Solid Polymer Derived From Phenolic Reactant Patents (Class 525/534)
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Patent number: 6420491Abstract: A catayltic process for the hydrogenation of aromatic polymers is disclosed. The catalyst used in the process is a metal or mixture of metals of sub-group VIII of the periodic table together with a support of silicon dioxide, aluminum oxide or a mixture thereof. The catalyst, having pores is characaterized in that the pores having diameters of 100 to 1,000 Å constitute less than 15 percent of the total volume of pores. The hydrogenation, that is carried out in the presence of at least one oxygen-containing hydrocarbon is characterized in that it is essentially complete and without significant degradation of molecular weights.Type: GrantFiled: January 16, 2001Date of Patent: July 16, 2002Assignee: Bayer AktiengesellschaftInventors: Volker Wege, Johann Rechner, Eberhard Zirngiebl
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Publication number: 20020091200Abstract: The present invention refers to an optical film comprising one or more polyarylates having at least some units represented by the general structure: 1Type: ApplicationFiled: April 10, 2001Publication date: July 11, 2002Applicant: FERRANIA S.p.A.Inventors: Simone Angiolini, Mauro Avidano, Paolo Salvarani, Roberto Bracco
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Patent number: 6417287Abstract: A process for the hydrogenation of aromatic polymers is disclosed. Accordingly, the solvent used comprise an ether that contains no &agr;-hydrogen atom on a carbon atom adjacent to the ether function. The process results in virtually complete hydrogenation of the aromatic units.Type: GrantFiled: June 12, 2000Date of Patent: July 9, 2002Assignees: Bayer Aktiengesellschaft, Teijin Ltd.Inventors: Volker Wege, Johann Rechner
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Patent number: 6380307Abstract: Silane functionalized polyaromatic polymers which may be prepared by reacting a polyaromatic polymer with a sulfonating agent and reacting the sulfonated polyaromatic polymer with a silane terminated coupling agent.Type: GrantFiled: July 6, 2000Date of Patent: April 30, 2002Assignee: University of Flordia Research Foundation, Inc.Inventors: Anthony B. Brennan, Rodrigo L. Orefice, Michael P. Zamora
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Patent number: 6376080Abstract: The invention relates to a method of preparing a polybenzoxazine which includes heating a molding composition including a benzoxazine and a heterocyclic dicarboxylic acid to a temperature sufficient to cure the molding composition, thereby forming the polybenzoxazine. Also disclosed are a method of preparing a polybenzoxazine composition having near-zero volume change after post cure and a method of coating a device using a polybenzoxazine composition of this invention.Type: GrantFiled: June 7, 1999Date of Patent: April 23, 2002Assignee: Loctite CorporationInventor: Anthony A. Gallo
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Patent number: 6365323Abstract: Disclosed is a composition which comprises a polymer containing at least some monomer repeat units with photosensitivity-imparting substituents which enable crosslinking or chain extension of the polymer upon exposure to actinic radiation, said polymer being of the formula wherein x is an interger of 0 or 1, A is one of several specified groups, such as B is one of several specified groups, such as or mixtures thereof, and n is an integer representing the number of repeating monomer units, wherein said photosensitivity-imparting substituents are allyl ether groups, epoxy groups, or mixtures thereof. Also disclosed are a process for preparing a thermal ink jet printhead containing the aforementioned polymers and processes for preparing the aforementioned polymers.Type: GrantFiled: March 16, 1999Date of Patent: April 2, 2002Assignee: Xerox CorporationInventors: Ram S. Narang, Timothy J. Fuller
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Patent number: 6365678Abstract: A process for the production of polyether block copolysulfones via trans-etherification is disclosed. In the inventive process, an aromatic sulfone polymer is reacted with an aliphatic polyether having on average at least one terminal OH function, preferably in the presence of a basic catalyst. In a preferred embodiment the reaction is carried out in a dipolar aprotic solvent.Type: GrantFiled: February 10, 2000Date of Patent: April 2, 2002Assignee: Bayer AktiengesellschaftInventors: Knud Reuter, Claus-Ludolf Schultz, Ute Wollborn, Heinz Pudleiner
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Patent number: 6365274Abstract: Powders of oxidized polyarylene sulfide and powders comprising from 1 to 99% by weight of oxidized polyarylene sulfide and from 1 to 99% by weight of a metal, carbide, ceramic or high temperature polyimide, polyamide imide, polyester imide and aromatic polyester plastic, or a mixture thereof are very suitable for use in thermal spraying and thereby form coatings having a strong chemical and mechanical resistance and high dimensional stability when exposed to high and low temperatures. Such coatings are advantageous for use as abradable seal clearance control coating in the compressor section of gas turbine engines, motor vehicle turbochargers and superchargers, and for use as a coating of reaction vessels, kitchen ware, sealings or bearings.Type: GrantFiled: February 25, 1999Date of Patent: April 2, 2002Assignee: Ticona GmbHInventors: DI. Helmut Scheckenbach, Christopher William Smith
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Publication number: 20020037941Abstract: A low dielectric constant material has a polymeric network that is fabricated from a first and a second component. The first component comprises a polymeric strand, and the second component comprises a molecule having a central portion with at least three arms extending from the central portion, wherein each of the arms includes a backbone with a reactive group. The first component and the second component form the polymeric network in a reaction that involves at least one of the reactive groups when the first and second components are thermally activated. Contemplated low dielectric constant materials are advantageously employed in the fabrication of electronic devices, and particularly contemplated devices include integrated circuits.Type: ApplicationFiled: December 3, 2001Publication date: March 28, 2002Inventors: Kreisler S. Lau, Feng Quan Liu, Boris Korolev, Emma Brouk, Ruslan Zherebin, David Nalewajek
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Patent number: 6339116Abstract: Biobased cross-linked compositions, methods of fabrication and structures, in particular biobased printed wiring boards using the compositions and methods of making the structures are described. Biobased materials such as lignin, crop oils, wood resins, tannins, and polysaccharides and combinations thereof are cross-linked, preferably using heat, a cross-linking agent, and an initiator. The materials fabricated have suitable properties for printed wiring boards which are made by impregnating a fiberglass or biobased cloth with an admixture of the biobased material, cross-linking agent and initiator which is processed by conventional methods to produce a printed wiring board.Type: GrantFiled: December 19, 1996Date of Patent: January 15, 2002Assignee: International Business Machines CorporationInventors: Ali Afzali-Ardakani, Jeffrey Donald Gelorme, Laura Louise Kosbar
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Patent number: 6335304Abstract: A metal (M) alkyl acid phosphate catalyst for the reaction of an epoxy compound with a carboxyl compound to provide a coating formulation that is stable at room temperature; that is humidity resistant, and non-yellowing, wherein the alkyl acid phosphate has the formula: (RO)n—(P═O)—(OH)m and wherein: a. each R is selected from the group consisting of: i) a C1 to C18 alkly, cycloalkyl, or aryl; ii) a linear or branched C6 to C18 alkyl substituted with —(O—CH2—CH2—)o or —(O—CH—CH3—CH2—)p, wherein o or p is from 1 to 20; iii) a &bgr;-hydroxyethyl compound, R′—X—CH2—CH—OH—CH2—, wherein R′ is a C6 to C18 alkyl or cycloalkyl or aryl, X is either —CH2—, —O— or —COO—; b. n+m=3 and n is between 2 to 1; and c. M is Zn or Sn (II) in a mole equivalent of 0.7 to 1.5 moles per mole of alkyl acid phosphate.Type: GrantFiled: November 9, 1999Date of Patent: January 1, 2002Assignee: KIng Industries, INCInventors: Zhiqiang Alex He, Werner J. Blank, Marie Emmanuelle Picci
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Patent number: 6329493Abstract: Plumbing articles made from a thermoplastic resin comprising a poly(biphenyl ether sulfone) and a poly(aryl ether sulfone) comprising bisphenol A residues.Type: GrantFiled: October 4, 1999Date of Patent: December 11, 2001Assignee: BP Corporation North America Inc.Inventors: Mohammad J. El-Hibri, Barry L. Dickinson
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Patent number: 6313185Abstract: Nanoporous materials are fabricated from polymers having backbones with reactive groups used in crosslinking. In one aspect of preferred methods and compositions, the reactive groups in the backbone comprise a diene and a dienophile. The diene may advantageously comprise a tetracyclone, and the dienophile may advantageously comprise an ethynyl. In another aspect of preferred methods and compositions, the reactive groups in the backbone are included in a conjugated system. Especially preferred polymeric strands comprise a poly(arylene ether) synthesized from a difluoroaromatic portion and an aromatic bisphenolic portion. It is still more preferred that the difluoroaromatic portions of the poly(arylene ether) are modified in such a way that some difluoroaromatic portions carry a thermolabile portion. In still other aspects crosslinking may advantageously occur without reliance on an exogenous crosslinker.Type: GrantFiled: September 24, 1998Date of Patent: November 6, 2001Assignee: Honeywell International Inc.Inventors: Kreisler Lau, Tian-An Chen, Roger Leung
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Patent number: 6306980Abstract: A novel resin composite consists of a thermosetting resin or photosensitive resin and a thermoplastic resin and has a guasi-homogeneous compatible structure not only having properties inherent to the thermosetting or photosensitive resin but also exhibiting values of properties higher than those inherent to the thermoplastic resin.Type: GrantFiled: April 19, 2000Date of Patent: October 23, 2001Assignee: Ibiden Co., Ltd.Inventors: Dong Dong Wang, Motoo Asai
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Patent number: 6306979Abstract: In a process for the preparation of derivatized carbon monoxide copolymers, functionalized linear, strictly alternating carbon monoxide copolymers of carbon monoxide, at least one 1-alkene (A), where (A) is an aryl compound substituted by at least one terminal allyl or homoallyl moiety and by at least one hydroxyl or amino group, or an a-olefinically unsaturated aliphatic alcohol, and, if desired, at least one C2-C20-1-alkene (B) are reacted with an organic compound (C) having at least one electrophilic group in an aprotic organic solvent.Type: GrantFiled: September 7, 2000Date of Patent: October 23, 2001Assignee: BASF AktiengesellschaftInventors: Joachim Queisser, Michael Geprägs, Bernhard Rieger, Roland Wursche
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Publication number: 20010031837Abstract: A (meth)acrylate terpolymer is provided comprising 1-30% of total terpolymer weight epoxy-functional (meth)acrylate monomer units, 1-98% of total terpolymer weight tackifier (meth)acrylate monomer units, and 1-98% of total terpolymer weight compatibilizing (meth)acrylate monomer units, wherein said compatibilizing (meth)acrylate monomer unit is a (meth)acrylic ester derived from an aromatic alcohol containing 6-14 carbon atoms. Also provided are self-fixturing adhesive compositions comprising the acrylate terpolymer of the present invention and methods of their use.Type: ApplicationFiled: April 5, 2001Publication date: October 18, 2001Applicant: 3M Innovative Properties CompanyInventors: Mario Alberto Perez, Ahmed Salih Abuelyaman, Ikuko Ebihara, Lani S. Kangas
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Publication number: 20010031851Abstract: The object was to provide an epoxy resin composition which has excellent flame retardancy, heat resistance and humidity resistance and is advantageously used for semiconductor encapsulating, laminated boards, electrical insulation and the like.Type: ApplicationFiled: February 15, 2001Publication date: October 18, 2001Inventors: Takao Fukuzawa, Takayoshi Hirai, Tetsuro Imura, Yoshinobu Ohnuma
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Publication number: 20010029284Abstract: In 100 parts by weight of a composition, from 2 to 89 parts by weight of a fluorinated polymer having a fluorine content of at least 65 wt %, from 97 to 10 parts by weight of a non-fluorinated polymer and from 1 to 35 parts by weight of a dispersing agent having a carboxylic acid group or its derivative, or a sulfonic acid group or its derivative, are blended.Type: ApplicationFiled: May 16, 2001Publication date: October 11, 2001Applicant: ASAHI GLASS COMPANY, LTD.Inventors: Masako Nagashima, Takeshi Eriguchi, Yuriko Kaida, Hiroki Kamiya, Masao Umino, Masataka Yokota
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Patent number: 6294621Abstract: A novel resin composite consists or a thermosetting resin or photosensitive resin and a thermoplastic resin and has a quasi-homogeneous compatible structure not only having properties inherent to the thermosetting or photosensitive resin but also exhibiting values of properties higher than those inherent to the thermoplastic resin.Type: GrantFiled: April 19, 2000Date of Patent: September 25, 2001Assignee: Ibiden Co., Ltd.Inventors: Dong Dong Wang, Motoo Asai
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Patent number: 6291077Abstract: A lactone chain-extended polyester polyol of the present invention comprises the reaction product of a lactone and a previously chain-extended phenolic-based hydroxyl compound. The previously chain-extended phenolic-based hydroxyl compound may comprise the reaction product of (i) a lactone or an alkoxylating agent selected from the group consisting of alkylene oxides and alkylene carbonates, and (ii) a phenolic aralkylation polymer comprising the reaction product of a phenolic monomer having at least two free reactive positions; a styrene derivative; and a coupling agent. The previously chain-extended phenolic-based hydroxyl compound also may be chain-extended by reacting with a lactam to produce a lactam chain-extended polyester polyamide. The polyols and polyamides of the present invention provide unique combinations of hard and soft functionalities, which translates into materials exhibiting a unique combination of toughness and hardness.Type: GrantFiled: August 28, 2000Date of Patent: September 18, 2001Assignee: Georgia-Pacific Resins, Inc.Inventors: Rajan Hariharan, David A. Hutchings, Kenneth A. Bourlier, Ellen V. Nagy
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Patent number: 6265498Abstract: A novel resin composite consists of a thermosetting resin or photosensitive resin and a thermoplastic resin and has a quasi-homogeneous compatible structure not only having properties inherent to the thermosetting or photosensitive resin but also exhibiting values of properties higher than those inherent to the thermoplastic resin.Type: GrantFiled: April 19, 2000Date of Patent: July 24, 2001Assignee: Ibiden Co., Ltd.Inventors: Dong Dong Wang, Motoo Asai
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Patent number: 6265491Abstract: A curable composition including a thermoset resin a curing agent component, an amount of a thermoplast component having reactive pendant and/or end groups, an organometallic curing catalyst component. The organometallic curing catalyst component is capable of forming cross-links with reactive pendant and/or end groups of the thermoset and thermoplast resins and comprises an organometallic complex compound of the formula I=M(R)n, where M is selected from titanium, zirconium, hafnium, cerium, vanadium, niobium, R is selected from mono-, bi- and tri and/or tetra dentate organic ligands and n is four or six.Type: GrantFiled: June 14, 1999Date of Patent: July 24, 2001Assignee: Cytec Technology Corp.Inventors: Jeffrey T. Carter, Patrick Terence McGrail
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Patent number: 6235850Abstract: A (meth)acrylate terpolymer is provided comprising 1-30% of total terpolymer weight epoxy-functional (meth)acrylate monomer units, 1-98% of total terpolymer weight tackifier (meth)acrylate monomer units, and 1-98% of total terpolymer weight compatibilizing (meth)acrylate monomer units, wherein said compatibilizing (meth)acrylate monomer unit is a (meth)acrylic ester derived from an aromatic alcohol containing 6-14 carbon atoms. Also provided are self-fixturing adhesive compositions comprising the acrylate terpolymer of the present invention and methods of their use.Type: GrantFiled: December 11, 1998Date of Patent: May 22, 2001Assignee: 3M Immovative Properties CompanyInventors: Mario Alberto Perez, Ahmed Salih Abuelyaman, Ikuko Ebihara, Lani S. Kangas
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Patent number: 6228970Abstract: A new poly (biphenyl ether sulfone) having improved polydispersity and also having low levels of low molecular weight oligomer.Type: GrantFiled: September 22, 1999Date of Patent: May 8, 2001Assignee: BP Amoco CorporationInventor: Selvaraj Savariar
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Patent number: 6207789Abstract: The present invention provides a resin containing in the backbone chain a structural unit represented by the following Formula (I) or (II), as a novel phenolic resin having a high Tg, a low moisture absorption, a low molding shrinkage, high adhesive properties and high flow properties. The present invention also provides a resin composition and a molding material each containing the above resin, and an electronic component device having a device element encapsulated with it.Type: GrantFiled: February 23, 2000Date of Patent: March 27, 2001Assignee: Hitachi Chemical Co., Ltd.Inventors: Haruaki Sue, Shinsuke Hagiwara, Fumio Furusawa, Seiichi Akagi, Kazuyoshi Tendo
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Patent number: 6197223Abstract: The present invention recites a method comprising reacting in a solvent in the presence of a base a) at least one diacidic monomer comprising about 1 to 100 mole % of at least one light-absorbing monomer having a light absorption maximum between about 300 nm and about 1200 nm and 99-0 mole % of a non-light absorbing monomer which does not absorb significant light at wavelengths above 300 nm or has a light absorption maximum below 300 nm, with b) an organic compound of Formula II X—B—X1 wherein B is a divalent organic radical to form a light absorbing composition comprising a mixture of a polymer having the formula and a cyclic compound having the general formula wherein B is as defined above; n is at least 2, m is 1, 2, 3 or 4 and A comprises the residue of a diacidic monomer comprising about 1 to 100 mole % of at least one light-absorbing monomer having a light absorption maximum between about 300 nm and about 1000 nm and wherein the remaining portion of AType: GrantFiled: May 26, 1999Date of Patent: March 6, 2001Assignee: Eastman Chemical CompanyInventors: Max Allen Weaver, James John Krutak, Sr., Brian Edison Maxwell, Gerry Foust Rhodes, Samuel David Hilbert, Jean Carroll Fleischer, William Whitfield Parham
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Patent number: 6194540Abstract: The sulfonation of a polyaniline or a derivative thereof by the use of a sulfonating agent, characterized by dispersing the polyaniline or the derivative thereof in a reaction solvent thereby inhibiting the formation of lumps of grains due to substantial aggregation. Preferably, the solvent for the reaction is an organic solvent incapable of reacting with the sulfonating agent. The initial stirring power for the reaction of sulfonation is preferred to be not less than 0.03 kW/m3 and the polyaniline or the derivative thereof is preferred to have a water content of not more than 8 wt. %. Further, this invention is characterized by subjecting a polyaniline having introduced a sulfonic acid group therein or a derivative thereof to hydrolysis in a mixed solution of water with a hydrophilic organic solvent. The hydrophilic organic solvent is preferred to be an alcohol.Type: GrantFiled: October 19, 1999Date of Patent: February 27, 2001Assignee: Nippon Shokubai Co., Ltd.Inventors: Shoji Ito, Kazuhiko Murata, Ryuji Aizawa, Yoshinobu Asako
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Patent number: 6172128Abstract: Nanoporous polymeric materials are fabricated in which polymeric strands are crosslinked via ring structures. Preferred ring structures are formed de novo during crosslinking, and at least some of the ring structures are preferably included in the backbones of the strands. At least one of the ring structures may advantageously comprise an aromatic structure, and may more advantageously comprise a benzyl moiety. Especially preferred polymers comprise a poly(arylene ether) synthesized from a difluoroaromatic portion and an aromatic bisphenolic portion. In another preferred aspect, the difluoroaromatic portions of the poly(arylene ether) carry at least two different crosslinking functionalities. In an even more preferred aspect, the crosslinking functionalities comprise an ethynyl and a tetracyclone. Nanoporosity is preferably introduced by thermolyzing one or more thermolabile portions in the crosslinked polymer. An especially preferred thermolabile portion comprises ethylene glycol-poly(caprolactone).Type: GrantFiled: April 6, 2000Date of Patent: January 9, 2001Assignee: Honeywell International Inc.Inventors: Kreisler Lau, Tian-An Chen, Roger Leung
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Patent number: 6166151Abstract: A lactone chain-extended polyester polyol of the present invention comprises the reaction product of a lactone and a previously chain-extended phenolic-based hydroxyl compound. The previously chain-extended phenolic-based hydroxyl compound may comprise the reaction product of (i) a lactone or an alkoxylating agent selected from the group consisting of alkylene oxides and alkylene carbonates, and (ii) a phenolic aralkylation polymer comprising the reaction product of a phenolic monomer having at least two free reactive positions; a styrene derivative; and a coupling agent. The previously chain-extended phenolic-based hydroxyl compound also may be chain-extended by reacting with a lactam to produce a lactam chain-extended polyester polyamide. The polyols and polyamides of the present invention provide unique combinations of hard and soft functionalities, which translates into materials exhibiting a unique combination of toughness and hardness.Type: GrantFiled: June 22, 1999Date of Patent: December 26, 2000Assignee: Georgia-Pacific Resins, Inc.Inventors: Rajan Hariharan, David A. Hutchings, Kenneth A. Bourlier, Ellen V. Nagy
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Patent number: 6156812Abstract: Compositions and methods are provided in which nanoporous polymeric materials are produced via stable, polymeric template strands having reactive groups that can be used for forming crosslinking functionalities and/or adding thermolabile groups, wherein at least some of the thermolabile groups are thermolyzed to produce voids. The template strands preferably comprise aromatic systems and vicinal keto groups, such as a polybenzil formed from fluorene bisphenol or 3,3'-dihydroxytolane with 4,4'-difluorobenzil. At least some of the reactive groups preferably react using an addition-elimination reaction. Especially preferred thermolabile groups comprise poly(propylene oxide), and especially preferred crosslinkers comprise ethynyl-moiety and tetracyclone moieties.Type: GrantFiled: April 6, 2000Date of Patent: December 5, 2000Assignee: Honeywell International Inc.Inventors: Kreisler Lau, Tian-An Chen, Boris Korolev
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Patent number: 6136929Abstract: Polyarylene ether for optical communications, expressed by the formula 1: ##STR1## The polyarylene ether has excellent resistance to heat and film processing properties and the light absorption loss in the wavelength range for optical communications is low. Also, by controlling the copolymerization ratio of a monomer whose hydrogen of C--H bond is substituted by F and a monomer whose hydrogen of C--H bond is substituted by Cl, the refractive index of the polymer can be adjusted to a level suitable for an optical material used for optical communications.Type: GrantFiled: September 4, 1998Date of Patent: October 24, 2000Assignee: SamSung Electronics Co., Ltd.Inventors: Kwan-soo Han, Woo-hyuk Jang, Eun-ji Kim, Tae-hyung Rhee
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Patent number: 6133403Abstract: Disclosed are acid hardenable phenolic resin compositions and novolac compositions modified with about 5 to about 15% by weight of at least one reactive diluent selected from the group consisting of benzylic alcohol, benzylic ether, ethylene glycol, 1,3-butylene glycol, monoallyl or methylallyl ethers of poly(methylol) alkanes, monoallyl ether of glycerine, allyl or methallyl glycidyl ether, N-acylated arylamine, N-acylated naphthylamine, N-substituted arylsulfonamide, and N-substituted arylamine. The reactive diluent can be used to improve impact resistance and flexibility of the acid hardenable phenolic resin. Preferably, the methods for modifying mix life of acid hardenable phenolic resin by use of aryl phosphite and benzylic alcohol, and methods for modifying novolac resins, as well as methods for making the present compositions and products, such as coiled filament pipe and laminate panels, employing the compositions are also disclosed.Type: GrantFiled: October 7, 1998Date of Patent: October 17, 2000Assignee: Borden Chemical, Inc.Inventor: Arthur H. Gerber
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Patent number: 6124408Abstract: A novel resin composite consists of a thermosetting resin or photosensitive resin and a thermoplastic resin and has a quasi-homogeneous compatible structure not only having properties inherent to the thermosetting or photosensitive resin but also exhibiting values of properties higher than those inherent to the thermoplastic resin.Type: GrantFiled: February 26, 1999Date of Patent: September 26, 2000Assignee: Ibiden Co., Ltd.Inventors: Dong Dong Wang, Motoo Asai
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Patent number: 6107419Abstract: Present invention relates to a process for preparing a high molecular weight epoxy resin which has a weight average molecular weight value more than 40,000 and an epoxy equivalent weight less than 10,000 g/eq. This high molecular weight epoxy is prepared by a reaction of a divalent epoxy resin with a bisphenol compound in the presence of a catalyst and a solvent characterized in utilizing 1.10 to 1.03/1 of molar ratio of epoxy group/phenolic hydroxyl group.Type: GrantFiled: December 10, 1997Date of Patent: August 22, 2000Assignee: Shell Oil CompanyInventors: Yoshikazu Kobayashi, Takaya Shinmura, Yojiro Yamamoto
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Patent number: 6072010Abstract: A thermoplastic resin composition containing a polyetherimide resin, a siloxane-polyetherimide copolymer and a branched polycarbonate resin exhibits exhibit high heat distortion temperature, improved room temperature impact properties and improved impact strength and ductility at low temperatures.Type: GrantFiled: December 23, 1997Date of Patent: June 6, 2000Assignee: General Electric Co.Inventor: Robert Puyenbroek
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Patent number: 6060170Abstract: This invention is a novel combination of crosslinking groups, which grafted to the backbone of thermally stable polymers, can be thermally induced to crosslink the polymers, affording a thermoset polymer system. This invention is particularly suited for high Tg polymers where the desired temperature for crosslinking reaction (cure) is in the range of 200-450.degree. C. This invention utilizes a graft technique to attach various diarylhydroxymethyl and 9-(9-hydroxyfluorenyl) groups to poly(arylene ether) polymer backbone. Upon thermal treatment of the modified (grafted) polymer at temperatures of 200-450.degree. C., crosslinking reactions take place, resulting in a thermoset polymer with increased Tg and elastic modulus above the Tg.Type: GrantFiled: February 25, 1998Date of Patent: May 9, 2000Assignee: Air Products and Chemicals, Inc.Inventor: William Franklin Burgoyne, Jr.
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Patent number: 6051661Abstract: Thermoplastic molding compositions modified with carboxyl groups and comprising:A) at least one polyarylene ether andB) if desired, at least one filler or reinforcing material, wherein the molding composition also includesC) at least one modified polyarylene ether which contains carboxyl groups and has recurring structural elements of the formulae I and II ##STR1## where Ar, Ar.sup.1, Ar.sup.2, Ar.sup.3, T, Z, Y, t, q, x and n are as variously defined, andR.sup.1 is H, C.sub.1 -C.sub.6 -alkyl or --(CH.sub.2).sub.n --COOH; and where the molar ratio of units of the formula I to units of the formula II is in the range from 0.05:99.95 to 99.95:0.05;the use of these molding compositions for producing films, fibers and shaped articles, and the objects produced using the molding compositions, are described.Type: GrantFiled: January 22, 1998Date of Patent: April 18, 2000Assignee: BASF AktiengesellschaftInventors: Martin Weber, Karin Elbl-Weiser
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Patent number: 6048945Abstract: A graft polymer obtained by free radically polymerizing:(A) a monomer or monomer mixture comprising:(a) from 10-100% by weight of a N-vinylcarboxamide of the formula: ##STR1## where R.sup.1 and R.sup.2 are each H or C.sub.1 -C.sub.6 -alkyl, (b) from 0-90% by weight of at least one other monoethylenically unsaturated monomer which is copolymerizable with (a), and(c) from 0-5% by weight of at least one monomer having at least two ethylenically unsaturated nonconjugated double bonds in the molecule, in the presence of(B) a polytetrahydrofuran or a polymer which contains at least 3 units of a C.sub.2 -C.sub.4 alkylene oxide and is a hornopolymer of C.sub.2-4 -alkylene oxide having two free terminal OH groups or random or block copolymers of C.sub.2-4 -alkylene oxides having two free terminal OH groups or the reaction products of C.sub.Type: GrantFiled: November 3, 1997Date of Patent: April 11, 2000Assignee: BASF AktiengesellschaftInventors: Walter Denzinger, Martin Rubenacker, Claudia Nilz, Primoz Lorencak, Dietmar Monch, Rudolf Schuhmacher, Andreas Stange
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Patent number: 6048948Abstract: There is a provided a method to produce a polymer composite material in which the rigid polymer (R.sub.m).sup.n is dispersed uniformly at the molecular level in the flexible polymer (M), preferably by both polymerization with no solvent in the molten and mixed state and subsequent polymerization in the solid state. According to the preferred embodiment of the present invention, the polymer composite material is produced by polymerization with no solvent in the molten and mixed state. In the case that the rigid polymer is polymerized from the monomer having a slow polymerization rate, in order to prevent roughness of the rigid polymer during polymerization, the polymerization in the molten state is stopped at the polymerization degree equal to that of an oligomer and the resulting composite is subsequently polymerized in the solid state to increase the polymerization degree of the rigid polymer.Type: GrantFiled: September 19, 1997Date of Patent: April 11, 2000Assignee: Mazda Motor CorporationInventor: Takahiro Tochioka
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Patent number: 6037410Abstract: The invention relates to process for the manufacture of a semi-transparent thermoplastic composition of a polyphenylene ether resin and a styrenic radial block copolymer. The compositions made by the process of the invention may also contain crystal polystyrene resin and exhibit enhanced physical properties, especially ductility. The invention also relates to articles formed out of the compositions made by the process of the invention.Type: GrantFiled: January 6, 1998Date of Patent: March 14, 2000Assignee: General Electric Co.Inventors: Adeyinka Adedeji, Johan Masschelein
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Patent number: 6034185Abstract: This invention relates to an epoxy resin composition which comprises polyalkyl phenol resins or polyalkyl phenol epoxy resins or both, wherein the polyalkyl phenol resins are represented by formula (I): ##STR1## wherein Ra, Rb and Rc may be the same or different from each other and stand for C.sub.1-5 alkyl styryl or halogen respectively;n is an integer of 0 to 4;k is an integer of 0 to 3;l is an integer of 0 to 4; andm is an integer of 1 to 10;and the polyalkyl phenol epoxy resins, which are obtained by reacting polyalkyl phenol resins of formula (I) with epihalohydrins, are represented by formula (II): ##STR2## wherein G stands for ##STR3## while the other symbols are the same as those defined above. The epoxy resin composition of this invention is able to provide a reactivity at lower temperatures and provide lower viscosity when used as hardener resins, as compared with traditional phenolic novolacs.Type: GrantFiled: October 6, 1997Date of Patent: March 7, 2000Assignee: Chang Chun Plastics Co., Ltd.Inventors: Kuen-Yuan Hwang, Hong-Hsing Chen, Biing Lu Perng, Shang Wen Chen
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Patent number: 6020119Abstract: Disclosed is a process which comprises reacting a polymer of the general formula ##STR1## or ##STR2## wherein x is an integer of 0 or 1, A is one of several specified groups, such as ##STR3## B is one of several specified groups, such as or mixtures thereof, and n is an integer representing the number of repeating monomer units, with a halomethylethyl ether, a hydrohalic acid, and acetic acid in the presence of a halogen-containing Lewis acid catalyst, thereby forming a halomethylated polymer.Type: GrantFiled: May 17, 1999Date of Patent: February 1, 2000Assignee: Xerox CorporationInventors: Daniel A. Foucher, Nancy C. Stoffel, Roger T. Janezic, Thomas W. Smith, David J. Luca, Bidan Zhang
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Patent number: 6013761Abstract: A process for the preparation of polyarylene sulfoxides, in which polyarylene sulfide, suspends in a concentrated acid of formula R--SO.sub.3 H, in which R is a halogen atom Ian OH group, an aliphatic radical having 1 to 6 C atoms or an aromatic radcal having 6 to 18 C atoms, or of the formula R.sup.1 --CR.sup.2 R.sup.3 --COOH, in which R.sup.1 is a halogen atom and R.sup.2 and R.sup.3, independently of one another are each a halogen atom, an aliphatic radical having 1 to 50 atoms or a halogenated aliphatic radical having 1 to 5 C atoms, is oxidized by metering in a 30 to 85% strength hydrogen peroxide solution with thorough mixing and at a temperature of from -20 to +45.degree. C. According to this process, the sulfide units of the polyarylene sulfide are converted virtually selectively and completely into sulfoxide units.Type: GrantFiled: November 19, 1998Date of Patent: January 11, 2000Assignee: Ticona GmbHInventors: Dirk Zierer, Helmut Scheckenbach
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Patent number: 6011122Abstract: A thermoplastic resin composition containing a polyetherimide resin, a siloxane-polyetherimide copolymer and a branched polycarbonate resin exhibits exhibit high heat distortion temperature, improved room temperature impact properties and improved impact strength and ductility at low temperatures.Type: GrantFiled: January 5, 1999Date of Patent: January 4, 2000Assignee: General Electric CompanyInventor: Robert Puyenbroek
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Patent number: 6007877Abstract: Disclosed is a composition which comprises a polymer containing at least some monomer repeat units with water-solubility- or water-dispersability-imparting substituents and at least some monomer repeat units with photosensitivity-imparting substituents which enable crosslinking or chain extension of the polymer upon exposure to actinic radiation, said polymer being of the formula ##STR1## wherein x is an integer of 0 or 1, A is one of several specified groups, such as ##STR2## B is one of several specified groups, such as ##STR3## or mixtures thereof, and n is an integer representing the number of repeating monomer units. In one embodiment, a single functional group imparts both photosensitivity and water solubility or dispersability to the polymer. In another embodiment, a first functional group imparts photosensitivity to the polymer and a second functional group imparts water solubility or dispersability to the polymer.Type: GrantFiled: August 29, 1996Date of Patent: December 28, 1999Assignee: Xerox CorporationInventors: Ram S. Narang, Timothy J. Fuller
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Patent number: 5998533Abstract: Polyarylene ethers having repeating units of the general formula I ##STR1## where t and q may each be an integer 0, 1, 2 or 3,T, Q and Z may each be a chemical bond or a group selected from --O--, --S--, --SO.sub.2 --, S.dbd.O, C.dbd.O, --N.dbd.N--, --R.sup.a C.dbd.CR.sup.b -- and --CR.sup.c R.sup.d --, with the proviso that at least one of the groups T, Q or Z is --SO.sub.2 -- or C--O and, if t and q are 0, Z is --SO.sub.2 -- or C.dbd.O,R.sup.a and R.sup.b are each hydrogen or C.sub.1 -C.sub.10 -alkyl,R.sup.c and R.sup.d are each hydrogen, C.sub.1 -C.sub.10 -alkyl, C.sub.1 -C.sub.10 -alkoxy or C.sub.6 -C.sub.18 -aryl, where the abovementioned groups may each be substituted by fluorine and/or chlorine, or, together with the carbon atom to which they are bonded, form a C.sub.4 -C.sub.7 -cycloalkyl group which may be substituted by one or more C.sub.1 -C.sub.6 -alkyl groups, andAr and Ar.sup.1 are each C.sub.6 -C.sub.18 -aryl which may be unsubstituted or substituted by C.sub.1 -C.sub.10 -alkyl, C.sub.6 -C.sub.Type: GrantFiled: December 11, 1997Date of Patent: December 7, 1999Assignee: BASF AktiengesellschaftInventors: Martin Weber, Christian Fischer
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Patent number: 5994480Abstract: A novel resin composite consists of a thermosetting resin or photosensitive resin and a thermoplastic resin and has a quasi-homogeneous compatible structure not only having properties inherent to the thermosetting or photosensitive resin but also exhibiting values of properties higher than those inherent to the thermoplastic resin.Type: GrantFiled: September 30, 1997Date of Patent: November 30, 1999Assignee: Ibiden Co., Ltd.Inventors: Dong Dong Wang, Motoo Asai
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Patent number: 5990261Abstract: A low birefringent organic optical component prepared from a resin consisting essentially of one or more repetitive structural units selected from the group consisting of structures represented by general formula (1); ##STR1## wherein A is either of the groups below. ##STR2## The organic optical component can exhibit excellent transparency, heat resistance and mechanical strength as well as a low birefringence. Also provided is a novel aromatic polyamide with a low permitivity and excellent transparency, processability and thermal stability, besides excellent heat resistance inherent in an aromatic polyamide.Type: GrantFiled: August 26, 1997Date of Patent: November 23, 1999Assignee: Mitsui Chemicals, Inc.Inventors: Wataru Yamashita, Tomomi Yoshimura, Atsushi Shibuya, Yoshihiro Sakata, Hideaki Oikawa, Keisuke Takuma, Masahiro Ohta
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Patent number: 5973072Abstract: The present invention is directed to a polymeric vehicle, the formulated coating composition and a coating binder made from the polymeric vehicle and a method for making the polymeric vehicle where the polymeric vehicle includes a phenolic urethane reactive diluent. The phenolic urethane reactive diluent may be made from a phenolic ester alcohol having at least one aliphatic hydroxyl group.Type: GrantFiled: March 21, 1996Date of Patent: October 26, 1999Assignee: Exxon Chemical Patents, Inc.Inventors: Frank N. Jones, Vijay Swarup, Ramachandran P. Subrayan, Suru Zhang
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Patent number: 5969054Abstract: The present invention relates to binder compositions containingA) 40 to 95 parts by weight of OH-functional graft copolymer resins prepared by copolymerizinga) 0.1 to 10 parts by weight of polybutadienes containing at least 20% of 1,2-vinyl groups,b) 5 to 30 parts by weight of aliphatic .alpha.-olefins,c) 0.1 to 35 parts by weight of glycidyl esters of .alpha.-alkylalkane-monocarboxylic acids,d) 10 to 70 parts by weight of unsaturated, aromatic monomers,e) 5 to 60 parts by weight of hydroxyalkyl esters of acrylic and/or methacrylic acid having primary hydroxyl groups,f) 0 to 50 parts by weight of (cyclo)aliphatic esters of acrylic and/or methacrylic acid,g) 0.1 to 20 parts by weight of .alpha.,.beta.Type: GrantFiled: July 7, 1997Date of Patent: October 19, 1999Assignee: Bayer AktiengesellschaftInventors: Christian Wamprecht, Michael Sonntag, Dieter Margotte