Abstract: A polymer includes at a terminus a cyclic amine radical bonded to the polymer through a ring nitrogen atom. The polymer can be provided by using a lithiated version of the cyclic amine to initiate polymerization of one or more ethylenically unsaturated monomers. The polymer can be used in the production in a variety of vulcanizates.

Abstract: The present invention is a novel block copolymer containing a controlled distribution copolymer block of a conjugated diene and a mono alkenyl arene, where the controlled distribution copolymer block has terminal regions that are rich in conjugated diene units and a center region that is rich in mono alkenyl arene units. Also disclosed is a method for manufacture of the block copolymer.

Abstract: The invention provides a rubber composition for golf balls which includes (A) a base rubber containing a polybutadiene having a cis-1,4 bond content of at least 60 wt %, (B) an unsaturated carboxylic acid and/or a metal salt thereof, and (C) two or more organic peroxides which include (C-1) an organic peroxide other than a diacyl peroxide and (C-2) an organic peroxide which is a diacyl peroxide. The golf ball rubber composition of the invention enables a high-quality molded and crosslinked product having a suitable hardness and a high resilience to be obtained.

Abstract: The invention provides a rubber composition for golf balls which includes (A) a base rubber containing a polybutadiene having a cis-1,4 bond content of at least 60 wt %, (B) an unsaturated carboxylic acid and/or a metal salt thereof, and (C) two or more organic peroxides which include (C-1) an organic peroxide having a one-minute half-life temperature of 145 to 185° C. and (C-2) an organic peroxide having a one-minute half-life temperature of 110 to 135° C. The golf ball rubber composition of the invention enables a high-quality molded and crosslinked product having a suitable hardness and a high resilience to be obtained.

Abstract: Disclosed herein are manganese, iron, cobalt, or nickel complexes containing 2,8-bis(imino)quinoline ligands and their use as catalysts or catalysts precursors for hydrosilylation reactions.

Abstract: Preparing brominated styrenic polymer by maintaining a mixture formed from (i) brominating agent, (ii) a solvent solution of styrenic polymer, and (iii) aluminum halide catalyst, at ?20 to +20° C., and terminating bromination in 20 minutes or less. New brominated anionic styrenic polymers have better melt flow and/or lower initial ?E values than the best previously-known brominated anionic styrenic polymers. Other features of such new polymers include high thermal stabilities at 320° C. and/or very low initial color values. Brominated styrenic polymers, especially brominated anionic styrenic polymers, are useful as flame retardants for thermoplastic polymers.

Abstract: A method for preparing a functionalized polymer, the method comprising the steps of (i) polymerizing conjugated diene monomer by employing a lanthanide-based catalyst to form a reactive polymer, and (ii) reacting the reactive polymer with a protected oxime compound.

Abstract: Elastomeric compounds having increased cold flow resistance may be obtained by utilizing from 10-100 phr of a functionalized rubbery polymer containing specified types of functionalizing units, at least 0.01 phr of a multivalent metal organic salt and 0-90 phr of at least one additional rubbery polymer.

Abstract: The present invention provides a polymeric agent which can incorporate a large amount of a drug, accumulate selectively in a tumor site, and has a molecular size of more than that for renal excretion. A metalloporphyrin derivative (such as zinc protoporphyrin) is associated with a styrene-maleic acid copolymer via non-covalent bond to give a SMA micelle complex, allowing provision of a polymeric pharmaceutical agent for treatment of cancer with a large amount of the drug incorporated. The SMA micelle complex can be produced by a method, wherein the metalloporphyrin derivative reacts with the styrene-maleic acid copolymer in the absence of a condensation agent under an alkaline condition, solubilized, adjusted to have a pH of 6-8, and subjected to a procedure for separating a polymer component to recover the micelle complex component for the polymeric pharmaceutical agent.

Abstract: A process is described for isomerizing halogenated butyl rubber from a microstructure that is predominantly exo-methylene (secondary allylic halide) to one that is predominantly endo-halomethyl (primary allylic halide). Isomerized halobutyl rubber is a halobutyl rubber that is more reactive toward a wide range of nucleophiles, thereby supporting more efficient processes for producing a variety of butyl rubber derivatives. The process includes mixing halogenated butyl rubber and a catalytic amount of metal carboxylate and optionally heating to form isomerized halogenated butyl rubber, and may be conducted in the absence or presence of solvent.

Abstract: Disclosed is a polymer light-emitting material for an organic electroluminescent device that displays excellent light-emitting performance and is applicable to a wet process. The polymer light-emitting material for an organic electroluminescent device is obtained by subjecting a thermoplastic resin having an Mw of 2,000-1,000,000 and containing a functional group in a unit constituting the backbone and a metal-containing phosphorescent dopant compound containing a reactive group capable of reacting with the said functional group to a polymer reaction so as to link a phosphorescent dopant moiety derived from the metal-containing phosphorescent dopant compound to the unit constituting the backbone of the thermoplastic resin. The content of the metal derived from the metal containing phosphorescent dopant compound in the said polymer light-emitting material is 0.001-20 wt %.

Abstract: Concurrently fed into a reaction zone held at about 10° C. or less are brominating agent, aluminum halide catalyst, and a solution of anionic styrenic polymer having a GPC Mn about 2000-30,000. The components are in at least two separate feed streams. The feeds are proportioned to maintain (a) the amount of aluminum halide being fed at about 0.8 mole percent or less based on the amount of aromatic monomeric units in the polymer being fed, and (b) amounts of brominating agent and unbrominated polymer in the reaction zone that produce a final washed and dried polymer product containing about 60-71 wt % bromine. The catalyst is deactivated, bromide ions and catalyst residues are washed away from the reaction mixture, and the brominated anionic styrenic polymer is recovered and dried. The dried polymer has a volatile bromobenzene content of about 600 ppm (wt/wt) or less as well as other beneficial properties.

Abstract: A method for forming a polymer including a sulfur-containing functional group, the method comprising introducing a sulfur-containing initiator defined by the formula with conjugated diene monomer and optionally copolymerizable monomer within a polymerization medium and allowing the sulfur-containing initiator to initiate the polymerization of the conjugated diene monomer and the optional copolymerizable monomer, where R1 is a monovalent organic group, R2 is a divalent organic group, R3 is a divalent organic group or a bond, and a is an integer from 1 to about 5.

Abstract: The present invention relates to white-emitting copolymers which are obtained by a combination of blue-, green- and red-emitting repeating units. The copolymers of the invention display better film formation and an improved efficiency when used in polymeric organic light-emitting diodes compared to materials according to the prior art.

Abstract: The present invention relates to a novel initiating system for the preparation of a living diene elastomer functionalized at the chain end by an amine group by anionic polymerization. The novel initiating system comprises an organolithium compound and a tin amide. The invention also relates to processes for the preparation of modified elastomers comprising an amine group at the chain end. These modified elastomers prove to be particularly advantageous in reinforced rubber compositions for tyres as they confer improved dynamic and mechanical properties in the vulcanized state.

Abstract: Vulcanizable elastomeric compositions and vulcanizates are prepared by employing a titanium compound. The titanium compound is believed to enhance the reaction between a silica particle and a silica-reactive compound.

Abstract: The present disclosure includes fluoropolymer-based materials, methods of making fluoropolymer-based materials, methods of using fluoropolymer-based materials, and the like.

Abstract: A synthetic graft has a glass composition comprises silicon as a network former and Sr as a stable isotope acting as a network modifier. The composition contains calcium as a network modifier and Zn acting as a as either a network modifier or as a network former. The glass composition may be mixed with a solution of polyalkenoic acid to provide advantageous glass polyalkenoate cements (GPCs). These cements are particularly effective for use as bone cements and fillers in the human skeleton as they set at room temperature, have similar strengths to bone, chemically bond to both bone and surgical metal, and release therapeutic ions, which can assist in wound healing and bone re-growth.

Abstract: The present invention concerns the use of RO. radicals, R being a hydrogen, an alkyl group having 2 to 15 carbons, an acyl group —COR? in which R? represents an alkyl group having 2 to 15 carbons, or an aroyl group —COAr in which Ar represents an aromatic group having 6 to 15 carbons, for the hydroxylation, alkoxylation or oxycarbonylation of polymer surfaces, the said polymers being different from polymers chosen from: polymethylmethacrylate (PMMA) and fluorocarbon polymers when R represents a hydrogen, or of polymer mixture surfaces, notably hydrophobic ones, the said polymers consisting in monomeric units of which at least 50% among these are aliphatic units, and the said RO. radicals being generated by electrochemical or photochemical means.

Abstract: The presently disclosed subject matter provides nanoscale coordination polymers for use as anticancer agents and as dual anticancer/imaging agents. The nanoscale coordination polymers can comprise a plurality of platinum metal complexes; nonplatinum anticancer drug bridging ligands complexed to multiple metal centers; or combinations thereof. The nanoscale coordination polymers can be targeted for delivery to cancer cells. They can also comprise stabilizing agents to allow for controlled and/or sustained release of anticancer agents in vivo.

Abstract: A gas-barrier material in which carboxyl groups are ionically crosslinked in an amount corresponding to an acid value of at least 330 mgKOH/g of a resin that has the carboxyl groups in an amount corresponding to an acid value of not smaller than 580 mgKOH/g. The gas-barrier material exhibits excellent gas-barrier property, retort resistance and flexibility under highly humid conditions, enables the film to be cured at a low temperature in a short period of time, and can be favorably produced.

Abstract: Described is the use of RO• radicals, R being a hydrogen, an alkyl group having 2 to 15 carbons, an acyl group —COR? in which R? represents an alkyl group having 2 to 15 carbons, or an aroyl group —COAr in which Ar represents an aromatic group having 6 to 15 carbons, for the hydroxylation, alkoxylation or oxycarbonylation of polymer or polymer mixture surfaces, the said polymers consisting in monomeric units of which at least 50% among these are aromatic units and the said RO• radicals being generated by electrochemical or photochemical methods.

Abstract: A compound of Formula (II) and (III), or a mixture of any two or more thereof; wherein M is Ti or Zr; R3 at each occurrence is H, F, Cl, Br, I, CN, OR4, NR5R6, substituted or unsubstituted alkyl, substituted or unsubstituted cycloalkyl, substituted or unsubstituted cycloalkylalkyl, unsubstituted heterocyclyl, or substituted or unsubstituted heterocyclylalkyl; R4 is H, substituted or unsubstituted alkyl, substituted or unsubstituted cycloalkyl, substituted or unsubstituted cycloalkylalkyl, unsubstituted heterocyclyl, or substituted or unsubstituted heterocyclylalkyl; R5 and R6 are independently H, substituted or unsubstituted alkyl, substituted or unsubstituted cycloalkyl, substituted or unsubstituted heterocyclylalkyl, or R5 and R6 may join to form a heterocyclic ring containing the N to which they are attached; and n?=0-4. Such compounds form optically transparent and/or clear films or particles or may be used to prepare such materials.

Abstract: The present invention relates to metal-containing compositions comprising a metal-containing precursor unit (MU), a prepolymer unit (PU), and a catalyst or an initiator capable of inducing a combining reaction of ethylenically unsaturated groups of the metal-containing precursor unit and the prepolymer unit. In another embodiment, the composition comprises MU and a catalyst or initiator capable of inducing a combining reaction of the metal-containing precursor units. Both MU and PU contain additional functional groups, which may be selected to impart compatibility with each other and to produce optically clear films. The metal-containing compositions can be used to produce films or articles having a transmittance of at least 90% and index of refraction in the range of 1.4 to 1.8 in the 400-700 nm range of light and 1.4 to 2.4 in the 150-400 nm range of light.

Abstract: Stable water-borne polymer compositions are disclosed. The compositions comprise a water-borne polymer, a metal cross-linking agent and a stabilizing agent comprising from 2 to 10 carbon atoms and at least two functional groups independently selected from hydroxy and carboxy. The stabilizing agent is present a 1.4 mole percent or more of the amount of metal cross-linking agent. Inventive compositions are particularly suitable for use in water-based inks and coatings. Methods of making and using the coating compositions are also described.

Abstract: Compositions of vinyl halide polymers such as PVC are rendered compostable by a prodegradant system of a monomeric adduct of an organotitanate or zirconate and an organotin. PVC sheets and composites are compostable in landfills.

Abstract: The present invention relates to a process for the selective hydrogenation of the carbon-carbon double bonds in diene-based polymers in bulk form by treatment of the polymer with hydrogen in the presence of a platinum group metal containing catalyst and in the absence of any organic solvent.

Abstract: An indwelling urinary drainage catheter (12, 110) includes synthetic polyisoprene rubber (SPIR). Advantageously, the SPIR catheter can meet the tensile and resiliency requirements of Foley applications while avoiding the risk of allergic reactions in sensitive patients. The SPIR comprises an accelerator system that uses a carbamate as the only accelerator, a guanidine as the only accelerator, a combination of guanidine and carbamate accelerators, a combination of carbamate and thiazole accelerators, or a combination of guanidine, carbamate and thiazole accelerators.

Abstract: Compositions comprising a polymer resin comprising at least one copolymer with hydrolysable groups, an amino acid or dicarboxylic acid water-generating organic compound, and a catalyst that comprises a metal atom and at least two ligands taken from the set alkyloxy and earhcxylate are used to form articles that moisture-cure through in-situ generation of water via ring-closing dehydration reactions.

Abstract: This invention discloses a process for synthesizing a dendrimer of a rubbery polymer comprising: (a) reacting a lithium terminated rubbery polymer with a halogenated tin containing compound to produce a polymer which is terminated with halogenated tin moieties, wherein the halogenated tin containing compound is of the structural formula: wherein X represents a halogen atom, wherein Z1 groups can be the same or different and are selected from alkyl groups containing from 1 to 8 carbon atoms, wherein x represents an integer from 1 to 20, wherein the molar ratio of the lithium terminated rubbery polymer to halogen atoms in the halogenated tin containing compound is within the range of 2:n to (n?1):n, wherein n represents the number of halogen atoms that are bonded directly to tin atoms in the halogenated tin containing compound; (b) reacting the polymer which is terminated with halogenated tin moieties with a molar excess of a tertiary alcohol to produce a polymer which is terminated with hydroxy tin moietie

Abstract: The present invention relates to a pre-accelerated resin composition, characterized in that the resin composition comprises an unsaturated polyester resin and/or a vinyl ester resin, a soluble copper compound and a heterocyclic aromatic amine and which resin composition is essentially free of cobalt. The present invention further relates to a two component composition in which the first component comprises such a resin composition and in which the second component comprises an organic peroxide.

Abstract: The invention provides a process for increasing the melt flow index of a polyolefin, the process comprising using a melt mixing device to melt mix the polyolefin in contact with oxygen and a transition metal catalyst having a redox potential ranging from 0 to 2 volts, wherein oxygen is introduced to the melt mixing device, and wherein the transition metal catalyst in contact with the polyolefin forms at least part of a component of the melt mixing device.

Abstract: A process for producing a phenylene ether oligomer comprising oxidative polymerization of a specific bivalent phenol compound and a specific monovalent phenol compound in an aromatic hydrocarbon solvent, wherein the aromatic hydrocarbon solvent of a phenylene ether oligomer solution obtained after the termination of the polymerization is replaced with a water-soluble organic solvent having a boiling point higher than that of the aromatic hydrocarbon solvent and the resultant phenylene ether oligomer solution is brought into contact with water, thereby precipitating the phenylene ether oligomer as particles.

Abstract: The present invention provides a resin composition having an oxygen scavenging function. The resin composition comprises 70 to 99.9 wt % of a polyvinyl alcohol resin (A) and 0.1 to 30 wt % of a thermoplastic resin (B) other than the polyvinyl alcohol resin (A), wherein the thermoplastic resin (B) has a carbon-carbon double bond and a functional group including a hetero atom, and an oxygen absorption rate of the resin composition is 0.001 ml/m2·day or more.

Abstract: Disclosed herein are novel polymer-tethered ligands, metal complexes comprising these ligands, and the use of these complexes as chain transfer catalysts to control the molecular weight of oligomeric and polymeric materials produced in a radical polymerization process. The materials made by the processes disclosed herein have significantly reduced color, making them suitable for a wide range of color-critical end-uses, including automotive coatings.

Abstract: This invention provides a modified natural rubber producible at a lower cost than the conventional techniques and capable of improving the low loss factor, wear resistance and fracture characteristics of the rubber composition using the modified natural rubber as the rubber component in the rubber composition, and a method for producing the modified natural rubber. This invention provides a modified natural rubber formed by adding a hydrazide compound having a polar group to at least one natural rubber raw material selected from the group consisting of a natural rubber, a coagulated natural rubber latex and a natural rubber cup lump, a rubber composition using the modified natural rubber, and a tire using the rubber composition in any tire member.

Abstract: A composition useful for treating fabrics. The composition contains a silver-containing copolymer having polymerized units of a monomer X which is an ethylenically unsaturated compound having a substituent group selected from an unsaturated or aromatic heterocyclic group having at least one nitrogen atom and polymerized units of a monomer Y which is an ethylenically unsaturated compound selected from carboxylic acids, organosulfuric acids, sulfonic acids, phosphonic acids and esters comprising polymerized units of ethylene oxide.

Abstract: A process for making a high viscosity poly(trimethylene terephthalate) (PTT) resin having a low cyclic dimer content of less than or equal to 1.1 wt % as determined with nuclear magnetic resonance analysis and an intrinsic viscosity in the range of 0.9 to 2.0 dL/g; the PTT resin composition provided by the process; and molded articles derived from the composition are disclosed.

Abstract: Process for modifying a polyolefin grafted with acid or anhydride groups, by at least partial neutralization of these groups with at least one neutralizing agent comprising an organic salt (1) that releases an organic acid (I) during the neutralization, according to which the organic acid (I) derived from the neutralization of the grafted polyolefin is reacted with at least one inorganic salt (2). Modified polyolefin (that can be) obtained by the process described above. Polymeric composition containing (A) at least one polymer, and (B) at least one modified polyolefin (that can be) obtained by the process above. Article comprising the modified polyolefin or the composition described above.

Abstract: Process for the preparation of polyalkenyl acylating agents which comprises: a. reacting at a temperature higher than 180° C. a reactive polyalkene, having a number average molecular weight Mn ranging from 500 to 5000 and having a content of terminal vinylidene groups greater than or equal to 30%, with an enophile; b. thermally carrying out the reaction for a time sufficient for having a conversion of the terminal vinylidene groups higher than 15%; c. completing the reaction always under heat in the presence of a reaction accelerator consisting of a Lewis acid selected from a tin, zinc, aluminum or titanium halide.

Abstract: A water-absorbing agent according to the present invention includes water-absorbent resin particles having an internal cross-linked structure, wherein a vicinity of a surface of the water-absorbent resin particle is cross-linked with a surface cross-linking agent, and the water-absorbent resin particle has therein a sea-island structure having (i) part containing a first water-soluble multivalent metal salt such as aluminum sulfate and (ii) part not containing the first water-soluble multivalent metal salt. With this arrangement, it is possible to provide a water-absorbing agent having less water-soluble component content, more excellent liquid permeability, and more excellent water retention under pressure than the conventional water-absorbing agent.

Abstract: A curable composition has an olefin polymer including hydrolysable silane groups on its main chain; and to a latent compound suitable for releasing a curing catalyst under the action of a rise in temperature and/or actinic radiation.

Abstract: Provided is a method comprising reacting the anionic living end of a polymer with a compound selected from the group consisting of tin halides and silicon halides to produced a polymer with a homolytically cleavable group containing a Sn—C bond or a Si—C bond. An engineered plastic may then be produced by adding the polymer containing a homolytically cleavable group containing a Sn—C bond or a Si—C bond to a solvent comprising at least one vinyl monomer; (b) optionally adding at least one additional inert solvent; (c) optionally adding additives selected from the group consisting of extender oils, modifiers, and antioxidants; and (d) initiating polymerization of the at least one vinyl monomer by the use of an initiator and/or heat, wherein a free radical is produced from the polymer containing a homolytically cleavable group containing a Sn—C bond or a Si—C bond.

Abstract: A pressure sensitive adhesive formed from a blend of an acrylate polymer having at least one crosslinkable functional group, and a liquid oligomer having at least one crosslinkable functional group, wherein at least one of the acrylate polymer and the oligomer is crosslinked in the presence of the other.

Abstract: The present invention relates to white-emitting copolymers which are obtained by a combination of blue-, green- and red-emitting repeating units. The copolymers of the invention display better film formation and an improved efficiency when used in polymeric organic light-emitting diodes compared to materials according to the prior art.

Abstract: Supported heterogeneous organotin catalysts of the formula X1, X2, or X3: wherein Z is a spacer group; Y is an insoluble phenyl-group containing copolymer; R1, R2, R3, R5, and R6 are independently selected from halogen, alkyl, alkylene, phenyl, vinyl, allyl, naphthyl, aralkyl, and Z; and R4 is alkyl, alkylene, phenyl, vinyl, allyl, naphthyl, or aralkyl.

Abstract: An improved process for the metathetic degradation of nitrile rubber using catalyst systems comprising the catalyst and also a phosphane or diphosphane is provided.

Abstract: A cushion gum for bonding a tire tread to a tire carcass, the cushion gum comprising an essentially unsaturated diene elastomer, between (0.5) and (25) phr of a metal salt of a carboxylic acid and a peroxide curing system. The essentially unsaturated diene elastomer may be, in some embodiments, a highly unsaturated diene elastomer such as, for example, natural rubber.

Abstract: Concurrently fed into a reaction zone held at about 10° C. or less are brominating agent, aluminum halide catalyst, and a solution of anionic styrenic polymer having a GPC Mn about 2000-30,000. The components are in at least two separate feed streams. The feeds are proportioned to maintain (a) the amount of aluminum halide being fed at about 0.8 mole percent or less based on the amount of aromatic monomeric units in the polymer being fed, and (b) amounts of brominating agent and unbrominated polymer in the reaction zone that produce a final washed and dried polymer product containing about 60-71 wt % bromine. The catalyst is deactivated, bromide ions and catalyst residues are washed away from the reaction mixture, and the brominated anionic styrenic polymer is recovered and dried. The dried polymer has a volatile bromobenzene content of about 600 ppm (wt/wt) or less as well as other beneficial properties.

Abstract: Preparing brominated styrenic polymer by maintaining a mixture formed from (i) brominating agent, (ii) a solvent solution of styrenic polymer, and (iii) aluminum halide catalyst, at ?20 to +20° C., and terminating bromination in 20 minutes or less. New brominated anionic styrenic polymers have better melt flow and/or lower initial ?E values than the best previously-known brominated anionic styrenic polymers. Other features of such new polymers include high thermal stabilities at 320° C. and/or very low initial color values. Brominated styrenic polymers, especially brominated anionic styrenic polymers, are useful as flame retardants for thermoplastic polymers.