Abstract: A block copolymer comprising at least one segment having an acid group and at least one segment substantially free from acid groups is provided wherein the segment substantially free from acid groups contains a structure of the following general formula (1): Ar1—Z—Ar2—O—Ar3—Om??(1) (wherein, m represents an integer of 10 or more, Ar1, Ar2 and Ar3 represent mutually independently a divalent aromatic group which may be substituted by an alkyl group having 1 to 10 carbon atoms, an alkoxy group having 1 to 10 carbon atoms, an aryl group having 6 to 10 carbon atoms or an aryloxy group having 6 to 10 carbon atoms, and Z represents —CO— or —SO2—, each Z in the segments representing independently —CO— or —SO2—). The block copolymer exhibits more excellent performances as a polymer electrolyte for fuel cells or the like.

Abstract: The present invention provides a phenol resin composition which imparts excellent heat resistance and flame retardancy in a cured article, the cured article, a resin composition for a copper-clad laminate, and a copper-clad laminate having both excellent heat resistance and flame retardancy. Disclosed is a phenol resin composition comprising a phenol resin (I) having a chemical structure (A) represented by structural formula (1) shown below in which an aromatic hydrocarbon group substituted with a carboxyl group is bonded to a triazine ring, as a partial structure in the molecular structure, and a curing agent (II) as essential components.

Abstract: One embodiment includes a dry adhesive material including catechol chemically attached to the surface of a shape memory polymer molecule. The catechol content may allow the dry adhesive to be utilized in both dry and wet conditions to bond objects together. The shape memory polymer may allow the dry adhesive to be reversibly attached to the objects.

Abstract: A halogenated aromatic polymer has between 2 and 100 monomer units each comprising an aromatic group substituted with at least one halide group, wherein at least one of said monomer units has the following formula (I): —Ar1-A-(Ar2-B)y-(Ar3-C)z-??(I) wherein Ar1, Ar2 and Ar3 are the same or different and each is an aromatic group substituted with at least one halide group; A is selected from CO, CO2, S, SO2, a single bond, and a C1 to C6 alkyl chain; B and C are the same or different and each is selected from O, CO, CO2, CO3, S, SO2, a single bond, and a C1 to C6 alkyl chain; and each of y and z is independently zero or 1.

Abstract: The present invention relates to thermoset resin fibre components, composite materials comprising thermoset resin fibre components, composite articles manufactured using such composite materials and methodologies for manufacturing same. The thermoset resin fibre components may comprise a single fibre of thermoset resin or a plurality of fibres commingled together. There properties and characteristics of the thermoset resin used are chosen according to the material to be produced therefrom. The thermoset fibre components may be woven into reinforcement fibres to form prepregs. Thermoplastic fibres may be commingled and co-woven with the thermoset fibre components.

Abstract: An oligomer having di-phenylethynyl endcaps is disclosed. The capped oligomer has the formula: D-A-D wherein D is a di-phenylethynyl endcap; and A is an oligomer selected from the group consisting of imidesulfone; ether; ethersulfone; amide; imide; ester; estersulfone; etherimide; amideimide; oxazole; oxazole sulfone; thiazole; thiazole sulfone; imidazole; and imidazole sulfone.

Abstract: Synthesis methods for creating polymeric compounds comprising dihydroxyphenyl derivatives (DHPD), or DHPp i.e. polymers modified with DHPD, with desired surface active effects are described. The polymer backbone of DHPp has structural or performance features that can be tailored to control physical properties of DHPp, allowing it to be useful for different applications i.e. tissue adhesives or sealants, adhesion promoting coatings, and antifouling coatings.

Abstract: Aromatic hydrogenated polymers comprising perfluoropolyether (PIPE) chains bonded to the aromatic rings to form sequences randomly distributed in the polymer structure, having the formula (I): (T1-CF2O—Rf—CF2)n-T3 in which: n is an integer from 1 to 10; T1 is an aromatic group of the backbone of the hydrogenated polymer, or alternatively condensed aromatic groups; T3 may be equal to T1, or alternatively a functional group —COOH or —COF; Rf is a (per)fluoropolyoxyalkylene chain, in which the starting hydrogenated aromatic polymers are obtained by polycondensation, stepwise polyaddition or polyaddition of cyclic monomers in which the ring is formed by at least 3 atoms.

Abstract: A sulfonated poly(arylene sulfone) contains an unsaturated bond. A cross-linked material may be formed from the sulfonated poly(arylene sulfone), and a clay nanocomposite may include the sulfonated poly(arylene sulfone) or the cross-linked material. A fuel cell includes the clay nanocomposite.

Abstract: The present invention relates to novel adducts useful for improving the toughness and curable compositions using such toughening adducts. In a particular aspect, the present invention relates to novel toughening adducts and thermosetting resin formulations having improved fracture toughness using those toughening adducts.

Abstract: A compound containing a crosslinkable moiety, a curable prepolymer, a blend, and a polymer sheet obtained therefrom, and an optical waveguide for optical interconnection. The compound is represented by the formula below: Ar—H wherein Ar includes a crosslinkable moiety at one end, a moiety selected from the group consisting of —O—, —S—, —COO—, —CO—, —COS—, —SO2—, and —NH—, and one or two repeating units selected from the group consisting of the following repeating units: wherein A in the repeating unit is carbon or nitrogen, and X is hydrogen or halogen. At least one of the core and the cladding in the optical waveguide includes the polymer sheet.

Abstract: Compositions comprising blends of polyphenylene and poly(aryl ether sulfone) and methods for making such blends are disclosed. Miscible blends of polyphenylene and poly(aryl ether sulfone) are also disclosed. The blends are useful in numerous applications such as in the preparation of articles and of foams having reduced density.

Abstract: A sulfonated polyUrylene ether) copolymer, a method of preparing the same, and a polymer electrolyte membrane using the sulfonated poly(arylene ether) copolymer are provided. A sulfonated poly(arylene ether) copolymer containing a sulfonic acid is synthesized by poly condensing a dihydroxy monomer having a sulfonate group with a dihalide monomer, or by polycondensing a dihalide monomer having a sulfonate group with a dihydroxy monomer. Moreover, a crosslinkable dihydroxy monomer or a crosslinkable dihalide monomer is polycondensed with the obtained poly(arylene ether) copolymer, thus enable crosslinking between polymers.

Abstract: Polymer bonding compositions having greater than about 1 milliequivalent primary amine/100 grams of the polymer, more preferably greater than about 3 milliequivalent non-tertiary amine/100 grams of the polymer. Preferably the polymer is not significantly crosslinked. These bonding compositions may be especially useful for bonding fluropolymers. Processes for making the novel polymers and the resulting multilayer bonded articles are described. The polymers include polymer-bonded ZNHLSi(OP)a(X)3-a-b(Y)b units. The bonding composition may be used for making multi-layer polymer laminates such as tubes and films and containers.

Abstract: The present invention relates to an organic spin coatable antireflective coating composition comprising with (i) at least one unit with fused aromatic rings in the backbone of the polymer of structure (1), (ii) at least one aromatic unit ring in the backbone of the polymer of structure (2) where the aromatic ring has a pendant alkylene(fusedaromatic) group and a pendant hydroxy group, and, (iii) at least one unit with an aliphatic moiety in the backbone of the polymer of structure (3). where, Fr1 is a substituted or unsubstituted fused aromatic ring moiety with 3 or more fused aromatic rings, Fr2 is a fused aromatic ring moiety with 2 or more fused aromatic rings, Ar is a substituted or unsubstituted aromatic ring moiety, R? and R? are independently selected from hydrogen and C1-C4 alkyl, y=1-4, and B is a substituted or unsubstituted aliphatic moiety, and R1 is selected from hydrogen or aromatic moiety. The invention further relates to a process for imaging the present composition.

Abstract: Disclosed is a halogen-free resin composition for printed wiring board production, which is remarkably reduced in quality deterioration due to moisture absorption of a semi-cured resin film (layer). Also disclosed is a copper film with resin or the like. The resin composition is characterized by containing a component A (one or more resins selected from the group consisting of bisphenol-A epoxy resins, bisphenol-F epoxy resins and bisphenol-AD epoxy resins, which have an epoxy equivalent of not more than 200, while being in a liquid state at 25 DEG C.), a component B (a linear polymer having a crosslinkable functional group), a component C (a crosslinking agent), a component D (an imidazole-based epoxy resin curing agent) and a component E (a phosphorus-containing epoxy resin). The resin composition is also characterized by containing 0.5-3.0% by weight of phosphorus atoms per 100% by weight of the resin composition. In the copper foil with resin, a resin layer is formed by using the resin composition.

Abstract: In accordance with the present invention, it has now been found that glycidyl epoxy resins containing substitution on the epoxide ring can be used with conventional epoxy curing agents and fluxing agents to produce underfill adhesives that are suitable for use with silver-based alloys. Owing to the structural similarity of the new materials to conventional epoxy resins, physical and material properties of the invention formulations are altered little, if at all, relative to products currently in use, and so are highly compatible with existing processes.

Abstract: A method for making a polysulfone having zwitterionic functionality comprising reacting a piperazine amine functionalized polysulfone with sultone is described as are blends with other polymers. Membranes containing polysulfones having zwitterionic functionality are also provided. Membranes thus formed are used in hemodialysis, hemofiltration, and water purification.

Abstract: A method for making a polyarylether having amide functionality includes reacting a dihydroxyaromatic compound having amide functionality with a dihaloaromatic sulfone or dinitroaromatic sulfone in the presence of a base. Polyarylethers having amide functionality and blends are also provided.

Abstract: A method for making a polyarylether block copolymer having amide functionality including reacting a dihydroxyaromatic compound having amide functionality and a dihaloaromatic sulfone or dinitroaromatic sulfone in the presence of a base to form a polyarylether having amide functionality and reacting the polyarylether having amide functionality with a polymer. The block copolymer and blends are also provided.

Abstract: A composition including a polyarylether copolymer is provided. The copolymer includes a polyarylether backbone; and a sulfonated oligomeric group bonded to the polyarylether suitable for use as a cation conducting membrane. Method of bonding a sulfonated oligomeric group to the polyarylether backbone to form a polyarylether copolymer. The membrane may be formed from the polyarylether copolymer composition. The chain length of the sulfonated oligomeric group may be controlled to affect or control the ion conductivity of the membrane.

Abstract: The invention provides novel metal oxide particles on which carbon nanotubes are supported. Needle- or flake-like crystalline metal oxide particles characterized in that carbon nanotubes grown parallel to each other in the direction nearly perpendicular to the surface of each particle are supported on the surfaces of the particles and that the carbon nanotubes supported on the particles are 1 to 500 ?m in length in the direction nearly perpendicular to the surface of each particle.

Abstract: A blend of epoxy resins includes a) an epoxy resin composition derived from the reaction of a liquid epoxy resin, a carboxyl terminated butadiene (CTB), and a carboxyl terminated polybutadiene-acrylonitrile (CTBN) and/or a random and terminal carboxyl functional polybutadiene-acrylonitrile (CTBNX), and b) unreacted epoxy resin. The carboxyl terminated butadiene is miscible with the unreacted epoxy resin and does not separate therefrom even upon aging. Upon cure as with a latent cure agent, a toughened epoxy resin is produced having unexpected good low temperature properties such as peel strength.

Abstract: A fuel cell separator material which exhibits a high fracture strain and a high strength, prevents breakage during cell stack assembly or cracking during a cell operation, and exhibits excellent properties such as conductivity and gas impermeability, and a method of producing the same are provided. The fuel cell separator material includes a carbon/cured resin molded product in which a carbon powder is bound with a binder which comprises a mixed resin of a bifunctional aliphatic alcohol ether-type epoxy resin and a polyfunctional phenol-type epoxy resin, a phenol resin curing agent, and a curing accelerator as essential components.

Abstract: The present invention provides Mannich base derivatives of N,N?-dimethyl secondary diamine polymers including Mannich base derivatives of methylamine-terminated poly-(N-methylazetidine) and Mannich base derivatives of methylamine-terminated poly-(N-methylazacycloheptane). Amine curing agent compositions and amine-epoxy compositions containing Mannich base derivatives of N,N?-dimethyl secondary diamine polymers are also disclosed.

Abstract: Disclosed is a sulfonated multiblock copolymer, which comprises a hydrophilic block (X) having a repeating unit represented by the following formula 1a, and a hydrophobic block (Y) having a repeating unit represented by the following formula 2, wherein the number (m) of the repeating unit of formula 1a in the hydrophilic block (X) and the number (n) of the repeating unit of formula 2 in the hydrophobic block (Y) satisfy the conditions of 4?m?400 and 4?n?400.

Abstract: Process for preparing polymeric aromatic phosphonates and also polymeric aromatic phosphonates which can be prepared by the process of the invention and blends comprising these polymeric aromatic phosphonates and at least one further polymer and also films, composites and membranes comprising these polymers or blends, the use of the membranes of the invention in fuel cells or in separation technology and also fuel cells comprising the membranes of the invention.

Abstract: A synthetic nucleus pulposus is provided that is useful in treatment of degenerative disc disease, augmentation of a degenerate disc, and alleviation of back pain. In an embodiment the synthetic nucleus pulposus comprises hyaluronan macromolecules that have been cross-linked via dihydroxyphenyl linkages. The synthetic nucleus pulposus restores or improves the water-retention capability of the disc. A method of treating an intervertebral disc with the cross-linked hyaluronan macromolecules is also provided. A method of regenerative therapy to address loss of cells of nucleus pulposus of an intervertebral disc based on treatment with the cross-linked hyaluronan macromolecules and mesenchymal stem cells is also provided.

Abstract: A flexibilized resorcinolic novolak resin is prepared by reacting a phenolic compound, such as resorcinol, with an unsaturated dihydroxy, an unsaturated aldehyde, an aliphatic dialdehyde, or a mixture thereof. An aldehyde (different from the unsaturated aldehyde and the aliphatic dialdehyde) is either simultaneously or subsequently added to the reaction mixture. The flexibilized resorcinolic novolak resin can be used in an adhesive composition for enhancing the adhesion between tire cords and rubber for tire applications.

Abstract: The invention provides methods and compositions having one-dimensional nanoparticle chains. A one-dimensional nanoparticle chain can comprise a linear substantially non-crosslinked polymer having pendant groups and asymmetrically functionalized nanoparticles attached to the polymer through the pendant groups. Additionally, an asymmetrically functionalized nanoparticle can comprise a nanoparticle core having an outer surface, a primary group of first ligands attached to a substantially continuous primary region of the outer surface, and a secondary group of second ligands attached to a substantially continuous secondary region of the outer surface, such that the primary group of first ligands and the secondary group of second ligands comprise a different ligand population.

Abstract: An optical disc of the present invention includes at least a light reflection layer and a light transmission layer formed on a substrate, wherein recording and reading are performed by a laser beam through the light transmission layer, the light transmission layer is formed from a cured film of a ultraviolet-curable composition containing an epoxy acrylate resin obtained by reacting a half ester compound (A), which is obtained from a lactone-adduct of a hydroxyalkyl (meth)acrylate (a1) and a dibasic acid anhydride (a2), and an epoxy resin (B), and the film thickness of the light transmission layer is from 50 to 150 ?m.

Abstract: In an epoxy resin having a low viscosity and excellent water resistance, an epoxy resin composition having the same, a paint composition and a method of forming a coating layer using the same, the epoxy resin composition includes an epoxy resin prepared by a reaction of a cashew nut shell liquid (CNSL) selected from cardol, cardanol, anacardic and an alkyl cardol, and a haloalkylene oxide. The paint composition having such epoxy resin composition may have excellent working efficiency and low-temperature curability, and may form a coating layer having improved water resistance.

Abstract: A redispersible polymer powder including: a polymer to be redispersed; and an ortho-cresol based condensation product or salt thereof; wherein the ortho-cresol based condensation product or salt thereof includes N-containing units derived from a N-based component incorporated into the ortho-cresol based condensation product or salt thereof during polymerisation.

Abstract: An inexpensive and durable polyelectrolyte composition includes both an aromatic polymer containing carbonyl linkages and/or sulfonyl linkages in the backbone chain and bearing cation-exchange groups and a fused salt exhibits a high ionic conductivity even in the absence of water or a solvent. The aromatic polymer is preferably an aromatic polyether sulfone comprising specific structural units and bearing cation-exchange groups, an aromatic polyether ketone comprising specific structural units and bearing cation-exchange groups, an aromatic polyether sulfone block copolymer consisting of at least one hydrophilic segment bearing cation-exchange groups and at least one hydrophobic segment free from cation-exchange groups, and/or an aromatic polyether ketone block copolymer consisting of at least one hydrophilic segment bearing cation-exchange groups and at least one hydrophobic segment free from cation-exchange groups.

Abstract: A polymer composition includes an aromatic ring-containing polymer represented by Formula 1: wherein m and n satisfy the relations 1?m<190, 0?n<190, and 1?m+n<190.

Abstract: A process is provided for the production of diaryl alkyl phosphonate by the reaction of triaryl phosphate with dialkyl alkyl phosphonate in the presence of alkali metal iodide catalyst; and, optionally, the diaryl alkyl phosphonate is reacted in situ with aromatic diol and, optionally, with at least one branching monomer, in the absence of other or further added catalyst to provide oligomeric and/or polymeric phosphonate products.

Abstract: Process for preparing polyether alcohols by polymerization by means of double metal cyanide catalysts (DMC catalysts), characterized in that, before or during the polymerization, one or more, optionally mixed additives consisting of compounds having one or more aromatic structures which may be monosubstituted or else polysubstituted and which have at least one hydroxyl group on the aromatic system are added to the reaction mixture.

Abstract: Disclosed is an episulfide group-substituted silicon compound (A) having a backbone structure represented by the following formula (1). (1) (In the formula, R1s respectively represent a substituent having an episulfide group, an unsubstituted or unsaturated acyloxy group-substituted (C1-C10) alkyl group or an aryl group. R1s may be the same as or different from one another, but at least one R1 in a molecule is a substituent having an episulfide group.

Abstract: Disclosed is a phenol aralkyl epoxy resin having a structure wherein at least a phenol or a naphthol is bound by using an aralkyl group as a linking group and a structure represented by formula (1) below, while satisfying the condition 1 below. This epoxy resin is excellent in workability during production of a composition and is easy to control quality. Condition 1: The following relation (?) is satisfied with A being the hydroxyl equivalent (as measured in accordance with JIS K 0070) of a phenol-modified epoxy resin obtained by adding an equivalent molar amount of phenol relative to the epoxy equivalent of the epoxy resin, and B being the epoxy equivalent of the epoxy resin.

Abstract: An object of the invention is to provide a functionalized polyphenylene ether useful for polymer alloys or electrical or electronic materials such as printed boards or insulating sealants. The invention relates to a functionalized polyphenylene ether having an average of not fewer than 0.1 unit of a structure represented by the following formula (1) per molecular chain: wherein n is an integer of 9 or more, R1 is an organic substituent having an epoxy group, and R2 is a hydrogen atom or an organic substituent having an epoxy group.

Abstract: New, highly effective substantially pure Mannich detergents for use in hydrocarbon fuels reduce engine deposits in spark and compression ignition internal combustion engines. The Mannich condensation reaction products are obtainable by reacting: (i) a polyamine having primary amino groups, (ii) a hydrocarbyl-substituted hydroxyaromatic compound, and (iii) an aldehyde, wherein the reaction is conducted at in a molar ratio of (i):(ii):(iii) of approximately 1:2:3 or 1:1:2. The Mannich detergent compounds may be dispersed in a liquid carrier to provide a fuel additive concentrate for hydrocarbon engine fuels which effectively control engine deposit formation in intake valves, port fuel injectors and combustion chambers.

Abstract: The invention relates to an epoxy resin composition for sealing comprising (A) an epoxy resin, and (B) a curing agent, wherein the following is comprised as the curing agent (B): (C) a compound or compounds represented by the following general formula (I) in which n is or n's are each an integer of 1 to 10, and m is or m's are each an integer of 1 to 10: wherein R1 is selected from a hydrogen atom and substituted or unsubstituted monovalent hydrocarbon groups having 1 to 10 carbon atoms, and R2 is selected from a hydrogen atom and substituted or unsubstituted monovalent hydrocarbon groups having 1 to 10 carbon atoms. This makes it possible to provide a halogen-free and antimony-free epoxy resin composition for sealing which is good in flame retardancy without lowering reliabilities, such as moldability, reflow resistance, humidity resistance and high-temperature-standing property, and an electron component device equipped with an element sealed with this composition.

Abstract: To provide an adamantane derivative, a compound having an adamantane skeleton, compositions containing them that can provide a cured product having excellent optical properties such as transparency and light resistance, long-term heat resistance and electric characteristics such as dielectric permittivity, and optical electronic members using the compositions. An adamantane derivative represented by the general formula (I), a compound with an adamantane skeleton represented by the general formula (VII) or (VIII), compositions containing them, and optical electronic members using the resin compositions.

Abstract: Insoluble polyphosphonates produced via a transesterification process, methods for preparing such insoluble polyphosphonates and polymer compositions and articles of manufacture including such insoluble polyphosphonates are described herein.

Abstract: The present invention relates to a process for preparing 2-alkylpolyisobutenylphenols and their Mannich adducts, to compositions obtainable by this process and to their use.

Abstract: The present invention provides curing agent compositions comprising benzylated polyalkylene polyamine compounds. Amine-epoxy compositions and articles produced from these amine-epoxy compositions are also disclosed.

Abstract: An encapsulant for encapsulating electronic components and a method of making and/or using the encapsulant may be provided. An electronic device that includes the encapsulant may be provided. The curable encapsulant composition may include a mixture of a functionalized polymer and at least one reactive monomer composition. The reactive monomer composition may include a reactive monomer component that may be a low temperature solid and may be present in an amount in the reactive monomer composition a range of greater than about 20 weight percent based on the total weight of reactive monomer composition.

Abstract: Compositions for coating food cans comprising a film-forming resin and an amine-terminated polyamide are disclosed. Food cans coated with such a coating, and methods for coating food cans, are also disclosed.

Abstract: An organic insulator composition including a crosslinking agent and a hydroxyl group-containing oligomer or hydroxyl group-containing polymer is provided. A dielectric film and an organic thin film transistor (OTFT) using an organic insulator composition are also provided. A dielectric film may include a compound having hydroxyl group-containing oligomers or hydroxyl group-containing polymers linked by crosslinking using a crosslinking agent having at least two vinyl ether groups. An organic thin film transistor may include a gate electrode on a substrate, a gate insulating layer on the gate electrode, source and drain electrodes on the gate insulating layer and an organic semiconductor layer contacting the gate insulating layer, wherein the gate insulating layer includes an dielectric film as described above.

Abstract: A polymer composition comprising a mixture of a) a first resin component comprising a polyaryl ether ketone, a polyaryl ketone, a polyether ketone, a polyether ether ketone, or a combination of two or more of the foregoing, and b) a second resin component comprising a specific type of copolycarbonate, wherein the mixture has at least two glass transition temperatures, as measured by ASTM method D5418, wherein the first glass transition temperature is from 120 to 160° C. and the second glass transition temperature is from 170 to 280° C. is disclosed. The compositions have improved properties such as improved load bearing capability at high temperature, better impact strength, and a high crystallization temperature.