Abstract: Cationic or amphoteric (co)polymer obtained by Hofmann degradation reaction, in aqueous solution, in the presence of an alkaline-earth and/or alkali metal hydroxide and of an alkaline-earth and/or alkali metal hypohalide, on a base (co)polymer comprising at least one nonionic monomer chosen from the group comprising acrylamide (and/or methacrylamide) and N,N-dimethylacrylamide, is characterized in that the base (co)polymer is modified beforehand with at least one polyfunctional compound containing at least 3 heteroatoms chosen from N, S, O and P and each having at least one mobile hydrogen. Use as a flocculation, retention and/or drainage aid, and dry strength aid is contemplated.

Abstract: Polymers including two or more different recurring units are disclosed herein. Also disclosed herein are methods of using such polymers to deliver nucleic acids to a cell.

Abstract: Disclosed are toughened, antistatic resin composition and an article comprising the composition wherein the composition comprises or consists essentially of poly(hydroxyalkanoic acid), such as polylactic acid; an impact modifier comprising an ethylene copolymer; and an ion conducting polymer.

Abstract: Methods for preparing functionalized polyvinylpyrrolidones with polymerizable functions. Also, amphipathic polydimethylsiloxane-PVP block copolymers, such as and (meth)acrylated and (meth)acrylamide-functionalized polyvinylpyrrolidone compounds, such as The block copolymers are useful as biomaterial components in biomedical devices. They provide improved wettability, lubricity, and material compatibility to the biomedical device, e.g., ophthalmic lenses.

Abstract: This disclosure discloses novel responsive polymers that comprise a rod segment and (or) a coil segment. This disclosure also discloses nanomaterial-polymer composite comprising the responsive polymers that are covalently linked with nanomaterials. Also disclosed are polymeric transducer materials and sensor systems that comprise the nanomaterial-polymer composite.

Abstract: Single-phase fluid compositions, comprising at least two isocyanate-reactive polyol components which are inherently incompatible with each other and as a mediator additive at least one copolymer compatibilizer additive effectuating compatibility between the originally incompatible polyol components, said copolymer comprising structural units having at least one nitrogen group which can be protonized.

Abstract: The present document relates to a manufacturing method for pH-sensitive graft polymer micelles and a polymer micelle-type pharmaceutical composition containing the graft copolymer. The pH-sensitive graft copolymer micelles are usable as various markers and contrast agents for various molecular images for the diagnosis and treatment of diseases and a carrier for delivery of various medicines according to disease. The pH-sensitive graft copolymer forms micelles that can be used in target-oriented diagnosis and medicine release according to changes in the pH of a body. The polymer micelles are provided by inducing a graft copolymer of poly(?-amino ester) compounds which has a solubility in water depending on pH but is incapable of forming the micelles due to a self-assembly phenomenon, and hydrophilic poly(ethylene glycol) compounds.

Abstract: Polyacetylinic oligomers suitable for high-temperature polymer-matrix composites are provided. The polyacetylinic oligomers have the formula: D-A-D wherein D is an endcap including at least one crosslinking functionality; and A is backbone selected from the group consisting of imidesulfone; ether; ethersulfone; amide; imide; ester; estersulfone; etherimide; amideimide; oxazole; oxazole sulfone; thiazole; thiazole sulfone; imidazole; and imidazole sulfone. At least one ethynyl functional group, however, is incorporated into the backbone such that crosslinking is not only realized at the endcaps but also at the ethynyl groups within the backbone of the oligomer itself.

Abstract: An oligomer having di-phenylethynyl endcaps is disclosed. The capped oligomer has the formula: D-A-D wherein D is a di-phenylethynyl endcap; and A is an oligomer selected from the group consisting of imidesulfone; ether; ethersulfone; amide; imide; ester; estersulfone; etherimide; amideimide; oxazole; oxazole sulfone; thiazole; thiazole sulfone; imidazole; and imidazole sulfone.

Abstract: A protective polymeric coating is applied to the surface of various objects which are to be exposed to a harsh environment. The protective polymeric coating covers the exposed surface, where the polymeric coating includes a polyimide polymer. The polyimide polymer in the polymeric coating has a backbone with at least one non-terminal phenyl group. A linkage is connected to the non-terminal phenyl group, where the linkage can be an amide linkage or an ester linkage. An oligomeric silsesquioxane compound is connected to the linkage through an organic substituent, where the oligomeric silsesquioxane is not incorporated into the polymer backbone. The polymeric coating provides protection to the underlying object.

Abstract: A reflective film includes a polymeric layer and a reflective component. The polymeric layer includes a polyimide polymer, where the polyimide polymer has a backbone with at least one non-terminal phenyl group. A linkage is connected to the non-terminal phenyl group, where the linkage can be an amide linkage or an ester linkage. An oligomeric silsesquioxane compound is connected to the linkage through an organic substituent, where the oligomeric silsesquioxane is not incorporated into the polymer backbone.

Abstract: A solar panel has a face which can be directed towards the sun for generating heat or electricity. The solar panel face is protected by a polymeric coating. The polymeric coating includes a polyimide polymer made by reacting at least one acid monomer with at least one diamine monomer to form the polyimide polymer backbone. The monomers are selected such that the polyimide backbone includes at least one non-terminal attachment point. An oligomeric silsesquioxane compound is attached to the polyimide backbone by reacting a functional group to the attachment point, where the functional group is connected to the oligomeric silsesquioxane compound. The polymeric compound can provide a relatively lightweight protective layer for the solar panel, which can reduce the total weight of the solar panel.

Abstract: A curable mixture is provided that is substantially free of volatile nonreactive compounds. Also provided is a method for making such curable mixtures, and a method of bonding substrates with such curable mixtures.

Abstract: A variety of graft copolymers can be formed sodium poly(aspartate) with a wide variety of monomers in an aqueous medium by the use of grafting method in the presence of radical initiator at a temperature of from about five degrees Centigrade to about 100 degrees Centigrade. Graft copolymers at high conversion with molecular weight up to millions can be prepared using this method.

Abstract: The present invention relates to a process for producing a polyester comprising: (a) forming a polyester in a melt phase having an intrinsic viscosity of about 0.65 or more, provided that said forming is not by solid state polymerization; and (b) adding an anhydride to the polyester during the melt phase. The present invention also includes articles comprising a composition produced by processes of the present invention.

Abstract: Novel conjugates of the pharmaceutically active metabolite of irinotecan and novel immunogens derived from this pharmaceutically active metabolite and monoclonal antibodies generated by these immunogens which are useful in immunoassays for the quantification and monitoring of the pharmaceutically active metabolite of irinotecan in biological fluids.

Abstract: The invention relates to copolymers based on unsaturated mono or dicarboxylic acid derivatives, oxyalkyleneglycol-alkenyl ethers, vinyl polyalkyleneglycol or ester compounds, in addition to the use thereof as additives for aqueous suspensions based on mineral or bituminous binding agents. Said invention is characterized in that the inventive copolymers, having a long lateral chain, impart small amounts of excellent processing properties to aqueous binding suspension, and simultaneously cause the water content in the concrete to be greatly reduced.

Abstract: An organic/inorganic hybrid material is provided, which includes an organic polymer and a plurality of inorganic nanoparticles, wherein the inorganic nanoparticles are self-connected or connected via a linker to constitute an inorganic network structure. By forming the inorganic network structure through interconnection of inorganic nanoparticles, the inorganic content in the hybrid materials can be drastically increased to improve the properties thereof. A method for fabricating the organic/inorganic hybrid material is also provided.

Abstract: A graft copolymer based on a component a) consisting of silica which has been reacted with an unsaturated silane, and a polymer component b) containing sulphonic acid is proposed. The silica used is preferably a nanosilica and the unsaturated silane is an ethylenically unsaturated alkoxysilane. The component b) is represented by a copolymer based on AMPS and a further ethylenically unsaturated monomer. The polymer according to the invention, which as a rule is a nanocomposite, is outstandingly suitable as an additive in construction chemistry applications and in the development, exploitation and completion of underground mineral oil and natural gas deposits, its effect as a water retention agent being particularly advantageous at high salinities and increased temperatures.

Abstract: A prepreg composite material that includes a fiber layer and a resin comprising a thermoset resin component, a curing agent and a fibrous micropulp. The micropulp component is an aramid fiber having a volume average length of from 0.01 to 100 micrometers. The prepreg is useful in composite panel construction for minimizing fluid permeation into the cured structure. This prepreg is particularly suitable for making honeycomb sandwich panels. Film adhesives, liquid and paste resins containing aramid fiber micropulp are also disclosed.

Abstract: A foam comprising the reaction product of one or more multifunctional acrylates with one or more multifunctional aceto- or cyano-acetate compounds in the presence of a base and a blowing agent.

Abstract: A material for solid polymer electrolyte, made of a polyether polymer having a moisture content in the range of 400 to 5,000 ppm by weight. A formed solid polymer electrolyte, which is made by mixing the material for solid polymer electrolyte together with an electrolyte salt compound soluble in the polyether polymer, has good ionic conductivity and high mechanical strength. A polyether polymer having a moisture content not larger than 0.04% by weight and a toluene-insoluble content not larger than 5% by weight. This polyether polymer gives a formed solid polymer electrolyte having a smooth surface.

Abstract: Described herein are compositions including heterocyclic organic compounds such as fused thiophene compounds, methods for making them, and uses thereof.

Abstract: Multilayered pellets are provided that contain an ethylene-vinyl alcohol copolymer (EVOH) and a polyamide resin and that have excellent thermal stability during pelletizing and melt molding. The multilayered pellets each are composed of at least two resin layers and include a resin layer A whose main component is EVOH and a resin layer B whose main component is a polyamide resin. In the multilayered pellets, at least 70 mol % of all the terminals of the polyamide resin are blocked by units each containing an imide structure.

Abstract: Biodegradable poly(ester-amides) are synthesized from amino acids, diols and dicarboxylic acids where one or both of the diols and dicarboxylic acids contain unsaturation; e.g., from di-p-nitrophenyl dicarboxylates and p-toluenesulfonic acid salts of bis(alpha-amino acid) disesters of diols where one or both of the dicarboxylate and diol moieties contain unsaturation or from di-p-nitrophenyl dicarboxylates, and p-toluene-sulfonic acid salts of bis(alpha-amino acid) diesters of diols and p-toluenesulfonic acid salt of lysine ester where one or both of the dicarboxylate and diol moieties contain unsaturation. The polymers are useful as biodegradable carriers for drugs of other bioactive agents.

Abstract: A thermally processable graft copolymer formed from a water soluble polymer and a water insoluble polymer, wherein the graft copolymer forms a hydrogel upon exposure to water.

Abstract: It is an object of the present invention to provide a resin composition having improved heat resistance (high crystallinity) and transparency without impairing rigidity intrinsic to a polylactic acid based resin, a molded body formed from the resin composition, and a new polylactic acid based resin used in the resin composition. A polylactic acid based resin (A) according to the present invention is characterized by having a specific structural moiety and a weight average molecular weight (Mw) of 5,000 to 1,000,000. A polylactic acid based resin composition according to the present invention is characterized by containing the above-described polylactic acid based resin (A).

Abstract: A thermally processable graft copolymer formed from a water soluble polymer and a water insoluble polymer, wherein the graft copolymer forms a hydrogel upon exposure to water.

Abstract: A copolymer and a process of making the copolymer are disclosed. The copolymer is produced from reacting a glycidyl ester and/or ether with a polyol comprising a functionality of at least 2 wherein at least 50% by weight of the copolymer comprises a minimum of 3n+X repeating units, wherein n is a monomer unit and X is a monomer unit and/or other reactant. The copolymer may also include less than 50% of the polymeric units having the same molecular weight. The present invention is further directed to processes for preparing the copolymer and to coating compositions employing the copolymer.

Abstract: A heat-curable resin composition, comprising (A) a polyimide silicone resin having a phenolic hydroxyl group and a radically polymerizable group bonded to a silicon atom, (B) an epoxy resin in such an amount that a molar ratio of the epoxy groups of the epoxy resin to the phenolic hydroxyl groups of the polyimide silicone resin (A) ranges from 0.2 to 10, and a catalytic amount of (C) an organic peroxide.

Abstract: An oligomer having di-phenylethynyl endcaps is disclosed. The capped oligomer has the formula: D-A-D wherein D is a di-phenylethynyl endcap; and A is an oligomer selected from the group consisting of imidesulfone; ether; ethersulfone; amide; imide; ester; estersulfone; etherimide; amideimide; oxazole; oxazole sulfone; thiazole; thiazole sulfone; imidazole; and imidazole sulfone.

Abstract: The invention provides a process for synthesising functionalised chain transfer polymers of Formula (1) or Formula (2) using thiocarbonyl thio compounds as chain transfer agents. Why R1 is a moiety comprising a functional group; Q is obtained from an olefinically unsaturated monomer; R? is selected from the group consisting of alkyl, substituted alkyl, alkoxy, substituted alkoxy, an aromatic saturated or unsaturated carbocyclic or heterocyclic ring, optionally substituted with one or more substituents, amino alkyl, cyanoalkyl, hydroxylalkyl, saturated and unsaturated amido; an organometallic species, a polymer chain and any of the foregoing substituted with one or more CN or OH groups; q=an integer of at least 2; p=an integer of at least 1. Chain transfer agents and polymers produced by the method are also provided.

Abstract: A polyurethane resin is synthesized from a compound represented by the following Formula (1), a polymerizable composition includes the polyurethane resin, a planographic printing plate precursor includes a photosensitive layer including the composition, and a method produces a diol compound that can be used as a raw material of the polyurethane resin. In Formula (1), R1 and R2 each independently represent a single bond or an alkylene group optionally having a substituent, R3 represents a hydrogen atom or an alkyl group, R4 represents a hydrogen atom or an alkyl group, and A represents a divalent or higher linking group, provided that R1 and R2 are not both a single bond.

Abstract: The present invention is directed to a non-gelled, curable composition including at least one compound having a plurality of imide functional groups. The compound in particular contains a reaction product of a) at least one hydroxyalkylamino functional succinimide; b) at least one polyisocyanate; and optionally c) at least one capping agent. The composition is suitable for use in coatings and castings.

Abstract: The invention provides a phenolic hydroxyl group-containing rubber-modified polyamide resin capable of providing a cured product with excellent heat resistance, adhesion properties, electrically insulating property and flame retardance and having a sufficient flexibility when being shaped into a film, which is characterized by having in its molecule (a) a phenolic hydroxyl group-containing aromatic polyamide segment represented by the following formula (1): (in the formula (1), m and n are average values and satisfy a relationship of 0.005?n/(m+n)?1.00 and m+n is an integer of 2-200, and Ar1 is a bivalent aromatic group, Ar2 is a bivalent aromatic group having a phenolic hydroxyl group and Ar3 is a bivalent aromatic group) and (b) a hydrogenated butadiene polymer segment.

Abstract: Methods for preparation of functionalized polyvinylpyrrolidone with polyme?zabl? functions and amphipathic polydimethylsiloxane-PVP block copolymers A (meth)acrylated polyvinylpyrrolidone compound and a (meth)acrylamide-functionalized polyvinylpyrrolidone structures are disclosed The block copolymers are useful as biomaterial components in biomedical devices They provide improved wettability, lubricity, and material compatibility to the biomedical device, e g, ophthalmic lenses

Abstract: Polymers initiated with hydroxamates and compositions containing such polymers are suitable for use in making medical devices, delivery agents, coatings for such items, and the like.

Abstract: The invention relates to novel photopolymers based on specific urethane acrylates as writing monomers, which are suitable for producing holographic media, in particular for visual display of images.

Abstract: The invention is based on the discovery that the compounds and compositions described herein are useful as film-forming adhesives for use in a variety of applications, including, for example, adhesive tapes for the electronic packaging industry. The invention compositions described herein can be cured in a variety of ways with or without a catalyst.

Abstract: Materials and methods for the generation of polyelectrolyte multilayers that can erode to release cationic components. The multilayers comprise layers that contain one or more cations and one or more charge-dynamic anionic polymers. Charge-dynamic anionic polymers contain side chains having removable functional groups. Removal of the functional groups results in a change in the net change in the charge of the polymer which can disrupt interactions between cations and the anionic polymers and facilitate release of cations.

Abstract: A polymerizable composition comprising: a polyurethane resin synthesized by using a compound represented by the following formula (I) as one of starting materials; a photopolymerization or thermal polymerization initiator; and an addition-polymerizable compound having an ethylenically unsaturated bond: wherein X represents a tri- or higher valent atom; R1 and R2 each independently represent a single bond or an alkylene group optionally having a substituent, provided that R1 and R2 do not represent a single bond at a same time; A represents a straight chain linking group; and n is an integer of from 1 to 5.

Abstract: A copolymer composition comprising monomers copolymerized in the following percentages by weight: (a) from about 20% to about 95% of a monomer, or mixture of monomers, of formula (I): CnF2n+1(CH2)x[(CF2CF2)y(CH2CH2)z]m-L-C(O)—C(R)?CH2??(I) wherein R is H, Cl, F or CH3, L is O, S, NH, S—(CH2)rO, S—(CH2)rNH, OC(O)NH—CH2CH2O, NHC(O)NHCH2CH2O, S—(CH2)rOC(O)NHCH2CH2O, or S(CH2)rNHC(O)NHCH2CH2O, and (b) from about 5% to about 80% of at least one of: (i) an alkyl (meth)acrylate monomer having a linear, branched or cyclic alkyl group of from about 6 to about 18 carbons; or (II) a monomer of formula (II) (R2)2N—R3—O—C(O)—C(R)?CH2??(II) wherein R is H, Cl, F or CH3, each R2 is independently a C1 to C4 alkyl; and R3 is a divalent linear or branched C1 to C4 alkylene; and wherein the nitrogen is from about 40% to 100% salinized; or (iii) a mixture thereof.

Abstract: A soluble polyimide polymer with tethered oligomeric silsesquioxane compounds is produced using efficient, gentle reactions. A carboxylic acid attachment point on the polymer backbone is used to connect the oligomeric silsesquioxane. The oligomeric silsesquioxane compound includes an amine or an alcohol on an organic tether, which reacts with the carboxylic acid attachment point to produce either an amide or an ester bond. The amide or ester bond includes a carbonyl carbon directly connected to a phenyl group in the polymer backbone. The resultant polyimide polymer has many beneficial properties.

Abstract: The present invention relates to the use of (meth)acrylate functionalized amide acetals as reactive components with crosslinking agents and UV radiation to give new coatings compositions.

Abstract: The present invention relates to a polymerizable composition comprising a) at least one ethylenically unsaturated monomer and b) at least one hydroxylamine of high molecular weight, preferably a long chain alkyl substituted hydroxylamine. Further aspects of the present invention are a process for polymerizing ethylenically unsaturated monomers, and the use of high molecular weight hydroxylamines for controlled polymerization.

Abstract: A composition comprising a polymer that is a reaction product of: a copolymer backbone comprising; (i) at least one acrylamide component, (ii) at least one co-monomer, (iii) at least one initiator and (iv) at least one chain transfer agent; and at least one cellulose reactive agent; wherein the copolymer backbone and cellulose reactive agent are combined with water to form a solution wherein the concentration of the copolymer backbone is about 0.1 to about 19% by weight based on the total weight of the solution. A process to make high solids copolymer backbone with low molecular weight and narrow molecular weight distribution has also been developed by a continuous polymerization process under refluxing conditions. In this process, a mixture of the acrylamide, co-monomer and chain transfer agent and the initiator are simultaneously and continuously added to a heel of water.

Abstract: Disclosed is a resin composition comprising a benzoxazole resin precursor having a first repeating unit obtained by reacting a bisaminophenol compound and a dicarboxylic acid compound, and a cross-linking agent wherein at least one of the bisaminophenol compound and the dicarboxylic acid compound has a diamondoid structure. The benzoxazole resin precursor further comprises a second repeating unit obtained by reacting a bisaminophenol compound not having a diamondoid structure and a dicarboxylic acid compound not having a diamondoid structure. Also disclosed is a resin film comprising the resin composition.

Abstract: Compositions comprising a blend of two or more paper strengthening agents have improved stability compared with previously known paper strengthening agents. One component is a polymeric paper strengthening agent, preferably a wet strengthening agent. The other component is a stabilized polyacrylamide prepared by (1) reacting a first portion of glyoxal with a polyacrylamide having pendant amide groups to form a first reaction mixture comprising polyacrylamide; (2) adding an acid to the first reaction mixture to form a second reaction mixture having a reduced pH and comprising the polyacrylamide; and (3) adding a second portion of glyoxal to the second reaction mixture to form the stabilized polyacrylamide. If desired, an aldehyde scavenger can be included in one or more of step (1), step (2), step (3), or the stabilized polyacrylamide. Such compositions can be used to enhance the strength of paper, particularly the wet strength of paper.

Abstract: Acrylate adhesive composition comprising N-methacryloyl-3,4-dihydroxyphenylalanine and/or N-acrylol-3,4-dihydroxyphenylalanine. The adhesive composition ensures an adhesion of substrates under moist conditions, in particular a biocompatible and waterproof adhesion to human skin.

Abstract: A functional aspartate prepared by A) reacting an aziridine with a Michael-acceptor molecule to form an aziridinyl aspartate, and B) reacting the aziridinyl aspartate with an active hydrogen containing compound to form the functional aspartate. The functional aspartate can be used in adhesive, sealant or coating compositions that also include an isocyanate functional material. The composition can be used in a method of bonding a first substrate to a second substrate that includes applying a coating of the above-identified adhesive composition to at least one surface of the first substrate or the second substrate, and contacting a surface of the first substrate with a surface of the second substrate, where at least on of the contacting surfaces has the coating applied thereto. The composition can also be used to coat substrates.