Acyclic Hydrocarbon Is Propylene Patents (Class 525/322)
  • Patent number: 5972520
    Abstract: A high gloss, impact resistant material is made by coextruding a cap layer of a metallocene polyethylene and clarified random copolymer polypropylene onto a core layer. The coextrusion process is guided by a dual manifold die which reduces the interfacial instability of the melt streams as the cap layer is being applied. When thermoformed, the material retains its gloss and exhibits excellent low temperature impact resistance.
    Type: Grant
    Filed: February 12, 1997
    Date of Patent: October 26, 1999
    Assignee: UVTEC, Incorporated
    Inventor: George Howell
  • Patent number: 5962594
    Abstract: Segmented polyolefins, which are produced by the reaction of mixtures of powdery polyolefins and polyolefin granulates with unsaturated monomers in the presence of thermally decomposing free radical-forming agents in continuous mixers in two consecutive reaction steps in the solid phase, a reaction step in a solid phase/melt transition phase and a melt homogenizing step, have a high strength and tenacity.The segmented polyolefins, as well as mixtures with conventional polyolefins, are suitable for the production of films, sheets, fibers, panels, coatings, pipes, hollow objects and foams.
    Type: Grant
    Filed: May 27, 1998
    Date of Patent: October 5, 1999
    Assignee: Borealis AG
    Inventors: Manfred Raetzsch, Hartmut Bucka, Achim Hesse, Norbert Reichelt
  • Patent number: 5962595
    Abstract: The invention relates to a high-molecular-weight reactor blend comprising a high-molecular weight polypropylene and a high-molecular weight ethylene-propylene copolymer and having an ethylene content in the range from 0.1 to 2% by weight based on the total amount of blend, a melt flow index MFR (230/5) of .ltoreq.5 dg/min and a molecular weight distribution M.sub.w /M.sub.n in the range from 6 to 20.
    Type: Grant
    Filed: May 22, 1997
    Date of Patent: October 5, 1999
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Volker Dolle, Thomas Bohm
  • Patent number: 5945492
    Abstract: The present invention relates to a process for the preparation of graft thermoplastic polymers in which at least one thermoplastic polymer (A) is grafted with a functional monomer in the presence of a substance which inhibits or reduces the crosslinking or the depolymerization of (A).This substance may be a stable nitroxide radical.Graft polymers are useful as compatibilizing agents in mixtures of polymers and as coextrusion binders. The invention also relates to multilayer structures including these binders.
    Type: Grant
    Filed: October 15, 1997
    Date of Patent: August 31, 1999
    Assignee: Elf Atochem S.A.
    Inventor: Patrice Robert
  • Patent number: 5942586
    Abstract: Catalyst for the polymerization of olefins, process for its preparation, and its use.The present invention relates to a supported catalyst for the polymerization of olefins, which can be prepared by reacting the reaction product formed from an aluminoxane and at least one metallocene with a microporous, polymeric support.
    Type: Grant
    Filed: June 7, 1995
    Date of Patent: August 24, 1999
    Assignee: Targor GmbH
    Inventors: Hans-Friedrich Herrmann, Bernd Bachmann, Bernhard Hierholzer, Walter Spaleck
  • Patent number: 5928762
    Abstract: An embossed sheet which is excellent in embossing properties, whitening resistance and transparency, can be prepared by using a resin composition containing specific ratios of (A) polypropylene having a specific melting point of 125.degree. C. or higher, (B) ethylene-.alpha.-olefin copolymer having specific properties and (C) random copolymer of aromatic vinyl compound and conjugated diene compound having specific properties. Further, the present invention provides the laminates which is made using the above embossed sheet and the method for producing them.
    Type: Grant
    Filed: September 19, 1996
    Date of Patent: July 27, 1999
    Assignees: Toppan Printing Co., Ltd, Nippon Petrochemicals Company, Limited
    Inventors: Tetsuo Aizawa, Masahiro Yamazoe, Ikuma Nishimura, Kazuhiko Ohta, Toshio Inoue, Tokuhito Suzuki
  • Patent number: 5891963
    Abstract: Disclosed herein are processes for polymerizing ethylene, acyclic olefins, and/or selected cyclic olefins, and optionally selected olefinic esters or carboxylic acids, and other monomers. The polymerizations are catalyzed by selected transition metal compounds, and sometimes other co-catalysts. Since some of the polymerizations exhibit some characteristics of living polymerizations, block copolymers can be readily made. Many of the polymers produced are often novel, particularly in regard to their microsructure, which give some of them unusual properties. Numerous novel catalysts are disclosed, as well as some novel processes for making them. The polymers made are useful as elastomers, molding resins, in adhesives, etc. Also described herein is the synthesis of linear .alpha.-olefins by the oligomerization of ethylene using as a catalyst system a combination a nickel compound having a selected .alpha.-diimine ligand and a selected Lewis or Bronsted acid, or by contacting selected .alpha.
    Type: Grant
    Filed: July 10, 1997
    Date of Patent: April 6, 1999
    Assignees: E. I. du Pont de Nemours and Company, University of North Carolina
    Inventors: Maurice S. Brookhart, Lynda Kaye Johnson, Christopher Moore Killian, Samuel David Arthur, Elizabeth Forrester McCord, Stephan James McLain
  • Patent number: 5874505
    Abstract: A polypropylene composition comprising 20 to 95% by weight of a stereoregular polypropylene characterized by the specified physical properties determined from .sup.13 C NMR spectra and 5 to 80% by weight of an .alpha.-olefin copolymer comprising 10 to 90% by weight of an .alpha.-olefin and 10 to 90% by weight of at least one of other .alpha.-olefins. The polypropylene composition demonstrates good balance of rigidity and impact resistance, high heat resistance and high toughness, when used as molding materials.
    Type: Grant
    Filed: November 28, 1997
    Date of Patent: February 23, 1999
    Assignee: Chisso Corporation
    Inventors: Jun Saito, Naoshi Kawamoto, Akiko Kageyama, Kouichi Hatada, Yoshiyuki Oogi, Tsutomu Ushioda
  • Patent number: 5854354
    Abstract: A process for preparing a propylene polymer composition comprising conducting multistage polymerization including a step (a) for preparing a propylene (co)polymer (a) and a step (b) for preparing an ethylene copolymer (b) in the presence of (A) a transition metal compound and (B) a compound activating the transition metal compound (A), in which the steps (a) and (b) may be carried out in any order, and the resulting propylene polymer composition contains the propylene (co)polymer (a) in an amount of 20 to 90% by weight and the ethylene copolymer (b) in an amount of 10 to 80% by weight and has MFR, as measured at 230.degree. C. under a load of 2.16 kg, of 0.01 to 500 g/10 min; and a propylene polymer composition prepared by this process. The process according to the invention can prepare a propylene polymer composition having excellent rigidity, heat resistance and impact resistance.
    Type: Grant
    Filed: June 7, 1995
    Date of Patent: December 29, 1998
    Assignee: Mitsui Petrochemical Industries, Ltd.
    Inventors: Takashi Ueda, Mikio Hashimoto, Masaaki Kawasaki, Daisuke Fukuoka, Junichi Imuta
  • Patent number: 5844046
    Abstract: A process for preparing an olefin polymer comprising the steps of: preparing an olefin polymer ?I! by polymerizing or copolymerizing an olefin in the presence of an olefin poymerization catalyst comprising a specific solid titanium catalyst component ?A!, a specific organoaluminum compound catalyst component ?B! and a specific electron donor catalyst component ?C!; preparing an olefin polymer ?II! by polymerizing or copolymerizing an olefin in an polymerizer different from that for the polymerization of the above step in the presence of an olefin poymerization catalyst comprising a specific solid titanium catalyst component ?A!, a specific organoaluminum compound catalyst component ?B! and a specific electron donor catalyst component ?D!; and then allowing the resulting olefin polymer ?I! and the resulting olefin polymer ?II! to coexist in one polymerizer to further polymerize or copolymerize an olefin.
    Type: Grant
    Filed: March 5, 1997
    Date of Patent: December 1, 1998
    Assignee: Mitsui Petrochemical Industries, Ltd.
    Inventors: Masaaki Ohgizawa, Mamoru Kioka
  • Patent number: 5786427
    Abstract: There are provided a highly rigid propylenic resin which has a melt index MI in the range of 0.1 to 1.2 g/10 minutes as determined at 230.degree. C. under 2.160 kg load and also satisfies a relationship between the MI and the elongational viscosity ?Y(Pa.s)!, said relationship being represented by the expression2.0.times.10.sup.5 .times.MI.sup.-0.68 .ltoreq.Y.ltoreq.8.0.times.10.sup.5.times. MI.sup.-0.68 ;and a blow molded article made from the above resin. The propylenic resin has favorable resistance to draw down and can produce a large-sized and lightweight blow molded article excellent in rigidity, dimensional stability and heat resistance.
    Type: Grant
    Filed: June 12, 1997
    Date of Patent: July 28, 1998
    Assignee: Idemitsu Petrochemical Co., Ltd.
    Inventors: Masato Kijima, Masayuki Shinohara, Minoru Sugawara, Koki Hirano
  • Patent number: 5780570
    Abstract: Process with two or more steps for the preparation in suspension of mixtures of ethylene-propylene (EPM) elastomer homopolymers or ethylene-propylene-diene (EPDM) elastomer terpolymers in the presence of a catalytic system essentially consisting of a compound of Vanadium and a cocatalyst essentially consisting of an Aluminum alkyl and in the presence of an activator, the above process being characterized in that:a) in the first step a first polymerization of the monomers is carried out in the presence of the Vanadium based catalyst;b) in the second or subsequent steps further polymerizable monomers and activator are added to the suspension of the polymer obtained in step (a).
    Type: Grant
    Filed: March 27, 1997
    Date of Patent: July 14, 1998
    Assignee: Enichem S.p.A.
    Inventor: Tiziano Tanaglia
  • Patent number: 5773516
    Abstract: Propylene polymers which comprise from 25 to 97% by weight of a propylene polymer (I) containing from 0 to 15% by weight of copolymerized C.sub.2 -C.sub.10 -alk-1-enes and also comprise from 3 to 75% by weight of a further propylene polymer (II) containing from 15 to 80% by weight of copolymerized C.sub.2 -C.sub.10 -alk-1-enes, are obtainable by two-stage polymerization of propylene and C.sub.2 -C.sub.10 -alk-1-enes in the presence of a Ziegler-Natta catalyst system which comprises a titanium-containing solid component a) comprising a compound of magnesium, a halogen, silica gel as support and a carboxylic ester as electron donor compound, and also as cocatalysts an aluminum compound b) and a further electron donor compound c), where, in a first polymerization stage, propylene is polymerized in the presence or absence of further C.sub.2 -C.sub.10 -alk-1-enes at from 50.degree. to 100.degree. C., pressures in the range from 15 to 40 bar and a mean residence time of from 0.
    Type: Grant
    Filed: December 6, 1996
    Date of Patent: June 30, 1998
    Assignee: BASF Aktiengesellschaft
    Inventors: Stephan Huffer, Meinolf Kersting, Franz Langhauser, Rainer Alexander Werner, Stefan Seelert, Patrik Muller, Jurgen Kerth
  • Patent number: 5753762
    Abstract: The present invention relates to polypropylene fibers and nonwoven fabrics produced from spunlaid or staple fibers having improved natural bulk. Said polypropylene fibers are made of a blend of sPP and iPP.
    Type: Grant
    Filed: February 12, 1997
    Date of Patent: May 19, 1998
    Assignee: Fina Research, S.A.
    Inventors: Daniel Leuckx, Etienne de Wergifosse, Rene F. Venneman
  • Patent number: 5741862
    Abstract: Highly flexible propylene/ethylene copolymers having a high rubber content are obtainable by two-stage polymerization from the gas phase in an agitated fixed bed by means of a Ziegler-Natta catalyst system which, in addition to a titanium-containing solid component, also contains an aluminum compound as a cocatalyst, in a first polymerization stage, propylene being polymerized at from 15 to 40 bar and from 50.degree. to 90.degree. C. and during an average residence time of the reaction mixture of from 0.5 to 5 hours and then, in a second polymerization stage, a mixture of propylene and ethylene being polymerized with the polymer discharged from the first polymerization stage, at from 5 to 30 bar, this pressure being at least 2 bar below the pressure of the first polymerization stage, and at from 60.degree. to 100.degree. C. and during an average residence time of the reaction mixture of from 0.
    Type: Grant
    Filed: January 13, 1997
    Date of Patent: April 21, 1998
    Assignee: BASF Aktiengesellschaft
    Inventors: Patrik Muller, Meinolf Kersting
  • Patent number: 5736613
    Abstract: There are provided a highly rigid propylenic resin which has a melt index MI in the range of 0.1 to 1.2 g/10 minutes as determined at 230.degree. C. under 2.160 kg load and also satisfies a relationship between the MI and the elongational viscosity ?Y(Pa.multidot.s)!, said relationship being represented by the expression2.0.times.10.sup.5 .times.MI.sup.-0.68 .ltoreq.Y.ltoreq.8.0.times.10.sup.5 .times.MI.sup.-0.68 ;and a blow molded article made from the above resin. The propylenic resin has favorable resistance to draw down and can produce a large-sized and lightweight blow molded article excellent in rigidity, dimensional stability and heat resistance.
    Type: Grant
    Filed: March 13, 1996
    Date of Patent: April 7, 1998
    Assignee: Idemitsu Petrochemical Co., Ltd.
    Inventors: Masato Kijima, Masayuki Shinohara, Minoru Sugawara, Koki Hirano
  • Patent number: 5712323
    Abstract: Essentially atactic cross-linked propylene homopolymer or amorphous cross-linked random copolymer of propylene with ethylene and/or at least one C.sub.4 -C.sub.10 .alpha.-olefin. Polymer composition comprising the above mentioned cross-linked atactic or amorphous polymers and other olefin polymers. Foamed polymer or polymer composition obtained by foaming said cross-linked atactic or amorphous polymers or said polymer composition.Process for the preparation of said polymer or foamed polymer composition.
    Type: Grant
    Filed: July 11, 1996
    Date of Patent: January 27, 1998
    Assignee: Montell North America Inc.
    Inventors: Vittorio Braga, Franco Sartori
  • Patent number: 5708090
    Abstract: Process for the preparation of a polypropylene molding compositionA propylene block copolymer having good flow properties and a very good low temperature impact strength is obtained in a high yield if a catalyst which consists of a chiral metallocene, containing a bridge, of the formula I ##STR1## and an aluminoxane is used for the polymerization of propylene and the comonomers.The polymerization is carried out in two stages, a crystalline propylene polymer being prepared in the first stage.
    Type: Grant
    Filed: June 5, 1995
    Date of Patent: January 13, 1998
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Michael Schreck, Andreas Winter, Volker Dolle, Hartmut Kondoch, Martin Antberg, Jurgen Rohrmann
  • Patent number: 5703170
    Abstract: A novel high performance pressure sensitive adhesive composition is provided comprised of a phase separated graft copolymer comprised of a polymerized acrylic or methacrylic acid ester backbone having grafted thereon pendant polymeric moieties such as polystyrene or poly-alpha-methylstyrene. The average number of carbon atoms present in the ester portion of the backbone ranges from 2.5 to 3.5. The composition is non-corrosive and has a low volatile content.
    Type: Grant
    Filed: January 17, 1997
    Date of Patent: December 30, 1997
    Assignee: Adhesives Research, Inc.
    Inventors: Michael J. Zajaczkowski, Barbara A. Stutzman
  • Patent number: 5674630
    Abstract: Polypropylene impact copolymer compositions are provided which contain a homopolymer phase of predominantly homopolymeric polypropylene, a copolymer phase of copolymerized ethylene and propylene, and a nucleating agent. The inventive compositions have a rubber content (Fc) in the range of 25 to 45% by weight, a crystallization temperature in the range of 122.degree. to 132.degree. C., a melt flow in the range of about 7 to about 60 dg/min, and a ratio of the intrinsic viscosity of the copolymer phase to the intrinsic viscosity of the homopolymer phase of 1.4 to about 1.9. The polypropylene impact copolymer compositions may be used to form cast films which preferably are soft, quiet, and suitable for use in products to be used next to the skin, such as diapers, adult incontinence pads and feminine hygiene products.
    Type: Grant
    Filed: May 8, 1995
    Date of Patent: October 7, 1997
    Assignee: Union Carbide Chemicals & Plastics Technology Corporation
    Inventor: Ananda M. Chatterjee
  • Patent number: 5674944
    Abstract: Batch inclusion packages made from films and film structures are disclosed. The films and film structures have at least one layer of at least one substantially linear ethylene/.alpha.-olefin polymer. The batch inclusion packages are useful in wrapping or containing various materials, such as carbon black, titanium dioxide, and rubber compounding ingredients.
    Type: Grant
    Filed: June 7, 1995
    Date of Patent: October 7, 1997
    Assignee: The Dow Chemical Company
    Inventors: Daniel James Falla, Debbie-Lee Walker
  • Patent number: 5670580
    Abstract: There are here disclosed a propylene block copolymer comprising (A) 50 to 95 wt % of a specific propylene polymer block which contains a propylene unit or the propylene unit and 4 wt % or less of an olefin unit having 2 to 8 carbon atoms and (B) 50 to 5 wt % of an ethylene-propylene copolymer block containing 20 to 90 wt % of an ethylene unit, 0.001 to 15.0 wt % of a unit derived from a diolefin being contained in at least one of the components (A) and (B), a reduced viscosity at a concentration of 0.05 g/dl measured in decalin at 135.degree. C. being in the range of 0.01 to 30 dl/g; its preparation process; a hydrogenated copolymer obtained from the propylene block copolymer; and a modified copolymer obtained by introducing a functional group into at least 5% of unsaturated bonds of the copolymer.
    Type: Grant
    Filed: August 23, 1995
    Date of Patent: September 23, 1997
    Assignee: Idemitsu Kosan Co., Ltd.
    Inventors: Toshinori Tazaki, Shuji Machida
  • Patent number: 5663237
    Abstract: A supercritical graft copolymerization process is described which includes the steps of: adding a polymer into a high pressure reactor; adding a free radically polymerizable monomer into the reactor; adding a free radical polymerization initiator; adding a sufficient amount of a supercritical solvent to dissolve at least a portion of the polymer and the monomer when supercritical conditions are achieved inside the reactor; and heating and pressurizing the reactor to achieve supercritical conditions therein for a time sufficient to effect a graft copolymerization on the polymer by the polymerizing monomer which forms at least one side chain on the polymer. In general, the reaction pressure will range from 70 atm. to 200 atm. and the reaction temperature will range from 50.degree. C. to 90.degree. C. In the examples provided above, the supercritical solvent was carbon dioxide.
    Type: Grant
    Filed: June 15, 1995
    Date of Patent: September 2, 1997
    Assignee: The University of Akron
    Inventors: Sunggyu Lee, Soonjong Kwak, Fouad Azzam
  • Patent number: 5656374
    Abstract: Polyolefin compositions, capable of developing substantial dielectric heat including (percent by weight):(I) 85-97% of a heterophasic olefin polymer optionally modified with polar monomers in amount from 0.3 to 0.03% of the heterophasic olefin polymer; and(II) 3-15% of at least one polymer having a dielectric heat loss factor greater than or equal to 0.01.
    Type: Grant
    Filed: June 6, 1995
    Date of Patent: August 12, 1997
    Assignee: Montell North America Inc.
    Inventors: Roberto Marzola, Luca Scanavini
  • Patent number: 5654372
    Abstract: A polypropylene composition comprising a melt-kneaded polyprolylene composition obtained, using Zieglar-Natta catalyst, by polymerizing a monomer comprising propylene to form a polymer comprising polypropylene (component A) in amount of from 60 to 80% by weight to the total polymer amount in substantially the absence of an inert solvent in a 1st step and then polymerizing a mixture of ethylene content of from 20 to 50% by weight (component B) in a vapor phase to form an ethylene-propylene copolymer (component B) in amount of from 20 to 40% by weight to the total polymer amount in a 2nd step, said polypropylene composition being such that the intrinsic viscosity of component B ([.eta.]B) is at least 2.0 dl/g and the ratio ([.eta.]B/[.eta.]A) of the intrinsic viscosity of the component B to the intrinsic viscosity of the component A ([.eta.]A) is 1.8 or less and the melt flow rate of the polypropylene composition after melt-kneaded being 0.5 to 10 g/10 minutes.
    Type: Grant
    Filed: March 8, 1996
    Date of Patent: August 5, 1997
    Assignee: Sumitomo Chemical Company Limited
    Inventors: Hajime Sadatoshi, Seiichiro Ima, Kazuki Wakamatsu, Jiro Mori, Eisuke Shiratani
  • Patent number: 5648422
    Abstract: Multistage process for the polymerization of one or more olefins of the formula CH.sub.2 .dbd.CHR, in which R is hydrogen or an alkyl, cycloalkyl or aryl group having from 1 to 10 carbon atoms, comprising:(A) a first stage of polymerization, in which a first olefin polymer is prepared in the presence of titanium catalyst or vanadium catalyst;(B) a treatment stage in which the catalyst used previously is deactivated and in which a metallocene compound is supported on the olefin polymer produced in stage (A); and(C) a second stage of polymerization in which one or more olefins are polymerized in the presence of the product obtained from stage (B).
    Type: Grant
    Filed: June 5, 1995
    Date of Patent: July 15, 1997
    Assignee: Montell Technology Company bv
    Inventors: Gianni Collina, Tiziano Dall'Occo, Maurizio Galimberti, Enrico Albizzati, Luciano Noristi
  • Patent number: 5641848
    Abstract: Disclosed is a blown film or sheet material comprising a broad molecular weight distribution propylene polymer material having a molecular weight distribution M.sub.w /M.sub.n of about 4 to about 60, a melt flow rate of about 0.5 to about 50 dg/min, and xylene insolubles at 25.degree. C. of greater than or equal to 94%. A mixture of the broad molecular weight distribution propylene polymer material and a heterophasic olefin polymer composition can also be used.
    Type: Grant
    Filed: July 24, 1995
    Date of Patent: June 24, 1997
    Assignee: Montell North America Inc.
    Inventors: James M. Giacobbe, Steven J. Pufka
  • Patent number: 5639822
    Abstract: High-flow propylene/ethylene copolymers which have a melt flow index of from 2 to 200 g/min under a load of 2.16 kg at 230.degree. C. and which may be produced from the gas phase by polymerization in two stages in an agitated fixed bed in the presence of hydrogen acting as chain stoppage regulator and using a Ziegler-Natta catalyst system comprising a titaniferous solid component which contains a magnesium compound on finely divided silicon oxide or on finely divided aluminum oxide or on a finely divided aluminum silicate having the empirical formula SiO.sub.2.aAl.sub.2 O.sub.3, where a stands for a value between 0.001 and 2, and an aluminum component, by means of a procedure comprisinga) a first polymerization stage in which propylene is polymerized under a pressure of from 20 to 40 bar and at a temperature of from 60.degree. to 90.degree. C.
    Type: Grant
    Filed: December 12, 1994
    Date of Patent: June 17, 1997
    Assignee: BASF Aktiengesellschaft
    Inventors: Klaus-Dieter Hungenberg, Harald Schwager, Klaus Dieter Ruempler, Patrik Mueller
  • Patent number: 5635567
    Abstract: Propylene polymer containing monomer units derived from at least one functional compound (A) comprising at least two vinyl unsaturations and one or a number of aromatic rings which exhibits a structural stress-hardening.
    Type: Grant
    Filed: December 18, 1995
    Date of Patent: June 3, 1997
    Assignee: Solvay (Societe Anonyme)
    Inventors: Fernand Gauthy, Eric Vandevijver, Martine Kaszacs
  • Patent number: 5629080
    Abstract: Thermobondable fiber of at least one first component of polypropylene having a melt flow rate of 0.5-30, and at least one second component of polypropylene having a melt flow rate of 60-1000.
    Type: Grant
    Filed: January 13, 1993
    Date of Patent: May 13, 1997
    Assignee: Hercules Incorporated
    Inventors: Rakesh K. Gupta, James E. Mallory, Kunihiko Takeuchi
  • Patent number: 5616153
    Abstract: A novel copolymer of an unsaturated acidic reactant and an atactic vinyl terminated propene polymer (VTPP) and its use in preparation of fuel and lubricant additives is taught. The VTPP has a major amount of polymer chains containing terminal vinyl unsaturation, a number average molecular weight of at least 500, and comprises at least 70 weight per cent propene and 0 to 30 weight per cent of at least one olefin selected from the group consisting of C.sub.2 and C.sub.4 to C.sub.10 olefins. The unsaturated acidic reactant comprises at least one unsaturated C.sub.4 to C.sub.10 carboxylic or dicarboxylic acid or anhydride. An oil soluble dispersant additive of the invention useful in oleaginous compositions is prepared by contacting the atactic VTPP copolymer with at least one nucleophilic reagent selected from the group consisting of amines, alcohols, metal reactants and mixtures thereof under conditions effective to form adducts of the nucleophilic reagent with the copolymer.
    Type: Grant
    Filed: October 3, 1995
    Date of Patent: April 1, 1997
    Assignee: Ethyl Corporation
    Inventors: Carl A. Mike, Joseph J. Valcho, Daniel Yuan-Fu Yu
  • Patent number: 5608009
    Abstract: There are herein disclosed an olefin copolymer which comprises an olefin unit and a diolefin unit and in which a weight-average molecular weight is in the range of 200 to 800,000, the content of the diolefin unit is in the range of 0.002 to 30 mol%, and a ratio TUS/DOU between the total content of unsaturated groups observed in a molecular chain (TUS mol%) and the content of the diolefin unit (DOU mol%) is in the range of 0.001 to 200; an olefin graft copolymer obtained by the graft polymerization of this olefin copolymer and an olefin; a hydrogenated olefin copolymer and olefin graft copolymer thereof; and a process for preparing these copolymers.These olefin copolymers are excellent in molding/working properties and have a good thermal stability, transparency and uniformity. Therefore, they are useful as a high-performance VLDPE, LDPE, L-LDPE and HDPE, and further useful as a novel branched propylene polymer, a thermoplastic elastomer, a compatibilizing agent for other resins, and the like.
    Type: Grant
    Filed: April 28, 1995
    Date of Patent: March 4, 1997
    Assignee: Idemitsu Kosan Co., Ltd.
    Inventors: Shuji Machida, Haruo Shikuma, Toshinori Tazaki, Tomio Tatsumi, Shinichi Kurokawa
  • Patent number: 5605969
    Abstract: In accordance with the present invention, there is provided a method for the preparation of an ethylene polymer composition having a density of 0.86-0.94 g/cm.sup.3 and an intrinsic viscosity [.eta.] of 1-6 dl/g using an olefin polymerization catalyst composed of a transition metal compound containing a ligand having a cycloalkadienyl skeleton and an organoaluminium oxy-compound, and there is also provided a method for the preparation of an ethylene polymer composition having density of 0.87-0.93 g/cm3 and an intrinsic viscosity [.eta.] of 0.5-6 dl/g.
    Type: Grant
    Filed: October 25, 1993
    Date of Patent: February 25, 1997
    Assignee: Mitsui Petrochemical Industries, Ltd.
    Inventors: Toshiyuki Tsutsui, Takashi Ueda
  • Patent number: 5589544
    Abstract: The invention relates to a soft thermoplastic elastomeric composition having improved resistance to oil swell and compression set comprising a blend of an engineering thermoplastic resin, a cured rubber concentrate and optionally a compatibilizer and a method for its preparation. The invention further relates to the cured rubber concentrate, a method for its preparation and the use thereof.
    Type: Grant
    Filed: May 15, 1995
    Date of Patent: December 31, 1996
    Assignee: Advanced Elastomer Systems, L.P.
    Inventor: Jacques Horrion
  • Patent number: 5589549
    Abstract: Multistage process for the polymerization of olefins CH.sub.2 .dbd.CHR, where R is hydrogen or an alkyl, cycloalkyl or aryl radical with 1-10 carbon atoms, comprising two stages of polymerization. In a first stage, in the presence of a titanium or a vanadium catalyst and working in one or more reactors, an olefinic polymer with particular values of porosity is prepared; in a second stage, in the presence of the said porous polymer and a metallocene compound and/or their reaction products, one or more olefins, that are equal to or different from those polymerized in the first stage, are polymerized in one or more reactors.
    Type: Grant
    Filed: June 5, 1995
    Date of Patent: December 31, 1996
    Assignee: Montell Technology Company bv
    Inventors: Gabriele Govoni, Mario Sacchetti, Stefano Pasquali
  • Patent number: 5589541
    Abstract: A process for producing a modified propylene polymer comprising the steps of premixing a propylene polymer with a vinyl monomer and polymerizing the vinyl monomer by kneading the premix at a temperature of a melting point thereof or higher is described, wherein the propylene polymer is a particulate propylene polymer having a specific surface area of 0.1 m.sup.2 /g or more. A modified propylene polymer composition is also described, obtained by mixing (a) a particulate propylene polymer having a specific surface area of 0.1 m.sup.2 /g or more, (b) 5% by weight or more of a vinyl monomer mainly comprising an aromatic vinyl monomer based on the total weight of the vinyl monomer and the propylene polymer, and (c) a radical polymerization initiator, substantially impregnating the vinyl monomer and the radical polymerization initiator into the propylene polymer, and then polymerizing the vinyl monomer by melt-kneading.
    Type: Grant
    Filed: March 28, 1995
    Date of Patent: December 31, 1996
    Assignee: Dainippon Ink and Chemicals Inc.
    Inventors: Masafumi Kinoshita, Toshio Niwa, O. Shibata
  • Patent number: 5571869
    Abstract: Grafted polymer particles are prepared by a free-radical addition polymerization mechanism using a flame produced by igniting a mixture of a combustible gas and an oxidant to heat at least a portion of the surface of a solid polymer particle to produce free-radicals thereon. At least one polymerizable ethylenically unsaturated monomer is contacted and reacted with the free-radicals formed on the surface of the polymer to form a graft thereon.
    Type: Grant
    Filed: April 25, 1995
    Date of Patent: November 5, 1996
    Assignee: The University of Akron
    Inventors: Sunggyu Lee, Ramesh Rengarajan
  • Patent number: 5563118
    Abstract: An additive composition comprising a graft and derivatized copolymer prepared from ethylene and at least one (C.sub.3 -C.sub.10) alpha- monoolefin and, optionally, a polyene selected from non-conjugated dienes and trienes comprising from about 15 to 80 mole percent of ethylene, from about 20 to 85 mole percent of said (C.sub.3 -C.sub.10) alpha- monoolefin and from about 0 to 15 mole percent of said polyene having an average molecular weight ranging from about 5,000 to 500,000, which has been reacted with at least one olefinic carboxylic acid acylating agent to form one or more acylating reaction intermediates characterized by having a carboxylic acid acylating function within their structure and reacting said reaction intermediate with an amino-aromatic compound to form said graft derivatized copolymer, and a lubricating oil composition containing same are provided.
    Type: Grant
    Filed: June 6, 1995
    Date of Patent: October 8, 1996
    Assignee: DSM Copolymer, Inc.
    Inventors: Munmaya K. Mishra, Isaac D. Rubin
  • Patent number: 5561196
    Abstract: This invention relates to grafted polypropylene compositions and a process for their production. More particularly, the invention relates to polypropylene compositions based on polypropylene homopolymers, and copolymers of propylene with ethylene and/or butadiene, grafted with certain epoxy-alkyl acrylate compounds, and a process for their production. The grafted polypropylene compositions are useful especially as compatibilizers for addition to other polymer compositions.
    Type: Grant
    Filed: July 13, 1995
    Date of Patent: October 1, 1996
    Assignee: Den norske stats oljeselskap a.s.
    Inventors: Hans K. Kotlar, Per M. Hansen
  • Patent number: 5561195
    Abstract: Polymeric compositions based on Linear Low Density Polyethylene (LLDPE) comprising: (A) from 75 to 95% by weight of an ethylene copolymer with an .alpha.-olefin CH.sub.2 =CHR, wherein R is an alkyl radical having from 1 to 10 carbon atoms, and (B) from 5 to 25% by weight of a copolymer of propylene with ethylene and an .alpha.-olefin CH.sub.2 =CHR.sup.I, wherein R.sup.I is an alkyl radical having from 2 to 10 carbon atoms. Copolymer (B) is characterised by a relatively high insolubility in xylene. The polymeric compositions of the invention are endowed with improved processability and improved mechanical properties with respect to the LLDPE of the conventional type.
    Type: Grant
    Filed: January 20, 1995
    Date of Patent: October 1, 1996
    Assignee: Montell Technology Company bv
    Inventors: Gabriele Govoni, Massimo Covezzi, Claudio Cometto
  • Patent number: 5541262
    Abstract: Crystalline propylene (co)polymers modified by grafting with a vinylpolybutadiene having 1,2-structure content of at least l0%.The (co)polymers are reacted with a liquid vinylpolybutadiene in the presence of a non-peroxidic radical initiator at a temperature in the range 200.degree. to 350.degree. C., the liquid vinylpolybutadiene having a 1,2-structure content of at least 10% and being generally used in amounts within the range 0.5 to 20% by weight.
    Type: Grant
    Filed: June 6, 1995
    Date of Patent: July 30, 1996
    Assignee: Centro Sviluppo Settori Impiego S.r.l.
    Inventors: Corrado Brichta, Francesco Mascia, Amodio Di Somma, Gabriele Torregiani, Antonio Addeo
  • Patent number: 5541260
    Abstract: Disclosed is a polymer composition containing:(A) from 70 to 98 parts by weight of a crystalline propylene homopolymer, or a crystalline random copolymer of propylene with ethylene and/or C.sub.4 -C.sub.10 .alpha.-olefins, containing from 0.5 to 10% by weight of ethylene and/or .alpha.-olefins [fraction (A)]; and(B) from 2 to 30 parts by weight of elastomeric copolymer of ethylene with one or more C.sub.4 -C.sub.10 .alpha.-olefins, containing from 60 to 85% by weight of ethylene, and partially soluble in xylene at 25.degree. C. [fraction (B)];wherein the composition has an intrinsic viscosity value in tetrahydronaphthalene at 135.degree. C. of the fraction soluble in xylene at 25.degree. C. ranging from 0.8 to 1.1 dl/g.
    Type: Grant
    Filed: March 6, 1995
    Date of Patent: July 30, 1996
    Assignee: Montell North America Inc.
    Inventors: Anteo Pelliconi, Antonio Ciarrocchi, Paola Massari
  • Patent number: 5536789
    Abstract: Propylene polymers have a molecular weight ratio Q (M.sub.w /M.sub.n) of from 6 to 30 and are obtainable by Ziegler-Natta polymerization in the presence of hydrogen as molecular weight regulator and are particularly suitable for the production of films and moldings.
    Type: Grant
    Filed: April 24, 1995
    Date of Patent: July 16, 1996
    Assignee: BASF Aktiengesellschaft
    Inventors: Harald Schwager, Peter Koelle, Rueger Schlund, Ralf Zolk, Juergen Kerth, Guenther Schweter, Klaus-Dieter Hungenberg, Werner Schoene
  • Patent number: 5519090
    Abstract: Propylene polymer blends containinga) a propylene homopolymer having a melt flow index of from 0.001 to 5 g/10 min, as determined at 230.degree. C. under a load of 2.16 kg,b) a propylene/ethylene copolymer having an ethylene content of from 5 to 80% w/w, andc) a propylene homopolymer having a melt flow index of from 1 to 10.sup.4 g/10 min, as determined at 230.degree. C. under a load of 2.16 kg,the ratio of the melt flow index of the propylene homopolymer c) to that of the propylene homopolymer a) being within the range 10:1 to 10.sup.7 :1.The blends of the invention are high-flow materials showing a broad molecular weight distribution, and are thus readily processible.
    Type: Grant
    Filed: November 4, 1994
    Date of Patent: May 21, 1996
    Assignee: BASF Aktiengesellschaft
    Inventors: Harald Schwager, Klaus-Dieter Hungenberg
  • Patent number: 5516849
    Abstract: The present invention provides a continuous process for producing an adducted derivatized EPM or EPDM oil solution in which a grafted ethylene polymer is adducted with an antioxidant diamine for formation of an adduct during holding.
    Type: Grant
    Filed: October 6, 1994
    Date of Patent: May 14, 1996
    Assignee: DSM Copolymer, Inc.
    Inventors: Tony L. Caines, Michael L. Junker
  • Patent number: 5514761
    Abstract: Disclosed are unsaturated .alpha.-olefin/.alpha., .omega.-diene copolymers, and a method of preparation thereof. The copolymers are generally crystalline, free of gel and cross-links, and contain unsaturated side chains and long chain branching. The copolymers contain up to 5 mole percent diene incorporated therein, and may be prepared by copolymerization using a solid-phase, insoluble coordination catalyst, without a solvent, and below the crystalline melting point of the copolymer.
    Type: Grant
    Filed: February 10, 1995
    Date of Patent: May 7, 1996
    Assignee: Exxon Chemical Patents Inc.
    Inventors: Bradley P. Etherton, James J. McAlpin, Terrence Huff, Edward N. Kresge
  • Patent number: 5489648
    Abstract: A modified polyolefin prepared from an aqueous suspension containing (a) a crystalline polyolefin, (b) 1 to 500 parts by weight of a vinyl monomer per 100 parts by weight of the crystalline polyolefin, and (c) 0.01 to 10 parts by weight of a radical polymerization initiator per 100 parts by weight of the vinyl monomer by impregnating the crystalline polyolefin (a) with the vinyl monomer (b) and heating the aqueous suspension to polymerize the vinyl monomer (b) at a temperature equal to or higher than a temperature at which the crystal region of the polyolefin (a) begins to substantially melt, which has an excellent effect of improving processability of other polyolefins and provides a polyolefin composition having excellent properties such as processability, impact resistance, rigidity and surface properties when the modified polyolefin is incorporated into polyolefins optionally with a core-shell graft copolymer and/or an inorganic filler.
    Type: Grant
    Filed: June 3, 1994
    Date of Patent: February 6, 1996
    Assignee: Kanegafuchi Kagaku Kogyo Kabushiki Kaisha
    Inventors: Yoshihiko Okimura, Taizo Aoyama, Hiroki Kobayashi, Akinori K. Shu, Kazuhiro Hara
  • Patent number: 5480942
    Abstract: Polymers and copolymers of propylene are modified by grafting with polyalkenylenes having a trans double bond content of higher than 30%. The preparation is carried out via thermic treatment of the propylene (co)polymer with said polyalkenylene at a temperature comprised between 200.degree. and 350.degree. C. an the presence of a free radical initiator other than peroxide.
    Type: Grant
    Filed: May 9, 1994
    Date of Patent: January 2, 1996
    Assignee: Spherilene S.r.l.
    Inventors: Antonio Addeo, Corrado Brichta, Francesco Mascia, Arturo Marchioni
  • Patent number: 5470843
    Abstract: Carbohydrate-containing polymers which can have an HLB* of from about 10 to about 20 are disclosed. The compounds comprise a hydrophilic polymer portion, a carbohydrate portion comprising from 1 to about 20 naturally occurring, identical or different, monosaccharide units, at least one bifunctional spacer coupling the carbohydrate portion to the hydrophilic polymer portion, and a potentiator moiety. The potentiator moiety can be is a crosslinking moiety located within the hydrophilic polymer or a hydrophobic, hydrophilic or ionic moiety. Processes for the preparation and use of such polymers are also disclosed.
    Type: Grant
    Filed: December 13, 1993
    Date of Patent: November 28, 1995
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Wilhelm Stahl, Michael Ahlers, Axel Walch, Eckhart Bartnik, Gerhard Kretzschmar, Susanne Grabley, Rudolf Schleyerbach
  • Patent number: 5468809
    Abstract: Polyolefin compositions having good transparency and impact resistance even at low temperatures including (by weight):A) from 25 to 95 parts of a crystalline random copolymer of propylene with ethylene and/or another .alpha.-olefin, containing more than 85% by weight of propylene, and having Haze values lower than 25%; andB) from 5 to 75 parts of a component comprising (a) an elastomeric copolymer of ethylene with propylene and/or another .alpha.-olefin, and optionally with minor proportions of a diene, containing 20-80 parts of ethylene, and (b) one or more of the polymers selected from LLDPE, LDPE, HDPE, having a Melt Index higher than 0.5 g/10 min., said (a) and (b) being present in such proportions that the ratio between the density of (A) and calculated average density of (B) is from 0.980 to 1.015.
    Type: Grant
    Filed: October 13, 1994
    Date of Patent: November 21, 1995
    Assignee: Montell North America Inc.
    Inventors: Renato Ghisellini, Giuliano Cecchin, Decio Malucelli