the present invention, the polymer may be present in a core layer, a cover layer, an intermediate layer (in the case of multi-layer balls), or a combination thereof.Type: GrantFiled: June 21, 2010Date of Patent: December 4, 2012Assignee: Acushnet CompanyInventors: Brian Comeau, David A. Bulpett, Kevin M. Harris, Murali Rajagopalan
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Patent number: 8273431Abstract: A polyamide resin composition contains a resin component containing at least a polyamide (X) and a fatty acid metallic salt having from 10 to 50 carbon atoms, and contains arbitrarily an additive (A) and/or an additive (B). The polyamide (X) is obtained through melt polycondensation of a diamine component containing 70% by mol or more of m-xylylenediamine and a dicarboxylic acid component containing 70% by mol or more of an ?,?-linear aliphatic dicarboxylic acid. The additive (A) is at least one compound selected from the group consisting of a diamide compound obtained from a fatty acid having from 8 to 30 carbon atoms and a diamine having from 2 to 10 carbon atoms, a diester compound obtained from a fatty acid having from 8 to 30 carbon atoms and a diol having from 2 to 10 carbon atoms, and a surfactant, and the additive (B) is at least one compound selected from the group consisting of a metallic hydroxide, a metallic acetate salt, a metallic alkoxide, a metallic carbonate salt and a fatty acid.Type: GrantFiled: May 31, 2007Date of Patent: September 25, 2012Assignee: Mitsubishi Gas Chemical Company, Inc.Inventors: Ryoji Otaki, Jun Mitadera, Tomonori Kato, Tomomichi Kanda
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Patent number: 8268425Abstract: The invention relates to a polyethylene molding composition which has a multimodal molar mass distribution and is particularly suitable for producing external sheathing of electric or information transmission cables. The molding composition has a density at a temperature of 23° C. in the range from 0.94 to 0.95 g/cm3 and an MFI190/5 in the range from 1.2 to 2.1 dg/min. It comprises from 45 to 55% by weight of a low molecular weight ethylene homopolymer A, from 30 to 40% by weight of a high molecular weight copolymer B of ethylene and another olefin having from 4 to 8 carbon atoms and from 10 to 20% by weight of an ultra high molecular weight ethylene copolymer C. The invention also relates to an electric or information transmission cable having an external sheath of the polyethylene molding composition which has a thickness in the range from 0.2 to 3 cm.Type: GrantFiled: November 17, 2005Date of Patent: September 18, 2012Assignee: Basell Polyolefine GmbHInventors: Heinz Vogt, Joachim Berthold
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Publication number: 20120196985Abstract: The present description relates to olefin block copolymers having excellent elasticity and processability in conjunction with enhanced heat resistance, and to a preparation method thereof. The olefin block copolymers comprise a plurality of blocks or segments that comprise ethylene or propylene repeating units and ?-olefin repeating units at different mole fractions from one another, wherein the block copolymer shows peaks at the 2? of 21.5±0.5° and 23.7±0.5° in a wide-angle x-ray diffraction (WAXD) pattern, and the peak ratio defined by (the peak area at 21.5±0.5°)/(the peak area at 23.7±0.5°) is no more than 3.0.Type: ApplicationFiled: January 26, 2012Publication date: August 2, 2012Inventors: Yong-Ho LEE, Manseong Jeon, Heon-Yong Kwon, Min-Seok Cho, Seon Kyoung Kim, Dae-Sik Hong, Se Hui Sohn, Ki-Soo Lee, Kyoung-Chan Lim
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Patent number: 8198374Abstract: A composition for use in forming a multi-block copolymer, said copolymer containing therein two or more segments or blocks differing in chemical or physical properties, a polymerization process using the same, and the resulting polymers, wherein the composition comprises the admixture or reaction product resulting from combining: (A) a first metal complex olefin polymerization catalyst, (B) a second metal complex olefin polymerization catalyst capable of preparing polymers differing in chemical or physical properties from the polymer prepared by catalyst (A) under equivalent polymerization conditions, and (C) a chain shuttling agent.Type: GrantFiled: December 8, 2010Date of Patent: June 12, 2012Assignee: Dow Global Technologies LLCInventors: Daniel J. Arriola, Edmund M. Carnahan, Yunwa Wilson Cheung, David D. Devore, David D. Graf, Phillip D. Hustad, Roger L. Kuhlman, Colin Li Pi Shan, Benjamin C. Poon, Gordon R. Roof, James C. Stevens, Pamela J. Stirn, Timothy T. Wenzel
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Patent number: 8053489Abstract: Crosslink agents used to copolymerize at least one hydrophilic monomer with at least one lens monomer typically used to prepare polymeric materials for ophthalmic lenses. The crosslink agents have a relatively high selectivity for the hydrophilic monomer and limited reactivity with the crosslink agent used to polymerize the lens monomer. Accordingly, the invention is also directed to a hydrophilic crosslinked polymer that comprises at least two monomeric units and at least two different crosslink units. The use of the dual crosslink system provides an improved means to control the final chemical, physical and structural characteristics of the resulting polymer.Type: GrantFiled: July 8, 2008Date of Patent: November 8, 2011Assignee: Bausch & Lomb IncorporatedInventors: Ivan M. Nunez, Joseph A. McGee, David E. Seelye
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Patent number: 8053529Abstract: A process for the polymerization of one or more addition polymerizable monomers and the resulting polymer products, said process comprising: 1) contacting an addition polymerizable monomer or mixture of monomers under addition polymerization conditions in a reactor or reactor zone with a composition comprising at least one olefin polymerization catalyst and a cocatalyst and characterized by the formation of polymer chains from said monomer or monomers; 2) transferring the reaction mixture to a second reactor or reactor zone and optionally adding one or more additional reactants, catalysts, monomers or other compounds prior to, commensurate with, or after said transfer; and 3) causing polymerization to occur in said second reactor or reactor zone to form polymer chains that are differentiated from the polymer chains formed in step 1); said process being characterized by addition of a chain shuttling agent to the reaction mixture prior to, during, or subsequent to step 1) such that at least some of the resultinType: GrantFiled: September 14, 2006Date of Patent: November 8, 2011Assignee: Dow Global Technologies LLCInventors: Edmund M. Carnahan, Phillip D. Hustad, Roger L. Kuhlman, Timothy T. Wenzel
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Patent number: 8012558Abstract: Release agent more particularly for an adhesive with an ethylene multi-block copolymer, the ethylene multi-block copolymer being composed of hard segment blocks, comprising at least 95% (w/w) ethylene and a comonomer, and of soft segment blocks, comprising ethylene and a comonomer, the fraction of comonomer in the soft segment blocks being between 10 and 20 mol %, and the fraction of the hard segment blocks in the ethylene multi-block copolymer being not more than 45% (w/w).Type: GrantFiled: August 12, 2008Date of Patent: September 6, 2011Assignee: tesa SEInventor: Nicole Behrens
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Publication number: 20110124818Abstract: A composition for use in forming a multi-block copolymer, said copolymer containing therein two or more segments or blocks differing in chemical or physical properties, a polymerization process using the same, and the resulting polymers, wherein the composition comprises the admixture or reaction product resulting from combining: (A) a first metal complex olefin polymerization catalyst, (B) a second metal complex olefin polymerization catalyst capable of preparing polymers differing in chemical or physical properties from the polymer prepared by catalyst (A) under equivalent polymerization conditions, and (C) a chain shuttling agent.Type: ApplicationFiled: December 8, 2010Publication date: May 26, 2011Inventors: Daniel J. Arriola, Edmund M. Carnahan, Yunwa Wilson Cheung, David D. Devore, David D. Graf, Phillip D. Hustad, Roger L. Kuhlman, Colin Li Pi Shan, Benjamin C. Poon, Gordon R. Roof, James C. Stevens, Pamela J. Stirn, Timothy T. Wenzel
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Publication number: 20110092651Abstract: A polymerization process and the resulting polymer composition, said process comprising polymerizing one or more addition polymerizable monomers and a polymerizable shuttling agent in the presence of at least one addition polymerization catalyst comprising a metal compound or complex and a cocatalyst under conditions characterized by the formation of a branched polymer, preferably comprising pseudo-block molecular architecture.Type: ApplicationFiled: December 23, 2010Publication date: April 21, 2011Inventors: Daniel J. Arriola, Edmund M. Carnahan, David D. Devore, Phillip D. Hustad, Brian A. Jazdzewski, Roger L. Kuhlman, Francis J. Timmers, Timothy T. Wenzel
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Patent number: 7893166Abstract: Embodiments of the invention provide a class of ethylene/?-olefin block interpolymers. The ethylene/?-olefin interpolymers are characterized by an average block index, ABI, which is greater than zero and up to about 1.0 and a molecular weight distribution, Mw/Mn, greater than about 1.3. Preferably, the block index is from about 0.2 to about 1. In addition or alternatively, the block ethylene/?-olefin interpolymer is characterized by having at least one fraction obtained by Temperature Rising Elution Fractionation (“TREF”), wherein the fraction has a block index greater than about 0.3 and up to about 1.0 and the ethylene/?-olefin interpolymer has a molecular weight distribution, Mw/Mn, greater than about 1.3.Type: GrantFiled: September 11, 2009Date of Patent: February 22, 2011Assignee: Dow Global Technologies, Inc.Inventors: Colin Li Pi Shan, Lonnie G. Hazlitt, Yunwa Wilson Cheung, Benjamin C. Poon, Phillip D. Hustad, Roger L. Kuhlman, Edmund M. Carnahan, Xiao Hua Qiu, Angela N. Taha
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Patent number: 7872071Abstract: The invention relates to a polyethylene molding composition which has a multimodal molar mass distribution and is particularly suitable for producing protective coatings on steel pipes. The molding composition has a density at a temperature of 23° C. in the range from 0.94 to 0.95 g/cm3 and an MFI190/5 in the range from 1.2 to 2.1 dg/min. It comprises from 45 to 55% by weight of a low molecular weight ethylene homopolymer A, from 30 to 40% by weight of a high molecular weight copolymer B of ethylene and another olefin having from 4 to 8 carbon atoms and from 10 to 20% by weight of an ultra high molecular weight ethylene copolymer C.Type: GrantFiled: November 17, 2005Date of Patent: January 18, 2011Assignee: Basell Polyolefine GmbHInventors: Joachim Berthold, Ludwig Böhm, Heinz Vogt
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Patent number: 7868097Abstract: A hybrid polymer has a structure in which a polyolefin segment and a polar polymer segment are connected not via a bonding group containing a heteroatom. A method of the invention produces the hybrid polymer with industrial advantages. The hybrid polymer includes a polyolefin segment (A) and a polar polymer segment (B), the polar polymer segment being obtained by radical polymerization of a radically polymerizable monomer.Type: GrantFiled: February 21, 2006Date of Patent: January 11, 2011Assignee: Mitsui Chemicals, Inc.Inventors: Hideyuki Kaneko, Shinichi Kojoh, Nobuo Kawahara, Shingo Matsuo, Tomoaki Matsugi, Norio Kashiwa
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Patent number: 7858707Abstract: A polymerization process and the resulting polymer composition, said process comprising polymerizing one or more addition polymerizable monomers and a polymerizable shuttling agent in the presence of at least one addition polymerization catalyst comprising a metal compound or complex and a cocatalyst under conditions characterized by the formation of a branched polymer, preferably comprising pseudo-block molecular architecture.Type: GrantFiled: September 14, 2006Date of Patent: December 28, 2010Assignee: Dow Global Technologies Inc.Inventors: Daniel J. Arriola, Edmund M. Carnahan, David D. Devore, Phillip D. Hustad, Brian A. Jazdzewski, Roger L. Kuhlman, Francis J. Timmers, Timothy T. Wenzel
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Patent number: 7858706Abstract: A composition for use in forming a multi-block copolymer, said copolymer containing therein two or more segments or blocks differing in chemical or physical properties, a polymerization process using the same, and the resulting polymers, wherein the composition comprises the admixture or reaction product resulting from combining: (A) a first metal complex olefin polymerization catalyst, (B) a second metal complex olefin polymerization catalyst capable of preparing polymers differing in chemical or physical properties from the polymer prepared by catalyst (A) under equivalent polymerization conditions, and (C) a chain shuttling agent.Type: GrantFiled: March 17, 2005Date of Patent: December 28, 2010Assignee: Dow Global Technologies Inc.Inventors: Daniel J. Arriola, Edmund M. Carnahan, Yunwa Wilson Cheung, David D. Devore, David D. Graf, Phillip D. Hustad, Roger L. Kuhlman, Colin Li Pi Shan, Benjamin C. Poon, Gordon R. Roof, James C. Stevens, Pamela J. Stirn, Timothy T. Wenzel
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Patent number: 7741407Abstract: The present invention is directed to golf balls having at least one layer which comprises a polymer produced by a process wherein one or more monomers are contacted with a composition comprising the admixture or reaction product resulting from combining (A) a first olefin polymerization catalyst, (B) a second olefin polymerization catalyst capable of preparing polymers differing in chemical or physical properties from the polymer prepared by the first olefin polymerization catalyst under equivalent polymerization conditions, and (C) a chain shuttling agent. Golf balls of the present invention include one-piece, two-piece, and multi-layer golf balls. In two-piece and multi-layer golf balls of the present invention, the polymer may be present in a core layer, a cover layer, an intermediate layer (in the case of multi-layer balls), or a combination thereof.Type: GrantFiled: December 13, 2006Date of Patent: June 22, 2010Assignee: Acushnet CompanyInventors: Brian Comeau, David A. Bulpett, Kevin M. Harris, Murali Rajagopalan
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Patent number: 7067591Abstract: A block copolymer having structural formula A-B or A-B-A, wherein A is a crystallizable isotactic polypropylene block segment and B is an amorphous olefin elastomeric block segment; the novel crystallizable block copolymer may be used as it is as a molding material, or as a compatibilizer, a surfactant, a mechanical property improvement agent and the like for other polyemers.Type: GrantFiled: January 10, 2002Date of Patent: June 27, 2006Assignee: Basell Poliolefine Italia S.p.A.Inventor: Kazuto Abe
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Publication number: 20030073785Abstract: The present invention provides an olefin block copolymer for a viscosity index improver capable of preparing a lubricating oil composition having excellent low temperature properties and excellent balance between viscosity and shear stability, a viscosity index improver and a lubricating oil composition comprising the viscosity index improver.Type: ApplicationFiled: May 31, 2002Publication date: April 17, 2003Inventors: Keiji Okada, Shigenobu Ikenaga, Ryousuke Kaneshige, Tomoaki Matsugi, Shinichi Kojoh, Terunori Fujita
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Patent number: 6451921Abstract: Block copolymers containing blocks of unsulfonated aromatic polyether sulfones and blocks of aromatic polyether sulfones sulfonated on the aromatics are characterized in that the block length of the unsulfonated aromatic polyether sulfones in each case comprises at least 10 repeating units and that the sequence of the main chain at the block transitions between two adjacent blocks of aromatic polyether sulfones is the same as it is inside these blocks. These block copolymers may be prepared by polycondensation, and are preferably used as membranes. The block copolymers provide compounds which in addition to an adjustable degree of sulfonation have a defined length of sulfonated and unsulfonated blocks. As a result, the spectrum of the polymers suitable for the preparation of synthetic membranes can be expanded and graded.Type: GrantFiled: February 20, 2001Date of Patent: September 17, 2002Assignee: Membrana GmbHInventors: Hilmar Weisse, Helmut Keul, Hartwig Höcker
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Patent number: 6239242Abstract: There are a number of recent developments relating to co- and homo-polymers of vinyl aromatic monomers. There are syndiotactic polymers of styrene, there are pseudo random polymers of styrene and ethylene. The present invention seeks to provide novel pseudoblock polymers of styrene and ethylene in which at least 10 weight % of the vinyl aromatic monomer is incorporated in the form of one or more atactic pseudoblocks.Type: GrantFiled: August 21, 1999Date of Patent: May 29, 2001Assignee: Nova Chemicals CorporationInventors: Qinyan Wang, Patrick Lam
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Patent number: 6221974Abstract: The invention relates to a process for the preparation of a creep-resistant polypropylene by means of the following steps: (a) copolymerizing propylene and ethylene into a random copolymer at 40 to 110° C. using: a catalyst system of the above-mentioned type; a portion of ethylene or C4-C10-&agr;-olefin leading to 1.0 to 10.0% by weight of ethylene repeating units in said random copolymer; and no or a minimal amount of hydrogen leading to a MFR10 value of between 0.01 and 5.0 g/10 min for said random copolymer, if this step is performed first, or to a MFR2 value for said polypropylene of between 0.05 and 0.40 g/10 min, if this step is performed after step (b); the proportion of random copolymer of this step being from 20 to 80% by weight of said polypropylene, (b) polymerizing propylene at 40 to 110° C. using: a catalyst system of the above-mentioned type; no or a minimal portion of ethylene leading to 0.0 to 1.Type: GrantFiled: December 21, 1998Date of Patent: April 24, 2001Assignee: Borealis Technology OyInventors: Mika Härkönen, Bo Malm, Anders Nymark
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Patent number: 6114461Abstract: Process for the preparation of vinylaromatic copolymers reinforced with rubber which comprises:a) dissolving a dienic rubber (i) and/or a linear block elastomer, vinylaromatic monomer-1,3 conjugated diene (ii), in a mixture comprising at least one vinylaromatic monomer and a pair of solvents consisting of a polar solvent and a nonpolar solvent;b) polymerizing the solution thus obtained, possibly in the presence of an initiator.Type: GrantFiled: February 21, 1997Date of Patent: September 5, 2000Assignee: Enichem S.p.A.Inventors: Davide Preti, Anna Grazia Rossi, Roberto Nocci, Nicola Vecchini
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Patent number: 6111022Abstract: The present invention is directed to a process of atom (or group) transfer radical polymerization for the synthesis of novel homopolymer or a block or graft copolymer, optionally containing at least one polar group, with well defined molecular architecture and narrow polydispersity index, in the presence of an initiating system comprising (i) an initiator having a radically transferrable atom or group, (ii) a transition metal compound, and (iii) a ligand; the present invention is also directed to the synthesis of a macromolecule having at least two halogen groups which can be used as a macroinitiator component (i) to subsequently form a block or graft copolymer by an atom or group transfer radical polymerization process; the present invention is also directed to a process of atom or group transfer radical polymerization for the synthesis of a branched or hyperbranched polymer; in addition, the present invention is directed to a process of atom or group transfer radical polymerization for the synthesis of a maType: GrantFiled: December 8, 1998Date of Patent: August 29, 2000Assignee: Carnegie-Mellon UniversityInventors: Krzysztof Matyjaszewski, Simion Coca, Scott G. Gaynor, Yoshiki Nakagawa, Seong Mu Jo
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Patent number: 5859126Abstract: Coating compositions containing an alkyd, urethane or unsaturated polyester resin, and an ester of an unsaturated acid and a fluorinated alcohol wherein the cured coating has an advancing hexadecane contact angle of at least about 40 degrees and durable improved oil and water repellency is disclosed.Type: GrantFiled: August 7, 1996Date of Patent: January 12, 1999Assignee: E. I. du Pont de Nemours and CompanyInventors: Douglas Robert Anton, Jack Robert Kirchner, William Wesley Bennett, Jr.
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Patent number: 5854354Abstract: A process for preparing a propylene polymer composition comprising conducting multistage polymerization including a step (a) for preparing a propylene (co)polymer (a) and a step (b) for preparing an ethylene copolymer (b) in the presence of (A) a transition metal compound and (B) a compound activating the transition metal compound (A), in which the steps (a) and (b) may be carried out in any order, and the resulting propylene polymer composition contains the propylene (co)polymer (a) in an amount of 20 to 90% by weight and the ethylene copolymer (b) in an amount of 10 to 80% by weight and has MFR, as measured at 230.degree. C. under a load of 2.16 kg, of 0.01 to 500 g/10 min; and a propylene polymer composition prepared by this process. The process according to the invention can prepare a propylene polymer composition having excellent rigidity, heat resistance and impact resistance.Type: GrantFiled: June 7, 1995Date of Patent: December 29, 1998Assignee: Mitsui Petrochemical Industries, Ltd.Inventors: Takashi Ueda, Mikio Hashimoto, Masaaki Kawasaki, Daisuke Fukuoka, Junichi Imuta
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Patent number: 5824759Abstract: A propylene resin composition obtained by dynamic heat treatment of a blend of (A) 100 parts by weight of a propylene-.alpha.-olefin block copolymer wherein a ratio (.eta..sub.1 /.eta..sub.2) of melt viscosity .eta..sub.1 at a shear rate of 10.sup.1 sec.sup.-1 to melt viscosity .eta..sub.2 at a shear rate of 10.sup.2 sec.sup.-1 is 3.5 to 8 as measured by a slit die method and (B)0.005 to 2 parts by weight of an organic peroxide, and having a melt flow rate (measured according to JIS K7210, at a temperature of 230.degree. C. under a load of 2.16 kg) adjusted to 50 to 300 g/10 minutes, a main endothermic peak temperature Tmp of 120.degree. to 150.degree. C. for melting temperature and a main exothermic peak temperature Tcp of 85.degree. to 105.degree. C. for crystallization temperature, as measured with a Differential Scanning Calorimetry, and a Tcp half-value width of 5.degree. C. or above, and a molded article obtained by using the same.Type: GrantFiled: November 1, 1996Date of Patent: October 20, 1998Assignee: Showa Denko K.K.Inventors: Kazuyuki Watanabe, Sakuyoshi Nakagami, Meiko Saihata
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Patent number: 5798420Abstract: This invention relates to block polymers containing both crystalline and elastomeric blocks, the block copolymer having an A block and a B block. The A block is a polyethylene or an ethylene polymer optionally containing an alpha-olefin and optionally a non-conjugated diene, and is generally crystalline. The B block is an ethylene, .alpha.-olefin copolymer. Also disclosed is a process for manufacture of the block copolymers and methods for coupling the block copolymers. Coupled block copolymers are useful as thermoplastic elastomers exhibiting physical properties approaching those of crosslinked EP or EPDM elastomers, but showing thermal processability after coupling. The block copolymers of the present invention may also be used as a lubricant or fuel additive, as a plastics blend component, and as a component in hot melt adhesives.Type: GrantFiled: May 19, 1997Date of Patent: August 25, 1998Assignee: Exxon Chemical Patents, Inc.Inventors: Charles Cozewith, Gary William Ver Strate, Roger K. West, Gaetano A. Capone
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Patent number: 5786442Abstract: A polyester mixture is prepared composed of a diol, a dicarboxylic acid and optionally a monofunctional compound as a chain stopper, in which there is less than 3 wt. % of compounds having a molecular weight of up to 800. The process preferably involves stripping off volatile components from the mixture, for example by molecular distillation. The mixture may be used for forming shaped plastic objects for use in car interiors.Type: GrantFiled: October 23, 1990Date of Patent: July 28, 1998Assignee: Unilever Patent Holdings B.V.Inventor: Johan Harmsen
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Patent number: 5753773Abstract: Multiphase block copolymers of propylene comprisinga) a polymer of propylene with from 0 to 5% by weight of further C.sub.2 -C.sub.10 1-alkenes,b) a copolymer of propylene with from 5 to 98% by weight of further C.sub.2 -C.sub.10 1-alkenes,the multiphase block copolymers having a melting point of less than 155.degree. C. and a stiffness (shear modulus G) conforming to the following condition (I): ##EQU1## where M.sub.a) denotes the amount of propylene polymer a) and M.sub.co denotes the amount of the multiphase block copolymer.are obtainable in particular by polymerization by means of metallocene-containing catalyst systems.Type: GrantFiled: November 9, 1995Date of Patent: May 19, 1998Assignee: BASF AktiengesellschaftInventors: Franz Langhauser, Juergen Kerth, Patrik Mueller, Meinolf Kersting, Guenther Schweier
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Patent number: 5731082Abstract: A cable comprising one or more electrical conductors or a core of one or more electrical conductors, each conductor or core being surrounded by a layer of insulation comprising a multimodal copolymer of ethylene and one or more alpha-olefins, each alpha-olefin having 3 to 8 carbon atoms, the copolymer having a broad comonomer distribution as measured by TREF with a value for the percent of copolymer, which elutes out at a temperature of greater than 90 degrees C., of greater than about 5 percent; a WTGR value of less than about 20 percent; a melt index in the range of about 0.1 to about 30 grams per 10 minutes; and a density in the range of 0.880 to 0.950 gram per cubic centimeter, and being prepared by a low pressure process.Type: GrantFiled: June 24, 1996Date of Patent: March 24, 1998Assignee: Union Carbide Chemicals & Plastics Technology CorporationInventors: Laurence Herbert Gross, Alfred Mendelsohn
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Patent number: 5641848Abstract: Disclosed is a blown film or sheet material comprising a broad molecular weight distribution propylene polymer material having a molecular weight distribution M.sub.w /M.sub.n of about 4 to about 60, a melt flow rate of about 0.5 to about 50 dg/min, and xylene insolubles at 25.degree. C. of greater than or equal to 94%. A mixture of the broad molecular weight distribution propylene polymer material and a heterophasic olefin polymer composition can also be used.Type: GrantFiled: July 24, 1995Date of Patent: June 24, 1997Assignee: Montell North America Inc.Inventors: James M. Giacobbe, Steven J. Pufka
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Patent number: 5612445Abstract: The epoxidation of alkyds containing anhydrides or diacids with cycloaliphatic unsaturation results in epoxy resins which cure rapidly in UV light to produce uniform films without the use of flow modifiers. The fatty acid portion of the alkyd functions as an internal plasticizer. Crosslinking occurs through oxirane rings in both the anhydride and fatty acid moieties of the alkyd to produce hard, but not brittle films. Excellent water resistance is obtained without thermal post curing.Type: GrantFiled: February 15, 1995Date of Patent: March 18, 1997Assignee: Arizona Chemical Co.Inventor: Raymond H. Jones
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Patent number: 5563118Abstract: An additive composition comprising a graft and derivatized copolymer prepared from ethylene and at least one (C.sub.3 -C.sub.10) alpha- monoolefin and, optionally, a polyene selected from non-conjugated dienes and trienes comprising from about 15 to 80 mole percent of ethylene, from about 20 to 85 mole percent of said (C.sub.3 -C.sub.10) alpha- monoolefin and from about 0 to 15 mole percent of said polyene having an average molecular weight ranging from about 5,000 to 500,000, which has been reacted with at least one olefinic carboxylic acid acylating agent to form one or more acylating reaction intermediates characterized by having a carboxylic acid acylating function within their structure and reacting said reaction intermediate with an amino-aromatic compound to form said graft derivatized copolymer, and a lubricating oil composition containing same are provided.Type: GrantFiled: June 6, 1995Date of Patent: October 8, 1996Assignee: DSM Copolymer, Inc.Inventors: Munmaya K. Mishra, Isaac D. Rubin
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Patent number: 5514757Abstract: The subject invention discloses a process for preparing a coupled styrene-isoprene-butadiene rubber which is particularly valuable for use in making automobile tire tread rubber compounds which comprises the steps of (1) solution terpolymerizing in an organic solvent from about 5 weight percent to about 40 weight percent styrene, from about 1 weight percent to about 10 weight percent isoprene, and from about 50 weight percent to about 94 weight percent 1,3-butadiene, based on total monomers, to a conversion of at least about 90% to produce a living styrene-isoprene-butadiene polymer, wherein the terpolymerization is initiated with an organolithium compound, and wherein the terpolymerization is conducted in the presence of a polar modifier at a molar ratio of the polar modifier to the organolithium compound, which is within the range of about 0.5:1 to about 5:1, and wherein the terpolymerization is conducted at a temperature which is within the range of about 20.degree. C. to about 150.degree. C.Type: GrantFiled: May 15, 1995Date of Patent: May 7, 1996Assignee: The Goodyear Tire & Rubber CompanyInventors: Wen-Liang Hsu, Adel F. Halasa, Barry A. Matrana, Scott M. Christian, Laurie E. Austin, Bill B. Gross
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Patent number: 5514455Abstract: A film comprising a blend of copolymers, which has been (i) extruded to a gauge in the range of about 0.3 to about 0.9 mil, said film having an Elmendorf Tear Strength in the machine direction of at least about 25 grams per mil greater than the Elmendorf Tear Strength in the machine direction of the same blend of copolymers, which has been extruded to a gauge of one mil, or (ii) extruded to a heavy gauge of at least about 5 mils and then biaxially oriented and reduced to a gauge of about 1.5 mils or less, first in the machine direction at a gauge reduction ratio of at least about 2:1, and then in the transverse direction at a gauge reduction ratio of at least about 1.5:1, said blend having been produced in situ by contacting ethylene and at least one alpha-olefin comonomer having 3 to 8 carbon atoms with a magnesium/titanium based catalyst system in each of two reactors connected in series, under polymerization conditions.Type: GrantFiled: July 8, 1994Date of Patent: May 7, 1996Assignee: Union Carbide Chemicals & Plastics Technology CorporationInventors: William J. Michie, Jr., Guylaine St. Jean
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Patent number: 5503914Abstract: A film comprising a blend of copolymers, which has been extruded (i) to a film having a gauge of less than about 1.8 mils; a dart impact strength of at least about 80 grams per mil at a density of 0.926 gram per cubic centimeter; and a dart impact strength of at least about 480 grams per mil at a density of 0.918 gram per cubic centimeter and/or (ii) to a film having a gauge of less than about 5 mils, and a blocking force of less than about 120 grams and a COF in the range of about 0.2 to about 0.5, said blend having been produced in situ by contacting ethylene and at least one alpha-olefin comonomer with a magnesium/titanium based catalyst system in each of two reactors connected in series, under polymerization conditions, wherein the polymer formed in the high molecular weight reactor has a flow index in the range of about 0.01 to about 30 grams per 10 minutes and a density in the range of about 0.860 to about 0.Type: GrantFiled: July 8, 1994Date of Patent: April 2, 1996Assignee: Union Carbide Chemicals & Plastics Technology CorporationInventors: William J. Michie, Jr., George E. Ealer, Guylaine St. Jean, Charles J. Sakevich, Diane J. Rickman-Davis
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Patent number: 5429757Abstract: An additive composition comprising a graft and derivatized copolymer prepared from ethylene and at least one (C.sub.3 -C.sub.10) alpha-monoolefin and, optionally, a polyene selected from non-conjugated dienes and trienes comprising from about 15 to 80 mole percent of ethylene, from about 20 to 85 mole percent of said (C.sub.3 -C.sub.10) alpha-monoolefin and from about 0 to 15 mole percent of said polyene having an average molecular weight ranging from about 5,000 to 500,000, which has been reacted with at least one olefinic carboxylic acid acylating agent to form one or more acylating reaction intermediates characterized by having a carboxylic acid acylating function within their structure and reacting said reaction intermediate with an amino-aromatic compound to form said graft derivatized copolymer, and a lubricating oil composition containing same are provided.Type: GrantFiled: March 18, 1994Date of Patent: July 4, 1995Assignee: Texaco Inc.Inventors: Munmaya K. Mishra, Isaac D. Rubin