Contains Two Or More Graft Or Graft-type Copolymers Or A Graft Or A Graft Type Copolymer And At Least One Block Or Block-type Copolymer Patents (Class 525/71)
  • Patent number: 11898029
    Abstract: Provided is a thermoplastic resin composition which includes: a base resin including, in a weight ratio of 70:30 to 90:10, a first copolymer formed by graft polymerization of a diene-based rubber polymer having an average particle diameter of 50 to 200 nm with a first monomer mixture including an alkyl(meth)acrylate-based monomer and an aromatic vinyl-based monomer and a second copolymer which is a copolymer of a second monomer mixture including an alkyl(meth)acrylate-based monomer and an aromatic vinyl-based monomer; and a plasticizer.
    Type: Grant
    Filed: June 4, 2020
    Date of Patent: February 13, 2024
    Assignee: LG CHEM, LTD.
    Inventors: Roo Da Lee, Jeong Su Choi, Won Seok Lee, Sang Hoo Park, Jong Ju Lee
  • Patent number: 11873394
    Abstract: A thermoplastic resin composition, including: 100 parts by weight of a thermoplastic resin (A); and 0.1 to 30 parts by weight of a processing aid (B). The processing aid (B) has a styrene-equivalent weight average molecular weight of from 300,000 to 8,000,000, and contains 60 wt % or more of a polymer (B1) obtained by polymerizing monomers comprising from 40 to 99.9 wt % of styrene, 0.1 to 10 wt % of an acid group-containing monomer, and 0 to 59.9 wt % of a vinyl monomer.
    Type: Grant
    Filed: June 13, 2019
    Date of Patent: January 16, 2024
    Assignee: KANEKA AMERICAS HOLDING, INC.
    Inventor: Yoshiaki Matsuoka
  • Patent number: 11873396
    Abstract: Nanostructures and associated compositions, systems, and methods are provided. In some embodiments, a nanostructure may comprise polymers, intermolecular bonding groups, and a particle. The polymers may be associated with the particle and the intermolecular bonding groups may be associated with at least some of the polymers. In some embodiments, at least some of the intermolecular bonding groups may have a different chemical composition and/or chemical property than the polymers. In some embodiments, nanostructures may reversibly associate with each other via the intermolecular bonding groups to form a material. In some such cases, the intermolecular bonding groups on different nanostructures may reversibly associate with each other. In some embodiments, the nanostructures may be designed, such that the energy required to disassociate at least a portion of the nanostructures in the material is greater than the energy required to dissociate a single association between intermolecular bonding groups.
    Type: Grant
    Filed: August 5, 2021
    Date of Patent: January 16, 2024
    Assignee: Massachusetts Institute of Technology
    Inventors: Robert J. Macfarlane, Jianyuan Zhang, Peter Jeffries Santos, Paul Anthony Gabrys
  • Patent number: 11859075
    Abstract: A core-shell particle including a core containing a perfluoropolymer and a shell containing a non-fluorine resin, the core having a periphery coated with the non-fluorine resin at a coverage of 90% or more, the perfluoropolymer being a polymer containing a polymerized unit based on a perfluoro monomer in an amount of 90 mol % or more relative to all polymerized units, and the shell having a mass of 50 or less relative to a total mass of the core and the shell of 80. Also disclosed is a method for producing the core-shell particle.
    Type: Grant
    Filed: December 13, 2018
    Date of Patent: January 2, 2024
    Assignees: DAIKIN INDUSTRIES, LTD., NISSIN CHEMICAL INDUSTRY CO., LTD
    Inventors: Katsuhide Ohtani, Masamichi Sukegawa, Kazuhiro Yamamura, Shoichi Arima, Takeshi Fukuzumi, Yuji Gama
  • Patent number: 11820849
    Abstract: The present invention relates to a method of preparing an ABS graft copolymer and a method of preparing a thermoplastic resin composition including the ABS graft copolymer. More specifically, the present invention relates to a method of preparing an ABS graft copolymer, in which a predetermined amount of a vinyl aromatic compound and a predetermined amount of a vinyl cyanide compound are grafted to a small-diameter rubber latex before enlarging particle size of the small-diameter rubber latex is performed, and then enlarging particle size of the small-diameter rubber latex is performed by adding a certain amount of a polymer coagulant, and to a method of preparing a thermoplastic resin composition including the ABS graft copolymer. According to the present invention, latex stability may be improved, and an ABS graft copolymer having excellent impact resistance may be prepared.
    Type: Grant
    Filed: February 14, 2019
    Date of Patent: November 21, 2023
    Assignee: LG Chem, Ltd.
    Inventors: Heejung Jeon, Geon Soo Kim, Changhoe Kim, Hyung Joon Kim, Minsu Chae
  • Patent number: 11772362
    Abstract: The present invention relates to a sandwich panel and a method of manufacturing the same. The sandwich panel according to the present invention has high density and improved physical properties such as flexural strength, flexural modulus, bending strength and lightening weighting ratio and is suitable for use in various consumer products or industrial materials.
    Type: Grant
    Filed: April 14, 2021
    Date of Patent: October 3, 2023
    Inventors: Won Kim, Myung Lee, Dayoung Yu, Jiwon Lim, Sang Hyun Rho, Dongmin Song, Seongmoon Jung
  • Patent number: 11655361
    Abstract: Provided is a thermoplastic resin composition which includes: a first copolymer including an acrylic graft copolymer; a second copolymer including an alkyl-substituted styrene-based monomer unit, a vinyl cyanide-based monomer unit, and a (meth)acrylate-based monomer unit; and a third copolymer including an alkyl-unsubstituted styrene-based monomer unit, a vinyl cyanide-based monomer unit, and a (meth)acrylate-based monomer unit. According to the present invention, a thermoplastic resin composition and a thermoplastic resin molded article, which are excellent in heat resistance, colorability, and scratch resistance, can be provided.
    Type: Grant
    Filed: February 10, 2020
    Date of Patent: May 23, 2023
    Assignee: LG CHEM, LTD.
    Inventors: Joon Hwi Jo, Seong Lyong Kim, Tae Hoon Kim, Dae Woo Lee, Jae Bum Seo
  • Patent number: 11549008
    Abstract: Thermoplastic resin composition comprising: (a1) at least one styrene-acrylonitrile copolymer component A1, (a2) at least one acrylonitrile styrene acrylate graft copolymer A2 as impact modifier, (a3) optionally at least one thermoplastic polymer A3 other than components A1 and A2, (b) at least one pigment B, (c) at least one hindered amine UV light stabilizer C, and (d) optionally further polymer additives D, other than components B and C, wherein the UV stabilizing component(s) present in the thermoplastic resin are only hindered amine UV light stabilizer(s) C.
    Type: Grant
    Filed: July 3, 2018
    Date of Patent: January 10, 2023
    Assignee: INEOS STYROLUTION GROUP GMBH
    Inventors: Tobias Schulz, Felix Rattay
  • Patent number: 11352488
    Abstract: Thermoplastic molding composition comprising (A) 40 to 80 wt.-% SAN copolymer (S/AN-ratio 78:22 to 65:35, Mw 80,000 to 250,000 g/mol); (B) 20 to 60 wt.-% SBC block copolymer (monovinylarene 61 to 64 wt.-%) comprising conjugated diene/monovinylarene tapered polymer blocks; and (C) 0 to 5 wt.-% additives and/or processing aids (C); exhibiting ultra-high melt flow with good mechanical, thermal and optical properties, a process for its preparation and its use for the production of bulky and/or thin walled articles.
    Type: Grant
    Filed: April 12, 2019
    Date of Patent: June 7, 2022
    Assignee: INEOS STYROLUTION GROUP GMBH
    Inventors: Norbert Niessner, Gisbert Michels, Thomas W. Cochran, Shridhar Madhav, Kirit Gevaria, Mukesh Modi
  • Patent number: 11352487
    Abstract: The present invention relates to thermoplastic molding compounds F containing at least two graft rubbers P-I and P-II which are processed by the co-precipitation of a mixture of the respective emulsions containing P-I and P-II. The present invention further relates to a method for producing such thermoplastic molding compounds F and to molded bodies obtained from a thermoplastic molding compound F according to the invention.
    Type: Grant
    Filed: May 12, 2016
    Date of Patent: June 7, 2022
    Assignee: INEOS STYROLUTION GROUP GMBH
    Inventor: Gisbert Michels
  • Patent number: 11345800
    Abstract: A tie layer composition comprising from 60 wt. to 95 wt. % of a first polyethylene composition comprising a first molecular weight ethylene-based polymer component and a second molecular weight ethylene-based polymer component, wherein the polyethylene resin has a density from 0.940 to 0.960 g/cc and a melt index (I2) from 0.01 to 5 g/10 min; and from 5 wt. % to 40 wt. % of a second polyethylene composition comprising: (i) a high density polyethylene having a density greater than or equal to 0.940 g/cc; and (ii) a maleic-anhydride grafted polyethylene.
    Type: Grant
    Filed: April 18, 2019
    Date of Patent: May 31, 2022
    Assignee: Dow Global Technologies LLC
    Inventors: Dane Chang, Condell Doyle
  • Patent number: 11274201
    Abstract: A thermoplastic resin composition of the present invention comprises a rubber-modified vinyl-based graft copolymer, a first aromatic vinyl-based copolymer, a second aromatic vinyl-based copolymer, and a polyalkylene glycol, wherein the first aromatic vinyl-based copolymer is a copolymer of methyl methacrylate, methyl acrylate, an aromatic vinyl-based monomer, and a monomer copolymerizable with the aromatic vinyl-based monomer, the second aromatic vinyl-based copolymer is a copolymer of an aromatic vinyl-based monomer and a monomer copolymerizable with the aromatic vinyl-based monomer, and the weight ratio of methyl methacrylate to methyl acrylate, in the first aromatic vinyl-based copolymer, is approximately 1:0.01 to approximately 1:0.2. The thermoplastic resin composition has excellent discoloration resistance, color, transparency, and the like even after irradiation with ionizing radiation.
    Type: Grant
    Filed: May 30, 2017
    Date of Patent: March 15, 2022
    Assignee: Lotte Advanced Materials Co., Ltd.
    Inventors: Yoen Kyoung Kim, Cheon Seok Yang, Byeong Yeol Kim, Seung Yong Bae, Bong Jae Jeong, Ju Sung Kim
  • Patent number: 11220557
    Abstract: The invention relates to a method for polymerizing acrylates using a reactor (50). Reaction heat produced in the reactor (50) is discharged via a boiling cooler (40) in that gaseous vapors produced in the reactor (50) are supplied to the boiling cooler (40), and condensed vapors are returned to the reactor (50) from the boiling cooler (40). At least one component containing acrylate is at least partly added via the boiling cooler (40) and reaches the reactor (50) via the boiling cooler (40). The invention additionally relates to a system for polymerizing an acrylate, comprising a reactor (50) and a boiling cooler (40) for discharging reaction heat produced in the reactor (50). The boiling cooler (40) has at least one filling opening (46) for supplying at least one component containing acrylate.
    Type: Grant
    Filed: September 5, 2017
    Date of Patent: January 11, 2022
    Assignee: INEOS STYROLUTION GROUP GMBH
    Inventors: Wolfgang Fischer, Peter Ittemann, Florian Patcas, Michael Ruf
  • Patent number: 11214645
    Abstract: The present invention relates to a method for preparing a graft copolymer including polymerizing a conjugated diene-based monomer to prepare a small-size conjugated diene-based polymer; enlarging the small-size conjugated diene-based polymer to prepare a large-size conjugated diene-based polymer; and polymerizing the small-size conjugated diene-based polymer, the large-size conjugated diene-based polymer, an aromatic vinyl-based monomer and a vinyl cyan-based monomer to prepare a graft copolymer, wherein a weight ratio of the small-size conjugated diene-based polymer and the large-size conjugated diene-based polymer is 10:90 to 40:60 in preparing the graft copolymer.
    Type: Grant
    Filed: January 23, 2019
    Date of Patent: January 4, 2022
    Assignee: LG CHEM, LTD.
    Inventors: Joo Byung Chai, Yu Sung Jung, Jong Beom Kim, Chang Sull Kim, Eun Seon Park, Tae Young Jeon, Young Min Kim
  • Patent number: 11214668
    Abstract: A resin composite is provided, which comprises: a first resin layer including a first rubber modified styrene-based resin composition; and a second resin layer including a second rubber modified styrene-based resin composition. The first and second rubber modified styrene-based resin compositions respectively comprise: a styrene-based copolymer; and rubber particles. In the first rubber modified styrene-based resin composition, on the basis of a total weight of all monomer units of the styrene-based copolymer being 100 wt %, the styrene-based copolymer comprises more than or equal to 21.0 wt % to less than or equal to 31.0 wt % of an acrylonitrile-based monomer unit. In the second rubber modified styrene-based resin composition, on the basis of a total weight of all monomer units of the styrene-based copolymer being 100 wt %, the styrene-based copolymer comprises more than or equal to 12.0 wt % to less than 21.0 wt % of an acrylonitrile-based monomer unit.
    Type: Grant
    Filed: September 26, 2019
    Date of Patent: January 4, 2022
    Assignee: CHIMEI CORPORATION
    Inventors: Hung-Jui Kuo, Jui-Hsi Hsu, Chen-Pao Huang
  • Patent number: 10870747
    Abstract: Method for producing a thermoplastic moulding compound containing: up to 40 wt. % of a graft copolymer A, containing 50-70 wt. % graft base A1 from an acrylic ester polymer and 30-50 wt. % of a graft shell A2, and 0-90 wt. % of a hard matrix B, wherein the reaction for producing the graft copolymer A is carried out in the presence of 0.01 to 4 times the molar amount of sodium carbonate, relative to the molar amount of initiator, wherein the reaction for producing copolymer A is carried out in the presence of 0.1 to 1 wt. % of an emulsifier relative to the amount of the respective monomers used, and wherein during the polymerisation reaction, during the post-polymerisation and/or after the polymerisation reaction, water or an aqueous alkali solution are added to the reaction mixture for producing the graft copolymer A.
    Type: Grant
    Filed: September 23, 2016
    Date of Patent: December 22, 2020
    Assignee: INEOS STYROLUTION GROUP GMBH
    Inventors: Wolfgang Fischer, Tobias Schulz
  • Patent number: 10551674
    Abstract: An optical film includes a polarizer, a uniaxially elongated film disposed on the polarizer, and a compensation film disposed on one side of the uniaxially elongated film. The polarizer includes a polymer having a glass transition temperature of greater than about 100° C. and including a structural unit derived from styrene or a styrene derivative. The compensation film has a refractive index satisfying Relationship Equations 1 and 2, the uniaxially elongated film has an in-plane retardation satisfying Relationship Equation 3 and a thickness retardation satisfying Relationship Equation 4, and the compensation film has an in-plane retardation satisfying Relationship Equation 5 and a thickness retardation satisfying Relationship Equation 6. A liquid crystal display including the optical film is also disclosed. Relationship Equations 1 to 6 are described in the detailed description.
    Type: Grant
    Filed: July 15, 2016
    Date of Patent: February 4, 2020
    Assignees: SAMSUNG ELECTRONICS CO., LTD., SAMSUNG SDI CO., LTD.
    Inventors: Sangah Gam, Hyung Jun Kim, Hye Young Kong, Jong Hoon Won, Myungsup Jung, Jong Hyuk Eun
  • Patent number: 10526436
    Abstract: A composition comprising (A) from 10 wt % to 90 wt % of a polymeric ethylene ionomer; (B) from 10 wt % to 40 wt % of a propylene component including at least one propylene based polymer having a propylene content of at least 50.0 wt %, based on the total weight of the propylene based polymer, and a melt flow rate from 0.5 g/10 min to 200.0 g/10 min (according to ASTM D-1238 at 230° C./2.16 kg); and (C) from 5 wt % to 20 wt % of a crystalline block composite.
    Type: Grant
    Filed: March 29, 2017
    Date of Patent: January 7, 2020
    Assignee: Dow Global Technologies LLC
    Inventors: Xiaosong Wu, Ronald J. Weeks, Rennisha Wickham
  • Patent number: 10329415
    Abstract: The present invention relates to a thermoplastic resin composition and, more specifically, to an acrylic resin composition having improved coloring property and heat resistance by comprising an acrylic graft copolymer, an aromatic vinyl-cyano vinyl-based copolymer and an acrylic resin, and thus is suitable for an automotive exterior material.
    Type: Grant
    Filed: July 31, 2014
    Date of Patent: June 25, 2019
    Assignee: Lotte Advanced Materials Co., Ltd.
    Inventors: Ji Eun Park, Young Hyo Kim, Kang Yeol Park, Ja Yoon Kim
  • Patent number: 10273355
    Abstract: A thermoplastic resin composition includes: (A) an acrylic graft copolymer; (B) an aromatic vinyl-vinyl cyanide-based copolymer; (C) a light stabilizer; and (D) a UV absorber having a maximum absorption wavelength of about 250 nm to about 320 nm. The thermoplastic resin composition can realize good coloring properties and weather resistance, while providing a high quality external appearance.
    Type: Grant
    Filed: August 27, 2015
    Date of Patent: April 30, 2019
    Assignee: Lotte Advanced Materials Co., Ltd.
    Inventors: Ji Eun Park, Young Hyo Kim, Ja Yoon Kim, Kang Yeol Park
  • Patent number: 10266615
    Abstract: The present invention relates to a method for preparing an acrylonitrile-butadiene-styrene graft copolymer having improved impact strength, which comprises: a step of preparing diene-based rubber latex by adding an acrylate-based cross-linking agent (Step 1); and a step of inserting the same cross-linking agent with the acrylate-based cross-linking agent, an aromatic vinyl-based compound and a vinyl cyan-based compound to the diene-based rubber latex and then subjecting thereof to graft copolymerization (Step 2), an acrylonitrile-butadiene-styrene graft copolymer prepared by the method, and an acrylonitrile-butadiene-styrene thermoplastic resin comprising the same.
    Type: Grant
    Filed: May 26, 2017
    Date of Patent: April 23, 2019
    Assignee: LG CHEM, LTD.
    Inventors: Sun Haeng Chung, Young Min Kim, Jin Hyoung Lee, Su Jeong Han, Yoo Vin Kim, Young Hwan Jeong, Jae Min Suk
  • Patent number: 10233267
    Abstract: The present invention relates to a method for preparing an acrylonitrile-butadiene-styrene graft copolymer having improved impact strength, which comprises: a step of preparing diene-based rubber latex by adding an acrylate-based cross-linking agent (Step 1); and a step of inserting the same cross-linking agent with the acrylate-based cross-linking agent, an aromatic vinyl-based compound and a vinyl cyan-based compound to the diene-based rubber latex and then subjecting thereof to graft copolymerization (Step 2), an acrylonitrile-butadiene-styrene graft copolymer prepared by the method, and an acrylonitrile-butadiene-styrene thermoplastic resin comprising the same.
    Type: Grant
    Filed: May 26, 2017
    Date of Patent: March 19, 2019
    Assignee: LG CHEM, LTD.
    Inventors: Sun Haeng Chung, Young Min Kim, Jin Hyoung Lee, Su Jeong Han, Yoo Vin Kim, Young Hwan Jeong, Jae Min Suk
  • Patent number: 10221322
    Abstract: Water-based compositions that are resistant to dirt pickup are described. The water-based composition includes a latex or water-dispersible polymer and a non-VOC UV-VIS (preferably, ultraviolet) absorber as a dirt pickup resistance additive. Methods of making water-based compositions including a non-VOC UV-VIS absorber as a dirt pickup resistance additive are also described.
    Type: Grant
    Filed: October 17, 2016
    Date of Patent: March 5, 2019
    Assignee: THE SHERWIN-WILLIAMS COMPANY
    Inventors: Mary Jane Hibben, Joseph Klen, Robert Sandoval, T. Howard Killilea
  • Patent number: 10208151
    Abstract: The present invention relates to a method for preparing a diene-based rubber latex having improved impact strength, gloss and flexibility, diene-based rubber latex prepared therefrom, and an acrylonitrile-butadiene-styrene graft copolymer having improved impact strength and production yield while having reduced rubber solid content ratio by comprising the same.
    Type: Grant
    Filed: December 10, 2015
    Date of Patent: February 19, 2019
    Assignee: LG CHEM, LTD.
    Inventors: Jae Min Suk, Young Min Kim, Jin Hyoung Lee, Su Jeong Han, Yoo Vin Kim, Young Hwan Jeong, Sun Haeng Chung
  • Patent number: 9644090
    Abstract: The invention relates to a polymer mixture made of styrene/nitrile monomer copolymers and of graft copolymers based on acrylate rubbers, and also to thermoplastic moulding compositions and mouldings produced therefrom and use of these.
    Type: Grant
    Filed: August 6, 2013
    Date of Patent: May 9, 2017
    Assignee: INEOS STYROLUTION EUROPE GMBH
    Inventors: Norbert Niessner, Michael Ishaque, Philipp Böckmann, Rolf Minkwitz
  • Patent number: 9487631
    Abstract: A polymer comprising a bulk polymer or copolymer PB together with an amount of a polymer-dendron additive D-PD of formula (I): is provided, such that the polymer comprises from 0.
    Type: Grant
    Filed: May 22, 2006
    Date of Patent: November 8, 2016
    Assignee: University of Durham
    Inventors: Lian Richard Hutchings, William James Feast, Richard Lewis Thompson, Amilcar Pillay-Narrainen
  • Patent number: 9447219
    Abstract: The ductility/stiffness balance of a rubber-modified monovinylidene aromatic polymer, e.g., HIPS, is increased without increasing the rubber content of the polymer and/or changing the size of the average rubber particle by a process comprising the step of crosslinking the rubber such that the rubber-modified polymer has an optical crosslink index (OCLI) of <0.5 and an injection molded/compression molded (IM/CM) modulus ratio ?1.3.
    Type: Grant
    Filed: October 6, 2010
    Date of Patent: September 20, 2016
    Assignee: Styron Europe GMBH
    Inventors: Gilbert C. E. Bouquet, Fredericus Slijkerman
  • Patent number: 9442073
    Abstract: Sensors (40) are described which comprise a reflective layer (52), a detection layer over the reflective layer (52), a semi-reflective layer (50) over the detection layer (48), and a masking layer (57) affixed to the reflective layer with a high Tg adhesive.
    Type: Grant
    Filed: March 5, 2012
    Date of Patent: September 13, 2016
    Assignee: 3M Innovative Properties Company
    Inventors: Guy D. Joly, Duane D. Fansler, Neal A. Rakow
  • Patent number: 9365711
    Abstract: The invention provides a composition comprising at least the following: A) an ethylene/a-olefin interpolymer with a density ?0.90 g/cc, and an I2 greater than 10; B) a functionalized olefin-based polymer; and C) an olefin-based polymer with a density greater than 0.90 g/cc, and selected from the group consisting of the following: a) an ethylene homopolymer, b) an ethylene/?-olefin interpolymer, c) a propylene/ethylene interpolymer, and d) a propylene/?-olefin interpolymer; and wherein the [density (C)?density (A)] is greater than, or equal to, 0.017; and wherein the weight ratio of [(A+C)/B] is greater than, or equal to, 3.0.
    Type: Grant
    Filed: September 21, 2012
    Date of Patent: June 14, 2016
    Assignee: Dow Global Technologies LLC
    Inventor: Ronald J. Weeks
  • Patent number: 9333785
    Abstract: There is provided an apparatus for forming a thermal transfer printing sheet. The apparatus includes: a release sheet feeder that feeds a release sheet having a release surface; a first image forming section that transfers an image, which is to be thermally transferred and printed on a transfer medium, onto the release surface of the release sheet; a second image forming section that forms a thermoplastic resin pattern corresponding to the image as a transfer base material and transfers the thermoplastic resin pattern onto the release surface of the release sheet; and a fixing section that fixes the image and the thermoplastic resin pattern onto the release surface of the release sheet in a film shape, through heat and pressure.
    Type: Grant
    Filed: September 7, 2012
    Date of Patent: May 10, 2016
    Assignees: CASIO ELECTRONICS MANUFACTURING CO., LTD., CASIO COMPUTER CO., LTD.
    Inventors: Tomohumi Sano, Toshiaki Kanamura, Satoshi Mitsui
  • Patent number: 9243683
    Abstract: A toothed belt is provided that has excellent environment resistance, high load resistance, high stiffness, and achieves high accuracy, light weight, compactness and low noise. A toothed belt is provided with a belt body including a plurality of core wires juxtaposed in the width direction of a rubber portion, a plurality of tooth rubber portions formed on one surface of the belt body, and a tooth cloth covering the surface of the tooth rubber portions. The rubber portion contains dioctyl sebacate and trimellitic acid ester in a mass part ratio of 1:19 to 1:1, the mass percentage of the dioctyl sebacate to the whole quantity of the rubber portion is less than 4 mass %, and the mass percentage of the total quantity of the dioctyl sebacate and the trimellitic acid ester to the whole quantity of the rubber portion is in a range from 4 mass % to 8 mass %.
    Type: Grant
    Filed: January 17, 2014
    Date of Patent: January 26, 2016
    Assignee: Tsubakimoto Chain Co.
    Inventors: Masato Tomobuchi, Hideyuki Sato, Masaru Kanamori, Shoichiro Shimizu
  • Patent number: 9187626
    Abstract: The present invention is an uncoated housing in which a molded product formed from a thermoplastic resin composition (D) containing 20-60% by mass of an acetone insoluble resin component (A), which contains a rubber component (a) with an average particle size of 0.05-0.3 ?m and has a coefficient of linear expansion of 11×10?5-20.5×10?5, 40-80% by mass of an acetone soluble resin component (B) (here, (A)+(B)=100% by mass), and a colorant (C), with (1) the acetone soluble resin component (B) containing 6.0-45% by mass of an unsaturated nitrile monomer derived component and (2) 2-20% by mass of a component with a molecular weight of 70,000 or less by gel permeation chromatography (GPC) measurements being contained in the acetone soluble resin component (B). On the basis of JIS K7105, the L* value for this uncoated housing is 13 or less, the luster 60-120%, and the haze value 30-90%.
    Type: Grant
    Filed: August 10, 2012
    Date of Patent: November 17, 2015
    Assignee: ASAHI KASEI CHEMICALS CORPORATION
    Inventors: Tomoyuki Fujisawa, Hiroharu Itaya
  • Patent number: 9131714
    Abstract: Conventional dried materials have a low oil adsorption property and oil retention ability. Therefore, a dried material that has an excellent oil adsorbing property and oil retention ability has been desired. Accordingly, an object of the present invention is to provide an oil-adsorbing composition that has an excellent oil adsorption property and oil retention ability; a method for producing the oil-adsorbing composition; and a method for using the oil-adsorbing composition.
    Type: Grant
    Filed: October 4, 2011
    Date of Patent: September 15, 2015
    Assignee: MATSUTANI CHEMICAL INDUSTRY CO., LTD.
    Inventors: Seizo Takaoka, Yasutoshi Hishikawa, Hiroyuki Kataoka
  • Patent number: 9127149
    Abstract: A refrigerator interior liner can be made of a composition including a monovinylaromatic polymer matrix having an average molecular weight in weight Mwabove 150,000 g/mol; rubber particles; and low- Mwplasticizers. The rubber particles can have an RPS volume of about 8.5 ?m, a monomodal distribution, a swell index above 13.8, and an RPVF of at least 39%. The composition can be prepared by forming a polymerizable mixture including a monovinylaromatic monomer, and dissolving a viscous rubber in the polymerizable mixture. A free radical initiator and a chain transfer agent can be contacted with the polymerizable mixture at conditions whereby phase inversion subsequently occurs. The chain transfer agent can produce an increase of the rubber to PS phase viscosity ratio within the inversion reactor. Polymerization can be continued until a monovinylaromatic polymer matrix having rubber particles dispersed therein is obtained.
    Type: Grant
    Filed: March 24, 2014
    Date of Patent: September 8, 2015
    Assignee: TOTAL RESEARCH & TECHNOLOGY FELUY
    Inventors: Michel Duc, Jan Neelen, Mark O'Neill
  • Patent number: 9119895
    Abstract: Disclosed is a self-adhesive matrix system comprising a styrene-ethylene/butylene-styrene (SEBS) copolymer in an oil/ethyl acetate mixture, a hydrogenated resin and a pharmaceutical or cosmetic active ingredient.
    Type: Grant
    Filed: December 10, 2009
    Date of Patent: September 1, 2015
    Assignee: BOUTY S.P.A.
    Inventors: Stefania Pagani, Maurizio Di Grigoli, Sergio Comuzio
  • Patent number: 9018295
    Abstract: Golf balls that have at least one layer formed from a cationic polyurea material. In particular, the compositions of the invention, which include a polymer backbone including urea linkages with cationic groups, may be formed from an isocyanate-containing component and an isocyanate-reactive component, at least one of which includes precursor cationic groups, in the presence of an alkylating, quaternizing, or ternarizing agent.
    Type: Grant
    Filed: December 12, 2008
    Date of Patent: April 28, 2015
    Assignee: Acushnet Company
    Inventors: Murali Rajagopalan, Shawn Ricci, Michael J. Sullivan, Kevin M. Harris, Pamela V. Arnold
  • Patent number: 8975334
    Abstract: Provided are crosslinkable propylene-based copolymers, methods for making the same, elastomeric compositions including the same, and articles made therefrom, e.g., films and fibers. Exemplary elastomeric compositions are composed of at least one propylene-based polymer comprising propylene derived units and one or more dienes, the propylene-based polymer having a triad tacticity of from 50% to 99% and a heat of fusion of less than 80 J/g; about 0.5 wt % to about 10 wt % vinyl siloxane; and about 0.1 wt % to about 1.0 wt % peroxide. The elastomeric compositions can be extruded and crosslinked at a temperature of at least about 50° C. and a relative humidity of at least about 90% to provide a crosslinked elastomeric composition. The crosslinked elastomeric compositions are particularly useful for making fibers and films.
    Type: Grant
    Filed: June 25, 2010
    Date of Patent: March 10, 2015
    Assignee: ExxonMobil Chemical Patents Inc.
    Inventor: Sunny Jacob
  • Patent number: 8969476
    Abstract: In one of its aspects the invention is directed to rubber modified thermoplastic resin compositions comprising discontinuous elastomeric phase particles derived from a unitary rubber substrate having at least a bimodal particle size distribution, wherein the elastomeric phase particles comprise a polymer having structural units derived from at least one (C1-C12)alkyl(meth)acrylate monomer and are dispersed in a rigid thermoplastic phase, wherein at least a portion of the rigid thermoplastic phase is grafted as a shell to elastomeric phase core particles, and wherein the rigid thermoplastic phase comprises structural units derived from at least one vinyl aromatic monomer, at least one monoethylenically unsaturated nitrile monomer and at least one (C1-C12)alkyl- or aryl-(meth)acrylate monomer.
    Type: Grant
    Filed: October 27, 2005
    Date of Patent: March 3, 2015
    Assignee: Sabic Global Technologies B.V.
    Inventors: Albin Peter Berzinis, James Edward Pickett
  • Patent number: 8952096
    Abstract: The invention provides graft copolymers obtainable by A) free-radically initiated polymerization of one or more vinyl esters a), one or more further ethylenically unsaturated monomers b) comprising at least one further functional group, B) subsequent polymer-analogous reaction of the copolymers from stage A) by joining the monomer units b) thereof to one or more further monomers b) such that at least one free-radically polymerizable group is introduced into the copolymers from stage A), characterized in that C) one or more ethylenically unsaturated monomers are polymerized onto the products from stage B) by free-radically initiated polymerization.
    Type: Grant
    Filed: December 9, 2009
    Date of Patent: February 10, 2015
    Assignee: Wacker Chemie AG
    Inventors: Florian Bauers, Michael Tobias Zarka
  • Patent number: 8932152
    Abstract: A center of a golf ball is formed from a composition having a flexural modulus from 150-450 MPa, a maximum loss factor (tan ?) between ?20 and 0° C. of 0.08 or less, a rebound resilience of 55% or more, and a slab hardness ranging from 40-60 in Shore D hardness. The center composition includes, as a resin component, 30 to 70 mass % of (A) a modified polyester elastomer having a Shore A hardness of 95 or less; 70-30 mass % of (B) a binary ionomer resin having a Shore D hardness of 65 or more, a flexural modulus of 300 MPa or more, and a melt flow rate (190° C., 2.16 kg) of 1.0 g/10 min or more; and 0-50 mass % of (C) a thermoplastic resin other than (A) and (B) components (provided that a total content of (A), (B), and (C) components is 100 mass %).
    Type: Grant
    Filed: October 4, 2012
    Date of Patent: January 13, 2015
    Assignee: Dunlop Sports Co. Ltd.
    Inventor: Satoko Okabe
  • Publication number: 20150005435
    Abstract: A thermoplastic resin composition includes (A) a first rubber-modified acrylic-based graft copolymer having an average rubber particle diameter of greater than or equal to about 100 nm and less than about 200 nm, (B) a second rubber-modified acrylic-based graft copolymer having an average rubber particle diameter of greater than or equal to about 200 nm and less than or equal to about 400 nm, (C) a first vinyl-based copolymer of an aromatic vinyl monomer and a unsaturated nitrile monomer, and (D) a second vinyl-based copolymer of an alkyl (meth)acrylate monomer, an aromatic vinyl monomer, and a unsaturated nitrile monomer. A molded article can be made using the same.
    Type: Application
    Filed: April 9, 2014
    Publication date: January 1, 2015
    Applicant: Cheil Industries Inc.
    Inventors: Ji-Eun PARK, Ja-Yoon KIM, Kyun-Ha BAN, Chang-Min HONG
  • Patent number: 8911854
    Abstract: The present invention provides an optical film and s retardation film characterized in that each of them includes: an acrylic resin; and 20-65 parts by weight of at least two graft copolymers containing a conjugated diene-based rubber, based on 100 parts by weight of the acrylic resin, wherein at least two of the graft copolymers have different particle sizes. The present invention also provides a production method therefore.
    Type: Grant
    Filed: June 3, 2009
    Date of Patent: December 16, 2014
    Assignee: LG Chem, Ltd.
    Inventors: Byoung-II Kang, Chang-Hun Han, Chan-Hong Lee, Dae-Woo Lee, Jae-Bum Seo, Sang-Seop Kim
  • Patent number: 8895645
    Abstract: A modified-asphalt composition prepared by introducing a diene end-capped block copolymer with a molten asphalt composition, where the block copolymer is defined by the formula ?-(D-V-d)x where each D is independently a polydiene block, each V is independently a vinyl aromatic block, each d is a polydiene end cap, ? is a coupling moiety, and x is an integer from 2 to 10.
    Type: Grant
    Filed: November 8, 2013
    Date of Patent: November 25, 2014
    Assignees: Firestone Polymers, LLC, Heritage Research Group
    Inventors: Christine Rademacher, Timothy Reece, Herb Wissel, Daniel Graves, Peter Boerner
  • Publication number: 20140323654
    Abstract: A process for producing rubber modified polymers having an increased rubber phase volume, including feeding a vinyl aromatic monomer and an elastomer to a polymerization reactor to form a reaction mixture, polymerizing the reaction mixture, combining a copolymer to the polymerized reaction mixture to form a combined mixture, subjecting the combined mixture to further polymerization, and obtaining a rubber modified polymer product from the further polymerization.
    Type: Application
    Filed: July 10, 2014
    Publication date: October 30, 2014
    Inventors: Carlos DeAnda, Graciela Morales, Jose M. Sosa, David Knoeppel
  • Patent number: 8871865
    Abstract: Disclosed is a thermoplastic composition comprising a polycarbonate terpolymer comprising structures derived from structures (I), (II) and (III), wherein (I) is a dihydroxy compound having the structure (A): wherein n is 0 to 4 and Rf is independently a halogen atom, a C1-10 hydrocarbon group, or a C1-10 halogen substituted hydrocarbon group; (II) comprises a second dihydroxy compound derived from Formula (A) and different from (I) and wherein n and Rf are as previously defined; and (III) a third dihydroxy compound not derived from Formula (A), wherein the sum of the mol percent of all of structures (I) and (II) is greater than 45% relative to the sum of the molar amounts of all of structures (I), (II) and (III) in the polycarbonate terpolymer and wherein said polycarbonate terpolymer is amorphous; an impact modifier; an ungrafted rigid copolymer; and a flame retardant. The thermoplastic composition has improved chemical resistance and flame retardance.
    Type: Grant
    Filed: June 12, 2007
    Date of Patent: October 28, 2014
    Assignee: Sabic Global Technologies B.V.
    Inventors: Bernardus Johannes Paulus Jansen, Christiaan Henricus Johannes Koevoets, Edward Kung, Wilhelmus Johannes Daniel Steendam
  • Publication number: 20140308501
    Abstract: Disclosed herein is an acrylic resin film that is less likely to whiten on bending when laminated on a plastic molded body or the like, has well-balanced physical properties such as high surface hardness, excellent transparency, and excellent cracking resistance, and is therefore suitable for use in decorative molding. The acrylic resin film is obtained by forming, into a film, a methacrylic resin composition (D) containing a specific methacrylate-based resin (A), a rubber-containing four-stage graft copolymer (B) containing rubber particles having an average particle size of 0.2 to 0.4 ?m, and a rubber-containing two-layer graft copolymer (C) containing rubber particles having an average particle size of 0.02 to 0.15 ?m.
    Type: Application
    Filed: October 2, 2012
    Publication date: October 16, 2014
    Applicant: KANEKA CORPORATION
    Inventors: Kimihide Nishimura, Nobuhiro Yamamoto
  • Patent number: 8852747
    Abstract: The invention relates to coextrusion binders including renewable and/or biodegradable polymers having good adhesion properties: at least one renewable and/or biodegradable polymer (A) grafted with a functional monomer including at least one reactive function, the grafting ratio being <1% in weight of the grafted polymer (A); at least one non-grafted renewable and/or biodegradable polymer (B) identical to (A) or compatible with (A) optionally a softener (C); and optionally a starch-based material (D). The invention also relates to multilayered structures including the binder of the present invention, in which the layers are preferably made of renewable and/or biodegradable compounds. The multilayered structures are advantageously useful in the field of food packaging.
    Type: Grant
    Filed: May 14, 2008
    Date of Patent: October 7, 2014
    Assignee: Arkema France
    Inventors: Fabrice Chopinez, Johann Laffargue, Jeau-Laurent Pradel, Damien Rauline, Samuel Devisme
  • Patent number: 8835559
    Abstract: A rubber-modified polystyrene resin composition is for making an electroplatable article which has a sectioned layer defining a unit area. The rubber-modified polystyrene resin composition includes a resin matrix, occlusion rubber particles dispersed in the resin matrix, and non-occlusion rubber particles dispersed in the resin matrix. A total sectional area ratio of the occlusion rubber particles to the non-occlusion rubber particles in the unit area ranges from 1.1 to 14.
    Type: Grant
    Filed: November 17, 2011
    Date of Patent: September 16, 2014
    Assignee: Chi Mei Corporation
    Inventors: Chien-Chung Wu, Chun-Ting Kuo, Wen-Yi Su, Chen-Hsiang Fang
  • Publication number: 20140255713
    Abstract: A method for manufacturing a propylene polymer, including: a) fermenting and optionally purifying first renewable materials to produce an alcohol or an alcohol mixture, the alcohol or alcohol mixture including at least isopropanol and/or at least a mixture of ethanol and 1-butanol; b) dehydrating the resulting alcohol or the alcohol mixture to produce an alkene or alkene mixture in a first series of reactors, the alkene or alkene mixture containing at least propylene; c) polymerizing the propylene in a second reactor, optionally in the presence of a comonomer, so as to produce a propylene polymer; d) isolating the propylene polymer obtained in step c); and e) grafting the propylene polymer obtained from step d). A grafted propylene polymer capable of being obtained by the method, to the compositions containing the polymer, as well as to the uses of the polymer.
    Type: Application
    Filed: May 21, 2014
    Publication date: September 11, 2014
    Applicant: ARKEMA FRANCE
    Inventors: Samuel DEVISME, Fabrice CHOPINEZ, Jean-Laurent PRADEL, Guillaume LE, Thomas ROUSSEL, Jean-Luc DUBOIS
  • Patent number: 8822597
    Abstract: A process for producing rubber modified polymers having an increased rubber phase volume, including feeding a vinyl aromatic monomer and an elastomer to a polymerization reactor to form a reaction mixture, polymerizing the reaction mixture, combining a copolymer to the polymerized reaction mixture to form a combined mixture, subjecting the combined mixture to further polymerization, and obtaining a rubber modified polymer product from the further polymerization.
    Type: Grant
    Filed: April 28, 2011
    Date of Patent: September 2, 2014
    Assignee: Fina Technology, Inc.
    Inventors: Carlos DeAnda, Graciela Morales, Jose M. Sosa, David Knoeppel