Mixed With Carboxylic Acid Or Derivative Reactant Or Polymer Therefrom Patents (Class 525/533)
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Patent number: 8563661Abstract: Phosphorus-containing compounds useful for flame retardant epoxy resins are disclosed. The flame retardant epoxy resins may be used to make electrical laminates. This invention is particularly useful in end use applications in which a low bromine or low halogen content is required or desired.Type: GrantFiled: January 9, 2013Date of Patent: October 22, 2013Assignee: Dow Global Technologies LLCInventor: Joseph Gan
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Patent number: 8530604Abstract: A polymer includes a reaction product of an epoxy resin, a first crosslinking agent, and a second crosslinking agent. The first crosslinking agent is reactive with the epoxy resin and has a first molecular weight. The second crosslinking agent is reactive with the epoxy resin and has a second molecular weight of at least ten times greater than the first molecular weight. The polymer has a first phase having a first glass transition temperature and a second phase having a second glass transition temperature that is lower than the first glass transition temperature. The polymer is transformable between a first shape and a second shape at the first glass transition temperature.Type: GrantFiled: November 30, 2010Date of Patent: September 10, 2013Assignee: GM Global Technology Operations LLCInventor: Ingrid A. Rousseau
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Patent number: 8519065Abstract: A problem to be solved by the invention is to provide a novel epoxy resin exhibiting excellent performance with respect to heat resistance and low thermal expansibility of a cured product, a curable composition using the same, and a cured product having excellent heat resistance and low thermal expansibility. The curable composition contains an epoxy compound and a curing agent as essential components, a calixarene-type novel epoxy compound being used as the epoxy compound. The novel epoxy compound has a resin structure represented by structural formula 1 below (in the formula, R1s each independently represent a hydrogen atom, an alkyl group, or an alkoxy group, and n is a repeat unit and an integer of 2 to 10).Type: GrantFiled: August 3, 2011Date of Patent: August 27, 2013Assignee: DIC CorporationInventor: Yutaka Satou
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Publication number: 20130217803Abstract: A curable resin comprising a curing agent, wherein the curing agent comprises an adjustable structural unit having a stable chain-like arrangement which is adjustable to a stable ring-like arrangement, wherein the ring-like arrangement comprises the constituents of the chain-like arrangement with two terminal constituents exhibiting an attractive chemical interaction, and is adjustable back from the ring-like arrangement to the chain-like arrangement by separation of the two terminal constituents.Type: ApplicationFiled: January 6, 2011Publication date: August 22, 2013Applicant: HEXCEL COMPOSITES LIMITEDInventor: John Cawse
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Patent number: 8475925Abstract: A coating is a mixture of polybenzimidazole polymer and an epoxy. The coating may further include a primer underlying the coating. The coating may further include an adhesion promoter. A solution includes a polybenzimidazole polymer, an epoxy resin, an initiator, and a carrier solvent. The solution may further include a stabilizer and/or an adhesion promoter.Type: GrantFiled: June 20, 2011Date of Patent: July 2, 2013Assignee: PBI Performance Products, Inc.Inventors: John C. Moore, Gregory S. Copeland, Michael Gruender
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Patent number: 8466238Abstract: The invention aims to provide latent curing agents which exert high low-temperature curing properties when used together with ionically polymerizable compounds and which exhibit high storage stability at room temperature. Latent curing agents for ionically polymerizable compounds which agents each contain a hydroxyl-free amine imide compound having an N—N bond energy of 100 to 210 kJ/mol as determined by B3LYP functional theory method.Type: GrantFiled: December 26, 2008Date of Patent: June 18, 2013Assignee: Mitsui Chemicals, Inc.Inventors: Hiroaki Tamatani, Mitsuaki Chida, Yugo Yamamoto, Yuichi Ito, Takashi Nakano, Naritoshi Yoshimura
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Patent number: 8440771Abstract: Phosphorus-containing compounds useful for flame retardant epoxy resins are disclosed. The flame retardant epoxy resins may be used to make electrical laminates. This invention is particularly useful in end use applications in which a low bromine or low halogen content is required or desired.Type: GrantFiled: January 20, 2012Date of Patent: May 14, 2013Assignee: Dow Global Technologies LLCInventor: Joseph Gan
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Patent number: 8431223Abstract: An embodiment of the present invention is a technique to form a resin. A mixture is formed by a curing agent dissolved in the epoxy resin. The epoxy resin contains a first rigid rod mesogen. The curing agent contains a second rigid rod mesogen and one of a hydroxyl, amine, and anhydride.Type: GrantFiled: July 16, 2012Date of Patent: April 30, 2013Assignee: Intel CorporationInventors: James C. Matayabas, Jr., Tian-An Chen
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Patent number: 8431655Abstract: The invention provides epoxy and oxetane compositions including the novel acyloxy and N-acyl curing agents described herein. Use of invention curing agents result in cured adhesive compositions with remarkably increased adhesion and reduced hydrophilicity when compared to resins cured with other types of curing agents. Furthermore, the curatives of this invention do not interfere with free-radical cure and are thus suited for use in hybrid cure thermoset compositions.Type: GrantFiled: June 15, 2010Date of Patent: April 30, 2013Assignee: Designer Molecules, Inc.Inventor: Stephen M Dershem
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Publication number: 20130091778Abstract: The invention relates to a thermally curable liquid resin composition intended for manufacturing abrasives that comprises at least one epoxy resin comprising at least two epoxy groups and at least one reactive diluent, said composition having a viscosity, at 25° C., less than or equal to 7000 mPa·s. Application of the resin composition for producing abrasive articles, especially bonded abrasives and coated abrasives. It also relates to the abrasive articles comprising abrasive grains connected by such a liquid resin composition.Type: ApplicationFiled: December 11, 2012Publication date: April 18, 2013Inventors: Alix ARNAUD, Philippe Espiard, Sandrine Pozzolo
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Patent number: 8399577Abstract: A curable epoxy resin composition including at least an epoxy resin component and a hardener component, and optionally further additives, wherein: (a) the epoxy resin component is an epoxy resin compound or a mixture of such compounds; (b) the hardener component includes (b1) an aliphatic and cycloaliphatic or aromatic polycarbonic acid anhydride; and (b2) a polyether-amine of the general formula (I), H2N—(CnH2n—O)m—CnH2n—NH2, wherein n is an integer from 2 to 8; and m is from about 3 to about 100; (c) the polycarbonic acid anhydride [component (b1)] is present in the curable epoxy resin composition in a concentration of 0.60 Mol to 0.93 Mol; and (d) the polyether-amine of the general formula (I) [component (b2)] is present in the curable epoxy resin composition in a concentration of about 0.02 Mol to about 0.1 Mol.Type: GrantFiled: February 24, 2012Date of Patent: March 19, 2013Assignee: ABB Research LtdInventors: Bandeep Singh, Stéphane Schaal, Xavier Kornmann, Prateek Puri
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Publication number: 20130059988Abstract: Functionalized polymer matrix and/or reinforcement materials that are capable of a thermoreversible Diels-Alder reaction are useful for making composite materials. Also disclosed is a composite material which includes one or both of functionalized reinforcement materials and functionalized polymer matrix materials, as well as a method for repairing a composite material including the step of thermally treating the composite material at a temperature sufficient to react a functionality on one of the reinforcement material and the polymer matrix material with another functionality via a Diels-Alder reaction. A method of making a composite material including functionalizing one or both of a reinforcing material and a polymer matrix material with a first reactive group, providing a second reactive group capable of undergoing a Diels-Alder reaction with the first reactive group and reacting the first and second reactive groups to form a composite material, is also described.Type: ApplicationFiled: May 18, 2011Publication date: March 7, 2013Applicant: DREXEL UNIVERSITYInventors: Giuseppe R. Palmese, Amy M. Peterson, Robert E. Jensen
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Patent number: 8389653Abstract: A urethane coating is formed by a reaction of a hydroxy-functional resin and a blocked isocyanate crosslinker. A method of catalyzing this reaction includes forming a polymeric ligand from the resin and/or the crosslinker. The method also includes incorporating a metal catalyst with the polymeric ligand to complex the metal catalyst with the polymeric ligand. The method further includes reacting resin and the crosslinker to form the urethane coating.Type: GrantFiled: March 30, 2006Date of Patent: March 5, 2013Assignee: BASF CorporationInventors: Timothy S. December, Cesar G. Ortiz, Hardy Reuter, Karl-Heinz Grosse-Brinkhaus, Guenter Ott
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Patent number: 8389630Abstract: Provided is a curable composition excellent in curability and mechanical properties as well as a cured product thereof. Specially provided is a curable composition containing a vinyl-based polymer (I) having one or more crosslinkable functional groups at a terminus on average and a nucleophilic agent (II) and a cured product obtained by curing the curable composition. Preferably, the curable composition of the invention further contains an epoxy resin (III).Type: GrantFiled: December 27, 2006Date of Patent: March 5, 2013Assignee: Kaneka CorporationInventors: Hitoshi Tamai, Kohei Ogawa, Yoshiki Nakagawa
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Epoxy resin hardener compositions and epoxy resin compositions containing such hardener compositions
Patent number: 8389652Abstract: An epoxy resin hardener composition including a reaction product of (i) a compound having at least one vicinal epoxy group, and (ii) an amino alcohol; an epoxy resin composition including the epoxy resin hardener composition and a compound having at least one vicinal epoxy group; and a powder coating composition including particles of the epoxy resin hardener composition and particles of a compound having at least one vicinal epoxy group.Type: GrantFiled: January 6, 2009Date of Patent: March 5, 2013Assignee: Dow Global Technologies LLCInventors: Joseph Gan, Matthieu M. Eckert, Carola Rosenthal, Bernhard Kainz, Emile C. Trottier -
Patent number: 8372922Abstract: An one-part epoxy resin composition for the use of bonding of a coil which is preferable for impregnation of a motor and a generator for an automobile, especially of a drive motor-generator set for a hybrid car, which has superior storage stability and a cured resin of the composition has excellent adhesion properties, thermal stability, and reliability, are provided. The one-part epoxy resin composition of the present invention comprises (A) a bisphenol A type and/or F type epoxy resin which is in liquid form at room temperature, (B) methylnadic anhydride as a cycloaliphatic anhydride which is in liquid form at room temperature, and (C) a nitrogen-containing latent hardening accelerator.Type: GrantFiled: September 11, 2007Date of Patent: February 12, 2013Assignee: Somar CorporationInventors: Tetsushi Takata, Takayuki Kawano
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Patent number: 8367780Abstract: A block or graft copolymer including a thermoplastic resin segment and as an aliphatic polyester segment is provided. The copolymer can be used as a compatibilizer for a resin alloy comprising polylactic acid, which can reduce the consumption of petroleum raw materials.Type: GrantFiled: December 4, 2009Date of Patent: February 5, 2013Assignee: Cheil Industries Inc.Inventors: Ji Won Pack, Byeong Do Lee, Chang Do Jung, Hyung Tak Lee
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Publication number: 20130028540Abstract: Provided are an epoxy resin curing agent having excellent properties and high gas barrier capability that epoxy resin has and, in addition thereto, capable of realizing good adhesiveness to polyester and aluminium; an epoxy resin composition containing the curing agent; an adhesive for lamination including the composition as the main ingredient thereof; and a laminate film, a multilayer wrapping material and a wrapping bag using the adhesive. The epoxy resin curing agent comprises a reaction product of the following (A), (B) and (C): (A) meta-xylylenediamine or para-xylylenediamine, (B) a polyfunctional compound having one acyl group and capable of forming an amide group moiety through reaction with a polyamine and forming an oligomer, (C) a metal (meth)acrylate salt with a divalent or more polyvalent metal.Type: ApplicationFiled: April 18, 2011Publication date: January 31, 2013Applicant: MITSUBISHI GAS CHEMICAL COMPANY, INC.Inventors: Nobuhiko Matsumoto, Eiichi Honda, Kana Kumamoto
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Publication number: 20130000839Abstract: The invention relates to a fixing mortar system for embedding anchoring means in mortar in holes or crevices, based on one or more hardening epoxy-based reactive resins, characterised in that it includes silanes which may or may not have reactive groups capable of participating in the polymerisation with a synthetic resin based on the hardening epoxy-based reactive synthetic resin(s) but which in any case have Si-bonded hydrolysable groups, and to related inventive subject matter such as processes, kits and uses.Type: ApplicationFiled: March 2, 2011Publication date: January 3, 2013Applicant: FISCHERWERKE GMBH & CO. KGInventors: Jurgen Grun, Martin Vogel, Clemens Schmidt, Christian Schlenk
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Publication number: 20120322955Abstract: A polyoxyethylene derivative represented by the formula (1): wherein a whole molecular weight of the polyoxyethylene derivative is 500 to 160,000; n is 5 to 3650; L1, L2, and L3 each independently represent an alkylene group, a phenylene group, an ester bond, an amide bond, an ether bond, a urethane bond, a carbonate bond, a secondary amino group, or a combination thereof; X represents a functional group capable of reacting with a bio-related substance; Y represents a hydrophilic group having plural hydroxyl groups made from a residual group of xylitol or volemitol or a residual group of polyglycerin of trimer to 31-mer; Z represents a residual group of a compound having 2 to 5 active hydrogen atoms; b and c are as follows: 1?b?4, 1?c?4, and 2?b+c?5; and d and e each independently are 0 or 1.Type: ApplicationFiled: March 30, 2012Publication date: December 20, 2012Applicant: NOF CORPORATIONInventors: Hiroki Yoshioka, Takashi Matani, Yuji Yamamoto
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Publication number: 20120308481Abstract: Radio-opaque biodegradable compositions are formed by modifying terminal groups of synthetic and natural biodegradable polymers such as polylactones with iodinated moieties. The biodegradable property of the compositions renders them suitable for use in medical field such as drug delivery, imaging. Compounds disclosed in this invention exist as neat liquid. Certain compositions disclosed in this invention form hydrophobic iodine rich domains when dissolved in water, such domains provide better contrasting properties as well as ability to dissolve hydrophobic bioactive drugs. Certain iodinated moieties disclosed in the invention are capable of cross linking natural proteins in situ in presence of suitable catalysts and co-catalysts.Type: ApplicationFiled: August 16, 2012Publication date: December 6, 2012Applicant: PATHAK HOLDINGS LLCInventors: Chandrashekhar P. Pathak, Sanjay M. Thigle
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Publication number: 20120289112Abstract: Improved mechanical properties of carbon nanotube (CNT)-reinforced polymer adhesive matrix nanocomposites are obtained by functionalizing the CNTs with a compound that bonds well to an epoxy matrix. The particles sufficiently improve mechanical properties of the nanocomposites, such as flexural strength and modulus.Type: ApplicationFiled: June 18, 2012Publication date: November 15, 2012Applicant: APPLIED NANOTECH HOLDINGS, INC.Inventors: DONGSHENG MAO, ZVI YANIV, TOM JACOB RAKOWSKI
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Publication number: 20120283357Abstract: This invention relates to an epoxy resin composition, in particular a curable phosphorus containing flame retardant epoxy resin composition comprising epoxy resin and an epoxy resin chain-extending amount of a diaryl alkylphosphonate and/or diaryl arylphosphonate and a cross-linking agent. The curable flame retardant compositions are useful in e.g., printed wiring boards or molding compounds for electronic applications, protective coatings, adhesives, as well as structural and decorative composite materials.Type: ApplicationFiled: November 1, 2011Publication date: November 8, 2012Applicant: ICL-IP America Inc.Inventors: Sergei V. Levchik, Andrew Mieczyslaw Piotrowski, Joseph Zilberman, Stephen J. Chaterpaul
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Patent number: 8304034Abstract: The present invention relates to one-solution type thermosetting resin composition for a protective film of a color filter, and a color filter including the same. The one-solution type thermosetting resin composition includes a copolymer (A) including (meth)acrylate with an epoxy cyclic structure at the side chain, (meth)acrylate with a hydroxyl terminal, acid anhydride, and maleimide with a substituent; an epoxy resin (B); a base-generating agent (C); and an organic solvent (D). When a protective film of a color filter is prepared by using the one-solution type thermosetting resin composition according to the present invention, it has excellent storage stability as well as excellent flatness, close-contacting property, transmission properties, heat resistance, and chemical resistance.Type: GrantFiled: December 31, 2007Date of Patent: November 6, 2012Assignee: Cheil Industries Inc.Inventors: Hyun-Moo Choi, O-Bum Kwon, Sun-Yul Lee
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Patent number: 8288486Abstract: Disclosed is an improved coating composition for food containers that is resistant to high pH processing environments. The improved coating composition is based upon an epoxy-amino resin coating composition that has been modified with other components to improve its performance in high pH environments balanced with flexibility, formability and abrasion resistance. Typically, the coating composition includes an epoxy resin, an amino resin cross-linking agent, a blocked polyisocyanate and a saturated polyester.Type: GrantFiled: October 12, 2011Date of Patent: October 16, 2012Assignee: W. R. Grace & Co.-Conn.Inventors: Armi G. Garcia, Benedick M. Francisco
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Patent number: 8268940Abstract: Disclosed is a halogen- and phosphorus-free flame-retardant adhesive resin composition which can be used in heat contact bonding of adherends at or below 250° C. and is excellent in heat resistance, solder heat resistance after moisture absorption, and processability. Also disclosed is an adhesive film produced from said composition. The flame-retardant adhesive resin composition comprises 65-98% by weight of a silicone unit-containing polyimide resin and 2-35% by weight of an epoxy resin having an acenaphthylene-substituted naphthalene skeleton. The adhesive film produced from the flame-retardant adhesive resin composition is suitable as an adhesive for a laminate for a multiplayer printed circuit board substrate, an adhesive for a hybrid circuit board substrate, and an adhesive for a coverlay film.Type: GrantFiled: March 6, 2008Date of Patent: September 18, 2012Assignee: Nippon Steel Chemical Co., Ltd.Inventors: Akira Mori, Kiwamu Tokuhisa, Kazuhiko Nakahara, Masashi Kaji
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Publication number: 20120225982Abstract: Described herein are metal amidine complexes in combination with a second compound useful as catalysts in a number of polymerization reactions, including polyurethane and epoxy polymerization reactions. Also described herein are various coating compositions and methods of using same for coating substrates using the metal amidine complexes in combination with a second compound.Type: ApplicationFiled: March 5, 2012Publication date: September 6, 2012Inventors: Ramanathan Ravichandran, Robert Coughlin, Bing Hsieh, Farouk Abi-Karam, John Florio
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Publication number: 20120220684Abstract: Disclosed is a curable formulation comprising a resin; all, or a substantial part, of which comprises one or more fatty acid esters, or their derivatives, obtained from plant oils. Due to the high viscosity of known curable resin materials, and in particular cationically photocurable and thermally curable resins epoxy resins, reactive diluents are conventionally added in order to reduce viscosity and render them suitable for certain methods of application, such as flexography and inkjet printing. However, if an excessive amount of reactive diluent is added to a formulation, the concentration of resin may be so low as to prevent a formulation from curing to form a cured, cross-linked material with acceptable properties. Thus the minimum viscosity of known formulations is limited by the amount of low viscosity reactive diluent which may be added to comparatively high viscosity resins.Type: ApplicationFiled: September 7, 2010Publication date: August 30, 2012Inventors: Ian Bryson, Jiaqian Li, Ian Malcom MacKinnon, Jinglan Zhang
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Patent number: 8247517Abstract: The use of 1,3-substituted imidazolium salts of the formula I in which R1 and R3 independently of one another are an organic radical having 1 to 20 C atoms, R2, R4, and R5 independently of one another are an H atom or an organic radical having 1 to 20 C atoms, it also being possible for R4 and R5 together to form an aliphatic or aromatic ring, and X is a dicyanamide anion as latent catalysts for curing compositions comprising epoxy compounds.Type: GrantFiled: June 9, 2008Date of Patent: August 21, 2012Assignee: BASF SEInventors: Lars Wittenbecher, Michael Henningsen, Georg Degen, Matthias Maase, Manfred Doering, Ulrich Arnold
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Patent number: 8242217Abstract: It is an object of the present invention to provide an epoxy resin curing agent which has a favorable pot life and good storage stability as a curing agent for epoxy resins and from which an epoxy resin cured product having good water resistance and hardness is obtained through curing. The present invention is an epoxy resin curing agent containing a secondary or tertiary branched thiol compound having a substituent on a carbon atom at the ?-position to a thiol group, and is also an epoxy resin composition comprising a polyvalent epoxy compound and the epoxy resin curing agent.Type: GrantFiled: December 8, 2008Date of Patent: August 14, 2012Assignee: Showa Denko K.K.Inventors: Yoshifumi Urakawa, Hideo Miyata, Isao Yamagami, Katsumi Murofushi
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Patent number: 8241739Abstract: The object of the invention is a new Sheet Molding Compound (SMC), Thick Molding Compound (TMC), or Bulk Molding Compound (BMC) comprising at thermosetting resin on the basis of renewable resources with which molded parts can be produced in a molding process at elevated temperature and pressure said process being suitable to produce molded parts in an industrial process.Type: GrantFiled: July 27, 2007Date of Patent: August 14, 2012Assignees: Polynt S.p.A., Bio-Composites and More GmbHInventors: Uwe Schonfeld, Oliver Turk, Giovanni Vargiolu, Klaus Dippon, Nicole Busam, Simone Weber
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Patent number: 8242216Abstract: An embodiment of the present invention is a technique to form a resin. A mixture is formed by a curing agent dissolved in the epoxy resin. The epoxy resin contains a first rigid rod mesogen. The curing agent contains a second rigid rod mesogen and one of a hydroxyl, amine, and anhydride.Type: GrantFiled: June 27, 2011Date of Patent: August 14, 2012Assignee: Intel CorporationInventors: James C. Matayabas, Jr., Tian-An Chen
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Patent number: 8232355Abstract: The present invention provides a liquid resin composition for electronic components, which is excellent in migration resistance and also superior in formability and reliability, as well as an electronic component device sealed therewith, and relates to a liquid resin composition for electronic components, which comprises (A) an epoxy resin, (B) a cyclic acid anhydride which is liquid at ordinary temperature and has an acid anhydride equivalent of 200 or more, and (C) a coupling agent.Type: GrantFiled: November 24, 2006Date of Patent: July 31, 2012Assignee: Hitachi Chemical Co., Ltd.Inventors: Hisato Takahashi, Hisashi Tsukahara, Kyouichi Tomita, Shinsuke Hagiwara
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Patent number: 8217099Abstract: A thermosetting resins composite, composed of: epoxy resin which can have a total polymerization with bismaleimide, occupying 1.75%-18.0% solids weight of the composite; bismaleimide compounds, occupying 0.15%-12.5% solids weight of the composite; free radical initiator, its mole fraction of which its addition accounts for reaction monomer total is 0.01%-0.15%; inhibitor, whose amount is the half to double of the initiator; styrene-maleic anhydride copolymers, occupying 17.5%-47.0% solids weight of the composite; filler, occupying 20%-60% solids weight of the composite; solvent, occupying 30%-50% solids weight of the composite; flame retardant which can be used in CCL industries.Type: GrantFiled: May 22, 2008Date of Patent: July 10, 2012Assignees: ITEQ (Dongguan) Corporation, ITEQ CorporationInventors: Yufang He, Lijun Su
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Patent number: 8211540Abstract: An adhesive film composition includes an elastomer resin having one or more of a hydroxy group, a carboxyl group, or an epoxy group, a film-forming resin, a silylated phenolic curing resin, an epoxy resin, a curing accelerator, and a filler.Type: GrantFiled: October 8, 2008Date of Patent: July 3, 2012Assignee: Cheil Industries, Inc.Inventors: Yong Woo Hong, Ki Seong Jung, Wan Jung Kim, Su Mi Im, Sang Jin Kim, Chang Beom Chung
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Patent number: 8207278Abstract: A composition of matter consisting of a stable solution containing a polymer derived from a solution of a polymer containing trace metals, the derived method comprising the steps of: (a) providing a polymer solution containing a polymer, a first solvent and trace metals; (b) passing said polymer solution through an acidic cation ion exchange material to remove said trace metals therefrom and thereby forming a polymer solution containing free acid radicals; (c) precipitating said polymer from said polymer solution of step b by contacting with a second solvent wherein the polymer is substantially insoluble therein; (d) filtering said solution and said second solvent to thereby form a solid polymer cake; and (e) contacting said cake from step d with sufficient quantities of additional said second solvent in order to remove free acid radicals there from.Type: GrantFiled: December 9, 2010Date of Patent: June 26, 2012Assignee: Dupont Electronic Polymers LPInventors: William Richard Russell, John Anthony Schultz
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Publication number: 20120156501Abstract: Curable adhesive compositions, cured adhesive compositions, and articles that include the cured adhesive compositions are described. The curable adhesive composition contains a) an epoxy resin, b) a curing agent, c) a reactive liquid modifier, and d) a toughening agent. The cured adhesive compositions can be used as structural adhesives.Type: ApplicationFiled: August 9, 2010Publication date: June 21, 2012Inventor: Christopher J. Campbell
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Patent number: 8198382Abstract: The present invention relates to an epoxy resin composition for photosemiconductor element encapsulation, the epoxy resin composition including the following components (A) to (D): (A) an epoxy resin having two or more epoxy groups in one molecule thereof, (B) an acid anhydride curing agent, (C) a curing accelerator, and (D) an alcohol compound having three or more primary hydroxyl groups in one molecule thereof.Type: GrantFiled: April 16, 2008Date of Patent: June 12, 2012Assignee: Nitto Denko CorporationInventor: Hiroshi Noro
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Publication number: 20120142822Abstract: A thermosetting resin composition which includes an epoxy-containing component and a curing agent component containing a cyclohexanetricarboxylic anhydride. The cured product of the thermosetting resin composition is excellent in surface hardness, solvent resistance, transparency, and adhesion to substrate, and is useful as a surface protection layer of the substrate.Type: ApplicationFiled: August 6, 2010Publication date: June 7, 2012Applicant: Mitsubishi Gas Chemical Company, Inc.Inventors: Takashi Sato, Shuichi Ueno
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Patent number: 8193297Abstract: The use of 1,3-substituted imidazolium salts of the formula I in which R1 and R3 independently of one another are an organic radical having 1 to 20 C atoms, R2, R4, and R5 independently of one another are an H atom or an organic radical having 1 to 20 C atoms, it also being possible for R4 and R5 together to form an aliphatic or aromatic ring, and X is a thiocyanate anion as latent catalysts for curing compositions comprising epoxy compounds.Type: GrantFiled: June 6, 2008Date of Patent: June 5, 2012Assignee: BASF SEInventors: Lars Wittenbecher, Matthias Maase, Georg Degen, Michael Henningsen, Manfred Doering, Ulrich Arnold
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Patent number: 8173726Abstract: A process including the polymerization of a reactive diluent, which is present in an aqueous dispersion that further includes an epoxy-amine material, is disclosed. The resulting composition is useful as a coating composition.Type: GrantFiled: October 7, 2010Date of Patent: May 8, 2012Assignee: Valspar Sourcing, Inc.Inventors: Martin Peter Joseph Heuts, Lonnie Jones
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Patent number: 8168731Abstract: Provided is a curable resin composition that exhibits good heat resistance and low thermal expansion, and that realizes good solubility in solvents, a cured product thereof, a printed wiring board including the composition, a novel epoxy resin that imparts these properties, and a process for producing the same. A curable resin composition contains, as essential components, an epoxy resin (A) having, in its molecular structure, a glycidyloxy group and a skeleton in which a naphthalene structure and a cyclohexadienone structure are bonded to each other via methylene group(s); and a curing agent (B).Type: GrantFiled: August 7, 2009Date of Patent: May 1, 2012Assignee: DIC CorporationInventors: Yutaka Satou, Kazuo Arita, Ichirou Ogura
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Publication number: 20120070593Abstract: Partially hydrogenated bisphenol-A based polymers. Coating compositions for food or beverage containers and medical devices, including a partially hydrogenated bisphenol-A based polymer. Food or beverage containers and medical devices coated with partially hydrogenated bisphenol-A based polymers. Food or beverage containers and medical devices made from partially hydrogenated bisphenol-A based polymers.Type: ApplicationFiled: September 17, 2010Publication date: March 22, 2012Inventors: William B. Carlson, Gregory D. Phelan, Phillip A. Sullivan
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Patent number: 8138278Abstract: A composition comprising a reaction product of reactants comprising (a) a compound comprising (i) a polysulfide moiety and (ii) an oxygen atom in a ?-position to a sulfur link having the formula: where each R is independently selected from H or a C1 to C20 organyl group, R? is independently selected from a C1 to C20 organyl group, R?? is independently selected from H or a C1 to C20 organyl group, and x has an average of greater than 2, (b) a compound comprising a nucleophilic moiety; and (c) a compound comprising a moiety reactive to active hydrogen.Type: GrantFiled: June 25, 2010Date of Patent: March 20, 2012Assignee: POLYMERight, Inc.Inventors: Leonid Rappoport, Alexander Vainer, Aleksander Yam
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Patent number: 8128782Abstract: The present invention provides an amine based epoxy resin curing agent and an epoxy resin composition containing the curing agent. The epoxy resin composition has a high gas barrier performance, a long pot life, and utility as a coating material or an adhesive for laminates.Type: GrantFiled: May 20, 2008Date of Patent: March 6, 2012Assignee: Mitsubishi Gas Chemical Company, Inc.Inventors: Shinichi Yonehama, Shigeyuki Hirose, Shinichi Ayuba, Eiichi Honda, Masayoshi Takahashi, Kana Kumamoto
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Patent number: 8124716Abstract: Phosphorus-containing compounds are disclosed which are obtainable by reacting: (A) at least one organophosphorus compound having a group selected from the group H—P?O; the group P—H and the group P—OH; and (B) at least one compound having the following Formula (I): [R?(Y)m?]m(X—O—R?)n??Formula (I) wherein R? is an organic group; Y is a functional group selected from the group consisting of hydroxy, carboxylic acid, and amine; X is a hydrocarbylene group; R? is hydrogen or a hydrocarbyl group having from 1 to 8 carbon atoms, R is alkyl or aryl group having from 1 to 12 carbon atoms; m?, m and n are, independently, numbers equal to or greater than 1. These compounds are useful for making flame retardant epoxy and polyurethane resins and ignition resistant thermoplastic resins, each of which is useful for a variety of end uses requiring flame retardancy or ignition resistance. Flame retardant epoxy resins may be used to make electrical laminates.Type: GrantFiled: November 4, 2010Date of Patent: February 28, 2012Assignee: Dow Global Technologies LLCInventor: Joseph Gan
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Publication number: 20120046425Abstract: A thermosettable resin composition including (a) at least one thermosetting resin; (b) at least one polymeric glycidyl reactive diluent; and (c) a hardener; a process for producing the thermosettable resin composition; a cured product comprising the cured thermosettable composition; and a process for producing the cured resin thermoset product including (I) admixing (a) at least one thermosetting resin; (b) at least one polymeric glycidyl reactive diluent; and (c) a hardener; and (II) curing the mixture of step (I).Type: ApplicationFiled: May 19, 2010Publication date: February 23, 2012Inventors: Markus Schrötz, Marcus Hummel, Ludwig Huelskaemper
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Patent number: 8114508Abstract: The present invention provides a composition of the modified maleic anhydride and the epoxy resins, including (A) one or more of the epoxy resin mixtures, (B) a modified maleic anhydride copolymer, (C) additives and (D) inorganic filler materials, wherein component (A) the epoxy resin mixture accounts for 35%˜56% by weight of the composition solids, component (B) the modified maleic anhydride copolymer accounts for 44%˜65% by weight of the composition solids, based on 100% by weight of total components (A), (B) and (C).Type: GrantFiled: October 20, 2009Date of Patent: February 14, 2012Assignee: Nan Ya Plastics CorporationInventor: Ming Jen Tzou
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Publication number: 20120012999Abstract: The present invention relates to a semiconductor-encapsulating adhesive, a semiconductor-encapsulating film-form adhesive, a method for producing a semiconductor device, and a semiconductor device. The present invention provides a semiconductor-encapsulating adhesive comprising (a) an epoxy resin, and (b) a compound formed of an organic acid reactive with an epoxy resin and a curing accelerator.Type: ApplicationFiled: July 16, 2010Publication date: January 19, 2012Applicant: HITACHI CHEMICAL COMPANY, LTD.Inventors: Kazutaka HONDA, Tetsuya ENOMOTO, Yuuki NAKAMURA
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Publication number: 20120004377Abstract: It is an object of the present invention to provide a clathrate that suppresses a curing reaction at low temperature to promote an improvement in storage stability (one-component stability), and can effectively cure a resin by heating treatment. A clathrate suitable for the clathrate is a clathrate containing (b1) at least one selected from the group consisting of an aliphatic polyvalent carboxylic acid, 5-nitroisophthalic acid, 5-tert-butylisophthalic acid, 5-hydroxyisophthalic acid, isophthalic acid, and benzophenone-4,4?-dicarboxylic acid; and (b2) at least one selected from the group consisting of an imidazole compound represented by the following formula (I), and 1,8-diazabicyclo[5.4.0]undecene-7, at a molar ratio of 1:1.Type: ApplicationFiled: March 15, 2010Publication date: January 5, 2012Inventors: Masami Kaneko, Kazuo Ono