Solid Graft Or Graft-type Copolymer Derived From Ethylenic Reactants Only Patents (Class 525/64)
  • Patent number: 10392506
    Abstract: The invention relates to compositions consisting of A) 70 to 90 parts by weight of at least one polycarbonate, B) 10 to 30 parts by weight of at least one graft polymer containing a rubber-elastic particulate graft base, which contains diene, and containing a vinyl co(polymer) shell, C) 0 to 15 parts by weight of at least one additive, wherein the sum of the parts by weight of components A) and B) in the composition is normalized to 100. The invention further relates to the use of the compositions to produce components containing a plastic carrier and a multi-ply metal layer, and to molded bodies produced from the compositions.
    Type: Grant
    Filed: July 4, 2016
    Date of Patent: August 27, 2019
    Assignee: Covestro Deutschland AG
    Inventors: Andreas Seidel, Wolfgang Schwartmann, Eckhard Wenz, Peter Weimar
  • Patent number: 9980885
    Abstract: A silicone-based copolymer resin powder is prepared by reacting a siloxane oligomer obtained from ring-opening of (a1) a cyclic organosiloxane in the presence of (a3) an acid catalyst and (a4) an anionic surfactant with (a2) a silane coupling agent having an alkoxy group and a polymerizable double bond to obtain (A) a linear or branched organopolysiloxane containing at least 2 silicon-bonded hydroxyl groups per molecule, copolymerizing (A) the linear or branched organopolysiloxane with (B) an ethylenically unsaturated monomer to form a copolymer as a core, and further polymerizing to the copolymer another ethylenically unsaturated monomer as a shell, the powder containing up to 0.3% by weight of the cyclic organosiloxane and up to 1% by weight of the anionic surfactant.
    Type: Grant
    Filed: October 31, 2014
    Date of Patent: May 29, 2018
    Assignee: Nissin Chemical Industry Co. Ltd.
    Inventors: Kentaro Watanabe, Akira Yamamoto
  • Patent number: 9957385
    Abstract: The invention relates to blends of vinyl chloride graft copolymers as well as to a method for preparing such vinyl chloride graft copolymers and their blends. The invention also relates to molded articles manufactured by using the blends according to the invention.
    Type: Grant
    Filed: February 11, 2013
    Date of Patent: May 1, 2018
    Assignee: VESTOLIT GmbH & Co. KG
    Inventors: Davide Brizzolara, Ingo Fischer, Jan-Stephan Gehrke, Dieter Polte, Axel Stieneker, Harald Sturm
  • Patent number: 9902850
    Abstract: A thermoplastic resin composition includes (A) a rubber-modified vinyl-based graft copolymer, (B) a silicone-modified aromatic vinyl-based copolymer, and (C) an aromatic vinyl-unsaturated nitrile-based copolymer. The thermoplastic resin composition can exhibit low-gloss characteristics and a synergistic effect of impact resistance and heat resistance.
    Type: Grant
    Filed: June 23, 2015
    Date of Patent: February 27, 2018
    Assignee: Lotte Advanced Materials Co., Ltd.
    Inventors: Bo Eun Kim, Joo Hyun Jang, Kwang Soo Park, Jae Won Heo, Young Sub Jin
  • Patent number: 9856371
    Abstract: A thermoplastic resin composition includes (A) a graft rubber copolymer, (B) an aromatic vinyl-vinyl cyanide-based copolymer, and (C) a silicone-modified aromatic vinyl-vinyl cyanide-based copolymer. The silicone-modified aromatic vinyl-vinyl cyanide-based copolymer (C) has an average particle size of about 100 ?m or less.
    Type: Grant
    Filed: June 23, 2015
    Date of Patent: January 2, 2018
    Assignee: Lotte Advanced Materials Co., Ltd.
    Inventors: Bo Eun Kim, Joo Hyun Jang, Jae Won Heo, Kwang Soo Park, Yu Jin Jung, Young Sub Jin
  • Patent number: 9796837
    Abstract: A masterbatch having functionalized silicone with an epoxy group or a secondary amine group as a slip additive, the polyethylene compound that the silicone-containing masterbatch has been let down into, and the plastic articles and films from such compounds having improved slip properties are disclosed. The improved slip properties are evidenced by essentially no migration of the slip additive 12 weeks after manufacturing and a dynamic coefficient of friction value of less than 0.4 and a static coefficient of friction 0.5 or less as measured within the first day of manufacturing according to the ASTM D1894-01 method.
    Type: Grant
    Filed: July 15, 2013
    Date of Patent: October 24, 2017
    Assignee: PolyOne Corporation
    Inventors: Jerome Alric, Jerome Waeler, Fabien Auvray
  • Patent number: 9796839
    Abstract: A masterbatch having epoxy-functionalized silicone as a slip additive, the polypropylene compound that the silicone-containing masterbatch has been let down into, and the plastic articles and films from such compounds having improved slip properties are disclosed. The improved slip properties are evidenced by (1) essentially no migration of the slip additive 12 weeks after manufacturing, (2) a dynamic coefficient of friction value of less than 0.4 and a static coefficient of friction 0.6 or less within the first day of manufacturing according to the ASTM D1894-01 method, and (3) less than 15% change in the dynamic and static coefficient of friction values between the first day of manufacturing and 20 days after manufacturing.
    Type: Grant
    Filed: July 15, 2013
    Date of Patent: October 24, 2017
    Assignee: PolyOne Corporation
    Inventors: Jerome Alric, Jerome Waeler, Fabien Auvray
  • Patent number: 9777162
    Abstract: To provide a waterborne curable resin composition that is advantageous for environmental protection measures, can be applied without use of a film-forming assistant and can improve the dispersion stability of the emulsion, and also improve physical properties of the coat such as curability, durability, and stain resistance. A waterborne curable resin composition having an acrylic emulsion produced by emulsion polymerization, wherein the acrylic emulsion contains a curable monomer and/or oligomer in emulsion particles.
    Type: Grant
    Filed: October 2, 2006
    Date of Patent: October 3, 2017
    Assignee: Nippon Shokubai Co., Ltd.
    Inventors: Yoshiyuki Yokota, Masaya Uchida
  • Patent number: 9670354
    Abstract: A thermoplastic polymer composition which is excellent in flexibility, mechanical properties, moldability, and particularly in heat resistance and is capable of adhering to ceramics, metals, and synthetic resins even at low temperature (for example, 190° C. or lower) without the treatment with a primer, and a molded product produced by using the thermoplastic polymer composition are described. The thermoplastic polymer composition includes 100 parts by mass of a thermoplastic elastomer (A), 1 to 100 parts by mass of a polyvinyl acetal resin (B), and 5 to 100 parts by mass of a polar group-containing polypropylene resin (C).
    Type: Grant
    Filed: August 24, 2011
    Date of Patent: June 6, 2017
    Assignee: KURARAY CO., LTD.
    Inventors: Asako Minamide, Mikio Masuda
  • Patent number: 9556345
    Abstract: The disclosure relates to the use of compounds of specific structure as defoaming wetting agents for aqueous coating systems, for example paints and varnishes. The disclosure is more particularly related to methods of reducing the surface tension and/or increasing the density of an aqueous coating system, which methods include adding alcohol propoxylates to an aqueous coating system. The alcohol propoxylates have the general structure R—O—(PO)xH, in which R is a saturated alkyl radical having 7 to 10 C atoms, PO is a propylene oxide unit, and x is a number in the range from 4 to 6. The resulting aqueous coating composition has good wetting properties, but is low in foam, so it does not disrupt processing operations of the coating system.
    Type: Grant
    Filed: May 26, 2011
    Date of Patent: January 31, 2017
    Assignee: Cognis IP Management GmbH
    Inventors: Sascha Oestreich, Renate Wolf, Peter Bene
  • Patent number: 9434839
    Abstract: To provide a polybutylene terephthalate resin composition offering excellent flowability, wherein the resin composition raises the weld strength and heat shock resistance of a welded body obtained by welding together molded products obtained by molding the polybutylene terephthalate resin composition. [Solution] A polybutylene terephthalate resin composition comprising a polybutylene terephthalate resin (A) having a weight-average molecular weight of 60,000-80,000 inclusive and an inorganic filler (B). Preferably, also included is 5-20 mass parts of an elastomer (C) relative to 100 mass parts of the polybutylene terephthalate resin (A).
    Type: Grant
    Filed: September 27, 2012
    Date of Patent: September 6, 2016
    Assignee: WinTech Polymer Ltd.
    Inventor: Kouichi Sakata
  • Patent number: 9416266
    Abstract: Provided is a thermoplastic resin composition including: an acrylic graft copolymer (A), an aromatic vinyl-vinyl cyanide compound copolymer (B), a polyalkyl(meth)acrylate resin (C), and an acrylic compound-grafted silicon-based impact reinforcing agent (D). The thermoplastic resin composition can have excellent impact resistance and colorability with minimal or no deterioration of dimensional stability, molding processability, weather resistance and mechanical and physical properties.
    Type: Grant
    Filed: October 22, 2014
    Date of Patent: August 16, 2016
    Assignee: Samsung SDI Co., Ltd.
    Inventor: Young Hyo Kim
  • Patent number: 9419284
    Abstract: A binder resin for an electrode of a nonaqueous electrolyte secondary battery is provided, which is used as the binder resin in a slurry composition for an electrode of a nonaqueous electrolyte secondary battery, containing a binder resin, an active material and an organic solvent.
    Type: Grant
    Filed: January 9, 2013
    Date of Patent: August 16, 2016
    Assignee: Mitsubishi Rayon Co., Ltd.
    Inventors: Daisuke Fujikawa, Fumino Momose, Mitsufumi Nodono, Masakazu Ito
  • Patent number: 9353255
    Abstract: Disclosed are an acrylonitrile-acrylate-styrene graft copolymer having a structure including a seed which comprises at least one of an aromatic vinyl compound, a vinyl cyanide compound and an alkyl (meth)acrylate compound, a core which surrounds the seed and comprises alkyl acrylate, and a shell which surrounds the core and comprises at least one of an aromatic vinyl compound, a vinyl cyanide compound and an alkyl (meth)acrylate compound, and having suitably controlled thicknesses and refractive indexes of the respective layers, and a thermoplastic resin composition comprising the acrylonitrile-acrylate-styrene graft copolymer.
    Type: Grant
    Filed: July 16, 2013
    Date of Patent: May 31, 2016
    Assignee: LG Chem, Ltd.
    Inventors: Min Jung Kim, Yong Yeon Hwang, Chun Ho Park, Sang Mi Lee, Yeong Min Lee, Eun Soo Kang, Hye Kyung Han
  • Patent number: 9332802
    Abstract: Ski boots and other cold weather articles are described made from polymer compositions that are exceptionally stable at low temperatures. The polymer composition, for instance, may contain a thermoplastic polymer, a thermoplastic elastomer, and an impact modifier. In one embodiment, each of the individual components are selected such that they do not undergo a second order transition within a temperature range of from about 50° C. to about ?40° C., and particularly from about 23° C. to about ?40° C. In one embodiment, the polymer compositions are used to mold the outer shell of a snow ski boot.
    Type: Grant
    Filed: December 20, 2012
    Date of Patent: May 10, 2016
    Assignee: Ticona LLC
    Inventors: Mukul Kaushik, Dirk Zierer, James L. Coleman, Jeanne Pilis, Kenneth L. Price
  • Patent number: 9328229
    Abstract: Ski boots and other cold weather articles are described made from polymer compositions that are exceptionally stable at low temperatures. The polymer composition, for instance, may contain a thermoplastic polymer, a thermoplastic elastomer, an impact modifier and a wear resistant additive. In one embodiment, various polymer components are selected such that they do not undergo a second order transition within a temperature range of from about 50° C. to about ?40° C., and particularly from about 23° C. to about ?40° C. In one embodiment, the polymer compositions are used to mold the outer shell of a snow ski boot.
    Type: Grant
    Filed: March 13, 2013
    Date of Patent: May 3, 2016
    Assignee: Ticona LLC
    Inventors: Mukul Kaushik, Dirk Zierer, Kenneth Leon Price, James Louis Coleman
  • Patent number: 9258891
    Abstract: Provided is a prepreg suffering little resin particle fall-off and little resin peeling during prepreg production and during handling in order to have excellent dielectric properties for PPE and favorable adhesiveness. A PPE-containing prepreg constituted of a base material and a curable resin composition including PPE particles, wherein the prepreg is characterized in that (1) PPE extracted from the prepreg using a mixed solvent of toluene and methanol in a mass ratio of 95:5 includes PPE particles (A) insoluble in the mixed solvent, (2) the amount of PPE contained in the PPE particles (A) is 70 mass % or higher, and (3) the number-average molecular weight of the PPE contained in the PPE particles (A) is 8,000-40,000.
    Type: Grant
    Filed: March 19, 2013
    Date of Patent: February 9, 2016
    Assignee: ASAHI KASEI E-MATERIALS CORPORATION
    Inventors: Masaaki Endo, Takamitsu Utsumi, Shoji Otani
  • Patent number: 9181430
    Abstract: Disclosed herein are compositions comprising a polymer comprising polyetherimide, polyetheretherketone, polyamide, polyoxyalkylene, or polyalkylene terephthalate, or a mixture thereof, and ultra-high molecular weight polyethylene, wherein the ultra-high molecular weight polyethylene comprises a surface modifier. Also disclosed are articles comprising one or more of the described compositions. This abstract is intended as a scanning tool for purposes of searching in the particular art and is not intended to be limiting of the present invention.
    Type: Grant
    Filed: February 4, 2014
    Date of Patent: November 10, 2015
    Assignee: SABIC Global Technologies B.V.
    Inventors: Reema Sinha, Susanta Mitra, Pramila Sharma, Domenico La Camera, Mohammad Moniruzzaman
  • Patent number: 9175159
    Abstract: A thermoplastic elastomer composition containing a (meth)acrylic elastomer (component A), a thermoplastic resin having a melting point of from 180° to 350° C., and having a functional group reactive with an epoxy group (component B), and a vinyl copolymer having a solubility in tetrahydrofuran and having two or more epoxy groups in one molecule, on average (component C), wherein proportions of each of the components are: 40 to 95 parts by weight of the (meth)acrylic elastomer (component A), 5 to 60 parts by weight of the thermoplastic resin (component B), and 0.1 to 30 parts by weight of the vinyl copolymer (component C), a total of the (meth)acrylic elastomer (component A) and the thermoplastic resin (component B) being 100 parts by weight, wherein the component C is constituted by monomer units containing 50% by weight or more of monomer units (monomer unit c1) of which SP value is from 17.5 to 25.0, and wherein a flow beginning temperature is from 180° to 350° C.
    Type: Grant
    Filed: January 17, 2013
    Date of Patent: November 3, 2015
    Assignee: ARONKASEI CO., LTD.
    Inventor: Madoka Furuta
  • Patent number: 9150006
    Abstract: Thermoplastic articles made from polyesters modified by neopentyl glycol laminate more quickly than cyclohexanedimethanol-modified versions yet retain the properties that make modified polyesters the material of choice in this market—water-like color and clarity, high impact strength, low lamination temperature and low flammability. For situations where a faster cycle time is not needed, articles laminated with neopentyl glycol-modified polyesters can alternatively be manufactured at lower temperatures.
    Type: Grant
    Filed: June 23, 2011
    Date of Patent: October 6, 2015
    Assignee: Eastman Chemical Company
    Inventors: Ryan Thomas Neill, Michael Eugene Donelson, Bryan Steven Bishop
  • Patent number: 9051459
    Abstract: A thermoplastic composition comprising the melt blending product of one or more thermoplastic polymers; and from 2 to 20 PHR, of one or more gloss reducing additives wherein each gloss reducing additive comprises a (meth)acrylate copolymer having a glass transition temperature of greater than or equal to 40° C. and 0.001 to 0.04 PHM derived from one or more crosslinking monomers and/or graft-linking agents having two or more ethylenically unsaturated radicals capable of free-radical polymerization, wherein a test specimen produced from the thermoplastic composition has roughness according to DIN 4768 of Ra greater than or equal to 0.6 microns, Rz greater than or equal to 6 microns, Rmax greater than or equal to 7 microns, and a gloss less than 65, 75 degree angle, is provided. Methods for producing the thermoplastic compositions, methods for producing articles from the thermoplastic compositions and such articles are also provided.
    Type: Grant
    Filed: October 10, 2011
    Date of Patent: June 9, 2015
    Assignee: Rohm and Haas Company
    Inventors: Paul R. Van Rheenen, Veera Nelliappan, Seth T. Stewart
  • Patent number: 9034983
    Abstract: A method for preparing poly(butylene terephthalate-co-adipate) copolymer by polymerizing 1,4-butane diol, an adipic acid component and an aromatic dicarboxy compound derived from polyethylene terephthalate, and a polyester component residue in the presence of a catalyst under conditions effective to form poly(butylene terephthalate-co-adipate) oligomers; adding a quencher; and reacting the quenched poly(butylene terephthalate-co-adipate) oligomers with a chain extender.
    Type: Grant
    Filed: March 1, 2012
    Date of Patent: May 19, 2015
    Assignee: SAUDI BASIC INDUSTRIES CORPORATION
    Inventors: Husnu Alidedeoglu, Ganesh Kannan
  • Publication number: 20150119489
    Abstract: Provided is a thermoplastic resin composition including: an acrylic graft copolymer (A), an aromatic vinyl-vinyl cyanide compound copolymer (B), a polyalkyl(meth)acrylate resin (C), and an acrylic compound-grafted silicon-based impact reinforcing agent (D). The thermoplastic resin composition can have excellent impact resistance and colorability with minimal or no deterioration of dimensional stability, molding processability, weather resistance and mechanical and physical properties.
    Type: Application
    Filed: October 22, 2014
    Publication date: April 30, 2015
    Inventor: Young Hyo KIM
  • Patent number: 9018300
    Abstract: Molding compositions comprising: a composition (I) present in an amount of 10 to 100% by weight, based on the molding composition, wherein the composition (I) comprises: (A) 40 to 95% by weight, based on the composition (I), of a copolymer comprising: ?-methylstyrene in an amount of 55 to 90% by weight, acrylonitrile in an amount of 10 to 50% by weight, and one or more other monomers in an amount of 0 to 5% by weight, wherein the percentages by weight of the ?-methylstyrene, the acrylonitrile and the one or more other monomers are based on the weight of component (A); (B) 2.5 to 75% by weight, based on the composition (I), of a polymer comprising: a vinylaromatic monomer in an amount of 60 to 90% by weight, acrylonitrile in an amount of 8.01 to 39.8% by weight, and maleic anhydride in an amount of 0.2 to 1.99% by weight, wherein the percentages by weight of the vinylaromatic monomer, the acrylonitrile and the maleic anhydride are based on the weight of component (B); and (C) 2.
    Type: Grant
    Filed: June 13, 2006
    Date of Patent: April 28, 2015
    Assignee: Styrolution Europe GmbH
    Inventors: Martin Weber, Klaus Muehlbach, Peter Ittemann, Stefan Grutke, Nicolas Inchaurrondo
  • Patent number: 9018295
    Abstract: Golf balls that have at least one layer formed from a cationic polyurea material. In particular, the compositions of the invention, which include a polymer backbone including urea linkages with cationic groups, may be formed from an isocyanate-containing component and an isocyanate-reactive component, at least one of which includes precursor cationic groups, in the presence of an alkylating, quaternizing, or ternarizing agent.
    Type: Grant
    Filed: December 12, 2008
    Date of Patent: April 28, 2015
    Assignee: Acushnet Company
    Inventors: Murali Rajagopalan, Shawn Ricci, Michael J. Sullivan, Kevin M. Harris, Pamela V. Arnold
  • Publication number: 20150111034
    Abstract: The present disclosure provides a polyolefin-based composition, suitable for use as a tie-layer adhesive composition, and a process for making the polyolefin-based composition. The polyolefin-based composition is made from and/or contains a grafted polyolefin copolymer composition, a base resin composition, and optionally, an additives composition. The grafted polyolefin copolymer composition is made from and/or contains a grafted polyolefin composition, an olefin elastomer composition, and a long-chain branched polyolefin composition. The grafted polyolefin is coupled to the olefin elastomer and the long-chain branched polyolefin.
    Type: Application
    Filed: October 17, 2013
    Publication date: April 23, 2015
    Applicant: Equistar Chemicals, LP
    Inventor: MAGED G. BOTROS
  • Patent number: 9006330
    Abstract: Disclosed are a thermal stabilizer-free thermoplastic resin composition and a method of preparing the same. The thermal stabilizer-free thermoplastic resin composition has superior impact resistance, falling ball impact resistance and gloss without using a separate thermal stabilizer. Particularly, the thermal stabilizer-free thermoplastic resin composition improves production efficiency when applied to a squeezing dehydrator because the thermoplastic resin composition is prepared without using a drying process.
    Type: Grant
    Filed: December 6, 2012
    Date of Patent: April 14, 2015
    Assignee: LG Chem, Ltd.
    Inventors: Bong Keun Ahn, Eun Seon Park, Keun Hoon Yoo, Joo Byung Chai, Yu Sung Jung, Won Deok Han, Tae Young Jeon
  • Patent number: 8993697
    Abstract: A polymer comprising a conducting or semiconducting segment coupled to a polymer segment having an insulating polymer backbone, the polymer further comprising a RAFT functional group coupled to the polymer segment, wherein there is no RAFT functional group in between the conducting or semiconducting segment and the polymer segment.
    Type: Grant
    Filed: June 28, 2013
    Date of Patent: March 31, 2015
    Assignee: Commonwealth Scientific and Industrial Research Institute Organisation
    Inventors: Ming Chen, Graeme Moad, Ezio Rizzardo, Richard Alexander Evans, Matthias Haeussler
  • Publication number: 20150072142
    Abstract: The present invention provides a polylactic acid film or sheet having tear strength so as not to break or tear during, for example, production or processing of the film or sheet or winding thereof into a roll, and causing neither melt nor deformation at high temperatures more than 100° C. In the polylactic acid film or sheet according to the present invention, the tear strength is not less than 100 N/mm when the film or sheet is torn at least in a flow direction (MD), a rate of dimensional change due to heating is not more than ±3% in the flow direction (MD) and a transverse direction (TD), and a rate of dimensional change due to loaded heating is not more than ±3% in the flow direction (MD).
    Type: Application
    Filed: December 21, 2012
    Publication date: March 12, 2015
    Applicant: NITTO DENKO CORPORATION
    Inventors: Hiroki Senda, Shigeki Ishiguro, Satomi Yoshie, Yuka Sekiguchi, Rie Hayashiuchi, Asuka Endo
  • Publication number: 20150072094
    Abstract: The present invention relates to a single- or multi-layered synthetic film primarily consisting of biodegradable polymers, said synthetic film consisting of one or more layers (a) of at least one biodegradable polymer and 1-35% by weight, relative to the total weight of the layer (a), of at least one modified, thermoplastic copolymer of ?,?-unsaturated olefins having 2-10 carbon atoms and (meth)acrylic acid and/or at least one (meth)acrylic acid derivative that is grafted, preferably with cyclic anhydride groups and/or carboxyl groups and/or ester groups, said invention further relating to a use of such a synthetic film as packaging material.
    Type: Application
    Filed: March 25, 2013
    Publication date: March 12, 2015
    Applicant: HUHTAMAKI FILMS GERMANY GMBH & CO. KG
    Inventors: Karl Mauser, Kurt Stark, Christian Schuetz
  • Publication number: 20150065637
    Abstract: A thermoplastic resin composition which contains (A) a graft copolymer that is obtained by grafting at least two kinds of monomers, which are selected from the group consisting of aromatic vinyl monomers, vinyl cyanide monomers and other copolymerizable monomers, onto a rubbery polymer, (B) a polymer that is obtained by polymerizing at least two kinds of monomers, which are selected from the group consisting of aromatic vinyl monomers, vinyl cyanide monomers and other copolymerizable monomers, and (C) a polyester that contains at least an alicyclic diol and an aromatic dicarboxylic acid. When the total of the components (A)-(C) is taken at 100% by mass, the component (A) is 15-50% by mass; and the component (A) has a linear expansion coefficient of from 12.5×10?5/° C. to 19×10?5/° C.
    Type: Application
    Filed: March 29, 2013
    Publication date: March 5, 2015
    Applicant: ASAHI KASEI CHEMICALS CORPORATION
    Inventors: Akiko Sugioka, Tomoyuki Fujisawa
  • Patent number: 8952096
    Abstract: The invention provides graft copolymers obtainable by A) free-radically initiated polymerization of one or more vinyl esters a), one or more further ethylenically unsaturated monomers b) comprising at least one further functional group, B) subsequent polymer-analogous reaction of the copolymers from stage A) by joining the monomer units b) thereof to one or more further monomers b) such that at least one free-radically polymerizable group is introduced into the copolymers from stage A), characterized in that C) one or more ethylenically unsaturated monomers are polymerized onto the products from stage B) by free-radically initiated polymerization.
    Type: Grant
    Filed: December 9, 2009
    Date of Patent: February 10, 2015
    Assignee: Wacker Chemie AG
    Inventors: Florian Bauers, Michael Tobias Zarka
  • Publication number: 20150025197
    Abstract: A process for preparing a reinforced and reactive thermoplastic composition having a continuous phase based on a thermoplastic polymer and dispersed therein is a discontinuous phase based on a reactive reinforcing agent that may be immiscible with the thermoplastic polymer is provided. A composition obtained by this process is also provided. The reinforcing agent is selected from the group consisting of epoxy resins, polyorganosiloxanes having SiH functional group(s), diisocyanates or polyisocyanates and mixtures thereof, comprises a grafting, a branching and/or a crosslinking, that are carried out in situ, by reactive compounding of these phases with a shear rate greater than 102 s?1, of the reinforcing agent onto the chain of the thermoplastic polymer, so that the discontinuous phase is dispersed homogeneously in the continuous phase in the form of nodules having a number-average size of less than 5 ?m.
    Type: Application
    Filed: April 4, 2014
    Publication date: January 22, 2015
    Applicant: Hutchinson
    Inventors: Nicolas Garois, Philippe Sonntag, Gregory Martin, Matthieu Vatan, Jacques Drouvroy
  • Publication number: 20150017451
    Abstract: There is described a polymer blend of a first and second polymer comprising: a) a first polymer of: vinyl (co)polymer; alkyd; urethane acrylic copolymer; polyurethane and/or polyester; b) a second copolymer from: b1) optionally at least 10 wt-% of one or derivatives of itaconic acid and/or isomers thereof; b2) up to 20 wt-% of one or more acid functional (or potentially acid functional) monomer(s) and b3) vinyl monomer(s) where wt % of each monomer (b1 to b3) is based on total (b) and where at least one of the first and second polymer is obtained from an itacon-functional monomer such as itaconic acid and/or its derivatives.
    Type: Application
    Filed: February 4, 2013
    Publication date: January 15, 2015
    Inventors: Tijs Nabuurs, Jeffrey Stubbs, Matthew Stewart Gebhard, Gerardus Cornelis Overbeek
  • Patent number: 8889766
    Abstract: A method of forming a solid-state polymer can include grafting a graft polymer to nanoparticles to provide grafted nanoparticles, and dispersing the grafted nanoparticles in a polymer matrix to provide a specified loading of the grafted nanoparticles within the polymer matrix to form a solid-state polymer. A solid-state polymer can include grafted nanoparticles comprising a polymer graft grafted to nanoparticles, and a polymer matrix, in which the grafted nanoparticles are dispersed to form a solid-state polymer, the dispersion configured to provide a specified loading of the grafted nanoparticles within the solid-state polymer.
    Type: Grant
    Filed: March 1, 2012
    Date of Patent: November 18, 2014
    Assignee: The Trustees of Columbia University in the City of New York
    Inventors: Jeffrey William Kysar, Sanat K. Kumar, Benjamin Fragneaud, Damien Maillard
  • Patent number: 8877862
    Abstract: Biodegradable compositions containing an aliphatic-aromatic copolyester derived from aromatic polyesters. Methods of making the compositions and articles made from the compositions.
    Type: Grant
    Filed: July 15, 2011
    Date of Patent: November 4, 2014
    Assignee: Saudi Basic Industries Corporation
    Inventors: Husnu Alp Alidedeoglu, Ganesh Kannan
  • Publication number: 20140322487
    Abstract: The thermoplastic resin composition of the present invention comprises: (A) a rubber-modified aromatic vinyl-based graft copolymer resin; (B) a polyester resin; (C) a maleimide-based polymer; (D) a copolymer resin of a modified aromatic vinyl compound-cyanide vinyl compound comprising a functional group which can react with a polyester; and (E) an aromatic vinyl-based resin copolymerized with an alkyl(meth)acrylate, wherein the aromatic vinyl-based resin copolymerized with the alkyl(meth)acrylate (E) is included in the composition at approximately 6 to 12 percent by weight.
    Type: Application
    Filed: September 14, 2012
    Publication date: October 30, 2014
    Applicant: Chell Industries Inc.
    Inventors: Dong Kil Choi, Dong Min Park, Sung Hee Ahn, Jae Won Lee
  • Publication number: 20140316067
    Abstract: A method of preparing a polyester/polyolefin hot-melt adhesive for use in a solar cell bus bar is disclosed, in which 2,6-naphthalenedicarboxylic acid and ethylene glycol are first sequentially subjected in a predetermined ratio to esterification and polycondensation in the presence of a certain amount of a titanium-based catalyst to result in a polyethylene naphthalate (PNT) with a weight-average molecular weight of 16,000˜20,000. The PNT is then melt-blended with a low-density polyethylene (LDPE) in the presence of a compatibilizer to produce the hot-melt adhesive that can be shaped into films having a high light transmittance, good mechanical properties, high heat and yellowing resistance and thus particularly suitable for use in solar cell bus bars.
    Type: Application
    Filed: October 24, 2013
    Publication date: October 23, 2014
    Applicant: Shanghai Tianyang Hot Melt Adhesive Co., Ltd.
    Inventors: Weilan Xue, Ping Zhao, Zhelong Li, Wanyu Zhu, Zuoxiang Zeng, Xu Gao, Juan Liu
  • Patent number: 8852747
    Abstract: The invention relates to coextrusion binders including renewable and/or biodegradable polymers having good adhesion properties: at least one renewable and/or biodegradable polymer (A) grafted with a functional monomer including at least one reactive function, the grafting ratio being <1% in weight of the grafted polymer (A); at least one non-grafted renewable and/or biodegradable polymer (B) identical to (A) or compatible with (A) optionally a softener (C); and optionally a starch-based material (D). The invention also relates to multilayered structures including the binder of the present invention, in which the layers are preferably made of renewable and/or biodegradable compounds. The multilayered structures are advantageously useful in the field of food packaging.
    Type: Grant
    Filed: May 14, 2008
    Date of Patent: October 7, 2014
    Assignee: Arkema France
    Inventors: Fabrice Chopinez, Johann Laffargue, Jeau-Laurent Pradel, Damien Rauline, Samuel Devisme
  • Patent number: 8822597
    Abstract: A process for producing rubber modified polymers having an increased rubber phase volume, including feeding a vinyl aromatic monomer and an elastomer to a polymerization reactor to form a reaction mixture, polymerizing the reaction mixture, combining a copolymer to the polymerized reaction mixture to form a combined mixture, subjecting the combined mixture to further polymerization, and obtaining a rubber modified polymer product from the further polymerization.
    Type: Grant
    Filed: April 28, 2011
    Date of Patent: September 2, 2014
    Assignee: Fina Technology, Inc.
    Inventors: Carlos DeAnda, Graciela Morales, Jose M. Sosa, David Knoeppel
  • Patent number: 8816008
    Abstract: The invention relates to an impact modified thermoplastic resin comprising a polymeric impact modifier with a core-shell structure comprising 2-octylacrylate.
    Type: Grant
    Filed: September 20, 2011
    Date of Patent: August 26, 2014
    Assignee: Arkema France
    Inventors: Rosangela Pirri, Stephane Girois, Pascale Dargelos, Magali Bergeret-Richaud
  • Publication number: 20140235791
    Abstract: Films (or a cap layer of co-extruded films) and methods of forming the same are described herein. The films generally include a modified olefin based polymer including polypropylene and from 1 wt. % to 30 wt. % polylactic acid (PLA), wherein the modified olefin based polymer exhibits a seal initiation temperature (SIT) that is at least 5° C. less than a seal initiation temperature of the polypropylene absent the PLA and a hot tack range of at least 20° C.
    Type: Application
    Filed: March 20, 2014
    Publication date: August 21, 2014
    Applicant: FINA TECHNOLOGY, INC.
    Inventors: Fengkui Li, John Ashbaugh
  • Patent number: 8809455
    Abstract: A dynamically vulcanized alloy contains at least one isobutylene-containing elastomer and at least one thermoplastic resin, wherein the elastomer is present as a dispersed phase of small vulcanized or partially vulcanized particles in a continuous phase of the thermoplastic resin. The dynamically vulcanized alloy also contains an anhydride functionalized oligomer. The alloy maintains a high Shore A hardness value while obtaining improved flowability for processing.
    Type: Grant
    Filed: August 27, 2009
    Date of Patent: August 19, 2014
    Assignee: ExxonMobil Chemical Patents Inc.
    Inventors: Maria D. Ellul, Anthony Jay Dias, Rodney May
  • Publication number: 20140228518
    Abstract: Methods for obtaining toughened products from unsorted post-consumer plastics is disclosed. A toughened plastic composition is further disclosed, which includes a first thermoplastic polymer, a different second thermoplastic polymer, and a maleic anhydride-grafted ethylene/propylene rubber compatibilizer.
    Type: Application
    Filed: April 16, 2014
    Publication date: August 14, 2014
    Applicant: King Abdulaziz City for Science and Technology
    Inventors: Fares D. Alsewailem, Abdulmajeed M. Algaflah, Yazeed A. Binkheder
  • Publication number: 20140227516
    Abstract: A carbon fiber sizing agent imparts good bonding performance to carbon fiber, is used to reinforce a thermoplastic matrix resin, and provides a carbon fiber strand applied with the sizing agent and a fiber-reinforced composite reinforced with the carbon fiber strand. The sizing agent for carbon fiber is used to reinforce thermoplastic matrix resin. The sizing agent essentially contains a polymer component having a glass transition temperature of at least 20 deg.C. and exhibits no endothermic peaks indicating an endothermic heat of fusion due to crystalline melting of at least 3 J/g in a determination with a DSC. The weight ratio of the polymer component is 10 to 100 wt % of the nonvolatile components of the sizing agent. The polymer component is at least one component selected from the group consisting of an aromatic polyester resin, aromatic polyester-polyurethane resin and amine-modified aromatic epoxy resin.
    Type: Application
    Filed: October 15, 2012
    Publication date: August 14, 2014
    Inventors: Yoshio Hashimoto, Yusuke Shimizu, Mikio Nakagawa
  • Publication number: 20140228517
    Abstract: A composition comprising a blend of a polyolefin, polylactic acid, and a reactive modifier. A method of producing an oriented film comprising reactive extrusion compounding a mixture comprising polypropylene, polylactic acid, a reactive modifier to form a compatibilized polymeric blend, casting the compatibilized polymeric blend into a film, and orienting the film. A method of preparing a reactive modifier comprising contacting a polyolefin, a multifunctional acrylate comonomer, and an initiator under conditions suitable for the formation of an epoxy-functionalized polyolefin wherein the epoxy-functionalized polyolefin has a grafting yield of from 0.2 wt. % to 15 wt. %.
    Type: Application
    Filed: April 15, 2014
    Publication date: August 14, 2014
    Applicant: FINA TECHNOLOGY INC.
    Inventors: Fengkui Li, Tim J. Coffy, Michel Daumerie
  • Patent number: 8802751
    Abstract: The invention relates to impact-modified polymer compositions, containing a polymer blend of polycarbonate with polyester and/or polyamide, plus an impact modifier blend of core/shell and functional polyolefin impact modifiers. The impact modifiers can provide the polymer blend composition with improved impact strength at equivalent loading, and also allow for higher amounts of polyester and/or polyamide in the blend without sacrificing impact strength.
    Type: Grant
    Filed: June 9, 2010
    Date of Patent: August 12, 2014
    Assignee: Arkema Inc.
    Inventors: Jason M. Lyons, Stephane Girois
  • Patent number: 8779050
    Abstract: The present invention relates to non-aging, impact-modified polycarbonate compositions and molding compositions comprising: A) from 60 to 86 parts by weight (based on the sum of components A+B+C) of aromatic polycarbonate and/or aromatic polyester carbonate, B) from 4 to 12 parts by weight (based on the sum of components A+B+C) of graft polymer comprising: B.1 from 10 to 50 wt. % (based on the graft polymer B) of a shell of at least one vinyl monomer, and B.2 from 90 to 50 wt. % (based on the graft polymer B) of a graft base of silicone-acrylate composite rubber, C) from 10 to 30 parts by weight (based on the sum of components A+B+C) of a polymer or copolymer based on vinyl monomer, and D) from 0 to 20 parts by weight of polymer additives.
    Type: Grant
    Filed: July 20, 2012
    Date of Patent: July 15, 2014
    Assignee: Bayer Materialscience AG
    Inventors: Achim Feldermann, Andreas Seidel, Eckhard Wenz
  • Patent number: 8759431
    Abstract: A durable polyoxymethylene composition includes a polyoxymethylene copolymer with 1,3-dioxolane as a comonomer, a lubricant, an inorganic filler, a nucleating agent including a sodium salt, a stabilizer, an anti-static agent. A ramp is made of the durable polyoxymethylene. The ramp and the durable polyoxymethylene have excellent micro-wear-resistant property.
    Type: Grant
    Filed: May 30, 2012
    Date of Patent: June 24, 2014
    Assignee: Min Aik Technology Co., Ltd.
    Inventors: Jung-Pao Chang, Chi-En Lin
  • Patent number: 8753728
    Abstract: The properties of melt blends of specific aliphatic-aromatic copolyesters and starch are improved by addition of a combination of polylactic acid, graft copolymers such maleic anhydride grafted polyethylene and maleic anhydride grafted polystyrene, and a hindered phenolic antioxidant. The blends exhibit increased melt strength and maximum draw down ratio versus blends of only aliphatic-aromatic copolyesters and starch. Films made from the blend are compostable and exhibit an attractive combination of mechanical and rheological properties for packaging materials.
    Type: Grant
    Filed: December 19, 2012
    Date of Patent: June 17, 2014
    Assignee: E I du Pont de Nemours and Company
    Inventor: Rameshchandra M Gohil