Solid Graft Or Graft-type Copolymer Derived From Ethylenic Reactants Only Patents (Class 525/64)
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Patent number: 11905405Abstract: Described herein are polymer compositions including at least one semi-crystalline, semi-aromatic polyester polymer and at least one impact modifier. The blends have excellent impact resistance and excellent dimensional stability. The blends also have excellent chemical resistance, whiteness, colorability and anodization resistance. The polymer compositions can optionally include at least one amorphous polymer. The at least one amorphous polymer can be an amorphous polycarbonate polymer or an amorphous polyester polymer or a polyester-carbonate. In some embodiments, the polymer composition can optionally include one or more additives. The polyester compositions described herein can be desirably incorporated into mobile electronic device components.Type: GrantFiled: January 26, 2022Date of Patent: February 20, 2024Assignee: SOLVAY SPECIALTY POLYMERS USA, LLCInventors: Mohammad Jamal El-Hibri, Keshav S. Gautam
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Patent number: 11702536Abstract: A thermoplastic resin composition includes 100 parts by weight of a base resin including 5 to 40% by weight of a vinyl cyanide compound-conjugated diene rubber-aromatic vinyl compound graft copolymer (a) containing conjugated diene rubber having a particle diameter of 0.05 ?m to 0.2 ?m, 5 to 40% by weight of a vinyl cyanide compound-conjugated diene rubber-aromatic vinyl compound graft copolymer (b) containing conjugated diene rubber having a particle diameter of greater than 0.2 ?m and less than or equal to 0.5 ?m, and 50 to 80% by weight of an aromatic vinyl compound-vinyl cyanide compound copolymer (c); and more than 0.01 parts by weight and less than 2 parts by weight of a compound having a kinematic viscosity (25° C.) greater than 5 cSt and less than 200 cSt. The resin composition has excellent plating characteristics.Type: GrantFiled: September 6, 2019Date of Patent: July 18, 2023Assignee: LG CHEM, LTD.Inventors: Ju Hyeong Lee, Byoung Il Kang, Seo Hwa Kim, Sejin Han, Seongkyun Kim
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Patent number: 11401404Abstract: Provided is a process for making a dispersion of composite particles comprising (i) providing a dispersion of crosslinked polyolefin particles in an aqueous medium, (ii) performing emulsion polymerization on one or more vinyl monomers in the presence of the crosslinked polyolefin particles to produce the dispersion of composite particles.Type: GrantFiled: November 29, 2018Date of Patent: August 2, 2022Assignees: Dow Global Technologies LLC, Rohm and Haas CompanyInventors: Liang Chen, Andy Jun Li, Matthew Carter, Robert S. Moglia, Ralph C. Even, Miroslav Janco, Carlos A. Cruz, Yannick Saint-Gerard
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Patent number: 11396596Abstract: Provided is a heat-resistant resin composition which includes: a base resin including: a graft copolymer prepared by graft polymerization of a diene-based rubber polymer with an aromatic vinyl-based monomer and a vinyl cyan-based monomer; a first styrene-based copolymer including an aromatic vinyl-based unit and a vinyl cyan-based unit; a second styrene-based copolymer including a maleimide-based unit, an aromatic vinyl-based unit, and a vinyl cyan-based unit; and a carbonate-based polymer; and a third styrene-based copolymer including an aromatic vinyl-based unit and a maleic acid-based unit.Type: GrantFiled: December 4, 2018Date of Patent: July 26, 2022Assignee: LG CHEM, LTD.Inventors: Do Hyeong Kim, Ho Namgung, Seong Lyong Kim, Dae San Jung
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Patent number: 11370903Abstract: A polypropylene composition for a dyeable polypropylene filament yarn includes a polypropylene having a melt flow rate ranging from 30 g/10 min to 40 g/10 min, a polyester serving to modify the polypropylene and having a melt flow rate ranging from 40 g/10 min to 50 g/10 min, and a compatibilizer serving to improve compatibility between the polypropylene and the polyester. The polypropylene composition has a melt flow rate ranging from 30 g/10 min to 40 g/10 min.Type: GrantFiled: December 17, 2019Date of Patent: June 28, 2022Assignee: GUANG XIN POLYMER COMPOSITES CO., LTDInventors: Wen-Pin Hung, Hung-Chia Yen
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Patent number: 11091660Abstract: The present invention relates to the use of a thermosetting polymeric powder composition in a 3D printing process to produce a 3D duroplast, wherein the composition comprises at least one curable polymeric binder material and at least one thermoplast having a Tg and/or Mp below the temperature provided in a pass of the printing process and wherein during each pass of the printing process said polymeric binder material is at least partially cured within the layer thus formed and also at least partially crosslinked with the previous layer. The invention furthermore relates to a 3D printing process using such a thermosetting polymeric powder composition and a 3D-printing product obtained when using such a thermosetting polymeric powder composition.Type: GrantFiled: March 13, 2018Date of Patent: August 17, 2021Assignee: TIGER COATINGS GMBH & CO. KGInventors: Le-Huong Nguyen, Carsten Herzhoff, Bernhard Brüstle, Gerhard Buchinger
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Patent number: 11078351Abstract: This disclosure relates to a continuous solution polymerization process where ethylene interpolymer products having an improved color index; for example, products having higher whiteness (Whiteness Index (WI)) and lower yellowness (Yellowness Index (YI)). Product color was improved by adjusting selected solution polymerization reaction conditions. The disclosed ethylene interpolymer products have improved color relative to comparative polyethylene compositions.Type: GrantFiled: March 5, 2018Date of Patent: August 3, 2021Assignee: NOVA Chemicals (International) S.A.Inventors: Fazle Sibtain, Christopher John Brooke Dobbin, Kenneth Edward Taylor, Hamidreza Khakdaman, P Scott Chisholm
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Patent number: 11046864Abstract: The problem to be solved by the present invention is to provide a polyester resin excellent in various properties wherein the film formability is good, film fracture (hairs) and scraping (galling) are not easily generated in the drawing/ironing process when applied to a metal-sheet-coating polyester film, the film surface is not damaged when used as the inner-surface film for a metallic can, and the metallic can is hardly corroded (dent resistance), by dropping or external impact (denting), after a product is made by enclosing contents into the can.Type: GrantFiled: July 5, 2013Date of Patent: June 29, 2021Assignees: DAIWA CAN COMPANY, Bell Polyester Products, Inc.Inventors: Takashi Kimiduka, Yuji Takeuchi, Junji Matsumura, Masaya Okimoto, Keita Katsuma, Hideaki Tomura, Sadamu Nakatsuka
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Patent number: 10822486Abstract: A thermoplastic resin composition of the present invention comprises: an acrylate-based rubber-modified vinyl-based graft copolymer; aromatic vinyl-cyanide vinyl-based copolymer resin; a first dulling agent; and a second dulling agent, wherein the first dulling agent is a copolymer (PS-g-SAN) in which a styrene-acrylonitrile copolymer is graft-polymerized in polystyrene, and the second dulling agent is a copolymer in which a styrene-acrylonitrile copolymer is graft-polymerized in a poly(ethylene-co-glycidyl methacrylate). The thermoplastic resin composition has excellent low-light properties, impact resistance and fluidity.Type: GrantFiled: August 25, 2017Date of Patent: November 3, 2020Assignee: Lotte Advanced Materials Co., Ltd.Inventors: Ji Eun Park, Kee Hae Kwon, In Choi Kim, Hyeong Seob Shin, Chang Min Hong
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Patent number: 10618259Abstract: A coated substrate which includes a) a fabric substrate layer; b) an adhesive layer which is formed from a first composition comprising a thermoplastic elastomer and an anhydride and/or carboxylic acid functionalized, chlorinated olefin-based polymer that has a chlorine content from 1 to 20 wt %, based on the total weight of the anhydride and/or carboxylic acid functionalized, chlorinated olefin-based polymer and the thermoplastic elastomer; and c) a non-polar olefin-based layer formed from a second composition comprising at least one non-polar olefin-based polymer is provided. Also provided are an adhesive composition and articles comprising the coated substrate.Type: GrantFiled: June 11, 2015Date of Patent: April 14, 2020Assignee: Dow Global Technologies LLCInventors: Haiyang Yu, Yong Chen, Yongchun Chen, Hang Wu
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Patent number: 10392506Abstract: The invention relates to compositions consisting of A) 70 to 90 parts by weight of at least one polycarbonate, B) 10 to 30 parts by weight of at least one graft polymer containing a rubber-elastic particulate graft base, which contains diene, and containing a vinyl co(polymer) shell, C) 0 to 15 parts by weight of at least one additive, wherein the sum of the parts by weight of components A) and B) in the composition is normalized to 100. The invention further relates to the use of the compositions to produce components containing a plastic carrier and a multi-ply metal layer, and to molded bodies produced from the compositions.Type: GrantFiled: July 4, 2016Date of Patent: August 27, 2019Assignee: Covestro Deutschland AGInventors: Andreas Seidel, Wolfgang Schwartmann, Eckhard Wenz, Peter Weimar
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Patent number: 9980885Abstract: A silicone-based copolymer resin powder is prepared by reacting a siloxane oligomer obtained from ring-opening of (a1) a cyclic organosiloxane in the presence of (a3) an acid catalyst and (a4) an anionic surfactant with (a2) a silane coupling agent having an alkoxy group and a polymerizable double bond to obtain (A) a linear or branched organopolysiloxane containing at least 2 silicon-bonded hydroxyl groups per molecule, copolymerizing (A) the linear or branched organopolysiloxane with (B) an ethylenically unsaturated monomer to form a copolymer as a core, and further polymerizing to the copolymer another ethylenically unsaturated monomer as a shell, the powder containing up to 0.3% by weight of the cyclic organosiloxane and up to 1% by weight of the anionic surfactant.Type: GrantFiled: October 31, 2014Date of Patent: May 29, 2018Assignee: Nissin Chemical Industry Co. Ltd.Inventors: Kentaro Watanabe, Akira Yamamoto
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Patent number: 9957385Abstract: The invention relates to blends of vinyl chloride graft copolymers as well as to a method for preparing such vinyl chloride graft copolymers and their blends. The invention also relates to molded articles manufactured by using the blends according to the invention.Type: GrantFiled: February 11, 2013Date of Patent: May 1, 2018Assignee: VESTOLIT GmbH & Co. KGInventors: Davide Brizzolara, Ingo Fischer, Jan-Stephan Gehrke, Dieter Polte, Axel Stieneker, Harald Sturm
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Patent number: 9902850Abstract: A thermoplastic resin composition includes (A) a rubber-modified vinyl-based graft copolymer, (B) a silicone-modified aromatic vinyl-based copolymer, and (C) an aromatic vinyl-unsaturated nitrile-based copolymer. The thermoplastic resin composition can exhibit low-gloss characteristics and a synergistic effect of impact resistance and heat resistance.Type: GrantFiled: June 23, 2015Date of Patent: February 27, 2018Assignee: Lotte Advanced Materials Co., Ltd.Inventors: Bo Eun Kim, Joo Hyun Jang, Kwang Soo Park, Jae Won Heo, Young Sub Jin
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Patent number: 9856371Abstract: A thermoplastic resin composition includes (A) a graft rubber copolymer, (B) an aromatic vinyl-vinyl cyanide-based copolymer, and (C) a silicone-modified aromatic vinyl-vinyl cyanide-based copolymer. The silicone-modified aromatic vinyl-vinyl cyanide-based copolymer (C) has an average particle size of about 100 ?m or less.Type: GrantFiled: June 23, 2015Date of Patent: January 2, 2018Assignee: Lotte Advanced Materials Co., Ltd.Inventors: Bo Eun Kim, Joo Hyun Jang, Jae Won Heo, Kwang Soo Park, Yu Jin Jung, Young Sub Jin
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Patent number: 9796837Abstract: A masterbatch having functionalized silicone with an epoxy group or a secondary amine group as a slip additive, the polyethylene compound that the silicone-containing masterbatch has been let down into, and the plastic articles and films from such compounds having improved slip properties are disclosed. The improved slip properties are evidenced by essentially no migration of the slip additive 12 weeks after manufacturing and a dynamic coefficient of friction value of less than 0.4 and a static coefficient of friction 0.5 or less as measured within the first day of manufacturing according to the ASTM D1894-01 method.Type: GrantFiled: July 15, 2013Date of Patent: October 24, 2017Assignee: PolyOne CorporationInventors: Jerome Alric, Jerome Waeler, Fabien Auvray
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Patent number: 9796839Abstract: A masterbatch having epoxy-functionalized silicone as a slip additive, the polypropylene compound that the silicone-containing masterbatch has been let down into, and the plastic articles and films from such compounds having improved slip properties are disclosed. The improved slip properties are evidenced by (1) essentially no migration of the slip additive 12 weeks after manufacturing, (2) a dynamic coefficient of friction value of less than 0.4 and a static coefficient of friction 0.6 or less within the first day of manufacturing according to the ASTM D1894-01 method, and (3) less than 15% change in the dynamic and static coefficient of friction values between the first day of manufacturing and 20 days after manufacturing.Type: GrantFiled: July 15, 2013Date of Patent: October 24, 2017Assignee: PolyOne CorporationInventors: Jerome Alric, Jerome Waeler, Fabien Auvray
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Patent number: 9777162Abstract: To provide a waterborne curable resin composition that is advantageous for environmental protection measures, can be applied without use of a film-forming assistant and can improve the dispersion stability of the emulsion, and also improve physical properties of the coat such as curability, durability, and stain resistance. A waterborne curable resin composition having an acrylic emulsion produced by emulsion polymerization, wherein the acrylic emulsion contains a curable monomer and/or oligomer in emulsion particles.Type: GrantFiled: October 2, 2006Date of Patent: October 3, 2017Assignee: Nippon Shokubai Co., Ltd.Inventors: Yoshiyuki Yokota, Masaya Uchida
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Patent number: 9670354Abstract: A thermoplastic polymer composition which is excellent in flexibility, mechanical properties, moldability, and particularly in heat resistance and is capable of adhering to ceramics, metals, and synthetic resins even at low temperature (for example, 190° C. or lower) without the treatment with a primer, and a molded product produced by using the thermoplastic polymer composition are described. The thermoplastic polymer composition includes 100 parts by mass of a thermoplastic elastomer (A), 1 to 100 parts by mass of a polyvinyl acetal resin (B), and 5 to 100 parts by mass of a polar group-containing polypropylene resin (C).Type: GrantFiled: August 24, 2011Date of Patent: June 6, 2017Assignee: KURARAY CO., LTD.Inventors: Asako Minamide, Mikio Masuda
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Patent number: 9556345Abstract: The disclosure relates to the use of compounds of specific structure as defoaming wetting agents for aqueous coating systems, for example paints and varnishes. The disclosure is more particularly related to methods of reducing the surface tension and/or increasing the density of an aqueous coating system, which methods include adding alcohol propoxylates to an aqueous coating system. The alcohol propoxylates have the general structure R—O—(PO)xH, in which R is a saturated alkyl radical having 7 to 10 C atoms, PO is a propylene oxide unit, and x is a number in the range from 4 to 6. The resulting aqueous coating composition has good wetting properties, but is low in foam, so it does not disrupt processing operations of the coating system.Type: GrantFiled: May 26, 2011Date of Patent: January 31, 2017Assignee: Cognis IP Management GmbHInventors: Sascha Oestreich, Renate Wolf, Peter Bene
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Patent number: 9434839Abstract: To provide a polybutylene terephthalate resin composition offering excellent flowability, wherein the resin composition raises the weld strength and heat shock resistance of a welded body obtained by welding together molded products obtained by molding the polybutylene terephthalate resin composition. [Solution] A polybutylene terephthalate resin composition comprising a polybutylene terephthalate resin (A) having a weight-average molecular weight of 60,000-80,000 inclusive and an inorganic filler (B). Preferably, also included is 5-20 mass parts of an elastomer (C) relative to 100 mass parts of the polybutylene terephthalate resin (A).Type: GrantFiled: September 27, 2012Date of Patent: September 6, 2016Assignee: WinTech Polymer Ltd.Inventor: Kouichi Sakata
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Thermoplastic resin composition having excellent colorability and mechanical and physical properties
Patent number: 9416266Abstract: Provided is a thermoplastic resin composition including: an acrylic graft copolymer (A), an aromatic vinyl-vinyl cyanide compound copolymer (B), a polyalkyl(meth)acrylate resin (C), and an acrylic compound-grafted silicon-based impact reinforcing agent (D). The thermoplastic resin composition can have excellent impact resistance and colorability with minimal or no deterioration of dimensional stability, molding processability, weather resistance and mechanical and physical properties.Type: GrantFiled: October 22, 2014Date of Patent: August 16, 2016Assignee: Samsung SDI Co., Ltd.Inventor: Young Hyo Kim -
Patent number: 9419284Abstract: A binder resin for an electrode of a nonaqueous electrolyte secondary battery is provided, which is used as the binder resin in a slurry composition for an electrode of a nonaqueous electrolyte secondary battery, containing a binder resin, an active material and an organic solvent.Type: GrantFiled: January 9, 2013Date of Patent: August 16, 2016Assignee: Mitsubishi Rayon Co., Ltd.Inventors: Daisuke Fujikawa, Fumino Momose, Mitsufumi Nodono, Masakazu Ito
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Patent number: 9353255Abstract: Disclosed are an acrylonitrile-acrylate-styrene graft copolymer having a structure including a seed which comprises at least one of an aromatic vinyl compound, a vinyl cyanide compound and an alkyl (meth)acrylate compound, a core which surrounds the seed and comprises alkyl acrylate, and a shell which surrounds the core and comprises at least one of an aromatic vinyl compound, a vinyl cyanide compound and an alkyl (meth)acrylate compound, and having suitably controlled thicknesses and refractive indexes of the respective layers, and a thermoplastic resin composition comprising the acrylonitrile-acrylate-styrene graft copolymer.Type: GrantFiled: July 16, 2013Date of Patent: May 31, 2016Assignee: LG Chem, Ltd.Inventors: Min Jung Kim, Yong Yeon Hwang, Chun Ho Park, Sang Mi Lee, Yeong Min Lee, Eun Soo Kang, Hye Kyung Han
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Patent number: 9332802Abstract: Ski boots and other cold weather articles are described made from polymer compositions that are exceptionally stable at low temperatures. The polymer composition, for instance, may contain a thermoplastic polymer, a thermoplastic elastomer, and an impact modifier. In one embodiment, each of the individual components are selected such that they do not undergo a second order transition within a temperature range of from about 50° C. to about ?40° C., and particularly from about 23° C. to about ?40° C. In one embodiment, the polymer compositions are used to mold the outer shell of a snow ski boot.Type: GrantFiled: December 20, 2012Date of Patent: May 10, 2016Assignee: Ticona LLCInventors: Mukul Kaushik, Dirk Zierer, James L. Coleman, Jeanne Pilis, Kenneth L. Price
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Patent number: 9328229Abstract: Ski boots and other cold weather articles are described made from polymer compositions that are exceptionally stable at low temperatures. The polymer composition, for instance, may contain a thermoplastic polymer, a thermoplastic elastomer, an impact modifier and a wear resistant additive. In one embodiment, various polymer components are selected such that they do not undergo a second order transition within a temperature range of from about 50° C. to about ?40° C., and particularly from about 23° C. to about ?40° C. In one embodiment, the polymer compositions are used to mold the outer shell of a snow ski boot.Type: GrantFiled: March 13, 2013Date of Patent: May 3, 2016Assignee: Ticona LLCInventors: Mukul Kaushik, Dirk Zierer, Kenneth Leon Price, James Louis Coleman
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Patent number: 9258891Abstract: Provided is a prepreg suffering little resin particle fall-off and little resin peeling during prepreg production and during handling in order to have excellent dielectric properties for PPE and favorable adhesiveness. A PPE-containing prepreg constituted of a base material and a curable resin composition including PPE particles, wherein the prepreg is characterized in that (1) PPE extracted from the prepreg using a mixed solvent of toluene and methanol in a mass ratio of 95:5 includes PPE particles (A) insoluble in the mixed solvent, (2) the amount of PPE contained in the PPE particles (A) is 70 mass % or higher, and (3) the number-average molecular weight of the PPE contained in the PPE particles (A) is 8,000-40,000.Type: GrantFiled: March 19, 2013Date of Patent: February 9, 2016Assignee: ASAHI KASEI E-MATERIALS CORPORATIONInventors: Masaaki Endo, Takamitsu Utsumi, Shoji Otani
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Patent number: 9181430Abstract: Disclosed herein are compositions comprising a polymer comprising polyetherimide, polyetheretherketone, polyamide, polyoxyalkylene, or polyalkylene terephthalate, or a mixture thereof, and ultra-high molecular weight polyethylene, wherein the ultra-high molecular weight polyethylene comprises a surface modifier. Also disclosed are articles comprising one or more of the described compositions. This abstract is intended as a scanning tool for purposes of searching in the particular art and is not intended to be limiting of the present invention.Type: GrantFiled: February 4, 2014Date of Patent: November 10, 2015Assignee: SABIC Global Technologies B.V.Inventors: Reema Sinha, Susanta Mitra, Pramila Sharma, Domenico La Camera, Mohammad Moniruzzaman
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Patent number: 9175159Abstract: A thermoplastic elastomer composition containing a (meth)acrylic elastomer (component A), a thermoplastic resin having a melting point of from 180° to 350° C., and having a functional group reactive with an epoxy group (component B), and a vinyl copolymer having a solubility in tetrahydrofuran and having two or more epoxy groups in one molecule, on average (component C), wherein proportions of each of the components are: 40 to 95 parts by weight of the (meth)acrylic elastomer (component A), 5 to 60 parts by weight of the thermoplastic resin (component B), and 0.1 to 30 parts by weight of the vinyl copolymer (component C), a total of the (meth)acrylic elastomer (component A) and the thermoplastic resin (component B) being 100 parts by weight, wherein the component C is constituted by monomer units containing 50% by weight or more of monomer units (monomer unit c1) of which SP value is from 17.5 to 25.0, and wherein a flow beginning temperature is from 180° to 350° C.Type: GrantFiled: January 17, 2013Date of Patent: November 3, 2015Assignee: ARONKASEI CO., LTD.Inventor: Madoka Furuta
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Patent number: 9150006Abstract: Thermoplastic articles made from polyesters modified by neopentyl glycol laminate more quickly than cyclohexanedimethanol-modified versions yet retain the properties that make modified polyesters the material of choice in this market—water-like color and clarity, high impact strength, low lamination temperature and low flammability. For situations where a faster cycle time is not needed, articles laminated with neopentyl glycol-modified polyesters can alternatively be manufactured at lower temperatures.Type: GrantFiled: June 23, 2011Date of Patent: October 6, 2015Assignee: Eastman Chemical CompanyInventors: Ryan Thomas Neill, Michael Eugene Donelson, Bryan Steven Bishop
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Patent number: 9051459Abstract: A thermoplastic composition comprising the melt blending product of one or more thermoplastic polymers; and from 2 to 20 PHR, of one or more gloss reducing additives wherein each gloss reducing additive comprises a (meth)acrylate copolymer having a glass transition temperature of greater than or equal to 40° C. and 0.001 to 0.04 PHM derived from one or more crosslinking monomers and/or graft-linking agents having two or more ethylenically unsaturated radicals capable of free-radical polymerization, wherein a test specimen produced from the thermoplastic composition has roughness according to DIN 4768 of Ra greater than or equal to 0.6 microns, Rz greater than or equal to 6 microns, Rmax greater than or equal to 7 microns, and a gloss less than 65, 75 degree angle, is provided. Methods for producing the thermoplastic compositions, methods for producing articles from the thermoplastic compositions and such articles are also provided.Type: GrantFiled: October 10, 2011Date of Patent: June 9, 2015Assignee: Rohm and Haas CompanyInventors: Paul R. Van Rheenen, Veera Nelliappan, Seth T. Stewart
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Patent number: 9034983Abstract: A method for preparing poly(butylene terephthalate-co-adipate) copolymer by polymerizing 1,4-butane diol, an adipic acid component and an aromatic dicarboxy compound derived from polyethylene terephthalate, and a polyester component residue in the presence of a catalyst under conditions effective to form poly(butylene terephthalate-co-adipate) oligomers; adding a quencher; and reacting the quenched poly(butylene terephthalate-co-adipate) oligomers with a chain extender.Type: GrantFiled: March 1, 2012Date of Patent: May 19, 2015Assignee: SAUDI BASIC INDUSTRIES CORPORATIONInventors: Husnu Alidedeoglu, Ganesh Kannan
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Thermoplastic Resin Composition Having Excellent Colorability and Mechanical and Physical Properties
Publication number: 20150119489Abstract: Provided is a thermoplastic resin composition including: an acrylic graft copolymer (A), an aromatic vinyl-vinyl cyanide compound copolymer (B), a polyalkyl(meth)acrylate resin (C), and an acrylic compound-grafted silicon-based impact reinforcing agent (D). The thermoplastic resin composition can have excellent impact resistance and colorability with minimal or no deterioration of dimensional stability, molding processability, weather resistance and mechanical and physical properties.Type: ApplicationFiled: October 22, 2014Publication date: April 30, 2015Inventor: Young Hyo KIM -
Patent number: 9018300Abstract: Molding compositions comprising: a composition (I) present in an amount of 10 to 100% by weight, based on the molding composition, wherein the composition (I) comprises: (A) 40 to 95% by weight, based on the composition (I), of a copolymer comprising: ?-methylstyrene in an amount of 55 to 90% by weight, acrylonitrile in an amount of 10 to 50% by weight, and one or more other monomers in an amount of 0 to 5% by weight, wherein the percentages by weight of the ?-methylstyrene, the acrylonitrile and the one or more other monomers are based on the weight of component (A); (B) 2.5 to 75% by weight, based on the composition (I), of a polymer comprising: a vinylaromatic monomer in an amount of 60 to 90% by weight, acrylonitrile in an amount of 8.01 to 39.8% by weight, and maleic anhydride in an amount of 0.2 to 1.99% by weight, wherein the percentages by weight of the vinylaromatic monomer, the acrylonitrile and the maleic anhydride are based on the weight of component (B); and (C) 2.Type: GrantFiled: June 13, 2006Date of Patent: April 28, 2015Assignee: Styrolution Europe GmbHInventors: Martin Weber, Klaus Muehlbach, Peter Ittemann, Stefan Grutke, Nicolas Inchaurrondo
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Patent number: 9018295Abstract: Golf balls that have at least one layer formed from a cationic polyurea material. In particular, the compositions of the invention, which include a polymer backbone including urea linkages with cationic groups, may be formed from an isocyanate-containing component and an isocyanate-reactive component, at least one of which includes precursor cationic groups, in the presence of an alkylating, quaternizing, or ternarizing agent.Type: GrantFiled: December 12, 2008Date of Patent: April 28, 2015Assignee: Acushnet CompanyInventors: Murali Rajagopalan, Shawn Ricci, Michael J. Sullivan, Kevin M. Harris, Pamela V. Arnold
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Publication number: 20150111034Abstract: The present disclosure provides a polyolefin-based composition, suitable for use as a tie-layer adhesive composition, and a process for making the polyolefin-based composition. The polyolefin-based composition is made from and/or contains a grafted polyolefin copolymer composition, a base resin composition, and optionally, an additives composition. The grafted polyolefin copolymer composition is made from and/or contains a grafted polyolefin composition, an olefin elastomer composition, and a long-chain branched polyolefin composition. The grafted polyolefin is coupled to the olefin elastomer and the long-chain branched polyolefin.Type: ApplicationFiled: October 17, 2013Publication date: April 23, 2015Applicant: Equistar Chemicals, LPInventor: MAGED G. BOTROS
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Patent number: 9006330Abstract: Disclosed are a thermal stabilizer-free thermoplastic resin composition and a method of preparing the same. The thermal stabilizer-free thermoplastic resin composition has superior impact resistance, falling ball impact resistance and gloss without using a separate thermal stabilizer. Particularly, the thermal stabilizer-free thermoplastic resin composition improves production efficiency when applied to a squeezing dehydrator because the thermoplastic resin composition is prepared without using a drying process.Type: GrantFiled: December 6, 2012Date of Patent: April 14, 2015Assignee: LG Chem, Ltd.Inventors: Bong Keun Ahn, Eun Seon Park, Keun Hoon Yoo, Joo Byung Chai, Yu Sung Jung, Won Deok Han, Tae Young Jeon
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Patent number: 8993697Abstract: A polymer comprising a conducting or semiconducting segment coupled to a polymer segment having an insulating polymer backbone, the polymer further comprising a RAFT functional group coupled to the polymer segment, wherein there is no RAFT functional group in between the conducting or semiconducting segment and the polymer segment.Type: GrantFiled: June 28, 2013Date of Patent: March 31, 2015Assignee: Commonwealth Scientific and Industrial Research Institute OrganisationInventors: Ming Chen, Graeme Moad, Ezio Rizzardo, Richard Alexander Evans, Matthias Haeussler
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Publication number: 20150072142Abstract: The present invention provides a polylactic acid film or sheet having tear strength so as not to break or tear during, for example, production or processing of the film or sheet or winding thereof into a roll, and causing neither melt nor deformation at high temperatures more than 100° C. In the polylactic acid film or sheet according to the present invention, the tear strength is not less than 100 N/mm when the film or sheet is torn at least in a flow direction (MD), a rate of dimensional change due to heating is not more than ±3% in the flow direction (MD) and a transverse direction (TD), and a rate of dimensional change due to loaded heating is not more than ±3% in the flow direction (MD).Type: ApplicationFiled: December 21, 2012Publication date: March 12, 2015Applicant: NITTO DENKO CORPORATIONInventors: Hiroki Senda, Shigeki Ishiguro, Satomi Yoshie, Yuka Sekiguchi, Rie Hayashiuchi, Asuka Endo
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Publication number: 20150072094Abstract: The present invention relates to a single- or multi-layered synthetic film primarily consisting of biodegradable polymers, said synthetic film consisting of one or more layers (a) of at least one biodegradable polymer and 1-35% by weight, relative to the total weight of the layer (a), of at least one modified, thermoplastic copolymer of ?,?-unsaturated olefins having 2-10 carbon atoms and (meth)acrylic acid and/or at least one (meth)acrylic acid derivative that is grafted, preferably with cyclic anhydride groups and/or carboxyl groups and/or ester groups, said invention further relating to a use of such a synthetic film as packaging material.Type: ApplicationFiled: March 25, 2013Publication date: March 12, 2015Applicant: HUHTAMAKI FILMS GERMANY GMBH & CO. KGInventors: Karl Mauser, Kurt Stark, Christian Schuetz
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Publication number: 20150065637Abstract: A thermoplastic resin composition which contains (A) a graft copolymer that is obtained by grafting at least two kinds of monomers, which are selected from the group consisting of aromatic vinyl monomers, vinyl cyanide monomers and other copolymerizable monomers, onto a rubbery polymer, (B) a polymer that is obtained by polymerizing at least two kinds of monomers, which are selected from the group consisting of aromatic vinyl monomers, vinyl cyanide monomers and other copolymerizable monomers, and (C) a polyester that contains at least an alicyclic diol and an aromatic dicarboxylic acid. When the total of the components (A)-(C) is taken at 100% by mass, the component (A) is 15-50% by mass; and the component (A) has a linear expansion coefficient of from 12.5×10?5/° C. to 19×10?5/° C.Type: ApplicationFiled: March 29, 2013Publication date: March 5, 2015Applicant: ASAHI KASEI CHEMICALS CORPORATIONInventors: Akiko Sugioka, Tomoyuki Fujisawa
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Patent number: 8952096Abstract: The invention provides graft copolymers obtainable by A) free-radically initiated polymerization of one or more vinyl esters a), one or more further ethylenically unsaturated monomers b) comprising at least one further functional group, B) subsequent polymer-analogous reaction of the copolymers from stage A) by joining the monomer units b) thereof to one or more further monomers b) such that at least one free-radically polymerizable group is introduced into the copolymers from stage A), characterized in that C) one or more ethylenically unsaturated monomers are polymerized onto the products from stage B) by free-radically initiated polymerization.Type: GrantFiled: December 9, 2009Date of Patent: February 10, 2015Assignee: Wacker Chemie AGInventors: Florian Bauers, Michael Tobias Zarka
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Publication number: 20150025197Abstract: A process for preparing a reinforced and reactive thermoplastic composition having a continuous phase based on a thermoplastic polymer and dispersed therein is a discontinuous phase based on a reactive reinforcing agent that may be immiscible with the thermoplastic polymer is provided. A composition obtained by this process is also provided. The reinforcing agent is selected from the group consisting of epoxy resins, polyorganosiloxanes having SiH functional group(s), diisocyanates or polyisocyanates and mixtures thereof, comprises a grafting, a branching and/or a crosslinking, that are carried out in situ, by reactive compounding of these phases with a shear rate greater than 102 s?1, of the reinforcing agent onto the chain of the thermoplastic polymer, so that the discontinuous phase is dispersed homogeneously in the continuous phase in the form of nodules having a number-average size of less than 5 ?m.Type: ApplicationFiled: April 4, 2014Publication date: January 22, 2015Applicant: HutchinsonInventors: Nicolas Garois, Philippe Sonntag, Gregory Martin, Matthieu Vatan, Jacques Drouvroy
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Publication number: 20150017451Abstract: There is described a polymer blend of a first and second polymer comprising: a) a first polymer of: vinyl (co)polymer; alkyd; urethane acrylic copolymer; polyurethane and/or polyester; b) a second copolymer from: b1) optionally at least 10 wt-% of one or derivatives of itaconic acid and/or isomers thereof; b2) up to 20 wt-% of one or more acid functional (or potentially acid functional) monomer(s) and b3) vinyl monomer(s) where wt % of each monomer (b1 to b3) is based on total (b) and where at least one of the first and second polymer is obtained from an itacon-functional monomer such as itaconic acid and/or its derivatives.Type: ApplicationFiled: February 4, 2013Publication date: January 15, 2015Inventors: Tijs Nabuurs, Jeffrey Stubbs, Matthew Stewart Gebhard, Gerardus Cornelis Overbeek
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Patent number: 8889766Abstract: A method of forming a solid-state polymer can include grafting a graft polymer to nanoparticles to provide grafted nanoparticles, and dispersing the grafted nanoparticles in a polymer matrix to provide a specified loading of the grafted nanoparticles within the polymer matrix to form a solid-state polymer. A solid-state polymer can include grafted nanoparticles comprising a polymer graft grafted to nanoparticles, and a polymer matrix, in which the grafted nanoparticles are dispersed to form a solid-state polymer, the dispersion configured to provide a specified loading of the grafted nanoparticles within the solid-state polymer.Type: GrantFiled: March 1, 2012Date of Patent: November 18, 2014Assignee: The Trustees of Columbia University in the City of New YorkInventors: Jeffrey William Kysar, Sanat K. Kumar, Benjamin Fragneaud, Damien Maillard
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Patent number: 8877862Abstract: Biodegradable compositions containing an aliphatic-aromatic copolyester derived from aromatic polyesters. Methods of making the compositions and articles made from the compositions.Type: GrantFiled: July 15, 2011Date of Patent: November 4, 2014Assignee: Saudi Basic Industries CorporationInventors: Husnu Alp Alidedeoglu, Ganesh Kannan
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Publication number: 20140322487Abstract: The thermoplastic resin composition of the present invention comprises: (A) a rubber-modified aromatic vinyl-based graft copolymer resin; (B) a polyester resin; (C) a maleimide-based polymer; (D) a copolymer resin of a modified aromatic vinyl compound-cyanide vinyl compound comprising a functional group which can react with a polyester; and (E) an aromatic vinyl-based resin copolymerized with an alkyl(meth)acrylate, wherein the aromatic vinyl-based resin copolymerized with the alkyl(meth)acrylate (E) is included in the composition at approximately 6 to 12 percent by weight.Type: ApplicationFiled: September 14, 2012Publication date: October 30, 2014Applicant: Chell Industries Inc.Inventors: Dong Kil Choi, Dong Min Park, Sung Hee Ahn, Jae Won Lee
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Publication number: 20140316067Abstract: A method of preparing a polyester/polyolefin hot-melt adhesive for use in a solar cell bus bar is disclosed, in which 2,6-naphthalenedicarboxylic acid and ethylene glycol are first sequentially subjected in a predetermined ratio to esterification and polycondensation in the presence of a certain amount of a titanium-based catalyst to result in a polyethylene naphthalate (PNT) with a weight-average molecular weight of 16,000˜20,000. The PNT is then melt-blended with a low-density polyethylene (LDPE) in the presence of a compatibilizer to produce the hot-melt adhesive that can be shaped into films having a high light transmittance, good mechanical properties, high heat and yellowing resistance and thus particularly suitable for use in solar cell bus bars.Type: ApplicationFiled: October 24, 2013Publication date: October 23, 2014Applicant: Shanghai Tianyang Hot Melt Adhesive Co., Ltd.Inventors: Weilan Xue, Ping Zhao, Zhelong Li, Wanyu Zhu, Zuoxiang Zeng, Xu Gao, Juan Liu
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Patent number: 8852747Abstract: The invention relates to coextrusion binders including renewable and/or biodegradable polymers having good adhesion properties: at least one renewable and/or biodegradable polymer (A) grafted with a functional monomer including at least one reactive function, the grafting ratio being <1% in weight of the grafted polymer (A); at least one non-grafted renewable and/or biodegradable polymer (B) identical to (A) or compatible with (A) optionally a softener (C); and optionally a starch-based material (D). The invention also relates to multilayered structures including the binder of the present invention, in which the layers are preferably made of renewable and/or biodegradable compounds. The multilayered structures are advantageously useful in the field of food packaging.Type: GrantFiled: May 14, 2008Date of Patent: October 7, 2014Assignee: Arkema FranceInventors: Fabrice Chopinez, Johann Laffargue, Jeau-Laurent Pradel, Damien Rauline, Samuel Devisme
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Patent number: 8822597Abstract: A process for producing rubber modified polymers having an increased rubber phase volume, including feeding a vinyl aromatic monomer and an elastomer to a polymerization reactor to form a reaction mixture, polymerizing the reaction mixture, combining a copolymer to the polymerized reaction mixture to form a combined mixture, subjecting the combined mixture to further polymerization, and obtaining a rubber modified polymer product from the further polymerization.Type: GrantFiled: April 28, 2011Date of Patent: September 2, 2014Assignee: Fina Technology, Inc.Inventors: Carlos DeAnda, Graciela Morales, Jose M. Sosa, David Knoeppel