Mixed With Polycarboxylic Acid Or Derivative And Polyhydroxy Reactant Or Polymer Thereof Patents (Class 525/444)
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Patent number: 11643548Abstract: A polymer blend is provided, comprising or consisting of: (A) a first polymer component, being a copolymer having a substantially random, partially blocky structure and selected from poly[(L-lactide)-co-(£-caprolactone)] and poly[(D-lactide)-co-(£-caprolactone)] and (B) a second polymer component different from the first polymer component (A) selected from poly(L-lactide), poly(D-lactide), poly[(L-lactide)-co-(£-caprolactone)] and poly[(D-lactide)-co-(£-caprolactone)], wherein the first and second polymer components (A) and (B) are selected such that the resulting polymer blend comprises a combination of constitution units derived from L-lactide and constitution units derived from D-lactide. The highly elastic material may be processed by electrospinning to produce elastic porous objects having a non-woven fibrous structure.Type: GrantFiled: September 26, 2018Date of Patent: May 9, 2023Assignee: HELMHOLTZ-ZENTRUM HEREON GMBHInventors: Andreas Lendlein, Axel Thomas Neffe, Paul Jakob Hommes-Schattmann, Quanchao Zhang
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Patent number: 11433647Abstract: [Problem] To provide a polyester resin-coated metal sheet which has excellent coating material adhesion capable of withstanding severe forming processing while retaining high decorative property and photoluminescence property and a container using the same. [Solution] The polyester resin-coated metal sheet of the present invention includes a metal sheet, and a non-oriented polyester resin formed of a plurality of layers provided on at least one surface of the metal sheet. A surface layer and an adjacent layer in contact with the surface layer, of the plurality of layers, have a difference therebetween in melting temperature of not less than 10° C., and a difference in tensile stress at an elongation of 250% under an environmental temperature of 70° C. of less than 3 MPa in tensile tests in a single-layer film state corresponding to each layer, and the surface layer contains fine particles.Type: GrantFiled: February 19, 2016Date of Patent: September 6, 2022Assignees: TOYO KOHAN CO., LTD., TOYO SEIKAN CO., LTD.Inventors: Kunihiro Yoshimura, Shinichi Taya, Tomoko Manita
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Patent number: 11427711Abstract: A composition for sealing defects in structural materials such as roads or paved surfaces, the composition preferably comprising one or more shape memory polymer (SMP) components capable of responding to increased temperature by decreasing in volume.Type: GrantFiled: April 27, 2020Date of Patent: August 30, 2022Assignee: Board of Supervisors of Louisiana State UniversityInventor: Guoqiang Li
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Patent number: 11149249Abstract: The present invention provides a base material for cell culture comprising a polyester resin comprising a dicarboxylic acid unit and a diol unit, wherein 1 to 80% by mol of the diol unit is a diol unit having a cyclic acetal structure.Type: GrantFiled: September 23, 2016Date of Patent: October 19, 2021Assignee: MITSUBISHI GAS CHEMICAL COMPANY, INC.Inventors: Haruna Ando, Shin Iida, Yasunori Yamaguchi
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Patent number: 11078327Abstract: A polyester copolymer has two types of ester bond-forming monomer residues as main structural units when the two types of ester bond-forming monomers are defined as “monomer A” and “monomer B”, respectively, the polyester copolymer satisfies (1) and (2): (1) an R value represented by equation: R value=[AB]/(2[A][B])×100 [A]: mole fraction of monomer A residues in the polyester copolymer [% by mol], [B]: mole fraction of monomer B residues in the polyester copolymer [% by mol], and [AB]: mole fraction of a structure in which the monomer A residues and the monomer B residues are adjacent to each other (A-B and B-A) in the polyester copolymer [% by mol], is 0.45 or more and 0.99 or less; and (2) a crystallization rate of at least one of the monomer A residues and the monomer B residues is less than 14%.Type: GrantFiled: August 1, 2018Date of Patent: August 3, 2021Assignee: Toray Industries, Inc.Inventors: Yoshinori Kakizawa, Koji Kadowaki, Kazuhiro Tanahashi, Hirokazu Sakaguchi, Kazuyuki Kidoba
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Patent number: 11001706Abstract: A polyester resin composition contains a polyester resin A containing 70 to 100 mass % of a polybutylene terephthalate resin and 0 to 30 mass % of a polyethylene terephthalate resin. The polyester resin composition further contains a metal organic acid salt B, which is either or both of an alkali metal organic acid salt and an alkaline earth metal organic acid salt, and a predetermined amount of a styrenic resin C. The polyester resin composition contains a predetermined amount of either or both of an alkali metal atom and an alkaline earth metal atom relative to 100 parts by mass of the polyester resin A. In the polyester resin composition, the amount of linear oligomers of polybutylene terephthalate or the amount of the linear oligomers of polybutylene terephthalate and linear oligomers of polyethylene terephthalate is less than or equal to 1000 mg/kg.Type: GrantFiled: January 26, 2018Date of Patent: May 11, 2021Assignee: TOYOBO CO., LTD.Inventors: Takuya Shimoharai, Satoru Horiguchi
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Patent number: 10968345Abstract: A polymer composition comprising at least two polyesters having improved mechanical properties including a good balance between ultimate tensile strength, elastic modulus and elongation on failure. In particular, the composition comprises from 1 to 99% by weight of at least one aromatic polyester (AP) comprising units from a diol component and units from an acid component, the units from the acid component comprising from 70 to 100 mol % of repeating units from at least one heterocyclic polyfunctional aromatic acid of renewable origin and from 99 to 1% by weight of at least a second aliphatic-aromatic polyester (AAPE). This composition is suitable for producing articles such as films, moulded objects, thermoformed objects or expanded articles. The heterocyclic aromatic acid is 2,5-furandicarboxylic acid and the aliphatic-aromatic polyester is biodegradable and is a copolyester comprising repeating units from aromatic acid of the phthalic acid type, aliphatic diacids, and aliphatic diols.Type: GrantFiled: December 22, 2011Date of Patent: April 6, 2021Assignee: NOVAMONT S.P.A.Inventors: Catia Bastioli, Luigi Capuzzi, Tiziana Milizia, Roberto Vallero
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Patent number: 10899881Abstract: The subject invention provides a means for modifying existing polyester polymers to optimize characteristics for solid state polymerization and for utilization in a wide array of specific applications. For instance, the modification technique of this invention may be used to adjust the melting point, crystallization temperature (either from the solid or on cooling from the melt), glass transition temperature, natural stretch ratio, barrier properties, melt strength, and/or solid state polymerization characteristic of the polyester. Application of the instant invention could result in a polymer with substantially different physical properties, potentially allowing its use in heretofore high cost, specialty applications. A further advantage of the invention is that recycled polymer may be modified to broaden its potential uses into more demanding higher performance applications.Type: GrantFiled: February 15, 2019Date of Patent: January 26, 2021Inventor: Kevin L. Rollick
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Patent number: 10724687Abstract: The subject matter described herein includes a safety device for a tank having a fluid material therein. The safety device includes a tank collar wherein the collar is threaded on an inner facing circumference and defines a groove on an outer facing circumference. The tank collar is engageably received by the tank by threadably engaging the threaded inner facing circumference with a correspondingly threaded outer facing surface of the tank. The safety device also includes a cap having a locking collar formed about an open end of the cap, wherein the collar defines apertures circumferentially spaced around an inner circumference thereof. The cap includes a locking ring configured for being translatably engaged with the locking collar. The cap includes at least one ball bearing that is received within one of the apertures. The at least one ball bearing is retractable and extendable within the aperture.Type: GrantFiled: August 30, 2018Date of Patent: July 28, 2020Inventors: Michael Wayne Wilkinson, Dennis Wayne Wilkinson, Joseph D. Goodman, Jr.
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Patent number: 10329393Abstract: Disclosed is a shrink film containing a copolyester having a minimum crystallization half-time of at least 8.6 minutes and a polyester plasticizer having a weight-average molecular weight of 900 to 12,000 g/mol. The polyester plasticizer includes (i) a polyol component comprising residues of a polyol having 2 to 8 carbon atoms, and (ii) a diacid component comprising residues of a dicarboxylic acid having 4 to 12 carbon atoms.Type: GrantFiled: December 12, 2012Date of Patent: June 25, 2019Assignee: Eastman Chemical CompanyInventors: Wayne Ken Shih, Kimberley Carmenia Carico, Nancy Ellen Kinkade
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Patent number: 10258747Abstract: A method for manufacturing a needle-equipped outer tube includes providing a needle; providing a joint member having a needle insertion hole into which the needle is insertable; providing an outer tube comprising a connection section at a first axial end portion of the outer tube; pressing the joint member, with the needle located in the needle insertion hole, toward the connection section, such that the joint member engages with the connection section of the outer tube; and thermally welding the needle and the joint member, as well as the joint member and the connection section, such that the needle is joined to the joint member, and the joint member is joined to the connection section of the outer tube.Type: GrantFiled: April 24, 2014Date of Patent: April 16, 2019Assignee: TERUMO KABUSHIKI KAISHAInventors: Kozo Matsumoto, Masaaki Kasai, Tsutomu Sugiki
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Patent number: 10167363Abstract: A polybutylene naphthalate polyester and process for preparing polybutylene naphthalate polyester, for improving barrier performance of polyesters used in making of monolayer or multilayer containers. The process comprising: a) mixing butane diol with polymerization catalysts, monoethylene glycol, color toner, and at least one crystallization suppressing agent; b) reacting said mixture with naphthalene dicarboxylic acid or ester thereof to obtain oligomerized product via esterification or ester interchange; c) polymerizing said oligomer using at least one polymerization catalyst to obtain amorphous polybutylene naphthalate polyester chips; d) crystallizing said polybutylene naphthalate polyester chips; and e) subjecting said polyester chips to solid state polymerization to upgrade the intrinsic viscosity (I.V.) up to more than 0.40 dl/gm.Type: GrantFiled: August 5, 2015Date of Patent: January 1, 2019Assignee: Ester Industries LimitedInventors: Sanjay Tammaji Kulkarni, Balasundaram Dillyraj, Chandrakant Omkar Vyas
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Patent number: 10040880Abstract: The present invention relates to an article consisting of or comprising a bidirectional shape-memory polymer (bSMP), the bSMP comprising: first phase-segregated domains (AD) having a first transition temperature (Tt,AD) corresponding to a crystallization transition or glass transition of the first domains (AD), second phase-segregated domains (SD) having a second transition temperature (Tt,AD) corresponding to a crystallization transition or glass transition of the second domains (SD), the second transition temperature (Tt,SD) being higher than the first transition temperature (Tt,AD), and covalent or physical bonds cross-linking the polymer chains of the bSMP, and in this way interconnecting the first and second domains (AD, SD), wherein the second phase-separated domains (SD) form a skeleton which is at least partially embedded in the first phase-segregated domains (AD), and wherein polymer chain segments of the bSMP forming the first domains (AD) are substantially orientated in a common direction, such thaType: GrantFiled: December 20, 2013Date of Patent: August 7, 2018Assignee: Helmholtz-Zentrum Geesthacht Zentrum fuer Material -und Kuestenforschung GmbHInventors: Marc Behl, Karl Kratz, Ulrich Noechel, Tilman Sauter, Joerg Zotzmann, Srinivasa Reddy Chaganti, Andreas Lendlein
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Patent number: 10007206Abstract: A magnetic carrier having a ferrite-type core material and a resin coat layer present on the surface of the ferrite-type core material, wherein the ferrite-type core material contains a magnetic ferrite-type core material particle and an amino group-bearing primer compound; the resin coat layer contains a coating resin A that is a polymer of monomer containing a (meth)acrylate ester having an alicyclic hydrocarbon group; the content of the amino group-bearing primer compound in the ferrite-type core material and the content of the resin coat layer in the magnetic carrier are within the prescribed range.Type: GrantFiled: February 7, 2017Date of Patent: June 26, 2018Assignee: CANON KABUSHIKI KAISHAInventors: Nobuyoshi Sugahara, Hironori Minagawa, Wakashi Iida, Atsushi Nakano
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Patent number: 9919470Abstract: The present invention is directed to a method of preparing an actuator capable of being repeatedly and reversibly shifted between two freestanding shapes (A, B) under stress-free conditions upon varying a temperature between a temperature Tlow and a temperature Tsep.Type: GrantFiled: June 17, 2014Date of Patent: March 20, 2018Assignee: HELMHOLTZ-ZENTRUM GEESTHACHT ZENTRUM FUER MATERIAL- UND KUESTENFORSCHUNG GMBHInventors: Marc Behl, Karl Kratz, Srinivasa Reddy Chaganti, Ulrich Noechel, Tilman Sauter, Andreas Lendlein
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Patent number: 9754721Abstract: Disclosed is a biaxially oriented film for electrical insulation having even better withstand voltage characteristics than before together with excellent film-forming properties. The biaxially oriented film for electrical insulation of the invention is a film that includes a substrate layer containing a crystalline thermoplastic resin as a main component. The substrate layer contains a phenolic stabilizer in an amount of 0.001 wt % or more and 3 wt % or less based on the weight of the substrate layer. The phenolic stabilizer is an alkylenebisamide-type hindered phenol.Type: GrantFiled: October 26, 2010Date of Patent: September 5, 2017Assignee: Teijin Dupont Films Japan LimitedInventor: Tetsuo Yoshida
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Patent number: 9637631Abstract: Described herein is a flooring product comprising a base layer, the base layer comprising: a filler and a polymeric binder, the polymeric binder comprising: an amorphous thermoplastic polyester and a semi-crystalline thermoplastic polyester, wherein the thermoplastic amorphous polyester has a Tg less than 30° C.Type: GrantFiled: January 28, 2016Date of Patent: May 2, 2017Assignee: AFI Licensing LLCInventors: Dong Tian, Gary A. Sigel, Fang Qiao, Rebecca L. Winey, Jeffrey S. Ross
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Patent number: 9207520Abstract: A filter device which may include first and second filter elements allowing air to pass therethrough, and first and second filter holding members holding the first and second filter elements such that they are linearly connected side by side. The holding members being connected to be foldable in the position where the filter elements are connected.Type: GrantFiled: February 17, 2011Date of Patent: December 8, 2015Assignee: SONY CORPORATIONInventors: Noriyuki Hagino, Yoshihisa Wada, Kazuhiro Takai
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Patent number: 9156940Abstract: An oxygen-scavenging composition is provided that includes an oxygen-scavenging polymer and a catalyst. The oxygen-scavenging polymer, which in preferred embodiments is suitable for use in packaging articles, includes a base polymer having a backbone, and an unsaturated side chain attached to the backbone. In one embodiment, the side chain comprises an unsaturated fatty-acid.Type: GrantFiled: August 26, 2008Date of Patent: October 13, 2015Assignee: Valspar Sourcing, Inc.Inventors: Richard H. Evans, Jeffrey Niederst, Paul E. Share
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Patent number: 9067878Abstract: Disclosed is a composition comprising an organogel which comprises: (a) an alkylated aromatic acid compound of the formula or mixtures thereof, wherein R1, R2, R3, R4, and R5 each, independently of the other, are hydrogen, alkyl, aryl, arylalkyl, or alkyl, provided that at least one of R1, R2, R3, R4, and R5 is —X—Rc, wherein —X— is a linking group between Rc and the aromatic group and Rc is alkyl; and (b) an organic liquid.Type: GrantFiled: December 15, 2011Date of Patent: June 30, 2015Assignee: Xerox CorporationInventors: Darren A. Makeiff, Rina Carlini
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Patent number: 9056950Abstract: A process for forming shaped three-dimensional products is described made from a composition containing at least one filler and an aromatic liquid crystal polymer. In one embodiment, the process includes forming a substrate such as a film, a sheet or a tube, through an extrusion process. Once the substrate is formed, the substrate is then heated and fed to a shaping process. The shaping process may comprise a thermal forming process or a blow molding process. In order to form the three-dimensional products, the aromatic liquid crystal polymer has a high heat of crystallization, a high melt temperature and/or a high melt viscosity.Type: GrantFiled: July 15, 2011Date of Patent: June 16, 2015Assignee: Ticona GmbHInventors: Achim Hofmann, Paul C. Yung
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Patent number: 9056956Abstract: A polyethylene terephthalate composition includes a copolymer component having at least 3 functional groups in an amount of 0.01 mol % to 1.00 mol % with respect to ethylene terephthalate units, in which a ratio (Mw/Mn) between the weight average molecular weight and number average molecular weight of the polyethylene terephthalate composition is 5.0 to 8.0; an alkali metal compound in an amount of 1.0 mol/ton to 3.0 mol/ton in terms of alkali metal element; a phosphorus compound in an amount of 1.5 mol/ton to 5.0 mol/ton in terms of elemental phosphorus; and an o-chlorophenol insoluble matter in an amount of less than 0.5 wt %.Type: GrantFiled: August 31, 2010Date of Patent: June 16, 2015Assignee: Toray Industries, Inc.Inventors: Hiroji Kojima, Jun Sakamoto, Koichi Dan, Shigeru Aoyama
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Patent number: 9046656Abstract: Multilayer optical films are described comprising at least one first optical layer comprising a birefringent thermoplastic polymer having an in-plane birefringence of at least 0.15 at 632.8 nm; and at least one second optical layer having an in-plane birefringence of less than 0.040 at 632.8 nm. The second optical layer comprises a copolymerized blend of at least one birefringent thermoplastic polymer and at least one second thermoplastic polymer.Type: GrantFiled: November 18, 2008Date of Patent: June 2, 2015Assignee: 3M Innovative Properties CompanyInventors: Yufeng Liu, Stephen A. Johnson
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Publication number: 20150141584Abstract: The present invention generally concerns polyester compounds derived from renewable monomer materials and manufacturing process thereof. The invention further pertains to polyester blends presenting improved maximum elongation characteristic.Type: ApplicationFiled: December 28, 2012Publication date: May 21, 2015Applicant: Natura Cosméticos S.A.Inventors: Christopher Saywell, Shaomin Mai, Clarissa Capelas Romeu, Julio Cesar Legramanti Neves
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Publication number: 20150125709Abstract: Disclosed is a method for manufacturing a film. 50 wt % to 85 wt % of a first polyester and 50 wt % to 15 wt % of a second polyester are dried and mixed to form a mixture. The first polyester is polyethylene terephthalate (PET), polyethylene naphthalate (PEN), or combinations thereof. The second polyester is copolymerized of 1 part by mole of terephthalic acid, m parts by mole of 1,4-cyclohexanedimethanol (1,4-CHDM), n parts by mole of 1,3-cyclohexanedimethanol (1,3-CHDM), and o parts by mole of ethylene glycol (EG). m+n+o=1, 0?o?0.4, 0.6?m+n?1, and 0.06?n/m?1.31. The mixture is melted and blended to form a polyester composition, which is extruded to form a sheet. The sheet is then biaxially stretched to obtain a film. The biaxially stretched film is then treated with a thermal setting.Type: ApplicationFiled: December 23, 2013Publication date: May 7, 2015Applicant: INDUSTRIAL TECHNOLOGY RESEARCH INSTITUTEInventors: Cheng-Hsing FAN, Chun-Yen CHEN, Ming-Tsong LEU, Chien-Pang WU
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Publication number: 20150112030Abstract: In one aspect, the invention relates to recycled polyethylene terephthalate compositions, fibers and articles produced therefrom, and methods for producing same. In a further aspect, the invention relates to homogenized post-consumer polyethylene terephthalate. In a further aspect, the invention relates to extruded polymer compositions, polymer mixtures, fibers, and/or Bulked Continuous Filament fibers comprising post-consumer polyethylene terephthalate. In a further aspect, the invention relates to processes for preparing recycled polyethylene terephthalate compositions. This abstract is intended as a scanning tool for purposes of searching in the particular art and is not intended to be limiting of the present invention.Type: ApplicationFiled: May 22, 2014Publication date: April 23, 2015Applicant: Columbia Insurance CompanyInventors: Hubert J. Booth, Christopher Eric Bradley, Daniel Ray Johnson, James Henry Keen, JR.
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Publication number: 20150110994Abstract: In one aspect, the invention relates to recycled polyethylene terephthalate compositions, fibers and articles produced therefrom, and methods for producing same. In a further aspect, the invention relates to homogenized post-consumer polyethylene terephthalate. In a further aspect, the invention relates to extruded polymer compositions, polymer mixtures, fibers, and/or Bulked Continuous Filament fibers comprising post-consumer polyethylene terephthalate. In a further aspect, the invention relates to processes for preparing recycled polyethylene terephthalate compositions. This abstract is intended as a scanning tool for purposes of searching in the particular art and is not intended to be limiting of the present invention.Type: ApplicationFiled: May 22, 2014Publication date: April 23, 2015Applicant: Columbia Insurance CompanyInventors: Hubert J. Booth, Christopher Eric Bradley, Daniel Ray Johnson, James Henry Keen, JR.
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Publication number: 20150111450Abstract: Disclosed herein are polyesters and fibers made therefrom. The fiber comprises a polymer, poly(trimethylene furandicarboxylate) (PTF), and PTF based copolymers.Type: ApplicationFiled: March 30, 2013Publication date: April 23, 2015Inventors: Fredrik Nederberg, Bhuma Rajagopalan
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Patent number: 9012573Abstract: This invention relates to a biodegradable polyester which is particularly suitable for use for the manufacture of wrapping films for packaging, comprising units deriving from at least one diacid and at least one diol, characterized by a high static friction coefficient in comparison with conventional biodegradable polyesters. A further object of this invention is a wrapping film comprising the said biodegradable polyester.Type: GrantFiled: October 27, 2011Date of Patent: April 21, 2015Assignee: Novamont S.p.A.Inventors: Catia Bastioli, Stefano Facco, Roberto Ponti, Angelos Rallis
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Publication number: 20150065610Abstract: A method for preparing poly(butylene terephthalate-co-adipate) copolymer includes reacting (i) poly(butylene terephthalate-co-adipate) oligomers, wherein the oligomers comprise at least one polymer residue derived from a polyethylene terephthalate component and a quencher, with (ii) a chain extender under conditions sufficient to form the poly(butylene terephthalate-co-adipate) copolymer.Type: ApplicationFiled: November 11, 2014Publication date: March 5, 2015Inventors: Husnu Alp ALIDEDEOGLU, Ganesh KANNAN
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Patent number: 8969488Abstract: The invention generally relates to a method of substantially homogeneously mixing ingredients comprising solid thermoplastic particulates and a viscous material in a container and apparatus useful therein. The invention also generally relates to a non-clogging device and mixing apparatus comprising same.Type: GrantFiled: August 31, 2011Date of Patent: March 3, 2015Assignee: Equipolymers GmbHInventors: Rolf Eckert, Guenter Kleis, Uwe Pfannmoller, Volkmar Voerckel, Jens-Peter Wiegner
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Patent number: 8962789Abstract: A method is disclosed herein for the preparation of modified poly (1,3-propanediol terephthalate). The method comprises adding linear polyester with average molecular weight of 800˜3000 and polyethylene glycol with average molecular weight of 200˜2000 into polymerization monomers before polymerization reaction, wherein the linear polyester is a polymer obtained by reaction of C3 ˜C10 straight chain aliphatic dicarboxylic acid or 1,4-cyclohexane diformic acid with C2 ˜C10 straight chain aliphatic diol or 1,4-cyclohexane diformic acid; the linear polyester is 0.5%˜6% of the mass of polymerization monomers; the polyethylene glycol is 0.5%˜8.5% of the mass of polymerization monomers.Type: GrantFiled: February 24, 2011Date of Patent: February 24, 2015Assignee: Jiangsu Zhonglu Technology Development Co., LtdInventor: Shuchang Bian
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Publication number: 20150051355Abstract: A biodegradable material has an improved biodegradability, an enhanced shape recovery rate after deformation of the material and an improved flexibility. The biodegradable material is a chemically cross-linked product of: a multivalent compound A having 3 or more functional groups X such as hydroxyl group; a multivalent compound B having 3 or more functional groups Y such as carboxyl group; and a compound C having a structure originated from a hydroxycarboxylic acid whose homopolymer formed by homopolymerization has a glass transition point of ?40° C. or lower.Type: ApplicationFiled: March 28, 2013Publication date: February 19, 2015Inventors: Masaki Fujita, Megumi Nakanishi, Kazuhiro Tanahashi
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Publication number: 20150045518Abstract: A biodegradable material is a chemically cross-linked product between a multivalent compound A having 3 or more functional groups X such as hydroxyl group; and a multivalent compound B having 3 or more functional groups Y such as carboxyl group wherein chemical cross-linkage(s) is/are formed by condensation reaction of the functional group(s) X and the functional group(s) Y; wherein (y+z)/(x+z) is 1.2 to 4.0 when MA>MB, and (x+z)/(y+z) is 1.2 to 4.0 when MA<MB; wherein x represents the number of the functional group(s) X not condensed with the functional group(s) Y; y represents the number of the functional group(s) Y not condensed with the functional group(s) X; z represents the number of the cross-linkage(s); MA represents weight average molecular weight of the multivalent compound A; and MB represents weight average molecular weight of the multivalent compound B.Type: ApplicationFiled: March 28, 2013Publication date: February 12, 2015Inventors: Masaki Fujita, Megumi Nakanishi, Kazuhiro Tanahashi
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Publication number: 20150018468Abstract: A molded article selected from the group consisting of (1) a sheet or a film, (2) a thermoformed article, (3) a stretched film, wherein the molded article is made of a polyester resin composition containing a polyester resin and a polyester-based plasticizer represented by the following formula (I): R1O—CO—R2—CO—[(OR3)mO—CO—R2—CO—]nOR1 (I), wherein R1 is an alkyl group having from 1 to 4 carbon atoms, R2 is an alkylene group having from 2 to 4 carbon atoms, R3 is an alkylene group having from 2 to 6 carbon atoms, m is the number of from 1 to 6, and n is the number of from 1 to 12, with proviso that all the R2's may be identical or different, and that all the R3's may be identical or different.Type: ApplicationFiled: February 7, 2013Publication date: January 15, 2015Inventors: Hiroki Sawada, Shigehisa Kamimura
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Publication number: 20150014202Abstract: Provided is a heat-shrinkable polyester-based film having: a slow shrinkage speed; a shrinkage rate that increases gently with the increase of temperature; a large shrinkage stress; and an excellent shrinkage finish. This heat-shrinkable polyester-based film is characterized in that: the ratio (A1/A2) between the absorbancy (A1) at 1340 cm?1 of the heat-shrinkable polyester-based film measured by the polarized ATR-FTIR method and the absorbancy (A2) at 1410 cm?1 is from 0.65 to 0.9 in the main shrinkage direction of the film and from 0.45 to 0.75 in the direction orthogonal to the main shrinkage direction; and the warm-water heat shrinkage rate for when the film is immersed in 90-degree warm water for 10 seconds is from 40% to 60% in the main shrinkage direction of the film and from 0% to 12% in the direction orthogonal to the main shrinkage direction.Type: ApplicationFiled: July 23, 2013Publication date: January 15, 2015Inventors: Masayuki Haruta, Yukinobu Mukoyama
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Publication number: 20150017406Abstract: A biaxially oriented polyester film for molding, wherein the film lengthwise-direction and widthwise-direction storage elastic moduli at 100° C. are each greater than or equal to 100 MPa and less than or equal to 1000 MPa, the film lengthwise-direction and width-wise direction storage elastic moduli at 180° C. are each greater than or equal to 41 MPa and less than or equal to 400 MPa, and the stresses at the time of 100% elongation (F100 values) in the film lengthwise direction and width direction at 150° C. are each greater than or equal to 5 MPa and less than or equal to 60 MPa.Type: ApplicationFiled: December 12, 2012Publication date: January 15, 2015Inventors: Isao Manabe, Hideo Shoji, Kozo Takahashi
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Patent number: 8901253Abstract: The invention relates to a polymer network with triple-shape-memory effect and an associated programming method. The invention also relates to a method for producing layer systems made of shape-memory materials comprising the polymer network. The polymer network includes A) a first crystalline switching segment made of a star polymer; and B) a second crystalline switching segment made of a linear polymer or a star polymer.Type: GrantFiled: October 29, 2009Date of Patent: December 2, 2014Assignee: Helmholtz-Zentrum Geesthacht Zentrum fur Material und Kustenforschung GmbHInventors: Marc Behl, Andreas Lendlein, Yakai Feng, Jorg Zotzmann
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Patent number: 8901243Abstract: Biodegradable compositions containing an aliphatic-aromatic copolyester derived from aromatic polyesters. Methods of making the compositions and articles made from the compositions.Type: GrantFiled: March 30, 2012Date of Patent: December 2, 2014Assignee: Saudi Basic Industries CorporationInventors: Husnu Alp Alidedeoglu, Ganesh Kannan
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Patent number: 8889256Abstract: Woven, knit, and non-woven fabrics, and garments and other textile goods fabricated therefrom, are prepared from yarns comprising fibers comprising a fluorinated polyester blend prepared by melt blending a fluorovinyl ether functionalized polyester with a non-fluorinated polyester. The fluoroether functionalized polyester can be a homopolymer or a copolymer. The goods so produced exhibit durable soil, oil, and water repellency.Type: GrantFiled: December 28, 2011Date of Patent: November 18, 2014Assignee: E I du Pont de Nemours and CompanyInventors: Neville Everton Drysdale, Dennis Gerard Madeleine, Fredrik Nederberg
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Publication number: 20140336300Abstract: The invention relates to a composition comprising a polyester, a photoreactive comonomer and a co-reactant, wherein the co-reactant comprises at least one member selected from the group consisting of an unsaturated diol, an unsaturated aliphatic diacid, an unsaturated aromatic diacid, an unsaturated aliphatic ester, an unsaturated aromatic ester, an unsaturated anhydride and mixtures thereof. Other aspects of the present invention include articles produced from these compositions and processes for producing these compositions.Type: ApplicationFiled: July 7, 2011Publication date: November 13, 2014Applicant: INVISTA NORTH AMERICA S.A R.L.Inventors: Simon Paul Bradshaw, Peter John Coleman, Stephen Derek Jenkins, Sanjay Mehta, Lon J. Mathias
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Publication number: 20140326931Abstract: The present invention provides a pigment dispersant that can improve the dispersion of an azo pigment in a water-insoluble solvent. The present invention relates to a compound having a bisazo moiety and a polyester moiety.Type: ApplicationFiled: November 8, 2012Publication date: November 6, 2014Inventors: Yuki Hasegawa, Yasuaki Murai, Masatake Tanaka, Takayuki Toyoda, Masashi Kawamura, Waka Hasegawa, Masashi Hirose
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Publication number: 20140322513Abstract: A stretched film includes a dispersion of at least one polyester and/or polycarbonate in a matrix of at least one polyester and/or polycarbonate different from the first polyester and/or polycarbonate, the percentage by weight of the dispersed polyester and/or polycarbonate in the dispersion being less than 50% and the dispersed polyester and/or polycarbonate being in the form of platelets. The stretched film can be used as a dielectric in a capacitor.Type: ApplicationFiled: July 7, 2014Publication date: October 30, 2014Inventors: Alexis Grosrenaud, Lucien Schosseler
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Patent number: 8852747Abstract: The invention relates to coextrusion binders including renewable and/or biodegradable polymers having good adhesion properties: at least one renewable and/or biodegradable polymer (A) grafted with a functional monomer including at least one reactive function, the grafting ratio being <1% in weight of the grafted polymer (A); at least one non-grafted renewable and/or biodegradable polymer (B) identical to (A) or compatible with (A) optionally a softener (C); and optionally a starch-based material (D). The invention also relates to multilayered structures including the binder of the present invention, in which the layers are preferably made of renewable and/or biodegradable compounds. The multilayered structures are advantageously useful in the field of food packaging.Type: GrantFiled: May 14, 2008Date of Patent: October 7, 2014Assignee: Arkema FranceInventors: Fabrice Chopinez, Johann Laffargue, Jeau-Laurent Pradel, Damien Rauline, Samuel Devisme
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Patent number: 8846825Abstract: The present invention relates to mixtures comprising of biodegradable polyesters comprising at least one polymer of natural origin and at least two aliphatic-aromatic polyesters of the diacid-diol type of which at least one with a high content of long chain aliphatic diacids of renewable origin showing excellent mechanical properties, sufficiently high melting temperatures, adequate crystallization rates, improved biodegradability properties as well as stability of physical properties over time.Type: GrantFiled: November 4, 2010Date of Patent: September 30, 2014Assignee: Novamont S.p.A.Inventor: Catia Bastioli
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Publication number: 20140243481Abstract: The properties of a liquid crystalline polymer (LCP) containing ester linkages and made in the presence of an excess of diol are improved by treating the LCP with a dicarboxylic acid at elevated temperature. The resulting LCPs are useful as molding resins and for films.Type: ApplicationFiled: April 11, 2014Publication date: August 28, 2014Applicant: Ticona LLCInventors: Marion Glen Waggoner, Richard Alan Jackson
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Patent number: 8804308Abstract: A stretched film comprising a dispersion of at least one polyester and/or polycarbonate in a matrix of at least one polyester and/or polycarbonate different from the first polyester and/or polycarbonate, the percentage by weight of the dispersed polyester and/or polycarbonate in the dispersion being less than 50% and the dispersed polyester and/or polycarbonate being in the form of platelets. The stretched film can be used as a dielectric in a capacitor.Type: GrantFiled: April 10, 2009Date of Patent: August 12, 2014Assignee: Dupont Teijin Films U.S. Limited PartnershipInventors: Alexis Grosrenaud, Luclen Schosseler
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Publication number: 20140213740Abstract: In one aspect, the invention relates to recycled polyethylene terephthalate compositions, fibers and articles produced therefrom, and methods for producing same. In a further aspect, the invention relates to homogenized post-consumer polyethylene terephthalate. In a further aspect, the invention relates to extruded polymer compositions, polymer mixtures, fibers, and/or Bulked Continuous Filament fibers comprising post-consumer polyethylene terephthalate. In a further aspect, the invention relates to processes for preparing recycled polyethylene terephthalate compositions. This abstract is intended as a scanning tool for purposes of searching in the particular art and is not intended to be limiting of the present invention.Type: ApplicationFiled: March 11, 2013Publication date: July 31, 2014Inventors: Hubert J. Booth, Christopher Eric Bradley, Daniel Ray Johnson, James Henry Keen, JR.
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Patent number: 8790787Abstract: A thermoplastic polymer advanceable by solid state polymerization is blended with at least one dissimilar thermoplastic polymer, or an organic or inorganic particulate filler. The blend is solid state polymerized to provide a modified polymer alloy or filled polymer blend having at least one physical or chemical property different from that of the blend before solid state polymerization. A substrate is coated with an adherent layer of the modified polymer alloy or filled polymer blend. The modified polymer alloy or filled polymer blend may also be coextruded with a layer of thermoplastic extrusion polymer having a melt viscosity similar to that of the modified polymer alloy or filled polymer blend and applied to a substrate to form an adherent coating.Type: GrantFiled: March 1, 2013Date of Patent: July 29, 2014Assignee: Valspar Sourcing, Inc.Inventor: Jeffrey Niederst
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Patent number: 8791212Abstract: Disclosed are block copolyesters comprising blocks of fluoroether functionalized aromatic polyester and blocks of unmodified aromatic polyester, the block copolyesters having a blockiness index, B, in the range of 0.25 to 1.0. The block copolymers incorporated into blends with unmodified aromatic polyester impart oil and soil resistance to shaped articles prepared from the blends.Type: GrantFiled: November 8, 2011Date of Patent: July 29, 2014Assignee: E I du Pont de Nemours and CompanyInventors: Neville Everton Drysdale, Elizabeth Forrester McCord, Fredrik Nederberg