Solid Polymer Derived From Or System Contains A Reactant Which Is A Fatty Acid Glycerol Ester, A Fatty Acid Or Salt Derived From A Naturally Occurring Glyceride, Tall Oil, Or Fattly Acid Derived From Tall Oil Patents (Class 525/444.5)
  • Patent number: 9150724
    Abstract: Polymer composition containing a thermoplastic polyester elastomer, which contains hard segments of a polyester and soft segments, that contain monomer units of a dimerized fatty acid and/or a derivative thereof, which polymer composition contains at least 0.1 wt % of a UV-absorber.
    Type: Grant
    Filed: September 19, 2012
    Date of Patent: October 6, 2015
    Assignee: DSM IP ASSETS B.V.
    Inventors: Paul Willem Jan Van Den Heuvel, Pieter Gijsman
  • Patent number: 8999503
    Abstract: A thermally removable pressure-sensitive adhesive sheet includes a substrate and a pressure-sensitive adhesive layer that is provided on at least one side of the substrate and made from a polyester-based pressure-sensitive adhesive composition containing a polyester including at least a lactic acid unit, a dibasic acid unit, and a glycol unit, a foaming agent, and a crosslinking agent. The dibasic acid unit includes a dimer acid, the polyester has a weight average molecular weight of 20,000 to 200,000 and a glass transition temperature of ?70 to ?20° C. as measured using a differential scanning calorimeter at a temperature rise rate of 20° C./minute, and the polyester has a hydroxyl value of 1 to 60 mgKOH/g.
    Type: Grant
    Filed: October 20, 2010
    Date of Patent: April 7, 2015
    Assignee: Nitto Denko Corporation
    Inventors: Hitoshi Takahira, Satomi Yoshie
  • Patent number: 8123978
    Abstract: The present invention provides a liquid crystalline polyester resin composition which imparts a good mold-releasability during molding and further is improved in heat resistance. Specifically, with 100 parts by weight of a liquid crystalline polyester resin is added 0.001 to 1 part by weight of a fatty acid ester which is a tetraester of pentaerythritol and a C10 to C32 higher fatty acid and has an acid value ranging from 0.01 to 0.5 and a hydroxyl value ranging from 0.01 to 5.
    Type: Grant
    Filed: October 28, 2008
    Date of Patent: February 28, 2012
    Assignee: Polyplastics Co., Ltd.
    Inventors: Kazufumi Watanabe, Hirokazu Ohshiba, Raita Nishikawa, Kenichi Yasusaka
  • Publication number: 20110135924
    Abstract: The present invention provides a polyester, a polyester composition and a pressure-sensitive adhesive composition capable of obtaining a pressure-sensitive adhesive which is global-environmentally friendly and is excellent in pressure-sensitive adhesion properties, using a plant-derived raw material; and a pressure-sensitive adhesive layer and a pressure-sensitive adhesive sheet which can be obtained by using the same. A polyester of the present invention is a polyester comprising at least a lactic acid unit, a dibasic acid unit and a glycol unit, wherein the dibasic acid unit contains dimer acid, and the polyester has a glass transition temperature as measured at a temperature rising rate of 20° C./minute using a differential scanning calorimeter, of ?70 to ?20° C., a weight average molecular weight of 20,000 to 300,000 and a hydroxyl value of 1 to 100 mgKOH/g.
    Type: Application
    Filed: August 5, 2009
    Publication date: June 9, 2011
    Applicants: NITTO DENKO CORPORATION, TOYO BOSEKI KABUSHIKI KAISHA
    Inventors: Hitoshi Takahira, Satomi Yoshie, Tadashi Nakajima, Daiki Funaoka, Katsuya Shimeno
  • Publication number: 20100041821
    Abstract: An alkyd resin comprising A) a polyol-polyacid alkyd; and B) a composition comprising a highly esterified polyol polyester, wherein the polyester comprises a polyol residue and a plurality of fatty acids esters, and wherein from about 5% to about 80% of the fatty acid esters contains exactly one pair of conjugated double bonds.
    Type: Application
    Filed: August 7, 2009
    Publication date: February 18, 2010
    Inventors: Delano R. Eslinger, Dennis A. Ryer, Neal Rogers, Roger S. Berger, Deborah J. Back
  • Patent number: 7192538
    Abstract: An antistatic composition containing various types of polymers such as a polyamide, an aliphatic polyester, an elastomer thereof and a polyurethane elastomer, and a metal salt in specific amounts, and preferably, an antistatic composition in which an additive component such as an organic compound which has an —{O(AO)n}— group (A represents an alkylene group having 2 to 4 carbon atoms, and n represents an integer of 1 to 7) and all molecular chain terminals of which are CH3 and/or CH2 groups is compounded as needed.
    Type: Grant
    Filed: March 1, 2001
    Date of Patent: March 20, 2007
    Assignees: Sanko Chemical Industry Co., Ltd., Riken Technos Corporation
    Inventors: Noriaki Fujihana, Yoshiharu Tatsukami, Masaki Enomoto, Ikuo Ohkoshi
  • Patent number: 6972316
    Abstract: The present invention relates to a series of esters that are water insoluble and hydrophobic. Surprisingly however we have found that by selecting the proper polyester having (a) a dipentaerythritol portion, in which several hydroxyl groups remain unreacted and consequently polar, (b) a polyhydroxystearic acid polyester portion and (c) a mono-fatty acid portion esters that will have an affinity for water are prepared. These esters allow for the incorporation of three times their weight in water into pigmented products, where they improve creaminess, emmoliency, skin feel, humectancy and long wear.
    Type: Grant
    Filed: August 2, 2004
    Date of Patent: December 6, 2005
    Assignee: Phoenix Research Corp
    Inventors: John Imperante, Anthony J. O'Lenick, Jr.
  • Patent number: 6887947
    Abstract: This invention relates to processes for the production of purified, partially esterified polyol fatty acid polyesters and the compositions derived from those processes. The purified, partially esterified polyol fatty acid polyesters of the present invention are particularly well suited for use in a variety of food, beverage, pharmaceutical, and cosmetic applications and comprise less than about 5% polyol; less than about 5 ppm of residual solvent; less than about 700 ppm of lower alky esters; less than about 5% of a soap and free fatty acid mixture; less than about 3% of ash; and have an acid value of less than about 6.
    Type: Grant
    Filed: May 28, 2002
    Date of Patent: May 3, 2005
    Assignee: The Procter & Gamble Company
    Inventors: Jared John Schaefer, James Earl Trout
  • Patent number: 6727344
    Abstract: Monofunctional polyfluorooxetane oligomers and polymers are prepared by the cationic polymerization of fluorooxetane monomers with a monoalcohol. The fluorooxetane oligomers or polymers can be copolymerized with generally cyclic ethers. Alternatively, the polyfluorooxetane oligomer or polymer having a single hydroxyl end group can be functionalized with a variety of compounds so as to yield a functional end group such as an acrylate, a methacrylate, an allylic, an amine, etc., with the functionalized oligomer or polymer being suitable for use in radiation curable or thermal curable coating compositions. These functionalized polymers can be copolymerized and cured to provide improvements in wetting and surface properties that have previously been provided by migratory chemicals such as waxes and oils.
    Type: Grant
    Filed: March 28, 2002
    Date of Patent: April 27, 2004
    Assignee: Omnova Solutions Inc.
    Inventors: Raymond J. Weinert, Guillermina C. Garcia, Aslam Malik, Roland Carlson, Robert E. Medsker
  • Patent number: 6693150
    Abstract: Disclosed are a fatty acid esters composition of a polyglycerine containing more than 70% of a fatty acid monoester which is defined by a specified analysis method, a process for the preparation thereof, a process for the preparation of a highly-purified fatty acid esters composition of a polyglycerine, and a highly-purified fatty acid esters composition of a polyglycerine having an oxirane oxygen concentration of below 100 ppm which is defined by a specified analysis method. The fatty acid esters compositions of a polyglycerine are useful as additives for a variety of food-stuffs, additives for a variety of thermoplastic resins, and as additives for a variety of cosmetics or detergents.
    Type: Grant
    Filed: August 9, 2001
    Date of Patent: February 17, 2004
    Assignee: Daicel Chemical Industries Ltd.
    Inventors: Toshio Endo, Terumasa Daito
  • Patent number: 6686051
    Abstract: A polyester polymer includes at least one hydroxyl terminated polyoxetane block containing repeat units derived from polymerizing at least one oxetane monomer having a pendant —CH2—O—(CH2)n—Rf group wherein said Rf group is partially or fully fluorinated. A preferred process for forming said polymer is by reacting a hydroxyl terminated polyoxetane with a polycarboxylic acid under appropriate conditions to form an ester linkage and then adding and reacting that product with polyester forming reactants. The polyester polymer containing at least one polyoxetane block therein when reacted with an amino resin curative can be used as a coating on a substrate wherein the coating has dry erase properties. The coated substrate can be used as prepared or applied to yet other substrates.
    Type: Grant
    Filed: October 27, 2000
    Date of Patent: February 3, 2004
    Assignee: OMNOVA Solutions Inc.
    Inventors: Raymond J. Weinert, Robert E. Medsker, Daniel D. Woodland, Edward N. Kresge, Daniel C. Gottschalk, Joe A. Wright
  • Patent number: 6683132
    Abstract: Self-crosslinking aqueous coating compositions are disclosed comprising a water-dispersible alkyd having both sulfonate and acetoacetate functionality, a suitable bi- or poly-functional primary amine, and a monofunctional primary or cycloaliphatic secondary amine. The crosslinking of the composition includes oxidative curing via the fatty acid segments of the alkyd, and crosslinking via reaction between the acetoacetate groups of the alkyd and the primary amine groups of the polyfunctional amine. The aqueous alkyd systems disclosed do not require the presence of amines for the purpose of dispersing the alkyds, while exhibiting superior tack-free and through-dry times when used in coating compositions. Performance levels are achieved that heretofore had required increases in molecular weight and Tg, with a concomitant increase in VOC levels. Also disclosed are methods of making the inventive compositions.
    Type: Grant
    Filed: December 19, 2002
    Date of Patent: January 27, 2004
    Assignee: Eastman Chemical Company
    Inventors: Martin Frederick Schick, Amy Lee Bolton, Thauming Kuo
  • Patent number: 6670429
    Abstract: A block copolyester comprises a hard segment and a soft segment, wherein the melting point of the copolyester is greater than or equal to 200° C., and the glass transition temperature of the copolyester is less than or equal to −40° C. The hard segment is preferably polyethylene terephthalate, polybutylene terephthalate, or polyethylene naphthalate. The soft segment is preferably formed from at least one dimer fatty acid and/or dimer fatty diol and/or equivalent thereof. The copolyester is especially suitable for use in automotive parts, particularly where thermal stability is required.
    Type: Grant
    Filed: December 31, 2002
    Date of Patent: December 30, 2003
    Assignee: Imperial Chemical Industries PLC
    Inventors: Eric Appelman, Jeffrey Thomas Carter
  • Patent number: 6656530
    Abstract: The refinish compositions contain an acetoacetate resin based on a monomeric polyol or a hydroxy-functional oligomer of such a polyol; a blocked polyamine (polyketimine and/or polyaldimine), pigment, and alkyd polymer. The alkyd is not reactive toward the acetoacetate resin or the blocked polyamine. The refinish compositions may be prepared from an intermix system that has a plurality of color bases and an unpigmented component. Each color base includes the alkyd resin and one or more pigments dispersed with the alkyd resin. The unpigmented component includes at least one of the acetoacetate-functional resin or the blocked polyamine. A drier for the alkyd resin may be included in one of the components or in a separate, additional component.
    Type: Grant
    Filed: February 1, 2002
    Date of Patent: December 2, 2003
    Assignee: BASF Corporation
    Inventors: Lawrence E. Thieben, John C. Goan
  • Publication number: 20030195304
    Abstract: Acetoacetate-functional alkyd resins are disclosed, as are compositions including such resins in combination with at least one drier and an organic solvent. The acetoacetate-functional alkyd resin described is the reaction product of an alkyd resin with an alkyl acetoacetate. Also disclosed are methods of preparing such compositions, and uses for such compositions.
    Type: Application
    Filed: April 12, 2002
    Publication date: October 16, 2003
    Inventors: Thauming Kuo, Paul Vincent Grosso, Gary Eugene Spilman, Mark Dwight Clark
  • Publication number: 20030195305
    Abstract: A waterborne acetoacetate-functionalized alkyd coating composition is disclosed which includes an acetoacetate-functionalized alkyd resin, at least one drier, and water. The acetoacetate-functionalized alkyd resin is the reaction product of (i) an alkyd resin, and (ii) an alkyl acetoacetate. Also disclosed is a method of preparing a waterborne acetoacetate-functionalized alkyd coating composition which includes the step of contacting an acetoacetate-functionalized alkyd resin with at least one drier in the presence of water.
    Type: Application
    Filed: April 12, 2002
    Publication date: October 16, 2003
    Inventors: Thauming Kuo, Paul Vincent Grosso, Gary Eugene Spilman, Mark Dwight Clark
  • Publication number: 20030149192
    Abstract: The refinish compositions contain an acetoacetate resin based on a monomeric polyol or a hydroxy-functional oligomer of such a polyol; a blocked polyamine (polyketimine and/or polyaldimine), pigment, and alkyd polymer. The alkyd is not reactive toward the acetoacetate resin or the blocked polyamine. The refinish compositions may be prepared from an intermix system that has a plurality of color bases and an unpigmented component.. Each color base includes the alkyd resin and one or more pigments dispersed with the alkyd resin. The unpigmented component includes at least one of the acetoacetate-functional resin or the blocked polyamine. A drier for the alkyd resin may be included in one of the components or in a separate, additional component.
    Type: Application
    Filed: February 1, 2002
    Publication date: August 7, 2003
    Applicant: BASF CORPORATION
    Inventors: Lawrence E. Thieben, John C. Goan
  • Patent number: 6423418
    Abstract: A substrate having an adherent and stain resistant layer having durability and flexibility, said layer comprising the reaction product of a reactive polyester having free carboxylic acid and/or hydroxyl groups, a hydroxyl terminated polymer including repeat units from an oxetane having pendant —CH2—O—(CH2)n—Rf groups (said Rf groups generally being a fluorinated alkyl group) and an amino resin curative. The substrate may be printed or embossed or both. The coated substrate has both stain resistant properties and dry erase properties with dry erase markers. The coated substrate can be used as prepared or applied to other substrates.
    Type: Grant
    Filed: February 4, 1999
    Date of Patent: July 23, 2002
    Assignee: Omnova Solutions Inc.
    Inventors: Marten S. Callicott, David L. Hyde, Charles M. Kausch, Anthony Verrocchi, Joe A. Wright, Raymond J. Weinert, Robert E. Medsker, Daniel D. Woodland, Daniel C. Gottschalk
  • Patent number: 6383651
    Abstract: A polyester polymer including at least one polyoxetane block of repeating units derived from polymerizing at least one oxetane monomer having at least one pendant —CH2—O—(CH2)n— Rf group wherein said Rf group is partially or fully fluorinated is described. A preferred process for forming said polymer by reacting the hydroxyl terminated polymer with a polycarboxylic acid under appropriate conditions to form an ester linkage and then adding and reacting that product with polyester forming reactants.
    Type: Grant
    Filed: August 27, 1999
    Date of Patent: May 7, 2002
    Assignee: Omnova Solutions Inc.
    Inventors: Raymond J. Weinert, Edward N. Kresge, Robert E. Medsker, Daniel D. Woodland
  • Patent number: 6291597
    Abstract: A composition comprising a polylactide polymer with improved extensional viscosity and methods of making the same are disclosed. The polylactide polymer composition is prepared by providing in the composition polylactide polymer molecules which have been modified, relative to linear non-substituted polylactide, to provide increased molecular interaction among polylactide backbone chains in the composition. The preferred polylactide polymer composition has a number average molecular weight of at least about 10,000 (preferably at least 50,000) and a polydispersity of at least about 2.5. In addition, the polylactide polymer composition should have a neck-in ratio of less than about 0.8.
    Type: Grant
    Filed: September 20, 1999
    Date of Patent: September 18, 2001
    Assignee: Cargill, Incorporated
    Inventors: Patrick Richard Gruber, Jeffrey John Kolstad, David Roy Witzke, Mark Henry Hartmann, Andrea Lee Brosch
  • Patent number: 6287552
    Abstract: The present invention relates to cosmetic or dermatological compositions capable of being applied to the skin, the keratinous fibers, the nails, the semimucous membranes and/or the mucous membranes, and which includes a dendritic polyester polymer having terminal hydroxyl functional groups or the combination of such a polymer with a film-forming polymer. It also relates to methods of cosmetic or dermatological treatment using these compositions as well as the use of the compositions for the preparation of dermatological or cosmetic compositions.
    Type: Grant
    Filed: September 17, 1999
    Date of Patent: September 11, 2001
    Assignee: L'Oreal
    Inventors: Florence Tournilhac, Pascal Simon
  • Patent number: 6284233
    Abstract: The present invention relates to an antiwrinkle composition that includes, in a physiologically acceptable medium: a dispersion of a film-forming polymeric system containing at least one polymer capable of forming a film permeable to water vapor, having a Young's modulus ranging from 108 to 1010 N/m2 and producing, after application at a concentration of 7% in water and then drying, a retraction of the isolated stratum corneum greater than 1% at a temperature of 30° C. and a relative humidity of 40%, and a dendritic polyester polymer having terminal hydroxyl functional groups.
    Type: Grant
    Filed: September 17, 1999
    Date of Patent: September 4, 2001
    Assignee: L'Oreal
    Inventors: Pascal Simon, Veronique Chevalier