Solid Polymer Derived From Reactant Containing Ethylenic Unsaturation Patents (Class 525/421)
  • Patent number: 6271306
    Abstract: The present invention provides water-borne adhesives and adhesive emulsions comprising: (1) 25 to 55 weight percent of a grafted polyolefin comprising the reaction product of (i) a polyolefin, (ii) an ethylenically unsaturated monomer having functionality capable of reacting with an amino group and (iii) an amino carboxylic acid; (2) a minor amount up to 10 weight percent of a surfactant; and (3) 55 to 80 weight percent water.
    Type: Grant
    Filed: December 16, 1999
    Date of Patent: August 7, 2001
    Assignee: Shell Oil Company
    Inventors: Manuel Soler Rodriguez, Charles C. Hwo
  • Patent number: 6228971
    Abstract: Novel imine functional copolymers are provided containing a plurality of groups of the structure: where R1 is hydrogen or methyl; R2 is hydrogen or an alkyl group having from about 1 to about 10 carbon atoms; R3 is an alkyl or aryl group having from about 1 to about 10 carbon atoms, or R3 is bonded to R2 and forms part of a five- or six-membered ring; and Y is a divalent linking group having from about 3 to about 15 carbon atoms. The composition is useful in film-forming compositions curable at ambient temperature and above.
    Type: Grant
    Filed: June 21, 1999
    Date of Patent: May 8, 2001
    Assignee: PPG Industries Ohio, Inc.
    Inventors: Jonathan T. Martz, Joseph M. Carney, Robert E. Jennings
  • Patent number: 6187830
    Abstract: The present invention relates to a process for the preparation of a foamed article having a foam density of less than 180 kg/m3 and an average cell diameter of less than 1.5 mm comprising the extrusion of a molten semi-crystalline thermoplastic resin composition in the presence of a foaming agent, with the semi-crystalline thermoplastic resin composition comprising a polymeric epoxide containing at least two epoxide groups being a copolymer of a monomer mixture comprising at least one C10 to C18-olefin and at least one ethylenically unsaturated compound comprising an epoxide group. The process results in the preparation of foamed articles having a regular and homogeneous structure. Another advantage of the present invention is that it is not necessary anymore to add a compound of Group Ia, IIa, or IIIa of the Periodic Table, such as LiCl, to the extrusion process.
    Type: Grant
    Filed: January 11, 2000
    Date of Patent: February 13, 2001
    Assignee: Akzo Nobel NV
    Inventors: Geert Boven, Gerard Henk Beijers, Jernej Jelenic
  • Patent number: 6187874
    Abstract: The invention provides an adhesive for electronic parts, which satisfies both points of heat resistance and the ability to form an adhesive layer, and of low-temperature adhesive property, and an adhesive tape for electronic parts making use of such an adhesive. The adhesive comprises, as a resin component, two polyimide resins different in glass transition temperature by at least 20° C. from each other, and an epoxy resin.
    Type: Grant
    Filed: August 13, 1999
    Date of Patent: February 13, 2001
    Assignee: Tomoegawa Paper Co., Ltd.
    Inventors: Ken Yoshioka, Hitoshi Narushima, Osamu Oka
  • Patent number: 6153708
    Abstract: A highly polymerizable N-vinylcarboxylic acid amide having an N-1,3-butadienylcarboxylic acid amide content of 30 ppm or less, a process for producing the same, and a process for producing a homopolymer of N-vinylcarboxylic acid amide or a copolymer thereof with another copolymerizable monomer using the same. Also, a highly polymerizable N-vinyl-carboxylic acid amide is produced by thermal cracking or catalytic cracking of N-(1-alkoxyethyl)carboxylic acid amide or ethylidenebiscarboxylic acid amide, wherein the N-vinyl-carboxylic acid amide content of the N-(1-alkoxyethyl)-carboxylic acid amide or ethylenebiscarboxylic acid amide is 10 wt % or less.
    Type: Grant
    Filed: March 18, 1999
    Date of Patent: November 28, 2000
    Assignee: Showa Denko Kabushiki Kaisha
    Inventors: Toshiyuki Aizawa, Hitoshi Nakamura, Tetsuo Kudo, Kunitoshi Wakabayashi, Kenji Shimamura, Shun-ichi Nagamatsu
  • Patent number: 6150474
    Abstract: The invention relates to a polymer blend composition containing (A) a linear alternating polyketone polymer on the basis of carbon monoxide and at least one ethylenically unsaturated hydrocarbon compound, (B) at least one polyamide and/or block copolyester amide, (C) optionally customary auxiliaries and additives such as stabilizers, pigments, fillers, plasticizers and impact modifiers, the polyamide and/or the block copolyester amide (B) having a carboxyl/amino end-groups ratio of more than 1.
    Type: Grant
    Filed: December 22, 1998
    Date of Patent: November 21, 2000
    Assignee: EMS-Inventa AG
    Inventors: Georg Stoppelmann, Manfred Hewel
  • Patent number: 6143817
    Abstract: This invention relates to a stabilized aqueous emulsion polymerization composition comprising (a) from about 10% to about 80% by weight of a polymer derived from an emulsion polymerizable ethylenically unsaturated monomer; (b) from about 0.1% to about 10% by weight of a polyamino acid heteropolymer; (c) from about 0.01% to about 1% by weight of a free radical polymerization initiating agent; and (d) the remainder water. The polyamino acid heteropolymer in (b) may be selected from the group consisting of polyaspartic acid heteropolymers, polyglutamic acid heteropolymers, copolymers of polyaspartic acid heteropolymers with polyglutamic acid heteropolymers, and mixtures thereof. The present invention also pertains to a method for emulsifying and stabilizing an aqueous free radical emulsion polymerization reaction employing the polyamino acid heteropolymers.
    Type: Grant
    Filed: October 7, 1998
    Date of Patent: November 7, 2000
    Assignee: National Starch & Chemical Co.
    Inventors: Malcolm Hallam, Grant T. Shouldice, Jacob J. Guth
  • Patent number: 6143836
    Abstract: A highly polymerizable N-vinylcarboxylic acid amide having an N-1,3-butadienylcarboxylic acid amide content of 30 ppm or less, a process for producing the same, and a process for producing a homopolymer of N-vinylcarboxylic acid amide or a copolymer thereof with another copolymerizable monomer using the same. Also, a highly polymerizable N-vinylcarboxylic acid amide is produced by thermal cracking or catalytic cracking of N-(1-alkoxyethyl)carboxylic acid amide or ethylidenebiscarboxylic acid amide, wherein the N-vinylcarboxylic acid amide content of the N-(1-alkoxyethyl)carboxylic acid amide or ethylenebiscarboxylic acid amide is 10 wt % or less.
    Type: Grant
    Filed: October 8, 1998
    Date of Patent: November 7, 2000
    Assignee: Showa Denko Kabushiki Kaisha
    Inventors: Toshiyuki Aizawa, Hitoshi Nakamura, Tetsuo Kudo, Kunitoshi Wakabayashi, Kenji Shimamura, Shun-ichi Nagamatsu
  • Patent number: 6132852
    Abstract: A multilayer wiring substrate using a resin composition comprising polyquinoline compound and bismaleimide compound as essential ingredients between wiring-carrying resin layers as insulating layers forms no void at the time of lamination, has an excellent adhesive property at various interfaces, has a heat stability after lamination and is high in reliability, so that, it is applicable to many fields not only including the multilayer wiring substrates capable of mounting LSI or tip carrier directly but also including multilayer wiring substrate for work station, mounting substrates for small-sized electronic devices such as camera and video for people's use, and high frequency multitip module multilayer substrate.
    Type: Grant
    Filed: March 12, 1999
    Date of Patent: October 17, 2000
    Assignee: Hitachi, Ltd.
    Inventors: Masahiro Suzuki, Akio Takahashi, Minoru Tanaka, Haruhiko Matsuyama, Haruo Akahoshi
  • Patent number: 6113980
    Abstract: A method for improving the chargeability of a powder coating composition containing an organic film-forming binder, which method comprises incorporating into the powder coating composition at least two different compounds containing a residue of the formula (A) ##STR1## as electron donors.
    Type: Grant
    Filed: January 30, 1998
    Date of Patent: September 5, 2000
    Assignee: Ciba Specialty Chemicals Corporation
    Inventor: Hugh Stephen Laver
  • Patent number: 6096850
    Abstract: Polyimide is produced by reacting two kinds of diamine compounds consisting of diaminopolysiloxane and a hydroxyl group-containing diamine or three kinds of diamine compounds consisting of diaminopolysiloxane, a hydroxyl group-containing diamine and an aromatic or alicyclic diamine with a 4,4'-(hexafluoroisopropylidene)diphthalic acid dianhydride, thereby once forming a polyamic acid, and subjecting the polyamic acid to polyimidization reaction. The resulting polyimide itself is soluble in low boiling organic solvents for general purpose use, typically methyl ethyl ketone. A photosensitive composition comprising the polyimide, a photo crosslinking agent and a photo acid-generating agent forms a negative type polyimide pattern upon development with an aqueous alkali solution.
    Type: Grant
    Filed: February 26, 1999
    Date of Patent: August 1, 2000
    Assignee: Nippon Mektron Limited
    Inventors: Lin-chiu Chiang, Jenq-Tain Lin, Nobuyuki Sensui
  • Patent number: 6096480
    Abstract: A photosensitive polyimidosiloxane composition comprising a polyimidosiloxane comprising 15-80 mole percent of the units, ##STR1## wherein X represents CO, O or a direct bond and R.sub.3 represents an aromatic residue containing a photosensitive group with an unsaturated hydrocarbon group, and 85-20 mole percent of the units, ##STR2## wherein X is as defined above, each R.sub.4 independently represents a divalent hydrocarbon residue, each R.sub.5 independently represents an alkyl group of 1-3 carbon atoms and 1 represents an integer of 3-30, a finely divided inorganic filler, and an organic solvent. The composition provides films having excellent light transmittance.
    Type: Grant
    Filed: December 5, 1997
    Date of Patent: August 1, 2000
    Assignee: Ube Industries, Ltd.
    Inventors: Seiji Ishikawa, Hiroshi Yasuno, Hiroyuki Sakurai
  • Patent number: 6077924
    Abstract: Polyimide is produced by reacting two kinds of diamine compounds consisting of diaminopolysiloxane and a hydroxyl group-containing diamine or three kinds of diamine compounds consisting of diaminopolysiloxane, a hydroxyl group-containing diamine and an aromatic or alicyclic diamine with a dicarboxylic acid anhydride having a 2,5-dioxotetrahydrofuryl group as one acid anhydride group, thereby once forming a polyamic acid, and subjecting the polyamic acid to polyimidization reaction. The resulting polyimide itself is soluble in low boiling organic solvents for general purpose use, typically methyl ethyl ketone. A photosensitive composition comprising the polyimide, a photo crosslinking agent and a photo acid-generating agent forms a negative type polyimide pattern upon development with an aqueous alkali solution.
    Type: Grant
    Filed: February 26, 1999
    Date of Patent: June 20, 2000
    Assignee: Nipopon Mektron Limited
    Inventors: Lin-chiu Chiang, Jenq-Tain Lin, Nobuyuki Sensui
  • Patent number: 6072024
    Abstract: A process is disclosed for producing with good productivity a cross-linked polyaspartic acid resin having biodegradability and high water absorbency. The process features inclusion of one of the following steps: (a) a polysuccinimide, which has been brought into a dispersed state by a dispersant, and a cross-linking agent are reacted to produce the cross-linked polyaspartic acid resin; (b) imide rings of a cross-linked polysuccinimide are subjected to a hydrolysis reaction while controlling a swelling degree of a resulting gel, whereby the cross-linked polyaspartic acid resin is produced; and (c) a gel of a cross-linked polysuccinimide, which has been obtained by reacting a cross-linking agent to a solution of a polysuccinimide in an organic solvent, is disintegrated to subject imide rings of the cross-linked polysuccinimide to a hydrolysis reaction, so that the cross-linked polyaspartic acid resin is produced.
    Type: Grant
    Filed: March 17, 1998
    Date of Patent: June 6, 2000
    Assignee: Mitsui Chemicals, Inc.
    Inventors: Yoshihiro Irizato, Makoto Sukegawa, Toshio Katoh, Hiroaki Tamatani, Akinori Nagatomo, Masaru Wada
  • Patent number: 6025439
    Abstract: Molecular dispersions of rigid-rod polybenzobisazole polymer/copolymer in thermoplastic matrices in a weight ratio of about 1:99 to 50:50 are prepared by dissolving the rigid-rod polymer in an alcoholic or aprotic solvent, dissolving the thermoplastic polymer in an alcoholic or aprotic solvent, combining the two solutions and recovering the resulting molecular composite from the combined solution. These molecular dispersions consist essentially of rigid-rod polybenzobisazole polymer/copolymer having sulfonic acid groups pendant to the polymer/copolymer backbone and thermoplastic polymers selected from the group consisting of polyvinylpyridines, poly(arylene ether ketone)s with a pyridyl functionality, aromatic poly(pyridine ether)s and poly(pyridine ether sulfone) copolymers, and polyimides with a pyridyl functionality.
    Type: Grant
    Filed: July 30, 1998
    Date of Patent: February 15, 2000
    Assignee: The United States of America as represented by the Secretary of the Air Force
    Inventors: Fred E. Arnold, Narayanan Venkatasubramanian, Thuy D. Dang, Derrick R. Dean
  • Patent number: 5998550
    Abstract: Molecular dispersions of rigid-rod polybenzobisazole polymer/copolymer in thermosetting matrices in a weight ratio of about 1:99 to 50:50 are prepared by dissolving the rigid-rod polymer in an alcoholic or aprotic solvent, dissolving the thermosetting polymer in an alcoholic or aprotic solvent, combining the two solutions and recovering the resulting molecular composite from the combined solution. These molecular dispersions consist essentially of rigid-rod polybenzobisazole polymer/copolymer having sulfonic acid groups pendant to the polymer/copolymer backbone and thermosetting polymers selected from the group consisting of iminobis(N-propyl-2-phenylethynyl-phthalimide), N-ethyl-(2,6-di-benzocyclobutenoxy)benzylamine, iminobis(N-propylnadic imide) and difunctional benzoxazine monomers of the formula ##STR1## wherein X is a single bond, --CO-- or --C(CH.sub.3).sub.2 -- and Q is --CH.sub.3 or --C.sub.6 H.sub.5.
    Type: Grant
    Filed: July 30, 1998
    Date of Patent: December 7, 1999
    Assignee: The United States of America as represented by the Secretary of the Air Force
    Inventors: Fred E. Arnold, Narayanan Venkatasubramanian, Thuy D. Dang, Derrick R. Dean
  • Patent number: 5998551
    Abstract: A crosslinked nylon block copolymer comprising a copolymer containing a polyamide block and an elastomeric block, irradiation crosslinked, including a compound which promotes crosslinking therein. In process form, the present invention comprises supplying a nylon block copolymer, containing a polyamide block and an elastomeric block, along with crosslinking promotor and exposing the block copolymer to irradiation, sufficient to crosslink the copolymer and improve mechanical properties therein. The crosslinked nylon block copolymers here have particular utility in both the medical and wire and cable industries.
    Type: Grant
    Filed: June 2, 1997
    Date of Patent: December 7, 1999
    Assignee: Lawrence A. Acquarulo
    Inventors: Charles J. O'Neil, Lawrence A. Acquarulo, Jr.
  • Patent number: 5986016
    Abstract: A thermoplastic resin composition containing a polyetherimide resin; a siloxane-polyetherimide copolymer; one or more resins selected from the group consisting of polycarbonate resins and copolyester-carbonate resins; and one or more component selected from glycidyl ester impact modifiers and siloxane-polycarbonate copolymers exhibits improved ductility and low temperature impact properties.
    Type: Grant
    Filed: December 23, 1997
    Date of Patent: November 16, 1999
    Assignee: General Electric Co.
    Inventors: Robert Puyenbroek, James Fishburn
  • Patent number: 5902897
    Abstract: The present invention relates to polyamines which are prepared by reactinga) unsaturated oligoesters having an average of 2 to 4 double bonds per molecule andb) optionally other unsaturated compounds suitable as Michael addition acceptors and having an average of 1 to 4 double bonds per molecule withc) (cyclo)aliphatic diamines having two primary amino groups andd) optionally other amino-functional compounds suitable as Michael addition donors.The present invention also relates to the use of these polyamines as a binder component in lacquers and coating compositions, particularly as reactants for blocked polyisocyanates in one-component stoving lacquers.
    Type: Grant
    Filed: July 19, 1996
    Date of Patent: May 11, 1999
    Assignee: Bayer Aktiengesellschaft
    Inventors: Christian Wamprecht, Theodor Engbert, Holger Casselmann, Josef Pedain, Jurgen Meixner
  • Patent number: 5866627
    Abstract: New photosensitive polyamic acid precursors are disclosed which have the formula: ##STR1## where Z is a tetravalent organic radical which contains at least one aromatic ring, Z' is a divalent organic radical which contains at least one aromatic ring, and R* is a photo polymerizable group. Particularly preferred compounds include BPDA-PDA and BPDA-ODA polyamic acid precursors. The precursor compositions within the practice of this invention are i-line, g-line, and i-/g-line active and show good photoresolution. The films formed exhibit excellent self-adhesion and adhesion to glass ceramic and silicon wafer substrates have low internal stress, a very low degree of solvent swelling, high thermal stability, and excellent mechanical properties such as high modulus/tensile strength and high elongation at break.
    Type: Grant
    Filed: June 30, 1997
    Date of Patent: February 2, 1999
    Assignee: International Business Machines Corporation
    Inventors: George Czornyj, Moonhor Ree, Willi Volksen, Dominic Changwon Yang
  • Patent number: 5840802
    Abstract: Low temperature ductile and impact resistant compositions are provided which comprise a polycarbonate resin and a dual graft multi-stage polyorganosiloxane/polyvinyl-based graft polymer composition. Also provided are thermally stabilized multi-stage polyorganosiloxane/polyvinyl-based graft polymers which have improved color-imparting and impact resistance-imparting properties and thermoplastic compositions containing the same.
    Type: Grant
    Filed: October 11, 1991
    Date of Patent: November 24, 1998
    Assignee: General Electric Company
    Inventors: James Louis DeRudder, I-Chung Wayne Wang
  • Patent number: 5834575
    Abstract: As a heteroaromatic compound made functional so as to be used in nonlinear optical materials, the present invention provides a heteroaromatic compound represented by the following Formula (1), (2), (3) or (4), a polymer obtained from any of these, a nonlinear optical element comprised of the polymer, an optical device having such an element, and a process for producing them. ##STR1## wherein Ar.sup.1, Ar.sup.2 and Ar.sup.3 each independently represent an aromatic group or an aromatic group having a substituent, R.sup.1, R.sup.2 and R.sup.3 each independently represent a hydrogen atom or a monovalent organic group, X represents a monovalent organic group, Y represents a hydrogen atom or a monovalent functional group, and n represents an integer of 2 to 10.
    Type: Grant
    Filed: November 13, 1996
    Date of Patent: November 10, 1998
    Assignee: Hitachi Chemical Company, Ltd.
    Inventors: Yutaka Honda, Iwao Fukuchi, Masato Taya, Kwan-Yue Alex Jen
  • Patent number: 5804649
    Abstract: The present invention discloses a water-soluble self-acid-doped polyaniline, and its sodium salt, which can be cast into free-standing films from their aqueous solutions. A process for preparing a water-soluble self-acid-doped polyaniline is also disclosed, which comprises reacting a polyaniline with a strong base to convert the amino nitrogen thereof to anionic nitrogen; reacting sultone with the anionic nitrogen to form a side chain alkanesulfonic acid group; doping with protonic acid to form precipitate; dissolving (undoping) the precipitate in an alkaline aqueous solution; removing excess alkali from the alkaline aqueous solution; and contacting the resulting aqueous solution with a H.sup.+ -type ion exchange resin. Moreover, an aqueous solution of the present water-soluble self-acid-doped PAn can be easily mixed with an additional water soluble polymer or polymer emulsion, which can then be cased into a polymer blend film having improved mechanical properties and coupling strength to a substrate.
    Type: Grant
    Filed: July 21, 1997
    Date of Patent: September 8, 1998
    Assignee: National Science Council
    Inventors: Show-An Chen, Gue-Wuu Hwang
  • Patent number: 5760168
    Abstract: Controlled molecular weight phenylethynyl terminated imide oligomers (PETIs) have been prepared by the cyclodehydration of precursor phenylethynyl terminated amic acid oligomers. Amino terminated amic acid oligomers are prepared from the reaction of dianhydride(s) with an excess of diamine(s) and subsequently endcapped with phenylethynyl phthalic anhydride(s) (PEPA). The polymerizations are carried out in polar aprotic solvents such as N-methyl-2-pyrrolidinone or N,N-dimethylacetamide under nitrogen at room temperature. The amic acid oligomers are subsequently cyclodehydrated either thermally or chemically to the corresponding imide oligomers. Direct preparation of PETIs from the reaction of dianhydride(s) with an excess of diamine(s) and endcapped with phenylethynyl phthalic anhydride(s) has been performed in m-cresol. Phenylethynyl phthalic anhydrides are synthesized by the palladium catalyzed reaction of phenylacetylene with bromo substituted phthalic anhydrides in triethylamine.
    Type: Grant
    Filed: October 21, 1996
    Date of Patent: June 2, 1998
    Assignee: The United States of America as represented by the Administrator of the National Aeuonautics and Space Administration
    Inventors: Paul M. Hergenrother, Joesph G. Smith, Jr.
  • Patent number: 5726251
    Abstract: A method is described wherein a compound containing amine functionality is reacted in its liquid form with carbon dioxide to convert the compound into a solid amine carbamate salt for use as a blocked amine curative in powder coating manufacturing and resulting powder coating operations. The blocked amine curative decomposes on heating and reverts back to a liquid amine providing a highly reactive curative and flow modifier for powder coating applications.
    Type: Grant
    Filed: October 11, 1996
    Date of Patent: March 10, 1998
    Assignee: Air Products and Chemicals, Inc.
    Inventors: Steven Paul Wilkinson, Jeffrey Thomas DePinto
  • Patent number: 5719238
    Abstract: A method of improving the tribological properties of a polyketone polymer are presented in which polyketone polymer starting materials are blended with an aramide. Blends produced according to this process are also presented. The blend is particularly useful in the manufacture of articles used in applications where surfaces are in contact during motion.
    Type: Grant
    Filed: July 7, 1995
    Date of Patent: February 17, 1998
    Assignee: Shell Oil Company
    Inventors: John Edmond Flood, John Wilbur Kelley
  • Patent number: 5712363
    Abstract: The present invention relates to coating compositions including a particular class of oligomeric sterically hindered polyamines as replacements for traditional blocked and unblocked polyamine crosslinkers. The use of these oligomeric sterically hindered polyamine crosslinkers resultss in a desirable pot life/cure speed relationship not generally available with traditional unblocked polyamine crosslinkers, as well as a lower VOC and often better appearance characteristics than generally available with the traditional blocked varieties.
    Type: Grant
    Filed: August 28, 1995
    Date of Patent: January 27, 1998
    Assignee: Akzo Nobel NV
    Inventors: Arie Noomen, Thomas Mezger, Klaus Hobel, Keimpe Jan van den Berg
  • Patent number: 5705574
    Abstract: Polyimide oligomers include (1) linear, mono-functional crosslinking oligomers prepared by condensing a monoanhydride end cap with a diamine that includes alternating ether and "sulfone" (--SO.sub.2 --, --S--, --CO--, --(CF.sub.3).sub.2 C--, or --(CH.sub.3).sub.2 C--) linkages connecting alternating aromatic radicals and with a dianhydride (or dianhydride mixture), particularly the unsaturated, aliphatic dianhydride commonly known as MCTC; (2) linear, mono- or difunctional crosslinking oligomers prepared by condensing an amine end cap with a diamine and a dianhydride; and (3) multidimensional, crosslinking oligomers having an aromatic hub and at least three radiating arms connected to the hub, each arm including a crosslinking end cap at its distal end and at least one imide linkage.Blends, prepregs, and composites can be prepared from the oligomers.
    Type: Grant
    Filed: June 5, 1995
    Date of Patent: January 6, 1998
    Assignee: The Boeing Company
    Inventors: Hyman R. Lubowitz, Clyde H. Sheppard
  • Patent number: 5677384
    Abstract: Grafted polyamidoamines and grafted polyethyleneimines obtainable by free-radically initiated polymerization of(a) 1-vinylpyrrolidone, 1-vinyltriazole, 1-vinylimidazoles, mixtures of said monomers or mixtures of at least one of said monomers with up to 20% by weight of other monoethylenically unsaturated monomers in the presence of(b) water-soluble or -dispersible polyamidoamines, polyethyleneimines or mixtures thereof in a weight ratio of (a):(b) from 5:95 to 95:5, are useful as dye transfer inhibitors in surfactant-based detergents when included therein in an amount from 0.05 to 10% by weight.
    Type: Grant
    Filed: September 7, 1995
    Date of Patent: October 14, 1997
    Assignee: BASF Aktiengesellschaft
    Inventors: Juergen Detering, Christian Schade, Knut Oppenlaender, Michael Zirnstein, Guenter Scherr, Wolfgang Trieselt, Volker Schwendemann
  • Patent number: 5674947
    Abstract: There are herein disclosed a method for preparing a modified resin which comprises thermal/reaction by the use of a norbornenyl group-containing compound typified by norbornenecarboguanamine or its derivative, a method for preparing an epoxy-modified resin which comprises the step of reacting the above-mentioned modified resin and an epoxide, a flame-retarding method, a thermal stabilization method, a compatibilizing method and a surface modification method which comprise utilizing the modified resin, as well as a coating resin composition and an adhesive resin composition containing the modified resin. According to the, preparation methods of the present invention, the deterioration of a material scarcely occurs, and a functional group which is excellent in flame retardancy, thermal stability, compatibility and the like can be introduced to the resins.
    Type: Grant
    Filed: August 14, 1995
    Date of Patent: October 7, 1997
    Assignee: Mitsui Toatsu Chemicals, Inc.
    Inventors: Tetsuya Oishi, Kazuo Sugazaki, Jin Suzuki
  • Patent number: 5654396
    Abstract: We achieve solvent resistance and extended use life for advanced polyimides by including at least some solvent-resistant linkages in the backbone in place of phenoxyphenyl sulfone linkages and using diPEPA or PEPA crosslinking end caps.
    Type: Grant
    Filed: June 5, 1995
    Date of Patent: August 5, 1997
    Assignee: The Boeing Company
    Inventors: Hyman R. Lubowitz, Clyde H. Sheppard
  • Patent number: 5648432
    Abstract: In the process of the present invention, a non-polar, aprotic solvent is removed from an oligomer/polymer solution by freeze-drying in order to produce IPNs and semi-IPNs. By thermally quenching the solution to a solid in a short length of time, the size of the minor constituent-rich regions is greatly reduced as they are excluded along with the major constituent from the regions of crystallizing solvent. The use of this process sequence of controlling phase morphology provides IPNs and semi-IPNs with improved fracture toughness, microcracking resistance, and other physical-mechanical properties as compared to IPNs and semi-IPNs formed when the solvent is evaporated rather than sublimed.
    Type: Grant
    Filed: June 7, 1995
    Date of Patent: July 15, 1997
    Assignee: The United States of America as represented by the Administrator of the National Aeronautics and Space Administration
    Inventors: Ruth H. Pater, Marion G. Hansen
  • Patent number: 5625011
    Abstract: The invention relates to molecular composites including a rigid reinforcing thermoplastic polymer dispersed on a molecular scale in a flexible organosiloxane/thermoplastic polymer copolymer, to a process for the preparation of the said composites and to a material with a surface enriched in siloxane, obtained from the said molecular siloxane composites, and to the uses of said composites and of the said material, in particular for aerospace construction.
    Type: Grant
    Filed: June 29, 1994
    Date of Patent: April 29, 1997
    Assignee: Agence Spatiale Europeenne
    Inventor: Sanjay Palsule
  • Patent number: 5608013
    Abstract: A polyimide obtained by reacting an acid dianhydride such as catechol bistrimellitate dianhydride, bisphenol A bistrimellitate dianhydride, etc. with a diamine such as 4,4'-diamino-3,3',5,5'-tetraisopropyl-diphenylmethane, etc. has high solubility in organic solvents and good moldability at low temperatures, and can provide a thermosetting resin composition together with a polymaleimide.
    Type: Grant
    Filed: March 7, 1995
    Date of Patent: March 4, 1997
    Assignee: Hitachi Chemical Company, Ltd.
    Inventors: Hidekazu Matsuura, Yasuo Miyadera
  • Patent number: 5560973
    Abstract: A process for preparing melt spun polymeric fiber made from polymerized amide monomers includes the steps of pigmenting the polymer, incorporating within the polymer sufficient SO.sub.3 H groups or salts thereof to give the polymer a sulphur content of between about 10 and about 160 equivalents per 10.sup.6 grams polymer and thereafter chemically blocking with a chemical blocking agent a portion of amino end groups present in the sulphonated polymer.
    Type: Grant
    Filed: May 22, 1995
    Date of Patent: October 1, 1996
    Assignee: BASF Corporation
    Inventors: Matthew B. Hoyt, Andrew M. Coons, III, David N. Dickson
  • Patent number: 5548037
    Abstract: A process for preparing melt spun polymeric fiber made from polymerized amide monomers includes the steps of pigmenting the polymer, incorporating within the polymer sufficient SO.sub.3 H groups or salts thereof to give the polymer a sulphur content of between about 10 and about 160 equivalents per 10.sup.6 grams polymer and thereafter chemically blocking with a chemical blocking agent a portion of amino end groups present in the sulphonated polymer.
    Type: Grant
    Filed: May 22, 1995
    Date of Patent: August 20, 1996
    Assignee: BASF Corporation
    Inventors: Matthew B. Hoyt, Andrew M. Coons, III, David N. Dickson
  • Patent number: 5543490
    Abstract: Polyaspartic acid is prepared by reacting maleic anhydride and ammonia to give maleamic acid, polymerizing the maleamic acid and subsequently hydrolyzing the product to give polyaspartic acid or a salt thereof.
    Type: Grant
    Filed: December 17, 1993
    Date of Patent: August 6, 1996
    Assignee: Bayer AG
    Inventors: Torsten Groth, Winfried Joentgen, Hans W. Linden, Nikolaus Muller, Heinz-Joachim Rother, Paul Wagner, Martin Kugler
  • Patent number: 5530089
    Abstract: Polysulfoneimide oligomers having crosslinking end cap moleties which provide improved solvent-resistance to cured composites are generally represented by backbones of the formula: ##STR1## wherein ##STR2## n=1 or 2; R and R' are divalent aromatic organic radicals having from 2-20 carbon atoms; ##STR3## E=allyl or methallyl; R=a trivalent C.sub.(6-13) aromatic organic radical;R.sub.1 =any of lower alkyl, lower alkoxy, aryl, or substituted aryl;R'=a divalent C.sub.(6-30) aromatic organic radical;j=0, 1, or 2; andG=--CH.sub.2 --, --O--, --S--, or --SO.sub.2 --The crosslinkable oligomers are made by reacting substituted phthalic anhydrides with hydroxyaryl amines and suitable crosslinking end cap reactants, or by self-condensation of phthalimide salts followed by capping the polymers.
    Type: Grant
    Filed: September 6, 1988
    Date of Patent: June 25, 1996
    Assignee: The Boeing Company
    Inventors: Clyde H. Sheppard, Hyman R. Lubowitz
  • Patent number: 5527863
    Abstract: Copolymers of polyaspartic acid which are suitable for the inhibition of scale deposition were obtained by reacting maleic acid, an additional polycarboxylic acid and ammonia in a stoichiometric excess, at 120.degree.-350.degree. C., preferably 180.degree.-300.degree. C., to provide copolymers of polysuccinimide. In a second embodiment, a polyamine was added to the reaction mix. These intermediate polysuccinimide copolymers could then be converted to the salts of copolymers of polyaspartic acid by hydrolysis with a hydroxide.Such copolymers are useful in preventing deposition of scale from water and find applications in treating water. Other applications include scale prevention additives for detergents. In addition, such copolymers inhibit dental tartar and plaque formation.
    Type: Grant
    Filed: January 27, 1995
    Date of Patent: June 18, 1996
    Assignee: Bayer AG
    Inventors: Louis L. Wood, Gary J. Calton
  • Patent number: 5525703
    Abstract: There is disclosed novel cross linked polyanhydroaspartic acid which is the product of the reaction of a polysuccinidmide with triaminononoane (TAN). Depending upon the amount a cross linking agent employed compositions of varying degrees of cross linking are produced. Mole ratio of polysuccinimide to TAN such as from 3 to 1 provides a water insoluble material while a mole ratio of 102 to 1 provides a water soluble material at 28% by weight. Such compounds find utility as thickeners, deflocculants, flocculants and water absorbers.
    Type: Grant
    Filed: December 27, 1994
    Date of Patent: June 11, 1996
    Assignee: Monsanto Company
    Inventor: Dennis J. Kalota
  • Patent number: 5523383
    Abstract: A process for the preparation of a photocurable resin which comprises the steps of(I) (a) imidating 20 to 80 mole % of the acid arthydride groups present in an adduct prepared by the addition reaction of an .alpha.,.beta.-unsaturated dicarboxylic acid arthydride to a conjugated diene polymer or copolymer with a primary amine to produce water and an amide,(b) reacting the thus formed water as a by-product with at least a part of the remaining acid arthydride groups in said adduct to produce the succinic acid groups by opening the ring of said acid arthydride groups,(II) dehydrating the thus produced succinic acid groups by heating to cause ring closure again thereby forming acid anhydride groups and(III) reacting at least a part, preferably at least 50 mole %, of the acid anhydride rings present in the polymer with an .alpha.,.beta.-unsaturated monocarboxylic acid ester having an alcoholic hydroxyl group to conduct a half-esterification by opening the ring of said acid arthydride groups.
    Type: Grant
    Filed: May 11, 1994
    Date of Patent: June 4, 1996
    Assignee: Nippon Petrochemicals Co., Ltd.
    Inventors: Nobuo Ikeda, Teruhisa Kuroki, Tatsuo Yamaguchi, Hiroyoshi Oomiya
  • Patent number: 5521257
    Abstract: Low-color polyaspartate homopolymers, copolymers or homopolymer/copolymer mixtures and the metal salts thereof, are produced by the oxidative, hydrolysis of polysuccinimide homopolymers, copolymers or homopolymer/copolymer mixtures, and metal salts thereof, in the presence of selected chlorine-free, non-chromogenic oxygen containing oxidizing agents. The preferred oxidizing agents are selected from the group consisting of hydrogen peroxide, sodium percarbonate, potassium percarbonate, sodium perborate tetrahydrate, sodium perborate monohydrate, sodium periodate, potassium periodate and peroxycarboxylic acids. The advantage of the claimed process is that low-color polyaspartates can be produced without the addition of further processing steps beyond the hydrolysis of the polysuccinimide presursor. Solid, low-color polyaspartates are obtained by evaporating to dryness the polyaspartate solutions obtained after oxidative hydrolysis.
    Type: Grant
    Filed: January 3, 1995
    Date of Patent: May 28, 1996
    Assignee: Donlar Corporation
    Inventor: Robert J. Ross
  • Patent number: 5510426
    Abstract: Higher molecular weight copolymers of polyaspartic acid which are suitable for the inhibition of scale deposition may be obtained by reacting maleic acid and ammonia in a stoichiometric excess, with a diamine or a triamine, at 120.degree.-350.degree. C., preferably 180.degree.-300.degree. C., and then converting the copolymer of polysuccinimide formed to a salt of a copolymer of polyaspartic acid by hydrolysis with a hydroxide.
    Type: Grant
    Filed: May 17, 1995
    Date of Patent: April 23, 1996
    Assignee: SRCHEM, Inc.
    Inventor: Louis L. Wood
  • Patent number: 5510427
    Abstract: Higher molecular weight copolymers of polyaspartic acid which are suitable for the inhibition of scale deposition may be obtained by reacting maleic acid and ammonia in a stoichiometric excess, with a diamine or a triamine, at 120.degree.-350.degree. C., preferably 180.degree.-300.degree. C., and then converting the copolymer of polysuccinimide formed to a salt of a copolymer of polyaspartic acid by hydrolysis with a hydroxide.
    Type: Grant
    Filed: May 17, 1995
    Date of Patent: April 23, 1996
    Assignee: SRCHEM, Inc.
    Inventor: Louis L. Wood
  • Patent number: 5504158
    Abstract: There is provided in accordance with the present invention polyphenylene ether/polyalkyleneterephthalamide compositions of high dimensional stabilities that are suitable for high temeprature applications comprising from about 20 to about 70 weight % of a functionalized polyphenylene ether; from about 20 to about 70 weight % of a polyalkyleneterephthalamide, wherein the polyalkyleneterephthalamide is derived from terephthalic acid and an .alpha.,.omega.-alkanediamine having 10 to 14 methylene groups; and from about 0 to about 20 weight % of a functionalized elastomeric polymer, wherein the blend absorbs less than 2 wt % of moisture and has a dimensional growth in water of less than 0.5%.
    Type: Grant
    Filed: January 10, 1995
    Date of Patent: April 2, 1996
    Assignee: AlliedSignal Inc.
    Inventors: Murali K. Akkapeddi, Jeffrey H. Glans
  • Patent number: 5502117
    Abstract: Higher molecular weight copolymers of polyaspartic acid which are suitable for the inhibition of scale deposition may be obtained by reacting maleic acid and ammonia in a stoichiometric excess, with a diamine or a triamine, at 120.degree.-350.degree. C., preferably 180.degree.-300.degree. C., and then converting the copolymer of polysuccinimide formed to a salt of a copolymer of polyaspartic acid by hydrolysis with a hydroxide.
    Type: Grant
    Filed: May 17, 1995
    Date of Patent: March 26, 1996
    Assignee: Srchem, Inc.
    Inventor: Louis L. Wood
  • Patent number: 5496914
    Abstract: Polymers of maleic, fumaric or malic acids or maleic, fumaric or malic acid and ammonia with amino acids are prepared by heating at 180.degree.-350.degree. C., preferably 200.degree.-300.degree. C. The polymer formed may be converted to a salt by hydrolysis with a metal hydroxide or ammonium hydroxide.
    Type: Grant
    Filed: January 18, 1995
    Date of Patent: March 5, 1996
    Assignee: SRCHEM, Inc.
    Inventors: Louis L. Wood, Gary J. Calton
  • Patent number: 5493002
    Abstract: Arylethynyl phthalic anhydrides have been synthesized and shown to have particular application as endcappers or pendant groups in high performance/high temperature thermosets which include amine terminal or amine pendant groups.
    Type: Grant
    Filed: July 6, 1994
    Date of Patent: February 20, 1996
    Assignees: Virginia Tech Intellectual Properties, Inc., Virginia Polytechnic Institute and State University
    Inventors: James E. McGrath, Gerald W. Meyer
  • Patent number: 5492979
    Abstract: A high temperature semi-interpenetrating polymer network (semi-IPN) was developed which had significantly improved processability, damage tolerance and mechanical performance, when compared to the commercial Thermid.RTM. materials. This simultaneous semi-IPN was prepared by mixing a thermosetting polyimide with a thermoplastic monomer precursor solution (NR-15082) and allowing them to react upon heating. This reaction occurs at a rate which decreases the flow and broadens the processing window. Upon heating at a higher temperature, there is an increase in flow. Because of the improved flow properties, broadened processing window and enhanced toughness, high strength polymer matrix composites, adhesives and molded articles can now be prepared from the acetylene endcapped polyimides which were previously inherently brittle and difficult to process.
    Type: Grant
    Filed: April 4, 1994
    Date of Patent: February 20, 1996
    Assignee: The United States of America as represented by the Administrator of the National Aeronautics and Space Administration
    Inventor: Ruth H. Pater
  • Patent number: H1601
    Abstract: A blend of polyketone and polycarbonate polymers is presented. The polymer blend is produced by blending polyketone polymer, polycarbonate polymer, and a reactive graft compatibilizer. The a reactive graft compatibilizer compatibilizes the blend.
    Type: Grant
    Filed: March 2, 1995
    Date of Patent: October 1, 1996
    Assignee: Shell Oil Company
    Inventors: Joseph M. Machado, Randall P. Gingrich