Acyclic Hydrocarbon Is Propylene Patents (Class 525/322)
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Patent number: 5972520Abstract: A high gloss, impact resistant material is made by coextruding a cap layer of a metallocene polyethylene and clarified random copolymer polypropylene onto a core layer. The coextrusion process is guided by a dual manifold die which reduces the interfacial instability of the melt streams as the cap layer is being applied. When thermoformed, the material retains its gloss and exhibits excellent low temperature impact resistance.Type: GrantFiled: February 12, 1997Date of Patent: October 26, 1999Assignee: UVTEC, IncorporatedInventor: George Howell
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Patent number: 5962594Abstract: Segmented polyolefins, which are produced by the reaction of mixtures of powdery polyolefins and polyolefin granulates with unsaturated monomers in the presence of thermally decomposing free radical-forming agents in continuous mixers in two consecutive reaction steps in the solid phase, a reaction step in a solid phase/melt transition phase and a melt homogenizing step, have a high strength and tenacity.The segmented polyolefins, as well as mixtures with conventional polyolefins, are suitable for the production of films, sheets, fibers, panels, coatings, pipes, hollow objects and foams.Type: GrantFiled: May 27, 1998Date of Patent: October 5, 1999Assignee: Borealis AGInventors: Manfred Raetzsch, Hartmut Bucka, Achim Hesse, Norbert Reichelt
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Patent number: 5962595Abstract: The invention relates to a high-molecular-weight reactor blend comprising a high-molecular weight polypropylene and a high-molecular weight ethylene-propylene copolymer and having an ethylene content in the range from 0.1 to 2% by weight based on the total amount of blend, a melt flow index MFR (230/5) of .ltoreq.5 dg/min and a molecular weight distribution M.sub.w /M.sub.n in the range from 6 to 20.Type: GrantFiled: May 22, 1997Date of Patent: October 5, 1999Assignee: Hoechst AktiengesellschaftInventors: Volker Dolle, Thomas Bohm
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Patent number: 5945492Abstract: The present invention relates to a process for the preparation of graft thermoplastic polymers in which at least one thermoplastic polymer (A) is grafted with a functional monomer in the presence of a substance which inhibits or reduces the crosslinking or the depolymerization of (A).This substance may be a stable nitroxide radical.Graft polymers are useful as compatibilizing agents in mixtures of polymers and as coextrusion binders. The invention also relates to multilayer structures including these binders.Type: GrantFiled: October 15, 1997Date of Patent: August 31, 1999Assignee: Elf Atochem S.A.Inventor: Patrice Robert
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Patent number: 5942586Abstract: Catalyst for the polymerization of olefins, process for its preparation, and its use.The present invention relates to a supported catalyst for the polymerization of olefins, which can be prepared by reacting the reaction product formed from an aluminoxane and at least one metallocene with a microporous, polymeric support.Type: GrantFiled: June 7, 1995Date of Patent: August 24, 1999Assignee: Targor GmbHInventors: Hans-Friedrich Herrmann, Bernd Bachmann, Bernhard Hierholzer, Walter Spaleck
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Patent number: 5928762Abstract: An embossed sheet which is excellent in embossing properties, whitening resistance and transparency, can be prepared by using a resin composition containing specific ratios of (A) polypropylene having a specific melting point of 125.degree. C. or higher, (B) ethylene-.alpha.-olefin copolymer having specific properties and (C) random copolymer of aromatic vinyl compound and conjugated diene compound having specific properties. Further, the present invention provides the laminates which is made using the above embossed sheet and the method for producing them.Type: GrantFiled: September 19, 1996Date of Patent: July 27, 1999Assignees: Toppan Printing Co., Ltd, Nippon Petrochemicals Company, LimitedInventors: Tetsuo Aizawa, Masahiro Yamazoe, Ikuma Nishimura, Kazuhiko Ohta, Toshio Inoue, Tokuhito Suzuki
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Patent number: 5891963Abstract: Disclosed herein are processes for polymerizing ethylene, acyclic olefins, and/or selected cyclic olefins, and optionally selected olefinic esters or carboxylic acids, and other monomers. The polymerizations are catalyzed by selected transition metal compounds, and sometimes other co-catalysts. Since some of the polymerizations exhibit some characteristics of living polymerizations, block copolymers can be readily made. Many of the polymers produced are often novel, particularly in regard to their microsructure, which give some of them unusual properties. Numerous novel catalysts are disclosed, as well as some novel processes for making them. The polymers made are useful as elastomers, molding resins, in adhesives, etc. Also described herein is the synthesis of linear .alpha.-olefins by the oligomerization of ethylene using as a catalyst system a combination a nickel compound having a selected .alpha.-diimine ligand and a selected Lewis or Bronsted acid, or by contacting selected .alpha.Type: GrantFiled: July 10, 1997Date of Patent: April 6, 1999Assignees: E. I. du Pont de Nemours and Company, University of North CarolinaInventors: Maurice S. Brookhart, Lynda Kaye Johnson, Christopher Moore Killian, Samuel David Arthur, Elizabeth Forrester McCord, Stephan James McLain
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Patent number: 5874505Abstract: A polypropylene composition comprising 20 to 95% by weight of a stereoregular polypropylene characterized by the specified physical properties determined from .sup.13 C NMR spectra and 5 to 80% by weight of an .alpha.-olefin copolymer comprising 10 to 90% by weight of an .alpha.-olefin and 10 to 90% by weight of at least one of other .alpha.-olefins. The polypropylene composition demonstrates good balance of rigidity and impact resistance, high heat resistance and high toughness, when used as molding materials.Type: GrantFiled: November 28, 1997Date of Patent: February 23, 1999Assignee: Chisso CorporationInventors: Jun Saito, Naoshi Kawamoto, Akiko Kageyama, Kouichi Hatada, Yoshiyuki Oogi, Tsutomu Ushioda
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Patent number: 5854354Abstract: A process for preparing a propylene polymer composition comprising conducting multistage polymerization including a step (a) for preparing a propylene (co)polymer (a) and a step (b) for preparing an ethylene copolymer (b) in the presence of (A) a transition metal compound and (B) a compound activating the transition metal compound (A), in which the steps (a) and (b) may be carried out in any order, and the resulting propylene polymer composition contains the propylene (co)polymer (a) in an amount of 20 to 90% by weight and the ethylene copolymer (b) in an amount of 10 to 80% by weight and has MFR, as measured at 230.degree. C. under a load of 2.16 kg, of 0.01 to 500 g/10 min; and a propylene polymer composition prepared by this process. The process according to the invention can prepare a propylene polymer composition having excellent rigidity, heat resistance and impact resistance.Type: GrantFiled: June 7, 1995Date of Patent: December 29, 1998Assignee: Mitsui Petrochemical Industries, Ltd.Inventors: Takashi Ueda, Mikio Hashimoto, Masaaki Kawasaki, Daisuke Fukuoka, Junichi Imuta
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Patent number: 5844046Abstract: A process for preparing an olefin polymer comprising the steps of: preparing an olefin polymer ?I! by polymerizing or copolymerizing an olefin in the presence of an olefin poymerization catalyst comprising a specific solid titanium catalyst component ?A!, a specific organoaluminum compound catalyst component ?B! and a specific electron donor catalyst component ?C!; preparing an olefin polymer ?II! by polymerizing or copolymerizing an olefin in an polymerizer different from that for the polymerization of the above step in the presence of an olefin poymerization catalyst comprising a specific solid titanium catalyst component ?A!, a specific organoaluminum compound catalyst component ?B! and a specific electron donor catalyst component ?D!; and then allowing the resulting olefin polymer ?I! and the resulting olefin polymer ?II! to coexist in one polymerizer to further polymerize or copolymerize an olefin.Type: GrantFiled: March 5, 1997Date of Patent: December 1, 1998Assignee: Mitsui Petrochemical Industries, Ltd.Inventors: Masaaki Ohgizawa, Mamoru Kioka
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Patent number: 5786427Abstract: There are provided a highly rigid propylenic resin which has a melt index MI in the range of 0.1 to 1.2 g/10 minutes as determined at 230.degree. C. under 2.160 kg load and also satisfies a relationship between the MI and the elongational viscosity ?Y(Pa.s)!, said relationship being represented by the expression2.0.times.10.sup.5 .times.MI.sup.-0.68 .ltoreq.Y.ltoreq.8.0.times.10.sup.5.times. MI.sup.-0.68 ;and a blow molded article made from the above resin. The propylenic resin has favorable resistance to draw down and can produce a large-sized and lightweight blow molded article excellent in rigidity, dimensional stability and heat resistance.Type: GrantFiled: June 12, 1997Date of Patent: July 28, 1998Assignee: Idemitsu Petrochemical Co., Ltd.Inventors: Masato Kijima, Masayuki Shinohara, Minoru Sugawara, Koki Hirano
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Patent number: 5780570Abstract: Process with two or more steps for the preparation in suspension of mixtures of ethylene-propylene (EPM) elastomer homopolymers or ethylene-propylene-diene (EPDM) elastomer terpolymers in the presence of a catalytic system essentially consisting of a compound of Vanadium and a cocatalyst essentially consisting of an Aluminum alkyl and in the presence of an activator, the above process being characterized in that:a) in the first step a first polymerization of the monomers is carried out in the presence of the Vanadium based catalyst;b) in the second or subsequent steps further polymerizable monomers and activator are added to the suspension of the polymer obtained in step (a).Type: GrantFiled: March 27, 1997Date of Patent: July 14, 1998Assignee: Enichem S.p.A.Inventor: Tiziano Tanaglia
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Patent number: 5773516Abstract: Propylene polymers which comprise from 25 to 97% by weight of a propylene polymer (I) containing from 0 to 15% by weight of copolymerized C.sub.2 -C.sub.10 -alk-1-enes and also comprise from 3 to 75% by weight of a further propylene polymer (II) containing from 15 to 80% by weight of copolymerized C.sub.2 -C.sub.10 -alk-1-enes, are obtainable by two-stage polymerization of propylene and C.sub.2 -C.sub.10 -alk-1-enes in the presence of a Ziegler-Natta catalyst system which comprises a titanium-containing solid component a) comprising a compound of magnesium, a halogen, silica gel as support and a carboxylic ester as electron donor compound, and also as cocatalysts an aluminum compound b) and a further electron donor compound c), where, in a first polymerization stage, propylene is polymerized in the presence or absence of further C.sub.2 -C.sub.10 -alk-1-enes at from 50.degree. to 100.degree. C., pressures in the range from 15 to 40 bar and a mean residence time of from 0.Type: GrantFiled: December 6, 1996Date of Patent: June 30, 1998Assignee: BASF AktiengesellschaftInventors: Stephan Huffer, Meinolf Kersting, Franz Langhauser, Rainer Alexander Werner, Stefan Seelert, Patrik Muller, Jurgen Kerth
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Patent number: 5753762Abstract: The present invention relates to polypropylene fibers and nonwoven fabrics produced from spunlaid or staple fibers having improved natural bulk. Said polypropylene fibers are made of a blend of sPP and iPP.Type: GrantFiled: February 12, 1997Date of Patent: May 19, 1998Assignee: Fina Research, S.A.Inventors: Daniel Leuckx, Etienne de Wergifosse, Rene F. Venneman
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Patent number: 5741862Abstract: Highly flexible propylene/ethylene copolymers having a high rubber content are obtainable by two-stage polymerization from the gas phase in an agitated fixed bed by means of a Ziegler-Natta catalyst system which, in addition to a titanium-containing solid component, also contains an aluminum compound as a cocatalyst, in a first polymerization stage, propylene being polymerized at from 15 to 40 bar and from 50.degree. to 90.degree. C. and during an average residence time of the reaction mixture of from 0.5 to 5 hours and then, in a second polymerization stage, a mixture of propylene and ethylene being polymerized with the polymer discharged from the first polymerization stage, at from 5 to 30 bar, this pressure being at least 2 bar below the pressure of the first polymerization stage, and at from 60.degree. to 100.degree. C. and during an average residence time of the reaction mixture of from 0.Type: GrantFiled: January 13, 1997Date of Patent: April 21, 1998Assignee: BASF AktiengesellschaftInventors: Patrik Muller, Meinolf Kersting
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Patent number: 5736613Abstract: There are provided a highly rigid propylenic resin which has a melt index MI in the range of 0.1 to 1.2 g/10 minutes as determined at 230.degree. C. under 2.160 kg load and also satisfies a relationship between the MI and the elongational viscosity ?Y(Pa.multidot.s)!, said relationship being represented by the expression2.0.times.10.sup.5 .times.MI.sup.-0.68 .ltoreq.Y.ltoreq.8.0.times.10.sup.5 .times.MI.sup.-0.68 ;and a blow molded article made from the above resin. The propylenic resin has favorable resistance to draw down and can produce a large-sized and lightweight blow molded article excellent in rigidity, dimensional stability and heat resistance.Type: GrantFiled: March 13, 1996Date of Patent: April 7, 1998Assignee: Idemitsu Petrochemical Co., Ltd.Inventors: Masato Kijima, Masayuki Shinohara, Minoru Sugawara, Koki Hirano
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Patent number: 5712323Abstract: Essentially atactic cross-linked propylene homopolymer or amorphous cross-linked random copolymer of propylene with ethylene and/or at least one C.sub.4 -C.sub.10 .alpha.-olefin. Polymer composition comprising the above mentioned cross-linked atactic or amorphous polymers and other olefin polymers. Foamed polymer or polymer composition obtained by foaming said cross-linked atactic or amorphous polymers or said polymer composition.Process for the preparation of said polymer or foamed polymer composition.Type: GrantFiled: July 11, 1996Date of Patent: January 27, 1998Assignee: Montell North America Inc.Inventors: Vittorio Braga, Franco Sartori
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Patent number: 5708090Abstract: Process for the preparation of a polypropylene molding compositionA propylene block copolymer having good flow properties and a very good low temperature impact strength is obtained in a high yield if a catalyst which consists of a chiral metallocene, containing a bridge, of the formula I ##STR1## and an aluminoxane is used for the polymerization of propylene and the comonomers.The polymerization is carried out in two stages, a crystalline propylene polymer being prepared in the first stage.Type: GrantFiled: June 5, 1995Date of Patent: January 13, 1998Assignee: Hoechst AktiengesellschaftInventors: Michael Schreck, Andreas Winter, Volker Dolle, Hartmut Kondoch, Martin Antberg, Jurgen Rohrmann
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Patent number: 5703170Abstract: A novel high performance pressure sensitive adhesive composition is provided comprised of a phase separated graft copolymer comprised of a polymerized acrylic or methacrylic acid ester backbone having grafted thereon pendant polymeric moieties such as polystyrene or poly-alpha-methylstyrene. The average number of carbon atoms present in the ester portion of the backbone ranges from 2.5 to 3.5. The composition is non-corrosive and has a low volatile content.Type: GrantFiled: January 17, 1997Date of Patent: December 30, 1997Assignee: Adhesives Research, Inc.Inventors: Michael J. Zajaczkowski, Barbara A. Stutzman
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Patent number: 5674630Abstract: Polypropylene impact copolymer compositions are provided which contain a homopolymer phase of predominantly homopolymeric polypropylene, a copolymer phase of copolymerized ethylene and propylene, and a nucleating agent. The inventive compositions have a rubber content (Fc) in the range of 25 to 45% by weight, a crystallization temperature in the range of 122.degree. to 132.degree. C., a melt flow in the range of about 7 to about 60 dg/min, and a ratio of the intrinsic viscosity of the copolymer phase to the intrinsic viscosity of the homopolymer phase of 1.4 to about 1.9. The polypropylene impact copolymer compositions may be used to form cast films which preferably are soft, quiet, and suitable for use in products to be used next to the skin, such as diapers, adult incontinence pads and feminine hygiene products.Type: GrantFiled: May 8, 1995Date of Patent: October 7, 1997Assignee: Union Carbide Chemicals & Plastics Technology CorporationInventor: Ananda M. Chatterjee
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Patent number: 5674944Abstract: Batch inclusion packages made from films and film structures are disclosed. The films and film structures have at least one layer of at least one substantially linear ethylene/.alpha.-olefin polymer. The batch inclusion packages are useful in wrapping or containing various materials, such as carbon black, titanium dioxide, and rubber compounding ingredients.Type: GrantFiled: June 7, 1995Date of Patent: October 7, 1997Assignee: The Dow Chemical CompanyInventors: Daniel James Falla, Debbie-Lee Walker
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Patent number: 5670580Abstract: There are here disclosed a propylene block copolymer comprising (A) 50 to 95 wt % of a specific propylene polymer block which contains a propylene unit or the propylene unit and 4 wt % or less of an olefin unit having 2 to 8 carbon atoms and (B) 50 to 5 wt % of an ethylene-propylene copolymer block containing 20 to 90 wt % of an ethylene unit, 0.001 to 15.0 wt % of a unit derived from a diolefin being contained in at least one of the components (A) and (B), a reduced viscosity at a concentration of 0.05 g/dl measured in decalin at 135.degree. C. being in the range of 0.01 to 30 dl/g; its preparation process; a hydrogenated copolymer obtained from the propylene block copolymer; and a modified copolymer obtained by introducing a functional group into at least 5% of unsaturated bonds of the copolymer.Type: GrantFiled: August 23, 1995Date of Patent: September 23, 1997Assignee: Idemitsu Kosan Co., Ltd.Inventors: Toshinori Tazaki, Shuji Machida
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Patent number: 5663237Abstract: A supercritical graft copolymerization process is described which includes the steps of: adding a polymer into a high pressure reactor; adding a free radically polymerizable monomer into the reactor; adding a free radical polymerization initiator; adding a sufficient amount of a supercritical solvent to dissolve at least a portion of the polymer and the monomer when supercritical conditions are achieved inside the reactor; and heating and pressurizing the reactor to achieve supercritical conditions therein for a time sufficient to effect a graft copolymerization on the polymer by the polymerizing monomer which forms at least one side chain on the polymer. In general, the reaction pressure will range from 70 atm. to 200 atm. and the reaction temperature will range from 50.degree. C. to 90.degree. C. In the examples provided above, the supercritical solvent was carbon dioxide.Type: GrantFiled: June 15, 1995Date of Patent: September 2, 1997Assignee: The University of AkronInventors: Sunggyu Lee, Soonjong Kwak, Fouad Azzam
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Patent number: 5656374Abstract: Polyolefin compositions, capable of developing substantial dielectric heat including (percent by weight):(I) 85-97% of a heterophasic olefin polymer optionally modified with polar monomers in amount from 0.3 to 0.03% of the heterophasic olefin polymer; and(II) 3-15% of at least one polymer having a dielectric heat loss factor greater than or equal to 0.01.Type: GrantFiled: June 6, 1995Date of Patent: August 12, 1997Assignee: Montell North America Inc.Inventors: Roberto Marzola, Luca Scanavini
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Patent number: 5654372Abstract: A polypropylene composition comprising a melt-kneaded polyprolylene composition obtained, using Zieglar-Natta catalyst, by polymerizing a monomer comprising propylene to form a polymer comprising polypropylene (component A) in amount of from 60 to 80% by weight to the total polymer amount in substantially the absence of an inert solvent in a 1st step and then polymerizing a mixture of ethylene content of from 20 to 50% by weight (component B) in a vapor phase to form an ethylene-propylene copolymer (component B) in amount of from 20 to 40% by weight to the total polymer amount in a 2nd step, said polypropylene composition being such that the intrinsic viscosity of component B ([.eta.]B) is at least 2.0 dl/g and the ratio ([.eta.]B/[.eta.]A) of the intrinsic viscosity of the component B to the intrinsic viscosity of the component A ([.eta.]A) is 1.8 or less and the melt flow rate of the polypropylene composition after melt-kneaded being 0.5 to 10 g/10 minutes.Type: GrantFiled: March 8, 1996Date of Patent: August 5, 1997Assignee: Sumitomo Chemical Company LimitedInventors: Hajime Sadatoshi, Seiichiro Ima, Kazuki Wakamatsu, Jiro Mori, Eisuke Shiratani
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Patent number: 5648422Abstract: Multistage process for the polymerization of one or more olefins of the formula CH.sub.2 .dbd.CHR, in which R is hydrogen or an alkyl, cycloalkyl or aryl group having from 1 to 10 carbon atoms, comprising:(A) a first stage of polymerization, in which a first olefin polymer is prepared in the presence of titanium catalyst or vanadium catalyst;(B) a treatment stage in which the catalyst used previously is deactivated and in which a metallocene compound is supported on the olefin polymer produced in stage (A); and(C) a second stage of polymerization in which one or more olefins are polymerized in the presence of the product obtained from stage (B).Type: GrantFiled: June 5, 1995Date of Patent: July 15, 1997Assignee: Montell Technology Company bvInventors: Gianni Collina, Tiziano Dall'Occo, Maurizio Galimberti, Enrico Albizzati, Luciano Noristi
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Patent number: 5641848Abstract: Disclosed is a blown film or sheet material comprising a broad molecular weight distribution propylene polymer material having a molecular weight distribution M.sub.w /M.sub.n of about 4 to about 60, a melt flow rate of about 0.5 to about 50 dg/min, and xylene insolubles at 25.degree. C. of greater than or equal to 94%. A mixture of the broad molecular weight distribution propylene polymer material and a heterophasic olefin polymer composition can also be used.Type: GrantFiled: July 24, 1995Date of Patent: June 24, 1997Assignee: Montell North America Inc.Inventors: James M. Giacobbe, Steven J. Pufka
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Patent number: 5639822Abstract: High-flow propylene/ethylene copolymers which have a melt flow index of from 2 to 200 g/min under a load of 2.16 kg at 230.degree. C. and which may be produced from the gas phase by polymerization in two stages in an agitated fixed bed in the presence of hydrogen acting as chain stoppage regulator and using a Ziegler-Natta catalyst system comprising a titaniferous solid component which contains a magnesium compound on finely divided silicon oxide or on finely divided aluminum oxide or on a finely divided aluminum silicate having the empirical formula SiO.sub.2.aAl.sub.2 O.sub.3, where a stands for a value between 0.001 and 2, and an aluminum component, by means of a procedure comprisinga) a first polymerization stage in which propylene is polymerized under a pressure of from 20 to 40 bar and at a temperature of from 60.degree. to 90.degree. C.Type: GrantFiled: December 12, 1994Date of Patent: June 17, 1997Assignee: BASF AktiengesellschaftInventors: Klaus-Dieter Hungenberg, Harald Schwager, Klaus Dieter Ruempler, Patrik Mueller
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Patent number: 5635567Abstract: Propylene polymer containing monomer units derived from at least one functional compound (A) comprising at least two vinyl unsaturations and one or a number of aromatic rings which exhibits a structural stress-hardening.Type: GrantFiled: December 18, 1995Date of Patent: June 3, 1997Assignee: Solvay (Societe Anonyme)Inventors: Fernand Gauthy, Eric Vandevijver, Martine Kaszacs
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Patent number: 5629080Abstract: Thermobondable fiber of at least one first component of polypropylene having a melt flow rate of 0.5-30, and at least one second component of polypropylene having a melt flow rate of 60-1000.Type: GrantFiled: January 13, 1993Date of Patent: May 13, 1997Assignee: Hercules IncorporatedInventors: Rakesh K. Gupta, James E. Mallory, Kunihiko Takeuchi
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Patent number: 5616153Abstract: A novel copolymer of an unsaturated acidic reactant and an atactic vinyl terminated propene polymer (VTPP) and its use in preparation of fuel and lubricant additives is taught. The VTPP has a major amount of polymer chains containing terminal vinyl unsaturation, a number average molecular weight of at least 500, and comprises at least 70 weight per cent propene and 0 to 30 weight per cent of at least one olefin selected from the group consisting of C.sub.2 and C.sub.4 to C.sub.10 olefins. The unsaturated acidic reactant comprises at least one unsaturated C.sub.4 to C.sub.10 carboxylic or dicarboxylic acid or anhydride. An oil soluble dispersant additive of the invention useful in oleaginous compositions is prepared by contacting the atactic VTPP copolymer with at least one nucleophilic reagent selected from the group consisting of amines, alcohols, metal reactants and mixtures thereof under conditions effective to form adducts of the nucleophilic reagent with the copolymer.Type: GrantFiled: October 3, 1995Date of Patent: April 1, 1997Assignee: Ethyl CorporationInventors: Carl A. Mike, Joseph J. Valcho, Daniel Yuan-Fu Yu
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Patent number: 5608009Abstract: There are herein disclosed an olefin copolymer which comprises an olefin unit and a diolefin unit and in which a weight-average molecular weight is in the range of 200 to 800,000, the content of the diolefin unit is in the range of 0.002 to 30 mol%, and a ratio TUS/DOU between the total content of unsaturated groups observed in a molecular chain (TUS mol%) and the content of the diolefin unit (DOU mol%) is in the range of 0.001 to 200; an olefin graft copolymer obtained by the graft polymerization of this olefin copolymer and an olefin; a hydrogenated olefin copolymer and olefin graft copolymer thereof; and a process for preparing these copolymers.These olefin copolymers are excellent in molding/working properties and have a good thermal stability, transparency and uniformity. Therefore, they are useful as a high-performance VLDPE, LDPE, L-LDPE and HDPE, and further useful as a novel branched propylene polymer, a thermoplastic elastomer, a compatibilizing agent for other resins, and the like.Type: GrantFiled: April 28, 1995Date of Patent: March 4, 1997Assignee: Idemitsu Kosan Co., Ltd.Inventors: Shuji Machida, Haruo Shikuma, Toshinori Tazaki, Tomio Tatsumi, Shinichi Kurokawa
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Patent number: 5605969Abstract: In accordance with the present invention, there is provided a method for the preparation of an ethylene polymer composition having a density of 0.86-0.94 g/cm.sup.3 and an intrinsic viscosity [.eta.] of 1-6 dl/g using an olefin polymerization catalyst composed of a transition metal compound containing a ligand having a cycloalkadienyl skeleton and an organoaluminium oxy-compound, and there is also provided a method for the preparation of an ethylene polymer composition having density of 0.87-0.93 g/cm3 and an intrinsic viscosity [.eta.] of 0.5-6 dl/g.Type: GrantFiled: October 25, 1993Date of Patent: February 25, 1997Assignee: Mitsui Petrochemical Industries, Ltd.Inventors: Toshiyuki Tsutsui, Takashi Ueda
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Patent number: 5589544Abstract: The invention relates to a soft thermoplastic elastomeric composition having improved resistance to oil swell and compression set comprising a blend of an engineering thermoplastic resin, a cured rubber concentrate and optionally a compatibilizer and a method for its preparation. The invention further relates to the cured rubber concentrate, a method for its preparation and the use thereof.Type: GrantFiled: May 15, 1995Date of Patent: December 31, 1996Assignee: Advanced Elastomer Systems, L.P.Inventor: Jacques Horrion
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Patent number: 5589549Abstract: Multistage process for the polymerization of olefins CH.sub.2 .dbd.CHR, where R is hydrogen or an alkyl, cycloalkyl or aryl radical with 1-10 carbon atoms, comprising two stages of polymerization. In a first stage, in the presence of a titanium or a vanadium catalyst and working in one or more reactors, an olefinic polymer with particular values of porosity is prepared; in a second stage, in the presence of the said porous polymer and a metallocene compound and/or their reaction products, one or more olefins, that are equal to or different from those polymerized in the first stage, are polymerized in one or more reactors.Type: GrantFiled: June 5, 1995Date of Patent: December 31, 1996Assignee: Montell Technology Company bvInventors: Gabriele Govoni, Mario Sacchetti, Stefano Pasquali
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Patent number: 5589541Abstract: A process for producing a modified propylene polymer comprising the steps of premixing a propylene polymer with a vinyl monomer and polymerizing the vinyl monomer by kneading the premix at a temperature of a melting point thereof or higher is described, wherein the propylene polymer is a particulate propylene polymer having a specific surface area of 0.1 m.sup.2 /g or more. A modified propylene polymer composition is also described, obtained by mixing (a) a particulate propylene polymer having a specific surface area of 0.1 m.sup.2 /g or more, (b) 5% by weight or more of a vinyl monomer mainly comprising an aromatic vinyl monomer based on the total weight of the vinyl monomer and the propylene polymer, and (c) a radical polymerization initiator, substantially impregnating the vinyl monomer and the radical polymerization initiator into the propylene polymer, and then polymerizing the vinyl monomer by melt-kneading.Type: GrantFiled: March 28, 1995Date of Patent: December 31, 1996Assignee: Dainippon Ink and Chemicals Inc.Inventors: Masafumi Kinoshita, Toshio Niwa, O. Shibata
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Patent number: 5571869Abstract: Grafted polymer particles are prepared by a free-radical addition polymerization mechanism using a flame produced by igniting a mixture of a combustible gas and an oxidant to heat at least a portion of the surface of a solid polymer particle to produce free-radicals thereon. At least one polymerizable ethylenically unsaturated monomer is contacted and reacted with the free-radicals formed on the surface of the polymer to form a graft thereon.Type: GrantFiled: April 25, 1995Date of Patent: November 5, 1996Assignee: The University of AkronInventors: Sunggyu Lee, Ramesh Rengarajan
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Patent number: 5563118Abstract: An additive composition comprising a graft and derivatized copolymer prepared from ethylene and at least one (C.sub.3 -C.sub.10) alpha- monoolefin and, optionally, a polyene selected from non-conjugated dienes and trienes comprising from about 15 to 80 mole percent of ethylene, from about 20 to 85 mole percent of said (C.sub.3 -C.sub.10) alpha- monoolefin and from about 0 to 15 mole percent of said polyene having an average molecular weight ranging from about 5,000 to 500,000, which has been reacted with at least one olefinic carboxylic acid acylating agent to form one or more acylating reaction intermediates characterized by having a carboxylic acid acylating function within their structure and reacting said reaction intermediate with an amino-aromatic compound to form said graft derivatized copolymer, and a lubricating oil composition containing same are provided.Type: GrantFiled: June 6, 1995Date of Patent: October 8, 1996Assignee: DSM Copolymer, Inc.Inventors: Munmaya K. Mishra, Isaac D. Rubin
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Patent number: 5561196Abstract: This invention relates to grafted polypropylene compositions and a process for their production. More particularly, the invention relates to polypropylene compositions based on polypropylene homopolymers, and copolymers of propylene with ethylene and/or butadiene, grafted with certain epoxy-alkyl acrylate compounds, and a process for their production. The grafted polypropylene compositions are useful especially as compatibilizers for addition to other polymer compositions.Type: GrantFiled: July 13, 1995Date of Patent: October 1, 1996Assignee: Den norske stats oljeselskap a.s.Inventors: Hans K. Kotlar, Per M. Hansen
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Patent number: 5561195Abstract: Polymeric compositions based on Linear Low Density Polyethylene (LLDPE) comprising: (A) from 75 to 95% by weight of an ethylene copolymer with an .alpha.-olefin CH.sub.2 =CHR, wherein R is an alkyl radical having from 1 to 10 carbon atoms, and (B) from 5 to 25% by weight of a copolymer of propylene with ethylene and an .alpha.-olefin CH.sub.2 =CHR.sup.I, wherein R.sup.I is an alkyl radical having from 2 to 10 carbon atoms. Copolymer (B) is characterised by a relatively high insolubility in xylene. The polymeric compositions of the invention are endowed with improved processability and improved mechanical properties with respect to the LLDPE of the conventional type.Type: GrantFiled: January 20, 1995Date of Patent: October 1, 1996Assignee: Montell Technology Company bvInventors: Gabriele Govoni, Massimo Covezzi, Claudio Cometto
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Patent number: 5541262Abstract: Crystalline propylene (co)polymers modified by grafting with a vinylpolybutadiene having 1,2-structure content of at least l0%.The (co)polymers are reacted with a liquid vinylpolybutadiene in the presence of a non-peroxidic radical initiator at a temperature in the range 200.degree. to 350.degree. C., the liquid vinylpolybutadiene having a 1,2-structure content of at least 10% and being generally used in amounts within the range 0.5 to 20% by weight.Type: GrantFiled: June 6, 1995Date of Patent: July 30, 1996Assignee: Centro Sviluppo Settori Impiego S.r.l.Inventors: Corrado Brichta, Francesco Mascia, Amodio Di Somma, Gabriele Torregiani, Antonio Addeo
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Patent number: 5541260Abstract: Disclosed is a polymer composition containing:(A) from 70 to 98 parts by weight of a crystalline propylene homopolymer, or a crystalline random copolymer of propylene with ethylene and/or C.sub.4 -C.sub.10 .alpha.-olefins, containing from 0.5 to 10% by weight of ethylene and/or .alpha.-olefins [fraction (A)]; and(B) from 2 to 30 parts by weight of elastomeric copolymer of ethylene with one or more C.sub.4 -C.sub.10 .alpha.-olefins, containing from 60 to 85% by weight of ethylene, and partially soluble in xylene at 25.degree. C. [fraction (B)];wherein the composition has an intrinsic viscosity value in tetrahydronaphthalene at 135.degree. C. of the fraction soluble in xylene at 25.degree. C. ranging from 0.8 to 1.1 dl/g.Type: GrantFiled: March 6, 1995Date of Patent: July 30, 1996Assignee: Montell North America Inc.Inventors: Anteo Pelliconi, Antonio Ciarrocchi, Paola Massari
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Patent number: 5536789Abstract: Propylene polymers have a molecular weight ratio Q (M.sub.w /M.sub.n) of from 6 to 30 and are obtainable by Ziegler-Natta polymerization in the presence of hydrogen as molecular weight regulator and are particularly suitable for the production of films and moldings.Type: GrantFiled: April 24, 1995Date of Patent: July 16, 1996Assignee: BASF AktiengesellschaftInventors: Harald Schwager, Peter Koelle, Rueger Schlund, Ralf Zolk, Juergen Kerth, Guenther Schweter, Klaus-Dieter Hungenberg, Werner Schoene
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Patent number: 5519090Abstract: Propylene polymer blends containinga) a propylene homopolymer having a melt flow index of from 0.001 to 5 g/10 min, as determined at 230.degree. C. under a load of 2.16 kg,b) a propylene/ethylene copolymer having an ethylene content of from 5 to 80% w/w, andc) a propylene homopolymer having a melt flow index of from 1 to 10.sup.4 g/10 min, as determined at 230.degree. C. under a load of 2.16 kg,the ratio of the melt flow index of the propylene homopolymer c) to that of the propylene homopolymer a) being within the range 10:1 to 10.sup.7 :1.The blends of the invention are high-flow materials showing a broad molecular weight distribution, and are thus readily processible.Type: GrantFiled: November 4, 1994Date of Patent: May 21, 1996Assignee: BASF AktiengesellschaftInventors: Harald Schwager, Klaus-Dieter Hungenberg
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Patent number: 5516849Abstract: The present invention provides a continuous process for producing an adducted derivatized EPM or EPDM oil solution in which a grafted ethylene polymer is adducted with an antioxidant diamine for formation of an adduct during holding.Type: GrantFiled: October 6, 1994Date of Patent: May 14, 1996Assignee: DSM Copolymer, Inc.Inventors: Tony L. Caines, Michael L. Junker
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Patent number: 5514761Abstract: Disclosed are unsaturated .alpha.-olefin/.alpha., .omega.-diene copolymers, and a method of preparation thereof. The copolymers are generally crystalline, free of gel and cross-links, and contain unsaturated side chains and long chain branching. The copolymers contain up to 5 mole percent diene incorporated therein, and may be prepared by copolymerization using a solid-phase, insoluble coordination catalyst, without a solvent, and below the crystalline melting point of the copolymer.Type: GrantFiled: February 10, 1995Date of Patent: May 7, 1996Assignee: Exxon Chemical Patents Inc.Inventors: Bradley P. Etherton, James J. McAlpin, Terrence Huff, Edward N. Kresge
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Patent number: 5489648Abstract: A modified polyolefin prepared from an aqueous suspension containing (a) a crystalline polyolefin, (b) 1 to 500 parts by weight of a vinyl monomer per 100 parts by weight of the crystalline polyolefin, and (c) 0.01 to 10 parts by weight of a radical polymerization initiator per 100 parts by weight of the vinyl monomer by impregnating the crystalline polyolefin (a) with the vinyl monomer (b) and heating the aqueous suspension to polymerize the vinyl monomer (b) at a temperature equal to or higher than a temperature at which the crystal region of the polyolefin (a) begins to substantially melt, which has an excellent effect of improving processability of other polyolefins and provides a polyolefin composition having excellent properties such as processability, impact resistance, rigidity and surface properties when the modified polyolefin is incorporated into polyolefins optionally with a core-shell graft copolymer and/or an inorganic filler.Type: GrantFiled: June 3, 1994Date of Patent: February 6, 1996Assignee: Kanegafuchi Kagaku Kogyo Kabushiki KaishaInventors: Yoshihiko Okimura, Taizo Aoyama, Hiroki Kobayashi, Akinori K. Shu, Kazuhiro Hara
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Patent number: 5480942Abstract: Polymers and copolymers of propylene are modified by grafting with polyalkenylenes having a trans double bond content of higher than 30%. The preparation is carried out via thermic treatment of the propylene (co)polymer with said polyalkenylene at a temperature comprised between 200.degree. and 350.degree. C. an the presence of a free radical initiator other than peroxide.Type: GrantFiled: May 9, 1994Date of Patent: January 2, 1996Assignee: Spherilene S.r.l.Inventors: Antonio Addeo, Corrado Brichta, Francesco Mascia, Arturo Marchioni
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Patent number: 5470843Abstract: Carbohydrate-containing polymers which can have an HLB* of from about 10 to about 20 are disclosed. The compounds comprise a hydrophilic polymer portion, a carbohydrate portion comprising from 1 to about 20 naturally occurring, identical or different, monosaccharide units, at least one bifunctional spacer coupling the carbohydrate portion to the hydrophilic polymer portion, and a potentiator moiety. The potentiator moiety can be is a crosslinking moiety located within the hydrophilic polymer or a hydrophobic, hydrophilic or ionic moiety. Processes for the preparation and use of such polymers are also disclosed.Type: GrantFiled: December 13, 1993Date of Patent: November 28, 1995Assignee: Hoechst AktiengesellschaftInventors: Wilhelm Stahl, Michael Ahlers, Axel Walch, Eckhart Bartnik, Gerhard Kretzschmar, Susanne Grabley, Rudolf Schleyerbach
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Patent number: 5468809Abstract: Polyolefin compositions having good transparency and impact resistance even at low temperatures including (by weight):A) from 25 to 95 parts of a crystalline random copolymer of propylene with ethylene and/or another .alpha.-olefin, containing more than 85% by weight of propylene, and having Haze values lower than 25%; andB) from 5 to 75 parts of a component comprising (a) an elastomeric copolymer of ethylene with propylene and/or another .alpha.-olefin, and optionally with minor proportions of a diene, containing 20-80 parts of ethylene, and (b) one or more of the polymers selected from LLDPE, LDPE, HDPE, having a Melt Index higher than 0.5 g/10 min., said (a) and (b) being present in such proportions that the ratio between the density of (A) and calculated average density of (B) is from 0.980 to 1.015.Type: GrantFiled: October 13, 1994Date of Patent: November 21, 1995Assignee: Montell North America Inc.Inventors: Renato Ghisellini, Giuliano Cecchin, Decio Malucelli