With Solid Polymer Derived From At Least One Nitrogen-containing Reactant Wherein At Least One Of The Reactants Forming The Solid Polymer Is Saturated; Or With Spfi Wherein At Least One Of The Necessary Ingredients Contains A Nitrogen Atom Or With A Reaction Product Thereof; Or With Nitrogen-containing Sicp Patents (Class 525/66)
  • Patent number: 5773511
    Abstract: The present invention relates to a coating composition which is excellent in handling and safety, enables the curing of the resultant coating composition at low temperature, and provides an excellent adhesion to polyolefin resin moldings. The coating composition comprises (1) 40-90 wt. % of a grafted and chlorinated polyolefin oligomer obtained by graft polymerizing a vinyl polymerizable monomer to a chlorinated polyolefin, the grafted and chlorinated polyolefin oligomer having a primary or blocked primary hydroxyl group at a position of 15 to 40 atoms away from the vinyl graft polymer chain grafted to the chlorinated polyolefin, a number average molecular weight of 5,000 to 50,000, 0.4 to 2.5 mole/kg-resin of a primary or blocked primary hydroxyl group, 50 to 95 wt. % of said vinyl graft polymer chain, and 5 to 50 wt. % of the chlorinated polyolefin used as a starting material, and (2) 60 to 10 wt. % of an imino-type, methylol-type or complete alkoxy-type melamine resin.
    Type: Grant
    Filed: November 20, 1995
    Date of Patent: June 30, 1998
    Assignee: Mazda Motor Corporation
    Inventors: Yoshiaki Marutani, Mika Ohsawa
  • Patent number: 5770646
    Abstract: A waterbased dispersion useful for forming aqueous coating compositions containing dispersed hydrophobic material, an aqueous carrier and a branched polymer dispersant (binder);the branched polymer has a weight average molecular weight of about 5,000-100,000 and contains 20-80% by weight of a hydrophilic backbone and correspondingly 80-20% by weight of macromonomer side chains; wherein the backbone is of polymerized ethylenically unsaturated monomers and 2-30% by weight, based on the weight of the backbone of polymerized ethylenically unsaturated monomers having an acid-functional group; and wherein at least 10% of the acid-functional groups are neutralized with an amine or an inorganic base and is hydrophilic in comparison to the side chains; andthe side chains are of macromonomers of polymerized ethylenically unsaturated monomers that are polymerized into the backbone via an ethylenically unsaturated group and the macromonomers have a weight average molecular weight of about 1,000-30,000 and wherein the wei
    Type: Grant
    Filed: October 29, 1996
    Date of Patent: June 23, 1998
    Assignee: E. I. du Pont de Nemours and Company
    Inventors: Joseph Albert Antonelli, Christopher Scopazzi, Kerstin Stranimaier
  • Patent number: 5770679
    Abstract: Polyamide resin compositions which are useful for molding parts with excellent malleability, thoughness, rigidity, and high heat deformation temperatures are prepared from 10 to 89% by weight of a polyamide resin, 1 to 30% by weight of at least one type of elastomer selected from among elastomers composed of ethylene/propylene/dienes, elastomers composed of ethylene/unsaturated carboxylic acid unsaturated carboxylic acid esters, and elastomers obtained by graft-modifying these elastomers, and from 10 to 60% by weight of a copolymer of ethylene and cyclic olefin that is noncrystalline and has a glass transition temperature of from 100.degree. to 190.degree. C.
    Type: Grant
    Filed: June 13, 1996
    Date of Patent: June 23, 1998
    Assignee: E. I. du Pont de Nemours and Company
    Inventors: Ryuichi Hayashi, Reiko Koshida
  • Patent number: 5763528
    Abstract: A coating composition of a film forming binder and an organic liquid carrier; wherein the binder contains about(a) 10-90% by weight, based on the weight of the binder, of a dispersed gelled acrylic polymer having a glass transition temperature of at least 20.degree.
    Type: Grant
    Filed: December 17, 1996
    Date of Patent: June 9, 1998
    Assignee: E. I. du Pont de Nemours and Company
    Inventors: Robert John Barsotti, Laura Ann Lewin, Christopher Scopazzi
  • Patent number: 5760125
    Abstract: A resin composition which has improved resistance to yellowing due to light without loss of the superior characteristics of polyphenylene ether polyamide resins comprises(A) a polyphenylene ether resin,(B) a polyamide resin,(C) a styrene thermoplastic resin,(D) a pigment;wherein the styrene thermoplastic resin and the pigment are dispersed in the polyphenylene ether resin and the polyphenylene ether resin is a particulate dispersion in the polyamide resin. The composition may further comprise a rubber polymer wherein the rubber polymer is dispersed in the polyphenylene ether resin.
    Type: Grant
    Filed: December 11, 1996
    Date of Patent: June 2, 1998
    Assignee: General Electric Company
    Inventors: Takashi Ohtomo, Hiromi Ishida, Hidekazu Kabaya, Hiroshi Kubo
  • Patent number: 5760105
    Abstract: There are disclosed a styrenic resin composition which comprises 1 to 95% by weight of a (a) styrenic polymer having syndiotactic configuration (SPS) or modified SPS; 1 to 95% by weight of a (b) thermoplastic resin having a polar group; 1 to 50% by weight of a (c) rubbery elastomer having an affinity for the component (a); and 0.1 to 10% by weight of a (d) compatibilizer having a polar group, a styrenic resin composition same as above except that the component (c) has a polar group capable of reacting with the component (b) as well as an affinity for the component (a) and a styrenic resin composition further comprising 1 to 350% parts by weight of an (e) inorganic filler based on 100 parts by weight of the above resin components. According to the present invention, there are obtained styrenic resin compositions that are well suited for various industrial materials and excellent in rigidity, heat resistance, impact resistance and water resistance.
    Type: Grant
    Filed: February 20, 1996
    Date of Patent: June 2, 1998
    Assignee: Idemitsu Kosan Co., Ltd.
    Inventors: Akihiko Okada, Hiroki Fukui
  • Patent number: 5760132
    Abstract: Improved thermoplastic compositions that are resistant to die beard growth are described herein, comprising poly(phenylene ether) resins, polyamide resins and an amount of a beard growth reducing agent selected from the group consisting of non-elastomeric polyolefin resins, partially fluorinated polyolefins, and mixtures of non-elastomeric polyolefin resins and partially fluorinated polyolefins, effective for inhibiting beard growth. The compositions may further comprise at least one impact modifier, flow promotor or filler.
    Type: Grant
    Filed: June 7, 1995
    Date of Patent: June 2, 1998
    Assignee: General Electric Company
    Inventors: Neil Andrew McGaughan, Gim Fun Lee, Jr., Ronald James Wroczyski, John Bennie Yates, Christiaan Henricus J. Koevoets, Jan P. Keulen, Jay Kumar Gianchandani, deceased
  • Patent number: 5760133
    Abstract: A process for the continuous production of a thermoplastic molding composition containing a mixture of a TPU and a thermoplastic (co)polymer is disclosed.
    Type: Grant
    Filed: April 17, 1996
    Date of Patent: June 2, 1998
    Assignee: Bayer Aktiengesellschaft
    Inventors: Herbert Heidingsfeld, Willi Meister, Bernhard Schulte, Wolfgang Brauer, Friedemann Muller, Hans-Georg Hoppe, Hans-Georg Wussow, Jurgen Winkler
  • Patent number: 5756576
    Abstract: The invention relates to a polymer composition comprising 5 to 79 wt. % of a graft copolymer of vinyl aromatic monomer units and monomer units chosen from the group of C.sub.1 -C.sub.4 alkyl methacrylates, C.sub.1 -C.sub.4 alkyl acrylates, methacrylonitrile and acrylonitrile on a rubber, 90 to 20 wt. % of a thermoplastic polymer with polar groups, and 1 to 50 wt. % of a terpolymer comprising a vinyl aromatic monomer, at least one monomer chosen from the group of C.sub.1 -C.sub.4 alkyl methacrylates, C.sub.1 -C.sub.4 alkyl acrylates, methacrylonitrile and acrylonitrile, and 0.2 to 5 mol % of an .alpha.,.beta.-unsaturated compound containing dicarboxylic anhydride, the wt. % of components (A), (B) and (C) being relative to the total weight of components (A), (B) and (C), characterized in that the molar mass of component (C) is comprised between 160,000 g/mol and 230,000 g/mol. The polymer composition has excellent mechanical properties, in particular a high impact resistance at low temperatures.
    Type: Grant
    Filed: December 27, 1996
    Date of Patent: May 26, 1998
    Assignee: DSM N.V.
    Inventors: Wilhelmus G. M. Bruls, Robbie A. M. Buntinx, Valerie M. C. Reid
  • Patent number: 5744068
    Abstract: Disclosed are thermoplastic blends of polyesteramides and poly(phenylene ether) resins as well as methods for preparing said polyesteramides and polycarbonate blends thereof. Preferred polyesteramides are those comprising amide units of formula (I) ##STR1## and ester units of formula (II) ##STR2## wherein the ratio of (I) to (II) is at least 1:1, and more preferably wherein at least 80% of the units of formula (I) are separated by at least one of the units of formula (II). The thermoplastic blends may additionally contain compatibilizers for the polyesteramide and poly(phenylene ether) resins.
    Type: Grant
    Filed: February 7, 1997
    Date of Patent: April 28, 1998
    Assignee: General Electric Company
    Inventors: Christian Maria Emile Bailly, Bret Ja Chisholm, Henricus Gerardus C. Denissen
  • Patent number: 5731380
    Abstract: An elastomeric composition comprising:(A) a polyester elastomer;(B) a thermoplastic polyurethane elastomer; and(C) a multiphase composite interpolymer comprising an elastomeric first phase, a final rigid thermoplastic phase and, optionally, one or more intermediate phases,wherein components (A) and (B) combined are present in the composition in an amount of from about 55 to about 90 percent by weight, based on the total weight of components (A), (B) and (C); and wherein the ratio by weight of component (A) to component (B) is from about 1:5 to about 8:1.
    Type: Grant
    Filed: April 11, 1997
    Date of Patent: March 24, 1998
    Assignee: Hoechst Celanese Corporation
    Inventor: Michael D. Golder
  • Patent number: 5719233
    Abstract: Novel modified polyphenylene ether-polyamide compositions comprising polyphenylene ether, polyamide and a polycarboxylic acid and the reaction product thereof and an improved process for preparing the same.
    Type: Grant
    Filed: March 20, 1995
    Date of Patent: February 17, 1998
    Assignee: General Electric Company
    Inventors: Robert R. Gallucci, Roelof van der Meer, Roger W. Avakian
  • Patent number: 5714550
    Abstract: The invention is directed to a polymer composition comprising:a) a blend comprising at least one polyamide and at least one polyphenylene ether;b) at least one polymeric siloxane compound; andc) at least one boron compound.
    Type: Grant
    Filed: October 23, 1996
    Date of Patent: February 3, 1998
    Assignee: General Electric Company
    Inventor: Jeremy Paul Shaw
  • Patent number: 5712043
    Abstract: Laminar articles having improved barrier properties to organic solvents and gases, fabricated directly from polyolefin and modified polyamide, are disclosed. The modified polyamide is a blend of 97-40 wt % polyamide and 3-60 wt % of compatabilizer which is a polyether ester amide block copolymer or a mixture of the block copolymer and alkylcarboxyl-substituted polyolefin.
    Type: Grant
    Filed: June 26, 1995
    Date of Patent: January 27, 1998
    Assignee: Industrial Technology Research Institute
    Inventors: Wen-Jer Chen, Hsin-Herng Wang, Der-Tarng Su, Bin-Yuan Lin, Hsien-Mhing Chen
  • Patent number: 5710216
    Abstract: Thermoplastic molding materials containA) from 1 to 98.5% by weight of a partly aromatic copolyamide,B) from 1 to 98.5% by weight of a polymethacrylimide,C) from 0.5 to 30% by weight of a polymeric component having OH groups,D) from 0 to 60% by weight of fibrous or particulate fillers or mixtures thereof,E) from 0 to 40% by weight of rubber impact modifiers andF) from 0 to 40% by weight of conventional additives and processing assistants.
    Type: Grant
    Filed: December 14, 1995
    Date of Patent: January 20, 1998
    Assignee: BASF Aktiengesellschaft
    Inventors: Martin Weber, Herbert Fisch, Gunter Pipper, Axel Gottschalk
  • Patent number: 5705565
    Abstract: Substantially linear ethylene polymers, e.g., polyethylenes prepared by constrained geometry catalysis (substantially linear ethylene), which are grafted with one or more unsaturated organic compounds containing both ethylenic unsaturation and a carbonyl group, e.g., maleic anhydride, exhibit desirable adhesive properties. These graft-modified substantially linear ethylene polymers also impart desirable compatibility and impact properties to various thermoplastic polymer blends.
    Type: Grant
    Filed: September 9, 1994
    Date of Patent: January 6, 1998
    Assignee: The Dow Chemical Company
    Inventors: Morgan M. Hughes, Kyle G. Kummer, Stephen R. Betso, Michael E. Rowland, Morris S. Edmondson
  • Patent number: 5703161
    Abstract: The invention relates to a polymer mixture which contains (A) 50 to 85 wt. % of a polyether block amide consisting of 30 to 60 wt. % of polyamide-12, polyamide-11 and/or polyamide-12,12 blocks and 70 to 40 wt. % of polyethylene glycol blocks,(B) 10 to 40 wt. % of a polyether block amide consisting of 65 to 85 wt. % of polyamide-12, polyamide-11 and/or polyamide-12,12 blocks and 35 to 15 wt. % of polyethylene glycol blocks, and(C) 5 to 40 wt. % of a poly(ethylene-co-vinylacetate-g-maleic anhydride) polymer consisting of 75 to 95 wt. % of ethylene, 5 to 25 wt. % of vinylacetate and 0.1 to 2 wt. % of maleic anhydride,wherein the data relating to wt. % for the constituents (A), (B) and (C) are with reference to the total amount of polymer mixture. The invention also relates to films produced from this polymer mixture and the use of these films to produce waterproof, water vapor permeable, wind resistant textile composite materials, dressing materials and hygiene items.
    Type: Grant
    Filed: August 27, 1996
    Date of Patent: December 30, 1997
    Assignee: Elf Atochem Deutschland GmbH
    Inventors: Roland Eugen Steenblock, Norbert Franz Kock, Detlef Herbert Fiedler
  • Patent number: 5696204
    Abstract: Thermoplastic moulding compositions comprisingA) 1 to 60 parts by weight of at least one particulate graft rubber polymer of the ABS type which is produced by emulsion polymerisation, in which at least 50% of the graft rubber particles (number) have a structure detectable via transmission electron microscopy photographs in which the individual particles contain irregular cellular inclusions of resin-forming polymer and the surface of the particles has an irregular jagged structure such that 5 to 30 of such peaks are present per depicted particle, which particles differ from an idealised round particle (having a diameter d) by a diameter d+d/x, where x=3 to 15,B) 40 to 99 parts by weight of at least one particulate graft rubber polymer of the ABS type which is produced by solution or bulk polymerisation and which has the morphology which is characteristic of bulk types of ABS, and optionallyC) 0 to 200 parts by weight of at least one thermoplastic, rubber-free resin.
    Type: Grant
    Filed: February 26, 1996
    Date of Patent: December 9, 1997
    Assignee: Bayer AG
    Inventors: Herbert Eichenauer, Edgar Leitz, Karl-Erwin Piejko, Heinrich Alberts
  • Patent number: 5691411
    Abstract: High performance polymer compositions comprising orthoester or orthocarbonate functionalized olefin polymers and polyphenylene ethers, polyamides or combinations thereof, and the compositions unexpectedly display improved impact resistances and/or decreased delamination.
    Type: Grant
    Filed: October 2, 1996
    Date of Patent: November 25, 1997
    Assignee: General Electric Company
    Inventors: Farid Fouad Khouri, John Robert Campbell
  • Patent number: 5691412
    Abstract: A polyamide/aliphatic polyester block copolymer (A) comprising a polyamide block and an aliphatic polyester block, (B) satisfying the expression, T.sub.1 -T<100-C (in which T is the melting point (.degree.C.) of the above block copolymer, T.sub.1 is the melting point (.degree.C.) of a polyamide composed of the polyamide block and C is the content (wt. %) of the polyamide block), (C) exhibiting the extraction amount which satisfies the expression, when extracted in tetrahydrofuran, E<(100-C).times.0.4 (in which E is the extraction amount (wt. %) when the block copolymer is refluxed in tetrahydrofuran, and C is the content (wt. %) of the polyamide block) and (D) having an intrinsic viscosity, measured at 35.degree. C., in the range of from 0.5 to 5; a process for the production thereof; a fiber formed therefrom; and an intimate blend comprising a thermoplastic resin having no or poor compatibility with polyamide and the block copolymer.
    Type: Grant
    Filed: May 25, 1995
    Date of Patent: November 25, 1997
    Assignee: Teijin Limited
    Inventors: Shunichi Matsumura, Takashi Ito, Takanori Miyoshi
  • Patent number: 5686527
    Abstract: Multiple component polymer compositions for fabrication into articles. In particular, polymeric compositions comprising a heat resistant polymer; a radio frequency ("RF") susceptible polymer; a compatibilizing polymer; the composition having physical properties within the range a<40,000 psi; b>=70%; c<30%; d>1.0; e<0.1%; f<0.1%; g>=0.05; h<=60%; i=0; wherein: a is the mechanical modulus of the composition measured according to ASTM D-882; b is the percent recovery in length of the composition after an initial 20% deformation; c is the optical haze of the composition being 9 mils in thickness according to ASTM D-1003; d is the loss tangent of the composition at 1 Hz measured at melt processing temperatures; e is the elemental halogen content by weight of the composition; f is the low molecular weight water soluble fraction of the composition; g is the dielectric loss between 1 and 60 MHz and over temperatures of 25.degree. to 250.degree. C.
    Type: Grant
    Filed: June 5, 1995
    Date of Patent: November 11, 1997
    Assignee: Baxter International Inc.
    Inventors: Dean Laurin, Angeles Lillian Buan, Lecon Woo, Michael T. K. Ling, Yuan Pang Samuel Ding, William Anderson, Larry A. Rosenbaum, Denise S. Hayward, Joseph P. Hoppesch, Gregg Nebgen, Stanley Westphal
  • Patent number: 5683768
    Abstract: The invention provides a flexible plastic formulation capable of being RF sealed, extruded, cast or blow-molded, gas, steam and radiation sterilized. The plastic formulation of the invention comprises: a) from about 40 to about 90 percent by weight of a polyolefin polypropylene based material; b) from about 3 to about 25 percent by weight of a functionialized block copolymer, the functionalized block copolymer consisting essentially of a central block copolymer molecule including generally equal proportions of ethylene and butylene units, and terminal blocks of polystyrene; and c) from about 3 to about 20 percent by weight a nylon. The plastic formulations of the invention are useful in the manufacture of blood bags, tubing and the like.
    Type: Grant
    Filed: December 21, 1994
    Date of Patent: November 4, 1997
    Assignee: Baxter International Inc.
    Inventors: Shaye-wen Shang, Michael Tung-Kiung Ling, Lecon Woo, Christopher C. Cometa
  • Patent number: 5683818
    Abstract: The present invention provides a method of improving the wear resistance of a polymeric composite comprising a polyamide and a polypropylene. The polymeric composite is a component of a tribological wear system in which a surface of the polymeric composite bears against another surface causing friction and wear of the polymeric composite. By the present method, at least one crystalline polymer is functionalized to graft with at least one of the polyamide and the polypropylene to form the composite.
    Type: Grant
    Filed: April 20, 1995
    Date of Patent: November 4, 1997
    Assignee: Kawasaki Chemical Holding Co., Inc.
    Inventor: Anne E. Bolvari
  • Patent number: 5674939
    Abstract: Moulding compounds the ABS type consisting of at least one resin matrix and a particulate graft-rubber polymer distributed therein and produced by emulsion polymerisation, wherein at least 70% of the graft-rubber particles (number) exhibit a structure of the rubber phase which can be detected by photographs taken with the aid of a transmission electron microscope and in which the individual particles contain irregular cellular inclusions of resin-forming polymer and the surface of the particles exhibits an irregularly jagged structure such that, for each particle illustrated, 5 to 30 of such jagged projections are present which differ from an idealised round particle (with a diameter d) by virtue of a diameter d+d/x with x=3 to 15, as well as a process for the manufacture of said moulding compounds.
    Type: Grant
    Filed: November 13, 1995
    Date of Patent: October 7, 1997
    Assignee: Bayer Aktiengesellschaft
    Inventors: Herbert Eichenauer, Adolf Schmidt, Edgar Leitz, Karl-Erwin Piejko
  • Patent number: 5674930
    Abstract: A thermoplastic resin composition having excellent characteristics such as impact resistance and coatability is described. The thermoplastic resin composition contains a propylene based polymer and a graft copolymer having an olefin homo/co-polymer portion forming its main chain and a vinyl copolymer portion forming its branched portion. In the graft copolymer, the proportion of the olefin homo/co-polymer portion is 5 to 95% by weight, and the vinyl copolymer portion occupies the remaining weight. The vinyl copolymer portion of the graft copolymer has a hydroxyl group as a functional group. One of the olefin homo/co-polymer portion and the vinyl copolymer portion forms a dispersed phase in the other with a particle size of 0.001 to 10 .mu.m. Consequently, the graft copolymer assumes a multi-phase structure. The thermoplastic resin composition optionally further contains a thermoplastic elastomer.
    Type: Grant
    Filed: January 4, 1996
    Date of Patent: October 7, 1997
    Assignee: NOF Corporation
    Inventors: Motoyuki Sugiura, Kazumine Ohara
  • Patent number: 5670575
    Abstract: A toughened polyamide blend which exhibits improved toughness at exceptionally low temperatures can be prepared from:(A) 60 to 90 weight percent of a polyamide matrix resin; and(B) 10 to 40 weight percent of a rubber component including:(1) a functionalized rubber selected from ethylene/propylene copolymers and ethylene/propylene/diene terpolymers, and(2) an ethylene copolymer of the formula E/X/Y whereinE is a radical formed from ethylene and is 40 to 90 weight percent of the ethylene copolymer,X is an acrylate ester of an alcohol having 1 to 10 carbon atoms and is 10 to 80 weight percent of the ethylene copolymer, andY is selected from glycidyl methacrylate and glycidyl acrylate and is 0.5 to 10 weight percent of the ethylene copolymer.
    Type: Grant
    Filed: November 1, 1995
    Date of Patent: September 23, 1997
    Assignee: E. I. Du Pont de Nemours and Company
    Inventor: Edmund Arthur Flexman, Jr.
  • Patent number: 5668236
    Abstract: The present invention relates to a hydrophilic highly swellable hydrogel based on (co)polymerized hydrophilic monomers or based on graft (co)polymers, characterized in that it is post-crosslinked with a polyamidoamine in an aqueous medium.
    Type: Grant
    Filed: April 29, 1996
    Date of Patent: September 16, 1997
    Assignee: Cassella Aktiengesellschaft
    Inventors: Fritz Engelhardt, Ulrich Riegel, Uwe Stuven, Helmut Klotzsche, Gustav Remmel
  • Patent number: 5665821
    Abstract: The present invention relates to resin compositions having a good compatibility of polyphenylene ether and polyamide and a natural color, which comprise (A) 5 to 95 parts by weight of a polyphenylene ether, (B) 1 to 50 parts by weight of a functionalized aromatic vinyl graft copolymer which is prepared by melt blending 100 parts by weight of a copolymer which is prepared by graft polymerizing 20 to 99 parts by weight of aromatic vinyl monomers onto 1 to 80 parts by weight of synthetic rubber polymer, 0.01 to 2 parts by weight of an organic peroxide and 0.01 to 10 parts by weight of reactive monomers having an unsaturated carboxylic acid or anhydride group, and (C) 5 to 95 parts by weight of a polyamide and optionally (D) up to 40 parts by weight of a synthetic resinous impact modifier.
    Type: Grant
    Filed: August 28, 1995
    Date of Patent: September 9, 1997
    Assignee: Cheil Industries Inc.
    Inventors: Jong-chul Lim, Jaegoo Doh, Hyungsu Kim, Jeheum Lee, Tae-uk Kim
  • Patent number: 5665820
    Abstract: Elastomeric polypropylenes modified by grafting and blends thereof with isotactic polypropylenes modified by grafting, and the use thereof as compatibilizers or adhesion promoters for blends and metal composites.
    Type: Grant
    Filed: October 11, 1995
    Date of Patent: September 9, 1997
    Assignee: PCD Polymere Gesellschaft m.b.H.
    Inventors: Dirk Leistner, Manfred Ratzsch, Achim Hesse, Norbert Hafner, Markus Gahleitner, Klaus Bernreitner
  • Patent number: 5663229
    Abstract: A polyamide-containing polymer mixture having a melt viscosity of 1,000 to 1,400 Pa.multidot.s (at 270.degree. C. and under a load of 122.6 N) and includes the following components:(A) 50 to 75 parts by weight of polyamide 6, polyamide 6,6, polyamide 12 or mixtures thereof;(B) 15 to 30 parts by weight of a polyolefin having a density of 0.921 to 0.96 g/cm.sup.3 onto which an unsaturated carboxylic acid or an unsaturated carboxylic acid derivative has been grafted, the degree of grafting being between 0.01 and 1 weight percent, with respect to the total weigh of grafted and ungrafted polyolefin;(C) 10 to 20 parts by weight of a grafted polyolefin elastomer including at least ethylene and propylene units;(D) Additives selected from the group including stabilizers, anti-friction agents and fillers,with the sum of the parts by weight of components (A) to (D) being 100, and the mixture being produced by mixing components (A), (B) and (D) or (A), (B), (C) and (D) and extruding them at 150 to 300 rpm.
    Type: Grant
    Filed: March 24, 1994
    Date of Patent: September 2, 1997
    Assignee: EMS-Inventa AG
    Inventors: Ulrich Presenz, Manfred Hewel
  • Patent number: 5658984
    Abstract: A permanent anti-static polycarbonate resin composition is comprises(a) 50-95 parts by weight of an aromatic polycarbonate resin,(b) 2-40 parts by weight of a block copolyamide resin,(c) 0-50 parts by weight of an aromatic polyester resin, and(d) 1-30 parts by weight of a multi-layered polymer having a structure comprising a core composed of a rubber-like polymer prepared from an alkyl acrylate monomer in which the carbon number of the alkyl group is 2-8, and an outer shell layer formed on the surface of the core and composed of a glass-like polymer prepared from an aromatic vinyl monomer or an aromatic vinyl monomer and a vinyl monomer copolymerizable therewith.
    Type: Grant
    Filed: December 21, 1995
    Date of Patent: August 19, 1997
    Assignee: Mitsubishi Engineering-Plastics Corporation
    Inventors: Kazuhiko Ishii, Goro Shimaoka, Michio Nakata
  • Patent number: 5654369
    Abstract: The invention provides a thermoplastic resin composition uniformly and permanently rendered antistatic which comprises (A) 100 parts by weight of a thermoplastic resin, (B) 3-30 parts by weight of a cationic copolymer comprising 80-98 mol % of an ethylene unit and 2-20 mol % of a cationic unit and having a weight-average molecular weight of 1,000-50,000, and (C) 0.
    Type: Grant
    Filed: July 22, 1996
    Date of Patent: August 5, 1997
    Assignee: Dai-Ichi Kogyo Seiyaku Co., Ltd.
    Inventors: Takayuki Tsubaki, Yutaka Nakayama, Hideyuki Sumi, Hiroshi Hotta
  • Patent number: 5654062
    Abstract: The present invention relates to an insulating composition for electrical cable comprising a mixture of an ethylene-alkyl acrylate or ethylene-vinyl acetate copolymer and of a polymeric compound, said polymeric compound being an ethylene-alkyl acrylate-maleic anhydride terpolymer or an ethylene-vinyl acetate-maleic anhydride terpolymer, and usual additives such as, for example, a crosslinking agent, its use for the preparation of an insulation sheath of electrical cables and the insulation sheath obtained.
    Type: Grant
    Filed: June 7, 1995
    Date of Patent: August 5, 1997
    Assignee: Elf Atochem S.A.
    Inventors: Jean Michel Chabagno, Gerard Junca, Philippe Montagne, Jean Pourtau
  • Patent number: 5654364
    Abstract: The invention relates to melt-miscible polyolefin blends, and a process for preparing the melt-miscible blends, of two or more polyolefins. Matching of the segment length of a modifying polyolefin with the segment length of a primary polyolefin, such as polypropylene or an ethylene/alpha-olefin copolymer, provides polyolefin blends heretofore unknown to be melt-miscible. A broad range of polyolefin blend compositions, and of polyolefin blends containing other polymers made compatible with the polyolefin blend compositions, are defined, all of the blend compositions having at least one melt-miscible polyolefin phase.
    Type: Grant
    Filed: April 21, 1995
    Date of Patent: August 5, 1997
    Assignee: Regents of the University of Minnesota
    Inventors: Frank Steven Bates, Jeffrey Harris Rosedale, Mark Frederic Schulz, Kristoffer Almdal
  • Patent number: 5652326
    Abstract: A polyetheresteramide having good heat resistance, permanent antistatic property and superior compatibility with thermoplastic resins and a resin composition containing of the polyetheresteramide are disclosed, wherein the polyetherester-amide consists essentially of a polyamide oligomer with carboxylic chain ends having a number average molecular weight between 200 and 5,000 and a bisphenol compound with oxyalkylene units having a number average molecular weight between 300 and 3,000. Antistatic resin compositions with good antistatic property and heat resistance are obtained from compositions comprising 3 to 40% by weight of the polyetheresteramide and 60 to 97% by weight of thermoplastic resins. The antistatic resin compositions can contain as compatibilizers vinyl polymers having functional groups such as carboxyl and epoxy groups or block polymers containing polyolefin blocks and aromatic vinyl polymer blocks.
    Type: Grant
    Filed: March 1, 1994
    Date of Patent: July 29, 1997
    Assignee: Sanyo Chemical Industries, Ltd.
    Inventors: Yasuhiro Ueda, Eiichi Senda, Yoshitsugu Takai, Tokiko Kokubu, Toshiaki Okamoto, Eiji Ichihara
  • Patent number: 5650466
    Abstract: Thermoplastic molding materials containA) from 5 to 95% by weight of a semicrystalline, partly aromatic copolyamide composed ofa.sub.1) from 30 to 44 mol % of units which are derived from terephthalic acid,a.sub.2) from 6 to 20 mol % of units which are derived from isophthalic acid,a.sub.3) from 43 to 49.5 mol % of units which are derived from hexamethylenediamine anda.sub.4) from 0.5 to 7 mol % of units which are derived from aliphatic cyclic diamines of 6 to 30 carbon atoms,the molar percentages of the components a.sub.1) to a.sub.4) summing to 100%,B) from 5 to 95% by weight of a copolymer of vinylaromatic compounds with .alpha.,.beta.-unsaturated dicarboxylic anhydrides and .alpha.,.beta.-unsaturated dicarboximides,C) from 0 to 90% by weight of an SAN, ABS or ASA polymer or of a polymer of a C.sub.1 -C.sub.
    Type: Grant
    Filed: January 4, 1996
    Date of Patent: July 22, 1997
    Assignee: BASF Aktiengesellschaft
    Inventors: Axel Gottschalk, Herbert Fisch, Gunter Pipper, Martin Weber
  • Patent number: 5648423
    Abstract: The polyamide resin composition of the present invention comprises 100 parts by weight of a polyamide resin and 5 to 200 parts by weight of a graft-modified ethylene/1-butene random copolymer having a graft quantity of an unsaturated carboxylic acid or its derivative of 0.01 to 10% by weight. The graft-modified ethylene/1-butene random copolymer is a graft-modified product of an ethylene/1-butene random copolymer having a 1-butene content of 15 to 25% by mol, an intrinsic viscosity [.eta.] of 0.5 to 3.5 dl/g, a glass transition temperature (Tg) of not higher than -60.degree. C., a crystallinity of less than 10%, and a parameter (B value) indicating randomness of a copolymerized monomer chain distribution, as measured by a .sup.13 C-NMR method, of 1.0 to 1.4. The polyamide resin composition shows high melt flowability, namely, good moldability, and it can provide a molded article excellent in flexibility, low-temperature impact resistance, resistance to water absorption and resistance to saline solutions.
    Type: Grant
    Filed: April 5, 1995
    Date of Patent: July 15, 1997
    Assignee: Mitsui Petrochemical Industries, Ltd.
    Inventors: Mamoru Kagami, Mutsuhiro Tanaka, Masahiro Sugi
  • Patent number: 5641825
    Abstract: The invention provides a composition of matter having oxygen scavenger capabilities. The composition comprises a blend of a first polymeric component comprising a polyolefin, the first polymeric component having been grafted with an unsaturated carboxylic anhydride or an unsaturated carboxylic acid, or combinations thereof, or with an epoxide; a second polymeric component having OH, SH or NHR.sup.2 groups where R.sup.2 is H, C.sub.1 -C.sub.3 alkyl, substituted C.sub.1 -C.sub.3 alkyl; and a metal salt capable of catalyzing the reaction between oxygen and the second polymeric component, the polyolefin being present in an amount sufficient so that the blend is non phase-separated. In the preferred composition maleic anhydride is the grafted material, the second polymeric component is MXD6 nylon and the metal is cobalt. A method of providing a homogeneous blend of a polyolefin with a second polymeric component having OH, SH or NHR.sup.2 groups is also set forth.
    Type: Grant
    Filed: March 28, 1994
    Date of Patent: June 24, 1997
    Assignee: Chevron Chemical Company
    Inventors: Robert Bacskai, Ta Yen Ching, Kiyoshi Katsumoto
  • Patent number: 5641833
    Abstract: A homogeneous polyolefinic blend and a preparation process thereof, are provided wherein the blend comprises polyolefin and a polymer which has a barrier property to organic liquid and vapor permeability. The barrier property is improved through the inclusion of mixed compatibilizing substances comprising an alkylcarboxyl-substituted polymer and reactive low molecular weight compounds. The compatibilizing substances are included by the means of ordinary processing equipment. The polymer with the barrier property having low organic liquid and vapor permeability is distributed as a multitude of thin, wide, disc-like layers in a polyolefin phase. The compatibilizing substances minimize the interfacial energy between the two polymers to adhere them together.
    Type: Grant
    Filed: January 11, 1995
    Date of Patent: June 24, 1997
    Assignee: Yukong Ltd.
    Inventors: Kwang Sik Jung, Moon Seok Lee, Yong Ho Kwon, Seong Jo Kim
  • Patent number: 5639833
    Abstract: The invention is directed to molding materials containingA) from 1 to 99% by weight of polyarylene ethers having repeating units I ##STR1## where t and q may each be an integer 0, 1, 2 or 3,T, Q and Z may each be a chemical bond or --O--, --S--, --SO.sub.2 --, S.dbd.O, C.dbd.O, --N.dbd.N--, R.sup.a C.dbd.CR.sup.b -- or --CR.sup.c R.sup.d --, with the proviso that at least one of the groups T, Q and Z is --SO.sub.2 -- or C.dbd.O,R.sup.a and R.sup.b,R.sup.c and R.sup.d, andAr and Ar.sup.1 are as defined in the specification,B) from 1 to 99% by weight of copolyamides containingb.sub.1) from 30 to 44 mol % of units which are derived from terephthalic acid,b.sub.2) from 6 to 20 mol % of units which are derived from isophthalic acid,b.sub.3) from 43 to 49.5 mol % of units which are derived from hexamethylenediamine,b.sub.4) from 0.5 to 7 mol % of units which are derived from aliphatic cyclic diamines of 6 to 30 carbon atoms andb.sub.5) from 0 to 4 mol % of further polyamide-forming monomers which differ from b.sub.
    Type: Grant
    Filed: August 10, 1995
    Date of Patent: June 17, 1997
    Assignee: BASF Aktiengesellschaft
    Inventors: Martin Weber, Herbert Fisch, Gunter Pipper, Axel Gottschalk
  • Patent number: 5637410
    Abstract: A polyolefin-containing adhesive blend comprising: (A) 1 to 30 parts by weight of a graft copolymer having a polyolefin backbone grafted with 0.001 to 30% by weight of at least one polymerisable ethylenically unsaturated carboxylic acid or derivative thereof, (B) 70 to 99 parts by weight of a polyolefin provided that at least 5 parts by weight of (B) is (C) a polyethylene having a density of less than 930 kgm.sup.-3 wherein the graft copolymer (A) has been reacted with a compound(D) which has at least two primary or secondary amino groups at least one of which is a primary amino group, the sum of (A), (B) and (C) being 100 parts by weight. Multilayer structures comprising a polyolefin layer, a polyketone layer and an intermediate layer of the adhesive blend are also disclosed.
    Type: Grant
    Filed: June 14, 1995
    Date of Patent: June 10, 1997
    Assignee: BP Chemicals Limited
    Inventors: James G. Bonner, Philip K. G. Hodgson
  • Patent number: 5637407
    Abstract: Composite including a rubber/thermoplastic blend adherent by itself to a thermoplastic material; the blend is in the form of a thermoplastic matrix containing rubber nodules functionalized and vulcanized during the mixing with the thermoplastic. Composite articles obtained by overmoulding the vulcanized rubber/thermoplastic blend onto the thermoplastic.
    Type: Grant
    Filed: November 10, 1994
    Date of Patent: June 10, 1997
    Assignee: Elf Atochem S. A.
    Inventors: Marius Hert, Patrick Alex, Martine Cerf, Christian Dousson
  • Patent number: 5633317
    Abstract: A resin composition containing graft copolymer having at least one isocyanate group and 10,000 to 20,000 number-average molecular weight or high-molecular-weight polymer having at least one isocyanate group and 10,000 to 200,000 number-average molecular weight, and low-molecular-weight polymer having or not having an isocyanate group and 500 to 8,000 number-average molecular weight. This resin composition has tackiness at ordinary temperature, and long pot life. It can be used for reactive hot melt type adhesives (which can omit hot press process), reactive hot melt type pressure-sensitive adhesives, or coating material.
    Type: Grant
    Filed: September 7, 1994
    Date of Patent: May 27, 1997
    Assignee: Mitsui Toatsu Chemicals, Inc.
    Inventors: Eiichi Kawasaki, Kiyoto Doi, Tadashi Kitamura, Kousuke Suewaka, Kazuya Shinkoda
  • Patent number: 5624994
    Abstract: The invention relates to a process for the preparation of composite material formed from a vulcanized elastomer, containing carboxylic acid or dicarboxylic acid anhydride groups, in combination with a thermoplastic elastomer containing polyamide blocks, which comprises vulcanizing an elastomer composition comprising said vulcanizable elastomer, a crosslinking system and, optionally, diverse adjuvants in a mold, one part of which is occupied by said thermoplastic elastomer containing polyamide blocks, the vulcanization temperature being between -15.degree. C. and +5.degree. C. with respect to the Vicat point of said thermoplastic elastomer containing polyamide blocks, the elastomer composition and the vulcanization kinetics being such that the material shows cohesive failure when subjected to stress for separation of the two elastomers.This process leads to composite materials which have excellent properties, in particular in respect of tensile strength (cohesive failure).
    Type: Grant
    Filed: October 13, 1995
    Date of Patent: April 29, 1997
    Assignee: Elf Atochem S. A.
    Inventors: Marius Hert, Patrick Alex
  • Patent number: 5623024
    Abstract: Disclosed is a fiber-forming polymer blend, comprising:a) a polyamide;b) a miscible amorphous polymer; andc) an immiscible amorphous polymer.
    Type: Grant
    Filed: January 25, 1996
    Date of Patent: April 22, 1997
    Assignee: BASF Corporation
    Inventors: Richard Kotek, Hans-Georg Matthies
  • Patent number: 5621041
    Abstract: Maleated polyolefins such as maleated polypropylene, maleated polyethylene, and the like can be used as compatibilizing agents for producing a polymer alloy of polyolefins, such as polypropylene, and liquid crystal polymers. The polymer alloys have improved stiffness, strength, and surface appearance characteristics.
    Type: Grant
    Filed: April 17, 1991
    Date of Patent: April 15, 1997
    Assignee: Center for Innovative Technology
    Inventors: Donald G. Baird, Arindam Datta
  • Patent number: 5616418
    Abstract: Polyblend compositions well adopted for the production of a wide variety of useful shaped articles having improved physical/chemical properties, e.g., fibers, films, sheets, composites, and the like, comprise (a) at least one polyamide thermoplastic elastomer, e.g., a polyetheresteramide, and (b) at least one modified polyolefin, e.g, an optionally maleized copolymerizate of ethylene and vinyl acetate, a copolymerizate of ethylene and (meth)acrylic acid, a copolymerizate of ethylene, vinyl acetate and (meth)acrylic acid and/or an alkyl (meth)acrylate, a copolymerizate of ethylene, an alkyl (meth)acrylate and, optionally, maleic anhydride, or maleized SBS, SIS or SEBS.
    Type: Grant
    Filed: December 28, 1994
    Date of Patent: April 1, 1997
    Assignee: Atochem
    Inventors: Thierry Vasselin, Michel Vuachet
  • Patent number: 5614588
    Abstract: The invention relates to a polymer mixture which contains(A) 50 to 85 wt. % of a polyether block amide consisting of 30 to 60 wt. % of polyamide-12, polyamide-11 and/or polyamide-12,12 blocks and 70 to 40 wt. % of polyethylene glycol blocks,(B) 10 to 40 wt. % of a polyether block amide consisting of 65 to 85 wt. % of polyamide-12, polyamide-11 and/or polyamide-12,12 blocks and 35 to 15 wt. % of polyethylene glycol blocks, and(C) 5 to 40 wt. % of a poly(ethylene-co-vinylacetate-g-maleic anhydride) polymer consisting of 75 to 95 wt. % of ethylene, 5 to 25 wt. % of vinylacetate and 0.1 to 2 wt. % of maleic anhydride,wherein the data relating to wt. % for the constituents (A), (B) and (C) are with reference to the total amount of polymer mixture. The invention also relates to films produced from this polymer mixture and the use of these films to produce waterproof, water vapor permeable, wind resistant textile composite materials, dressing materials and hygiene items.
    Type: Grant
    Filed: March 24, 1995
    Date of Patent: March 25, 1997
    Assignee: Elf Atochem Deutschland GmbH
    Inventors: Roland E. Steenblock, Norbert F. Kock, Detlef H. Fiedler
  • Patent number: 5610223
    Abstract: The impact strength of a thermoplastic molding composition containing polyamide resin is improved upon the incorporation therewith of a particular silicone rubber powder. The silicone rubber powder, added at a level of about 1 to 25 percent contains a mixture of (a) a polydiorganosiloxane and (b) finely divided silica filler.
    Type: Grant
    Filed: July 13, 1995
    Date of Patent: March 11, 1997
    Assignee: Bayer Corporation
    Inventor: James P. Mason
  • Patent number: RE35509
    Abstract: Compatiblized mixtures of a polyphenylene ether, a polyamide and a compatibilizer are described. The mixtures have improved physical properties as a result of using in the mixtures a polyamide having a terminal amine group to terminal carboxyl group ratio of greater than 1.
    Type: Grant
    Filed: July 15, 1994
    Date of Patent: May 13, 1997
    Assignee: General Electrical Company
    Inventors: Susumi Fujii, Hiromi Ishida, Masataka Morioka, Akihiro Saito, Roelof van der Meer